Refinery Model

Crudes Arab Light

Crude Light Gas Light Naphtha Med. Naphtha Heavy Naphtha Light Kero Heavy Ker LGO VGO VR ARTBP Start Point (F) 158 212 302 374 455 536 650 1049 650TBP Cut Point (F) 158 212 302 374 455 536 650 1049

Vol % 4.9 4 8.5 7.9 8.6 8.5 11.2 29.8 14.8 44.6Wt % 3.76 3.29 7.37 7.16 8.05 8.21 11.18 32.09 17.7 49.79

Gravity, API 33.4 84.4 69.9 59.4 51.2 45.3 39.8 34.3 22.2 6.9 16.3S.G. 0.8575 0.6554 0.7027 0.7412 0.7745 0.8004 0.8259 0.8535 0.9207 1.0224 0.09545

VABP (F) 185 257.5 338 414.3 495.8 592.5 834.5Characterization Factor 12.29 12.08 11.97 11.95 11.93 11.92 11.84

Total Sulfur, wt. % 1.79 0.023 0.025 0.0291 0.054 0.1337 0.7233 1.2159 2.4817 4.34 3.1422Mercaptan Sulfur( ppm wt)

Total Nitrogen, wt.% 0.098 0 0 0 0.0001 0.0005 0.0019 0.0064 0.0549 0.2959 0.1405Aniline Pt. (F) 133 142.3 152.4 161.6 178

Naphthenes Vol. % 15.2 18.8 20Aromatics Vol. % 6.7 12.7 18.3 22.4 25.6

RON 60.7 50.5 36.9 22Smoke Pt. (mm) 22.9 18.9

Cetane Index 49.5 53.5 53 28.8Freeze Pt. (F) -49.4 -5.5Pour Pt. (F) -30 -59.1 -19.9 17.5 87.5 115 35

Viscosity @ 100F (cs) 6.25 1.38 2.28 4.52 54.6Viscosity @ 140F (cs) 46800 92.3Viscosity @ 210F (cs) 0.67 0.98 1.6 6.42 1590 24.2

Nickel (ppm wt) 4.4 25 8.92Vanadium (ppm wt) 20.5 116 41.31

Conradson Carbon Wt. % 3.58 20.3 7.6price #REF!

Main Input

Enter the following information.

Table 1.1

Crudes

Crude # Type Amount

crude1 4 Fulma 250,000

crude2 16 No Crude 0

crude3 16 No Crude 0

Table 1.2

Prices of Crudes

Number Type MARKET Price ($/bbl) ASKING PRICE (WK1) ASKING PRICE (WK2)

1 62.66

2 56.50 57

3 62.66

4 55.00 54

5 63.00

6 62.66

7 70.32

8 43.29

9 62.66

10 56.00

11 62.66

12 62.66

13 55.00

14 62.66

15 62.6616 No Crude 0.00

Iranian Light1

Bonny Light (Nigeria)2

Magnus1

Fulma1

Isthmus (Mexico)2

Maya1

Brent (United Kingdom)2

Arab Heavy(Safaniya)1

BU Attifel1

Tapis Blend1

Oficina1

Soviet Export Grade1

WTI1

San Joaquin Valley1

Alaskan North Slope3

1Spot Price, belonged to Feb28,05-Mar4,05, is posted by platt 2Spot Price, as on May 25, 2007, Source: Oil & Gas Journal, Volume 105.223Spot Price, as on June 01, 2007, Source: Oil & Gas Journal, Volume 105.22

Main Input


Table 1.3

Other Prices ($/bbl)

ASKING PRICE (WK3) ASKING PRICE (WK4) ASKING PRICE (WK5) ASKING PRICE (WK6)

Table 1.4

Other Details:

Desired Gasoline Octane

Platformer Octane

Vol. Frac. HeavyKero to Diesel

Gasoline4

Kerosene5

Diesel5

Fuel Oil5

C25

C35

C45

4As on July, 12, 2007 Source: http://www.msnbc.msn.com/id/12400801/ 5PTT(formula), Platt, SRI , ICIS and CMAI

Main Input


Other Prices ($/bbl)

72.5

66.0

68.0

50.0

17.0

27.6

33.4

Other Details:

