53
Index Acronyms AA Acrylic acid, 344, 382, 448 ABS Acrylonitrile-butadiene-styrene, 139, 392 ACH Acetone cyanhydrin, 237 ACP 2,2 -Azobis-(2-cyanopropanol), 470 AKD Alkylketene dimer, 313 AlN Aluminum nitride, 286 AMPC Allyl-N -(4-methyl-phenyl)carbamate, 401 ASA Alkenyl succinic anhydride, 313 ATRP Atom transfer radical polymerization, 400 BAMPO Bis(m-aminophenyl)methylphosphine oxide, 112 BAPQ 2,3-Bis(4-(4-aminophenoxy)phenyl)quinoxaline-6-carboxylic acid, 279 BAQ 2,3-Bis(4-aminophenyl)quinoxaline-6-carboxylic acid, 279 BCB Benzocyclobutene, 331 1,2-BDE 1,4-butanediol diglycidyl ether, 95, 133 BDM 4,4 -Bis(maleimido)diphenylmethane, 258, 270, 383 BDMA Benzyldimethylamine, 102 BDMAEE Bis(2-dimethylaminoethyl)ether, 63 BenzOXA Benzoxazole, 395 BET Brunauer Emmett Teller, 380 BIAE 2-Bromoisobutyric acid ethylester, 401

Reactive Polymers Fundamentals and Applications || Index

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Page 1: Reactive Polymers Fundamentals and Applications || Index

Index

Acronyms

AAAcrylic acid, 344, 382, 448

ABSAcrylonitrile-butadiene-styrene, 139, 392

ACHAcetone cyanhydrin, 237

ACP2,2′-Azobis-(2-cyanopropanol), 470

AKDAlkylketene dimer, 313

AlNAluminum nitride, 286

AMPCAllyl-N-(4-methyl-phenyl)carbamate, 401

ASAAlkenyl succinic anhydride, 313

ATRPAtom transfer radical polymerization, 400

BAMPOBis(m-aminophenyl)methylphosphine oxide, 112

BAPQ2,3-Bis(4-(4-aminophenoxy)phenyl)quinoxaline-6-carboxylic acid, 279

BAQ2,3-Bis(4-aminophenyl)quinoxaline-6-carboxylic acid, 279

BCBBenzocyclobutene, 331

1,2-BDE1,4-butanediol diglycidyl ether, 95, 133

BDM4,4′-Bis(maleimido)diphenylmethane, 258, 270, 383

BDMABenzyldimethylamine, 102

BDMAEEBis(2-dimethylaminoethyl)ether, 63

BenzOXABenzoxazole, 395

BETBrunauer Emmett Teller, 380

BIAE2-Bromoisobutyric acid ethylester, 401

Page 2: Reactive Polymers Fundamentals and Applications || Index

484 INDEX

Bis-GMA2,2-Bis[4-(3-methacryloxy-2-hydroxypropoxy)phenyl]propane, 456

BMIBismaleimide, 269

BMIPBisphenol A bismaleimide, 270

BMIPOBis(3-maleimidophenyl)phenylphosphine oxide, 273

BMPP2,2-Bis[4-(4-maleimido phenoxy)phenyl]propane, 295

BMPPPOBismaleimide(3,3′-bis(maleimidophenyl))phenylphosphine oxide, 112

BOX2,2′-(1,4-Phenylene)bisoxazoline, 383

BPBenzophenone, 435

BPFRBoric acid-modified phenolic resins, 164

BPODibenzoyl peroxide, 19

BTBismaleimide triazine, 262, 286

CBCN,N ′-Carbonylbiscaprolactam, 53

CECyanate ester, 258

CHPCumene hydroperoxide, 156

CMKGMCarboxymethyl konjac glucomannan, 79

CNTCarbon nanotube, 287

COTCold offset temperature, 479

CQCamphorquinone, 463

CRControlled rheology, 411

CTBNCarboxy-terminated butadiene/acrylonitrile copolymers, 104

CTECoefficient of thermal expansion, 286

DADiels-Alder reaction, 203, 277, 331

DAPNPT2,4-Di(2-allylphenoxy)-6-(2-naphthyloxy)-1,3,5-triazine, 283

DBA2,2′-Diallyl bisphenol A, 256, 269

DBBA3,5-Di-tert-butyl-4-hydroxybenzyl acrylate, 438

Page 3: Reactive Polymers Fundamentals and Applications || Index

INDEX 485

DBTDLDibutyltin dilaurate, 54

DCPDicumyl peroxide, 349, 432

DD1,10-Decanediol, 74

DDM4,4′-Diaminodiphenylmethane, 272

DDS4,4′-Diaminodiphenyl sulfone, 102

DEMDiethyl maleate, 432

DGEBABisphenol A diglycidyl ether, 95

DGEBTFAdduct of 2-chlorobenzotrifluoride and glycerol diglycidyl ether, 100

DHBP2,5-Dimethyl-2,5-di(tert-butylperoxy)hexane, 383, 413

DHPDOPO10-(2,5-Dihydroxyphenyl)-9,10-dihydro-9-oxa-10-phospha- phenanthrene-10-oxide, 112

DMAAN,N-Dimethylacrylamide, 448

3-DMABA3-dimethylaminobenzoic acid, 125

4-DMABA4-dimethylaminobenzoic acid, 125

DMAEMA2-(Dimethylamino)ethyl methacrylate, 54

DMAMP2-(Dimethylamino)-2-(hydroxymethyl)-1,3-propanediol, 169

DMB.ADimethylol butanoic acid, 60

DMBA4-Dimethylamino-1-butanol, 77

DMPADimethylol propionic acid, 78

DMTDimethyl terephthalate, 23

DMTA2-Dimethylamino-2-methyl-1-propanol, 169

DOPO9,10-Dihydro-9-oxa-10-phosphaphenanthrene-10-oxide, 112, 274

DSCDifferential scanning calorimetry, 27, 71, 126, 198, 254, 271, 351, 374, 432, 465

DTBPDi-tert-butyl peroxide, 414

DVS-BCBBis(benzocyclobutenyl)divinyltetramethylsiloxane, 335

e-EPDMEpoxidized ethylene propylene diene, 139

Page 4: Reactive Polymers Fundamentals and Applications || Index

486 INDEX

EAAEthylene-co-acrylic acid, 140, 386

EDAEthylene diamine, 60

EDMABEthyl-4-dimethylamino benzoate, 461

EGEthylene glycol, 1, 74Expandable graphite, 70

EGMAEthylene/glycidyl methacrylate copolymer, 140, 379

EHMOXAEthyl hydroxymethyl oxazoline, 395

EOEthylene oxide, 3, 56, 399

EPDMEthylene propylene diene monomer, 384

EPNEpoxy-novolak, 282

EPREthylene/propylene rubber, 380

EVAEthylene/vinyl acetate, 102, 309, 379

EVALSHMercapto-modified EVA, 396

12F-PEKFluorinated poly(aryl ether ketone), 106

FAFurfuryl alcohol, 203

6FDAHexafluoropropylidenebisphthalic dianhydride, 231

FT-IRFourier transform infrared (spectroscopy), 71

GLYMO3-Glycidoxypropyltrimethoxysilane, 132

GMAGlycidyl methacrylate, 95, 379, 438

GTLGlycol trilinoleate, 442

HBPHyperbranched polymers, 97

HD1,6-Hexanediol, 58

HDI1,6-Hexane diisocyanate, 6, 51

HDPEHigh density poly(ethylene), 380, 435

HEMA2-Hydroxyethyl methacrylate, 438, 458

Page 5: Reactive Polymers Fundamentals and Applications || Index

INDEX 487

HIPSHigh impact poly(styrene), 375

HMF5-Hydroxymethylfurfural, 203

HMTAHexamethylenetetramine, 169

HOTHot offset temperature, 479

HPMN-(4-Hydroxyphenyl)maleimide, 272

HQHydroquinone, 236

HTEP(6-Hydroxy)hexyl-2-(trimethylaminonio)ethyl phosphate, 77

IAItaconic acid, 430

ICIntegrated circuites, 286

IFSSInterfacial shear strength, 295

IPDIIsophorone diisocyanate, 51

IPNInterpenetrating polymer network, 258, 283, 376

IPO2-isopropenyl-2-oxazoline, 404

IRInfrared spectroscopy, 19, 62, 205, 253, 273, 344, 379

LCLiquid crystalline, 98

LCDsLiquid crystal displays, 136

LCPLiquid crystalline polymers, 384

LDPELow density poly(ethylene), 344, 380, 425

LLDPELinear low density poly(ethylene), 380, 435

LOILimiting oxygen index, 20, 113, 166, 273

LPALow-profile additives, 17

MAMaleic anhydride, 15, 344, 379, 425

MA-g-PPMaleic anhydride-grafted-poly(propylene), 385

MBAMethacryloyl-β-alanine, 458

MCDEA4,4′-Methylene bis(3-chloro-2,6-diethylaniline), 105

Page 6: Reactive Polymers Fundamentals and Applications || Index

488 INDEX

MDA4,4′-Methylenedianiline, 105

MDIDiphenylmethane diisocyanate, 51, 353, 381

MDPEMedium density poly(ethylene), 378

MFMelamine/formaldehyde, 197

MFIMelt flow index, 411

MFRMelt flow rate, 411

MFTMinimum fix temperature, 479

MKEA4,4-Bis(N,N-dimethyl-N-(2-ethoxycarbonyl-1-propenyl)ammonium hexafluoro antimonate)benzophenone,

122MMA

Methyl methacrylate, 438MMT

Montmorillonite, 11, 350, 437MPGE

4-(N-Maleimidophenyl)glycidyl ether, 270MPTS

3-Methacryloxypropyl-trimethoxysilane, 235MWCNT

Multiwalled carbon nanotube, 207, 288, 357, 389MWD

Molecular weight distribution, 423NBR

Nitrile butadiene rubber, 104, 379NLO

Nonlinear optical, 1371H-NMR

Proton nuclear magnetic resonance spectroscopy, 95OCDI

4,4′-Diphenylmethane carbodiimide, 383ODOPB

2-(6-Oxid-6H-dibenz[c,e][1,2]oxa-phosphorin-6-yl)-1,4-benzenediol, 112OMT

organophilic montmorillonite, 69OXA

Ricinoloxazoline maleate, 438PA

Polyamide, 140, 345, 379PA6

Poly(ε-caprolactam), 387Polyamide 6, 139, 350, 383, 436

PANIPoly(aniline), 245

Page 7: Reactive Polymers Fundamentals and Applications || Index

INDEX 489

PAVEPerfluoro (alkyl vinyl ether), 315

PBAPentabromobenzyl acrylate, 335

PBO2,2′-(1,3-Phenylene)bis(2-oxazoline), 398

PBTPoly(butylene terephthalate), 140, 367, 379

PCPoly(carbonate), 245, 351, 395

PCDMAPoly(carbonate)dimethacrylate, 474

PCLPoly(ε-caprolactone), 354, 381, 443

PDClPOPoly(2,6-dichloro-1,4-phenylene oxide), 390

PEPoly(ethylene), 341, 385, 437

PE-g-MAPoly(ethylene) grafted with maleic anhydride, 385, 437

PECHPoly(epichlorohydrin), 70

PEEKPoly(ether ether ketone), 103, 285

PEEKPoly(ether ether ketone), 285

PEEK-CPhenolphthalein poly(ether ether ketone), 103

PEEK-TPoly(ether ether ketone) based on tertiary butyl hydroquinone, 103

PEGPoly(ethylene glycol), 81, 197, 271, 320, 357

PEG-PDMSBlock copolymer of poly(ethylene glycol) and poly(dimethyl siloxane), 446

PEIPoly(etherimide), 283

PENPoly(ethylene 2,6-naphthalate), 390

PEOPoly(ethylene oxide), 102, 374Poly(ethylene-octene) copolymer, 387

PETPoly(ethylene terephthalate), 30, 129, 231, 351, 379, 436

PFphenol/formaldehyde (resin), 155

PFSPhenol/formaldehyde sulfonate, 175

PHBPoly(p-hydroxybenzoate), 390

Page 8: Reactive Polymers Fundamentals and Applications || Index

490 INDEX

PHBVPoly(β-hydroxybutyrate-co-β-hydroxyvalerate), 354

PLβ-Propiolactone, 77

PLAPoly(lactic acid), 353, 388Poly(lactide), 355

PLEPhotopolymerizable liquid encapsulants, 138

PMDAPyromellitic dianhydride, 365

PMMAPoly(methyl methacrylate), 69, 102, 226, 235, 373, 442

POSSPolyhedral oligomeric silsesquioxane, 469

PPPoly(propylene), 341, 378, 420, 428

PPDEPoly(phthaloyl diphenyl ether), 285

PPEPoly(phenylene ether), 138, 398

PPGPolyoxypropylene glycol, 264

PPIDEPoly(phthaloyl diphenyl ether-co-isophthaloyl diphenyl ether), 285

PPOPoly(2,6-dimethyl-1,4-phenylene oxide), 379

PPTDEPhthaloyl diphenyl ether-co-terephthaloyl diphenyl ether, 285

PPyPoly(pyrrole), 107, 478

PSPoly(styrene), 347, 374, 441

PSAPressure-sensitive adhesives, 311

PTFEPoly(tetrafluoroethylene), 165, 448

PTMEGPoly(tetramethylene ether), 349

PTTPoly(trimethylene terephthalate), 375

PUPoly(urethane), 49

PUDMAPoly(urethane) dimethacrylate, 456

PUEPoly(urethane) elastomer, 69

PVAPoly(vinyl alcohol), 197

Page 9: Reactive Polymers Fundamentals and Applications || Index

INDEX 491

PVCPoly(vinyl chloride), 63, 132, 399, 440, 478

PVDFPoly(vinylidene fluoride), 393

PVDHPoly(vinylidene difluoride-co-hexafluoropropylene), 296

re-HDPERecycled high density poly(ethylene), 380

RTMResin transfer molding, 270

s-PSSyndiotactic poly(styrene), 139

SANPoly(styrene-co-acrylonitrile), 102, 392

SBRStyrene butadiene rubber, 314, 396, 438

SDSSodium dodecyl sulfate, 446

SEBSStyrene-b-(ethylene-co-1-butene)-b-styrene triblock copolymer, 380

SEBS-g-MAStyrene-ethylene/butylene-styrene triblock copolymer, 379

SEMScanning electron microscopy, 16, 283, 353, 380

SGStyrene/glycidyl methacrylate, 139

SIPO2-Isopropenyl-2-oxazoline, 404

SISPoly(styrene-b-isoprene-b-styrene), 311

SMAStyrene/maleic anhydride copolymer, 384, 437

SOCSpiroorthocarbonate, 120, 459

SSOSilsesquioxane, 128

SUS10-Undecenyl sulfate, 446

TAICTriallyl isocyanurate, 138

TBBPATetrabromobisphenol A, 97

TDIToluene diisocyanate, 50, 376

TDSTransdermal delivery system, 246

TEATriethylamine, 169

TEGDMATriethylene glycol dimethacrylate, 454

Page 10: Reactive Polymers Fundamentals and Applications || Index

492 INDEX

TEMPO2,2,6,6-Tetramethyl-1-piperidinyloxy, 400

TEOSTetraethoxysilane, 112, 360

TFETetrafluoroethylene, 315

TGAThermogravimetric analysis, 239

TGDDMTetraglycidyl-4,4′-diaminodiphenylmethane, 97, 366

THFTetrahydrofuran, 458

TLCPThermotropic liquid crystalline polymer, 389

TMDSCModulated differential scanning calorimetry, 126

TMPTATrimethylol propane triacrylate, 349

TPSThermoplastic starch, 396

TPUThermoplastic polyether poly(urethane)s, 80

TRISTrimethylol propane triacrylate, 438

UBMIUrethane-modified bismaleimide, 111

UDMA1,6-Bis(methacryloxy-2-ethoxycarbonylamino)-2,4,4-trimethylhexane, 456

UFUrea/formaldehyde, 5, 162, 180

UHMFUltra high melt flow, 421

UHMWPEUltra-high molecular weight poly(ethylene), 447, 471

UPUnsaturated polyester, 1

VAcVinyl acetate, 438

VEUHVinylester-urethane hybrid resins, 139

VOACVinylbenzyloctadecyldimethyl ammonium chloride, 12

VOCsVolatile organic compounds, 423

VTEOSVinyltriethoxysilane, 437

VTMSVinyltrimethoxysilane, 437

Page 11: Reactive Polymers Fundamentals and Applications || Index

INDEX 493

WPUWaterborne poly(urethane), 79

ZrDMAZirconyl dimethacrylate, 470

Chemicals

α-Methylene-γ -butyrolactone, 459α-Methylstyrene, 4α-Pinene, 303α,α′-Dibromo-m-xylene, 292β-Pinene, 303β-Propiolactone, 77((3-(4-(1-(4-(3-(Bis-carboxymethylamino) 2-hydroxy-propoxy) phenyl)-1-methyl-ethyl) phenoxy)

