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    Occupational Safety & Health Program

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    PSM Program Review ChecklistUse this checklist to help determine employer compliance with theProcess Safety Management Standard issued by theOccupational Safety and Health Administration. Please note that the checklist does not include all of the standards

    requirements and does not reflect all OSHAletters of interpretation or compliance directives in particular

    situations.

    There are 3 elements to a review of a PSM program:1. Documentationreviewexamination of the documentation of the programs required by the standard.2. Field Inspection & Verificationexamination of the physical covered process; its equipment, piping,

    instrumentation, procedures, and operation.3. Interviewsdiscussions with employees and contractors to determine if the implemented program matches the

    program outlined in the documentation.

    In order to gather the information needed to audit a PSM program the following questions need to be asked for each PSMprogram element

    Who What When Where Why How WhoWho is responsible for developing and implementing each of the program elements? WhatWhat are the requirements and contents of each program element? WhenWhen are the required actions for each element completed and when were they required to be

    completed?

    WhereWhere have actions been implemented or changed? WhyWhy have the implementation decisions and priorities been made as recorded in the documentation? HowHow is the program implemented and how is the programs effectiveness evaluated and improved?

    An essential part of verifying program implementation is to audit the flow of information and activities among theelements. When information in one element is changed or when action takes place in one element that affects otherelements, an auditor/reviewer should examine a sample of the related elements to see if the appropriate changes andfollowup actions have taken place.

    The following example demonstrates the interrelationship among the elements:During a routine inspection of equipment (Mechanical Integrity), the maintenance worker discovers a valve that nolonger meets the applicable code and must be changed. Because the type of valve is no longer made, a different type of

    valve must be selected and installed (Management of Change). The type of valve selected may mandate different stepsfor the operators (Operating Procedures)who will require training and verification in the new procedures (Training).The rationale for selecting the type of valve must be made available for review by employees and their representatives(Employee Participation).

    When the new valve is installed by the supplier (Contractors), a qualified and safe contractor must be selected to performthe work(Contractor Management). The workwill involve shutting down part of the process (Pre-startup SafetyReview) as well as brazing some of the lines (Safe Work Practices - Hot Work Permit). The employer must review the

    response plan (Emergency Planning) to ensure that procedures are adequate for the installation hazards. AlthoughManagement of Changeprovisions cover interim changes, after the new valve is in place the Process Safety

    Informationwill have to be updated before the (Process Hazard Analysis) is updated or revalidated, to account forpotential hazards associated with the new equipment. Also, inspection and maintenance procedures and training will needto be updated (Mechanical Integrity).

    In summary, 12PSM elements can be affected by changing one valve. A reviewer/inspector/auditor/compliance officerwould check a representative number of these 11 elements to confirm that the required follow-up activities have beenimplemented for the new valve.

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    Application of PSM Standard to Facility - 1910.119(a)

    Does the workplace have any of the following:A process which involves a chemical at or above the specified threshold quantities listed in Appendix A of

    the PSM Standard (attached to checklist); or

    A process which involves a flammable liquid or gas [as defined in 1910.1200(c)] on site in one location, in aquantity of 10,000 pounds (4535.9 kg) or more.

    Exemptions: A threshold quantity of flammable liquids if it is stored in atmospheric tanks or transferred without the

    benefit of chilling or refrigeration

    Hydrocarbon fuels used solely for workplace consumption as a fuel (e.g., propane used for comfortheating or gasoline for vehicle refueling.) These fuels cannot be part of a process containing other

    highly hazardous chemicals covered by the PSM standard.

    Retail facilities. Oil or gas well drilling or servicing operations. Normally unoccupied remote facilities. Note: for determining coverage by the PSM standard, the quantity of flammable liquids stored in

    atmospheric tanks may be excluded from the quantity in the covered process pursuant to the Meer

    Decision.

    Important interpretation: June 11, 2007OSHA defines on-site in one location for PSM to mean that the

    standard applies when a threshold quantity of highly hazardous chemical (HHC) exists within an area underthe control of an employer or group of affiliated employers. It also applies to any group of vessels that are

    interconnected, or in separate vessels that are close enough in proximity that the HHC could be involved in a

    potential catastrophic release.

