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Advanced Materials International Forum, Bari 18-19 settembre, conferenza internazionale dedicata ai materiali avanzati e alle loro possibili applicazioni nei settori industriali, con un focus particolare sui trasporti (aerospazio, automotive, navale e cantieristico).
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INTEGRATED APPROACH FOR THE DEVELOPMENT OF ADVANCED STRUCTURES AND SYSTEMS
Luigi Ambrosio
Department of Chemical Science & Materials Technology
National Research Council
P.Le A. Moro, 7 – 00185 Roma
direttore.dsctm@cnr.it
www.dsctm.cnr.it
CHEMICAL METHODOLOGYROMA
MACROMOLECULESMLANO, MMILANO, Genova, Biella
NANOSTRUCTURED MATERIALSROMA, Bologna ,Palermo
ORGANIC SYNTHESIS & PHOTOREACTIVITYBOLOGNA, Ferrara
MOLECULAR SCIENCE & TECHNOLOGYMILANO, Padova, Perugia
MEMBRANE TECHNOLOGYCOSENZA, Padova
CRYSTALLOGRAPHYBARI , Roma, Trieste
ENERGY & INTERPHASESPADOVA , Genova, Lecco, Milano, Pavia
POLYMERS, CCOMPOSITES & BIOMATERIALSNAPOLI , Catania, Pisa, Trento
CHEMISTRY & MOLECULAR RECOGNITIONMILANO, Roma
CHEMISTRY OF ORGANOMETALLIC COMPOUNDSFIRENZE, Bari, Pisa
BIOMOLECULAR CHEMISTRY
NAPOLI, Sassari, Catania, Roma, Padova
CERAMIC MATERIALS SCIENCE & E TECHNOLOGYFAENZA
INSTITUTES
http://www.dsctm.cnr.it/ direttore.dsctm@cnr.it 7812
534
206
48
Amministrativo
Dirigente
Ricercatore
Tecnico
Tecnologo
Dipartimento Scienze Chimiche e Tecnologie dei Materiali
Tot Personale 878
CHEMICAL-PHYSICAL PROCESSES
MESSINA, Bari, Pisa, Roma, Rende
RESEARCH PLATFORMS
NANOMEDICINE SUISTANABLE CHEMISTRY ADVANCED MATERIALS
KEY ENABLING TECNOLOGIES
- Tissue Engineering
- Natural biopharmaceutical
molecules
- Drug delivery
- Drug discovery
- Nanoparticles
- Biosensors
- Nutraceutics
- Teranostic
- Modelling
-Energy from renewable sources
- Hydrogen generation
and storage
-Carbon Capture and
Sequestration
-Biorefinery
- Intermediates & Biomaterials
-Chemical processes with low
environmental impact
- Modelling
- Nanostructures
- Polymers & Composites
- Ceramics & Composites
- Metals & Composites
- Biodegradable Materials
- Multifunctional Biomaterials
- Coatings & Adhesive
- Nanostructured Membranes
- Optoelectronic& Photonics
- Sensors
- Rapid Prototyping
Made in Italy Health Energy Transports Advanced
Manufacturing Industrial Processes Cultural Heritage Building
• New sustainable chemical processes with
high efficiency and selectivity.
• Electro/photocatalysis & and renwable fluorescent
composites for applications in the energy sector.
• Hydrogen chemistry and technology: production,
storage and employment in fuel cells.