2-hydroxypropyl) carboxy methylamino) acetic acid, 81,(3-Aminopropyl)triethoxysilane, 132, 447(4-(N,N-Diallyl)-4′-nitrophenyl)azoaniline, 297(4-Octyloxyphenyl)phenyliodonium hexafluoroantimonate, 124(6-Hydroxy)hexyl-2-(trimethylaminonio)ethyl phosphate, 771,1,2,2-Tetramethoxyethane, 1801,1-Bis(4-cyanatophenyl)ethane, 2521,1-Dimethyl-3-hydroxybutyl hydroperoxide, 4331,10-Decanediol, 741,1′-(Methylene di-4,1-phenylene)bismaleimide, 2891,2,4-Trimethoxybenzene, 1251,2-Bis(2,3-epoxycyclohexyloxy)propane, 1301,2-Bis(4-benzocyclobutenyl)ethylene, 3361,2-Bis(benzocyclobutenyl)ethane, 3311,2-Bis(isocyanate)ethoxyethane, 501,2-Bis-[2(2-hydroxy-5-methylphenyl)-5-benzotriazolyl]-ethane, 541,2-Dihydrocyclobutabenzene-3,6-dicarboxylic acid, 3321,2-Epoxy-3-phenoxypropane, 1061,2-Propanediol, 81,3,5-Tris(3-dimethylaminopropyl)-s-hexahydrotriazine, 641,3-Bis(4-cyanatophenyl-1-(1-methylethylidene))benzene, 2521,3-Bis[2′-cyano-3′,3-diphenylacryloyloxy]- 2,2-bis-[[2-cyano-3′,3′-diphenylacryloyloxy]methyl]propane, 4711,3-Propanesulfone, 771,3-[Di(4-glycidyloxy diphenyl-2,2′-propane)]isophthalate, 2611,3-dichlorotetramethyldisiloxane, 2261,4-Butane diamine, 791,4-Butanediol, 771,4-Di(tert-butylperoxyisopropyl)benzene, 4171,4-Diaminobutane, 4371,4-Diazabicyclo[2.2.2]octane, 63, 641,4-[Di(4-cyanato diphenyl-2,2′-propane)]terephthalate, 2611,4-dilithio-1,3-butadiyne, 2261,5,7-Triazabicyclo[4.4.0]dec-5-ene, 3231,5-Diazabicyclo[4.3.0]non-5-ene, 3231,5-Diazobicyclo[4.3.0]non-5-ene, 64

Page 12: Reactive Polymers Fundamentals and Applications || Index

494 INDEX

1,5-Hexadiyne, 3311,5-Naphthalene diamine, 1161,6-Bis(methacryloxy-2-ethoxycarbonylamino)-2,4,4-trimethylhexane, 4561,6-Hexane diamine, 551,6-Hexane diisocyanate, 521,6-hexanediol dimethacrylate, 4571,7-Bis(chlorotetramethyldisiloxy)-m-carborane, 2261,8-Diazabicyclo[5.4.0]undec-7-ene, 3231,8-Diazobicyclo[5.4.0]undec-7-ene, 641-(α-Naphthyl)-3,3-di(2-hydroxyethyl)-triazene-1, 601-(2-Aminoethyl)piperazine, 3971-(2-Methoxyphenyl)piperazine, 731-(3-Dimethylaminopropoxy)-2-butanol, 651-(isopropenylphenyl)-1,1-dimethylmethyl isocyanate, 541-Methylimidazole, 641-Phenyl-3,3-di(2-hydroxyethyl)-triazene-1, 601-Pyrenesulfonyl chloride, 12710-Undecenyl sulfate, 44611-Methacryloyloxy-1,1-undecanedicarboxylic acid, 4622,14-Dithiacalix[4]arene, 1592,2,6,6-Tetramethyl-1-piperidinyloxy, 400, 4462,2,6,6-tetramethyl-1-piperidinyloxy, 4192,2-Bis(4-cyanatophenyl)propane, 2522,2-Bis[4-(4-aminophenoxy)phenyl]propane, 2312,2-Bis[4-(4-maleimido phenoxy)phenyl]propane, 269, 270, 2952,2-Bis[p-(2-hydroxy-3-methacryloxypropoxy)phenyl]propane, 4552,2-Dimethoxy-1,2-diphenylethan-1-one, 1252,2-Dimethoxy-2-phenylacetophenone, 2402,2′-(1,3-Phenylene)bis(2-oxazoline), 3982,2′-(1,4-Phenylene)bisoxazoline, 3832,2′-Diallyl bisphenol A, 109, 2562,2′-Dipyridyl disulfide, 3212,3-Bis(4-(4-aminophenoxy)phenyl)quinoxaline-6-carboxylic acid, 2792,3-Bis(4-aminophenyl)quinoxaline-6-carboxylic acid, 2792,4,6-Trimethylbenzoyldiphenylphosphine oxide, 242,4,6-Triphenylpyrylium tetrafluoroborate, 3252,4,6-Tris(2,4,6-tribromophenoxy)-1,3,5-triazine, 1132,4-Di(2-allylphenoxy)-6-(2-naphthyloxy)-1,3,5-triazine, 283, 2852,4-Diamino-4′-methylazobenzene, 1162,4-Dihydroxybenzophenone, 4712,5-Dimethyl-2,5-di(tert-butylperoxy)-3-hexyne, 3522,5-Dimethyl-2,5-di(tert-butylperoxy)hexane, 352, 383, 4132,6-Di(4-aminophenoxy)benzonitrile, 2832,6-di-(2-pvridyl)-1-methyl-piperid-4-one-3,5-dicarboxylate, 252,6-di-tert-Butyl-4-methylphenol, 4662-(6-Oxid-6H-dibenz[c,e][1,2]oxa-phosphorin-6-yl)-1,4-benzenediol, 1122-(6-Oxid-6H-dibenz[c,e][1,2]oxaphosphorin-6-yl)methanol, 1122-(Dimethylamino)-2-(hydroxymethyl)-1,3-propanediol, 1692-(dimethylamino)ethyl methacrylate, 542-Acetoxyethyl-dibutyltin chloride, 67

Page 13: Reactive Polymers Fundamentals and Applications || Index

INDEX 495

2-Azabicyclo[2.2.1]heptane, 642-Benzyl-2-dimethylamino-1-(4-morpholinophenyl)butan-1-one, 1252-Dimethylamino-2-methyl-1-propanol, 1692-Ethylhexyl acrylate, 2362-Hydroxy-2-methyl-1-phenyl-propan-1-one, 242-Hydroxy-4-octoxybenzophenone, 4712-Hydroxyethyl methacrylate, 81, 235, 3542-Hydroxymethyl-4,6-dimethylphenol, 1662-Hydroxypropyl acrylate, 112-Isocyanatoethyl methacrylate, 235, 4552-Isopropenyl-2-oxazoline, 4042-Methyl-1,3-propanediol, 82-Methyl-1-[4-(methylthio)phenyl]-2-morpholinopropan-1-one, 1252-Methyl-2,4-bis(2,3-epoxycyclohexyloxy)pentane, 1302-Methyl-2,5-dioxo-1-oxa-2-phospholane, 212-[(3,5-dimethylpyrazolyl) carboxyamino]ethyl methacrylate, 72-tert-Butylperoxy-2-methyl-5-hexene-3-yne, 3852-isopropenyl-2-oxazoline, 404, 4372-methacryloyloxyethyl isocyanate, 73,23-dioxatrispirotricyclo[3.2.1.0[2.4]]octane-6,5′-1,3-dioxane- 2′2′′- 1,3-dioxane-5′′,

7′′′-tricyclo[3.2.1.0[2.4]octane], 1203,3′,4,4′-Diphenyl sulfone tetracarboxylic dianhydride, 2313,3′-dihydroxy-4,4′-diaminobiphenyl, 2313,5-Bis(4-aminophenoxy)benzoic acid, 553,5-Di-tert-butyl-4-hydroxybenzyl acrylate, 438, 4383,6,9-Triethyl-3,6,9-trimethyl-1,4,7-triperoxonane, 4153,9-Di(p-methoxybenzyl)-1,5,7,11-tetra-oxaspiro[5.5]undecane, 1203-Glycidoxypropyltrimethoxysilane, 132, 2193-Isopropenyl-α,α-dimethylbenzene isocyanate, 383, 3833-Ketocoumarin, 1373-Methacryloxypropoxytrimethoxysilane, 4703-Methacryloxypropyl-trimethoxysilane, 2353-Methyl-1,2,3,6-tetrahydrophthalic anhydride, 1184,4-Bis(N,N-dimethyl-N-(2-ethoxycarbonyl-1-propenyl)ammonium hexafluoro antimonate)benzophenone, 1224,4-Methylene biscyclohexyl diisocyanate, 504,4′-Bis(2-hydroxy-3-methacryloylpropoxy)biphenyl, 4574,4′-Bis(maleimido)diphenylmethane, 2694,4′-Diamino-3,3′-dimethyldicyclohexylmethane, 1154,4′-Diaminodiphenyl sulfone, 102, 1164,4′-Diaminodiphenylmethane, 116, 272, 2774,4′-Dihydroxychalcone, 1364,4′-Diphenylmethane carbodiimide, 3834,4′-Methylene bis(3-chloro-2,6-diethylaniline), 1054,4′-Methylenedianiline, 1054,4′-Oxydianiline, 2774,4′-Oxydiphthalic anhydride, 3344,4′-[1,3-phenylene(1-methyl ethylidene)]bisaniline, 3344-(N-Maleimidophenyl)glycidyl ether, 2704-(N-maleimidophenyl)glycidyl ether, 2734-Amino-benzocyclobutene, 334

Page 14: Reactive Polymers Fundamentals and Applications || Index

496 INDEX

4-Dimethylamino-1-butanol, 774-Dimethylaminobenzaldehyde, 1254-Dimethylaminobenzoin, 1254-Hydroxyacetophenone, 2044-Vinyl-1-cyclohexene, 2215-(2,5-Dioxotetrahydrofuryl)-3-methyl-3-cyclohexene-1,2-dicarboxylic anhydride, 1185-Hydroxymethylfurfural, 2035-[2-(5-Methyl furylene vinylene)]furancarboxyaldehyde, 2125-dimethylaminonaphthalene-1-(2-aminoethyl)sulfonamide, 1276,6′-Dithiodinicotinic acid, 3217,26-Dioxatrispirobicyclo[4.1.0]heptane-4,5′-1,3-dioxane-2′,2′′-1,3-dioxane-5′′,4′′-bicyclo[4.1.0]heptane, 4599,10-Dihydro-9-oxa-10-phosphaphenanthrene-10-oxide, 70, 112, 2749-Anthroic acid, 127N,N-Dimethyl-p-toluidine, 461N,N-Dimethylacrylamide, 448N,N-Dimethylethanolamine, 64N,N-Dimethylethylethanolamine, 77N,N ′-(4-aminophenyl)-p-benzoquinone diimine, 271N,N ′-Carbonylbiscaprolactam, 53, 53N,N ′-Ethylene-bisstearamide, 350N-(4-Hydroxyphenyl)maleimide, 272N-Ethylmorpholine, 64N-Phenylglycine, 125N-tert-butyl-1-diethylphosphono-2,2-dimethylpropyl nitroxide, 419N-aminoethyl piperazine, 116m-Phenylene diamine, 116, 174m-Tetramethylxylene diisocyanate, 52o-Carboxy phthalanilic acid, 7o-Diazonaphthoquinone, 172o-Quinodimethane, 331o-Xylylene, 331p-Aminophenol, 97p-Vinyltoluene, 4p-Aminophenol, 97p-Methylcalix[6]arene, 123p-Phenyl diamine, 270acrylic acid 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9-hexadecafluoro-nonyl ester, 348glycidyl methacrylate, 455polyamide 6, 43610-(2,5-Dihydroxyphenyl)-9,10-dihydro-9-oxa-10-phospha- phenanthrene-10-oxide, 112α,α′-Bis(tert-butylperoxy)diisopropyl benzene, 416α,α′-Dihydroxyl-poly(butyl acrylate), 54α,α′-dimethylol propionic acid, 81α-Cumylperoxyneodecanoate, 415α-Hydroxy-acetophenone, 24α-hydroxy-acetophenone, 24α-Methylene-γ -butyrolactone, 455α-Methylstyrene, 4α-methylstyrene, 4, 221, 239α-Pinene, 303

Page 15: Reactive Polymers Fundamentals and Applications || Index

INDEX 497

α-terpineol, 129α,α′-di(tert-butylperoxy)diisopropylbenzene, 395α,α,α′,α′-tetrabromo-o-xylene, 331β-carotine, 303β-Naphthol, 156β-Pinene, 303γ -butyrolactone, 169ε-Caprolactam, 375ε-caprolactam, 53, 383(3-aminopropyl)triethoxysilane, 14, 69, 210, 280(3-methacryloxypropyl)trimethoxysilane, 13–15(4-(1-methylethyl)phenyl)(4-methylphenyl)iodonium tetrakis pentafluorophenylborate, 124(4-(2-hydroxytetradecyloxyphenyl))phenyliodoniumhexafluoroantimonate, 124(4-(N,N-diallyl)-4′-nitrophenyl)azoaniline, 296(N-4,6-diamino-1,3,5-triazin-2-yl)-1,3,5-triazine-2,4,6-triamine, 1931,1,1-Trimethylol propane, 601,1,1-trimethylol propane, 52, 57, 581,1,1-trimethylol propane dipropenyl ether, 51,1,1-tris(4-hydroxyphenyl)ethane, 1371,1,4,4,7,7-Hexamethylcyclo-4,7-diperoxynonane, 4131,1-bis(3-methyl-4-cyanatophenyl)cyclohexane, 2521,1-Bis(4-cyanatophenyl)ethane, 2521,1-bis(4-cyanatophenyl)ethane, 1271,1-bis(tert-butylperoxy)-3,3,5-trimethylcyclohexane, 33, 2421,1-Di(tert-amylperoxy)cyclohexane, 4131,1-Di(tert-butylperoxy)-3,3,5-trimethylcyclohexane, 34, 4131,1-di(tert-butylperoxy)-3,3,5-trimethylcyclohexane, 4421,1-Di(tert-butylperoxy)cyclohexane, 4131,1-di-(tert-butylperoxy)cyclohexane, 351,1-Dibromo-2,2-bis(4-cyanatophenyl)ethylene, 2521,1-Dichloro-2,2-bis(4-cyanatophenyl)ethylene, 2521,1-Dimethyl-3-hydroxybutyl-2-(carboxy)perbenzoate, 4321,1-dimethyl-3-hydroxybutyl-2-(carboxy)perbenzoate, 4331,1-Dimethyl-3-hydroxybutyl-2-(carboxy)peroxycyclohexanecarboxylate, 4321,1-Dimethyl-3-hydroxybutyl-3-(carboxy)-5-norbornene-2-yl- peroxycarboxylate, 4321,1-Dimethyl-3-hydroxybutyl-6-(hydroxy)peroxyhexanoate, 4321,1-Dimethyl-3-hydroxypropyl-3-(carboxy)peroxypropanoate, 4321,1′-(1-methylethylidene)bis(4-(1-(2-furanylmethoxy)- 2-propanolyloxy))benzene, 2781,1′-(methylene di-4,1-phenylene)bismaleimide, 2821,2,3,4,5-pentamethylcyclopenta-1,3-dienide, 2921,2,4-trichlorobenzene, 4001,2,5,6-dibenzocyclooctadiene, 3311,2-bis(aminomethyl)cyclobutane, 1151,2-butanediol, 291,2-Diaminocyclohexane, 1151,2-Dihydrocyclobutabenzene-3,6-dicarboxylic acid, 3311,2-dihydrocyclobutabenzene-3,6-dicarboxylic acid, 3341,2-dimethylimidazole, 631,2-epoxy-3-phenoxypropane, 1121,2-naphthoquinonediazide, 172

