1

PRIMARY STANDARD

SOLUTIONS CERTIFIED (CRM)

ICPICP-MSAASGCION Chromatography

HIGHT PURITY REAGENTS AND ACIDSREFERENCE MATERIALS (CRM)

For information, contact :TecDev Le Villaret CH 1432 Belmont s/ Yverdon Switzerland

Tel +41 (24) 435 22 02 Fax : +41 (24) 435 22 03 Email : tecdev@swissonline.ch

mailto:tecdev@swissonline.ch

2

INDEX

STANDARD SOLUTION ASTASOL® PRIMARY CERTIFIED FOR ELEMENTS OR IONS ..............4

1. History and background ................................................................................................ 42. Docteur Sychra’s letter .................................................................................................. 4CERTIFIED REFERENCE MATERIAL : CERTIFICATES AND OPERATING CONDITIONS .............5

3. certificates and operating conditions........................................................................... 5

IDENTIFICATION OF NEW CRM – CALIBRATION SOLUTIONS ......................................................9CRM STANDARD FOR ICP, ICP-MS, AAS ......................................................................................10

4. Solution primary CRM Standards 1g/l ou 10g/ ASTASOL®, for ICP, AAS,............ 105. Primary Multi elements CRM ASTASOL®, 100 ml for ICP, AAS, ............................. 146. Solutions working standards mono element ASTASOL®, ........................................ 167. Multi-elements Standards Solutions ASTASOL® -MIX ............................................. 178. Mono element Standards Solutions in oil ASTASOL®-OS........................................ 189. Multielement Standarsd Solutions ASTASOL®-OS MIX on request......................... 18IC – IONS CHROMATOGRAPHY .....................................................................................................19

10. Solutions Primary Standards 1g/l CRM ASTASOL®, for Ions Chromatography .... 1911. Primary Multi element CRM solution ASTASOL®, 100 ml for Ion Chomatography.1912. Solutions Secondary Standards for Ion chromatography ASTASOL®, ................... 2013. Eluants (concentrate) for IC ........................................................................................ 2014. Certified calibration Solutions CRM for détermination of organic et inorganiccarbon*. ................................................................................................................................ 20

AUXILIARY REAGENTS..................................................................................................................21

15. Matrix modifier, Desioniseur, « releasing agents » ................................................... 2116. Mineral acids of extra high purity (with certificate of guarantee) ............................ 2117. Other reagents and chemical products...................................................................... 2218. High purity metals ........................................................................................................ 23

CERTIFIED REFERENCE MATERIAL (SOILS)................................................................................24

LABORATORY CONTROL MATERIALS METRANAL™(LCM) ............................26

CHROMATOGRAPHY CPG..............................................................................................................29

19. ASTASOL-CH: Standards Solution for chromatography.......................................... 2920. Calibration solutions for the determination of polycyclic aromatic hydrocarbon(PAH's) Single analyte......................................................................................................... 3021. Multi analyte calibration solutions Polycyclic aromatic Hydrocarbons (PAH's) ... 30

3

22. Calibration solution for determination of Polychlorinated Biphenyls (PCB'S),single analyte....................................................................................................................... 3223. Calibration solution for determination of Polychlorinated Biphenyls (PCB'S),multi analyte ........................................................................................................................ 3324. Calibration solutions for the determination of volatile organic compounds (VOC,BTEX) Single analyte........................................................................................................... 3325. Calibration solutions for the determination of volatile organic compounds (VOC,BTEX) Multi analytes ........................................................................................................... 3426. Calibration solutions for the determination of pesticides (metabolites) singleelement................................................................................................................................. 3527. Calibration solutions for the determination of pesticides (metabolites)Multianalyte.......................................................................................................................... 3628. Calibration Solutions for détermination of Chorophenols ....................................... 3829. Calibration solutions for détermination of nitrosamines.......................................... 3930. Calibration Solutions for determination of phtalates (EPA 8060) ............................ 39ACCESSORIES FOR STANDARDS.................................................................................................40

31. Empty CERTAN® Bottles and accessories:............................................................... 4032. Cleaning equipment for CERTAN® bottles ................................................................ 40

STANDARD SOLUTIONS FOR PH ET CONDUCTIVITY..................................................................41

33. Buffer solutions Phanal TM........................................................................................... 4134. Calibration solutions for conductivity CONDUCTANAL TM....................................... 42

4

STANDARD SOLUTION ASTASOL® PRIMARY CERTIFIED FOR ELEMENTS OR IONS

1. History and backgroundANALYTIKA Ltd. created by Professor Sychra, produces a wide range of single element calibration standard solutions(trade name ASTASOL®) for atomic spectrometry (ICP-OES, ICP-MS, AFS, AAS), molecular absorption spectrometry andion chromatography. These standard solutions (concentration of 1 000 mg, 5 000 mg and 10 000 mg of the analyte per litre)are prepared by experienced specialist (strictly following relevant metrological regulations) from ultra pure metals orcompounds, acids purified by subboiling distillation and ultra pure deionised water. Each starting material is evaluated forthe assay of the analyte by classical analytical methods (gravimetric, titrimetric) as well as for trace impurities by sensitiveinstrumental methods (ICP-OES, ICP-MS). The rigor and the constant quality brought to the preparation of the solutionssucceeded to the pleasure of ANALYTIKA to be agree by the Czech institute of metrology for the production of referencematerials certified (CRM) in aqueous solution. Agreement N° 017/CR/070 covers mono and multi element calibrationsolutions of individual elements and ions and 24 multielement calibration solutions carrying numbers composed of CZ9001to CZ9200 at present. New solution will be added continuously especially multi element calibration solutions relevant toparticular analytical requirement.The solutions are delivered amber HDPE or glass bottles decontaminated by special leaching procedures. Each standard isaccompanied with a certificate of quality. An expiry date is 2 years or 3 years. The production and distribution of thesestandards was agreed and is followed by the Czech Metrological Institute and the Czech Institute for Accreditation.Our offer includes also 10 multi-element standard solutions. A special attention should be paid to the standard M010(composed of 28 elements) which was thoroughly tested for stability for 3 years.ASTASOL®-OS are calibration standard solutions in oil. The starting material is always an organometallic oil concentrate(CONOSTAN), the matrix is a base oil. These standards are designed for analytical applications when an analyte isdissolved in an organic solvent (e.g. analysis of petroleum and petroleum products, determination of wear metal in usedlubricating oils, determination of oil additives, etc.).* Professor Vaclav Sychra : before creating the Analytica company, Professor Sychra, of international reputation, taught thespectroscopic techniques and the analytic chemistry in the university Prague, since 1965. He is the author of more than 50scientific articles, of one book and 10 patents, whole in the domain of the spectral methods and the analysis of the traces.Professor Sychra was for more than 10 years the vice-president of the Czech Spectroscopy Society

2. Docteur Sychra’s letterDear customers, dear business partners:

We are very happy that I can announce a certification of aqueous calibration solutions of elements and ions, which ourcompany produces more than ten years under the trade name ASTASOLR Based on the successful defence of theCertification Report, the Certifying Body for Reference Materials at the Czech Metrology Institute authorized ANALYTIKARLtd. for the consecutive production of the certified reference material ,Aqueous Calibration Solution" (Certificate No.017/CR/070, set of calibration solutions Nos. CZ9001-9200).This set is an open system; at present, 82 calibration solutionsof individual elements and ions and 24 multielement calibration solutions are certified. New solutions will be addedcontinuously and rapidly, especially multi element calibration solutions relevant to particular analytical requirements.All details concerning the production, certification and the use of the CRM's-",Aqueous Calibration Solution" are describedin the Certificate (see further in this leaflet). The Certificate has two parts: the Certificate itself (a 4 pages general documentcommon for all analytes) and so call Identification Sheet of a specific CRM of a particular batch which characterizes in detailthe analyte(s). The Identification Sheet is an integral part of the Certificate as a legal-metrological document.All calibration solutions which are now available are listed in the table enclosed. Besides a wide range of certified calibrationsolutions, 40 calibration solutions of the most frequently used analytes are also available as a cheap uncertified "dailycalibrant". These solutions are directly traceable to the corresponding CRM's.

Two new groups of calibration solutions have been added recently: calibration solutions especially designed for ionchromatography (with suffix IC) and for organic and inorganic carbon.

We do believe that our new CRM's "Aqueous Calibration Solution" (due to their wide range of analytes and concentrations,high quality and very competitive prices) will be well accepted by the world analytical community and that they will become -similarly as the calibration solutions certified by other national certifying bodies (e.g. NIST, BAM, LGC, EMPA an importantmean for the quality assurance and traceability to SI unit in inorganic elemental analysis.

Dr. Vaclav Sychra Ph.D.

Managing Director

5

Certified Reference Material : certificates and operating conditions

3. certificates and operating conditions

___________________________________________________________________

CZECH METROLOGY INSTITUTEREFERENCE MATERIALS CERTIFYING BODY, PRAGUE

V Botanice 4, CZ-150 72 Praha 5, tel: +420 2 5732 4096, fax: +420 2 57324982

CERTIFICATE

Certified Reference Material - Aqueous Calibration Solution

CZ 9001 -- CZ 9200

Aqueous calibration solutions of individual elements and ions with certified concentration in the 1 g/1 and 10 g/1 levels andaqueous calibration solutions of the combination of elements and/or ions with certified concentrations in various levelsrelevant to particular analytical requirements. The Certified Reference Materials are intended for calibration of instrumentsand providing traceability to SI unit. They can be used by analytical techniques analysing aqueous solutions such as atomicspectrometry (AAS, AFS, ICP-AES, ICP-MS), molecular absorption spectrophotometry, ion chromatography, and someselected electroanalytical methods. The attached Identification Sheet of a specific CRM of a particular batch is an integralpart of the Certificate as a legal-metrological document.

Producer

ANALYTIKA® LTD Phone/Fax : 00420-2-8589616Ke Klicovu 816, CZ - 190 00 Prague 9 E-mail : sales@analytika.netCzech RepublicProject-in-charge : Vâclav Sychra

Authorization for consecutive productionIssued on: 15. 6. 2001 Valid until: 15. 6. 2010 Certificate No: 017/CR/070

mailto:sales@analytika.net

6

Preparation procedure. The mass of the starting primary substance ( pure metal or compound) calculated with respect toan assay of the certified constituent and the target volume of the batch, is weighed on an analytical balance and transferredquantitatively to a tall 600 = 800ml beaker and dissolved completely in appropriate media (e.g. water, acid, acid mixture).The resulting solution is then transferred into a volumetric flask (with volume corresponding to the target volume of thebatch - usually 5 or 10 1), containing reagents ultimately forming the designed matrix. After adding demineralised water upto 90 = 95°,'0 of the final volume the solution is tempered to 20.0±0.1°C, filled up to the mark with similarly tempered waterand thoroughly mixed. A sample is taken of the prepared solution and impurities determined. The solution, divided with ameasuring cylinder into ultimate unit portions, is then filled into dry leached bottles which are closed with a polypropylenescrew cap, provided with protective parafilm, labelled and stored. All data relevant to the particular CRM batch (e.g. sourceand declared assay of the primary substance, weighing, volume and temperature measurement, determination of impurities,codes, dates of the preparation steps and personnel involved, etc.) are duly recorded and filed in both written and electronicform at least until the certification expires. One unit of each batch is stored for a period of at least 5 years.

Starting primary substances and other applied materials. High purity metals with a declared assay of minimum 99.99%are preferred, and compounds of a defined and constant stoichiometry and declared assay and/or impurities content areused when a suitable metal is not available.The supplier of primary substances must comply with ISO Guide 34 [2], namely to employ a certified Quality ManagementSystem. Each supply of the primary substance must be accompanied with complete documentation, including anidentification of sources and treatment, assay and impurity contents. As required by this Guide, the supplier's data areverified by the CRM producer and by other subcontracted accredited laboratories (e.g. trace metal impurities byspectroscopic methods such as ICP-AES, ICP-MS, AAS, the assay by primary gravimetric or volumetric methods). Sub boildistilled acids (prepared by the CRM producer), other ultra pure chemicals (ammonium hydroxide, hydrogen peroxide, etc.)and demineralised water with a specific conductivity below 0.5 S/cm are further applied in the CRM preparation. Theirimpurity contents are regularly monitored. They are generally negligible compared with the concentration of the certifiedconstituent.

Weighing, volume and temperature measurement. A Class 1 electromechanical analytical balance with a validverification (type Sartotius 2004 MP) is used to weigh the primary substances. All volumetric vessels used (flasks, pipettes,burettes) are of Accuracy Class 1, calibrated by their producers. They are accompanied with certificates with an uncertaintyof volume at 20.0°C statement. Two mercury thermometers 0 - 30°C (with a scale division by 0.1°C), regularly calibrated byauthorised institutions are used for the temperature measurement.

Coding and parking. A four-digit code - CRM CZ 9001 through 9200 - identifies the certified constituent (constituents),whereas the alternative certified concentration level and matrix is differentiated in both the Identification Sheet and the labelby an alphanumeric code (in parentheses). The certified concentrations 1.000g/1 and 10.00 g/1 are marked 1 and 10,respectively. The letter following denotes the matrix: C stands for a diluted HCl, N for a diluted HN03, S a diluted H2SO4, Fa diluted HF, H a H20 matrix, a combination of letters, e.g. C,N specifies a diluted HCl + HN03, etc.CRMs should be stored in their original packing (in an upright position) at temperatures between 10 to 30°C, away from anystrong light source (e.g. sunshine, uv lamp). It is advised to record the first opening of the bottle, to close it immediately afterevery use and to discard the contents of the bottle when less than 10 percent of the original volume of the solution is left.A basic packing unit is 500ml (with options of 250 and 100m1) in an amber HDPE bottle or an amber glass bottle wheneveran interaction of the certified constituent with HDPE may be suspected (e.g. mercury, precious metals). Prior to filling, thebottles and caps are leached by HCl (5% v/v) for a longer period, washed repeatedly with demineralised water andthoroughly dried. After filling with CRM, the remaining volume above the liquid is purged by nitrogen, the bottle closedhermetically with a polypropylene screw cap and sealed with parafilm. The bottle is labelled with a resistant plastic labelcontaining all data as required by CRM standards, i.e. CRM and batch codes, producer identification and contact data,expiry term and further data and warning symbols when required by specific regulations.

Homogeneity and stability. The CRMs are considered homogeneous due to their physico- character (diluted solutions)and thus homogeneity testing is not required.An assumption of stability and the consequent expiration period is based on both over ten years experience with thepreparation of similar RMs and a test of possible instability factors. These factors are of general (e.g.water evaporation byregular weighing of the filled bottle) and specific character (e.g. adsorption and desorption of the particular certifiedconstituent on the walls of the bottle, precipitation, etc.) Along with these tests the content of the certified constituent in thebottle is compared (at least twice during the validity period) with that of a newly prepared batch and/or a correspondingCRM from other producers.