    * * I F TH E WORKPLACE HAS ANY OF THESE OPERATIONS OR PROCESSES, I T MUST COMPLY

    WITH THE PSM STANDARD. **

    Examples of industries that may have highly hazardous chemicals and processes covered by the PSM standard:

    Industrial production of organics and inorganicmaterials

    Paints Pharmaceuticals Adhesives

    Sealants and Fibers Petrochemical facilities Paper Mills Food Processing with Anhydrous Ammonia over

    the TQ

    Conversion Example

    Gallons to lbs conversion = gal lons x 8.33 x specif ic gravity of the liquid = lbs of li quidExample: Weight of 10,000 gall ons of gasoli ne = 10,000 x 8.33 x 0.739 = 61,559 lbs

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    YES NO Employee Participation1910.119(c)(1)

    Has the employer developed a written plan of action for implementation of employeeparticipation?

    YES NO Employee Participation1910.119(c)(2)Has the employer consulted with employees and their representatives on the conduct and

    development of process hazard analyses and on the development of all other elements of the

    PSM standard?

    YES NO Employee Participation1910.119(c)(3)Do employees and their representatives have access to process hazard analyses and all other

    information required by the PSM standard?

    YES NO Hazard Information Collection1910.119(d)(1)

    Has the employer collected information pertaining to the hazards of the process?

    Toxicity PELs Physical data Reactivity

    Corrosivity Thermal & chemical stability Hazards of mixing chemicals MSDSs

    YES NO Technology of the Process Information Collection1910.119(d)(2)(i)(A)Does the employer have block diagrams or simplified process flow diagrams for each

    covered process?

    YES NO Technology of the Process Information Collection1910.119(d)(2)(i)(B-D)Does the employer have information on the technology of the covered process for the

    following:

    Process chemistry1910.119(d)(2)(i)(B). Maximum intended inventory1910.119(d)(2)(i)(C). Safe upper and lower limits for: temperature, pressures, flows, levels, compositions

    or other pertinent metrics for the process1910.119(d)(2)(i)(D).

    YES NO Technology of the Process Information Collection1910.119(d)(2)(i)(E)Has the employer performed and documented an evaluation of the consequences ofdeviations in the covered process, including those affecting the health and safety of

    employees?

    YES NO Equipment of the Process Information Collection1910.119(d)(3)(i)(A-H)Does the employer have information on the equipment of the covered process for thefollowing:

    Materials of construction1910.119(d)(3)(i)(A). Piping and instrument diagrams (P&IDs)1910.119(d)(3)(i)(B). Electrical classification1910.119(d)(3)(i)(C). Relief system design and design basis1910.119(d)(3)(i)(D). Ventilation system design1910.119(d)(3)(i)(E). Design codes or standards used1910.119(d)(3)(i)(F). Material and energy balances for processes1910.119(d)(3)(i)(G). Safety systems1910.119(d)(3)(i)(H).

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    YES NO Equipment of the Process Information Collection1910.119(d)(3)(i)(A-H)

    Has the PSM documentation including all elements above been field verified and comparedto the actual equipment and components in the covered process?

    YES NO Process Hazard Analysis 1910.119(e)(1)Has the employer performed an initial process hazard analysis on the covered processes?

    YES NO Process Hazard Analysis

    1910.119(e)(2)(i-vii)Has the employer used one or more of the following methodologies to perform the processhazard analysis (PHA)?

    What if1910.119(e)(2)(i). Checklist1910.119(e)(2)(ii). What if/Checklist1910.119(e)(2)(iii). Hazard and Operability Study (HAZOP)1910.119(e)(2)(iv). Failure mode and effects analysis (FEMA)1910.119(e)(2)(v). Fault tree analysis1910.119(e)(2)(vi). An appropriate equivalent methodology1910.119(e)(2)(vii).

