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Pre- and Post-Bulkhead Water Quality Peru Creek/Snake River CO Presentation Given to Snake River Task Force 7 Nov 2016 Rob Runkel ([email protected]) U.S. Geological Survey, Toxic Substances Hydrology Program

Pre- and Post-Bulkhead Water Quality Peru Creek/Snake River CO · Pre- and Post-Bulkhead Water Quality Compare spatial profiles, pre & post – Concentration & Load – Pre-bulkhead

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Page 1: Pre- and Post-Bulkhead Water Quality Peru Creek/Snake River CO · Pre- and Post-Bulkhead Water Quality Compare spatial profiles, pre & post – Concentration & Load – Pre-bulkhead

Pre- and Post-Bulkhead Water QualityPeru Creek/Snake River CO

Presentation Given to Snake River Task Force 7 Nov 2016Rob Runkel ([email protected])

U.S. Geological Survey, Toxic Substances Hydrology Program

Page 2: Pre- and Post-Bulkhead Water Quality Peru Creek/Snake River CO · Pre- and Post-Bulkhead Water Quality Compare spatial profiles, pre & post – Concentration & Load – Pre-bulkhead

Overview● 2009 Study Results● Pre- (2009) and Post- (2014/2015) Bulkhead Comparison

● Concentrations● Loads● Peru Mouth vs. Snake below Peru

● Checks for Leakage

● Cinnamon Gulch

● Next Steps

Page 3: Pre- and Post-Bulkhead Water Quality Peru Creek/Snake River CO · Pre- and Post-Bulkhead Water Quality Compare spatial profiles, pre & post – Concentration & Load – Pre-bulkhead

2009 Study Reach

~AW1

Page 4: Pre- and Post-Bulkhead Water Quality Peru Creek/Snake River CO · Pre- and Post-Bulkhead Water Quality Compare spatial profiles, pre & post – Concentration & Load – Pre-bulkhead

2009 Results

Page 5: Pre- and Post-Bulkhead Water Quality Peru Creek/Snake River CO · Pre- and Post-Bulkhead Water Quality Compare spatial profiles, pre & post – Concentration & Load – Pre-bulkhead

2009 Results

Page 6: Pre- and Post-Bulkhead Water Quality Peru Creek/Snake River CO · Pre- and Post-Bulkhead Water Quality Compare spatial profiles, pre & post – Concentration & Load – Pre-bulkhead

2009 Results

Page 7: Pre- and Post-Bulkhead Water Quality Peru Creek/Snake River CO · Pre- and Post-Bulkhead Water Quality Compare spatial profiles, pre & post – Concentration & Load – Pre-bulkhead

2009 Results

Page 8: Pre- and Post-Bulkhead Water Quality Peru Creek/Snake River CO · Pre- and Post-Bulkhead Water Quality Compare spatial profiles, pre & post – Concentration & Load – Pre-bulkhead

Post Bulkhead

Photo by Jeff Graves, State of Colorado

Page 9: Pre- and Post-Bulkhead Water Quality Peru Creek/Snake River CO · Pre- and Post-Bulkhead Water Quality Compare spatial profiles, pre & post – Concentration & Load – Pre-bulkhead

Bulkhead #1

Refurbished F Level Portal Penn Mine F Level

Page 10: Pre- and Post-Bulkhead Water Quality Peru Creek/Snake River CO · Pre- and Post-Bulkhead Water Quality Compare spatial profiles, pre & post – Concentration & Load – Pre-bulkhead

Bulkhead #1F Level Cross Cut Bulkhead #1

Page 11: Pre- and Post-Bulkhead Water Quality Peru Creek/Snake River CO · Pre- and Post-Bulkhead Water Quality Compare spatial profiles, pre & post – Concentration & Load – Pre-bulkhead

Pre- and Post-Bulkhead Water Quality● Compare spatial profiles, pre & post

– Concentration & Load

– Pre-bulkhead (2009 USGS & EPA)(Note: other pre-bulkhead data are available for 2010-2014)

– Post-bulkhead 1 (Oct 2014)

– Post-bulkhead 2 (Oct 2015)