Certification, certified values and their uncertainties. Certification of concentration values is based on the CRMpreparation by ISO Guide 35 [3], i.e. on weighing and volume measurement. They are calculated from an assay of thecertified constituent in the primary substance, declared by its supplier and duly verified by the CRM producer. The certifiedconcentration (ni/v) and its uncertainty are expressed in g/1 at a temperature of 20±0.1°C.The uncertainty of a certified value is estimated in compliance with ISO and EURACHEM methodologies [4,5]. It combinesthe calculated standard uncertainties of the individual CRM preparation steps with an expert estimate of the standarduncertainty of the assay of the certified constituent in the primary substance, usually a dominant contribution. The expandedcombined uncertainty calculated with a coverage factor K = 2 is expressed as a two-sided half interval by one significantfigure, with the certified value given by the same number of digits.

The particular certified values and uncertainties, mostly at a level of 0.2% (rel.), are specified in the Identification Sheetstogether with the expiry terms and other relevant information.

7

Traceability and quality assurance. Traceability to SI unit (mol) is secured by using a primary substance with a verifiedcontent of the certified constituent and by the method of the CRM preparation - weighing and volume measurement.The CRM producer has a standard Quality Management System in force. The appropriateness of the certification anduncertainty estimate methodology was Further confirmed by the Metrological Laboratory of the Prague Institute of ChemicalTechnology.

Instructions for use. The selection of the concentration of a certified constituent and a matrix adequate to the particularanalytical method, as well as the correct preparation of diluted calibration solutions and their proper application is entirelywithin the user's responsibility.The expiry term is valid provided the CRM is properly stored and handled in compliance with these instructions. Thecertification ceases to be valid if the CRM is damaged, contaminated or modified. (Please note the difference between thevalidity period of the authorization of the producer and the expiry term of a particular batch of CRM given in its IdentificationSheet).The user is responsible for an update of his contact data with the CRM producer to facilitate immediate relay of informationon possible expiry terms and other essential data changesSafety regulations for transportation, storage and use of CRM are specified in the Safety Data Sheet enclosed with eachsupply

Reference

1. J. R. Moody, R. R. Greenberg, K. W. Pratt, T. C. Rains (NIST U.S.A.) : Analytical Chemistry, Vol. 60, No. 21, 1203A(1988). Recommended Inorganic Chemicals for Calibration.

2. ISO Guide 34: 2000, General Requirements for the Competence of Reference Material Producers3. ISO Guide 35: 1989 (E), Certification of Reference Materials - General and Statistical Principles4. Document EURACHEM: 1999, Quantifying Uncertainty in Analytical Measurement5. ISO Guide to the Expression of Uncertainty in Measurement, ISBN 92-67-10188-9, Geneva 1993.6. ISO/IEC Guide 25: 1990 General Requirement for the Competence of Calibration and Testing Laboratories.7. ISO Guide 30: 1992, Terms and Definitions Used in Connection with Reference Materials.8. ISO Guide 31: 1998, Reference Materials - Contents of Certificates and Labels.9. ISO Guide 33: 1989, Uses of Certified Reference Materials.10. Document BCR/01/97:1997, Guidelines for the Production and Certification of BCR Reference Materials11. Reference Materials for Environmental Analysis, ed. by R. E. Clement, L. H Chapter 3: Preparation and Verification of

ICP and AA Reference Standards

8

CERTIFICATE - IDENTIFICATION SHEET

Certified Reference Material - Aqueous Calibration Solution

CZ 9001 (lON) SilverCertified Value 10.00 ± 0.02 g/1 Ag at 20°Cand Uncertainty:Starting Primary Substance: Ag metal, assay 99.999%Matrix: HN03, 2% (v/v)

HN03 subboil distilled H2O demineralized conductivity 0,001g/ll: None Impurities determined by ICP-AES, ICP-MS, AAS and other methods.

Unit Volume, Packing, Code: 140mI Amber glass bottle sealed and labeled with an original producer's label Trade naine ASTASOL® - Ag Order No. CZ9001 1 ON 1

Batch No: Expiration Term: Date of Issue:

Producer: ANALYTIKA, LTD, Ke Klicovu 816, CZ-190 00 Prague 9Czech RepublicPhone/fax: 004202-8589616 E-mail: sales@analytika.netQuality Manager: Ing. Helena Koppovâ

Project-in-Charge: Dr. Vâclav Sychra Ph.D, Managing Director

Signed:

This Identification Sheet is an integral part of the Certificate No. 017/CR/070

mailto:sales@analytika.net

9

Identification of new CRM – calibration solutions

CZ90011N5

Standard identification of the CzechMetrology Institute

identification of the analyte( 001 = Ag, 033 = Mn071 = Br-072 = Cl- etc…081 = M001 etc…)

Identification of the concentration 1 = 1g/l10 = 10 g/l

Identification of the matrixN = HNO3C = HClF = HFA = AmmoniaH = H2OCN = aqua regiaS = H2SO4FN = HNO3 + HF

Identification of the volume 5 = 500 ml1 = 100 ml

10

CRM STANDARD for ICP, ICP-MS, AAS

4. Solution primary CRM Standards 1g/l ou 10g/ ASTASOL®, for ICP, AAS,HCl, HNO3, H20 matrix. Packing 500 ml or 100 ml

Order No. DescriptionElement

Concentration(g/l)

Starting material andits purity

Matrix (%,v/v) Volumeml

Packingmaterial

CZ 90011N1 Silver Ag 1.000 ± 0.002 Ag 99.999 2% HNO3 100 glassCZ 90011N5 1.000 ± 0.002 Ag 99.999 2% HNO3 500 glassCZ 900110N1 10.00 ± 0.02 Ag 99.999 2% HNO3 100 glassCZ 90021C1 Aluminium Al 1.000 ± 0.002 Al 99.999 5% HCl 100 HDPECZ 90021C5 1.000 ± 0.002 Al 99.999 5% HCl 500 HDPECZ 900210C1 10.00 ± 0.02 Al 99.999 5% HCl 100 HDPECZ 90021N1 1.000 ± 0.002 Al 99.999 5% HNO3 100 HDPECZ 90021N5 1.000 ± 0.002 Al 99.999 5% HNO3 500 HDPECZ 900210N1 10.00 ± 0.02 Al 99.999 5% HNO3 100 HDPECZ 90031N1 Arsenic As 1.000 ± 0.002 As 99.999 2% HNO3 100 HDPECZ 90031N5 1.000 ± 0.002 As 99.999 2% HNO3 500 HDPECZ 900310N1 10.00 ± 0.02 As 99.999 2% HNO3 100 HDPECZ 90041C1 Gold Au 1.000 ± 0.002 Au 99.998 5% HCl 100 GlassCZ 900410C1 10.00 ± 0.02 Au 99.998 5% HCl 100 GlassCZ 90051H1 Boron B 1.000 ± 0.002 H3BO3 99.99 H2O 100 HDPECZ 90051H5 1.000 ± 0.002 H3BO3 99.99 H2O 500 HDPECZ 900510H1 10.00 ± 0.02 H3BO3 99.99 H2O 100 HDPECZ 90061N1 Barium Ba 1.000 ± 0.002 BaCO3 99.999 2% HNO3 100 HDPECZ 90061N5 1.000 ± 0.002 BaCO3 99.999 2% HNO3 500 HDPECZ 900610N1 10.00 ± 0.02 BaCO3 99.999 2% HNO3 100 HDPECZ 90061C1 1.000 ± 0.002 BaCO3 99.999 2% HCl 100 HDPECZ 90061C5 1.000 ± 0.002 BaCO3 99.999 2% HCl 500 HDPECZ 900610C1 10.00 ± 0.02 BaCO3 99.999 5% HCl 100 HDPECZ 90071N1 Beryllium Be 1.000 ± 0.002 BeO 99.99 2% HNO3 100 HDPECZ 900710N1 10.00 ± 0.02 BeO 99.99 2% HNO3 100 HDPECZ 90081N1 Bismuth Bi 1.000 ± 0.002 Bi 99.999 5% HNO3 100 HDPECZ 90081N5 1.000 ± 0.002 Bi 99.999 5% HNO3 500 HDPECZ 900810N1 10.00 ± 0.02 Bi 99.999 5% HNO3 100 HDPECZ 90091N1 Calcium Ca 1.000 ± 0.002 CaCO3 99.995 2% HNO3 100 HDPECZ 90091N5 1.000 ± 0.002 CaCO3 99.995 2% HNO3 500 HDPECZ 900910N1 10.00 ± 0.02 CaCO3 99.995 2% HNO3 100 HDPECZ 90091C1 1.000 ± 0.002 CaCO3 99.995 2% HCl 100 HDPECZ 90091C5 1.000 ± 0.002 CaCO3 99.995 2% HCl 500 HDPECZ 900910C1 10.00 ± 0.02 CaCO3 99.995 5% HCl 100 HDPECZ 90101N1 Cadmium Cd 1.000 ± 0.002 Cd 99.999 2% HNO3 100 HDPECZ 90101N5 1.000 ± 0.002 Cd 99.999 2% HNO3 500 HDPECZ 901010N1 10.00 ± 0.02 Cd 99.999 2% HNO3 100 HDPECZ 90101C1 1.000 ± 0.002 Cd 99.999 2% HCl 100 HDPECZ 90101C5 1.000 ± 0.002 Cd 99.999 2% HCl 500 HDPECZ 901010C1 10.00 ± 0.02 Cd 99.999 5% HCl 100 HDPECZ 90111N1 Cerium Ce 1.000 ± 0.002 CeO2 99.99 5 % HNO3 100 HDPECZ 901110N1 10.00 ± 0.02 CeO2 99.99 5% HNO3 100 HDPECZ 90121N1 Cobalt Co 1.000 ± 0.002 Co 99.995 2% HNO3 100 HDPECZ 90121N5 1.000 ± 0.002 Co 99.995 2% HNO3 500 HDPECZ 901210N1 10.00 ± 0.02 Co 99.995 2% HNO3 100 HDPECZ 90121C1 1.000 ± 0.002 Co 99.995 2% HCl 100 HDPECZ 90121C5 1.000 ± 0.002 Co 99.995 2% HCl 500 HDPECZ 901210C1 10.00 ± 0.02 Co 99.995 5% HCl 100 HDPECZ 90131C1 Chromium Cr 1.000 ± 0.002 Cr 99.995 2% HCl 100 HDPECZ 90131C5 1.000 ± 0.002 Cr 99.995 2% HCl 500 HDPECZ 901310C1 10.00 ± 0.02 Cr 99.995 5% HCl 100 HDPECZ 90131N1 1.000 ± 0.002 Cr(NO3)3 .9H2O 99.99+ 2% HNO3 100 HDPECZ 90131N5 1.000 ± 0.002 Cr(NO3)3 .9H2O 99.99+ 2% HNO3 500 HDPE

11

CZ 901310N1 10.00 ± 0.02 Cr(NO3)3 .9H2O 99.99+ 2% HNO3 100 HDPECZ 90141H1 Cesium Cs 1.000 ± 0.002 CsCl 99.999 H2O 100 HDPECZ 901410H1 10.00 ± 0.02 CsCl 99.999 H2O 100 HDPECZ 90141N1 1.000 ± 0.002 CsNO3 99.999 2% HNO3 100 HDPECZ 901410N1 10.00 ± 0.02 CsNO3 99.999 2% HNO3 100 HDPECZ 90151N1 Copper Cu 1.000 ± 0.002 Cu 99.999 2% HNO3 100 HDPECZ 90151N5 1.000 ± 0.002 Cu 99.999 2% HNO3 500 HDPECZ 901510N1 10.00 ± 0.02 Cu 99.999 2% HNO3 100 HDPECZ 90151C1 1.000 ± 0.002 Cu 99.999 2% HCl 100 HDPECZ 90151C5 1.000 ± 0.002 Cu 99.999 2% HCl 500 HDPECZ 901510C1 10.00 ± 0.02 Cu 99.999 2% HCl 100 HDPECZ 90161N1 Dysprosium Dy 1.000 ± 0.002 Dy2O3 99.99+ 2% HNO3 100 HDPECZ 901610N1 10.00 ± 0.02 Dy2O3 99.99+ 2% HNO3 100 HDPECZ 90171N1 Erbium Er 1.000 ± 0.002 Er2O3 99.99+ 2% HNO3 100 HDPECZ 901710N1 10.00 ± 0.02 Er2O3 99.99+ 2% HNO3 100 HDPECZ 90181N1 Europium Eu 1.000 ± 0.002 Eu2O3 99.999 2% HNO3 100 HDPECZ 901810N1 10.00 ± 0.02 Eu2O3 99.999 2% HNO3 100 HDPECZ 90191N1 Iron Fe 1.000 ± 0.002 Fe 99.999 2% HNO3 100 HDPECZ 90191N5 1.000 ± 0.002 Fe 99.999 2% HNO3 500 HDPECZ 901910N1 10.00 ± 0.02 Fe 99.999 5% HNO3 100 HDPECZ 90191C1 1.000 ± 0.002 Fe 99.999 5% HCl 100 HDPECZ 90191C5 1.000 ± 0.002 Fe 99.999 5% HCl 500 HDPECZ 901910C1 10.00 ± 0.02 Fe 99.999 5% HCl 100 HDPECZ 90201N1 Gallium Ga 1.000 ± 0.002 Ga 99.999 2% HNO3 100 HDPECZ 902010N1 10.00 ± 0.02 Ga 99.999 2% HNO3 100 HDPECZ 90211N1 Gadolinium Gd 1.000 ± 0.002 Gd2O3 99.995 2% HNO3 100 HDPECZ 902110N1 10.00 ± 0.02 Gd2O3 99.995 2% HNO3 100 HDPECZ 90221FN1 Germanium Ge 1.000 ± 0.002 Ge 99.999 1% HF + 5% HNO3 100 HDPECZ 902210FN1 10.00 ± 0.02 Ge 99.999 1% HF + 5% HNO3 100 HDPECZ 90231FN1 Hafnium Hf 1.000 ± 0.002 Hf 99.9 1% HF + 5% HNO3 100 HDPECZ 902310FN1 10.00 ± 0.02 Hf 99.9 1% HF + 5% HNO3 100 HDPECZ 90241N1 Mercury Hg 1.000 ± 0.002 Hg 99.999+ 2% HNO3 100 glassCZ 90241N5 1.000 ± 0.002 Hg 99.999+ 2% HNO3 500 glassCZ 902410N1 10.00 ± 0.02 Hg 99.999+ 2% HNO3 100 glassCZ 90251N1 Holmium Ho 1.000 ± 0.002 Ho2O3 99.999 2% HNO3 100 HDPECZ 902510N1 10.00 ± 0.02 Ho2O3 99.999 2% HNO3 100 HDPECZ 90261N1 Indium In 1.000 ± 0.002 In 99.999 2% HNO3 100 HDPECZ 902610N1 10.00 ± 0.02 In 99.999 2% HNO3 100 HDPECZ 90271C1 Iridium Ir 1.000 ± 0.002 (NH4)2IrCl6 99.998 5% HCl 100 glassCZ 902710C1 10.00 ± 0.02 (NH4)2IrCl6 99.998 5% HCl 100 GlassCZ 90281H1 Potassium K 1.000 ± 0.002 KCl 99.999 H2O 100 HDPECZ 90281H5 1.000 ± 0.002 KCl 99.999 H2O 500 HDPECZ 902810H1 10.00 ± 0.02 KCl 99.999 H2O 100 HDPECZ 90281N1 1.000 ± 0.002 KNO3 99.99 2% HNO3 100 HDPECZ 90281N5 1.000 ± 0.002 KNO3 99.99 2% HNO3 500 HDPECZ 902810N1 10.00 ± 0.02 KNO3 99.99 2% HNO3 100 HDPECZ 90291N1 Lanthanum La 1.000 ± 0.002 La2O3 99.999 2% HNO3 100 HDPECZ 902910N1 10.00 ± 0.02 La2O3 99.999 2% HNO3 100 HDPECZ 90301C1 Lithium Li 1.000 ± 0.002 Li2CO3 99.997 2% HCl 100 HDPECZ 90301C5 1.000 ± 0.002 Li2CO3 99.997 2% HCl 500 HDPECZ 903010C1 10.00 ± 0.02 Li2CO3 99.997 5% HCl 100 HDPECZ 90301N1 1.000 ± 0.002 Li2CO3 99.997 2% HNO3 100 HDPECZ 90301N5 1.000 ± 0.002 Li2CO3 99.997 2% HNO3 500 HDPECZ 903010N1 10.00 ± 0.02 Li2CO3 99.997 2% HNO3 100 HDPECZ 90311N1 Lutetium Lu 1.000 ± 0.002 Lu2O3 99.99 2% HNO3 100 HDPECZ 903110N1 10.00 ± 0.02 Lu2O3 99.99 2% HNO3 100 HDPECZ 90321N1 Magnesium Mg 1.000 ± 0.002 Mg 99.99 2% HNO3 100 HDPECZ 90321N5 1.000 ± 0.002 Mg 99.99 2% HNO3 500 HDPECZ 903210N1 10.00 ± 0.02 Mg 99.99 2% HNO3 100 HDPECZ 90321C1 1.000 ± 0.002 Mg 99.99 2% HCl 100 HDPECZ 90321C5 1.000 ± 0.002 Mg 99.99 2% HCl 500 HDPECZ 903210C1 10.00 ± 0.02 Mg 99.99 5% HCl 100 HDPECZ 90331N1 Manganese Mn 1.000 ± 0.002 Mn 99.98 2% HNO3 100 HDPECZ 90331N5 1.000 ± 0.002 Mn 99.98 2% HNO3 500 HDPECZ 903310N1 10.00 ± 0.02 Mn 99.98 2% HNO3 100 HDPE