    YES NO Process Hazard Analysis

    1910.119(e)(3)(i-vii)Does the PHA(s) address the following?

    Hazards of the process1910.119(e)(3)(i). Equipment in the process1910.119(e)(3)(i). Identification of previous incidents1910.119(e)(3)(ii). Engineering and administrative controls1910.119(e)(3)(iii). Consequences of failure for engineering or administrative controls; including

    consequences of deviation and steps required to correct or avoid deviation

    1910.119(e)(3)(iv). Facility siting1910.119(e)(3)(v). Human factors1910.119(e)(3)(vi). A qualitative evaluation of safety and health effects of failure on employees in the

    workplace1910.119(e)(3)(vii).

    YES NO Process Hazard Analysis 1910.119(e)(4)Was the PHA(s) performed by a team that had the following? Expertise in engineering and process operations. At least one employee with experience and knowledge specific to the covered

    process. With one member of the team knowledgeable in the specific evaluation

    methodology used to perform the PHA.

    YES NO Process Hazard Analysis

    1910.119(e)(5)Does the employer have a system to promptly address PHA findings and recommendations? Does the system address findings and recommendations in a timely manner? Are the resolutions documented? Document actions taken? Is there a written schedule for completion of recommended actions? Has the actions taken or scheduled for resolution of recommendations been

    communicated to employees, contractors or other persons possible impacted by the

    recommendations or actions?

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    YES NO Process Hazard Analysis 1910.119(e)(6)Have PHAs been updated and revalidated at least every five years?

    YES NO Process Hazard Analysis 1910.119(e)(7)Has the employer retained all documentation for PHAs, updates, revalidations,

    recommendations, and resolutions of recommendations?

    YES NO Operating Procedures1910.119(f)(1)

    Has the employer developed and implemented written safe operating procedures for eachcovered process; addressing the steps for each operating phase, the operational limits, safetyand health considerations, and safety systems and their function?

    Steps for each operating phase: Initial startup1910.119(f)(1)(i)(A).Normal operations1910.119(f)(1)(i)(B). Temporary operations1910.119(f)(1)(i)(C). Emergency shutdown including the conditions under which emergency shutdown is

    required, and assignment of responsibility to qualified operators to ensure timely andsafe shutdown1910.119(f)(1)(i)(D).

    Emergency operations1910.119(f)(1)(i)(E).Normal shutdown1910.119(f)(1)(i)(F).

    Startup after turnaround or emergency shutdown1910.119(f)(1)(i)(G).Operating limits: Consequences of deviation1910.119(f)(1)(ii)(A). Steps required to avoid or correct deviation1910.119(f)(1)(ii)(B).

    Safety and health considerations: Properties and hazards of chemicals present in the covered process

    1910.119(f)(1)(iii)(A). Precautions required to prevent exposure; including engineering and administrative

    controls, and PPE1910.119(f)(1)(iii)(B).

    Control measure to be taken if physical or airborne exposure occurs 1910.119(f)(1)(iii)(C).

    Quality control of raw materials and control of hazardous chemical inventory1910.119(f)(1)(iii)(D).

    Any special or unique hazards (like forklifts hitting ammonia refrigeration pipes)1910.119(f)(1)(iii)(E).

    Safety systems and their proper operation1910.119(f)(1)(iv).

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    YES NO Employee Training1910.119(g)(1)Has the employer trained each employee involved in operating a covered process before theemployee is involved in operating the process?

    PSM training programs MUST be developed for: Affected employeesThose not directly involved in the process operation but with

    jobs at the facility with a covered process.

    Authorized employeesThose directly involved in the process operation. Contractors who may perform work on a covered process.

    Vendors/Visitors who may visit the facility and may potentially be exposed to thecovered processPrimarily in emergency evacuation procedures and PPE

    requirements (if necessary).

    Training subjects should include at least the following:

    Lock-out/Tag-out Hot work Line & equipment opening Confined space entry (if applicable) Emergency response Operating procedures Management of Change

    Other Training Subjects May be Required for Authorized Employees and Contractors

    YES NO Employee Training1910.119(g)(2)Has refresher training been provided for employees involved in operating a covered processat least every three years or as needed?