Page 16: Reactive Polymers Fundamentals and Applications || Index

498 INDEX

1,2-propanediol, 291,2-propylene glycol, 5, 71,3,5-triazine-2,4,6-triamine, 1931,3,5-tris(3-dimethylaminopropyl)-s-hexahydrotriazine, 631,3-aminoethylpropanediol, 3951,3-Bis(3-aminopropyl)tetramethyl disiloxane, 961,3-Bis(4-cyanatophenyl-1-(1-methylethylidene))benzene, 2521,3-Bis(4-cyanatophenyl-1-(methylethylidene))benzene, 2521,3-bis(4-maleimido phenoxy)benzene, 2711,3-Bis(maleimido)benzene, 2801,3-Bis(maleimidomethyl)cyclohexane, 270, 2801,3-butanediol dimethacrylate, 4571,3-Di(2-tert-butylperoxyisopropyl)benzene, 4161,3-di-n-butyltetramethyldisilazane, 2271,3-di-tert-butyltetramethyldisilazane, 2271,3-dichlorotetramethyldisiloxane, 2251,3-Didodecyloxy-2-glycidyl-glycerol, 951,3-diethenyl-1,1,3,3-tetramethyldisiloxane, 2231,3-dihexyltetramethyldisilazane, 2271,3-diphenyltetramethyldisilazane, 2271,3-divinyl-1,1,3,3-tetramethyldisiloxane, 2231,4-bis(4-maleimido phenoxy)benzene, 2711,4-bis(diethoxymethyl silyl)benzene, 2191,4-bis(ethoxydimethyl silyl)benzene, 2271,4-butanediisocyanate, 771,4-Butanediol, 23, 96, 1571,4-butanediol, 29, 34, 69, 1851,4-butanediol diglycidyl ether, 95, 1331,4-Cyclohexane diamine, 601,4-cyclohexanedimethanol, 33, 1031,4-Di(2-hydroxyethyl)hydroquinone, 601,4-Di(tert-butylperoxyisopropyl)benzene, 4131,4-diallyl phenyl ether, 2701,4-diazabicyclo[2.2.2]octane, 631,4-dihydroxybenzene, 4311,4-dilithio-1,3-butadiyne, 2251,5-diazabicyclo[4.3.0]non-5-ene, 3231,5-diazobicyclo[4.3.0]non-5-ene, 641,5-Hexadiyne, 3311,5-Naphthalene diamine, 1151,5-Naphthalene diisocyanate, 501,5-naphthalene diisocyanate, 491,6-hexamethylene-bis(2-furanylmethylcarbamate), 2791,6-Hexane bismaleimide, 2701,6-hexanediol diacrylate, 242, 2451,6-Hexanediol dimethacrylate, 4571,7-Bis(chlorotetramethyldisiloxy)-m-carborane, 2251,8-Diazabicyclo[5.4.0]undec-7-ene, 3241,8-diazabicyclo[5.4.0]undec-7-ene, 3231,8-Diazobicyclo[5.4.0]undec-7-ene, 64

Page 17: Reactive Polymers Fundamentals and Applications || Index

INDEX 499

1-(2-hydroxypropyl)imidazole, 631-(3′-(Imidazolinyl)propyl)urea, 631-(3′-Aminopropyl)imidazole, 631-allyl-2-cyanatobenzene, 2511-Benzocyclobutenyl vinyl ether, 331, 3331-benzocyclobutenyl-1-bromoethyl ether, 3331-benzocyclobutenyl-1-hydroxyethyl ether, 3311-benzyl-5-phenylbarbituric acid, 4611-bromobenzocyclobutene, 3331-chloro-2,3-epoxypropane, 951-decene, 991-diisobutylene, 3061-dodecene, 99, 4421-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)amide, 1751-hexene, 4461-Methoxypoly(oxyethylene)benzocyclobutene, 3311-methoxypoly(oxyethylene)benzocyclobutene, 3311-methyl-3-propyl-5-butylmelamine, 1931-methylimidazole, 63, 1161-methylpiperazine, 651-octadecanethiol, 3501-octene, 991-tetradecene, 991-vinyl-2-pyrrolidinone, 18310-undecene-1-ol, 44617-β-estradiol, 2462(di-methylamino)ethanol, 652,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9-hexadecafluoro-decane-1,10-diol, 1002,2,3,3,4,4,5,5-octafluoro-hexane-1,6-diol, 1002,2,5,5-Tetramethyl-1-pyrrolidinyloxy, 4192,2,6,6-Tetramethyl-1-piperidinyloxy, 4192,2,6,6-Tetramethyl-4-hydroxypiperidine-1-oxyl monophosphonate, 4192,2-Bis(4,4-di-tert-butylperoxycyclohexyl)propane, 4132,2-Bis(4-(oligo(ethoxy))phenyl)propane diacetate, 4632,2-Bis(4-(oligo(ethoxy))phenyl)propanedimethacrylate, 4632,2-Bis(4-Cyanatophenyl)1,1,1,3,3,3-hexafluoropropane, 2522,2-Bis(4-cyanatophenyl)propane, 2522,2-bis(4-cyanatophenyl)propane, 2632,2-Bis(4-hydroxy-3,5-dibromophenyl)propane, 2382,2-Bis(4-hydroxyphenyl)butane, 1562,2-Bis(4-hydroxyphenyl)propane, 1562,2-bis[4-(4-maleimido phenoxy)phenyl]propane, 2632,2-Di(tert-amyl)peroxypropane, 4132,2-Di(tert-butylperoxy)butane, 4132,2-Dimethoxy-2-phenylacetophenone, 242,2′-(1,3-Phenylene)bis(2-oxazoline), 3502,2′-[(1-Methylethylidene) bis[(2,6-dibromo-4,1-phenylene)oxy]] bis[4,6-bis[(2,4,6-tribromophenyl)oxy]]-1,3,5-

triazine, 1122,2′-[(1-Methylethylidene)bis(4,1-phenyleneoxymethylene)]bis(oxirane), 1002,2′-Azobis(2,4-dimethyl-4-methoxyvaleronitrile), 418

Page 18: Reactive Polymers Fundamentals and Applications || Index

500 INDEX

2,2′-Azobis(2,4-dimethylvaleronitrile), 240, 4182,2′-azobis(2,4-dimethylvaleronitrile), 4442,2′-Azobis(2-acetoxy)propane, 4182,2′-azobis(2-acetoxy)propane, 3952,2′-azobis(2-amidinopropane)hydrochloride, 2492,2′-azobis(2-ethylpropionitrile), 4452,2′-Azobis(2-methylbutyronitrile), 4182,2′-azobis(2-methylbutyronitrile), 232,2′-Azobis(cyclohexanenitrile), 4182,2′-Azobis(isobutyronitrile), 2402,2′-azobis(isobutyronitrile), 23, 444, 4772,2′-Bis(α-methacryloxy-β-hydroxypropoxyphenyl)propane diphosphonate, 4712,2′-bis(4-cyanatophenyl)isopropylidene, 2582,2′-bis(4-cyanatophenyl)propane, 2582,2′-Diallyl bisphenol A, 270, 283, 285, 289, 2922,2′-diallyl bisphenol A, 284, 2912,2′-Diallylbisphenol A, 2592,2′-Dihydroxy-4,4′-dimethoxybenzophenone, 2382,2′-Dihydroxy-4-methoxybenzophenone, 2382,2′-dipyridyl disulfide, 3212,2′-dithiobis(benzothiazole), 3582,2′-oxybis(N,N-dimethylethanamine), 642,2′-pyromellitdiimidodisuccinic anhydride, 592,2′-thiobis[4-tert-butylphenol], 1592,3,8,9-Di(tetramethylene)-1,5,7,11-tetraoxaspiro[5.5]undecane, 952,3,8,9-di(tetramethylene)-1,5,7,11-tetraoxaspiro[5.5]undecane spiroorthocarbonate, 1202,3-butanediol, 292,3-dimethyl-2,3-diphenylbutane, 4332,3-epoxypropoxy methacrylate, 4582,3-Epoxypropyl(methyl)dimethoxysilane, 2192,3-Epoxypropyl(phenyl)dimethoxysilane, 2192,3-Epoxypropyltriethoxysilane, 2192,3-Epoxypropyltrimethoxysilane, 2192,3-epoxypropyltrimethylammonium chloride, 3622,3-tris(dibromopropylene)phosphate, 4342,4,6-Trimethylbenzoyldiphenylphosphine oxide, 24, 4572,4,6-trimethylbenzoyldiphenylphosphine oxide, 232,4,6-trimethylphenol, 1652,4,6-Tris(2,4,6-tribromophenoxy)-1,3,5-triazine, 1122,4,6-tris(dimethylaminomethyl)phenol, 66, 1172,4-Di(2-allylphenoxy)-6-N,N-dimethylamino-1,3,5-triazine, 2832,4-di(2-allylphenoxy)-6-N,N-dimethylamino-1,3,5-triazine, 2852,4-diamino-3,5-diethyl toluene, 1152,4-diethylthioxanthone, 1222,4-Dihydroxybenzophenone, 2382,4-dimethyl-2,5-di(tert-butylperoxy)-3-hexyne, 4032,4-dinitrotoluene, 512,4-hexadienedioic acid, 4032,4-Pentandione, 182,5,8-triamino-1,3,4,6,7,9,9b-heptaazaphenalene, 193

Page 19: Reactive Polymers Fundamentals and Applications || Index

INDEX 501

2,5-Bis(aminomethyl)bicyclo[2.2.1]heptane di(methylisopropylketimine), 1162,5-dicarboxyaldehyde-furan, 2032,5-Dimethyl-2,5-bis(benzoylperoxy)hexane, 1192,5-Dimethyl-2,5-di(2-ethylhexanoylperoxy)hexane, 4132,5-Dimethyl-2,5-di(tert-butylperoxy)-3-hexyne, 413, 4162,5-dimethyl-2,5-di(tert-butylperoxy)-3-hexyne, 395, 4152,5-Dimethyl-2,5-di(tert-butylperoxy)hexane, 413, 4302,5-dimethyl-2,5-di(tert-butylperoxy)hexane, 4222,5-Dimethyl-2,5-di(benzoylperoxy)hexane, 4132,5-Dimethyl-2,5-di(hydroperoxy)hexane, 4132,5-dimethyl-2,5-di-tert-butylperoxyhexane, 4152,5-dimethyl-2,5-di(tert-butylperoxy)hexane, 4152,5-Dimethylhexene-2,5-diperoxyisononanoate, 4152,5-Furandicarboxylic acid, 2032,6-Bis(4-benzocyclobutenyloxy)benzonitrile, 3312,6-Bis-4-benzocyclobutene benzo[1,2-d:5,4-d′]bisoxazole, 3312,6-diamino-3,5-diethyl toluene, 1152,6-dimethyl-3,5-diacetyl-1,4-dihydropyridine, 1792,7-dihydroxynaphthalene dicyanate, 2522-(2-N,N-Diethylaminoethoxy)ethanol, 632-(2-N,N-diethylaminoethoxy)ethanol, 662-(2′-Hydroxy-5′-tert-octylphenyl)benzotriazole, 2382-(3,4-Epoxycyclohexyl)ethyl(methyl)dimethoxysilane, 2192-(3,4-Epoxycyclohexyl)ethyl(phenyl)diethoxysilane, 2192-(3,4-Epoxycyclohexyl)ethyltriethoxysilane, 2192-(3,4-Epoxycyclohexyl)ethyltrimethoxysilane, 2192-(3,5-Di-tert-amyl-2-hydroxyphenyl)benzotriazole, 2382-(3,5-Di-tert-Butyl-2-hydroxyphenyl)-5-chlorobenzothiazole, 2382-(3,5-Di-tert-butyl-2-hydroxyphenyl)benzotriazole, 2382-(3-tert-Butyl-5-methyl-2-hydroxyphenyl)-5-chlorobenzothiazole, 2382-(5-Methyl-2-hydroxyphenyl)benzotriazole, 2382-(6-Oxid-6H-dibenz[c,e][1,2]oxa-phoshorin-6-yl)-1,4-benzenediol, 952-(Acryloyloxy)ethyl morpholone-4-carboxylate, 2352-(Acryloyloxy)ethyl piperidine-1-carboxylate, 2352-(Dimethylamino)-2-(hydroxymethyl)-1,3-propanediol, 1702-(dimethylamino)-2-(hydroxymethyl)-1,3-propanediol, 1622-(methacryloyloxy)ethyl phosphate, 4582-[(3,5-dimethylpyrazolyl) carboxyamino]ethyl methacrylate, 72-[2-Hydroxy-3,5-bis(α,α-dimethylbenzyl)phenyl]-2H-benzotriazole, 2382-[4-(dimethylamino)phenyl] ethanol, 4612-allylphenol, 265, 284–2862-Azabicyclo[2.2.1]heptane, 632-butyne-1,4-diol, 12-cyanoacrylate, 321, 3232-cyanoacrylic acid, 3202-Cyclohexyl-5-methylphenol, 1562-cyclohexyl-5-methylphenol, 1722-diisobutylene, 3062-Dimethylamino-2-methyl-1-propanol, 162, 1702-Dimethylaminoethyl urea, 65

