Pierre BRAUNSTEIN - Academia Europaea...P. Braunstein - p 1 PUBLICATION LIST Pierre BRAUNSTEIN Laboratoire de Chimie de Coordination Institut de Chimie (UMR 7177 CNRS) Université

P. Braunstein - p 1

PUBLICATION LIST

Pierre BRAUNSTEIN

Laboratoire de Chimie de Coordination Institut de Chimie (UMR 7177 CNRS) Université de Strasbourg 4, rue Blaise Pascal 67081 STRASBOURG Cedex Téléphone: (+33) 03 68 85 13 08 E-mail: [email protected]

P. Braunstein - p 2

BOOKS / SPECIAL ISSUES

* “Guest Editor” de "Recent Advances in Di- and Polynuclear Chemistry", New J. Chem. 1988, 12, 307-720. * “Guest Editor” avec W. A. Herrmann de "New Perspectives in Organometallic Chemistry", New J. Chem.

1990, 14, 389-587. * “Guest Editor” avec P. Sobota et J. J. Ziolkowski (Pologne) des "Proceedings of the 13th Summer School on

Coordination Chemistry”, Polanica-Zdroj, Pologne, 2-8/6/1996, New J. Chem. 1997, 21, 647-846. * “Guest Editor” de "Inorganic Chemistry in France", Coord. Chem. Rev. 1998, 178-180, 1-1846. * “Editor” avec P. R. Raithby et L. A. Oro de lʻouvrage “Metal Clusters in Chemistry”, Wiley-VCH, 1999, 3

volumes, 1798 pages *

REVIEW ARTICLES

R1. J. TIROUFLET, P. BRAUNSTEIN Aspects de la chimie organométallique des métaux de transition. Partie I: Synthèse et réactivité. L'Actualité Chimique (Soc. Chim. Fr.), 1975, n° 3, 4-16. R2. J. TIROUFLET, P. DIXNEUF, P. BRAUNSTEIN Aspects de la chimie organométallique des métaux de transition. Partie III: Cinq familles typiques:

métallocarbènes, métallocarbynes, ylures, clusters, métallocarboranes et quelques applications. L'Actualité Chimique (Soc. Chim. Fr.), 1975, n° 5, 3-16. R3. E. SAPPA, A. TIRIPICCHIO, P. BRAUNSTEIN Alkyne-substituted Homo- and Heterometallic Carbonyl Clusters of the Iron, Cobalt, and Nickel Triads. Chem. Rev. 1983, 83, 203-239. R4. P. BRAUNSTEIN, J. ROSE Gold in Bimetallic Molecular Clusters. Their Synthesis, Bonding, Chemical and Catalytic Reactivities. Gold Bull. 1985,18, 17-30. R5. E. SAPPA, A. TIRIPICCHIO, P. BRAUNSTEIN Selective Metal-Ligand Interactions in Heterometallic Transition Metal Clusters. Coord. Chem. Rev. 1985, 65, 219-284. R6. P. BRAUNSTEIN Clusters Moléculaires: Matériaux, Architectures, Finalités. Nouv. J. Chim. 1986, 10, 365-368. R7. P. BRAUNSTEIN, D. MATT, D. NOBEL Reactions of Carbon Dioxide with C-C Bond Formation Catalyzed by Transition Metal Complexes. Chem. Rev. 1988, 88, 747-764. R8. R. BENDER, P. BRAUNSTEIN, C. de MERIC de BELLEFON Electronic and Steric Effects in Closely Related Heteronuclear Clusters. Selective Pathways in Synthetic and

Catalytic Bimetallic Chemistry. Polyhedron Symposia-in-Print, Polyhedron, 1988, 7, 2271-2283. R9. T. M. GOMES CARNEIRO, D. MATT, P. BRAUNSTEIN Polynuclear Iridium Hydrido Complexes. Coord. Chem. Rev. 1989, 96, 49-88. R10. P. BRAUNSTEIN, J. ROSÉ Heterometallic Clusters in Catalysis. In "Stereochemistry of Organometallic and Inorganic Compounds", I. Bernal (Ed.); Elsevier: Amsterdam