    YES NO Employee Training1910.119(g)(3)

    Has the employer documented all training, ascertaining that employees have received andunderstood the training? Documentation should include the following:

    Identity of employee. Date of training. Means used to verify employee understanding of the training (test, interview, etc.)

    YES NO Contractor Management1910.119(h)(2)(i)

    When selecting a contractor, has the employer obtained and evaluated information regarding

    the contractors safety and health performance and programs?

    YES NO Contractor Management1910.119(h)(2)(ii)

    Has the employer informed contract employer of the known potential fire, explosion ortoxic release hazards related to the contractors work and process?

    YES NO Contractor Management1910.119(h)(2)(iii)

    Has the employer explained to contractor employer the applicable provisions of the

    emergency action plan?

    YES NO Contractor Management1910.119(h)(2)(iv)

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    Has the employer developed and implemented safe work practices to control the entrance,

    presence and exiting of contractors in covered process areas?

    YES NO Contractor Management1910.119(h)(2)(v)Has the employer periodically evaluated the performance of all contractors in fulfilling their

    obligations in regards to training and related documentation of for contractor employees?

    YES NO

    Contractor Management1910.119(h)(2)(vi)Has the employer maintained an illness and injury log (OSHA form 300) for workperformed by contract employees in the covered process area?

    YES NO Contractor Management1910.119(h)(3)(i-iv)Has the contractor employer done the following:

    Trained each contractor employee is trained in the work practices necessary to safelyperform the job.

    Instructed each contractor employee in the known potential fire, explosion or toxicrelease hazards related to the job and process.

    Document that each contractor employee has received and understood the trainingrequired, and the documentation includes the identity of the employee, date oftraining, and means used to verify the contract employee understood the training.

    Ensure that contractor employees follow safety rules of the facility.YES NO Contractor Management1910.119(h)(2)(v)

    Has the contractor notified the employer of unique hazards presented by the contractoremployers work in the covered process area?

    YES NO Pre-Startup Safety Review1910.119(i)Did the employer perform a pre-startup review for all new facilities or modified facilities

    that are modified enough to require change to the process safety information?

    YES NO Mechanical Integrity of Process Equipment1910.119(j)(2)Does the employer have written procedures to maintain the on-going integrity of the

    following process equipment: Pressure vessels and storage tanks. Piping systems (including piping components such as valves.) Relief and vent systems and devices. Emergency shutdown systems. Controls (including monitoring devices and sensors, alarms, and interlocks.) Pumps.

    YES NO

    Mechanical Integrity of Process Equipment

    1910.119(j)(3)Does the employer have documentation of training that each employee involved in the

    maintaining of the on-going integrity of covered process equipment has been informed ofthe hazards of the process and the procedures applicable to the employees job task and how

    to perform the job task in a safe manner?

    YES NO Mechanical Integrity of Process Equipment1910.119(j)(4)

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    Does the employer have documentation that the employer has performed inspections and

    tests on the covered process equipment following generally accepted engineering practicesor manufacturers recommendationson a frequency that is according to generally accepted

    engineering practices, manufacturers recommendations or more frequently if determined by

    prior experience? The documentation should include: date, name of person performing

    inspection or test, description of inspection or test, and results of the inspection or test.

    YES NO Mechanical Integrity of Process Equipment1910.119(j)(5)Has the employer corrected deficiencies in integrity before further use or in a safe and

    timely manner when necessary means are taken to assure safe operation?

    YES NO Mechanical Integrity of Process Equipment1910.119(j)(6)Quality assuranceHas the employer assured that fabricated equipment is suitable for the

    process application (applicable codes), has been inspected and checked for properinstallation consistent with design specification and manufacturers recommendations, and

    all maintenance materials and spare parts are also suitable for the process application?

    YES NO Hot Work1910.119(k)Has the employer issued a hot work permit for hot work operations conducted on or near acovered process?