Page 20: Reactive Polymers Fundamentals and Applications || Index

502 INDEX

2-dodecen-1-yl succinic anhydride, 3812-ethenylisopropanol, 2232-Ethoxyethyl cyanoacrylate, 3182-ethyl-4-methylimidazole, 1162-Ethylhexyl N-methacryloylcarbamate, 2352-ethylhexyl N-methacryloylcarbamate, 2362-Ethylhexyl acrylate, 2352-ethylhexyl acrylate, 101, 235, 4452-ethylhexyl alcohol, 2362-Furan formaldehyde, 2032-Furfurylmethacrylate, 2032-heptanone, 1722-hydroxy-2-methyl-1-phenyl-1-propane, 3252-Hydroxy-2-methylphenylpropane-1-one, 242-hydroxy-2-methylphenylpropane-1-one, 52-Hydroxy-4(2,3-epoxypropoxy) benzophenone, 952-Hydroxy-4-methoxy-4′-chlorobenzophenone, 2382-Hydroxy-4-methoxybenzophenone, 2382-Hydroxy-4-octoxybenzophenone, 2382-Hydroxybenzoquinone, 3222-hydroxyethyl acrylate, 17, 592-hydroxyethyl methacrylate, 133, 242, 3952-hydroxymethyl-4,6-dimethylphenol, 1672-hydroxypropyl acrylate, 138, 4452-isocyanatoethyl methacrylate, 2432-mercaptoethanol, 54, 4442-methacrylamide-2-methylpropenesulfonic acid, 4022-Methacryloyloxyethyl isocyanate, 2352-methacryloyloxyethyl isocyanate, 72-methacryloyloxyethyldihydrogen phosphate, 4622-Methoxy-1-methylethyl cyanoacrylate, 3182-methoxybenzyl-1,3-propanediol, 1202-Methoxyethyl cyanoacrylate, 3182-Methyl-1,3-propanediol, 32-Methyl-1,3-propylene diol, 602-Methyl-2,5-dioxo-1-oxa-2-phospholane, 202-methyl-2,5-dioxo-1-oxa-2-phospholane, 212-methyl-2-(4-piperidyl)-1,3-propanediol, 662-methyl-2-(4-pyridyl)-1,3-propanediol, 662-methylfuran, 206, 2952-methylolphenol, 1712-methylphenol, 1652-naphthol, 2852-octen-1-ylsuccinic anhydride, 4622-Octyl cyanoacrylate, 3182-Phenyl-2-imidazoline, 3232-propenylphenol, 2842-sulfonyl(meth)acrylate, 4023,3,3-Trifluoropropyltrimethoxysilane, 2183,3,4,4,5,5,5-heptafluoro-1-pentene, 233

Page 21: Reactive Polymers Fundamentals and Applications || Index

INDEX 503

3,3,6,6,9,9-Hexamethylcyclo-1,2,4,5-tetraoxanonane, 4133,3′,5,5′-Tetraethyl-4,4′-diaminodiphenylmethane, 1153,3′-(p-phenylene)bis(2,4,5-triphenylcyclopentadienone), 2783,3′-(oxydi-p-phenylene)bis(2,4,5-triphenylcyclopentadienone), 2783,3′-Bis(maleimidophenyl)phenylphosphine oxide, 2883,3′-bis(maleimidophenyl)phenylphosphine oxide, 2743,4-Epoxycyclohexyl-methyl-3,4-epoxycyclohexane carboxylate, 953,4-epoxycyclohexylmethyl-3′,4′-epoxycyclohexane carboxylate, 1223,4-ethylenedioxythiophene, 4783,4-poly(isoprene), 3113,5,5-Trimethylhexanoyl peroxide, 4133,5-di-tert-butyl-4-hydroxyphenyl-propanoic acid, 4313,5-diacetyl-1,4-dihydrolutidine, 1793,5-diaminobenzoic acid, 673,5-diaminophenyl-4-benzocyclobutenylketone, 3343,5-dimethylpyrazole, 533,5-Dimethylthio-toluene diamine, 603,6,6,9,9-Pentamethyl-3-(ethyl acetate) 1,2,4,5-tetraoxacyclononane, 4133,6,6,9,9-Pentamethyl-3-n-propyl-1,2,4,5-tetraoxacyclononane, 4133,6,9-triethyl-3,6,9-trimethyl-1,4,7-triperoxonane, 414, 4223,6,9-triethyl-3-6-9-trimethyl-1,4,7-triperoxonane, 4233,7,11-Trimethyl-1-dodecyn-3-ol, 2243,9-Di(p-methoxybenzyl)-1,5,7,11-tetra-oxaspiro[5.5]undecane, 1203-(2-cyanatophenyl)propyltrimethoxysilane, 2653-(4-cyanatophenyl)propyltrimethoxysilane, 2653-aminopropyltriethoxysilane, 245, 3463-Carboxy-2,2,5,5-tetramethyl-pyrrolidinyloxy, 4193-Chloro-1,2-propanediol, 703-dimethylamino-1,2-propanediol, 693-Dimethylaminobenzoic acid, 1253-Glycidoxypropyl(methyl)dibutoxysilane, 2193-Glycidoxypropyl(methyl)diethoxysilane, 2193-Glycidoxypropyl(methyl)dimethoxysilane, 2193-Glycidoxypropyltributoxysilane, 2193-Glycidoxypropyltriethoxysilane, 2193-glycidoxypropyltrimethoxysilane, 137, 2653-Hydroxy-1,1-dimethylbutylperoxyneodecanoate, 4153-Hydroxy-1-azabicyclo[2.2.2]octane, 633-hydroxy-1-azabicyclo[2.2.2]octane, 663-hydroxymethyl quinuclidine, 663-mercapto-1,2-propanediol, 673-methacryloxypropyl-trimethoxysilane, 248, 4723-Methyl-1,2,3,6-tetrahydrophthalic anhydride, 1183-methyl-1,2,3,6-tetrahydrophthalic anhydride, 1093-Methyl-1-dodecyn-3-ol, 2243-Methyl-3-hydroxymethyl quinuclidine, 663-nitroperoxybenzoic acid, 993-phenyl-1-propanol, 4003-Phenyl-3,4-dihydro-2H-1,3-benzoxazine, 2753-Phenyl-3-tert-butylperoxyphthalide, 413

Page 22: Reactive Polymers Fundamentals and Applications || Index

504 INDEX

3-quinuclidinol, 663-Sulfolene, 3223-trimethoxysilylpropylmethacrylate, 245, 4374,4-Bis(N,N-dimethyl-N-(2-ethoxycarbonyl-1-propenyl) ammonium hexafluoro antimonate)benzophenone, 1214,4-Dicyanatobiphenyl, 2524,4′-Bis(o-propenylphenoxy)benzophenone, 2834,4′-bis(sec-Butylamine)dicyclohexylmethane, 604,4′-bis(sec-Butylamine)diphenylmethane, 604,4′-Bis(diethylamino)benzophenone, 1254,4′-bis(dimethylamino)benzophenone, 1224,4′-bis(maleimido)diphenylmethane, 285, 2904,4′-Bismaleimidophenylphosphonate, 2704,4′-diaminodibenzyl, 544,4′-Diaminodiphenyl sulfone, 116, 1284,4′-diaminodiphenyl sulfone, 109, 3904,4′-Diaminodiphenylmethane, 96, 115, 1284,4′-diaminodiphenylmethane, 109, 111, 127, 2774,4′-dihydroxybiphenyl, 4584,4′-Diisocyanato dicyclo hexylmethane, 504,4′-diphenylmethane diisocyanate, 49, 504,4′-diphenylmethanedimaleimide, 2784,4′-Dithiodianiline, 1164,4′-hexafluoropropylidenebisphthalic dianhydride, 2314,4′-Methylene bis(2-chloroaniline), 604,4′-Methylene bis(3-chloro-2,6-diethylaniline), 60, 1164,4′-methylene bis(cyclohexyl isocyanate), 694,4′-methylenedianiline, 2824,4′-Nitrophenylazoaniline, 1374,4′-oxydianiline, 2774,5-Dimethyl-2-oxo-1,3,2-dioxathiolane, 3234-(3-iodopropyl)benzocyclobutene, 4464-(tert-Amylperoxy)-4-methyl-2-pentanol, 4134-allylphenol, 2654-Chloro-3,5-diamino-benzoic acid isobutylester, 604-dimethylaminobenzaldehyde, 4604-Dimethylaminobenzoic acid, 1254-dimethylaminophenethanol, 4604-dimethylaminopyridine, 1284-Hydroxy-2,2,6,6-tetramethyl-1-piperidinyloxy, 4194-Hydroxy-2,2,6,6-tetramethyl-piperidin-1-oxyl, 4274-hydroxyacetanilide, 1064-hydroxybutyl acrylate, 594-hydroxybutylvinyl ether, 2924-maleimidophenyl isocyanate, 2774-Methacryloxyethyl trimellitate, 4714-Methoxy-2,2,6,6-tetramethyl-1-piperidinyloxy, 4194-Methylcyclohexylmethyl methacrylate, 2354-methylcyclohexylmethyl methacrylate, 2354-methylolphenol, 1714-methylphenol, 165

Page 23: Reactive Polymers Fundamentals and Applications || Index

INDEX 505

4-nitroperoxybenzoic acid, 994-Oxo-2,2,6,6-tetramethyl-1-piperidinyloxy, 4194-Propoxy-2,2,6,6-tetramethyl-piperidin-1-oxyl, 4274-Trimethylsiloxybenzocyclobutene, 3314-vinyl-1-cyclohexene, 2214′,4′-diphenylmethane diamine, 564′-cyano-4-biphenyloxyvaleric acid, 457, 4585-Dimethylamino-3-methyl-1-pentanol, 635-Methylfurfural, 2035-norbornene-2,3-dicarboxylic anhydride, 2715-sulfonatoisophthalic acid, 56,6-(1-methylethyliden)-bis-(3,4-dihydro-3-phenyl-2H-1,3-benzoxazine), 2756,6′-dithiodinicotinic acid, 3216-Hydroxy-5-[(4-sulfophenyl)azo]-2-naphthalenesulfonic acid, 3227-allyloxy-2-naphthol, 2797-methyl-1,6-octadiene, 4469,10-dihydro-10[2,3-di(hydroxy carbonyl)propyl]-10-phosphaphenanthrene-10-oxide, 219,10-Dihydro-9-oxa-10-phosphaphenanthrene-10-oxide, 2889,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide, 219-Fluorenyl tetramethylene sulfonium hexafluoroantimonate, 1219-methylanthracene, 260cis,cis-muconic acid, 403cis,trans-muconic acid, 403cis-2-butene-1,4-diol, 1exo-3,6-Epoxy-1,2,3,6-tetrahydro phthalic anhydride, 95exo-3,6-Epoxy-1,2,3,6-tetrahydro phthalimidocaproic acid, 95m-Aminophenol, 156m-chloroperbenzoic acid, 133m-Cresol, 156m-cresol, 172m-Methoxyphenol, 156m-Phenylene diamine, 115m-phenylene diamine, 128, 280N,N,N ′,N ′,N ′′-pentamethyldiethylene triamine, 63N,N,N ′,N ′-Tetraethylethylene diamine, 323N,N,N ′,N ′-Tetramethyl-1,3-butane diamine, 323N,N,N ′,N ′-Tetramethylethylene diamine, 323N,N-4,4-dibenzylbismaleimide, 270, 279N,N-4,4-Diphenylmethanebismaleimide, 270N,N-4,4-diphenylmethanebismaleimide, 279N,N-bis(3-dimethylamino propyl)formamide, 66N,N-bis(3-dimethylamino-n-propyl)amine, 64N,N-Bis[3-(dimethylamino)propyl]formamide, 64N,N-diethyltoluidine, 321N,N-dimethyl-p-phenylene diamine, 3N,N-Dimethyl-p-toluidine, 321, 463N,N-Dimethyl-N′,N ′-di(2-hydroxypropyl)-1,3-propane diamine, 323N,N-dimethylacetamide, 280, 432N,N-Dimethylaniline, 25N,N-dimethylaniline, 124

Page 24: Reactive Polymers Fundamentals and Applications || Index

506 INDEX

N,N-dimethylbenzylamine, 63, 118N,N-dimethylcyclohexylamine, 63N,N-Dimethylethanolamine, 63N,N-dimethylethylamine, 63N,N-dimethylformamide, 381, 432N,N ′,N ′′-tris(5-hydroxy-3-oxapentyl)melamine, 193N,N ′-m-phenylenedimaleimide, 278N,N ′-m-Phenylenedimaleimide, 384N,N ′-o-phenyl enedimaleimide, 278N,N ′-p-phenylenedimaleimide, 278N,N ′-bis(2-hydroxypropylaniline), 60N,N ′-Bis(3-dimethylaminopropyl) urea, 65N,N ′-diphenylethane-1,2-diamine, 3N,N ′-diphenylhexane-1,6-diamine, 3N,N ′-hexamethylenebismaleimide, 278N-allyldiaminodiphenyl ether, 270N-(1-Methylethyl)-1-cyclohexyl-1-(diethylphosphono)nitroxide, 419N-(1-Phenyl-2-methylpropyl)-1-diethylphosphono-1-methylethyl nitroxide, 419N-(1-Phenylbenzyl)-((1-diethylphosphono)-1-methylethyl)nitroxide, 419N-(3-Dimethylaminopropyl)-2-ethylhexanoic acid amide, 63N-(4-hydroxyphenyl)maleimide, 272, 281N-(p-carboxyphenyl)maleimide, 129N-(p-hydroxy)phenyl maleimide, 264N-2-Aminoethyl-3-aminopropyl-tris(2-ethylhexoxy)silane, 323N-tert-Butyl-1-(2-naphthyl)-2-methylpropyl nitroxide, 419N-tert-Butyl-1-dibenzylphosphono-2,2-dimethylpropyl nitroxide, 419N-tert-Butyl-1-diethylphosphono-2,2-dimethylpropyl nitroxide, 419N-tert-Butyl-1-phenyl-2-methylpropyl nitroxide, 419N-tert-Butyl[(1-diethylphosphono)-2-methyl-propyl]nitroxide, 419N-aminoethyl piperazine, 115N-Benzylpyrazinium hexafluoroantimonate, 120N-Benzylquinoxalinium hexafluoroantimonate, 120n-Butyl acrylate, 235n-butyl acrylate, 17, 59, 233, 235, 245, 377, 445, 477n-Butyl cyanoacrylate, 318n-butyl cyanoacrylate, 319n-Butyl methacrylate, 235, 441n-butyl methacrylate, 245, 442n-butyl vinyl ether, 124n-Butyl-4,4-di(tert-butylperoxy)valerate, 415N-ethyldiisopropanolamine, 465N-Ethylmorpholine, 63N-ethylmorpholine, 63n-hexanol, 6n-hexyl isocyanate, 54N-methyl-2-pyrrolidone, 280, 287N-methyldiethanolamine, 465N-Methylmorpholine, 63N-methylmorpholine, 63, 321n-Octylamine, 323

Page 25: Reactive Polymers Fundamentals and Applications || Index

INDEX 507

N-phenyl maleimide, 119, 281, 292N-Phenyl-1-diethylphosphono-1-methylethyl nitroxide, 419N-Phenyl-1-diethylphosphono-2,2-dimethylpropyl nitroxide, 419N-phenyldiethanolamine, 478N-propyldiethanolamine, 465N-vinyl carbazole, 124N-vinyl pyrrolidone, 444N-vinylformamide, 180O,O-tert-Amyl-O-(2-ethylhexyl)monoperoxy carbonate, 415O,O-tert-Butyl-O-(2-ethylhexyl)monoperoxy carbonate, 415O,O-tert-Butyl-O-isopropyl monoperoxy carbonate, 415o,o-di-1-phenylethyl phenylphosphonate, 121o,o-di-tert-Butyl phenylphosphonate, 120o,o-Di-tert-butyl-1-piperidinylphosphonamidate, 120o,o-di-tert-butyl-1-piperidinylphosphonamidate, 121o,o-Dicyclohexyl phenylphosphonate, 120o,o′-dimethallyl bisphenol A, 285o-tert-Butyl-di-1-piperidinylphosphonamidate, 120o-tert-butyl-di-1-piperidinylphosphonamidate, 121o-aminobenzoic acid, 7o-aminophenol, 395o-Cresol, 156o-cresol, 112, 176, 261o-nitrotoluene, 51o-phenylphenol, 112p-Methoxyphenylacrylate, 388p-nonylphenol, 282p-tert-Butylphenyl salicylate, 238p-acetoxystyrene, 119p-Aminophenol, 96p-Benzoquinone, 322, 432p-benzoquinone, 112, 247, 462p-Chlorobenzoyl peroxide, 413p-Cresol, 156p-cresol, 172p-hydroxystyrene, 101p-maleimidobenzoic anhydride, 289p-Methoxyphenol, 322p-nitrotoluene, 51p-Octylphenyl salicylate, 238p-styrenesulfonic acid, 402, 448p-Toluenesulfonic acid, 205p-toluenesulfonic acid, 8, 53, 155, 205, 218, 270p-Vinyl toluene, 4tert-Amyl hydroperoxide, 413tert-Amylperoxy-2-ethylhexanoate, 415tert-Amylperoxybenzoate, 23tert-Amylperoxyneodecanoate, 415tert-Amylperoxypivalate, 415tert-butyl acrylamide, 445

