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Page 1: The Impact of Next Generation Storage on the Electric Grid

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JOINT CENTER FORENERGY STORAGE RESEAR

The Impact of Next GenerationElectricity Storage on the Grid

George CrabtreeDirector, JCESR

Argonne National aboratory!ni"er#ity of Illinoi# at Chicago

Outline$pport%nitie#& tran#portation and electricity gridCentral and di#trib%ted #torage

Grid of the f%t%re& #torage, #mart, di#trib%tedithi%m'ion or beyond lithi%m'ion(

EPIC

University of ChicagoDecember 9, 201

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Todayithi%m'ion batterie# enable the per#onal electronic# re"ol%tion

>ore"er changed the +ay +e interact+ith people and information

Tomorrow

)20* electric carsDis#lace gasoline cars+e#lace foreign oil "ith 'omesticelectricity +e'uce energy use an' carbon emissions

ri'-scale electricity storage.i'es#rea' 'e#loyment of "in' an' solar

Enhance reliability, /e ibility, resilienceUncou#le instantaneous generation

from instantaneous 'eman'

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!S Energy Demand Tran#portation and Electricity Grid

T r a n # p o r t a t i

o n 8 @ =

R e # i d e n t i a l

C o m m e r c i a l

N o n ' e l e

c t r i c

4 4 =

E l e c t r i c i t y

G

r i d A B =

I n d % #

t r i a l

N o n ' e

l e c t r i c

8 8 =

Tran#portation 8@=

Electricity B=

834EIA 0onthly Energy Re"ie+ Table

8 4 70ay 8342:

er#onal electronic# 8=In energy term#, half the marFet forcar# and the grid i# 43x per#onalelectronic#

T+o bigge#t energy %#e#

.i'es#rea' 'e#loyment of electric cars an'storage on the gri' re uires ine #ensive, high

#erformance, ne t generation batteries

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Tran#portation Challenge#

Replace fo##il +ith electric mobility rimary challenge#• Dri"ing range& h%ndred# of mile# in#tead of ten# of mile#• >a#t charging& min%te# in#tead of ho%r#• Inexpen#i"e& H83/ in#tead of H@3/ • Safe& ro%tine and exceptional circ%m#tance#

car cra#h in the rain(

Secondary challenge#Charging infra#tr%ct%re& local and long di#tance

Same tran#portation f%nctionality +ith alternati"e technology)ell de;ned challenge# and targeted o%tcome#

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Electricity Grid Challenge#$pen ne+ hori.on# in grid architect%re and operation Ne+ grid electricity #er"ice#

• >irming %ct%ating rene+able#• Time #hifting exce## +ind and #olar to march demand• Replacing expen#i"e, dirty, ine cient peaFer plant# +ith

inexpen#i"e, clean e cient ba#eload• >reK%ency and "oltage reg%lation for %ltra'#teady, digital'

K%ality po+er• Integrate #torage +ith intelligence and di#trib%ted energy

re#o%rce# for Lgrid of the f%t%reM Secondary challenge#

• Reg%latory en"ironmentNot de#igned for #torageRi#F a"er#e to experiment# to te#t ne+ concept#

• 1%#ine## plan#& ho+ do %tilitie# embrace the grid of thef%t%re(

Dramatically di erent architect%re, f%nctionality and

#er"ice#1road ne+ hori.on# for inno"ation

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40% of US primary energy devoted to electricity production

Electricity - the Great Enabler

source: EPR

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!0

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Electricity as a Sustainable Energy Carrier

coalga#

heat mechanicalmotion electricity

comm%nication

digitalelectronic#

lightingheating

refrigeration

tran#portation

ind%#tryn%clear;##ion

9= of primary energy2= of C$ 8 emi##ion#5 = of energy lo#t

hydro+ind

f%el cell#

#olarelectric

#olarthermal

clean, e cient, "er#atileaccommodate# many#o%rce# and %#e#fo##il and rene+able

e '

e '

load

po+ergrid

Electric"ehicle#

CentralGeneration

Di#trib%ted!#e

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Generation: Wind and Solar Electricity