• Organic and organometallic compounds for third
generation photovoltaics
• Technologies for C1-chemistry: CO2 exploitation
and confinement (CCS)
• Intermediates
• Functional nanostructure membranes
• Protein based thermoplastic products
• Multifunctional biomaterials
• Packaging
CNR patent, 2011
CNR patents, 2006 - 2012
Recemic substrate enzyme ProductOrgani
c
phase
100%
0
%
Aq
phaseMembrane
Recemic substrate enzyme ProductOrgani
c
phase
100%
0
%
Aq
phaseMembrane
Science 2012
0 1000 2000 3000 4000 5000 6000
0
20
40
60
80
100
120
% rilasciata in EtOH
% rilasciata in H2O
% r
ila
scia
ta
t (min)
SUSTAINABLE CHEMISTRY Main Activities -
Results
µm mm nm
• Multi scale polymer nano-composite
100 m100 m100 m100 m100 m100 m
SOLUTIONS SINGLE SHEETS BULK MATERIALS
• Graphene based materials
• Ceramics and metals for extreme conditions
• Materials technology for cultural heritage FEG-SEM
• Silk fibroin in optoelectronics devices:
Transistors & light emitting transistors
ADVANCED MATERIALS & KEY ENABLING
TECHNOLGY Main Activities -
Results
•Development of new drugs and diagnostics on molecular basis.
•Protein expression, Structural and Computational Biology, Cellular
Biology, HTS technologies.
• Isolation and characterization of new molecules from natural
substances for health, cosmetics and pharmaceuticals.
• Magnetic nano-composite scaffolds
• Electrospun nanostructured
platforms.
• Hydrogels for Protein release for
central nervous pathology
•Biosensors
•Bio-electronics platforms - Transparent
Organic Cell Stimulating and Sensing
Transistors for neural cells
Electrospun nanostructured platforms
Nature Materials, May 2013
O
O
O
OH OH
O O
O
O
Onchidium sp.Onchidium sp.
Onchidium sp.
NANOMEDICINE Main Activities -
Results
54 Patents
Health
Materials &
Enabling
Technologies
Sustainability
PATENTS & SPIN-OFF
INTERNATIONAL AGREEMENTS
Advanced Materials & Silk Platform
Biomaterials for Health – Advanced
Materials - Education
Advanced Materials - Education
Green Chemistry – Biotechnology
Advanced Materials - Membranes
ROLE IN EUROPEAN STRATEGY
INTERNATIONAL COOPERATION
Member of High Level Group
Key Enabling Technologies (KETs)
Tenders – Methodology, work plan and
roadmap for cross-cutting KETs activities in
Horizon 2020.
NANOREG – Coord. Ministry of Infrastructure
and the Environment - The Netherland
A common European approach to the regulatory
testing of nanomaterials.
ADVANCED MATERIALS & KEY ENABLING
TECHNOLGY
Al-Ti based inter-
metallic alloys for
blades turbine
Ni based alloys for
mono-crystalline
components
Development and
thermo-physic
characterization of
high TT SMA alloys
for functional
components 75 nm
g =(111)
75 nm
g =(111) B = [0-11]
T
B = [0-11]
T
--- twinning --- matrix
Systems: Ag ,Cu ,Pb alloys
Alloy with Mp< 1200°C
CuZnAl SMA
Applications: heat exhanger ,
high surface electrodes,
catalysis; structural components
INNOVATIVE ALLOYS
METALLIC FOAMS
Ultra High Temperature Ceramics for Aerospace
Polymers – Epoxies
– Polyolefins: PP
– Thermoplastic polyurethanes (TPU)
– Polyesters: PET
– Biopolymers: PCL (natural fibers)
– Engineering thermopl: PES, PEN, PEEK
Nano reinforcements – CNT
– Clay
– Silica
– Graphene
Fibers - Carbon
- Glass
- Kevlar,......
Fiber & nano reinforcing composites
The activities were performed in the
framework of the project “ARCA ” granted
to IMAST Scarl by Italian Ministry M.I.U.R.