    YES NO Management of Change1910.119(l)(1-2)Does the employer have written procedures to manage change in the covered process(es)?

    Procedures should cover the following: Technical basis for proposed change. Impact of change on safety and health. Modification to operating procedures.Necessary time period for the change. Authorization requirements for the proposed change.

    YES NO Management of Change1910.119(l)(3)Have affected employees and contractors been informed and trained on change in thecovered process prior to start-up of the process or affected portion of the process?

    YES NO Management of Change1910.119(l)(4-5)Has the employer updated the following procedures, practices and/or documentation

    affected by the change in the process? Process information. Operation procedures or practices. Inspection and testing procedures. PHAs. Flow charts, P&IDs, equipment #s, mechanical integrity certificates, etc.

    YES NO Incident Investigation1910.119(m)(1)Has the employer investigated each incident, which resulted in, or could reasonably haveresulted in, a catastrophic release of highly hazardous chemical in the workplace?

    YES NO Incident Investigation1910.119(m)(2)

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    Has an incident investigation been initiated as promptly as possible, but not later than 48

    hours following the incident?

    YES NO Incident Investigation1910.119(m)(3)Did the investigation team(s) consist of at least one person knowledgeable in the process

    involved, including a contract employee if the incident involved work of the contractor, and

    other persons with appropriate knowledge and experience?

    YES NO Incident Investigation1910.119(m)(4)Did the investigation team issue a report at the conclusion of the investigation which

    included at a minimum the following:

    Date of incident. Date investigation begun. A description of the incident. The factors that contributed to the incident. Any recommendations resulting from the investigation.

    YES NO Incident Investigation1910.119(m)(5)Has the employer established a system to promptly address and resolve incident findingsand recommendations, with documentation of resolutions and corrective actions?

    YES NO Incident Investigation1910.119(m)(6)Has the employer reviewed all incident reports with affected personnel whose job tasks are

    relevant to the incident findings, including contract employees?

    YES NO Incident Investigation1910.119(m)(7)Has the employer retained all incident reports for at least 5 years?

    YES NO Emergency Planning and Response1910.119(n)Has the employer developed and implemented an emergency plan for the entire plant inaccordance with the provisions of 29 CFR 1910.38?

    YES NO Compliance Audit1910.119(o)(1-3)Has the employer performed an audit of the PSM program to certify they have evaluated

    compliance with the provisions of the PSM standard at least every 3 years conducted by at

    least one person knowledgeable in the process, and a report issued?

    YES NO Compliance Audit1910.119(o)(4)Has the employer promptly determined and documented appropriate response to each of the

    findings?

    YES NO Compliance Audit1910.119(o)(5)Has the employer retained the two most recent compliance audit reports?

    YES NO Trade Secrets1910.119(p)Has the employer made all information necessary to comply with the PSM standard

    available to those persons responsible for compiling the process safety information?

    YES NO Trade Secrets1910.119(p)

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    Have employee and their designated representatives had access to trade secret(s)

    information contained within process hazard analysis and other documents required to bedeveloped by this standard?

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    Appendix A1910.119 List of Highly Hazardous Chemicals, Toxics and Reactives