Desired Gasoline Octane 87

Platformer Octane 96

Vol. Frac. HeavyKero to Diesel 0.4

Gasoline4

Kerosene5

Diesel5

Fuel Oil5

C25

C35

C45

As on July, 12, 2007 Source: http://www.msnbc.msn.com/id/12400801/

PTT(formula), Platt, SRI , ICIS and CMAI

Crude 1

Type 4 Fulma crude price 55.00 $/bbl Bbl/day 250,000

Table 2.1

Crude Light Gas Light Naphtha Med. Naphtha Heavy Naphtha Light Kero Heavy Kero LGO VGO VR ARTBP Start Point (F) - - 158.00 212.00 302.00 374.00 455.00 536.00 650.00 1,049.00 650.00 TBP Cut Point (F) - 158.00 212.00 302.00 374.00 455.00 536.00 650.00 1,049.00 - -

Vol % - 4.97 6.11 12.19 9.28 10.01 8.37 12.00 28.66 5.71 34.37 Wt % - 3.95 5.29 11.20 8.86 9.85 8.48 12.42 31.53 6.62 38.15

Gravity, API - 84.70 66.70 55.50 48.50 43.00 38.10 34.40 24.70 16.70 23.30 S.G. - 0.65 0.71 0.76 0.79 0.81 0.83 0.85 0.91 0.95 0.91

VABP (F) - - 185.00 256.70 338.00 414.30 495.60 593.10 823.50 - - Characterization Factor - - 12.10 11.82 11.80 11.79 11.81 11.93 11.99 - -

Total Sulfur, wt. % - 0.00 0.00 0.00 0.01 0.03 0.06 0.21 0.51 0.75 0.56 Mercaptan Sulfur (ppm wt) - - - - - - - - - - -

Total Nitrogen, wt.% - - - - - - - - - - - Aniline Pt. (F) - - - - 130.30 139.90 150.60 167.80 197.40 - -

Naphthenes Vol. % - - 25.30 25.30 25.30 - - - - - - Aromatics Vol. % - - 7.70 16.50 20.40 23.30 24.10 - - - -

RON - 70.80 57.60 51.80 39.70 - - - - - - Smoke Pt. (mm) - - - - - 22.00 18.90 - - - -

Cetane Index - - - - - 45.20 50.50 53.30 33.20 - - Freeze Pt. (F) - - - - - (56.40) (15.80) - - - - Pour Pt. (F) - - - - - (66.40) (25.80) 39.20 107.10 - 90.00

Viscosity @ 100F (cs) - - - - - 1.52 2.58 5.19 52.43 - - Viscosity @ 140F (cs) - - - - - - - - - - 44.10 Viscosity @ 210F (cs) - - - - - 0.72 1.07 1.77 7.31 - 11.30

Nickel (ppm wt) - - - - - - - - - 5.59 0.97 Vanadium (ppm wt) 20.50 - - - - - - - - 27.65 4.80

Conradson Carbon Wt. % 3.58 - - - - - - - - 10.57 1.83

Table 2.2

Vol %Methane - Ethane 0.15 Propane 0.60 Isobutane 0.60 n-butane 1.35 Total 2.70

C4

Crude 2

Type 16 No Crude crude price - $/bbl Bbl/day -

Table 3.1

Crude Light Gas Light Naphtha Med. Naphtha Heavy Naphtha Light Kero Heavy Kero LGO VGO VR ARTBP Start Point (F) - - - - - - - - - - - TBP Cut Point (F) - - - - - - - - - - -

Vol % - - - - - - - - - - - Wt % - - - - - - - - - - -

Gravity, API - - - - - - - - - - - S.G. - - - - - - - - - - -

VABP (F) - - - - - - - - - - - Characterization Factor - - - - - - - - - - -

Total Sulfur, wt. % - - - - - - - - - - - Mercaptan Sulfur( ppm wt) - - - - - - - - - - -

Total Nitrogen, wt.% - - - - - - - - - - - Aniline Pt. (F) - - - - - - - - - - -

Naphthenes Vol. % - - - - - - - - - - - Aromatics Vol. % - - - - - - - - - - -

RON - - - - - - - - - - - Smoke Pt. (mm) - - - - - - - - - - -

Cetane Index - - - - - - - - - - - Freeze Pt. (F) - - - - - - - - - - - Pour Pt. (F) - - - - - - - - - - -

Viscosity @ 100F (cs) - - - - - - - - - - - Viscosity @ 140F (cs) - - - - - - - - - - - Viscosity @ 210F (cs) - - - - - - - - - - -