Stable climateEnergy #ec%rity

Oiable technologie#on deployment path+emaining science challengesimpro"e e ciencylo+er co#t 4 B

@

3 4 B

B

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3

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!S )ind and SolarElectricity

C%m%lati"e In#talledCapacity

+ind

#olar

(ve output: !) *+US ave use: 4,0 *+

- '&"% ofUS electricity

!,% growt./yr 40% wind and solarelectricity y #0'0

, r i '

c o n n

e c t e '

P 2

3 o t

a l

P 2 4 C 5 P

C 5 P

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Time of Day

ba#e loadcoal, n%clear

clean, e cientinexpen#i"e generation

Total !/ElectricityDemand dirty, ine cient,

expen#i"e generation

'ischar

gebattery clean, e cient

inexpen#i"egeneration

Generation& >lattten eaF# and Oalley#

Tipping pointco#t of batterie# le## than

co#t of peaFer plant

peaFpo+e

r

chargebatter

y

di#patchablepo+er

e g , combinedcycle

nat%ral ga#

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48*49*49 4

Smart Grid& T+o )ay Informationand o+er >lo+#

Energy Storage&

Add a ThirdDimen#ion$rea%s the century ol'

constraint to matchinstantaneous generation to

instantaneous 'eman'

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Use7 Distribute' Energy 4 Energy 5torage 4 5mart ri' 8icrogri'

Tailor #er"ice forc%#tomer

• +esi'ence• eighborhoo'• O:ce buil'ings• 5ho##ing center • ;actory • Cam#us• 8ilitary base

$ne #i.e doe# not ;t all

0icrogridGeneration Q Demand Q Storage

• &ocal energy management • +ene"able generation• Co-generation7 electricity4heating• 5hort 'elivery 'istance• +e'uce' 'e#en'ence on gri'• 5ervice #ro<le tailore' to customer • =Personali6e'> energy

A net+orF ofinteracting microgrid#

A DC 0icrogrid(DC component#• 5olar #anel• $attery • &ED lighting• Electronics• Everything e ce#t motors5hort 'elivery 'istance5im#li<e', less e #ensive

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!#e& )hich Side of the0eter(

Pome1attery

http&**+++ a%toe"ol%tion com*ne+#*;r#t'image#'+ith'te#la#'home'battery'leaFed'co%ld'be'rated'at'more'than'233'F+h'B234B html

Store exce## electricity in home battery for later %#e!#e 23= le## electricity from grid

Threaten# %tility b%#ine## plan

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Carbon ano'e8etal O i'e catho'e

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Post-commerciali6ation im#rovement

Crabtree, *ocs, 3rahey, 8+5 $ulletin, In Press

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T R ( 1 S P 2 R T ( T 2 1

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Safety e9uivalent to anatural gas tur ine

JCESR& 1eyond ithi%m'ion 1atterie# for Car# and theGrid Vision

Tran#form tran#portation and the electricity grid

+ith high performance, lo+ co#t energy #torage Mission

Deli"er electrical energy #torage +ith ;"e time# the energyden#ity and one';fth the co#t of today # commercial batterie#

+ithin ;"e year#

Legacies• A library of the fundamental !ien!e of the material# and

phenomena of energy #torage at atomic and molec%lar le"el#• T"o #rototy#e $ one for tran #ortation and one for the

ele!tri!ity %rid , that, +hen #caled %p to man%fact%ring,

ha"e the potential to meet JCESR # tran#formati"e goal#• A ne" #aradi%m for battery R&D that integrate#

di#co"ery #cience, battery de#ign, re#earch prototyping andman%fact%ring collaboration in a #ingle highly interacti"eorgani.ation

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Beyond Lithium-Ion Battery Space is Rich and Unexplored