12

CZ 90331C1 1.000 ± 0.002 Mn 99.98 2% HCl 100 HDPECZ 90331C5 1.000 ± 0.002 Mn 99.98 2% HCl 500 HDPECZ 903310C1 10.00 ± 0.02 Mn 99.98 5% HCl 100 HDPECZ 90341A1 Molybden Mo 1.000 ± 0.002 Mo 99.999 2% NH4OH 100 HDPECZ 90341A5 1.000 ± 0.002 Mo 99.999 2% NH4OH 500 HDPECZ 903410A1 10.00 ± 0.02 Mo 99.999 2% NH4OH 100 HDPECZ 90351H1 Sodium Na 1.000 ± 0.002 NaCl 99.995 H2O 100 HDPECZ 90351H5 1.000 ± 0.002 NaCl 99.995 H2O 500 HDPECZ 903510H1 10.00 ± 0.02 NaCl 99.995 H2O 100 HDPECZ 90351N1 1.000 ± 0.002 NaNO3 99.99 2% HNO3 100 HDPECZ 90351N5 1.000 ± 0.002 NaNO3 99.99 2% HNO3 500 HDPECZ 903510N1 10.00 ± 0.02 NaNO3 99.99 2% HNO3 100 HDPECZ 90361FN1 Niobium Nb 1.000 ± 0.002 Nb 99.9+ 1% HF + 5% HNO3 100 HDPECZ 903610FN1 10.00 ± 0.02 Nb 99.9+ 1% HF + 5% HNO3 100 HDPECZ 90371N1 Neodymium Nd 1.000 ± 0.002 Nd2O3 99.99 2% HNO3 100 HDPECZ 903710N1 10.00 ± 0.02 Nd2O3 99.99 2% HNO3 100 HDPECZ 90381N1 Nickel Ni 1.000 ± 0.002 Ni 99.999 2% HNO3 100 HDPECZ 90381N5 1.000 ± 0.002 Ni 99.999 2% HNO3 500 HDPECZ 903810N1 10.00 ± 0.02 Ni 99.999 2% HNO3 100 HDPECZ 90381C1 1.000 ± 0.002 Ni 99.999 2% HCl 100 HDPECZ 90381C5 1.000 ± 0.002 Ni 99.999 2% HCl 500 HDPECZ 903810C1 10.00 ± 0.02 Ni 99.999 5% HCl 100 HDPECZ 90391C1 Osmium Os 1.000 ± 0.002 (NH4)2OsCl6 99.998 5% HCl 100 glassCZ 903910C1 10.00 ± 0.02 (NH4)2OsCl6 99.998 5% HCl 100 glassCZ 90401S1 Phosphorus P 1.000 ± 0.002 NH4H2PO4 99.999 0.05% H2SO4 100 HDPECZ 90401S5 1.000 ± 0.002 NH4H2PO4 99.999 0.05% H2SO4 500 HDPECZ 904010S1 10.00 ± 0.02 NH4H2PO4 99.999 0.05% H2SO4 100 HDPECZ 90411N1 Lead Pb 1.000 ± 0.002 Pb 99.999 2% HNO3 100 HDPECZ 90411N5 1.000 ± 0.002 Pb 99.999 2% HNO3 500 HDPECZ 904110N1 10.00 ± 0.02 Pb 99.999 2% HNO3 100 HDPECZ 90421C1 Palladium Pd 1.000 ± 0.002 Pd 99.999 5% HCl 100 glassCZ 904210C1 10.00 ± 0.02 Pd 99.999 5% HCl 100 glassCZ 90431N1 Praseodymium Pr 1.000 ± 0.002 Pr6O11 99.999 2% HNO3 100 HDPECZ 904310N1 10.00 ± 0.02 Pr6O11 99.999 2% HNO3 100 HDPECZ 90441C1 Platinum Pt 1.000 ± 0.002 Pt 99.995 5% HCl 100 glassCZ 904410C1 10.00 ± 0.02 Pt 99.995 5% HCl 100 glassCZ 90451H1 Rubidium Rb 1.000 ± 0.002 RbCl 99.98 H2O 100 HDPECZ 904510H1 10.00 ± 0.02 RbCl 99.98 H2O 100 HDPECZ 90451N1 1.000 ± 0.002 RbNO3 99.99 2% HNO3 100 HDPECZ 904510N1 10.00 ± 0.02 RbNO3 99.99 2% HNO3 100 HDPECZ 90461H1 Rhenium Re 1.000 ± 0.002 NH4ReO4 99.999 H2O 100 HDPECZ 904610H1 10.00 ± 0.02 NH4ReO4 99.999 H2O 100 HDPECZ 90471C1 Rhodium Rh 1.000 ± 0.002 (NH4)3RhCl6 99.99 5% HCl 100 glassCZ 904710C1 10.00 ± 0.02 (NH4)3RhCl6 99.99 5% HCl 100 glassCZ 90481C1 Ruthenium Ru 1.000 ± 0.002 (NH4)2RuCl6 99.95 5% HCl 100 glassCZ 904810C1 10.00 ± 0.02 (NH4)2RuCl6 99.95 5% HCl 100 glassCZ 90491H1 Sulphur S 1.000 ± 0.002 (NH4)2SO4 99.999 H2O 100 HDPECZ 904910H1 10.00 ± 0.02 (NH4)2SO4 99.999 H2O 100 HDPECZ 90501C1 Antimony Sb 1.000 ± 0.002 Sb 99.999 10% HCl 100 HDPECZ 90501C5 1.000 ± 0.002 Sb 99.999 10% HCl 500 HDPECZ 905010C1 10.00 ± 0.02 Sb 99.999 10% HCl 100 HDPECZ 90501FN1 1.000 ± 0.002 Sb 99.999 1% HF + 5% HNO3 100 HDPECZ 90501FN5 1.000 ± 0.002 Sb 99.999 1% HF + 5% HNO3 500 HDPECZ 905010FN1 10.00 ± 0.02 Sb 99.999 1% HF + 5% HNO3 100 HDPECZ 90511N1 Selenium Se 1.000 ± 0.002 Se 99.999 2% HNO3 100 HDPECZ 905110N1 10.00 ± 0.02 Se 99.999 2% HNO3 100 HDPECZ 90521N1 Scandium Sc 1.000 ± 0.002 Sc2O3 99.999 2% HNO3 100 HDPECZ 905210N1 10.00 ± 0.02 Sc2O3 99.999 2% HNO3 100 HDPECZ 90531H1 Silicon Si 1.000 ± 0.002 Na2SiO3 99.9 H2O 100 HDPECZ 90531H5 1.000 ± 0.002 Na2SiO3 99.9 H2O 500 HDPECZ 905310H1 10.00 ± 0.02 Na2SiO3 99.9 H2O 100 HDPECZ 90531F1 1.000 ± 0.002 (NH4)2SiF6 99.99 0.05% HF 100 HDPECZ 90531F5 1.000 ± 0.002 (NH4)2SiF6 99.99 0.05% HF 500 HDPECZ 905310F1 10.00 ± 0.02 (NH4)2SiF6 99.99 0.05% HF 100 HDPE

13

CZ 90541N1 Samarium Sm 1.000 ± 0.002 Sm2O3 99.99 2% HNO3 100 HDPECZ 905410N1 10.00 ± 0.02 Sm2O3 99.99 2% HNO3 100 HDPECZ 90551C1 Tin Sn 1.000 ± 0.002 Sn 99.999 10% HCl 100 HDPECZ 90551C5 1.000 ± 0.002 Sn 99.999 10% HCl 500 HDPECZ 905510C1 10.00 ± 0.02 Sn 99.999 20% HCl 100 HDPECZ 90551FN1 1.000 ± 0.002 Sn 99.999 1% HF + 5% HNO3 100 HDPECZ 90551FN5 1.000 ± 0.002 Sn 99.999 1% HF + 5% HNO3 500 HDPECZ 905510FN1 10.00 ± 0.02 Sn 99.999 1% HF + 5% HNO3 100 HDPECZ 90561N1 Strontium Sr 1.000 ± 0.002 SrCO3 99.995 2% HNO3 100 HDPECZ 90561N5 1.000 ± 0.002 SrCO3 99.995 2% HNO3 500 HDPECZ 905610N1 10.00 ± 0.02 SrCO3 99.995 2% HNO3 100 HDPECZ 90561C1 1.000 ± 0.002 SrCO3 99.995 2% HCl 100 HDPECZ 90561C5 1.000 ± 0.002 SrCO3 99.995 2% HCl 500 HDPECZ 905610C1 10.00 ± 0.02 SrCO3 99.995 5% HCl 100 HDPECZ 90571FN1 Tantalum Ta 1.000 ± 0.002 Ta 99.98 1% HF + 5% HNO3 100 HDPECZ 905710FN1 10.00 ± 0.02 Ta 99.98 1% HF + 5% HNO3 100 HDPECZ 90581N1 Terbium Tb 1.000 ± 0.002 Tb4O7 99.999 2% HNO3 100 HDPECZ 905810N1 10.00 ± 0.02 Tb4O7 99.999 2% HNO3 100 HDPECZ 90591C1 Tellurium Te 1.000 ± 0.002 Te 99.999 20% HCl 100 HDPECZ 90591C5 1.000 ± 0.002 Te 99.999 20% HCl 100 HDPECZ 905910C1 10.00 ± 0.02 Te 99.999 20% HCl 100 HDPECZ 90601N1 Thorium Th 1.000 ± 0.002 ThO2 99.95 5% HNO3 100 HDPECZ 906010N1 10.00 ± 0.02 ThO2 99.95 5% HNO3 100 HDPECZ 90611FN1 Titanium Ti 1.000 ± 0.002 Ti 99.98 1% HF + 5% HNO3 100 HDPECZ 90611FN5 1.000 ± 0.002 Ti 99.98 1% HF + 5% HNO3 500 HDPECZ 906110FN1 10.00 ± 0.02 Ti 99.98 1% HF + 5% HNO3 100 HDPECZ 90621N1 Thallium Tl 1.000 ± 0.002 TlNO3 99.9995 2% HNO3 100 HDPECZ 90621N5 1.000 ± 0.002 TlNO3 99.9995 2% HNO3 500 HDPECZ 906210N1 10.00 ± 0.02 TlNO3 99.9995 2% HNO3 100 HDPECZ 90631N1 Thulium Tm 1.000 ± 0.002 Tm2O3 99.99 2% HNO3 100 HDPECZ 906310N1 10.00 ± 0.02 Tm2O3 99.99 2% HNO3 100 HDPECZ 90641N1 Uranium U 1.000 ± 0.002 U3O8 99.95 2% HNO3 100 HDPECZ 906410N1 10.00 ± 0.02 U3O8 99.95 2% HNO3 100 HDPECZ 90651N1 Vanadium V 1.000 ± 0.002 NH4VO3 99.95+ 2% HNO3 100 HDPECZ 90651N5 1.000 ± 0.002 NH4VO3 99.95+ 2% HNO3 500 HDPECZ 906510N1 10.00 ± 0.02 NH4VO3 99.95+ 2% HNO3 100 HDPECZ 90661A1 Tungsten W 1.000 ± 0.002 W 99.99+ 2% NH4OH 100 HDPECZ 90661A5 1.000 ± 0.002 W 99.99+ 2% NH4OH 500 HDPECZ 906610A1 10.00 ± 0.02 W 99.99+ 2% NH4OH 100 HDPECZ 90671N1 Yttrium Y 1.000 ± 0.002 Y2O3 99.999 2% HNO3 100 HDPECZ 906710N1 10.00 ± 0.02 Y2O3 99.999 2% HNO3 100 HDPECZ 90681N1 Ytterbium Yb 1.000 ± 0.002 Yb2O3 99.99 2% HNO3 100 HDPECZ 906810N1 10.00 ± 0.02 Yb2O3 99.99 2% HNO3 100 HDPECZ 90691N1 Zinc Zn 1.000 ± 0.002 Zn 99.999 2% HNO3 100 HDPECZ 90691N5 1.000 ± 0.002 Zn 99.999 2% HNO3 500 HDPECZ 906910N1 10.00 ± 0.02 Zn 99.999 2% HNO3 100 HDPECZ 90691C1 1.000 ± 0.002 Zn 99.999 2% HCl 100 HDPECZ 90691C5 1.000 ± 0.002 Zn 99.999 2% HCl 500 HDPECZ 906910C1 10.00 ± 0.02 Zn 99.999 5% HCl 100 HDPECZ 90701FN1 Zirconium Zr 1.000 ± 0.002 Zr 99.98 1% HF + 5% HNO3 100 HDPECZ 907010FN1 10.00 ± 0.02 Zr 99.98 1% HF + 5% HNO3 100 HDPE