Nickel (ppm wt) - - - - - - - - - - - Vanadium (ppm wt) - - - - - - - - - - -

Conradson Carbon Wt. % - - - - - - - - - - -

Vol %Methane - Ethane - Propane - Isobutane - n-butane - Total -

C4-

Crude 3

Type 16 No Crude crude price - $/bbl Bbl/day -

Table 4.1

Crude Light Gas Light Naphtha Med. Naphtha Heavy Naphtha Light Kero Heavy Kero LGO VGO VR ARTBP Start Point (F) - - - - - - - - - - - TBP Cut Point (F) - - - - - - - - - - -

Vol % - - - - - - - - - - - Wt % - - - - - - - - - - -

Gravity, API - - - - - - - - - - - S.G. - - - - - - - - - - -

VABP (F) - - - - - - - - - - - Characterization Factor - - - - - - - - - - -

Total Sulfur, wt. % - - - - - - - - - - - Mercaptan Sulfur( ppm wt) - - - - - - - - - - -

Total Nitrogen, wt.% - - - - - - - - - - - Aniline Pt. (F) - - - - - - - - - - -

Naphthenes Vol. % - - - - - - - - - - - Aromatics Vol. % - - - - - - - - - - -

RON - - - - - - - - - - - Smoke Pt. (mm) - - - - - - - - - - -

Cetane Index - - - - - - - - - - - Freeze Pt. (F) - - - - - - - - - - - Pour Pt. (F) - - - - - - - - - - -

Viscosity @ 100F (cs) - - - - - - - - - - - Viscosity @ 140F (cs) - - - - - - - - - - - Viscosity @ 210F (cs) - - - - - - - - - - -

Nickel (ppm wt) - - - - - - - - - - - Vanadium (ppm wt) - - - - - - - - - - -

Conradson Carbon Wt. % - - - - - - - - - - -

Table 4.2

Vol %Methane - Ethane - Propane - Isobutane - n-butane - Total -

C4-

Crude Blend

Table 5.1

Type Amount (bbl/day) Price ($/bbl) Crude Input Price 55.00 ($/bbl)

4 Fulma 250,000.00 55.00 16 No Crude - - Total Amount 250,000 (bbl/day)

16 No Crude - -

Table 5.2

Crude Light Gas Light Naphtha Med. Naphtha Heavy Naphtha Light Kero Heavy Kero LGO VGO VR ARTBP Start Point (F) - - 158.00 212.00 302.00 374.00 455.00 536.00 650.00 1,049.00 650.00 TBP Cut Point (F) - 158.00 212.00 302.00 374.00 455.00 536.00 650.00 1,049.00 - -

Vol % - 4.97 6.11 12.19 9.28 10.01 8.37 12.00 28.66 5.71 34.37 Wt % - 3.95 5.29 11.20 8.86 9.85 8.48 12.42 31.53 6.62 38.15

Gravity, API - 84.70 66.70 55.50 48.50 43.00 38.10 34.40 24.70 16.70 23.30 S.G. - 0.65 0.71 0.76 0.79 0.81 0.83 0.85 0.91 0.95 0.91

VABP (F) - - 185.00 256.70 338.00 414.30 495.60 593.10 823.50 - - Characterization Factor - - 12.10 11.82 11.80 11.79 11.81 11.93 11.99 - -

Total Sulfur, wt. % - 0.00 0.00 0.00 0.01 0.03 0.06 0.21 0.51 0.75 0.56 Mercaptan Sulfur( ppm wt) - - - - - - - - - - -

Total Nitrogen, wt.% - - - - - - - - - - - Aniline Pt. (F) - - - - 130.30 139.90 150.60 167.80 197.40 - -

Naphthenes Vol. % - - 25.30 25.30 25.30 - - - - - - Aromatics Vol. % - - 7.70 16.50 20.40 23.30 24.10 - - - -

RON - 70.80 57.60 51.80 39.70 - - - - - - Smoke Pt. (mm) - - - - - 22.00 18.90 - - - -

Cetane Index - - - - - 45.20 50.50 53.30 33.20 - - Freeze Pt. (F) - - - - - (56.40) (15.80) - - - - Pour Pt. (F) - - - - - (66.40) (25.80) 39.20 107.10 - 90.00

Viscosity @ 100F (cs) - - - - - 1.52 2.58 5.19 52.43 - - Viscosity @ 140F (cs) - - - - - - - - - - 44.10 Viscosity @ 210F (cs) - - - - - 0.72 1.07 1.77 7.31 - 11.30

Nickel (ppm wt) - - - - - - - - - 5.59 0.97 Vanadium (ppm wt) 20.50 - - - - - - - - 27.65 4.80