Three concept#0%lti"alent IntercalationChemical Tran#formationNon'AK%eo%# Redox >lo+

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Pers#ective:i ion; Tran#form tran#portation and electricity grid +ith high

performance, lo+ co#t energy #torage

8i ion; Deli"er electrical energy #torage +ith ;"e time# theenergy den#ity and one';fth the co#t *eyond lithium ion

Legacies:

A library of the fundamental !ien!e of the material# and

phenomena of energy #torage at atomic and molec%lar le"el#T"o #rototy#e $ one for tran #ortation and one for the ele!tri!ity%rid , that, +hen #caled %p to man%fact%ring, ha"e the potential to meet

JCESR # performance and co#t goal#A ne" #aradi%m for battery R&D that integrate# di#co"ery #cience,

battery de#ign, re#earch prototyping and man%fact%ring collaboration ina #ingle highly interacti"e organi.ation

• A bold ne+ approach to battery R D• Accelerate the pace of di#co"ery and inno"ation• 1ring the comm%nity to the beyond lithi%m'ion

opport%nity

0ore on JCESR +eb#ite+++ -ce#r org

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S%pplemental Slide#

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roof'of'conceptrototype# Tran#portation

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ultivalent ntercalation

7.emical Transformation

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E&EC3+OC!E8ICB& DI5CO E+ &B$Wet and dry electrochemical interfaces• Model single crystals• Practical nanoparticles

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201

Tran#portation Energy Storage Arc0%lti"alent'ion Intercalation

Cathode# 1attery Sy#tem0g * Diglyme * O839

Electrolyte#0gVV Sol"ation in Diglyme

E x p e r i m e n t

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8g-solvent- - - 8g-anion

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201 F

e" catho'e7 8n 2OA

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electrolyte#

V

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henol'ba#ed All'0g7DT1 :0gClQ0gCl 8

an et al Chem Comm 94, 5842 78349:

1attery Sy#tem#0g Diglyme'T>SI

7DT1 :0gCl'0gCl 8

O8$ 9

0n 8$ 2

Electrolyte conditioning and#tr%ct%re 0g

#tripping*depo#ition1arile et al, J hy# Chem C 8342, 8349

+ole of ! 2O an' solvent co-intercalation in 2O

autam, Chem 8ater 2?, @?@@ 201 F3e#avcevi% BC5 ano 201

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48*49*49

0ay contain trade #ecret# or commercial or ;nancial information that i# pri"ileged or con;dential and exemptfrom p%blic di#clo#%re

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5333 cycle# Uian et al, Nat%re Comm 5&5 58 78349:

A D'depo#ited arti;cial membrane#& iAlS x& high i cond%cti"ityCompo#ite polymer membrane#& > E'diol V i 8S' 8S9

>lexible, high iV cond%cti"ity, 9O operating +indo+, imper"io%# to poly#%l;de#

B##ealOery high theoretical #peci;c energy 7 ),0?@h 5% :

S%lf%r& Nat%rally ab%ndant, non'toxic, lo+ co#tChallengesIn#tability of i metal i*electrolyte depletion

oly#%l;de 7 S: #h%ttle mechani#m& #elf'di#charge

In#ol%ble S* i8S artial acti"e material%tili.ation

Common to &i-5 ;lo" an' &i-5 5tationary

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+ard a Non'aK%eo%# Redox >lo+ Grid 1attery

Three JCESR inno"ation#

834

Redox $rganic0olec%le#7R$0: 4 nm

De#ign organicmolec%le#

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8349

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Challenge of mixing bet+eenenergy #torage tanF# i# #ol"ed

OH-the-shelf Cellguar' membranes

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Ion #airs are common in 'ivalent solvation shells Bnions an' solvents in 'ivalent solvation shells

are not stable at electrochemical interfaces

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Ne+ opport%nityDesign solvation shell as 'elivery

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8@

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#toring and relea#ing energyReplace intercalation +ith high energychemical reaction& i'S, i'$, Na'S,

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