Page 26: Reactive Polymers Fundamentals and Applications || Index

508 INDEX

tert-butyl acrylate, 402tert-butyl alcohol, 121tert-Butyl catechol, 322tert-butyl catechol, 26tert-Butyl hydroperoxide, 413, 416tert-butyl hydroperoxide, 23, 242, 478tert-Butyl hydroquinone, 322tert-butyl methacrylate, 402tert-Butylcumyl peroxide, 23tert-Butylperoxy-2-ethylhexanoate, 23, 415tert-Butylperoxy-3,5,5-trimethylhexanoate, 415tert-Butylperoxyacetate, 415tert-Butylperoxybenzoate, 23, 25, 415, 416tert-butylperoxybenzoate, 18, 240, 242tert-Butylperoxyisobutyrate, 415tert-Butylperoxyisononanoate, 415tert-Butylperoxymaleate, 415tert-Butylperoxyneodecanoate, 415tert-Butylperoxypivalate, 415tert-butylperoxypivalate, 444tert-hexyl hydroperoxide, 462tert-Hexylperoxybenzoate, 23Abietic acid, 279, 303Acetaldehyde, 156Acetic anhydride, 204, 277Acetic anhydride, 443Acetoacetoxy methyl methacrylate, 428Acetone cyanhydrin, 237Acetone, 156Acetonitrile, 99Acetyl acetone peroxide, 23Acetyl acetone, 179Acetyl chloride, 53Acetyl peroxide, 413Acetyltributyl citrate, 246Acrolein, 235–236Acrylamide, 183, 249, 364, 448Acrylic acid, 5, 59, 77, 101, 183, 235, 237, 387, 396, 447–448Acrylonitrile, 56, 65, 447Acryloyl glutamic acid, 455Acryloyl-β-alanine, 455Adipic Acid, 23, 29, 57–58, 355Allo-ocimene, 303Allyl acetoacetate, 468Allyl alcohol propoxylate, 23Allyl alcohol, 6Allyl bromide, 22Allyl chloride, 95, 100Allyl cyanoacrylate, 318Allyl glycidyl ether, 128, 129, 133, 402

Page 27: Reactive Polymers Fundamentals and Applications || Index

INDEX 509

Allyl glycidyl ether, 95Allyl-4-[(4-N,N-diallyl)aminophenylazo]-α-cyanocinnamate, 296Allyl-4-[(4-N-allyl-N-ethyl)aminophenylazo]-α-cyanocinnamate, 296Allylamine, 247, 295Allylsuccinic anhydride, 462Aluminium(III)acetylacetonate, 256Aluminum bromide, 205Aluminum isopropoxide, 361Aluminum isopropyloxide, 119Aluminum nitride, 286Aluminum tri-sec-butylate, 468Aluminum trichloride, 205Aminopropyltriethoxysilane, 14Aminopropyltriethoxysilane, 230Ammonium persulfate, 364Ammonium polyphosphate, 20–21, 70Ammonium sulfate, 205Amoxicillin, 81Ampicillin, 81Amylopectin, 443Amylose starch, 442Anatase, 246Aniline, 51Anthracene, 122Anthraquinone dicyanate, 252Antimony trioxide, 15, 20, 22, 238, 254Ascorbic acid, 77, 224, 460–461Aspartic acid, 355Atropine, 233Azelaic acid, 355Barbituric acid, 460–461Barium metaborate, 238Barium sulfate, 11Barium titanate, 14Benzenesulfonic acid, 218Benzil, 463Benzocyclobutene, 331Benzoguanamine, 193, 199Benzoic acid 2,2,6,6-tetramethyl-piperidin-1-oxyl-4-yl ester, 427Benzoic acid, 34Benzoin isobutyl ether, 463Benzoin methyl ether, 24, 463Benzoin phenyl ether, 463Benzophenone, 240, 435, 463Benzoxazole, 395Benzoyl chloride, 53Benzyl methacrylate, 102Benzyl tetrahydrothiophenium hexafluoroantimonate, 120Benzyldimethylamine, 102Benzyltrimethylammonium chloride, 133, 272

Page 28: Reactive Polymers Fundamentals and Applications || Index

510 INDEX

Betulin, 303Bicumene, 433Bicyclo[4.2.0]octa-1,3,5-triene, 331Bis(m-aminophenyl)methylphosphine oxide, 112Bis(1-methyl-imidazole)zinc(II)diacetyl-acetonate, 256Bis(1-methyl-imidazole)zinc(II)dicyanate, 256Bis(1-methyl-imidazole)zinc(II)dioctoate, 256Bis(1-oxyl-2,2,6,6-tetramethylpiperidine4-yl)sebacate, 419Bis(2,4,6-trimethylbenzoyl)phenylphosphine oxide, 34Bis(2,6-dichlorobenzoyl)-(4-propylphenyl)phosphine oxide, 24Bis(2,6-dimethoxybenzoyl)-2,4,4-trimethylpentylphosphine oxide, 23–24Bis(2,6-dimethoxybenzoyl)-2,4,4-trimethylpentylphosphine, 24Bis(2-dimethylaminoethyl)ether, 63–64Bis(2-hydroxy-3,5-dimethylbenzyl)ether, 166Bis(2-hydroxy-3,5-dimethyl-benzyl)methylene, 166Bis(2-hydroxyethyl)terephthalate, 30Bis(2-methacryloyloxyethyl)hydrogen phosphate, 462Bis(3-(N,N-dimethylamino)propyl)amine, 63Bis(3,4-epoxy-6-methylcyclo hexylmethyl)adipate, 95Bis(3,5,5-trimethylhexanoyl)peroxide, 240Bis(3,5-dimethyl-4-cyanatophenyl)methane, 252Bis(3-aminophenyl)phenylphosphine oxide, 273Bis(3-diethylphosphono-4-hydroxyphenyl)sulfide, 112Bis(3-glycidyloxy)phenylphosphine oxide, 112Bis(3-maleimidophenyl)phenylphosphine oxide, 273Bis(3-mercaptophenyl)sulfone, 135Bis(4-(1,2,4-triazoline-3,5-dione-4-yl)phenyl)methane, 278Bis(4-tert-butyl-1-isopropyl-2-imidazolyl)disulfide, 321Bis(4-tert-Butylcyclohexyl)peroxydicarbonate, 23, 240Bis(4-aminophenoxy)phenylphosphine oxide, 112Bis(4-aminophenyl)phenylphosphine oxide, 79, 114Bis(4-cyanato-3,5-dimethylphenyl)anisylmethane, 252Bis(4-cyanato-3,5-dimethylphenyl)naphthylmethane, 252Bis(4-cyanatocumyl)benzene cyanate, 251Bis(4-cyanatophenyl)ether, 252Bis(4-cyanatophenyl)methane, 252Bis(4-cyanatophenyl)thioether, 252Bis(4-hydroxy-3,5-dimethylphenyl)anisylmethane, 252Bis(4-hydroxy-3,5-dimethylphenyl)naphthylmethane, 252Bis(4-hydroxyphenyl)methane, 156Bis(4-maleimidephenyl) succinate, 275Bis(4-maleimidophenyl)ether, 269–270Bis(4-maleimidophenyl)sulfone, 269–270Bis(4-nitrophenyl)phenylphosphine oxide, 79Bis(benzocyclobutenyl)-m-divinylbenzene, 335Bis(benzocyclobutenyl)divinyltetramethylsiloxane, 336Bis(dimethyl silyl)benzene, 225Bis(hydroxyethyl)-p-toluidine, 461Bis(hydroxymethyl)furan, 203Bis(methyl salicyl)carbonate, 351

Page 29: Reactive Polymers Fundamentals and Applications || Index

INDEX 511

Bis[N-(3-imidazolidinylpropyl)]oxamide, 64Bis[N-(3-morpholinopropyl)]oxamide, 64Bis[2-(methacryloyloxy)ethyl]phosphate, 458Bis[3-(2,3-epoxypropyl thio)phenyl]sulfone, 95Bis-p-aminocyclohexylmethane, 115Bis-1,3-methyl-1,2,3,4,5-pentamethylcyclopenta-2,4-diene benzene, 292Bisaminomethylcyclohexane, 115Biseugenyl succinate, 275Bishydantoin, 96Bismaleimide(3,3′-bis(maleimidophenyl))phenylphosphine oxide, 112Bismaleimide, 263Bismuth neodecanoate, 67Bisphenol A bismaleimide, 270Bisphenol A dicyanate, 256, 263–264Bisphenol A diglycidyl ether dimethacrylate, 453Bisphenol A diglycidyl ether, 95Bisphenol A, 97Bisphenol A, 23, 96, 99, 100, 118, 155–156, 158, 351Bisphenol B, 155–156Bisphenol F, 96–97, 156, 165Boric acid, 63, 165, 217, 286Boric anhydride, 205Boron fluoride, 205Boron trifluoride, 119, 209, 306, 322Butadiene diepoxide, 95Butyl stearate, 319Butylene oxide, 56Butyraldehyde, 156Calcium hydroxy apatite, 467Calcium stearate, 18, 412Calixarene, 121Camphene, 303Camphorquinone, 457, 463Caprinoguanamine, 199Carboxymethyl chitin, 79Carboxymethyl konjac glucomannan, 79Cardanol, 131, 156Cardene, 331Cardol, 156Carene, 303, 306Carophyllene, 303Casein, 79Cassava starch, 382Catechol, 322Cefaclor, 81Cefotaxime, 81Celluloid, 453Cellulose, 382Ceric ammonium nitrate, 364Cetyl pyridinium chloride, 476

Page 30: Reactive Polymers Fundamentals and Applications || Index

512 INDEX

Chitin, 364Chitosan, 75, 212, 364, 382Chloro acetic acid, 318Chlorobenzene, 218Chlorodibutyltin hydride, 67Chloroethyl diazoacetate, 437Chloroplatinic acid, 223Chlorosulfonic acid, 295Choline octoate, 224Chrysanthemol, 303Cinnamic acid, 136Citric acid, 34, 205Cobalt 2-ethylhexanoate, 240Cobalt acetylacetonate, 24Cobalt octoate, 18, 24Cobalt(II)acetylacetonate, 256Copper phthalocyanine, 476Corn starch, 159, 232, 443Creatinine, 440Creosote, 233Cumene hydroperoxide, 23, 156, 413, 462Cupric oxide, 262Cuprous oxide, 262Cyanoethylmethylaniline, 463Cyanogen bromide, 251Cyanuric chloride, 285Cyclobutabenzene, 331Cyclobutarene, 331Cyclohexanone peroxide, 242Cyclohexene oxide, 122Cyclohexene, 99Cyclohexenoic acid, 129Cyclohexyl methacrylate, 235Cyclopentylamine, 182Decabromodiphenyloxide, 20, 21Decalin, 438Decanedioic acid bis(2,2,6,6-tetramethyl-piperidin-1-oxyl-4-yl), 427Decanoyl peroxide, 413Di(2-tert-butylperoxyisopropyl)benzene, 416Di(2-ethylhexyl)peroxydicarbonate, 415Di-tert-amyl peroxide, 413Di-tert-butyl fumarate, 402Di-tert-butyl peroxide, 25, 413–414Di-2-ethylhexyl phosphate, 471Di-2-ethylhexyl phosphite, 471Di-2-methacryloxyethyl-2,2,4-trimethylhexamethylene dicarbamate, 455Diabietylketone, 278Diallyl phthalate, 4, 263Diaminotricyclododecane, 115Dibenzodiazyl disulfide, 321

Page 31: Reactive Polymers Fundamentals and Applications || Index

INDEX 513

Dibenzoyl peroxide, 23, 25, 240, 325, 400, 413, 416, 460Dibromoneopentylglycol, 22Dibromostyrene, 22Dibutoxybis(acetylacetonato)titanium(IV), 287Dibutyl phosphite, 471Dibutyl phthalate, 319Dibutyltin bis(2,3-dihydroxypropylmercaptide), 67Dibutyltin bis(4-hydroxyphenylacetate), 67Dibutyltin diacetate, 67, 222Dibutyltin dilaurate, 54, 66–67, 258, 280, 400, 475Dibutyltin dilauryl mercaptide, 66Dibutyltin dimercaptide, 67Dibutyltin oxide, 120, 400, 478Dichloroacetic acid, 25Dichlorobenzaldehyde, 133Dichlorobis(triphenylphosphine)platinum(II), 223Dichlorodimethylsilane, 232, 281Dichloroethane, 98Dichloromethane, 256, 295Dicumyl hydroperoxide, 416Dicumyl peroxide, 23, 242, 379, 416–417, 425, 432Dicumyl, 434Dicyandiamide, 116, 193, 272Dicyclohexylmethane-4,4′-diisocyanate, 50–51Dicyclohexylperoxydicarbonate, 415Dicyclopentadiene, 3, 23, 306Didodecyl fumarate, 34Diethanolamine hydrochloride, 55Diethanolamine, 131Diethyl maleate, 380, 432Diethyl malonate, 53Diethyl sebacate, 319Diethyl-2,2-dicyanoglutarate, 317Diethylaminoethyl acrylate, 433Diethylaminoethyl methacrylate, 433, 465Diethylaminopropylamine, 115–116Diethylene glycol diacrylate, 442Diethylene glycol, 5, 8, 29, 35, 57, 58, 60, 65, 129, 478Diethylenetriamine, 115–116Diethylenetriamine, 56Diethylketone, 414Diethylsuccinate, 375, 387Diethyltoluene diamine, 60Diglycidyl tetrahydrophthalate, 367Dihydrophthalimide, 278Dihydroxyethyl-p-toluidine, 460Diisobutyl aluminum hydride, 361Diisopropylbenzene mono hydroperoxide, 413Dimethoxy ethanal, 180Dimethoxydiethoxysilane, 218

Page 32: Reactive Polymers Fundamentals and Applications || Index

514 INDEX

Dimethyl ammonium methyl sulfate, 476Dimethyl itaconate, 436Dimethyl sebacate, 319Dimethyl terephthalate, 23, 478Dimethyl-2,4-di-(2-pvridyl)-3-methyl-7-(pyridine-2-ylmethyl) 3,7-diaza-bicvclo[3.3.1]nonan-9-one-