1989, Vol.III, p. 3-138. R11. P. BRAUNSTEIN, D. NOBEL Transition Metal Mediated Reactions of Organic Isocyanates. Chem. Rev. 1989, 89, 1927-1945. R12. P. BRAUNSTEIN Interplay between Bridging Groups and Metal-Metal Bonds in Heterometallic Clusters. Materials Chemistry and Physics, 1991, 29, 33-63.

P. Braunstein - p 3

R13. P. BRAUNSTEIN Molecular clusters and ligands: a powerful interplay. in Perspectives in Coordination Chemistry, A.F. Williams, C. Floriani, A. E. Merbach (Eds.); Verlag Helvetica

Chimica Acta/VCH: CH-4010 Bâle, 1992, p. 67-107. R14. P. BRAUNSTEIN Metal-metal and metal-ligand interactions in heterometallic complexes. New J. Chem. 1994, 18, 51-60. R15. P. BRAUNSTEIN, J. ROSÉ Catalysis and Related Reactions with Compounds Containing Heteronuclear Metal-Metal Bonds in Comprehensive Organometallic Chemistry, Second Edition, E. W. Abel, F. G. A. Stone, G. Wilkinson (Eds.), Pergamon Press: Oxford 1995, Vol. 10, Chapter 7, p 351-385. R16. P. BRAUNSTEIN, M. KNORR Reactivity of the metal-silicon bond in organometallic chemistry. J. Organomet. Chem. 1996, 500, 21-38. R17. P. BRAUNSTEIN, M. KNORR CO-, isonitrile-, and phosphine-induced silyl migration reactions in heterobimetallic Fe-Pd and Fe-Pt

complexes. in Organosilicon Chemistry II, From Molecules to Materials, N. Auner and J. Weis (Eds.); VCH: D-69451

Weinheim, 1996, p. 553-563. R18. P. BRAUNSTEIN, M. KNORR Influence of silyl ligands on the reactivity of heterobimetallic complexes: insertion and migration reactions. in Metal-Ligand Interactions - Structure and Reactivity, N. Russo and D. R. Salahub (Eds.); Kluwer Academic

Publishers, Dordrecht (The Netherlands) - NATO ASI Ser., Ser. C, 1996, 474, 49-83. R19. P. BRAUNSTEIN Les clusters en chimie. L'Actualité Chimique 1996, 7, 75-85. R20. P. BRAUNSTEIN, Y. CHAUVIN, J. NÄHRING, J. PIETSCH Tuning the Reactivity of Mono- and Bimetallic Coordination and Organometallic Complexes. in Progress in Coordination and Organometallic Chemistry, G. Ondrejovic and A. Sirota (Eds.); Slovak

Technical University Press, Bratislava, 1997, 3, 3-18. R21. P. BRAUNSTEIN, J. ROSÉ Heterometallic Clusters for Heterogeneous Catalysis in Catalysis by Di- and Polynuclear Metal Clusters, R. D. Adams, F. A. Cotton (Eds.), John Wiley, New-York

1998, p 443-508. R22. P. BRAUNSTEIN, M. KNORR, Ch. STERN The Unusual Chemistry of Bimetallic Silyl Complexes in Selective Reactions of Metal-Activated Molecules, H. Werner and P. Schreier (Eds.); Vieweg Publishers,

Braunschweig/Wiesbaden (Germany), 1998, 197-205. R23. P. BRAUNSTEIN, M. KNORR, Ch. STERN Bimetallic Silicon Chemistry: New Opportunities in Coordination and Organometallic Chemistry Coord. Chem. Rev. (Special Issue dedicated to the Inorganic Chemistry in France), 1998, 178-180, 903-965. R24. P. BRAUNSTEIN, X. MORISE Catalytic Dehydrogenative Coupling of Stannanes in Education in Advanced Chemistry, Vol. 6: Mechanistic Aspects of Molecular Catalysis, B. Marciniec (Ed.);