Conradson Carbon Wt. % 3.58 - - - - - - - - 10.57 1.83

Table 5.3

Vol %Methane - Ethane 0.15 Propane 0.60 Isobutane 0.60 n-butane 1.35 Total 2.70

C4-

Products & Gross Margin

Table 6.1

type1 : Fulma type2: No Crude type3: No Crude

Table 6.2

Volumes, Values and Properties of ProductsBbl/day Value($) SG Octane Sulfur (wt%) Pour Point (F) Freeze Point (F) Cetane Index

1,100 18,700

2,400 66,144

11,800 394,002 Gasoline 109,300 7,924,250 0.74 89.2 0.0001 Jet/Kero 37,600 2,481,600 0.82 0.0018 -51 Diesel 86,100 5,854,800 0.85 15 0 59.3 Fuel Oil 1,000 50,000 1.13 1.3993 Total 249,300 16,789,496

Table 6.3

crude feed 250,000 13,750,000 gross margin ($/day) 2,859,209 $/day gross margin/bbl ($/day) 11.44 $/bbl

Table 6.4 Table 6.5

Desired Gasoline Octane 87.00 65.62 H2 from Steam Reformer (mmscf/day 57.67 User must add this number to meet H2 requirments

Platormer Octane 96.00 H2 required for HT (mmscf/day) 123.28

Frac. VGO to HC 0.98

Increase hydrogen from the platformer by increasing frac. VGO to HC

Table 6.6

SpecificationsMinimum Calculated Values On Spec?

octane R+M/2 Octane > 87 89.2 yespour point (F) < 0 -0.1 yesfreeze point (F) < -45 -51.2 yescetane index Cetane Number > 50 59.3 yesSulphur in Gasoline (ppmwt%) < 300 100 yesSulphur in Diesel (ppmwt) < 15 10 yesSulphur in Fuel Oil (wt%) < 1.5 1.4 yes

C2

C3

C4

H2 from Plat (mmscf/day)

Summary Page

Table 7.1

Type Amount (bbl/day) Price ($/bbl)4 Fulma 250,000 55.00

16 No Crude - - 16 No Crude - -

Table 7.2

Unit Capacity (bbl/day) Current Use % of Capacity

JetKero 75000 45950 61%

FCC 60000 5255 9%

VGOHTU 105000 71650 68%

Alky 30000 13155 44%

VR 200000 85925 43%

Diesel 70000 43288 62%

Coker 90000 14275 16%

Hydrocracker 130000 76644 59%

Naptha 100000 88125 88%

Coker Naptha 20000 2259 11%

LCOHTU 10000 734 7%

Refinery Investment CostsProcessCrude DistillationVacuum DistillationNaphtha HydrotreatingKerosene HydrotreatingDiesel Hydrotreating

Vacuum Gas Oil Hydrotreating

Fluid Catalytic Cracking

Hydrocracking

Hydrogen MM$/MM SCFD

Platformer

Isomerization

Alkylation (per barrel of alkyl 15

Coking

Sulfur MM$/Metric Ton per Day

Tankage and I 50

Crude Berth $MMProduct Pier $MM per berthOther OSBL 35% of Process Units

Capital Investment 2.5

32.5

33.5

4.5

8

8

2.5

9

6

7

0.5

10035

M Dollars per Barrel of FEED/ Day

Total Process


375 Bbl/day

Light Gas

6750 Bbl/day 1500 Bbl/dayNaphtha 11838 Bbl/day

88125 Bbl/day

Alky4875 Bbl/day 13155 Bbl/day 1152 Bbl/day

LN Isom Naphtha35633 Bbl/day 35633 Bbl/day

WSR Naphtha Naphtha81375 Bbl/day 81216 Bbl/day

28.7 scf/Bbl HN Plat Naphtha86671 Bbl/day 69401

Bbl/day

Crude Light Jet/Kero Jet/Kero Prod250000 Bbl/day 37580 Bbl/day 37645 Bbl/day LN 692 BBl/day

29.4 scf/BblHN

1601 BBl/dayHeavy Jet/Kero

8370 Bbl/day

Diesel Total Diesel Diesel Prod 30 scf/Bbl30000 Bbl/day 43288 Bbl/day 43721 Bbl/day

