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5-Methoxy-diethyltryptamineThe Drug Enforcement Administration's Special Testing and Research Laboratory
generated this monograph using structurally confirmed reference material.
Page 1 of 5SWGDRUG.org/monographs.htmLatest Revision: 1/8/2015
NH
NCH3
CH3OCH3
Form Chemical Formula Molecular Weight Melting Point (oC)
Base C15H22N2O 246 Not Determined
HCl C15H22N2O. HCl 282 Not Determined
1. GENERAL INFORMATION
IUPAC Name:
CAS#:
Synonyms:
Source:
Appearance:
UVmax(nm):
N,N-diethyl-2-(5-methoxy-1H-indol-3-yl)ethanamine
Not Available
5-Methoxy-DET, 5-MeO-DET
DEA Reference Material Collection
Brown powder
Not Determined
2. CHEMICAL AND PHYSICAL DATA
2.1 CHEMICAL DATA
5-Methoxy-diethyltryptamineThe Drug Enforcement Administration's Special Testing and Research Laboratory
generated this monograph using structurally confirmed reference material.
Page 2 of 5SWGDRUG.org/monographs.htmLatest Revision: 1/8/2015
3. QUALITATIVE DATA
3.1 NUCLEAR MAGNETIC RESONANCE
Sample Preparation: Dilute analyte to ~25 mg/mL inD2O containing TSP for 0 ppm reference and maleicacid as quantitative internal standard.
Instrument: 400 MHz NMR spectrometerParameters: Spectral width: at least containing -3 ppm through 13 ppm
Pulse angle: 90o
Delay between pulses: 45 seconds1H NMR: 5-Methoxy-diethyltryptamine HCl Lot 2DAK-29-05; D2O; 400MHz
8 7 6 5 4 3 2 1 0
0
1
2
3
4
5
6
7
8
9
10
66231111
TMSMaleic Acid
HDO
7.25 7.00
0
0.25
0.50
1111
3.4 3.3 3.2 3.1
62
1.275
6
3.900
3
5-Methoxy-diethyltryptamineThe Drug Enforcement Administration's Special Testing and Research Laboratory
generated this monograph using structurally confirmed reference material.
Page 3 of 5SWGDRUG.org/monographs.htmLatest Revision: 1/8/2015
3.2 GAS CHROMATOGRAPHY/MASS SPECTROMETRY
Sample Preparation: Dilute analyte ~4 mg/mL base extracted into chloroform.
Instrument:Column:Carrier Gas:Temperatures:
Agilent gas chromatograph operated in split mode with MS detector HP-5 MS (or equivalent); 30m x 0.25 mm x 0.25 µmHelium at 1 mL/minInjector: 280oCMSD transfer line: 280oCMS Source: 230oCMS Quad: 150oCOven program:
1) 100oC initial temperature for 1.0 min2) Ramp to 300oC at 12 oC/min3) Hold final temperature for 9.0 min
Injection Parameters: Split Ratio = 20:1, 1 µL injectedMS Parameters: Mass scan range: 30-550 amu
Threshold: 100Tune file: stune.uAcquisition mode: scan
Retention Time: 14.090 minEI Mass Spectrum: 5-Methoxy-diethyltryptamine HCl Lot # 2DAK-29-05
m/z240220200180160140120100806040
[x 1
06 ]In
tens
ity
1
2
3
4
5
6
303030 3030303030 3030303030 3030303030 30303030
424242 4242424242 4242424242 4242424242 42424242
585858 5858585858 5858585858 5858585858 58585858636363 6363636363 6363636363 6363636363 63636363 777777 7777777777 7777777777 7777777777 77777777
868686 8686868686 8686868686 8686868686 86868686
103
103
103
103
103
103
103
103
103
103
103
103
103
103
103
103
103
103
103
103
103
103 11
711
711
711
711
711
711
711
711
711
711
711
711
711
711
711
711
711
711
711
711
711
7
130
130
130
130
130
130
130
130
130
130
130
130
130
130
130
130
130
130
130
130
130
130
145
145
145
145
145
145
145
145
145
145
145
145
145
145
145
145
145
145
145
145
145
145 160
160
160
160
160
160
160
160
160
160
160
160
160
160
160
160
160
160
160
160
160
160
174
174
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174
174
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174
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174
188
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188
188
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188
188
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188
188
188
188
188
188
188
204
204
204
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204
204
204
204
204
204
204
204
204
204
204
204
204
204
204
204
204
204
215
215
215
215
215
215
215
215
215
215
215
215
215
215
215
215
215
215
215
215
215
215
228
228
228
228
228
228
228
228
228
228
228
228
228
228
228
228
228
228
228
228
228
228
241
241
241
241
241
241
241
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241
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241
241
241
241
241
241
241
241
241
241
241 24
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
624
6
EI+
5-Methoxy-diethyltryptamineThe Drug Enforcement Administration's Special Testing and Research Laboratory
generated this monograph using structurally confirmed reference material.