1999, 1-15. R25. P. BRAUNSTEIN, J. ROSÉ Heterometallic Clusters in Catalysis in Metal Clusters in Chemistry, P. Braunstein, L. A. Oro and P. R. Raithby (Eds.); Wiley-VCH, Weinheim

(Germany), 1999, Vol. 2, pp. 616-677. R26. P. BRAUNSTEIN, X. MORISE Dehydrogenative Coupling of Hydrostannanes Catalyzed by Transition-Metal Complexes Chem. Rev. 2000, 100, 3541-3552.

P. Braunstein - p 4

R27. P. BRAUNSTEIN, F. NAUD Hemilability of Hybrid Ligands and the Coordination Chemistry of Oxazoline-Based Systems Angew. Chem. Int. Ed. 2001, 40, 680-699. R28. P. BRAUNSTEIN, N. M. BOAG Alkyl, Silyl, and Phosphane Ligands - Classical Ligands in Nonclassical Bonding Modes Angew. Chem. Int. Ed. 2001, 40, 2427-2433. R29. P. BRAUNSTEIN

Functional ligands and complexes for new structures, homogeneous catalysts and nanomaterials J. Organomet. Chem. 2004, 689, 3953-3967 (special volume for the 40th anniversary of JOMC)

R30. F. SPEISER, P. BRAUNSTEIN, L. SAUSSINE Catalytic Ethylene Dimerization and Oligomerization : Recent Developments with Nickel Complexes

Containing P,N-Chelating Ligands. Acc. Chem. Res. 2005, 38, 784-793. R31. P. BRAUNSTEIN Bonding and Organic and Inorganic Reactivity of Metal-Coordinated Phosphinoenolates and Related

Functional Phosphine-Derived Anions. Chem. Rev. 2006, 106, 134-159. R32. S. SCULFORT, P. BRAUNSTEIN Intramolecular d10-d10 interactions in heterometallic clusters of the transition metals Chem. Soc. Rev. 2011, 40, 2741-2760. R33. C. FLIEDEL, P. BRAUNSTEIN

Recent advances in S-functionalized N-heterocyclic carbene ligands: from the synthesis of azolium salts and metal complexes to applications. J. Organomet. Chem. 2014, 751, 286-300 (50th Anniversary special issue of the Journal of Organometallic Chemistry).

R34. A. K. SINGH, D. S. PANDEY, Q. XU, P. BRAUNSTEIN Recent Advances in Supramolecular and Biological Aspects of Arene Ruthenium(II) Complexes Coord. Chem. Rev. (Special Organometallic Issue) 2014, 270-271, 31-56.

R35. S. ZHANG, R. PATTACINI, P. BRAUNSTEIN

Coordination Chemistry of Oxazoline/Thiazoline-Based P,N Ligands In Organometallic Chemistry: Recent Advances, A. J. L. Pombeiro (Ed.), Elsevier, Chapter 14, pp. 185-198, 2014.

R36. A. BOUDIER, P.-A. R. BREUIL, L. MAGNA, H. OLIVIER-BOURBIGOU, P. BRAUNSTEIN Ethylene oligomerization using iron complexes: beyond the discovery of bis(imino)pyridine ligands Chem. Commun. 2014, 50, 1398-1407 (Feature article). R37. P. BRAUNSTEIN The Diversity of the Metal-Ligand Interplay in Coordination Chemistry Bull. Jpn. Soc. Coord. Chem. (BJSCC) 2014, 63, 19-28. R38. R. BENDER, R. WELTER, P. BRAUNSTEIN Phosphanido-Bridged Triangular Platinum Clusters as Versatile Platforms: A Personal Account Inorg. Chim. Acta (Special Issue “Metal-Metal Bonded Compounds and Metal Clusters”), 2015, 424, 20-28. R39. P. BUCHWALTER, J. ROSÉ, P. BRAUNSTEIN

Multimetallic Catalysis Based on Heterometallic Complexes and Clusters Chem. Rev. 2015, 115, 28-126.