Naptha 0 Bbl/day

153 scf/BblAR

85925 Bbl/day FCC LCO Middle Distillate734 Bbl/day

729 Bbl/day

HVGO HVGO HVGO

71650 Bbl/day 1,433 1422 Bbl/day

Bbl/day 165 scf/Bbl 709 Bbl/day 922 Bbl/day

110.3 scf/Bbl FCC Gas Total Gas1740 Bbl/day 2954 Bbl/day

HVGO

70217 Bbl/day FCC WCN3160 Bbl/day 1322 Bbl/day

HGO5255 Bbl/day

FCC HCO Fuel Oil Product317 Bbl/day

Coker Gas 10461214 Bbl/day

Coker NaphthaVR 2259 Bbl/day

14275 Bbl/day

Coker LGO4918 Bbl/day 6957 Bbl/day

Coker HGO HCLN6427 Bbl/day 10073 Bbl/day

HGO HCHN76644 Bbl/day 27549 Bbl/day

HCDiesel42415 Bbl/day

HCBottoms3832 Bbl/day

C2

Sat C3

Sat C4

C3, C4

Sat C4 C4

H2

H2

H2

H2

C2 Unsat C3

H2

H2

Unsat C4

C4

CDU

NapthaUnit

NHTU

Isom

Plat

KHTU

DHTU

VR Unit

VGOHTU

Coker

HC

FCC

Alky

CNHTU

LCOHTU

C4C4

Fuel OilFuel Oil

Jet Fuel/ KeroseneJet Fuel/

Kerosene

3

4

3

4

C2C2C3C3

2

1

21

CDU

Table 8.1


Table 8.2

Top Naphtha Temperature (F) 374Top Jet/Kero Temperature (F) 536Top Diesel Temperature (F) 650

Table 8.3

Stream Volume % Bbl/dayInCrude 250000

OutTo Gas 2.70 6750To Naphtha Unit 32.55 81375Light Kero 10.01 25025Heavy Kero 8.37 20925LGO 12.00 30000AR 34.37 85925Total 100.00 250000

Table 8.4

Vol%Crude Light Gas Light Naphtha Med. Naphtha Heavy Naphtha

Fulma 4.97 6.11 12.19 9.28 No Crude - - - - No Crude - - - -

JetKero Unit

Table 9.1


Table 9.2 Table 9.3 Table 9.4

Stream Volume (bbl/day) Calculations for HT Kerosene PropertiesIn 45950 Ho (scf/Bbl) 29.39 SG 0.82Out H/day (mm scf/day) 1.4 Sulfur (wt%) 0.00 to HT 37580 H 0.05 Nitrogen (wt%) 0.000 to Diesel 8370 H2S 0.037 Characterization Factor 0.8to Naphtha Unit 5 NH3 0.000 VABP (F) -460to Product 37645 RG 0.007 Freeze Point -51.2

Naphtha Yield (wt%) 0.011Kero Yield (wt%) 100.00

Vol Frac. Heavy Kero to Diesel 0.40

FCC2 B C D E F G H I3 Table 10.1

4 type1 : Fulma 5 type2: No Crude 6 type3: No Crude 7

8

9 Table 10.2 Table 10.3 Table 10.4

10 Stream Volume (bbl/day) Calculations for FCC Properties 11 In Conversion 80 Naphtha Properties12 Feed from VGOHTU 1422 FQP 84.8 Gravity, API 59

13 Feed from HC 3832 90.5 SG 0.75

14 0.66 Sulfur (wt%) 0.0515 Total feed to FCC 5255 Gasoline Yield (LV%) 60.1 RON(clear) 91.8

16 30.3 MON(clear) 80.9

17 Out 1.67

18 Lights to Gas 1740 11.4 LCO Properties

19 Naphtha to Product 3160 19.0 SG 0.93

20 LCO to LCOHTU 734 0.71 Sulfur (wt%) 0.86

21 HCO to Prod A53 317 8.03 Characterization Factor 11.99

22 2954 3.32 Gravity, API 14

23 709 0.51

24 922 9.63 HCO Properties

25 1322 2.37 SG 1.13

26 6.96 Sulfur (wt%) 1.4027 Coke + FG Yield 8.2228 Table 10.5 Ratio of Coke/(Coke+FG) 0.6629 Isobutane Fraction 0.34 Coke Yield 5.44

30 n-Butane Fraction 0.16 2.7831 Butene Fraction 0.50 Total Cycle Oil Yield (LV%) 20.032 Ratio HCO/TCO 0.3033 HCO Yield (LV%) 6.0334 LCO Yield (LV%) 14.0

35 0.33

36 0.0337 Gravity Factor LCO 5.2338 WF 1.0639 Total Cycle Oil Yield (wt%) 21.140 LCO Yield (wt%) 13.841 HCO Yield (wt%) 7.2