– Coming attaction (data not back from lab):Post-bulkhead 2 (Oct 2016)

● Check for F Level leakage– Monitor wetland inflows & wells

Page 12: Pre- and Post-Bulkhead Water Quality Peru Creek/Snake River CO · Pre- and Post-Bulkhead Water Quality Compare spatial profiles, pre & post – Concentration & Load – Pre-bulkhead

Post Bulkhead Sampling (Oct 2014-16)

● 13 stream sites● 8 inflows● 6 wells● Streamflow by ADV

Page 13: Pre- and Post-Bulkhead Water Quality Peru Creek/Snake River CO · Pre- and Post-Bulkhead Water Quality Compare spatial profiles, pre & post – Concentration & Load – Pre-bulkhead

Pre and Post Bulkhead pH

Preliminary Results as of December 1, 2016

Page 14: Pre- and Post-Bulkhead Water Quality Peru Creek/Snake River CO · Pre- and Post-Bulkhead Water Quality Compare spatial profiles, pre & post – Concentration & Load – Pre-bulkhead

Pre- and Post-Bulkhead Zn

Preliminary Results as of December 1, 2016

Page 15: Pre- and Post-Bulkhead Water Quality Peru Creek/Snake River CO · Pre- and Post-Bulkhead Water Quality Compare spatial profiles, pre & post – Concentration & Load – Pre-bulkhead

Pre- and Post-Bulkhead Cu

Preliminary Results as of December 1, 2016

Page 16: Pre- and Post-Bulkhead Water Quality Peru Creek/Snake River CO · Pre- and Post-Bulkhead Water Quality Compare spatial profiles, pre & post – Concentration & Load – Pre-bulkhead

Streamflows used to calculate loads

Cinnam

on Gulch

Warden

Gulch

Chihua

hu a Gulch

Upper S

n ake R

.

Preliminary Results as of December 1, 2016

Page 17: Pre- and Post-Bulkhead Water Quality Peru Creek/Snake River CO · Pre- and Post-Bulkhead Water Quality Compare spatial profiles, pre & post – Concentration & Load – Pre-bulkhead

Pre & Post Bulkhead Zn Load

Cinnam

on Gulch

Warden G

ulch

Chihuahu a G

ulch

Upper S

n ake R

.

Preliminary Results as of December 1, 2016

Page 18: Pre- and Post-Bulkhead Water Quality Peru Creek/Snake River CO · Pre- and Post-Bulkhead Water Quality Compare spatial profiles, pre & post – Concentration & Load – Pre-bulkhead

Change due to Bulkhead #1(2009 pre-bulkhead vs. 2014 post-bulkhead #1)

Comparison based on SW-49 Comparison based on SW-50(Peru Cr near mouth) (Snake R. below Peru Creek)

Conc Load Conc Load

pH B WAl W N W BCd B N N BCu B B B BFe W W N BPb B B B BMn N N N BSO4 N N W BZn N N N B

Better (B), Worse (W), or Neutral (N)

Preliminary Results as of December 1, 2016

Page 19: Pre- and Post-Bulkhead Water Quality Peru Creek/Snake River CO · Pre- and Post-Bulkhead Water Quality Compare spatial profiles, pre & post – Concentration & Load – Pre-bulkhead

Bulkhead #2● Low Flow Water Quality

– Post-bulkhead #2: Oct 2015

– Post-bulkhead #2: Oct 2016 (data not back from lab)

Page 20: Pre- and Post-Bulkhead Water Quality Peru Creek/Snake River CO · Pre- and Post-Bulkhead Water Quality Compare spatial profiles, pre & post – Concentration & Load – Pre-bulkhead

Change due to Bulkhead #2(2014 post-bulkhead #1 vs. 2015 post-bulkhead #2)

Comparison based on SW-49 Comparison based on SW-50(Peru Cr near mouth) (Snake R. below Peru Creek)

Conc Load Conc Load

pH W WAl W W W WCd N B W WCu N N W WFe B B W WPb N N W WMn W N W WSO4 W W W WZn N N W W

Better (B), Worse (W), or Neutral (N)