Page 4 of 5SWGDRUG.org/monographs.htmLatest Revision: 1/8/2015
3.3 INFRARED SPECTROSCOPY (FTIR)
Insrument: FTIR with diamond ATR attachment (1 bounce)Scan Parameters: Number of scans: 32
Number of background scans: 32Resolution: 4 cm-1
Sample gain: 8Aperture: 150
FTIR ATR (Diamond, 1 Bounce): 5-Methoxy-diethyltryptamine HCl Lot # 2DAK-29-05
Wavenumber (cm-1)3500 3000 2500 2000 1500
%Tr
ansm
ittan
ce
20
30
40
50
60
70
432432432432432432432432432432432432432432432432432432432432432432
642642642642642642642642642642642642642642642642642642642642642642
700700700700700700700700700700700700700700700700700700700700700700
810810810810810810810810810810810810810810810810810810810810810810
823823823823823823823823823823823823823823823823823823823823823823
92692692692692692692692692692692692692692692692692692692692692692610281028102810281028102810281028102810281028102810281028102810281028102810281028102810281099
109910991099109910991099109910991099109910991099109910991099109910991099109910991099
1178117811781178117811781178117811781178117811781178117811781178117811781178117811781178
1215121512151215121512151215121512151215121512151215121512151215121512151215121512151215
1225122512251225122512251225122512251225122512251225122512251225122512251225122512251225
12401240124012401240124012401240124012401240124012401240124012401240124012401240124012401460
1460146014601460146014601460146014601460146014601460146014601460146014601460146014601491
149114911491149114911491149114911491149114911491149114911491149114911491149114911491
1624162416241624162416241624162416241624162416241624162416241624162416241624162416241624
2596259625962596259625962596259625962596259625962596259625962596259625962596259625962596
2640264026402640264026402640264026402640264026402640264026402640264026402640264026402640
2939293929392939293929392939293929392939293929392939293929392939293929392939293929392939
3184318431843184318431843184318431843184318431843184318431843184318431843184318431843184
Wavenumber (cm-1)1700 1600 1500 1400 1300 1200 1100 1000 900 800 700
%Tr
ansm
ittan
ce
20
30
40
50
60
70
432432432432432432432432432432432432432432432432432432432432432432
642642642642642642642642642642642642642642642642642642642642642642
700700700700700700700700700700700700700700700700700700700700700700
710710710710710710710710710710710710710710710710710710710710710710
810810810810810810810810810810810810810810810810810810810810810810
823823823823823823823823823823823823823823823823823823823823823823
926926926926926926926926926926926926926926926926926926926926926926
1028102810281028102810281028102810281028102810281028102810281028102810281028102810281028
10661066106610661066106610661066106610661066106610661066106610661066106610661066106610661099
109910991099109910991099109910991099109910991099109910991099109910991099109910991099
1178117811781178117811781178117811781178117811781178117811781178117811781178117811781178
1215121512151215121512151215121512151215121512151215121512151215121512151215121512151215
1225122512251225122512251225122512251225122512251225122512251225122512251225122512251225
1240124012401240124012401240124012401240124012401240124012401240124012401240124012401240
1439143914391439143914391439143914391439143914391439143914391439143914391439143914391439
14461446144614461446144614461446144614461446144614461446144614461446144614461446144614461460
1460146014601460146014601460146014601460146014601460146014601460146014601460146014601491
149114911491149114911491149114911491149114911491149114911491149114911491149114911491
1624162416241624162416241624162416241624162416241624162416241624162416241624162416241624
5-Methoxy-diethyltryptamineThe Drug Enforcement Administration's Special Testing and Research Laboratory
generated this monograph using structurally confirmed reference material.
Page 5 of 5SWGDRUG.org/monographs.htmLatest Revision: 1/8/2015
4. ADDITIONAL RESOURCES
No resources identified as of 1/8/15.
Recommended