Yield of C3/400 Prod

Ratio C5/400 to C3/400

C3/C4 LPG Yield (LV%)

Ratio C4LPG to C3LPG

C3 LPG (LV%)

C4 LPG (LV%)

C3=/Total C3 LPG

C3= Yield (LV%)

Gas to H2S Unit C3 Yield (LV%)

C2 to Product Ratio C4= in C4 LPG

C3 to Product C4= Yield (LV%)

C4 to Alky nC4 Yield (LV%)

iC4 Yield (LV%)

FG Yield (C2)

Ratio H2S Yield/Feed Sulfur

H2S Yield

VGOHTU

Table 11.1



Stream Volume (bbl/day) Calculations for HT HVGO PropertiesIn Ho (scf/Bbl) 110.31 SG 0.90 Feed from VR Unit 71650 H 0.185 Characterization Factor 12.0

0.2 Sulfur (wt%) 0.05

Out 0.492 Nitrogen (wt%) 0.00

HVGO to HC 70217 0.000 HVGO to HT 1433 RG 0.085To Naphtha Unit 2 Naphtha Yield 0.100To Jet/Kero Unit 0 Mid Dist Yield 0.842To Diesel Unit 13 HVGO Yield 98.75HVGO to FCC 1422

Fraction to Hydrocracker 0.98

H2 (mm scf/day)

H2S

NH3

Alkyl

Table 12.1


Table 12.2

Stream Volume (bbl/day)In From

Naphtha Hydrocracker FCC Total In

3375 2,644 213 6,232

1500 4,314 451 6,264

0 - 658 658 Total 4875 6,957 1,322 13,155

OutAlky to Product 1152

11838

Table 12.3

Alky PropertiesRON 96MON 93.5

nC4

iC4

nC4=

Sat C4 to Product

VR Unit

Table 13.1


Table 13.2

Stream Volume (bbl/day)InAR to Unit 85925

OutVR to Coker 14275

71650VGO to HT

Diesel


Stream Volume (bbl/day) Feedstock Properties Product PropertiesIn Heavy Kero Properties Gas PropertiesHeavy Kero From Crude 8370 SG 0.83 SG - LGO from Crude 30000 Sulfur (wt%) 0.06 Sulfur (wt%) -

Coker Unit

Table 15.1



Stream Volume (bbl/day) Calculations for Coker Properties

In 0.19 Naptha PropertiesVR to Coker 14275 RG (wt.%) 3.86 Sulfur (wt%) 0.11

4.46 Nitrogen (wt%) 0.000Out Naphtha (wt.%) 12.58 Paraffins (LV%) 40.0Coker Gas to FCC Gas 1214 Coke (wt%) 5.73 Olefins (LV%) 34.0 To Coker Naphtha Unit 2259 TGO (wt%) 73.38 Naphthenes (LV%) 15.0 LGO to Diesel 4918 Ratio LGO/TGO 0.42 Aromatics (LV%) 11.0 HGO to HC 6427 LGO (wt%) (400/650F) 30.49 SG 0.7587

171 HGO (wt%) (650/950F) 42.89 LGO PropertiesSG 0.84

Table 15.5 Sulfur (wt%) 0.34 Isobutane Fraction 0.16 Nitrogen (wt%) 0.00 n-Butane Fraction 0.41 Characterization Factor 11.99 Butenes Fraction 0.43

HGO PropertiesSG 0.91Sulfur (wt%) 0.62

Nitrogen (wt%) 0.00

H2S (wt.%)

C3/C4 LPG (wt%)

C4 to Alky

Hydrocracker2 B C D E F G H I3 Table 16.1

4 type1 : Fulma 5 type2: No Crude 6 type3: No Crude 78 Table 16.2 Table 16.3 Table 16.4

9 Stream Volume (bbl/day) Calculations for HC Properties10 In H (wt%) 2.54 Light Naphtha Properties

11 HVGO from HT 70217 0.57 SG 0.67

12 HGO from Coker 6427 0.0013 Total HGO to HT 76644 HC Yield (wt%) 102.0 Heavy Naphtha Properties14 Light Gas (wt%) 9.7 VABP (F) 272.40 15 Out RG (wt%) 1.91 Characterization Factor 11.92

16 HCLN to Isom 10073 5.7 SG 0.76 17 HCHN to Platformer 27549 Naphtha Yield (wt%) 30.0 RON(clear) 55.59 18 HCDiesel to Product 42415 Diesel Yield (wt%) 54.7 MON(clear) 55.99