Preliminary Results as of December 1, 2016

Page 21: Pre- and Post-Bulkhead Water Quality Peru Creek/Snake River CO · Pre- and Post-Bulkhead Water Quality Compare spatial profiles, pre & post – Concentration & Load – Pre-bulkhead

Where we're at / Where we should(?) be: pH

Pre-bulkhead: 2009

Post-bulkhead #1, 2014

Post-bulkhead #2, 2015

Preliminary Results as of December 1, 2016

Page 22: Pre- and Post-Bulkhead Water Quality Peru Creek/Snake River CO · Pre- and Post-Bulkhead Water Quality Compare spatial profiles, pre & post – Concentration & Load – Pre-bulkhead

Where we're at / Where we should(?) be: ZnPre-bulkhead: 2009

Post-bulkhead #1, 2014

Post-bulkhead #2, 2015

F level

Cin

n. G

ulch

Preliminary Results as of December 1, 2016

Page 23: Pre- and Post-Bulkhead Water Quality Peru Creek/Snake River CO · Pre- and Post-Bulkhead Water Quality Compare spatial profiles, pre & post – Concentration & Load – Pre-bulkhead

Checks for Post-Bulkhead Leakage● Monitor WQ of wetland inflows – PC-510, PC-600, PC-742

– Pre-Bulkhead: Sept 2009; Sept 2014

– Post-Bulkhead: Oct 2014; July 2015; Oct 2015; Oct 2016

510 LBI 600 LBI 742 LBI

Page 24: Pre- and Post-Bulkhead Water Quality Peru Creek/Snake River CO · Pre- and Post-Bulkhead Water Quality Compare spatial profiles, pre & post – Concentration & Load – Pre-bulkhead

Checks for Post-Bulkhead Leakage – InflowsCd Cu

Mn

Zn

Bhead #1

Bh

ead #2

Bhe

ad #1

Bhe

ad #1

Bhea

d #1

Bh

ead #2

Bhea

d #2

Bhe

ad #2

Preliminary Results as of December 1, 2016

Page 25: Pre- and Post-Bulkhead Water Quality Peru Creek/Snake River CO · Pre- and Post-Bulkhead Water Quality Compare spatial profiles, pre & post – Concentration & Load – Pre-bulkhead

Checks for Post-Bulkhead Leakage● Monitor WQ of wells

– GWC1 – 4 observations (2 pre, 1 post #1, 1 post #2)

– AW1 and BW1 – 3 obs. (1 pre, 1 post #1, 1 post #2)

Other wells with less data:

– GW3

– GW1, GW4

– GW5, MW02, MW04

Page 26: Pre- and Post-Bulkhead Water Quality Peru Creek/Snake River CO · Pre- and Post-Bulkhead Water Quality Compare spatial profiles, pre & post – Concentration & Load – Pre-bulkhead

Checks for Post-Bulkhead Leakage – Well AW1

Zn

Bhea

d #1

Bh

ead #2

Bhead #1

Cd

Bh

ead #1

CuB

head #2

Mn

Bhead

#1

Bhead

#2

Bhea

d #2

Bhead

#1

Zn

Preliminary Results as of December 1, 2016

Page 27: Pre- and Post-Bulkhead Water Quality Peru Creek/Snake River CO · Pre- and Post-Bulkhead Water Quality Compare spatial profiles, pre & post – Concentration & Load – Pre-bulkhead

Post-Bulkhead Leakage● Monitor WQ of wetland inflows

– PC-600 & PC-742 chemistry stable

– PC-510 increase possible but dubious

● Monitor WQ of wells– GWC1 and BW1 stable

– AW1 possibily increasing– GW1, GW3, GW4, GW5, MW02, MW04 – find/generate addl data

Page 28: Pre- and Post-Bulkhead Water Quality Peru Creek/Snake River CO · Pre- and Post-Bulkhead Water Quality Compare spatial profiles, pre & post – Concentration & Load – Pre-bulkhead

Other sources: Cinnamon Gulch● Contributes Pb, Al, Acidity,

SO4, Mn, Zn● Bird/CGS publication (2003):

Only 4% due to mining!● 7 draining adits● 2009 USGS Study (unpublished)