nm µm mm m
A. Martone, C. Formicola, M. Giordano, M. Zarrelli. “Reinforcement Efficiency of Multi-Walled Carbon Nanotube/epoxy nanocomposite” – Composite Science and
Technology, Volume 70, Issue 7, pp. 1154-1160 (2010) DOI: 10.1016/j.compscitech.2010.03.001
A. Martone, G. Faiella, V. Antonucci, M. Giordano, M. Zarrelli. “The effect of the aspect ratio of carbon nanotubes on their effective reinforcement modulus in an epoxy
matrix” - Composites Science and Technology (2011) DOI: 10.1016/j.compscitech.2011.04.002
A. Martone, M. Giordano, V. Antonucci, M. Zarrelli, 2011. Enhancing damping features of advanced polymer composites by micromechanical hybridization. Composites
Part A: Applied Science and Manufacturing 42, 1663-1672. doi:10.1016/j.compositesa.2011.07.019
Cfr. S. Ijima, J. Chem. Phys. 104 (5),1996
tanδ vs % wt
1 % 3%
1 %wt MWNT
Loss factor vs T
Multi scale composites enhancing damping features
GRAPHENE MAINSTREAM
RESEARCH
EUROPEAN
PROJECTS
INDUSTRIAL
COLLABORATIONS
New Initiative:
FET FLAGSHIP
1 Billion €/10 years
100 m100 m100 m100 m100 m100 m
SOLUTIONS SINGLE SHEETS BULK MATERIALS
Coordination of two EU projects on graphene-
organic hybrids (1 Marie Curie ITN + 1 ESF
EUROCORES)
CNR is one of the official Partner of the
GRAPHENE FLAGSHIP initiative
GRAPHENE NANO-TECHNOLGY PLATFORM
GRAPHENE COMPOSITES
Neat matrices
Commodity: PE, EVA, PS
Thermoplastic polyurethanes (TPU)
Polyesters: PET, PEN, PLA, PCL
Biopolymers: Zein, Collagen
Engineering: PES, PC, PPSU, PEI
Batch foaming
Nanocomposites
EVA: clay
PP: clay
TPU: MWCNT
PET: MWCNT, Clay
PEN: SiO2, Expanded Graphite, clay (MMT)
PES: SiO2, Expanded Graphite
Process-properties: rheology, gas solubility and diffusivity, modelling
Materials
THERMOPLASTIC FOAMS
Complex structures and shapes can be obtained by combining foaming of the core and skin consolidation directly in the mold
Thermoplastic nanocomposite skins
Nanocomposite
foamed core In situ foaming
PEN/graphene nanocomposites
Sandwich structures: in situ foaming
Ultrasonic Waves
Protein layer makes
the surface of
graphite hydrophilic
Protein-coated sheets of
graphene detach from
graphite
Controlling the electrical conductivity of proteins with graphene
Electroactive
Polymers
Bio-sensors
Smart Materials
500
nm
1.E-08
1.E-07
1.E-06
1.E-05
1.E-04
0% 0.10% 0.30% 0.60%
GO Content [wt/wt%]
Ele
ctr
ica
l C
on
du
cti
vit
y [
S/m
]
Thermoplastic zein/graphene bionanocomposites
NANOMEDICINE
NANOMEDICINE
Personalized Medicine Main Activities -
Results
3 D RAPID PROTOTYPING SCAFFOLDS
3D IMAGING (TAC, MRI)
HUMAN BODY
CAD AND
MODELING
3D PRINTING
CUSTOM-MADE SCAFFOLD DESIGN & PREPARATION
PROTOTYPE
MICRO-CT SKYSCAN 1072
A System Approach for Tissue Regeneration
EDUCATION: INTEGRATION OF KNOWLEDGE
ADVANCED
MATERIALS
INDUSTRIAL
BIOTECHNOLOGY
NANOTECHNOLOGY
MICRO & NANO
ELECTRONICS
ADVANCED
MANUFACTURING
SYSTEMS
PHOTONICS
…..TO DEVELOP FUTURE HUMAN CAPITAL AND SKILLS
ADVANCED STRUCTURES
&
TECHNOLOGIES
CONCLUSIONS
9/13/2
014
22
• The Materials Science play a central role in
finding innovative solutions to major societal
challenges;
• Materials Science is one of the driving
forces of innovation with significant impact on
all strategic industrial sectors;
• Materials are fundamental for the KETs and
their cross-cutting aspects.
• Key Enabling Technologies approach &
integration will foster European Industrial
Renaissance (COM (2014) 14/2)
The Major Event on Technologies During
the Italian Presidency of Europe
23
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