14

5. Primary Multi elements CRM ASTASOL®, 100 ml for ICP, AAS, Ref Catal. N°

Elements Elements

Concentration (mg/l)Concentration (mg/l)

Matrice (vol. %)Matrixe (vol. %)

Packing

CZ 9081 MC1(M0011) a

K,Li,Na 1000 ± 2 (each) 2% HCl HPDE

CZ 9082 MN1(M0021) a

Ba,Ca,Mg,Sr 1000 ± 2 (each) 2% HNO3 HPDE

CZ 9083 MC1(M0031)a,b

Ca,K,Mg,Na Ca 100 ± 0.2, K 150 ± 0.3,Mg 20 ± 0.04, Na 3300 ± 6.6

1% HCl HPDE

CZ 9084 MN1(M0041) a

Co,Cr,Cu,Fe, Mn,Ni,V 500 ± 1 (each) 5% HNO3 HPDE

CZ 9085 MCN1(M0051)a,b,c

As,Be,Cd, Co,Cr,Cu,Hg,Mo,Ni, Pb,V,Zn

As 25 ± 0.05, Be 10 ± 0.02 Cd 2 ± 0.004, Co 50 ± 0.1,Cr 100 ± 0.2, Cu 50 ± 0.1, Hg 2 ± 0.004, Mo 10 ± 0.02,Ni 100 ± 0.2, Pb 200 ± 0.4,V 200 ± 0.4, Zn 100 ± 0.2

5% aquaregia

HPDE

CZ 9086 MN1(M0061)a,d,e

Al,B,Ba,Be, Cd,Co,Cr,Cu,Fe,Mn,Ni,Pb, Se,Tl,V,Zn

Al 100 ± 0.2, B 20 ± 0.04, Ba 5 ± 0.01, Be 2 ± 0.004,Cd 20 ± 0.04, Co 50 ± 0.1, Cr 20 ± 0.04, Cu 20 ± 0.04,Fe 20 ± 0.04, Mn 10 ± 0.02, Ni 50 ± 0.1, Pb 200 ± 0.4,Se 5 ± 0.01, Tl 100 ± 02, V 50 ± 01, Zn 50 ± 0.1

10% HNO3 GLASS

CZ 9087 MC1(M0071)a,e

Au,Ir,Os,Pd, Pt,Rh,Ru 100 ± 0.2 (each) 20% HCl GLASS

CZ 9088 MC1(M0081)a,e

Ce,Dy,Er,Eu, Gd,Ho,La,Lu,Nd,Pr,Sc,Sm, Tb,Tm,Y,Yb

Ce 100 ± 0.2, Dy 20 ± 0.04, Er 20 ± 0.04, Eu 20 ± 0.04,Gd 20 ± 0.04, Ho 20 ± 0.04, La 100 ± 0.2, Lu 20 ± 0.04,Nd 100 ± 0.2, Pr 100 ± 0.2, Sc 20 ± 0.04, Sm 20 ± 0.04,Tb 20 ± 0.04, Tm 20 ± 0.04, Y 20 ± 0.04, Yb 20 ± 0.04

5% HNO3 HPDE

CZ 9089 MN1(M0091)a

Cd,Co,Cu,Cr, Mn,Ni,Pb,V,Zn 100 ± 0.2 (each) 5% HNO3 HPDE

CZ 9090 MN1(M00101)a,f

Al,As,B,Ba, Be,Bi,Ca,Cd,Co,Cr,Cu,Fe,K, Li,Mg,Mn,Mo,Na,Ni,Pb, Se,Sr,Ti,Tl,V,Zn

100 ± 0.2 (each) 5% HNO3 HPDE

CZ 9091 MN1(M0111)a,

Ca,K,Mg,Na 1000± 2 each 2% HNO3 HPDE

CZ 9092 MN1(M0121)a

Al,B,Ba,Ca,Cd,Co,Cr,Cu,Fe,Mg,Mn,Ni,Pb,Zn

1000± 2 each 10% HNO3 HPDE

CZ 9093 MN1(M0131)a

Al,Ba,Ca,Cd,Co,Cr,Cu,Fe,Mg,Mn,Na,Ni,Pb,Ti,Zn

100± 0.2each 5% HNO3 HPDE

CZ 9094 MFN1(M0141)a

As,Be,Ca,Cd, Co,Cr,Cu,Fe,Li,Mg,Mn,Mo,Ni,P,Pb,Sb,Se,Sn,Sr,Ti,Tl,V,Zn

100± 0.2 each 5% HNO30.2 % HF

HPDE

CZ 9095 MN1(M0151)g

Al,Be,Bi,Cd,Co,Cu,Fe,Li,Mn,Mo,Ni,Pb,Si,Sr,V,W,Zn,Zr

100± 0.2 each 5% HNO3 HPDE

CZ 9096 MN1(M00161)g

As,Sb,Se,Sn 100± 0.2 each 5% HNO3 HPDE

CZ 9097 MN1(M00171)g

Ca,K,Mg,Na,P,S 100± 0.2 each 1% HNO3 HPDE

CZ 9098 MN1(M00181)h

As,Be,Ca,Cd,Co,Cr,Cu,Fe,Mg,Mn,Mo,Ni,Pb,Sb,Se,Ti,Tl,V,Zn

100± 0.2 each 5% HNO3 HPDE

CZ 9099 MN1(M00191)g

Ag,Hg 100± 0.2 each 5% HNO3 HPDE

CZ 90100 MH1(M0201)e

Br-, Cl-, F-, 1000± 2 each H2O HPDE

CZ 90101 MH1 NO3-, PO4-, SO42-, 1000± 2 each H2O HPDE

15

(M0211)e

CZ 90102 MH1(M0221)e

Br-, Cl-, F-, NO3-, PO4-, SO42-, 100± 0.2 each H2O HPDE

CZ 90103 MH1(M0231)e

Ba,Ca,K,Li,Mg,Na,NH4+,Sr 100± 0.2 each H2O HPDE

a) Original trade nameb) Blood serum matrix.c) Recommended for the determination of toxic elements in soils..d) Recommended for the evaluation of the waste leaches .e) Shelf life 12 monthf) Ag and Sb were deleted (compared to the orinal M010) in order to increase the long term stability.g) Recommended to use in water analysis according EN ISO 11885: 1997 (The concentrate to be diluted 10x).h) Recommended for EPA method No. 200.7 and 600/482-055

.Other multi element calibration standard solutions can be prepared on request.

16

6. Solutions working standards mono element ASTASOL®,Concentration: 1.000 ± 0.005g/lThese standards are manufactured with the same rigor that the CRM standards. They can be used like standards ofverification and work. They are equivalent and very often superior to all standards non CRMS, available on the market,(others that CRM ex NIST, BCR, ANALYTIKA).

AVERTISSEMENT : It is recommend to verify the real level of certification of other standards provided by othersuppliers to avoid disagreement at certification audit time (type GLP, Cofrac etc)

Certificate of qualityA S T A S O L® Calibration solution

ElementCatalogue order number :Concentration :Matrix :Starting material :Quality control of nominal composition of thecalibration solution and traceability

Packing material :

Shelf - life : .

AgS 0011.0 t 0.005 g/l at 20 °C2 % HN03 (v/v)Ag 99.99%By comparing the concentration of this calibration solution with thatof an independent internal calibration solution traceable to CzechCRM CZ 9001(1 N)

500 ml amber glass bottle decontaminated by leaching with acids.

Stability and accuracy is guaranteed until the date shown at the labelprovided that the solution is tightly capped and stored under normallaboratory conditions

Certificate valid till : Batch numberANALYTIKA® IA.Ke Klicovu 2x/816190 00 Praha 9Czech Republic Signed by: : ..............................................phone/fax: 0420-2-858 96 16 Managing Director

Packing 500 ml

Order No. DescriptionElement

Concentration(g/l)

Starting material and itspurity

Matrix (%,v/v) Packingmaterial

S001 Ag Argent Silver 1.000 ± 0.005 Ag 99.99 2% HNO3 glassS002 Al Aluminium Aluminium 1.000 ± 0.005 Al 99.995 5% HCl HDPES003 As Arsenic Arsenic 1.000 ± 0.005 As 99.999 2% HNO3 HDPES005 B Bore Boron 1.000 ± 0.005 H3BO3 99.99 H2O HDPES006 Ba Barium Barium 1.000 ± 0.005 BaCO3 99.99 2% HNO3 HDPES008 Bi Bismuth Bismuth 1.000 ± 0.005 Bi 99.999 5% HNO3 HDPES009 Ca Calcium Calcium 1.000 ± 0.005 CaCO3 99.99 2% HNO3 HDPES010 Cd Cadmium Cadmium 1.000 ± 0.005 Cd 99.999 2% HNO3 HDPES012 Co Cobalt Cobalt 1.000 ± 0.005 Co 99.99 2% HNO3 HDPES013 Cr Chrome Chromium 1.000 ± 0.005 Cr(NO3)3 .9H2O 99.99+ 2% HNO3 HDPES015 Cu Cuivre Copper 1.000 ± 0.005 Cu 99.999 2% HNO3 HDPES019 Fe Fer Iron 1.000 ± 0.005 Fe 99.995 2% HNO3 HDPES024 Hg Mercure Mercury 1.000 ± 0.005 Hg 99.999+ 2% HNO3 glassS028 K Potassium Potassium 1.000 ± 0.005 KNO3 99.99 H2O HDPES030 Li Lithium Lithium 1.000 ± 0.005 Li2CO3 99.99 2% HNO3 HDPES032 Mg Magnesium Magnesium 1.000 ± 0.005 Mg 99.99 2% HNO3 HDPES033 Mn Manganese Manganese 1.000 ± 0.005 Mn 99.98 2% HNO3 HDPES034 Mo Molybdene Molybdenum Mo 99.99 2% NH4OH HDPES035 Na Sodium Sodium 1.000 ± 0.005 NaNO3 99.99 H2O HDPES038 Ni Nickel Nickel 1.000 ± 0.005 Ni 99.999 2% HNO3 HDPES040 P Phosphore Phosphorus 1.000 ± 0.005 NH4H2PO4 99.999 0.05% H2SO4 HDPES041 Pb Plomb Lead 1.000 ± 0.005 Pb 99.999 2% HNO3 HDPES050 Sb Antimoine Antimony 1.000 ± 0.005 Sb 99.999 10% HCl HDPE

17

S051 Se Selenium Selenium 1.000 ± 0.005 Se 99.999 2% HNO3 HDPES053 Si Silice Silicon 1.000 ± 0.005 Na2SiO3 99.9 H2O HDPES055 Sn Etain Tin 1.000 ± 0.005 Sn 99.999 10% HCl HDPES056 Sr Strontium Strontium 1.000 ± 0.005 SrCO3 99.99 2% HNO3 HDPES061 Ti Titanium Titanium 1.000 ± 0.005 Ti 99.98 1% HF + 5% NO3 HDPES062* Tl Thallium Thallium 1.000 ± 0.005 TlNO3 99.995 2% HNO3 HDPES065 V Vanadium Vanadium 1.000 ± 0.005 NH4VO3 99.95+ 2% HNO3 HDPES066 W Tungsten Tungsten 1.000 ± 0.005 W 99.99+ 2% NH4OH HDPES069 Zn Zinc Zinc 1.000 ± 0.005 Zn 99.995 2% HNO3 HDPE

*) Delivery time 3-4 weeksOther standard solutions delivered from the stock

Packing 100 mll

Order No. DescriptionElement

Concentration(g/l)

Starting material and itspurity

Matrix (%,v/v) Packingmaterial

S0001 Ag Argent Silver 1.000 ± 0.005 Ag 99.99 2% HNO3 glassS0002 Al Aluminium Aluminium 1.000 ± 0.005 Al 99.995 5% HCl HDPES0003 As Arsenic Arsenic 1.000 ± 0.005 As 99.999 2% HNO3 HDPES0005 B Bore Boron 1.000 ± 0.005 H3BO3 99.99 H2O HDPES0006 Ba Barium Barium 1.000 ± 0.005 BaCO3 99.99 2% HNO3 HDPES0008 Bi Bismuth Bismuth 1.000 ± 0.005 Bi 99.999 5% HNO3 HDPES0009 Ca Calcium Calcium 1.000 ± 0.005 CaCO3 99.99 2% HNO3 HDPES0010 Cd Cadmium Cadmium 1.000 ± 0.005 Cd 99.999 2% HNO3 HDPES0012 Co Cobalt Cobalt 1.000 ± 0.005 Co 99.99 2% HNO3 HDPES0013 Cr Chrome Chromium 1.000 ± 0.005 Cr(NO3)3 .9H2O 99.99+ 2% HNO3 HDPES0015 Cu Cuivre Copper 1.000 ± 0.005 Cu 99.999 2% HNO3 HDPES0019 Fe Fer Iron 1.000 ± 0.005 Fe 99.995 2% HNO3 HDPES0024 Hg Mercure Mercury 1.000 ± 0.005 Hg 99.999+ 2% HNO3 glassS0028 K Potassium Potassium 1.000 ± 0.005 KNO3 99.99 H2O HDPES0030 Li Lithium Lithium 1.000 ± 0.005 Li2CO3 99.99 2% HNO3 HDPES0032 Mg Magnesium Magnesium 1.000 ± 0.005 Mg 99.99 2% HNO3 HDPES0033 Mn Manganese Manganese 1.000 ± 0.005 Mn 99.98 2% HNO3 HDPES0034 Mo Molybdene Molybdenum 1.000 ± 0.005 Mo 99.99 2% NH4OH HDPES0035 Na Sodium Sodium 1.000 ± 0.005 NaNO3 99.99 H2O HDPES0038 Ni Nickel Nickel 1.000 ± 0.005 Ni 99.999 2% HNO3 HDPES0040 P Phosphore Phosphorus 1.000 ± 0.005 NH4H2PO4 99.999 0.05% H2SO4 HDPES0041 Pb Plomb Lead 1.000 ± 0.005 Pb 99.999 2% HNO3 HDPES0050 Sb Antimoine Antimony 1.000 ± 0.005 Sb 99.999 10% HCl HDPES0051 Se Selenium Selenium 1.000 ± 0.005 Se 99.999 2% HNO3 HDPES0053 Si Silice Silicon 1.000 ± 0.005 Na2SiO3 99.9 H2O HDPES0055 Sn Etain Tin 1.000 ± 0.005 Sn 99.999 10% HCl HDPES0056 Sr Strontium Strontium 1.000 ± 0.005 SrCO3 99.99 2% HNO3 HDPES0061 Ti Titanium Titanium 1.000 ± 0.005 Ti 99.98 1% HF + 5% NO3 HDPES0062* Tl Thallium Thallium 1.000 ± 0.005 TlNO3 99.995 2% HNO3 HDPES0065 V Vanadium Vanadium 1.000 ± 0.005 NH4VO3 99.95+ 2% HNO3 HDPES0066 W Tungsten Tungsten 1.000 ± 0.005 W 99.99+ 2% NH4OH HDPES0069 Zn Zinc Zinc 1.000 ± 0.005 Zn 99.995 2% HNO3 HDPE

*) Delivery time 3-4 weeksOther standard solutions delivered from the stock

7. Multi-elements Standards Solutions ASTASOL® -MIXWe can manufacture, on request all standards solution, following your specifications. In this case a minimum quantity ofmanufacture is imposed (in general 2 liters). The delivery takes place in the conditioning of your choice and we can assuresome contracts with rhythmic deliveries. The tariffs are provided on request

Win a precious time while achieving savings.Interrogate us, we are very competitive

18

8. Mono element Standards Solutions in oil ASTASOL®-OSFor analysis in non aqueous media. Concentration: 1.000 ± 0.005 g/kg

The solutions ASTASOL-OS are manufactured from concentrated oil organo metallic (CONOSTAN) dilute in standard oil.Thesis standards are dedicated heart analytic applications in non aqueous environment (i.e. analysis of oil and oil products,used lubricants, determination of the additives in oil, etc.).