1,5-dicarboxylate, 25Dimethylamine, 104, 286Dimethyldichlorosilane, 220Dimethyldiethoxysilane, 218Dimethyldimethoxysilane, 218, 222Dimethylmelamine, 193Dimethylol butanoic acid, 60Dimethylol propionic acid, 78Dinonylphenol cyanate, 251Dioctyl adipate, 319Dioctyl glutarate, 319Dioctyl phthalate, 319Dipentaerythritol pentaacrylate monophosphate, 471Dipentaerythritol pentamethacrylate monophosphate, 471Diphenyl iodonium hexafluoroantimonate, 124Diphenylchlorosilane, 220Diphenyldimethoxysilane, 218Diphenyliodoniumhexafluorantimonate, 460Diphenylmelamine, 193Diphenylphosphine, 224Dipropylene glycol, 29Dodecanedioic acid, 355Dodecanoyl peroxide, 413, 416Dodecenyl succinic anhydride, 118–119Dodecyl acrylate, 427Dodecyl aldehyde, 324Dodecyl diacid, 352Dodecyl mercaptane, 444Dodecylphenol, 256E-12,13-epoxyoctadeca-E-9-enoic acid ester, 95Eosine, 463Epichlorohydrin, 95–96, 99–100, 114Epoxy allyl soyate, 95Epoxy methyl soyate, 95Epoxychlorotriazine, 399Ethanolamine, 182, 397Ethenylphenyloxirane, 95Ethyl α-(bromomethyl)acrylate, 122Ethyl N-methacryloylcarbamate, 236Ethyl acrylate, 235–236Ethyl acrylate, 59, 139–140, 183Ethyl cyanoacetate, 317Ethyl cyanoacrylate, 317–318, 328Ethyl diazoacetate, 437Ethyl formate, 169

Page 33: Reactive Polymers Fundamentals and Applications || Index

INDEX 515

Ethyl hydroxymethyl oxazoline, 395Ethyl methacrylate, 235Ethyl methacrylate, 246Ethyl-(4,4′-bismaleimidophenyl)phosphonate, 274, 288Ethyl-3,3-di(tert-amylperoxy)butyrate, 415Ethyl-3,3-di(tert-butylperoxy)butyrate, 415Ethyl-4-dimethylamino benzoate, 125, 457, 460–461Ethylal, 180Ethylaluminum dichloride, 305Ethylamine, 182, 209Ethylene Carbonate, 55Ethylene diamine, 56–57, 60, 307Ethylene glycol antimonite, 22Ethylene glycol dimethacrylate, 235, 457Ethylene glycol, 1, 5, 35, 57–58, 60, 74, 243, 249, 277, 333, 354Ethylene oxide, 3, 56–57, 114, 237, 399Ethylene propylene diene monomer, 422Ethylene/propylene rubber, 422Ethylmelamine, 193Ethylmethylphosphinic anhydride, 254Ethyltriethoxysilane, 218Ethyltrimethoxysilane, 218Ethynyl cyclohexanol, 224Farnesene, 308Ferric acetylacetonate, 67, 118Ferrous ammonium sulfate, 364Fluorohectorite, 109Formaldehyde, 156–157, 159, 204, 270, 281, 317Formic acid, 61, 199Fumaric acid, 1, 478Furan, 203, 277Furfural, 203–204Furfuryl alcohol, 203–204, 277Glutamic acid, 99Glutaric acid, 29, 58Glutaric anhydride, 118, 133, 433Glycerol diglycidyl ether, 95Glycerol dimethacrylate, 475Glycerol, 1, 56–58, 60, 243, 279, 362, 365, 396, 442Glycerophosphate dimethacrylate, 471Glycerophosphoric acid, 471Glyceryl dimethacrylate phosphate, 471Glyceryl triacetate, 319Glyceryl tributyrate, 319Glyceryl-2-phosphate, 471Glycidyl acrylate, 6, 249Glycidyl dimethacrylate, 242Glycidyl methacrylate, 6, 95, 139, 375–376, 389, 428Glycidyl phenyl ether, 121Glycol trilinoleate, 442

Page 34: Reactive Polymers Fundamentals and Applications || Index

516 INDEX

Glyoxal, 156, 180Graphene oxide, 379Guttapercha, 303Hectorite, 10Heptamethyltrisiloxane, 221Heptanoic anhydride, 443HET acid, 2, 20, 22HET anhydride, 118HET-anhydride, 1Hexa(allylamino)cyclotriphosphonitrile, 384Hexa(methoxymethyl)melamine, 169Hexabromocyclododecane, 434Hexafluoroisobutene, 99Hexafluoropropene, 246Hexahydro-4-methylphthalic anhydride, 118Hexahydrophthalic acid, 96Hexahydrophthalic anhydride, 108, 118Hexakis(methoxymethyl)melamine, 109Hexakis(methylol)melamine, 169Hexamethoxymethyl melamine, 199Hexamethyldisilazane, 227Hexamethyldisiloxane, 222Hexamethylene diamine, 115–116, 182Hexamethylene diisocyanate, 50, 77, 277Hexamethylenediisocyanate, 456Hexamethylenetetramine, 64, 168–169Hexamethylol melamine, 194Hexamethylphosphoramide, 432Hexane-1,6-diamine, 49Hexane-1,6-diisocyanate, 49Hexanediol diglycidyl ether, 100Hexanitrohexaazaisowurtzitane, 76Hydrazine monohydrate, 79Hydrazine, 57–60Hydro, 2–3Hydroquinone monomethyl ether, 463–466Hydroquinone, 2, 322, 334Hydroquinone, 9, 13, 390Hydroxy-2-methyl-1-phenyl-propanone, 125Hydroxybenzoic acid, 334Hydroxyethyl methacrylate monophosphate, 471Hydroxyethyl methacrylate, 455Hydroxynaphthoic acid, 334Isobutenylsuccinic anhydride, 462Isobutyl cyanoacrylate, 318Isobutyl vinyl ether, 124Isophorone diamine, 60, 115Isophorone diisocyanate, 52Isophorone diisocyanate, 50Isophorone diisocyanate, 69, 75, 78–79, 81

Page 35: Reactive Polymers Fundamentals and Applications || Index

INDEX 517

Isophorone, 75Isophthalic acid, 1–2, 23, 29, 35, 58, 103Isophthaloyl bis-4-benzocyclobutene, 331–332Isophthaloyl dichloride, 352Isopropoxybenzoin, 463Isopropyl alcohol, 112, 249Isopropyl chloride, 218Isopropyl myristate, 319Isosebacic acid, 29Itaconic acid, 17, 21, 430Itaconic anhydride, 344, 462Lauric acid, 319Laurolactam, 402Lauroyl peroxide, 240, 242, 413Lauryllactam, 350Lead naphthenate, 67Lead octoate, 67Limonene, 96, 303Linear low density poly(ethylene), 380Linoleic acid, 442Lithium stearate, 351Longifolene, 303Low density poly(ethylene), 380Lupeol, 303Lysine-diisocyanate, 50, 77Magnesium hydroxide, 378Magnesium oxide, 398Maleated poly(propylene), 379Maleic anhydride, 1, 8, 23, 379, 425, 428, 441Manganese octoate, 24Manganese(III)acetylacetonate, 323Melam, 193Melamine cyanurate, 20, 70Melamine phosphate, 112, 367Melamine, 193Melem, 193Melon, 193Menthane diamine, 115–116Mercaptopropyltrimethoxysilane, 232Methacrylamide, 249Methacrylate-terminated phosphoric acid ester, 471Methacrylic acid, 5Methacrylic anhydride, 55Methacryloxyethyl phosphate, 471Methacryloyl chloride, 55, 57Methacryloyl glutamic acid, 455Methacryloyl isocyanate, 235–236Methacryloyl-β-alanine, 458Methacryloyloxyethane-1,1-diphosphonic acid, 471Methoxyethylmorpholine, 64

Page 36: Reactive Polymers Fundamentals and Applications || Index

518 INDEX

Methoxypropyl cyanoacrylate, 328Methyl N-methacryloylcarbamate, 235–236Methyl acrylate, 4, 235–236, 246, 441, 443Methyl cyanoacrylate, 318Methyl methacrylate, 4, 18, 235–237, 242, 245, 339, 438, 461Methyl nadic anhydride, 118–119Methyl salicylate, 351–352Methyl-p-maleimidobenzoate, 289Methylal, 180Methylamine, 182Methylbutynol, 224Methyl-di(phenylethynyl)silane, 281Methyldichlorosilane, 220Methyldiethanolamine, 240Methylene bis(4-phenyl isocyanate), 157Methylethylketone peroxide, 18Methylethylketone peroxide, 23, 416Methylethylketone, 414Methylethylketoxime, 53Methylisobutylketone peroxide, 414, 416Methylisobutylketone, 414Methylmelamine, 193Methylphenylchlorosilane, 220–221Methylphenyldiethoxysilane, 218Methylphenyldimethoxysilane, 218Methylpropylketone peroxide, 25Methyltricaprylylammonium chloride, 99Methyltrichlorosilane, 220Methyltriethoxysilane, 218, 227Methyltrimethoxysilane, 218, 222Methyltris(methylethylketoxime)silane, 222Methylvinyldimethoxysilane, 218Mica, 11, 68Monomethyl itaconate, 436Montmorillonite, 11Myrcene, 303, 314N′,N′-dimethylpiperazine, 63Nadic anhydride, 271–272, 441Naphthoquinonediazidesulfonic acid, 172Natural rubber, 308, 311, 400Neopentyl glycol, 1–2, 29, 58, 157, 242Neopentyl(diallyl)oxy tri(dioctyl)pyrophosphatotitanate, 15Nitrokonjac glucomannan, 75Nonafluorohexene, 233Nonylphenol, 256Norbornane diketimine, 116Novolak resins, 131Octamethylcyclotetraoxysilane, 378Octyl mercaptane, 444Octyl methacrylate, 385

Page 37: Reactive Polymers Fundamentals and Applications || Index

INDEX 519

Oxalic acid, 155Palmitic anhydride, 443Paraformaldehyde, 156–157, 165, 168, 317Pentabromobenzyl acrylate, 79, 335Pentaerythritol triacrylate monophosphate, 471Pentaerythritol triacrylate, 352Pentaerythritol trimethacrylate monophosphate, 458, 471–472Pentaerythritol, 56, 58, 157, 185, 367, 431Pentaerythrol triacrylate, 243Perfluoro (alkyl vinyl ether), 315Peroxyacetic acid, 99Perylene(peri-dinaphthalene), 259Phellandrene, 303Phenol, 156, 165, 189, 203, 233, 306, 444Phenolphthalein poly(ether ether ketone), 103Phenolphthalein, 279Phenyl N-methacryloylcarbamate, 235–236Phenyl glycidyl ether, 95, 126Phenyl propanedione, 463Phenyl-(4,4′-bismaleimidophenyl)phosphonate, 274, 288Phenylmelamine, 193Phenylphosphonic acid, 120Phenylsilane, 223Phenyltrimethoxysilane, 19, 218Phlogopite, 185Phosgene, 49Phosphorus oxychloride, 121Phthalic anhydride, 1–2, 8, 23, 29, 35, 58, 65, 103, 118–119, 391, 433Phthaloyl chloride, 264Pimaric acid, 303Pimelic acid, 29Pinane hydroperoxide, 413Piperidine, 121Poly(β-hydroxybutyrate-co-β-hydroxyvalerate), 354Poly(ε-caprolactam), 387Poly(ε-caprolactone), 321, 354, 361–362, 367Poly(p-hydroxybenzoate), 390Poly(p-phenylene benzobisthiazole), 334Poly(p-phenylene vinylene), 81Poly(2,2-di(4-phenylene)propane phthalate), 264Poly(2,2-di(4-phenylene)propane phthalate-co-2,2-di(4-phenylene)propane isophthalate), 264Poly(2,6-dichloro-1,4-phenylene oxide), 390, 398Poly(3-hydroxybutyric acid), 321Poly(benzo[1,2-d4,5-d′]bisthiazole-2,6-diyl)-1,4-phenylene, 331Poly(butylene terephthalate), 140, 367, 379Poly(epichlorohydrin), 70Poly(ether ether ketone), 103Poly(ethylene 2,6-naphthalate), 390Poly(ethylene glycol)dimethacrylate, 235, 243, 457Poly(ethylene glycol)methacrylate, 354

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520 INDEX

Poly(ethylene oxide), 102Poly(ethylene terephthalate), 231Poly(ethylene-octene) copolymer, 387Poly(glycolic acid), 321, 328Poly(hydroxy fullerene), 97Poly(lactic acid), 321, 328Poly(oxypropylene)diamine, 132Poly(phenylene sulfide), 396Poly(phthaloyl diphenyl ether), 285Poly(phthaloyl diphenyl ether-co-isophthaloyl diphenyl ether), 285Poly(propylene oxide)diamine, 116Poly(styrene), 102Poly(styrene-b-(ethylene-co-butylene)), 380Poly(styrene-co-acrylonitrile), 102Poly(tetrafluoroethylene), 448Poly(tetramethylene ether), 349Poly(thiophene), 447Poly(urethane) dimethacrylate, 456Poly(vinyl acetate), 17Poly(vinyl chloride), 63Poly(vinyl chloride-co-vinyl acetate), 17Poly(vinyl chloride-co-vinyl acetate-co-maleic anhydride), 17Poly(vinylidene difluoride-co-hexafluoropropylene), 296Polydioxanone, 328Polyoxypropylene glycol, 263–264Polysulfone, 264Polytetramethylene glycol, 77Potassium hydroxide, 9Pristine, 12Propanephosphonic anhydride, 254Propionaldehyde, 156Propionamide, 169Propylamine, 182Propylene glycol, 1, 35, 58, 60, 243, 246Propylene oxide, 3, 56, 57, 382, 402Pyrogallol, 322Pyromellitic dianhydride, 23, 110, 118–119, 365Pyrophosphoric acid, 328Quinacridone, 476Rectorite, 68Resorcinol dicyanate, 252Resorcinol, 155–156Retinol, 303Rice starch, 435Ricinoloxazoline maleate, 438Rosin, 304Rutile, 246Sago starch, 381Salicylaldehyde, 99Salicylic acid, 64

Page 39: Reactive Polymers Fundamentals and Applications || Index

INDEX 521

Sebacic acid, 30, 355Silicon oxycarbide, 226Sisal, 15, 388Sodium ascorbate, 224Sodium dodecyl sulfate, 446–477Sodium hypochlorite, 99Sodium stearate, 399Sodium sulfoisophthalate, 478Sodium trimetaphosphate, 360Sorbitol monoethoxylate, 362Sorbitol, 362Soy flour, 79Squalene, 303Stannous octoate, 67, 367Starch, 79Strychnine, 233Styrene butadiene rubber, 314Styrene oxide, 95Styrene, 4, 428Styrene-ethylene/butylene-styrene triblock copolymer, 379Succinic acid, 58Sucrose, 56, 133Sulfanilamide, 98, 116Sulfonic acid, 77, 218, 322, 446Sulfur dioxide, 317, 322Tapioca starch, 382Tartaric acid, 78, 205Terephthalic acid, 1–2, 5, 23, 29, 35, 334, 390Terephthaloyl dichloride, 334, 352Terephthaloylbis(4-oxybenzoic) acid, 95Terpinene, 303Terpinolene, 303, 307Tetra-n-butyl ammonium fluoride, 323Tetra-n-butylammonium chloroacetate, 65Tetra-n-butylammonium cyanoborohydride, 324Tetrabromobisphenol A, 20, 96, 112, 238Tetrabromophthalic anhydride, 20, 22Tetrabutylphosphonium acetate, 351Tetrabutyltitanate, 287, 351Tetrachloromethane, 432Tetrachlorophthalic anhydride, 17Tetraethoxysilane, 69, 112, 218, 233, 470Tetraethyl thiuram disulfide, 347Tetraethylene glycol dimethacrylate, 457Tetrafluoroethylene, 315Tetraglycidyl-4,4′-diaminodiphenylmethane, 97, 366Tetrahydrofuran, 56, 204, 246, 280, 342, 460Tetrahydrofurfuryl methacrylate, 455Tetrahydrophthalic anhydride, 118–119Tetrahydrophthalimide, 204