    CHEMICAL NAME CAS* TQ**

    Acetaldehyde 75-07-0 2500

    Acrolein (2-Popenal) 107-02-8 150

    Acrylyl Chlorde 814-68-6 250

    Allyl Chlorid 107-05-1 1000

    Allylamine 107-11-9 1000Alkylaluminum Varies 5000

    Ammonia, Anhydrous 7664-41-7 10000

    Ammonia solutions (greater than 44% ammonia by weight) 7664-41-7 15000

    Ammonium Perchlorate 7790-98-9 7500

    Ammonium Permanganate 7787-36-2 7500

    Arsine (also called Arsenic Hydride) 7784-42-1 100

    Bis(Chloromethyl) Ether 542-88-1 100

    Boron Trichloride 10294-34-5 2500

    Boron Trifluoride 7637-07-2 250

    Bromine 7726-95-6 1500

    Bromine Chloride 13863-41-7 1500

    Bromine Pentafluoride 7789-30-2 2500

    Bromine Trifluoride 7787-71-5 15000

    3-Bromopropyne (also called Propargyl Bromide) 106-96-7 100

    Butyl Hydroperoxide (Tertiary) 75-91-2 5000

    Butyl Perbenzoate (Tertiary) 614-45-9 7500

    Carbonyl Chloride (see Phosgene) 75-44-5 100

    Carbonyl Fluoride 353-50-4 2500

    Cellulose Nitrate (concentrationgreater than 12.6% nitrogen) 9004-70-0 2500

    Chlorine 7782-50-5 1500

    Chlorine Dioxide 10049-04-4 1000

    Chlorine Pentrafluoride 13637-63-3 1000

    Chlorine Trifluoride 7790-91-2 1000

    Chlorodiethylaluminum (also called DiethylaluminumChloride)

    96-10-6 5000

    1-Chloro-2,4-Dinitrobenzene 97-00-7 5000

    Chloromethyl Methyl Ether 107-30-2 500

    Chloropicrin 76-06-2 500

    Chloropicrin and Methyl Bromide mixture None 1500

    Chloropicrin and Methyl Chloride mixture None 1500

    Cumene Hydroperoxide 80-15-9 5000

    Cyanogen 460-19-5 2500

    Cyanogen Chloride 506-77-4 500

    Cyanuric Fluoride 675-14-9 100

    Diacetyl Peroxide (concentration greater than 70%) 110-22-5 5000

    Diazomethane 334-88-3 500

    Dibenzoyl Peroxide 94-36-0 7500

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    CHEMICAL NAME CAS* TQ**

    Diborane 19287-45-7 100

    Dibutyl Peroxide (Tertiary) 110-05-4 5000

    Dichloro Acetylene 7572-29-4 250

    Dichlorosilane 4109-96-0 2500

    Diethylzinc 557-20-0 10000

    Diisopropyl Peroxydicarbonate 105-64-6 7500

    Dilauroyl Peroxide 105-74-8 7500

    Dimethyldichlorosilane 75-78-5 1000

    Dimethylhydrazine, 1,1- 57-14-7 1000

    Dimethylamine, Anhydrous 124-40-3 2500

    2,4-Dinitroaniline 97-02-9 5000

    Ethyl Methyl Ketone Peroxide (also Methyl Ethyl KetonePeroxide; concentration greater than 60%)