IMPORTANT : ask for our original CONOSTAN catalog

Référence Reference Elément Element Qté (g) Qty (g)SOS001 Al Aluminium Aluminium 100 HSOS002 Ba Barium Barium 100 HSOS003 Ca Calcium Calcium 100 HSOS004 Cd Cadmium Cadmium 100 HSOS005 Cr Chrome Chromium 100 HSOS006 Cu Cuivre Copper 100 HSOS007 Fe Fer Iron 100 HSOS008 K Potassium Potassium 100 HSOS009 Mg Magnésium Magnesium 100 HSOS010 Mn Manganèse Manganese 100 HSOS011 Na Sodium Sodium 100 HSOS012 Ni Nickel Nickel 100 HSOS013 P Phosphore Phosphorus 100 HSOS014 Pb Plomb Lead 100 HSOS015 Si Silice Silicon 100 HSOS016 Sn Etain Tin 100 HSOS017 V Vanadium Vanadium 100 HSOS018 Zn Zinc Zinc 100 HSOS019 Ag Argent Silver 100 HSOS020 B Bore Boron 100 HSOS021 Be Béryllium Beryllium 100 HSOS022 Mo Molybdène Molybdenum 100 HSOS023 Sb Antimoine Antimony 100 HSOS024 Sc Scandium Scandium 100 HSOS025 Ti Titanium Titanium 100 HSOS100 Huile de base Base oil 1000 H

a) Le produit de départ est une huile organométallique concentrée.Starting material is an organometallic oil concentrate

b) H - bouteille HDPE ambrée

9. Multielement Standarsd Solutions ASTASOL®-OS MIX on requestWe can manufacture, on request all standards solution, following your specifications. In this case a minimum quantity ofmanufacture is imposed. The delivery takes place in the conditioning of your choice and we can assure some contracts withrhythmic deliveries. The tariffs are provided on request

Win a precious time while achieving savings.Interrogate us, we are very competitive

19

IC – IONS CHROMATOGRAPHY

These certified reference materials are prepared from the highest purity starting primary substances (typically betterthan 99.99%) and ultrapure demineralized water (conductivity ≤ 0.5µS/cm). They are filtered through membraneultrafiltres (0.45µm) to prevent clogging of chromatographic columns. Some of these solutions are practicallyidentical with those listed for the particular analyte in previous tables. A suffix “IC“ added to their catalogue numbershows that they are filtered and recommended for use in ion chromatography. The solutions are prepared in water or0.005% (v/v) HNO3 matrix with a fungicide additive to ensure their long-term stability. Packing size is 100 ml.

10. Solutions Primary Standards 1g/l CRM ASTASOL®, for Ions Chromatography

Order No. DescriptionElement Concentration (g/l)Starting material and itspurity

Matrix (%,v/v) Volumeml

Packingmaterial

CZ90061H1IC Barium Ba 1.000 ± 0.002 Ba(NO3)2 99.995 H2O 100 HDPECZ90091H1IC Calcium Ca 1.000 ± 0.002 Ca(NO3)2 99.99 H2O 100 HDPECZ90141H1IC Cesium Cs 1.000 ± 0.002 CsNO3 99.999 H2O 100 HDPECZ90281N1IC Potassium K 1.000 ± 0.002 KNO3 99.995 0.005% HNO3 100 HDPECZ90301N1IC Lithium Li 1.000 ± 0.002 LiNO3 99.997 0.0005 HNO3 100 HDPECZ90321H1IC Magnésium Mg 1.000 ± 0.002 Mg(NO3)2 99.995 H2O 100 HDPECZ90351N1IC Sodium Na 1.000 ± 0.002 NaNO3 99.999 0.005% HNO3 100 HDPECZ90451N1IC Rb 1.000 ± 0.002 RbNO3 99.995 0.005% HNO3 100 HDPECZ90561N1IC Strotium Sr 1.000 ± 0.002 Sr(NO3)2 99.995 0.005% HNO3 100 HDPECZ 90711H1 Bromide Br- 1.000 ± 0.002 KBr 99.99 H2O 100 HDPECZ 907110H1 10.00 ± 0.02 KBr 99.99 H2O 100 HDPECZ 90721H1 Chloride Cl- 1.000 ± 0.002 KCl 99.99 H2O 100 HDPECZ 90721H5 1.000 ± 0.002 KCl 99.99 H2O 500 HDPECZ 907210H1 10.00 ± 0.02 KCl 99.99 H2O 100 HDPECZ 90731H1 Fluoride F- 1.000 ± 0.002 NaF 99.98 H2O 100 HDPECZ 90731H5 1.000 ± 0.002 NaF 99.98 H2O 500 HDPECZ 907310H1 10.00 ± 0.02 NaF 99.98 H2O 100 HDPECZ 90741H1 Iodide I- 1.000 ± 0.002 KI 99.997 H2O 100 HDPECZ 907410H1 10.00 ± 0.02 KI 99.997 H2O 100 HDPECZ 90751H1 Nitrite NO2- 1.000 ± 0.002 NaNO2 99.99 H2O 100 HDPECZ 90751H5 1.000 ± 0.002 NaNO2 99.99 H2O 500 HDPECZ 907510H1 10.00 ± 0.02 NaNO2 99.99 H2O 100 HDPECZ 90761H1 Nitrate NO3- 1.000 ± 0.002 NH4NO3 99.999 H2O 100 HDPECZ 90761H5 1.000 ± 0.002 NH4NO3 99.999 H2O 500 HDPECZ 907610H1 10.00 ± 0.02 NH4NO3 99.999 H2O 100 HDPECZ 90771H1 Phosphate PO43- 1.000 ± 0.002 NH4H2PO4 99.999 H2O 100 HDPECZ 90771H5 1.000 ± 0.002 NH4H2PO4 99.999 H2O 500 HDPECZ 907710H1 10.00 ± 0.02 NH4H2PO4 99.999 H2O 100 HDPECZ 90781H1 Sulphate SO42- 1.000 ± 0.002 (NH4)2SO4 99.999 H2O 100 HDPECZ 90781H5 1.000 ± 0.002 (NH4)2SO4 99.999 H2O 500 HDPECZ 907810H1 10.00 ± 0.02 (NH4)2SO4 99.999 H2O 100 HDPECZ 90791H1 Chromium6+ Cr6+ 1.000 ± 0.002 K2Cr2O7 99.997 H2O 100 HDPECZ 90791H5 1.000 ± 0.002 K2Cr2O7 99.997 H2O 500 HDPECZ 907910H1 10.00 ± 0.02 K2Cr2O7 99.997 H2O 100 HDPECZ 90801H1 Ammonium NH4+ 1.000 ± 0.002 NH4Cl 99.998 H2O 100 HDPECZ 90801H5 1.000 ± 0.002 NH4Cl 99.998 H2O 500 HDPECZ 908010H1 10.00 ± 0.02 NH4Cl 99.998 H2O 100 HDPE

11. Primary Multi element CRM solution ASTASOL®, 100 ml for Ion Chomatography. Réf Element Concentration (mg/l) Matrice (vol. %) PackageCZ9100MH1IC Br-, Cl-, F- 1000 ± 2 (each) H2O HDPECZ9101MH1IC NO3-, PO43-, SO42- 1000 ± 2 (each) H2O HDPECZ9102MH1IC Br-, Cl-, F-, NO3-

PO43-, SO42-100 ± 0.2 (each) H2O HDPE

CZ9103MH1IC Ba, Ca, K, Li, Mg, Na,NH4+, Sr

100 ± 0.2 (each) H2O HDPE

CZ9104MH1IC* NH4+- N, NO3- - N,PO43- - P, SO42- - S

100 ± 0.2 (each) H2O HDPE

20

12. Solutions Secondary Standards for Ion chromatography ASTASOL®,These standards are manufactured with the same rigor that the CRM standards. They can be used like standards ofverification and work. They are equivalent and very often superior to all standards non CRMS, available on the market,(others that CRM ex NIST, BCR, ANALYTIKA).

AVERTISSEMENT : It is recommend to verify the real level of certification of other standards provided by othersuppliers to avoid disagreement at certification audit time (type GLP, Cofrac etc)

Packing 500 ml concentration: 1.000 ± 0.005g/l

Order No. DescriptionElementConcentration(g/l)

Starting material and itspurity

Matrix(%,v/v)

Packingmaterial

A002 Cl- Chloride 1.000 ± 0.005 KCl 99.99 H2O HDPEA005 F- Fluoride 1.000 ± 0.005 NaF 99.98 H2O HDPEA007 NO2- Nitrite 1.000 ± 0.005 NaNO2 99.99 H2O HDPEA008 NO3- Nitrate 1.000 ± 0.005 NH4NO3 99.999 H2O HDPEA009 PO43- Phosphate 1.000 ± 0.005 NH4H2PO4 99.999 H2O HDPEA011 SO42- Sulphate 1.000 ± 0.005 (NH4)2SO4 99.999 H2O HDPEC001 Cr6+ Chromium6+ 1.000 ± 0.005 K2Cr2O7 99.997 H2O HDPEC002 NH4+ Ammonium 1.000 ± 0.005 NH4Cl 99.998 H2O HDPE

OIC001 Formate, HCOO- 1.000 ± 0.01 HCOONH4 99.0 H2O HDPEOIC002 Acetate, CH3COO- 1.000 ± 0.005 CH3COONH4 99, 99 H2O HDPEOIC003 Oxalate, (COO)22- 1.000 ± 0.005 (COO)2(NH4)2 ·H2O 99.99 H2O HDPEOIC004 Tartrate,

(CHOH)2(COO)22-1.000 ± 0.01 (CHOH)2(COO)2(NH4) 99.0 H2O HDPE

13. Eluants (concentrate) for IC Catal. N° Concentration (mg/l) Volume ml packing

IC-CON 1(0.25M Na2CO3)

Concentrate to make 5l0.005M Na2CO3

100 HDPE

IC-CON 2(0.25M NaHCO3)

Concentrate to make 5l0.005M NaHCO3

100 HDPE

IC-CON 3(0.125M Na2CO3+ 0.125M NaHCO3)

Concentrate to make 5l .0.0025M Na2CO3 +0.0025M NaHCO3

100 HDPE

IC-CON 4(0.25M HCl)

Concentrate to make 5l0.005M HCl

100

*Dilute to the volume (100 ml to 5 l) quantitatively with a demineralised water to get 5 l of a fresh mobile phase

14. Certified calibration Solutions CRM for détermination of organic et inorganiccarbon*.

Order No. DescriptionAnalyte Concentration (g/l)Matériau de base et sapureté

Matrix(%,v/v) Volume ml

Packingmaterial

CZ 91041H5(TIC1H5)

Cinorg.(TIC) 1.000 ± 0.002 Na2CO3 99.999NaHCO3 99.99+

1: 1

H2O 500 HDPE

CZ91051H5(TOC1H5)

Corg (TOC) 1.000 ± 0.002 Potassiumhydrogenphtalate 99.99+

H2O 500 HDPE

CZ91061H5(TIOCH5)

Cinorg+CorgTIC+TOC 1: 1

1.000 ± 0.002 H2O 500 HDPE

* For use with EN 1484-43

21

Auxiliary ReagentsThe offer covers the most popular support reagents such as deionizers and releasing agents (for flame AAS) and matrixmodifiers (for electrothermal AAS). All these reagents are prepared from starting materials of the highest available purity.

15. Matrix modifier, Desioniseur, « releasing agents »Référence. Agent Starting material Matrix Volume

concentration (g/l) And putrity (vol.) (ml)V001 CsCl 25 CsCl 99,997 H2O 500 HV002 KCl 25 KCl 99.999 H2O 500 HV003 LaCl3 25 La2O3 99.999 2% HCl 500 HV004 AlCl3 25 Al 99.999 2% HCl 500 HV0041a CsCl 5 +

Al(NO3)2.9H2O5

25CsCl 99.997Al 99.999

H2O 250 H

V0042b CsCl 10 +La(LaCl3)

10100

CsCl 99.997La2O3 99.999

2% HCl 250 H

V005 Pd(NO3)2 2 Pd 99,999% 1% HNO3 50 GV0051 Pd 10 Pd 99.999 5% HNO3 25 GV006 Mg(NO3)2 2 Mg(NO3)2 . 6H2O 99,9995% H2O 100 GV0061 Mg 10 Mg (NO3)2·6H2O 99.998 0, 2% HNO3 25 HV007c NH4H2PO4 200 NH4H2PO4 99.999 H2O 50 HV008c Ascorbic acid Ascorbic acid 99+ H2O 50 HV009 Ni(NO3)2 10 Ni(NO3)2·6H2O 99.998 1% HNO3 50 H

V0091 Ni(NO3)2 50 Ni(NO3)2·6H2O 99.998 1% HNO3 25 HV010 NH4NO3 50 NH4NO3 99.999 1% HNO3 50 HV011 Ca(NO3)2 50 Ca(NO3)2·4H2O 99.999 1% HNO3 25 Ha) Spectroscopic buffer by Schuhknecht and Schinkelb) Spectroscopic buffer by Schinkelc) Solid material ready to use after dilution to 50 ml with deionized waterd) H-amber HDPE bottle, G-amber glass bottle16. Mineral acids of extra high purity (with certificate of guarantee) The most frequently used mineral acids are offered in very high purity produced by double subboiling distillation of thepurified starting material ( trade name ANALPURE SD ). This results in most metallic impurities being reduced to ppbranges. All acids are accompanied with the certificate of guarantee based on the results from ultratrace laboratory wheremore than 60 trace elements are determined by ICP - OES and ICP - MS techniques. The acids are delivered in specialbottles (long - term leached borosilicate glass or modified HDPE) which ensure minimum contamination of the acid from thematerial of the bottle.

