Ricobond 7002 and 7004 - ChemRep

Ricobond 7002 and 7004 Aqueous Dispersions of Functionalized Low

Molecular Weight Polymers

Cray Valley Hydrocarbon Specialty Chemicals 2 Cray Valley Hydrocarbon Specialty Chemicals 2

Cray Valley HSC A Division of Total’s Refining and Chemicals

Upstream Supply and Marketing Refining and

Chemicals

Our

Organization

• Oil & gas exploration

• Production

• Gas & power

• Alternative energy

•Supply and Marketing

of Oil Products

• Refining

•America

•Europe

•Asia

•Polymers

2012 Sales -- $257 Billion

130+ Countries

96,000+ Employees


TOTAL’s R&C Group

Refining & Chemicals

Bostik

GPN Atotech

Hutchinson

Refining & Base

Chemicals

Europe

Business Unit

Polymers

Business Unit

Refining & Petrochemicals

Americas

Business Unit

Refining &

Petrochemicals Eastern

Hemisphere

Business Unit

Cray Valley HSC


Global Presence

Research

Regional HQ

Sales Office

Global HQ

Manufacturing

Distribution Network


Core Competencies

• Polymer Product Development

- Anionic - Free radical

- Cationic - Metathesis

- Processes for producing low molecular weight (500 – 10,000 g/mol)

- Hydrogenation

- Functionlization

• Most Products Used As Additives


SMA® Styrene-Maleic Anhydride Copolymers

FEATURES

APPLICATIONS

• Composition Range • S/MA = 1:1 to 8:1

• Low Molecular Weight

• Derivitization

• hydrophilic to hydrophobic

• wide Tg range

• reactivity

• water solubility

• pH, temperature tolerance

• Pigment Dispersions • ink, paint, OPV

• Paper • sizing

• flocculants

• Consumer Goods • carpet shampoos

• waxes, polishes

• Oilfield • Drilling mud additives

• Thermoplastics • HDT

• chain extension (PA)

• rheology

• Electronics • PWBs

O OO

yx

OO

OH RO

x y

Cray Valley Hydrocarbon Specialty Chemicals 7 Cray Valley Confidential Cray Valley Hydrocarbon Specialty Chemicals 7

SMA® Resins

Product S:MA

Ratio

Acid

Value mgKOH/g

Low Mw

Visc.@

200oC

(Poise)

High Tg

(oC)

SMA 1000 1:1 465-495 5,000 ~60,000 155

SMA 2000 2:1 335-375 7,500 ~6,000 135

SMA 3000 3:1 255-305 9,500 ~3,000 125

SMA EF-40 4:1 195-235 11,000 ~750 115

SMA EF-60 6:1 141-171 11,500 ~70 106

SMA EF-80 8:1 105-135 14,000 ~100 104

CH CH2 CH CH

CC

yx

O O

n

O


SMA Derivatives

O OO

yx

OO

OH RO

x y

where x = 50 – 90%

y = 10 – 50%

where R = variable

CH CH2 CH CH

C CO Ox n

NH OH

RSMA Resins

+ ROH

SMA Imides

SMA Amic Acids

SMA Esters

+ R-NH2 – H2O

+ R-NH2

+ SO3/NaOH

CH CH2 CH CH

CC

y

O O

CH CH2 CH CH

C C

O-Na

+

O O(1-y)x (1-x)

n

SO3-Na

+

Na+O

-

Na+O

-

O-Na

+

Sulfonated SMA


RICON®

Butadiene Homopolymers and Copolymers

x y zFEATURES

APPLICATIONS

• Controlled Microstructure

• Controlled Macrostructure

• Functionality

• thermal properties (Tg)

• solubility parameters

• viscosity

• diffusion constants

• reactivity

• Rubber Additives • process aids

• viscoelastic mod.

