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Reagents!
Hey guys! Here’s a list of the reagents that I think are important to know. Remember, this list is not completely comprehensive! I can’t include every single reagent on here, but this should
have most of the big ones. All of the images on here come from the Smith textbook. In fact, all of this information mostly comes from the Key Concepts sections of your textbook. I just
compiled them into this document!
Please make sure to review other study materials in addition to this! Best of luck!!! You can do this!
Chapter 16
Electrophilic Addition
H-X
Chapter 18
Electrophilic aromatic Substitution
Halogenation
X2 / FeX3
Nitration
HNO3 / H2SO4
Sulfonation
SO3 / H2SO4
Friedel-Crafts Alkylation
RCl / AlCl3
Friedel-Crafts Acylation
RCOCl / AlCl3
Nucleophilic Aromatic Substitution
Strong nucleophiles! (-OH, -OR, -NH2, -SR)
Addition elimination
Elim-Add: EXTREME CONDITIONS; BENZYNE INTERMEDIATE
Halogenation of alkyl benzenes
Oxidation of alkyl benzenes
Reduction
Chapter 19
Preparation of carboxylic acids
Oxidation of primary alcohols
Oxidation of alkyl benzenes (see ch 18)
Oxidative Cleavage of Alkynes
Not a reagent but might be useful: general acid-base rxn of carboxylic acids
Chapter 20
General stuff:
Nucleophilic addition
Nucleophilic Substitution
Reduction:
REDUCTION, here’s a nice couple of chart things:
Oxidation
Organometallic reagents!
Protecting groups are a thing you should probably review!
TBDMS-Cl/ imidazole is an example. Step 3 is deprotection.
Grignard + Carbon dioxide -> carboxylic acid
Chapter 21
Nucleophilic addition
Wittig
Chapter 22
Nucleophilic acyl substitution
Chapter 23
Chapter 24
Chapter 25
Chapter 26
Chapter 27
Chapter 28 doesn’t really have much in terms of reagents
Chapter 29
Chapter 30 doesn’t really have much in terms of reagents
Miscellaneous charts/Figures
GOOD LUCK Y’ALL!!! HAPPY STUDYING!~
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