Reference Acids and Trade name Volumeconcentration (ml)

SAc 0031b HCl 35% Anal pure SD 1000 HSAc 0061b HNO3 68% Anal pure SD 1000 GSAc 0091b HF 48% Anal pure SD 1000 HSAc 0121b H2SO4 94% Ultra pure 1000 GH – HDPE Bottle G - Glass Bottle

SAc 0031b Chlorydric Acid 35% Anal pure S.D.Contents min. 35 % Cd (Cadmium) < 1 ppb Na (Sodium) < 20 ppbBr- < 50 ppm Co (Cobalt) < 1 ppb Ni (Nickel) < 1 ppbPO43- < 0,02 ppm Cr (Chromium) < 1 ppb Pb (Plomb) < 1 ppbSO42- < 0,5 ppm Cu (Cuivre) < 1 ppb Se (Selenium) < 1 ppbAg (Argent) < 1 ppb Fe (Fer) < 10 ppb Sn (Etain) < 1 ppbAl (Aluminium) < 5 ppb Hg (Mercure) < 1 ppb Sr (Strontium) < 1 ppbAs (Arsenic) < 1 ppb K (Potassium) < 10 ppb Ti (Titane) < 1 ppbBa (Barium) < 1 ppb Li (Lithium) < 1 ppb Tl (Thallium) < 1 ppbBe (Beryllium) < 1 ppb Mg (Magnesium) < 5 ppb V (Vanadium) < 1 ppbBi (Bismuth) < 1 ppb Mn (Manganèse) < 1 ppb Zn (Zinc) < 2 ppbCa (Calcium) < 20 ppb Mo (Molybdenum) < 1 ppb

22

SAc 0061b Nitric Acid 65% Anal pure S.D.Contents min. 65 % Cd (Cadmium) < 1 ppb Ni (Nickel) < 1 ppbCl- < 0,05 ppm Co (Cobalt) < 1 ppb Mo (Molybdenum) < 1 ppbPO43- < 0,1 ppm Cr (Chromium) < 5 ppb Pb (Plomb) < 1 ppbSO42- < 0,25 ppm Cu (Cuivre) < 1 ppb Se (Selenium) < 1 ppbAg (Argent) < 1 ppb Fe (Fer) < 10 ppb Sn (Etain) < 1 ppbAl (Aluminium) < 1 ppb Hg (Mercure) < 1 ppb Sr (Strontium) < 1 ppbAs (Arsenic) < 1 ppb K (Potassium) < 10 ppb Ti (Titane) < 1 ppbBa (Barium) < 1 ppb Li (Lithium) < 1 ppb Tl (Thallium) < 1 ppbBe (Beryllium) < 1 ppb Mg (Magnesium) < 5 ppb V (Vanadium) < 1 ppbBi (Bismuth) < 1 ppb Mn (Manganese) < 1 ppb Zn (Zinc) < 5 ppbCa (Calcium) < 20 ppb Na (Sodium) < 20 ppb

SAc0091b Fluorhydric Acid 48% Analpure S.D.Contents min. 48 % Cd (Cadmium)

23

18. High purity metals

Metal Purety FormeAluminium 99.995 % Al4N5 ingots, rods, wires, foilsAluminium 99.999 % Al5N ingots, rods, wires, foilsAluminium 99.9995 % Al5N5 ingots, rods, wires, foilsAntimoine 99.995 % Sb4N5 ingotsAntimoine 99.999 % Sb5N ingotsBismuth 99.999 % Bi5N ingots, shotCadmium 99.999 % Cd5N ingots, rods, wires, foilsCadmium 99.9995 % Cd5N5 ingots, rods, wires, foilsCadmium 99.9999 % Cd6N ingots, rods, wires, foilsCuivre 99.999 % Cu5N ingots, rods, wires, foilsPlomb 99.999 % Pb5N ingots, rods, wires, foils, shotTelurium 99.999 % Te5N ingots, piecesTelurium 99.9999 % Te6N ingots, piecesEtain 99.999 % Sn5N ingots, rods, wires, foils, shotZinc 99.998 % Zn4N8 ingots, rods, wires, foils, shotIndium 99.999 % In5N ingots, rods, wires, foils, shotIndium 99.9995 % In5N5 ingots, rods, wires, foils, shotIndium 99.9999 % In6N ingots, rods, wires, foils, shotPricelist on request

Laboratory packing:Reference Metal and purety**) Forme Quantity (g)Me 001 Aluminium,Al 99.999% turnings 50 g

100 gMe 002 Aluminium,Al 99.9995% turnings 50 g

100 gMe 003 Antimoine 99.999% pieces, shot 50 g

100 gMe 004 Bismuth,Bi 99.999% turnings 50 g

100 gMe 005 Cadmium,Cd 99.999% turnings 50 g

100 gMe 006 Cadmium,Cd 99.9995% turnings 50 g

100 gMe 007 Cuivre,Cu 99.999% turnings 50 g

100 gMe 008 Plomb,Pb 99.999% turnings 50 g

100 gMe 009 Tellurium,Te 99.999% pieces 50 g

100 gMe 010 Etain,Sn 99.999% turnings 50 g

100 gMe 011 Zinc,Zn 99.998% turnings 50 g

100 g*) Analysis Certificat and individuel impurity list included**) Basic Metal

24

CERTIFIED REFERENCE MATERIAL (Soils)

A production of matrix certified reference materials (CRM)and laboratory control materials (LCM) is one of our the mostrapidly developing activities during last several years. Wecooperate with several recognised European manufacturersand distributors as well as with several experienced localsubcontractors and laboratories accredited according to ISO9001 and EN 45001/45011, respectively. The productionstrictly follows relevant ISO requirements postulated in ISOGuides 25, 30-35, ISO/REMCO N 514 and other documents.In 1995, we introduced on the market a set of four CRMs ofsoils certified for total element contents and for contents ofelement extractable fractions in aqua regia, cold 2 M nitricacid and boiling 2 M nitric acid (see further in this catalogue).At present, 4 other CRMs are in preparation.

A great attention is paid to the rapid development ofLCMs, i.e. low-cost RM to be used by routine analyticallaboratories for regular checking of their analytical equipment(e.g. for setting-up control charts), for proficiency testing andother applications. We have on stock (in bulk) a wide range offully processed, homogenized and radiationally sterilizedmaterials (including homogeneity and stability testing), suchas e.g. river and lake sediments, sewage sludge, soils,biological materials (strawberry leaves, orange peel, greenalgae), food materials (milled onion) etc. These materials canbe rapidly finalized, bottled and packed according to thecustomer’s requirements.

We also distribute reference materials produced byother Czech producers and certified by the CzechMetrological Institute. A certified reference material No. 6002(Hazardous Elements in Horse Liver) is shown as anexample.

Référence Nom de vente QuantitéCRM 7001 Light Sandy Soil (normal analyte levels) 80 gCRM 7002 Light Sandy Soil (elevated analyte levels) 80 gCRM 7003 Clay Loam Soil (normal analyte levels) 80 gCRM 7004 Loam (elevated analyte levels) 80 gCRM 7001-7004 Set 4x 80 g

Certified and information values of total element contents in CRM No. 7001 - 7004 (µg/g dry weight)

CRM No. 7001 No. 7002 No. 7003 No. 7004Element Mean ± Unc. N/n** Mean ± Unc. N/n** Mean ± Unc. N/n** Mean ± Unc. N/n**

As 12.3 ± 1.1 5/7 32.4 ± 1.9 8/11 16.7 ± 3.1 12/16 49.6 ± 3.0 9/12Ba 970 ± 77 4/6 987 ± 86 3/4 495 ± 28 4/6 568 ± 27 4/6Be 3.32 ± 0.26 13/17 8.77 ± 0.32 13/17 2.18 ± 0.16 14/17 4.17 ± 0.18 10/14Cd 0.32 ± 0.05 15/16 0.31 ± 0.04 13/16 0.32 ± 0.04 10/14 1.52 ± 0.15 15/19Co 9.66 ± 0.61 14/17 12.6 ± 0.9 17/20 11.5 ± 0.7 15/20 20.0 ± 1.25 14/18Cr 89.6 ± 4.2 18/23 179 ± 8 17/22 79.8 ± 6.7 17/23 82.2 ± 6.3 18/22Cu 30.8 ± 0.9 17/21 29.3 ± 0.6 7/20 29.1 ± 0.8 18/21 183 ± 5 16/2Hg 0.087 ±

0.00611/14 0.090 ± 0.012 12/14 0.096 ± 0.014 10/14 0.223 ± 0.016 10/13

Mn 540 ± 20 10/14 587 ± 37 14/16 600 ± 37 13/16 869 ± 34 9/12Ni 31.9 ± 1.6 18/21 42.0 ± 1.7 19/21 31.3 ± 1.5 18/21 33.3 ± 1.1 17/21Pb 43.8 ± 3.7 19/21 58.9 ± 4.9 18/21 33.5 ± 2.4 17/21 93.4 ± 3.4 17/20V 58.7 ± 6.3 13/18 54.9 ± 6.8 13/18 76.2 ± 6.4 13/18 126 ± 7 16/18Zn 120 ± 7 19/21 69.0 ± 7.7 13/18 81.0 ± 7.6 17/21 227 ± 7 19/21

* Mean ± Uncertainty of certified and information values are given in bold and normal figures, respectively;** Number of accepted laboratory sets/number of reported sets (after elimination of outliers from technical reasons)

25

Certified and information values of contents of conventionally defined element fractions extractable by aqua regia in CRMNo. 7001 - 7004 (µg/g dry weight)

CRM No. 7001 No. 7002 No. 7003 No. 7004Element Mean ± Unc. N/n** Mean ± Unc. N/n** Mean ± Unc. N/n** Mean ± Unc. N/n**

As 10.4 ± 1.0 15/20 26.1 ± 1. 11/15 11.6 ± 0.7 12/16 42.4 ± 2.2 13/17Ba 108 ± 9 6/6 99.1 ± 8.8 5/6 146 ± 14 5/6 217 ± 19 5/6Be 1.02 ± 0.10 18/19 2.83 ± 0.15 16/20 1.29 ± 0.13 16/19 2.69 ± 0.21 20/20Cd 0.29 ± 0.04 12/16 0.28 ± 0.03 11/15 0.32 ± 0.03 11/15 1.44 ± 0.07 17/25Co 9.15 ± 0.47 23/25 11.1 ± 0.5 23/25 10.3 ± 0.5 25/25 17.5 ± 0.9 25/25Cr 71.9 ± 5.9 26/26 147 ± 8 20/26 42.4 ± 3.6 26/26 46.3 ± 3.8 25/26Cu 28.9 ± 0.8 24/26 27.3 ± 0.7 23/26 25.4 ± 0.9 24/26 167 ± 1 16/20Hg 0.085 ±

0.0208/10 0.080 ± 0.016 6/8 0.093 ± 0.023 5/6 0.21 ± 0.04 8/10

Mn 479 ± 18 18/19 531 ± 19 16/19 529 ± 19 17/19 741 ± 36 17/19Ni 31.8 ± 1.2 24/26 40.1 ± 1.2 24/26 28.8 ± 1.2 25/26 30.4 ± 1.2 24/26Pb 24.1 ± 1.7 26/26 35.5 ± 0.9 20/26 25.2 ± 1.1 20/26 83.1 ± 2.3 25/26V 52.0 ± 3.4 18/19 44.6 ± 3.4 16/19 52.9 ± 2.7 18/19 95.1 ± 4.9 19/20Zn 108 ± 3.5 26/26 64.0 ± 1.5 23/26 69.4 ± 1.8 23/26 198 ± 6 25/26

Certified and information values of contents of conventionally defined element fractions extractable by boiling 2 mol/l HNO3in CRM No. 7001 - 7004 (µg/g dry weight)

CRM No. 7001 No. 7002 No. 7003 No. 7004Element Mean ± Unc. N/n** Mean ± Unc. N/n** Mean ± Unc. N/n** Mean ± Unc. N/n**

As 5.92 ± 0.67 8/11 15.1 ± 2.1 10/13 3.58 ± 0.75 11/13 27.1 ± 2.9 12/14Ba 76.0 ± 17.8 5/5 - - 101 ± 21 5/5 - -Be 0.71 ± 0.04 15/17 1.94 ± 0.09 15/17 0.95 ± 0.02 14/17 2.17 ± 0.06 13/17Cd 0.22 ± 0.04 18/19 0.26 ± 0.03 14/19 0.27 ± 0.04 17/19 1.44 ± 0.07 17/25Co 8.44 ± 0.65 19/19 10.2 ± 0.6 16/19 8.31 ± 0.46 18/19 12.5 ± 0.6 18/19Cr 48.5 ± 4.5 19/19 121 ± 11 18/19 23.8 ± 2.3 19/19 27.3 ±2.0 18/19Cu 24.1 ± 1.05 19/19 23.8 ± 1.1 19/19 20.6 ± 1.2 19/19 159 ± 5 16//19Hg 0.059 ±

0.0148/10 0.046 ± 0.005 10/9 0.054 ± 0.008 7/10 0.16 ± 0.03 10/10

Mn 438 ± 26 12/14 481 ± 31 12/14 476 ± 28 12/14 572 ± 35 12/14Ni 18.7 ± 1.2 19/19 33.7 ± 2.0 19/19 22.2 ± 1.1 19/19 21.4 ± 0.9 18/19Pb 23.7 ± 1.4 19/19 34.1 ± 1.8 19/19 22.7 ± 1.3 19/19 82.6 ± 1.9 14/19V .42.7 ± 4.2 16/16 37.7 ± 3.1 15/16 25.3 ± 2.8 17/17 48.9 ± 4.3 15/17Zn 97.1 ± 2.9 18/19 58.1 ± 2.2 18/19 54.2 ± 2.3 17/19 169 ± 8 18/19

Certified and information values of contents of conventionally defined element fractions extractable by cold 2 mol/l HNO3 inCRM No. 7001 - 7004 (µg/g dry weight)