P. Braunstein - p 5

PUBLICATIONS

1. P. BRAUNSTEIN, J. DEHAND New compounds containing Pt-Mo and Pd-Mo bonds. J. Organomet. Chem. 1970, 24, 497. 2. P. BRAUNSTEIN, J. DEHAND Trans-bis(pyridine)bis(pentacarbonylmanganate) et trans-bis(pyridine)bis(tétracarbonylcobaltate) de

palladium. C.R. Acad. Sc. Paris, Ser. C , 1972, 274, 175. 3. P. BRAUNSTEIN, J. DEHAND Vibrational frequencies of new types of metal-metal bonds. J. Chem. Soc., Chem. Commun. 1972, 164. 4. M. PFEFFER, P. BRAUNSTEIN, J. DEHAND Anomalies dans des complexes trans carrés plans du platine et du palladium. Inorg. Nucl. Chem. Lett. 1972, 8, 497. 5. P. BRAUNSTEIN New route to aryl-gold σ -bonded complexes. J. Chem. Soc., Chem. Commun. 1973, 851. 6. P. BRAUNSTEIN, R. J. H. CLARK The preparation, properties and vibrational spectra of complexes containing the AuCl2-, AuBr2- and AuI2-

ions. J. Chem. Soc., Dalton Trans. 1973, 1845. 7. P. BRAUNSTEIN, J. DEHAND, M. PFEFFER Cyclopalladation via reaction on coordinated ligand. Inorg. Nucl. Chem. Lett. 1974, 10, 521. 8. P. BRAUNSTEIN, J. DEHAND, M. PFEFFER Synthèse et réactivité de composés cyclopalladés. II. Complexes anioniques à liaison σ palladium-aryle. Inorg. Nucl. Chem. Lett. 1974, 10, 581. 9. P. BRAUNSTEIN, R. J. H. CLARK Synthesis and properties of arylgold(III) compounds. Inorg. Chem. 1974, 13, 2224. 10. M. PFEFFER, P. BRAUNSTEIN, J. DEHAND Etude spectroscopique de composés carrés plans du Pt(II) et du Pd(II) avec des pyridines substituées. I.

Vibrations des coordinats. Spectrochim. Acta, Part A 1974, 30, 331. 11. M. PFEFFER, P. BRAUNSTEIN, J. DEHAND Etude spectroscopique de composés carrés plans du Pt(II) et du Pd(II) avec des pyridines substituées. II.

Vibrations du squelette carré plan. Spectrochim. Acta, Part A 1974, 30, 341. 12. P. BRAUNSTEIN, J. DEHAND, M. PFEFFER New bimetallic organopalladium(II) compounds containing a Pd-Co or Pd-Mo bond trans to a Pd-C bond. J. Organomet. Chem. 1974, 76, C35. 13. P. BRAUNSTEIN, J. DEHAND Composés organométalliques à liaisons métal-métal. III. Systèmes linéaires M2-M1L2-M2 où M1 = Pd(II),

Pt(II); M2 = Mn(CO)5, L = Py, 3-MePy, 4-MePy . J. Organomet. Chem. 1974, 81, 123. 14. P. BRAUNSTEIN, J. DEHAND, M. GROSS, P. LEMOINE Décomposition thermique du bis(η-cyclopentadiényle dicarbonyle fer). J. Therm. Anal. 1975, 8, 109.