80%

Page 29: Pre- and Post-Bulkhead Water Quality Peru Creek/Snake River CO · Pre- and Post-Bulkhead Water Quality Compare spatial profiles, pre & post – Concentration & Load – Pre-bulkhead

Cinn. Gulch 2009 Synoptic

Page 30: Pre- and Post-Bulkhead Water Quality Peru Creek/Snake River CO · Pre- and Post-Bulkhead Water Quality Compare spatial profiles, pre & post – Concentration & Load – Pre-bulkhead

Cinnamon Gulch Adits CIN-195 LBI

source of water to CIN-489L (2 adits)

Page 31: Pre- and Post-Bulkhead Water Quality Peru Creek/Snake River CO · Pre- and Post-Bulkhead Water Quality Compare spatial profiles, pre & post – Concentration & Load – Pre-bulkhead

Cinnamon Gulch Adits source of water to CIN-504 LBI

source of water to CIN-760

5 adits in photos+ Delaware+ Silver Spoon

Page 32: Pre- and Post-Bulkhead Water Quality Peru Creek/Snake River CO · Pre- and Post-Bulkhead Water Quality Compare spatial profiles, pre & post – Concentration & Load – Pre-bulkhead

Cin Gulch LoadsAl Load

#1: 68 mg/s – 760 RBI (Adit)#2: 52 mg/s – Silverspoon & 195 LBI (Adits)

#4: 42 mg/s – natural

#3: 48 mg/s – 1-3 LB Adits

Delaware

Preliminary Results as of December 1, 2016

Page 33: Pre- and Post-Bulkhead Water Quality Peru Creek/Snake River CO · Pre- and Post-Bulkhead Water Quality Compare spatial profiles, pre & post – Concentration & Load – Pre-bulkhead

Conclusions● 2014: Bulkhead #1 reduced loads and conc.

● 2015: Bulkhead #2, minimal/no improvement

● Lack of improvement may be due to leakage

● Future monitoring: focus on Low Flow

– most of the year

– highest concentrations/toxicity

– may not need summer/high flow sampling

Page 34: Pre- and Post-Bulkhead Water Quality Peru Creek/Snake River CO · Pre- and Post-Bulkhead Water Quality Compare spatial profiles, pre & post – Concentration & Load – Pre-bulkhead

Future● 2016 Results – do they support '15 results

(was Bulkhead #2 not of consequence?)

● 2016 Results – Basin Wide Synoptic to Snake Headwaters ● More Pre/Post Comparison

– additional data for wells● 2017 low flow sampling

● Cinnamon Gulch analysis

Page 35: Pre- and Post-Bulkhead Water Quality Peru Creek/Snake River CO · Pre- and Post-Bulkhead Water Quality Compare spatial profiles, pre & post – Concentration & Load – Pre-bulkhead

Notes: Slides 2-7, 27 – Results from 2009 USGS study; for additional details, see:Runkel, R.L., Walton-Day, K., Kimball, B.A., Verplanck, P.L., and Nimick, D.A., 2013, Estimating instream

constituent loads using replicate synoptic sampling, Peru Creek, Colorado: Journal of Hydrology, v. 489, p. 26-41. DOI: 10.1016/j.jhydrol.2013.02.031

Slide 12 – Acoustic Doppler Velocimetry (ADV)

Slides 13-18, 20-22, 24, 26 – Data from collaborative USGS/EPA low flow studies conducted in 2014 and 2015, wherein water quality samples were processed US EPA contractors and streamflow estimates were obtained by USGS hydrologists.

Slide 28 – Bird/CGS (2003):Bird, D.A., 2003, Characterization of anthropogenic and natural sources of acid rock drainage at the

Cinnamon Gulch abandoned mine land inventory site, Summit County, Colorado: Environmental Geology, v. 44 no. 8, p. 919-932 DOI: 10.1007/s00254-003-0835-9

Slide 32 – Results from 2009 USGS study; results are provisional and subject to revision

Unless noted otherwise, all photographs by R.L. Runkel

Contact Information:Rob RunkelResearch HydrologistU.S. Geological SurveyColorado Water Science [email protected]://profile.usgs.gov/runkel