CRM No. 7001 No. 7002 No. 7003 No. 7004Element Mean ± Unc. N/n** Mean ± Unc. N/n** Mean ± Unc. N/n** Mean ± Unc. N/n**

As 2.32 ± 0.36 14/18 6.12 ± 0.83 15/18 1.30 ± 0.19 13/18 16.4 ± 1.8 16/18Ba 68.0 ± 5.1 5/5 67.3 ± 6.8 5/5 93.6 ± 5.0 5/5 142 ± 10 5/5Be 0.52 ± 0.05 18/19 1.40 ± 0.11 17/20 0.69 ± 0.05 18/20 1.84 ± 0.08 16/20Cd 0.18 ± 0.02 19/23 0.21 ± 0.02 18/23 0.23 ± 0.01 17/23 1.36 ± 0.01 10/14Co 5.19 ± 0.21 21/24 6.64 ± 0.30 21/24 5.90 ± 0.25 22/24 9.42 ± 0.38 22/24Cr 23.6 ± 2.1 21/24 62.9 ± 6.1 25/25 9.06 ± 0.67 24/25 14.6 ± 1.1 25/25Cu 18.1 ± 0.5 25/25 19.8 ± 0.5 25/25 15.8 ± 0.3 24/25 137 ± 4 24/25Hg 0.052 ±

0.01215/15 0.041 ± 0.010 12/15 0.040 ± 0.009 13/15 0.094 ± 0.014 14/16

Mn 357 ± 21 14/16 425 ± 22 13/16 435 ± 19 14/16 527 ± 24 14/16Ni 10.0 ± 0.6 24/25 16.0 ± 1.4 25/25 11.9 ± 0.6 25/25 13.0 ± 0.7 24/25Pb 20.7 ± 0.6 23/25 30.6 ± 1.1 24/25 19.3 ± 0.4 19/25 71.7 ± 2.5 25/25V 21.0 ± 1.5 16/19 21.3 ± 1.7 17/19 11.4 ± 0.7 16/20 29.9 ± 2.3 19/20Zn 58.0 ± 3.0 23/25 34.2 ± 2.0 24/25 24.4 ± 0.9 21/25 119 ± 5 24/25

26

Laboratory control materials METRANAL™(LCM)

METRANALS™ are secondary reference materials (laboratory control materials) for calibration prepared foruse in a National scheme of traceability. Analyte concentrations and uncertainties were verified by severalmetrological laboratories associated in "METROCHEM" group. BCR, LGC, NIST certified reference materials(when available) or isotopic dilution-mass spectrometry were used to ensure traceability. All materials areradiationally stabilized (25 kGy).

Laboratory control material conditionnement (g)Metranal 1 – River sediment 1 80Metranal 2 – River sediment 2 40Metranal 3 – Strawberry leaf 25Metranal 6 – Sewage sludge 1 60Metranal 7 – Sewage sludge 2 40Metranal 8 – Green algae 20

METRANAL 1: River sediment 1

Analyte Total sample decomposition Aqua regia extraction*Concentration

(mg/kg)**Uncertainty(mg/kg)***

Concentration(mg/kg)**

Uncertainty(mg/kg)***

Ag 3.10 0.38 2.50 0.32As 29.0 2.0 24.1 3.2Ba 522 104 275 22Be 2.65 0.80 1.58 0.32Bi 0.72 0.14 0.69 0.14Cd 3.10 0.68 2.66 0.54Co 15.60 1.4 12.5 1.5Cr 118 12 93.0 14Cu 97.0 10 91.2 8.0Fe 28500 3800 25500 2700Hg 1.55 0.14 1.38 0.20Mn 1370 140 1330 106Mo 1.13 0.12 0.97 0.02Ni 45.0 8.2 35.4 5.0Pb 93.2 10 82.4 16.4Sb 2.52 0.50 1.73 0.34Se 1.02 0.20 0.74 0.14Sn 8.75 1.74 7.37 1.48V 73.0 10 43.2 5.6Zn 520 68 465 64

* According to DIN 38414-S7** Dry weight at 105°C*** Expanded combined uncertainty (k÷2)

27

METRANAL 2: River sediment 2, METRANAL 7: Sewage sludge 2

Analyte Metranal 2 Metranal 7Concentration

g/kg)*Uncertainty

g/kg)**Concentration

g/kg)*Uncertainty

g/kg)**Anthracene 393 128 91 44Benzo(a)anthracene 998 260 716 196Benzo(b)fluoranthene 829 228 747 234Benzo(k)fluoranthene 423 116 351 88Benzo(g,h,i)perylene 546 156 627 176Benzo(a)pyrene 742 222 588 160Dibenzo(a,h)anthracene

89 34 83 21

Fluoranthene 1995 572 1615 548Chrysene 831 234 815 134Indeno(1,2,3-cd)pyrene

585 166 582 212

Phenathrene 982 274 1000 348Pyrene 1677 424 1542 480PCB - 28 23.3 6.8 20 6PCB - 31 16.3 5.0 15 6PCB - 52 29.2 9.0 12 2PCB - 77 2 0.4PCB - 101 28.1 7.6 32 4PCB - 110 17.4 5.4 21 4PCB - 118 12.2 3.2 17 6PCB - 138 61.3 15.4 67 20PCB - 149 50.6 12.6 52 10PCB - 153 70.2 19.8 74 10PCB - 163 20.1 6.2 18 6PCB - 170 33.4 8.8 27 6PCB - 180 63.6 15.4 64 20PCB - 187 30.8 7.8 27 10PCB - 194 14.2 4.0 10 4Pentachlorbenzene 4.3 2Hexachlorobenzene 45.1 11.2 28 6O, p´- DDE 1.5 1P, p´- DDE 19.0 5.6 52 10P, p´- DDD 28.9 7.0 26 12P, p´- DDT 45.8 12.4 14 8

* Dry weight at 40°C ** Expanded combined uncertainty (k÷2)

28

METRANAL 3: Strawberry leaf, METRANAL 8: Green algae

Analyte Metranal 3 Metranal 8Concentration

(mg/kg)*Uncertainty(mg/kg)***

Concentration(mg/kg)*

Uncertainty(mg/kg)***

Al 1120 110 41 3As 0.26 0.06Ba 124 24Ca 15500 1540 1380 80Cd 0.18 0.01 0.023 0.004Co 18 1.6Cr 1.70 0.34Cu 8.68 0.76 34 1.6Fe 912 90 290 20Hg 0.038 0.08 0.017 0.01K 21200 2100Li 0.69 0.14Mg 4210 420 1580 120Mn 187 18 43 3.4Ni 2.68 0.16 0.8 0.1Pb 1.88 0.22 0.21 0.01Sr 77.0 16Zn 27.1 1.8 38 3

* Dry weight at 105°C ** Expanded combined uncertainty (k÷2)

METRANAL 6: Sewage sludge 1

Analyte Total sample decomposition Aqua regia extraction*Concentration

(mg/kg)**Uncertainty(mg/kg)***

Concentration(mg/kg)**

Uncertainty(mg/kg)***

55 4 52 4As 9.0 1 8.6 1Be 0.90 0.2 0.55 0.1Cd 6.1 0.4 6.3 0.4Co 15 2 8.2 1.4Cr 106 12 90 12Cu 340 18 376 30Hg 6.0 0.6 5.5 0.8Mn 550 30 530 40Ni 60 8 49 8Pb 104 6 100 12Sn 29 2 25 2V 38 4 22 2Zn 1220 60 1125 60

* According to DIN 38414-S7 ** Dry weight at 105°C *** Expanded combined uncertainty (k÷2)

29

Chromatography CPG

19. ASTASOL-CH: Standards Solution for chromatography

Recently, ANALYTIKA Ltd. introduced on themarket a new line of calibration standard solutionsfor chromatography in CERTAN® bottle combinesthe advantages of sealed glass ampoules andscrew capped bottles. The capillary serves as arecondensation zone for the solvent thus limitingthe loss of volatile organic solvent and reducingthe sealing surface of the inside of the cap.Together these features ensure a perfect seal andguarantee an unchanging concentration ofanalytes in the standard solution for a long time.Another advantage is easy filling and removal ofaliquots with a normal „GC“ syringe

30

20. Calibration solutions for the determination of polycyclic aromatic hydrocarbon (PAH's)Single analyte

Order number Trade name Concentration VolumeAnalyte(s) µg/ml ml

CE055 1.5M anthracene 100 CERTAN® 1.5 mlCE054 1.5M benzo(a)pyrene 100 CERTAN® 1.5 mlCE053 1.5M fluoranthene 100 CERTAN® 1.5 mlCE056 1.5M chrysene 100 CERTAN® 1.5 mlCE051 1.5A 2-methylnaphtalene 10 CERTAN® 1.5 mlCE050 4.5M naphtalene 1000 CERTAN® 4.5 mlCE052 1.5M phenanthrene 100 CERTAN® 1.5 mlCE057 1.5M pyrene 100 CERTAN® 1.5 ml

M - methanol, A - acetonitrile21. Multi analyte calibration solutions Polycyclic aromatic Hydrocarbons (PAH's)

Reference Trade name Concentration VolumeCompound) µg/ml ml

CE001 1.5A PAH MIX - 1 (WHO) CERTAN 1,5mlCE001 4.5A CERTAN 4,5ml

benzo(b)fluoranthene 20benzo(k)fluoranthene 20benzo(g,h,i)perylene 20benzo(a)pyrene 20fluoranthene 50indeno(1,2,3,c,d)pyrene 50

CE002 4.5A PAH MIX - 2 (EPA 610) CERTAN 4,5mlCE002 4.5C CERTAN 4,5ml

acenaphtene 10acenaphtylene 10anthracene 10benzo(a)anthracene 10benzo(b)fluoranthene 10benzo(k)fluoranthene 10benzo(g,h,i)perylene 10benzo(a)pyrene 10dibenzo(a,h)anthracene 10phenanthrene 10fluoranthene 10fluorene 10chrysene 10indeno(1,2,3,c,d)pyrene 10naphtalene 10pyrene 10

CE003 1.5A PAH MIX - 3 (EPA 610) CERTAN 1,5mlacenaphtene 500acenaphtylene 800anthracene 100benzo(a)anthracene 100benzo(b)fluoranthene 200benzo(k)fluoranthene 100benzo(g,h,i)peryiene 200benzo(a)pyrene 100dibenzo(a,h)anthracene 200phenanthrene 100fluoranthene 200fluorene 200chrysene 100naphtalene 500indeno(1,2,3,c,d)pyrene 100

31

pyrene 100CE004 1.5A PAH MIX - 4 CERTAN 1,5ml

benzo(a)pyrene 100fluoranthene 200

CE005 4.5T PAH MIX – 5 (EPA 610) CERTAN® 4.5 mlacenaphtene 100acenaphtylene (each)anthracenebenzo(a)anthracenebenzo(b)fluoranthenebenzo(k)fluoranthenebenzo(g, h, i)perylenebenzo(a)pyrenedibenzo(a, h)anthracenefluoranthenefluorenechryseneindeno(1, 2, 3, c, d)pyrenenaphtalenephenanthrenepyrene

CE006 1.5M PAH MIX - 6 CERTAN® 1.5 mlCE006 4.5M CERTAN® 4.5 ml

anthracene 10benzo(k)fluoranthene 5benzo(a)anthracene 10benzo(a)pyrene 10benzo(b)fluoranthene 20benzo(g, h, i)perylene 20dibenzo(a, h)anthracene 20fluoranthene 20chrysene 10indeno(1, 2, 3, c, d)pyrene 20naphtalene 40pyrene 40

I – iso-octane C – cyclohexane M – methanol A –acetonitrile

32

22. Calibration solution for determination of Polychlorinated Biphenyls (PCB'S), singleanalyteRéférence Trade name Concentration Volume

Compound µg/ml mlCE100 1.5l PCB S028 CERTAN 1,5ml

PCB, congener No.28 50CE106 1.5l PCB S031 CERTAN 1,5ml

PCB, congener No.31 50CE101 1.5l PCB S052 CERTAN 1,5ml

PCB, congener No.52 50CE 107 1.5l PCB S077 CERTAN 1,5ml

PCB, congener No.77 50CE108 1.5l PCB S110 CERTAN 1,5ml

PCB, congener No. 110 50CE109 1.5I PCB S118 CERTAN 1,5ml

PCB, congener No. 118 50CE103 1.5I PCB S138 CERTAN 1,5ml

PCB, congener No.138 50CE110 1.5I PCB S149 CERTAN 1,5ml

PCB, congener No. 149 50CE104 1.5I PCB S153 CERTAN 1,5ml

PCB, congener 153 50CE111 1.5I PCB S163 CERTAN 1,5ml

PCB, congener No. 163 50CE112 1.5I PCB S170 CERTAN 1,5ml

PCB, congener No. 170 50CE105 1.5I PCB S180 CERTAN 1,5ml

congener NO.180 50CE1 13 1.5I PCB S187 CERTAN 1,5ml

PCB, congener No. 187 50CE 114 1.5I PCB S194 CERTAN 1,5ml

PCB, congener No. 194 50CE150 10I PCB MIX-1 (each) CERTAN 10ml

PCB congeners No.: 28,52,101,118, 138,10153,180,194 10

CE151 4.5M PCB MIX-2 (each) CERTAN 4.5ml

CE151 10M PCB congeners No.: 28,52,101,118, 138,153,180,194 1 CERTAN 10ml

CE 152 4.5I PCB MIX-3 (each) CERTAN 4.5mlPCB congeners No.: 28,31,52,77,101,110, 10,118,138,149,153,163,170,180,187,194 10

CE153 1.5I PCB MIX-4 (each) CERTAN 1.5mlPCB congeners No.: 28,52,101,138,153,180 20

CE 154 4.5N PCB MIX-5 (each) CERTAN 4.5mlPCB congeners No.: 28,52,101,138,153, 180 2

CE 155 4.5I PCB MIX-6 CERTAN 4.5mlAroclor 1242 100

CE156 4.5I PCB MIX-7 CERTAN 4.5mlAroclor 1260 100

CE157 10I PCB MIX-8 CERTAN 10mlAroclor 1242 100Aroclor 1260 100

I – iso-octane C – cyclohexane M – methanol A – acetonitrile

33

23. Calibration solution for determination of Polychlorinated Biphenyls (PCB'S), multianalyte

Reference Trade name Concentration VolumeCompound µg/ml ml

CE150 10I PCB MIX-1 CERTAN® 10 mlPCB congeners No.: 28, 52, 101, 118, 138,153, 180, 194

10 (each)

CE151 4.5M PCB MIX-2 CERTAN® 4.5 mlCE151 10M PCB congeners No.: 28, 52, 101, 118, 138,

153, 180, 1941 (each) CERTAN® 10 ml

CE152 4.5I PCB MIX-3 CERTAN® 4.5 ml PCB congeners No.: 28, 31, 52, 77, 101,110, 118, 138, 149, 153, 163, 170, 180, 187, 194