P. Braunstein - p 6

15. P. BRAUNSTEIN, J. DEHAND Composés organométalliques à liaisons métal-métal. IV. Systèmes linéaires M2-M1L2-M2 où M1 =

Pd(II),Pt(II); M2 = Co(CO)4, Mo(CO)3η-C5 H5; L = Py, 3-MePy. Bull. Soc. Chim. Fr. 1975, 1997. 16. P. BRAUNSTEIN, J. DEHAND Influence of electronic factors on metal-metal stretching frequencies in linear trimetallic systems. J. Organomet. Chem. 1975, 88, C24. 17. P. BRAUNSTEIN, J. DEHAND, J.F. NENNIG Organometallic compounds with metal-metal bonds. Part V. New heteronuclear tetrametallic clusters of

platinum with cobalt or molybdenum and a new homotrimetallic platinum cluster. J. Organomet. Chem. 1975, 92, 117. 18. P. BRAUNSTEIN, J. DEHAND, B. MUNCHENBACH Complexes organométalliques à liaisons métal-métal. VII. Complexes bimétalliques du nickel avec des

métaux de transition intermédiaires dans la redistribution de coordinats PPh3, CO et NO. J. Organomet. Chem. 1977, 124 , 71. 19. G. LE BORGNE, S.-E. BOUAOUD, D. GRANDJEAN, P. BRAUNSTEIN, J. DEHAND, M. PFEFFER Structure cristalline et moléculaire du tétracarbonylcobaltato-pyridine[N(phénylamino)-α-méthyl

benzylidenimino-2-C,N]palladate(II), composé à liaison Pd-Co. J. Organomet. Chem. 1977, 136, 375. 20. E. O. FISCHER, T. L. LINDNER, F. R. KREISSL, P. BRAUNSTEIN Übergangsmetall-Carbin-Komplexe mit Metal-Metal Bindungen. Chem. Ber. 1977, 110, 3139. 21. J.-P. BARBIER, R. BENDER, P. BRAUNSTEIN, J. FISCHER, L. RICARD Organometallic complexes with metal-metal bonds. VIII. A new homopentametallic cluster: Pt5(CO)(µ2-

CO)5L4 [L = PEt3, PPh3]; synthesis and structure. J. Chem. Res. (S) 1978, 230; J. Chem. Res. (M) 1978, 2913. 22. P. BRAUNSTEIN, D. MATT, F. MATHEY, D. THAVARD Functional phosphines: a new synthesis of diphenylphosphinoacetonitrile and ethyldiphenyl-

phosphinoacetate; some of their complexes with Fe(0), Au(I), Ni(II), Pd(II), Pt(II), Rh(III) and Ir(III). Stereodynamic behaviour of [Rh{Ph2PCH2C(O)OC2H5}{Ph2PCH2C(O)OC2H5}Cl3 .

J. Chem. Res. (S) 1978, 232; J. Chem. Res. (M) 1978, 3041. 23. R. BENDER, P. BRAUNSTEIN, Y. DUSAUSOY, J. PROTAS Preparation and crystal structure of Pd2Mo2(η5-C5H5)2(µ3-CO)2(µ2-CO)4(PEt3)2 . A planar

triangulated palladium-molybdenum-carbonyl cluster. Angew. Chem., Int. Ed. Engl. 1978, 17, 596; Angew. Chem. 1978, 90, 637. 24. J.-P. BARBIER, P. BRAUNSTEIN, J. FISCHER, L. RICARD The first platinum-cobalt heteropentametallic cluster: Pt3Co2(CO)4(µ2-CO)5(PEt3)3. Inorg. Chim. Acta 1978, 31, L361. 25. J.-P. BARBIER, P. BRAUNSTEIN Organometallic complexes with metal-metal bonds. XI. Linear dimetallioplatinum complexes M-PtL2-M with M = Co(CO)4, Co(CO)3PPh3, Fe(CO)3NO, Mn(CO)5, Mo(CO)3(η-C5H5) or W(CO)3(η-C5H5);