19 HCBot to FCC 3832 115.0 Sulfur (wt%) 0.00

20 6957 Napthenes 56.00 21 Aromatics 6.00 22

23 Table 16.5 Diesel Properties24 Isobutane Fraction 0.62 VABP (F) 498.40 25 n-Butane Fraction 0.38 Characterization Factor 12.01 26 SG 0.82 27 API 40.82 28 Pour Point (F) (55.00)

29 CAPACITY EXCEEDED - REDUCE FEED TO UNIT Sulfur (wt%) 0.01 30 Cetane Index 55.61

H2S

NH3

C4 LPG

H2 (mmscf/day)

C4 to Alky

Gasoline

Table 17.1


Table 17.2 Table 17.3

Stream Volume (bbl/day) Octane ValuesFrom FCC Unit 3160 Gasoline from RON MON From Isom Unit 35633 FCC Unit 92 81 From Plat Unit 69401 Isom Unit 86 86 From Alky Unit 1152 Plat Unit 96 86 Total Gasoline 109346 Alkyl Unit 96 94

Total Gasoline 93 86

Table 17.4

Gasoline InfoDesired Prod. Octane 87MON(clear) 85.7RON(clear) 92.6Actual Prod. Octane 89.2

Naphtha Unit

Table 18.1



Stream Volume (bbl/day) Calculations for HTIn ASF 0.01Naphtha In 88125 28.7From Isom Unit 35633 H/day (scf/day) 2332055 From Plat Unit 69401 H 0.06

0.00Out RG 0.25

Light Gas Off 0.00Total 6750 HN (naphtha yield) 99.81

375

1500

4875 Table 18.4

PropertiesNaphtha to HT Naphtha Propertiesfrom CDU 81375 SG 0.74After HT Total 81216 Sulfur (wt%) 0.0001

Nitrogen (wt%) 0.0000000To ReformersIsom Unit Isom PropertiesNaphtha from NHTU 25560 RON(clear) 86Naptha from HC 10073 MON(clear) 86Naptha from CNHTU 692 Yield 100Total to Isom 35633Plat Unit Plat PropertiesNaphtha from NHTU 59122 RON(clear) 96Naphtha from HC 27549 RON (for formula) 0.96Naptha from CNHTU 1601 Napthene Content 37.9Total to Plat 86671 Aromatic Content 14.5

0.5Plat Yield (LV%) 200 psig 78

Table 18.5 Plat Yield (LV%) 100 psig 80

0.31 732

0.69 945

0 MON(clear) 86

65.6

Ho (scf/Bbl)

NH3

H2S

C2

Sat C3

Sat C4

N2A

iC4 Frac H2 (scf/Bbl) (200 psig)

nC4 Frac H2 (scf/Bbl) (100 psig)

nC4= Frac

H2 (mm scf/day) (100 psig)

Coker Naphtha Unit

Table 20.1



Stream Volume (bbl/day) Calculations for CNHTIn ASF 0.01Naphtha In 2259 29.8

H/day (mmscf/day) 0.07Naphtha to CNHT H 0.06

from Coker 2259 0.00After HT Total 2254 RG 0.27

0.02Out HN (naphtha yield) 99.77To ReformersIsom UnitNaphtha from CNHT 692 Table 20.4

Total to Isom 692 PropertiesPlat Unit Naphtha PropertiesNaphtha from CNHT 1601 SG 0.76Total to Plat 1601 Sulfur (wt%) 0.0001

Nitrogen (wt%) 0.0000050

Ho (scf/Bbl)

NH3

H2S

Coker Naphtha Unit

FCC Light Cycle Oil Unit

Table 21.1



Stream Volume (bbl/day) Calculations for LCOHTIn 164.9LCO In 734 H/day (mmscf/day) 0.12

H 0.27

0.05Out RG 0.04

0.86Naptha 0 HN (naphtha yield %) 0.05Mid. Dist. 729 MD (mid. Distillate yield % 99.27

Table 21.4

PropertiesFeedstock PropertiesSG 0.9312API Gravity 13.6Boiling Point (F) 535Sulfur (wt %) 0.86Nitrogen (wt%) 0.07Bromine No. 7Pour Point 0Visc. 122 F 2.5Visc 210 F 1.23Characterization 11.99

Ho (scf/Bbl)