10 (each)

CE153 1.5I PCB MIX-4 CERTAN® 1.5 mlPCB congeners No.: 28, 52, 101, 138, 153, 180 20 (each)

CE154 4.5N PCB MIX-5 CERTAN® 4.5 mlPCB congeners No.: 28, 52, 101, 138, 153, 180 2 (each)

CE155 4.5I PCB MIX-6 CERTAN® 4, 5 mlAroclor 1242 100

CE156 4.5I PCB MIX-7 CERTAN® 4, 5 mlAroclor 1260 100

CE157 10I PCB MIX-8 CERTAN® 10 mlAroclor 1242 100Aroclor 1260 (each)

I - iso-octane C - cyclohexane M - methanol N - acetone A – acetonitrile

24. Calibration solutions for the determination of volatile organic compounds (VOC, BTEX)Single analyte

Order number Trade nameAnalyte(s) and their concentrations µg/ ml

Volume( ml)

CE200 4.5M benzene 5000 CERTAN® 4.5 mlCE235 4.5I bromdichloromethane 1000 CERTAN® 4.5 mlCE233 4.5I dibromochloromethane 1000 CERTAN® 4.5 mlCE228 4.5M 1, 2 – dichlorobenzene 1000 CERTAN® 4.5 mlCE229 4.5M 1, 3 – dichlorobenzene 1000 CERTAN® 4.5 mlCE230 4.5M 1, 4 – dichlorobenzene 1000 CERTAN® 4.5 mlCE222 4.5M 1, 2 – dichloroethane 5000 CERTAN® 4.5 mlCE223 1.5M 1, 1 – dichloroethylene 1000 CERTAN® 1.5 mlCE223 4.5M 1, 1 – dichloroethylene 1000 CERTAN® 4.5 mlCE224 1.5M cis 1, 2 – dichloroethylene 1000 CERTAN® 1.5 mlCE224 4.5M cis 1, 2 – dichloroethylene 1000 CERTAN® 4.5 mlCE201 4.5M ethylbenzene 5000 CERTAN® 4.5 mlCE227 4.5M chlorobenzene 1000 CERTAN® 4.5 mlCE206 4.5M styrene 2000 CERTAN® 4.5 mlCE221 4.5M tetrachloromethane 5000 CERTAN® 4.5 mlCE226 4.5M 1, 1, 2, 2 – tetrachloroethylene 5000 CERTAN® 4.5 mlCE202 4.5M toluene 5000 CERTAN® 4.5 mlCE231 4.5I tribromomethane (bromoform) 1000 CERTAN® 4.5 mlCE225 4.5M 1, 1, 2 – trichloroethylene 5000 CERTAN® 4.5 mlCE220 4.5M trichloromethane (chloroform) 5000 CERTAN® 4.5 mlCE237 1.5M vinylchloride 200 CERTAN® 1.5 mlCE203 4.5M o – xylene 5000 CERTAN® 4.5 mlCE204 4.5M m – xylene 5000 CERTAN® 4.5 mlCE205 4.5M p – xylene 5000 CERTAN® 4.5 ml

34

25. Calibration solutions for the determination of volatile organic compounds (VOC, BTEX)Multi analytesRefence Trade name

Analyte(s) and their concentrations µg/ mlVolume

(ml)

CE210 1.5M BTEX MIX – 1 CERTAN®1.5 ml

CE210 4.5M CERTAN®4.5 mlbenzene, ethylbenzene, toluene, 2000o – xylene, m – xylene, p – xylene (each)

CE211 1.5M BTEX MIX – 2 CERTAN® 1.5 mlCE211 4.5M CERTAN® 4.5 ml

benzene, ethylbenzene, toluene, 1000o – xylene, m – xylene, p – xylene, styrene (each)

CE280 1.5M VOC MIX – 1 CERTAN® 1.5 mlCE280 4.5M CERTAN® 4.5 ml

trichloromethane, tetrachloromethane, 10001, 2 – dichloroethane, 1, 1 – dichloroethylene, (each)cis 1, 2 – dichloroethylene,1, 1, 2 – trichloroethylene1, 1, 2, 2 – tetrachloroethylene, chlorobenzene,1, 2 – dichlorobenzene, 1, 3 – dichlorobenzene,1, 4 – dichlorobenzene

CE281 10I VOC MIX – 2 CERTAN® 10 mltrichloromethane, tetrachloromethane, 10001, 2 – dichloroethane, 1, 1, 2 – trichloroethylene,1, 1, 2, 2 – tetrachloroethylene, (each)tribromomethane, dibromochloromethane,bromodichloromethane

CE282 1.5M VOC MIX – 3 CERTAN® 1.5 mlCE282 4.5M CERTAN® 4.5 ml

dibromomethane, 1, 1 – dichloroethane, 1001, 2 – dichloroethane, 1, 2 – dichloropropane, (each)1, 1, 1, 2 – tetrachloroethane,1, 1, 2, 2 – tetrachloroethane,1, 1, 2, 2 – tetrachloroethylene,tetrachloromethane,tribromomethane, 1, 1, 1 – trichloroethane,1, 1, 2 – trichloroethane, trichloromethane,1, 1, 2 – trichloroethylene,1, 2, 3 – trichloropropane

CE283 1.5M VOC MIX - 4 CERTAN® 1.5 mlCE283 4.5M CERTAN® 4.5 ml

bromobenzene, bromodichloromethane, 100chlorobenzene, dibromochloromethane, (each)1, 2 – dichlorobenzene, 1, 3 – dichlorobenzene,1, 4 – dichlorobenzene, 1, 1 – dichloroethylene,cis-1, 2 – dichloroethylene,trans-1, 2 – dichloroethylene,dichloromethane, cis-1, 2 – dichloropropylene,trans-1, 3 - dichloropropylene

CE284 4.5M VOC MIX - 5 CERTAN® 4.5 ml1, 1-dichloroethylene, cis-1, 2 – dichloroethylene, 1000trans-1, 2 – dichloroethylene, (each)1, 1, 2 – trichloroethylene,1, 1, 2, 2 - tetrachloroethylene

CE285 4.5M VOC MIX - 6 CERTAN® 4.5 mltribromomethane, trichloromethane, 1000bromodichloromethane, (each)dibromochloromethane

I - iso-octane , M – methanol

35

26. Calibration solutions for the determination of pesticides (metabolites) single element

Référence Composé SolvantCE439 4.5A aldicarb acetonitrile

CE400 4.5A aldrin acetonitrile

CE400 1.5I aldrin iso-octaneCE440 4.5A atrazine acetonitrileCE428 4.5A azinphos-methyl acetonitrileCE428 4.5I azinphos-methyl iso-octaneCE441 4.5A bentazone acetonitrileCE401 4.5C chlorpyriphos-ethyl cyclohexaneCE402 4.5C chlorpyriphos-methyl cyclohexaneCE434 4.5C cis-chlordane cyclohexaneCE435 4.5C trans-chlordane cyclohexaneCE442 4.5A chlortoluron acetonitrileCE443 4.5A cyanazine acetonitrileCE445 4.5A 2, 4 -D acetonitrileCE403 4.5C 4, 4´-DDA cyclohexaneCE404 4.5C 2, 4´-DDD cyclohexaneCE405 4.5C 4, 4´-DDD cyclohexaneCE444 4.5C 2, 4´-DDE cyclohexaneCE406 4.5C 4, 4´-DDE cyclohexaneCE407 4.5C 2, 4´-DDT cyclohexaneCE408 4.5C 4, 4´-DDT cyclohexaneCE446 4.5A dicamba acetonitrileCE447 4.5A dichlorprop acetonitrileCE409 4.5C dieldrin cyclohexaneCE429 4.5A dimethoat acetonitrileCE429 4.5I dimethoat iso-octaneCE448 4.5A dinoseb acetonitrileCE410 4.5I alfa-endosulfan iso-octaneCE411 4.5I beta-endosulfan iso-octaneCE412 4.5I endrin iso-octaneCE449 4.5M endrin-aldehyde methanolCE430 4.5A fenitrothion acetonitrileCE430 4.5I fenitrothion iso-octaneCE413 4.5M alfa-HCH methanolCE414 4.5M beta-HCH methanolCE415 4.5M gama-HCH (lindane) methanolCE416 4.5M delta-HCH methanolCE417 4.5I heptachlor iso-octaneCE427 1.5I heptachlor-epoxide (A+B 1: 1) iso-octaneCE450 4.5M heptachlor-epoxide (B) methanolCE418 4.5I hexachlorobenzene iso-octaneCE419 4.5A imazalil acetonitrileCE451 4.5A isodrin acetonitrileCE452 4.5A isoproturon acetonitrileCE420 4.5A malathion acetonitrileCE453 4.5A MCPA acetonitrileCE454 4.5A mecoprop (MCPP) acetonitrileCE455 4.5A metazachlor acetonitrileCE456 4.5A metiocarb acetonitrileCE457 4.5A metobromuron acetonitrileCE458 4.5A metoxuron acetonitrileCE421 4.5M 4, 4´-metoxychlor methanolCE459 4.5M mirex MethanolCE450 4.5A parathion-ethyl acetonitrileCE451 4.5A parathion-methyl acetonitrileCE422 4.5M pentachlorobenzene methanolCE431 4.5A phosalon acetonitrileCE431 4.5I phosalon iso-octaneCE432 4.5A phosmet acetonitrileCE432 4.5I phosmet iso-octane

36

CE423 4.5C pirimiphos- methyl cyclohexaneCE452 4.5A propoxur acetonitrileCE433 4.5A quinalphos acetonitrileCE433 4.5I quinalphos iso-octaneCE424 4.5C quintozene cyclohexaneCE454 4.5M simazine methanolCE463 4.5A sebuthylazine acetonitrileCE455 4.5M 2, 4, 5 - T methanolCE456 4.5A terbuthylazine acetonitrileCE425 4.5C tetradifon cyclohexaneCE436 4.5I 1, 2, 3-trichlorobenzene iso-octaneCE437 4.5I 1, 2, 4-trichlorobenzene iso-octaneCE438 4.5I 1, 2, 5-trichlorobenzene iso-octaneCE426 4.5C trifluralin cyclohexane

27. Calibration solutions for the determination of pesticides (metabolites) MultianalyteOrder Trade name Concentration Volume

number Analyte(s) µg/ml mlCE500 4.5I OCP mix - 1 10 CERTAN 4,5ml

gamma - HCH (Lindane) 104,4'- DDT 10Heptachlor 104,4'- Methoxychlor 10Hexachlorbenzene 10

CE501 4.5I OCP MIX - 2 10 CERTAN 4,5mlalpha - HCH 10beta - HCH 10gamma - HCH (Lindane) 10delta - HCH 104,4'- DDD 104,4'- DDE 104,4'- DDT 10Heptachlor 104,4'- Methoxychlor 10Hexachlorbenzene 10

CE502 10M OCP MIX - 3 CERTAN 10mlalpha - HCH 1beta - HCH 1gamma - HCH (Lindane) 1delta - HCH 14,4'- DDD 14,4'- DDE 14,4'- DDT 1Heptachlor 14,4'- Methoxychlor 1Hexachlorbenzene 1

CE503 1.5I OCP MIX - 4 CERTAN 1,5mlaldrin 10Dieldrin 10Endrin 10alpha – Endosulphan 10beta - Endosulphan 10gamma - HCH (Lindane) 10Trifluralin 10Hexachlorbenzene 10Heptachlor 104,4'- Methoxychlor 104,4'- DDD 104,4'- DDE 104,4’-DDT 10

CE504 10I OCP MIX - 5 CERTAN 1,5ml1,2,3 – Trichlorbenzene 101,2,4 - Trichlorbenzene 101,3,5 – Trichlorbenzene 10

37

Pentachlorbenzene 10Hexachlorbenzene 10

CE506 4.5I OCP MIX - 6 CERTAN® 4.5 mlaldrin 10dieldrin (each)gama-HCH (lindane)heptachlorheptachlorepoxide (A)heptachlorepoxide (B)

CE505 1.5C OPP mix - 1 CERTAN 1,5mlChlorpyriphos (ethyl) 50Chlorpyriphos (methyl) 50lmazalil 50Malathion 50Pirimiphos (methyl) 50gamma - HCH (Lindane) 10Quintozene 50Tetradifon 50

CE507 1.5I OPP MIX - 2 CERTAN® 1.5 mlCE507 4.5I CERTAN® 4.5 mlCE507 1.5A CERTAN® 1.5 mlCE507 4.5A CERTAN® 4.5 ml

azinphos-methyl 1000chlorpyriphos (ethyl) (each)chlorpyriphos (methyl)dimethoatefenitrothionphosalonephosmetpirimiphos (methyl)quinalphos

CE700 4.5I OCP + PCB MIX - 1 CERTAN® 4, 5 mlalpha - HCH 10beta - HCH (each)gamma - HCH (lindane)delta - HCH4, 4´- DDD4, 4´- DDE4, 4´- DDTheptachlor4, 4´- methoxychlorhexachlorbenzenePCB - 28 PCB - 118PCB - 52 PCB - 138 PCB - 180PCB - 101 PCB - 158 PCB - 194

CE508 1.5A PEST MIX - 1 CERTAN® 1.5 mlCE508 4.5A CERTAN® 4.5 mlCE508 1.5E CERTAN® 1.5 mlCE508 4.5E CERTAN® 4.5 ml

aldicarb 100chlortoluron (each)isoproturonmetobromuronmetoxuron

CE509 1.5A PEST MIX - 2 CERTAN® 1.5 mlCE509 4.5A CERTAN® 4.5 mlCE509 1.5E CERTAN® 1.5 mlCE509 4.5E CERTAN® 4.5 ml

atrazine 100cyanazine (each)metazachlorsebuthylazinesimazineterbuthylazine

CE510 1.5A PEST MIX - 3 CERTAN® 1.5 mlCE510 4.5A CERTAN® 4.5 ml

38

CE510 1.5E CERTAN® 1.5 mlCE510 4.5E CERTAN® 4.5 ml

bentazone 1002, 4 D (each)dichlorpropMCPAmecoprop (MCPP)

CE511 1.5A PEST MIX - 4 CERTAN® 1.5 mlCE511 4.5A CERTAN® 4.5 mlCE511 1.5E CERTAN® 1.5 mlCE511 4.5E CERTAN® 4.5 ml

hexachlorobenzene 100isodrine (each)mirex

I - iso-octane, C - cyclohexane, M - methanol, N - acetone, A - acetonitrile, E - ethylacetate

28. Calibration Solutions for determination of Chlorophenols

Single analyte

Order number Trade nameAnalyte(s) and their concentrations µg/ml

Volume(ml)

CE800 1.5M 4 – chlorophenol 1000 CERTAN® 1.5