• coagents

• adhesion promoters

• filler dispersion

• Electronics • potting agents

• epoxy modification

• PWBs

• Thermoplastics • filler dispersion

• processing aids

• oxygen barrier


Poly bd® and Krasol®

Polybutadiene Polyols

FEATURES

APPLICATIONS

• Terminal Hydroxyl Groups • Poly bd f = 2.3 - 2.5

• Krasol f = 1.9 – 2.0

• Polybutadiene Backbone

• Reactive Intermediates

• hydrophobicity

• chemical resistance

• urethane chemistry

• reactivity

• Sealants • IGS

• automotive

• Adhesives • reactive

• waterborne

• Thermoplastics • filler dispersion

• processing aids

• oxygen barrier

• Coatings • hydrophobic

• anti-corrosive

• coil coatings

• PUDs

HO OH

0.2 0.60.2

n

OH OH

0.6 0.250.15

n


DYMALINK® Reactive Monomers

FEATURES

APPLICATIONS

• Metal Centered Monomers • Zn, Ca, Al…

• Variable Ligands • unsaturated or saturated

• Reactivity

• imparts ionic character

• PO coagents

• S cure activation

• adhesion

• dynamic properties

• Rubber • tires

• PT and CV belts

• fluid routing

• general under-the-hood

• wire and cable

• Golf • core compression

• resilience

• Thermoplastics • HDT

• Polymerization • comonomers

O

Zn

O

O O

R R


Wingtack®, Norsolene®, & Cleartack®

Petroleum Hydrocarbon Resins

FEATURES

APPLICATIONS

• Composition Spectrum • C5, C9, pure monomer

• Wide SP range

• Hydrogenation

• compatibility

• liquid and solid forms

• low color, low odor

• tackification

• rheology

• Adhesives • hotmelts

• PSAs

• non wovens

• bookbinding

• automotive/ industrial

• converting

• Rubber • tackifiers

• process aids

• compatibilizers

• Thermoplastics • nucleating agents

• rheology

• Sealants • IGS

• automotive

• Coatings/Industrial • paint striping

• investment casting

Ricobond 7002 and 7004

Functionalized

Hydrocarbon resins

Water-based dispersions

Cray Valley Hydrocarbon Specialty Chemicals

• Polymeric backbone with

functional groups

• Hydrophobic/hydrophilic features

• Adhesion to polar substrates

• Dispersing polar fillers

• Adhesion to rubber

• Crosslinking into rubber with

peroxide cure

• Water-based

• Low viscosity

• Good wetting

• Compatible with waterborne

polymer systems

• Adhesion to different

substrates

Aqueous Dispersions of Functionalized Low


Pilot Scale samples available for testing

Name CVX50092 Ricobond

7002 CVX50120

Ricobond

7004

Functional

Groups/Chain 2 5 9 11

Viscosity, cps @

25°C <100 <200 <1 000 <500

pH 8.0-9.0 8.0-9.0 8.0-9.0 8.0-9.0

Solids, wt% 28-31 28-31 28-31 28-31


Sample Preparation

Aqueous dispersions tested alone and blended with carboxylated styrene

butadiene emulsions (CSBE)

Mylar (PET) sheet coated with blend using #20 Mayer Rod

Film dried at 150 C⁰ for 1min

Mylar film rolled onto compounded EPDM/peroxide rubber sheet

Mylar/blend/rubber cured in heated press

After curing rubber plaque is cut into 2.5cm wide strips. Peel Resistance, PET to rubber

Test Method

Measure adhesion using modified T-peel test

Modified ASTM D1876 method

Samples tested at room temperature

Test speed : 10in/min

Adhesion Testing Polyethylene Terephthalate (PET) Film to EPDM Rubber Sheet


11 F/chain, 20% F

9 F/chain, 17% F

Effect of functionality on adhesion

Aqueous dispersions tested 100% in EPDM/Peroxide-PET


6 F/chain = CVX 50230 9 F/chain = CVX 50120 11 F/chain = Ricobond 7004

CVX50230

CVX50120

Ricobond 7004

0

5

10

15

20

25

Peel Adhesion lbs/in

Peel Adhesion lbs/in

Cray Valley Hydrocarbon Specialty Chemicals 17

Blending of Ricobond 7004 with

Carboxylated SB Emulsions

• Ricobond 7004 dramatically improves the adhesion of carboxylated SB

emulsions to PET film.

• Cohesive failure is observed when adding Ricobond 7004 to GenFlo 8045.

0

5

10

15

20

25

30

PET GenFlo 3003 GenFlo 8045

lbs/

in

Adhesion of CSBE vs. blend with Ricobond 7004 in EPDM/Peroxide –PET Composite

No Aq Dispersion

20:80 AqDisp: Latex

Cohesive failure

Advantages of Ricobond 7004, 7002 Adhesion promoter for carboxylated SB emulsions

Adhesion between rubber and polymeric substrates

Increased Water resistance

Suggested Applications Additive in Water-based formulations where substrate adhesion needs to

be enhanced

Water based Adhesives

Nonwoven applications

Paper sizing applications

Dispersing aid for polar fillers

Water based alkyd coatings

Aqueous Dispersions of Functionalized Low



Cray Valley Hydrocarbon Specialty Chemicals 19

Thank You!

Questions?

[email protected]

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Our website:

www.crayvalley.com

mailto:[email protected]

http://www.cvpolymeradditives.com/

Documents

Ricobond 7002 and 7004 - ChemRep