Page 40: Reactive Polymers Fundamentals and Applications || Index

522 INDEX

Tetrakis(4-hydroxyphenyl)ethane, 96–97Tetramethoxysilane, 19, 218, 223Tetramethylammonium pivalate, 66Tetramethyldivinyldisiloxane, 222Tetrapropoxysilane, 218Thermoplastic starch, 396Thiourea, 193Thioxanthone, 122Thiuram disulfide, 424Tin oxide, 238Tin-di-n-butyl-di-3,5-amino benzoate, 67Titanium n-butoxide, 129Titanocene, 463Toluene diamine, 56Toluene diisocyanate, 50, 81, 242, 277Tosyl isocyanate, 67Tri(p-chloro phenyl)phosphine, 162Tri(p-cresyl)phosphate, 319Tri(2-ethylhexyl)phosphate, 319Tri(acryloyloxyethyl) phosphate, 238Tri-n-butylborane, 460Triallyl cyanurate, 4, 5Triallyl isocyanurate, 138, 384Triarylsulfonium hexafluoroantimonate, 136Tributylamine, 465Tributylborane, 463Tributylphosphine, 323Tricresyl phosphate, 238Triethanolamine, 56, 65, 135, 180, 187, 461, 465Triethoxyvinylsilane, 14Triethyl citrate, 246Triethyl phosphate, 70, 319Triethyl phosphite, 432Triethylamine, 63, 79, 162, 169–170, 350, 381Triethylborane, 461Triethylene diamine, 63Triethylene glycol diacrylate, 249Triethylene glycol dimethacrylate, 455Triethylene glycol divinyl ether, 5Triethylene glycol methylvinyl ether, 122Triethylenetetramine, 115, 258Triflic acid, 120, 217Trifluoromethanesulfonic acid, 120Triglycidyl isocyanurate, 95Triglycidyloxy phenyl silane, 95, 112Triisopropanolamine, 465Trimellitic anhydride, 5Trimercaptothioethylamine, 116, 135Trimethoxysilane, 265Trimethylamine, 172

Page 41: Reactive Polymers Fundamentals and Applications || Index

INDEX 523

Trimethylborate, 205Trimethylchlorosilane, 220Trimethylene glycol-di-p-aminobenzoate, 60Trimethylmelamine, 193Trimethylol propane diallyl ether, 5Trimethylol propane ethoxylate triacrylate, 247Trimethylol propane triacrylate, 235, 236, 349, 438, 438, 442Trimethylol propane triacrylate, 18, 242, 247, 317Trimethylol propane, 1Trimethylol propane, 1, 56–57, 157Trimethylolpropyl trimethacrylate, 457Trioctyl trimellitate, 319Trioxane, 156Triphenyl phosphite, 399Triphenylphosphine oxide, 292Triphenylphosphine, 162Tripropylamine, 465Tripropylene glycol diacrylate, 242, 442Tris(p-toluenesulfonato)iron(III), 478Tris(2-allylphenoxy)-s-triazine, 296Tris(2-allylphenoxy)triphenoxy cyclotriphosphazene, 296Tris(2-aminoethyl)amine, 324Tris(2-chloroethyl)phosphate, 238Tris(2-hydroxyphenyl)phosphine oxide, 112Tris(pentafluorophenyl)borane, 223Trismercaptopropionate, 291Trypsin, 448Urea, 181Urethane dimethacrylate, 465Uretonimine, 52Vanadium acetylacetonate, 24Vanillin, 204Vermiculite, 175, 185Vernonia oil, 95Vinyl acetate, 67, 183, 438Vinyl-4-tert-butylbenzoate, 442Vinylbenzyldodecyldimethyl ammonium chloride, 11Vinylbenzyloctadecyldimethyl ammonium chloride, 12Vinylcyclohexene epoxide, 95Vinylidene fluoride, 246Vinyloxazoline, 403Vinylpyridine, 4Vinylpyrrolidone, 34Vinyltriethoxysilane, 437Vinyltriethylsilane, 437Vinyltrimethoxysilane, 71, 218, 248, 437Vinyltrimethylsilane, 437Wollastonite, 14Wollastonite, 15Zeolite, 68

Page 42: Reactive Polymers Fundamentals and Applications || Index

524 INDEX

Zinc 2-ethylhexanoate, 240Zinc chloride, 205Zinc hexacyanocobaltate, 56Zinc hydroxystannate, 20Zinc naphthenate, 256Zinc octoate, 224, 256Zinc stearate, 17, 476Zirconium hydroxide, 238Zirconium oxide, 467Zirconium phosphate, 238Zirconium propoxide, 260Zirconium tetrachloride, 118Zirconyl chloride, 470Zirconyl dimethacrylate, 470

General Index

Ablative propertiesallyl boron compounds, 286

AC-calorimeters, 126Acceleration

gelation, 112polymerization, 26, 320

Accelerators, 25crosslinking, 222crown ethers, 320cyanoacrylates, 320dental polymers, 461ester-type, 169

Acetalscosolvents for UF, 180cyclic, 58, 453dichlorobenzaldehyde, 133melamine/urea/formaldehyde resins, 180

Acetylationsisal, 388starch, 443

Acid-base reactions, 35Acidolysis reaction

poly(carbonate), 397polyester, 390

Acoustic ceiling tiles, 197Acrylic resins

films, 246Adhesion

amino-functionalized polysiloxane, 233coupling agent, 265coupling sites, 172cyanate ester resin, 265

dental polymer, 471graphite/bismaleimide composite, 296hybrid resins, 106interfacial, 362interlaminar, 11plasma activation, 449self-assembling polymers, 232sisal fibers, 388tackifiers, 309terpene phenol resin, 313to glass fibers, 4, 14to Kevlar fiber, 295to nonpolar substrates, 323to oily surfaces, 104

Aerobic degradation, 355Aerodams, 352Aerospace applications, 15, 127, 217, 251Agave sisalana, 388Agricultural applications, 157, 190, 203Alder-ene reaction, 270, 445Alkenoylcarbamates, 236Allophanate, 59Amalgam replacement, 453Amphiphilic polymers, 95Anti-punk properties, 163Antibodies, 295Anticarcinogenic activity, 95Antifoaming agents, 230Antifouling compositions, 232Antioxidants, 227

chewing gum, 314grafted, 437

Page 43: Reactive Polymers Fundamentals and Applications || Index

INDEX 525

Antiplasticizers, 105hyperbranched polymers, 97

Antistatic formulations, 111, 240Aryl cyanates

hydrolysis, 251Autocatalysis

isocyanate, 71phenol, 115

Autocatalytic curing, 256, 258, 291Autocatalytic polyol, 57Automotive applications, 63, 106, 131, 155, 217, 352Backbiting, 289, 355Backcoats, 232Bagasse, 15, 203Base catalyzed

equilibration polymerization, 219inorganic bases, 162

Batch cell method, 237Batteries, 111, 243

lithium, 80Benzene yellow, 476Beverage containers, 367Binders

abrasive, 170, 171friction, 170glass fibers, 162, 171, 188, 210petroleum recovery, 170sand, 171, 209

Bioabsorbable polymers, 327Biocomposites, 243Biodegradability

poly(lactide), 361starch, 362

Biodegradablecomposites, 106compositions, 354epoxy-polyester resins, 133grafted polymer, 354Lysine-diisocyanate, 50poly(lactide), 361polyesters, 34terpene resins, 311

Biofibers, 106Biuret, 59, 62Blow molding, 366

Blowingchemical, 61epoxy resins, 131formic acid, 61physical, 61

Blowmolding, 352Bonding

adhesive, 448adhesives, 318chemical, 15, 103, 163covalent, 449hydrogen, 79, 328, 443interfacial, 13, 107, 139interphase, 102, 375polyolefin substrates, 324primers, 323

Bone cement, 33– 4, 475Bookbindery, 312Boron trifluoride complexes, 115, 118Bottles, 31, 355Bragg reflector mirrors, 337Brake composites, 175Bridges

dental, 463ether, 181methylene, 159, 161, 181, 205methylene-ether, 204phenoxy, 167silicon groups, 273

Brittleness, 1, 103, 163, 269, 315, 335, 355, 479Brunauer Emmett Teller equation, 380Bubbles, 24, 175, 238, 312Building materials, 32, 132, 228, 240, 246, 248Bumpers, 352Cables, 230, 437Calcification, 78Capacitors, 109, 243Capillary flow microreactor, 199Carbon

glass-like, 174, 208Carbon black, 475Carbonylation

propyne, 237urethane, 49

Carboxybetainegrafting, 77

carboxylation, 175Caries, 470Cashew nut shell liquid, 15Cassava, 381

3

Page 44: Reactive Polymers Fundamentals and Applications || Index

526 INDEX

Cast elastomers, 49Casting, 31, 73, 118, 132

polymerization, 239sand binders, 206steel, 188syrups, 235

Catalysisacidolysis, 397copolyesterification, 8enzymatic degradation, 328isomerization, 3latent, 67titanium dioxide, 292urethane, 64zwitterions, 65

Catalystsaddition-fragmentation, 122delayed-action, 64, 117latent, 67, 116, 120, 205, 261organometallic, 66

Cavitationshear banding, 101ultrasonic curing, 206

Ceiling temperature, 322, 343, 428, 429Cement

bone, 34dental, 461furan resins, 206

Ceramicsaluminum nitride, 286microcellular, 226synthesis by pyrolysis, 226

Chainbranching, 424entanglements, 17, 111reversible termination, 400

Chain extenders, 69, 79, 104, 269, 350, 365diols, 20for polyesters, 34glycols, 59photosensitive, 59waterborne, 60

Chain extensionMichael addition, 277BCB, 334Diels-Alder reaction, 277diglycidyl compound, 367polyaddition, 366

Chain scission, 374, 412shear induced, 426

UV, 246Chain stoppers, 221, 334undecanol, 2Chain transfer, 120, 232, 350, 411, 437

mercaptan, 54, 444Charge carrier, 34Charge control

toner, 34Charring

agents, 70aromatic polyesters, 58

Chelates, 24, 80, 81, 119Chemoreceptors, 122Chewing gums, 314Chitin

N-deacetylation, 75Chlorodioxins, 185Chlorofluorocarbons

blowing, 61Chlorosulfonation, 295Chromatography

packing materials, 209stationary phases, 122

Chrome yellow, 476Chromophore

conjugated furans, 212Disperse Orange 3, 137maleimide, 291phenylazo-benzothiazoles, 138

Clay, see also Oganoclays,108Hectorite, 10macroporous, 174nanocomposites, 378organo, 108organophilic, 12Rectorite, 68

Cloud point, 102, 104, 126, 307, 309Co-condensation

melamine and urea, 194urea resins, 180

Co-continuous phase, 17, 111, 263, 264, 283, 380Coagulation, 199Coal-tar pitches, 209Coalescence

dispersed droplets, 138dispersed phase, 377, 378prevention, 382viscosity dependence, 138

Coatings, 1, 32, 56, 78, 118, 131, 217, 245, 287, 313waterborne, 131

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INDEX 527

Coconut shells, 173Coefficient

diffusion, 474extinction, 124friction, 33, 128, 314heat transfer, 340thermal conductivity, 340thermal expansion, 98, 251, 271

Cohesion, 236, 312, 479Cohesion energy density, 430Colloidal silica, 475, 476Colorant, 34, 314Colorants, 475Coloration, 8Coloring agents

toners, 475Comb-like polymers, 54, 57, 324Combustion, 19, 73, 185, 225, 460Comonomer assisted grafting, 438Compatibilizers

block copolymers, 104epoxy resins, 139grafted polymers, 427UP resin, 33, 35

Composites, 269hydrophobic, 459rigid rod-like, 334wood flour, 379

Condensationbase catalyzed, 317Calixarenes, 122crosslinking, 224hydrolytic, 218intermolecular, 221Knoevenagel, 317resols, 158

Conducting glues, 111Conducting paints, 111Conductivity

electric, 135ionic, 81thermal, 11, 134, 253, 261, 286, 340

Consolidationrestoration materials, 132sand, 211

Controlled-releasedrugs, 199fertilizers, 133

Coordination catalysts, 119Copolymerization

cationic, 122Corona discharge, 323, 447Corrosion

problems, 61, 65, 254resistance, 6, 33, 131, 206, 253

Cotackifiers, 309Coupling agent, 221

for compatibilization, 384for sisal fibers, 15silane, 14, 107, 232, 453

Crack front, 105Crack front bowing, 105Crack propagation, 105Crack trapping mechanism, 13Crazing, 239Critical solution temperature, 311Crosslinkers, 317, 335Crosslinking inhibitor

N,N-dimethylformamide, 432Crown ethers

accelerators, 320polymerization retarder, 121

Crystallinity reduction, 58, 80, 140, 380, 398Curing

fluorescence response, 127, 256microwave, 128, 291, 333, 466ultrasonic, 205

Cycloaddition, 212, 278, 331anisotropic, 136

Cyclocondensationphenols, 159

Cyclotrimerisation, 255, 258Cyclotrimerization, 255, 263Cytocompatibility

poly(urethane), 77Cytotoxicity, 474

HEMA monomer, 458spiroorthocarbonates, 120

Deep-drawing, 396Degradation

acid, 72competitive crosslinking, 35controlled rheology, 429enzymatic, 246glycolytic, 129hydrolytic, 76, 294mechanism, 419microbial, 311photo, 246thermal, 13, 73, 262

Page 46: Reactive Polymers Fundamentals and Applications || Index

528 INDEX

Dehydrobromination, 447Dehydrochloration, 100Dehydrochlorination, 63, 132, 441, 447Dehydrodecarboxylation, 278Dendrimers, 54, 96, 324Depolycondensation

poly(urethane), 73Depolymerizable systems, 328Depolymerization, 30, 310, 367Devices

electronic, 109, 111, 138electrophotography, 475medical, 230optical, 137photocopying, 230

Diacyl peroxides, 23, 414diatomaceous earth, 377DiBenedetto equation, 290dicarboxylic acid

α,β-unsaturated, 11Dielectric analysis

α-relaxation, 126dielectric loss factor, 126Diels-Alder polymerization, 278, 292Diels-Alder reaction, 8, 203, 270, 279, 295, 446

o-xylylene, 331retro, 167, 206, 278, 295

Diisocyanatesblocked, 53

Dimerα-methyl styrene, 444

Dimerizationisocyanates, 66

Dinnerware, 197Dip-coating, 174Discoloration, 56, 62, 63, 461Dispersive mixing, 354Disproportionation termination, 419Diterpenes, 303Donor-acceptor complex, 97Drug release, 246Dual initiator system, 18Dynamic fracture toughness, 13Elasticity

improvement, 172, 193melt, 352, 377

Electrochromic devices, 80Electrochromic windows, 135Electrodeposition, 131Electroless plating, 141

Electrolytesgel-type, 135photosensitive, 212solid, 80, 135, 243

Electronparamagnetic resonance, 447Electrophotography, 475Emission suppressants, 5, 11, 163End groups

amino, 398carboxyl, 140functionalization, 402

Enzymatic synthesis, 55Epoxidation reaction, 98, 99Estrogenic activity

dental resins, 475Exchanger

cation, 322Exfoliation

nanoclays, 69nanocomposites, 109

Expandable graphite, 21, 70Explosive polymerization, 124Fermentation, 354, 361Ferroelectric film, 245Fibers, 107, 222

Aramid, 204binder, 164, 188, 217biodegradable, 361carbon, 15coupling agent, 107cure inhibiting, 14fused silica, 62glass, 14, 467graphite, 260insulation, 171jute, 15Kevlar, 295mineral wool, 212natural, 15poly(ethylene) dyeing, 447polyester, 58sisal, 388strength improvement, 209