    1338-23-4 5000

    Ethyl Nitrite 109-95-5 5000

    Ethylamine 75-04-7 7500

    Ethylene Fluorohydrin 371-62-0 100

    Ethylene Oxide 75-21-8 5000

    Ethyleneimine 151-56-4 1000

    Fluorine 7782-41-4 1000

    Formaldehyde (Formalin) 50-00-0 1000

    Furan 110-00-9 500

    Hexafluoroacetone 684-16-2 5000

    Hydrochloric Acid, Anhydrous 7647-01-0 5000

    Hydrofluoric Acid, Anhydrous 7664-39-3 1000

    Hydrogen Bromide 10035-10-6 5000

    Hydrogen Chloride 7647-01-0 5000

    Hydrogen Cyanide, Anhydrous 74-90-8 1000

    Hydrogen Fluoride 7664-39-3 1000

    Hydrogen Peroxide (52% by weight or greater) 7722-84-1 7500

    Hydrogen Selenide 7783-07-5 150

    Hydrogen Sulfide 7783-06-4 1500

    Hydroxylamine 7803-49-8 2500

    Iron, Pentacarbonyl 13463-40-6 250

    Isopropylamine 75-31-0 5000

    Ketene 463-51-4 100

    Methacrylaldehyde 78-85-3 1000Methacryloyl Chloride 920-46-7 150

    Methacryloyloxyethyl Isocyanate 30674-80-7 100

    Methyl Acrylonitrile 126-98-7 250

    Methylamine, Anhydrous 74-89-5 1000

    Methyl Bromide 74-83-9 2500

    Methyl Chloride 74-87-3 15000

    Methyl Chloroformate 79-22-1 500

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    CHEMICAL NAME CAS* TQ**

    Methyl Ethyl Ketone Peroxide (concentration greater than 60%) 1338-23-4 5000

    Methyl Fluoroacetate 453-18-9 100

    Methyl Fluorosulfate 421-20-5 100

    Methyl Hydrazine 60-34-4 100

    Methyl Iodide 74-88-4 7500

    Methyl Isocyanate 624-83-9 250

    Methyl Mercaptan 74-93-1 5000

    Methyl Vinyl Ketone 79-84-4 100

    Methyltrichlorosilane 75-79-6 500

    Nickel Carbonly (Nickel Tetracarbonyl) 13463-39-3 150

    Nitric Acid (94.5% by weight or greater) 7697-37-2 500

    Nitric Oxide 10102-43-9 250

    Nitroaniline (para Nitroaniline) 100-01-6 5000

    Nitromethane 75-52-5 2500

    Nitrogen Dioxide 10102-44-0 250

    Nitrogen Oxides (NO; NO(2); N2O4; N2O3) 10102-44-0 250

    Nitrogen Tetroxide (also called Nitrogen Peroxide) 10544-72-6 250

    Nitrogen Trifluoride 7783-54-2 5000

    Nitrogen Trioxide 10544-73-7 250

    Oleum (65% to 80% by weight; also called Fuming SulfuricAcid)

    8014-94-7 1000

    Osmium Tetroxide 20816-12-0 100

    Oxygen Difluoride (Fluorine Monoxide) 7783-41-7 100

    Ozone 10028-15-6 100

    Pentaborane 19624-22-7 100

    Peracetic Acid (concentration greater 60% Acetic Acid; also

    called Peroxyacetic Acid)

    79-21-0 1000

    Perchloric Acid (concentration greater than 60% by weight) 7601-90-3 5000

    Perchloromethyl Mercaptan 594-42-3 150

    Perchloryl Fluoride 7616-94-6 5000

    Peroxyacetic Acid (concentration greater than 60% Acetic Acid;also called Peracetic Acid)

    79-21-0 1000

    Phosgene (also called Carbonyl Chloride) 75-44-5 100

    Phosphine (Hydrogen Phosphide) 7803-51-2 100

    Phosphorus Oxychloride (also called Phosphoryl Chloride) 10025-87-3 1000

    Phosphorus Trichloride 7719-12-2 1000

    Phosphoryl Chloride (also called Phosphorus Oxychloride) 10025-87-3 1000

    Propargyl Bromide 106-96-7 100

    Propyl Nitrate 627-3-4 2500

    Sarin 107-44-8 100

    Selenium Hexafluoride 7783-79-1 1000

    Stibine (Antimony Hydride) 7803-52-3 500

    Sulfur Dioxide (liquid) 7446-09-5 1000

    Sulfur Pentafluoride 5714-22-7 250

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    CHEMICAL NAME CAS* TQ**

    Sulfur Tetrafluoride 7783-60-0 250

    Sulfur Trioxide (also called Sulfuric Anhydride) 7446-11-9 1000

    Sulfuric Anhydride (also called Sulfur Trioxide) 7446-11-9 1000

    Tellurium Hexafluoride 7783-80-4 250

    Tetrafluoroethylene 116-14-3 5000

    Tetrafluorohydrazine 10036-47-2 5000

    Tetramethyl Lead 75-74-1 1000

    Thionyl Chloride 7719-09-7 250

    Trichloro (chloromethyl) Silane 1558-25-4 100

    Trichloro (dichlorophenyl) Silane 27137-85-5 2500

    Trichlorosilane 10025-78-2 5000

    Trifluorochloroethylene 79-38-9 10000

    Trimethyoxysilane 2487-90-3 1500

    Footnote* Chemical Abstract Service Number

    Footnote** Threshold Quantity in Pounds (Amount necessary to be covered by this standard.)


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