NH3

H2S

FCC Light Cycle Oil Unit

PropertiesNaphtha Properties Middle Distillate PropertiesSG 0.7732 SG 0.92API Gravity 51.5 API Gravity 24.5Boiling Point (F) 267 Boiling Point (F) 527.30Sulfur (wt %) 0.007 Sulfur (wt %) 0.0431Nitrogen (wt%) 0.005 Nitrogen (wt%) 0.0317

Steam Reformer

Table 22.1

Stream Volume (mmscfd) Table 22.2

Crude Feed (bbl/day) 250000Hydrogen Required From Platformer 65.6To Hydrotreating 123.28Required from Reformer 57.67

Table 22.3

In CalculationsMethane Required 28.83 Methane Needed (mmscfd) 28.83

Out $6.86Hydrogen 57.67 Energy Content 911.5

Balance 0.00

Total Cost ($/day) $180,286.78Marginal Cost ($/bbl) $0.72

Current Spot Price1

1As on April 23, 2010

Steam Reformer

Calculationsmmscfd

USD/MMBtuBTU/scf

Item Per-Unit InvestmentCrude Distillation 2.5

Vacuum Distillation 3Naphtha Hydrotreating 2.5Kerosene Hydrotreating 3

Diesel Hydrotreating 3.5Vacuum Gas Oil Hydrotreating 4.5

Fluid Catalytic Cracking 8Hydrocracking 8

Hydrogen 2500Platformer 9

Isomerization 6Alkylation (per barrel of alkylate) 15

Coking 7Sulfur 500

Tankage and Interconnecting Piping 50Crude Berth 100

Product Pier $MM per berth 35SUBTOTAL

Other OSBL 35% of Process UnitsTOTAL CAPITAL COST

Unit of Measure Amount Unit of Measure Total Investment (x$1000 day/bbl feed) 250,000 Bbl/day $625,000,000 (x$1000 day/bbl feed) 85,925 Bbl/day $257,775,000 (x$1000 day/bbl feed) 81,375 Bbl/day $203,437,500 (x$1000 day/bbl feed) 37,580 Bbl/day $112,740,000 (x$1000 day/bbl feed) 43,288 Bbl/day $151,508,944 (x$1000 day/bbl feed) 1,433 Bbl/day $6,448,500 (x$1000 day/bbl feed) 5,255 Bbl/day $42,036,366 (x$1000 day/bbl feed) 76,644 Bbl/day $613,150,552

($ day/MMSCFD) 123 MM SCFD/day $308,204(x$1000 day/bbl feed) 86,671 Bbl/day $780,039,684(x$1000 day/bbl feed) 35,633 Bbl/day $213,799,104(x$1000 day/bbl feed) 1,152 Bbl/day $17,281,860(x$1000 day/bbl feed) 14,275 Bbl/day $99,925,000

($/(metric ton per day)) 5 Metric ton/day $2,500($ day/bbl) 5,250,000 Bbl/day $262,500,000

($MM) 1 - $100,000,000($MM) 1 - $35,000,000

$3,520,953,215x1.35

$4,753,286,840 4.4 bill actual

$1,859,112.87 PER DAY$13,013,790.12 PER WEEK

$7.44 PER BBL

Week Item Revenue ($/bbl) Cost ($/bbl) bbl no. of parcels

1 (4/13 1st half)

WTI GM 9.8 - 500,000 2Fulma GM 10.54 - 1,000,000 4Fulma lost CRUDE - -1.1 500,000 2Bonny GM 10.18 - 250,000 1REVENUECAPITAL COST PAYOFFPROFIT/LOSS

2 (4/13 2nd half)

WTI GM 9.8 - 1,750,000 7Fulma lost CRUDE - -2 1,500,000 6REVENUECAPITAL COST PAYOFFPROFIT/LOSS

3

WTI GM 9.81 - 250,000 1Fulma lost CRUDE - -0.5 1,500,000 6Fulma GM 11.44 - 1,500,000 6REVENUECAPITAL COST PAYOFFPROFIT/LOSS

4

Fulma GM 11.44 - 1,750,000 7Fulma lost CRUDE - -2 250,000 1REVENUECAPITAL COST PAYOFFPROFIT/LOSS

TOTAL profit/loss4,900,000

10,540,000-550,0002,545,000

17,435,000-13,013,7904,421,210

17,150,000-3,000,00014,150,000-13,013,7901,136,2102,452,500-750,000

17,160,00018,862,500-13,013,7905,848,710

20,020,000-500,000

19,520,000-13,013,7906,506,210

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