Fillers, 11, 165, 222, 467dental, 55flame retardant, 254natural fibers, 15plant-based, 12

Film blowing, 366Flame retardants, 20, 70, 112, 185, 238

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INDEX 529

Flammability, 21, 197, 253, 335Flash point, 225, 418Flexibility enhancers, 103Flip-chip manufacturing, 134Flocculation

sewage treatment, 170Flory-Huggins interaction parameter, 374Flow improvers, 34Fluorescence response, 127Fluorocarbons

blowing, 61Fly ash, 12Foams, 67, 170, 175

ceramic, 80flexible, 56floral applications, 170microcellular, 226PET, 366rigid, 52, 56

Footwear, 396Formaldehyde

dispersions, 164exothermic hazards, 163free, 176hydroxylamine titration, 176low emission types, 163ratio to phenol, 161reduction, 164resol resins, 164scavengers, 163

Foundriesfuran binders, 210

Foundry sands, 188Fragrant oil

encapsulation, 199Friedel Crafts

alkylation, 401catalysts, 205, 306reaction, 274

Fries rearrangement, 351Furan

photosensitive polymer electrolyte, 212Functionalization

block copolymers, 380macromonomer, 54montmorillonite, 11of nitrile rubber, 397poly(lactide), 357poly(propylene), 383, 428star branched polymers, 109

terminating reagents, 400furniture coatings, 24, 31Gardner scale, 310Gel coat, 2, 5, 6, 10Gel point, 26, 126, 263, 289

thermal mechanical analysis, 26Gelling, 61

catalysts, 60hybride resins, 19inhibition, 227preliminary, 8, 217reduced contraction, 465viz. blowing, 63

Gelsdrug delivery system, 133thermoreversible, 296

Glass transition temperatureIPN, 19modelling, 102structure properties relationships, 29

Gloss polyesters, 11Glue resins, 179Graphite, 475Gratings, 337, 446Grignard

reagents, 217synthesis, 221

Halomethylation, 175Hantz reaction, 179Hanza yellow, 476Hardeners, 116, 168, 169Hemp, 14Hildebrand solubility parameter, 305, 308Himalaya pine, 303Hindered amine light stabilizers, 23Hock process, 96Holography, 137, 446Hot-melt adhesive, 311–312

reactive, 71Hot-melt extrusion

adhesives, 311Household applications, 131, 230, 240, 241, 248Hydrocarbonylation

ethene, 237Hydrogels, 133Hydroperoxides, 413Hydrosilylation, 427hydrosilylation, 220, 446

aromatic compounds, 220crosslinking, 225

Page 48: Reactive Polymers Fundamentals and Applications || Index

530 INDEX

inhibitors, 223platinum complexes, 223silicones, 128

Hydrosylilation, 265Ignition point

peroxides, 414Image

latent, 475Indene resins, 312Inhibitor

coloring, 9silicones, 220trimerization, 66

Inhibitorsanionic polymerization, 322crosslinking, 432grafting, 432hydrosilylation, 223radical polymerization, 9, 220, 236, 466

Iniferter Method, 400Initiation

ultrasonic, 435Initiator systems

dual, 466Initiators

anionic, 292, 325atom transfer radical polymerization, 312cationic, 119controlled rheology, 412dental polymers, 460dual, 18encapsulated, 259functionalized, 432iniferter method, 400latent, 121peroxide, 23radical, 239, 262redox, 453UV-sensitive, 32

Insertioncarbene, 437epoxide, 119epoxy, 261intercalation, 108vinyl monomer, 400

Intercalation, 108, 378melt processing, 68

Interfacial slip, 374Interlayers

charged, 108

Intramolecular cyclization, 289Intumescence, 70, 367Ionomers

acrylic modified polyolefins, 389–390poly(urethane), 69

Iron black, 475Isocyanates

comb-like, 54phosgene-free synthesis, 49

Isomerizationallyl ether, 5oxazoline, 261propylene oxide, 56unsaturated polyester, 3

Jute, 14, 15, 165Karstedt catalysts, 221, 223, 265Keratinization, 326Ketone Peroxides, 23Kinetics

autocatalytic curing, 102, 165crosslinking, 74curing, 25, 71, 110, 461cyclotrimerization, 263grafting, 432infrared spectroscopy, 289intragallery curing, 108isomerization, 3monitoring, 125peroxide decomposition, 417photopolymerization, 465polyesterification, 7polymerization, 160self-catalyzed reaction, 9water content, 168

Knoevenagel reaction, 317Laminates

continuous fibers, 106hyperbranched polymers, 97printed circuit boards, 260

Lenses, 135Lignin, 362Low-profile additives, 13, 17Lubricants, 106Macroradicals, 352, 425, 429, 431, 433, 438

poly(propylene), 384Mandioca, 381Manicure compositions, 326Manihot, 381Manioc, 381Mannich

Page 49: Reactive Polymers Fundamentals and Applications || Index

INDEX 531

bases, 118reaction, 169

Marbleartificial, 241conservation, 246

Masterbatchesperoxides, 415

Mechanochemistry, 425Melt condensation, 8, 9Melt phase boundaries, 373Membranes

carbon, 173dialysis, 440drug release, 246molecular sieves, 174poly(urethane), 68reactive, 133thermally stable, 296

Mercury porosimetry, 380Mesomorphic phases, 389Metallocene catalyst, 445

terminal unsaturation, 402Metallocene salts, 325Methylene blue, 476Methylolation, 181Michler’s ketone, 122Microcapsules, 190

controlled-release of drugs, 199Microcracking, 29, 105Microfibrils, 390Microfiltration membranes, 173Microgels, 35, 101, 478Microvoids, 17, 29Microwave curing, 127Mixer

batch, 35, 400Brabender, 386cavity transfer, 425extruder, 350, 373Plasti-Corder, 390static, 425

Modifiersalkenyl, 251conductivity, 106epoxy adhesives, 132epoxy resins, 70impact strength, 422interphase, 376liquid rubber, 104melt strength, 366

polyterpene resins, 312tiazone, 182toughness, 139, 183, 263, 283unaturated polyester, 3urea resins, 193

Moduluscompression, 12elastic, 79, 129, 253flexural, 11, 12, 253, 264, 412shear, 295storage, 263, 274, 446tensile, 11, 31, 381, 388

Moisture barriers, 311Molecular sieve, 174, 362Monomer reactivity ratios, 18, 25, 439Monoterpenes, 303Multi-initiator systems, 466Multiring monomers, 274Multivariate analysis, 127, 294MüLler-Rochow process, 220Nail chapping, 326Nanocomposites, 13, 373, 378

clay, 378intercalation, 12layered silicate, 69, 108montmorillonite, 69rectorite, 68silica, 69silicate, 253

Nanofibers, 467, 468Nanofillers

silsesquioxane, 287Nanoparticles

layered silicate, 109metal oxide, 467, 468titanium dioxide, 13

Nanotubes, 107Natural rubber, 303Natural rubber, 246

epoxidized, 13Nematic

acrylics, 457film, 136network, 98

Neoprene rubber, 311Network

breaking, 129, 206hybrid, 20, 112interlock, 19interpenetrating, 18, 19, 74, 109, 138, 263, 292

Page 50: Reactive Polymers Fundamentals and Applications || Index

532 INDEX

liquid crystalline, 98nonazeotropic composition, 25porous, 296reduction of crosslink density, 251reinforcement, 158reversible, 130silicone, 222unsaturated polyester, 1

Nigrosine, 476Nitroxides

cyclic, 400Nitroxyl radicals, 419Nonlinear optics, 137, 296Novolak, 96

bismaleimide-modified, 287cyanate ester, 252diallyl bisphenol A, 270epoxy resin, 112, 261resin, 155, 158thermoplastic, 444toughener for, 315

Nucleation, 199, 264, 387Number

acid, 9Avogadro, 430hydroxyl, 58Sherwood, 340

Optical applications, 95, 116benzocyclobutene, 337

Optical resins, 135Organisms

aquatic, 232Organoclays, 11, 12, 108Oxamides, 64Ozone

depletion potential, 61resistance, 227, 311, 396treatment, 337

Paintability, 402Paper release agents, 230Paraffin wax, 11, 307Particle collisions, 377Peresters, 23, 415Peroxides

flash points, 418half-lifes, 417

Phase transfer catalyst, 99, 350Phosgenation, 51Phosgene

reaction of bisphenol, 350

Phosphorylation, 175Photo curing, 127, 325Photoalignment method, 136Photochemical

bromination, 447chlorination, 447generation of dienes, 279reaction, 137, 212

Photodimerizationchalcone, 136

Photoinitiators, 23, 463Photoinitiators, 34, 121, 259

cationic, 122radical, 125visible light, 124

Photopolymerization, 19, 465cationic, 121–122postpolymerization, 121radical, 133

Photoresistgratings, 337negative, 59, 259positive, 172

Photostability, 137Photostabilizers, 470Phytotoxicity, 213Pine resin, 304Plasma treatment, 446Plasticizers

cyanoacrylate esters, 318Plasticizersepoxy resins, 111Poly(urethane)

waterborne, 79Polyamide 6

γ -crystals, 387Polyesterimides, 283Polymerization

anionic, 325coordinative, 119emulsion, 103, 390Enthalpy, 342Entropy, 342furfuryl alcohol, 210living, 55metathesis, 344multibranching, 96suspension, 230, 477

Polymersheat-resistant, 69, 219, 231, 280, 292hyperbranched, 96, 139, 279, 324

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INDEX 533

self-healing, 190telechelic, 401

Polyphosphazenes, 135Polyurea resins, 59Postcure treatment, 127, 280, 290, 465Postpolymerization

photo curing, 121Pot life, 9, 25, 26, 115, 118, 259Pour point depressants, 33–34Powder coatings, 32Prepregs, 261, 269Pressure-sensitive adhesive

hot-melt, 445Primers, 323, 475Printed circuit boards, 108, 132, 223, 231, 260Printing inks, 121, 306Printing medium

ink-jet, 248toner, 475

Promotersadhesion, 427, 458, 471amine, 19dental polymers, 460redox, 24silicone synthesis, 220visbreaking, 175

Pulse-cure method, 466Pyrones

cycloadduct, 278Quinoline yellow, 476Radical

β-scission, 414, 424branching, 352chlorination, 447copolymerization, 25coupling, 374diffusion control, 18grafting, 357, 379, 425, 426grafting kinetics, 432induced decomposition, 433inhibitor, 461initiator, 22photoinitiator, 121polymerization kinetics, 27scavenger, 446stable, 418, 426telomerization, 54

Radical polymerizationatom transfer, 400, 401bismaleimides, 279

chain transfer, 232cyanoacrylate, 325living, 400ring opening, 459

Reactive solvents, 138, 157Reactors

bent loop, 340Recombination termination, 429Reductive amination, 59, 65Reinforcing materials

epoxides, 106unsaturated polyesters, 14

Relaxationdipol, 126viscoelastic, 263

Renewable resourcesvegetable cellulose, 203

Residence time, 35, 339, 348, 402, 412, 425, 426Resistance

hydrolytic, 58impact, 13, 20, 389, 402thermal, 12, 33

Reworkable resins, 129Rigidity control, 4, 29, 58Ring and ball method, 310Rubber tackifier, 3Rutherford back-scattering technique, 447Salicylates

ultraviolet absorbers, 238Sanitary products, 32, 230, 241, 312, 395Sawdust, 12, 15Scaffold, 77Scavengers

acid, 58formaldehyde, 161, 163

Schiff bases, 98Schotten-Baumann reaction, 458Schulz-Flory distribution, 57Scission

homolytic, 419Sealants, 230, 311Self-extinguishing

unsaturated polyesters, 21Sequence length

reactivity, 8Sesquiterpenes, 303Sewage treatment

phenol/formaldehyde resins, 170Shrinkage, 23, 26, 66, 128, 457

cationic polymerization, 460

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534 INDEX

control, 17cyclic monomers, 459low profile additive, 18measurements, 18strain, 465

Silacrown compoundspreparation, 320promoter, 320

Silaferrocenophanes, 220Silly putty, 217Silsequioxane resins, 217Sisal, 14Sizing agents, 313Softening point, 310, 312Soil amendment, 190Solubility parameters

peroxides, 430Solvents and polymers, 309

Solventsaprotic, 280

Solvolysis, 71, 129Solvolysis, 23Spin-coating, 138Spoilers, 352Stabilizers

acid, 317efficiency, 431foam, 230poly(vinyl chloride), 132storage time, 53, 322UV, 403

Starchgrafted, 441

Starchacetylated, 443amylose, 442blend, 362, 364cassava, 382corn, 159, 443esterification, 442grafted, 354, 443modified, 362rice, 435sago, 381tapioca, 382thermoplastic, 396

Steamactivation, 174distillation, 304hydrolysis, 367

treatment, 165Stereolithography, 247Steric hindrance, 8, 63, 111, 289, 291, 443Storage time

inhibitors, 9phenolic resin, 172unsaturated polyester resin, 9

Strengthbond, 319cohesive, 317compressive, 7, 11, 171, 334, 458flexural, 11, 12, 15, 217, 223, 258, 263, 264peel, 104, 128, 261, 309tensile, 13, 19, 69, 74, 79, 106, 183, 263, 293,

296, 324, 382, 398, 436Sulfonation, 175Supercritical carbon dioxide, 429Superglues, 317Surface metallization, 141Swelling

chromatography support, 209drug delivery system, 133jute, 165

Syrupscasting, 235

Tackifier, 246, 308Tackifying resin

waterborne, 311Tapes

adhesive, 132, 231, 312Tapioca, 381Tempera paintings, 246Tetraterpenes, 303Thermal cracking, 175thermal transfer ribbons, 231Thermochromic dyes, 473Thermolabile linkages, 129Thermolysis, 120

peroxyketals, 433recycling, 129

Thermotropic polymers, 334, 389Thickeners, 321Thixotropic

additives, 10Thixotropic

resins, 6Tint agents

dental polymers, 454, 470Tissue adhesives, 327, 328

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INDEX 535

Tonersbisphenol A fumarate, 33low fix temperature, 478styrene-acrylic resin, 478textile printing, 479

Top coat, 2Tougheners, 139, 283Tougheners

dendrimers, 97rubbers, 104

Toxicityisocyanates, 52maleic anhydride, 431silacrown ethers, 320tissue adhesives, 327

Transesterification, 1, 58, 129, 169, 317, 320, 351,367, 389

zinc acetate, 31Trimerization, 256Triterpenes, 303Trommsdorff effect, 18, 26Ullmann reaction, 252Ultrasonic

assisted extrusion, 373curing, 205initiation, 435reactor, 72

Ultraviolet absorbers, 23, 238Ultraviolet stabilizers, 23unsaturated polyesters

π -interactions, 19

waterborne, 5Urdiol, 55Urethane dimethacrylates, 55Vector fluids, 386Vinyl offset, 478Vinyl staining, 63, 66Visbreaking, 175Viscosity

branched polymers, 366chain stopper, 460controlled rheology, 412grafting, 429hot-melt adhesives, 312interfacial slip, 374intrinsic, 365, 403liquid crystalline polymer, 389, 457reactive diluents, 270thickeners, 321vis-breaking processes, 422

Visible light sensitizer, 124Vitrification, 111, 126, 247Wagner-Jauregg reaction, 290Wastewater treatment plants, 355Water sorption, 293, 467, 474Wetting agent, 213gen Wheat straw, 388Whiskers, 107Xanthens, 165Yucca, 381Zwitterionic salts, 65