L = tBuNC or C6H11NC; the first Fe-Pt-Fe and W-Pt-W chains. J. Chem. Res. (S) 1978, 412; J. Chem. Res. (M) 1978, 5028. 26. P. BRAUNSTEIN, E. KELLER, H. VAHRENKAMP Organometallic complexes with metal-metal bonds. XII. A trimetallic carbene complex with Mo-Pt-Mo bonds. Preparation and structure of trans-Pt(C6H11NC){C6H11NHC(OC2H5)}[Mo(CO)3(η5-C5H5)]2 J. Organomet. Chem. 1979, 165, 233. 27. R. BENDER, P. BRAUNSTEIN, Y. DUSAUSOY, J. PROTAS Complexes organométalliques à liaisons métal-métal. XIII. Préparation de clusters hétérotétra métalliques

platine-molybdène et platine-tungstène et structure cristalline de Pt2Mo2(η5-C5H5)2(CO)6[P(C2H5)3]2 J. Organomet. Chem. 1979, 172, C51.

P. Braunstein - p 7

28. P. BRAUNSTEIN, D. MATT, Y. DUSAUSOY, J. PROTAS Reaction of α-phosphino functional carbanions with coordinated nitriles. Synthesis of bis-chelate (P,N)

platinum complexes; X-ray crystal and molecular structure of trans-Pt[P(Ph)2C(CO2Et)C(Ph)NH]2. J. Chem. Soc., Chem. Commun. 1979, 763. 29. P. BRAUNSTEIN, D. MATT, O. BARS, D. GRANDJEAN Synthesis and crystal structure of a chiral complex containing a non-linear heterotrimetal chain: PtMn2(µ2-

PPh2)2(CO)9. Angew. Chem., Int. Ed. Engl. 1979, 18, 797; Angew. Chem. 1979, 91, 859. 30. P. LEMOINE, A. GIRAUDEAU, M. GROSS, P. BRAUNSTEIN Electroreduction of linear trimetallic complexes: M-Hg-M, (M-Au-M)-, M-PtL2-M [M = Co(CO)4, Fe(CO)3NO,

Mn(CO)5, Cr(CO)3(η-C5H5), Mo(CO)3(η-C5H5) or W(CO)3(η-C5H5); L = ButNC or C6H11NC]; unexpected generation of radicals.

J. Chem. Soc., Chem. Commun. 1980, 77. 31. Th. WÜRMINGHAUSEN, H.-J. REINECKE, P. BRAUNSTEIN Mass spectra of some platinum clusters. Electron impact and field desorption studies of Ptn(CO)m(PR3)p

complexes. Org. Mass Spectrom. 1980, 15, 38. 32. P. BRAUNSTEIN, D. MATT, J. FISCHER, L. RICARD, A. MITSCHLER The [Ph2PCHC(O)OEt]- carbanion as chelating or bridging ligand in ortho-metallated N,N-dimethyl

benzylamine palladium complexes. Obtention of a reversible CO2 carrier. Nouv. J. Chim. 1980, 9, 493. 33. P. BRAUNSTEIN, E. SAPPA, A. TIRIPICCHIO, M. TIRIPICCHIO CAMELLINI Synthesis and X-ray structure of (η-C5H5)2Ni2Fe(CO)3S, the first iron-nickel cluster with a sulphur atom

nearly symmetrically bridging three metal atoms. Inorg. Chim. Acta 1980, 45, L191. 34. P. LEMOINE, A. GIRAUDEAU, M. GROSS, P. BRAUNSTEIN Electrochemistry of platinum(II) coordination compounds. I. Electroreduction of dihalogenobis

(isocyanide)platinum(II) complexes. J. Organomet. Chem. 1980, 202, 447. 35. P. LEMOINE, A. GIRAUDEAU, M. GROSS, P. BRAUNSTEIN Electrochemistry of platinum(II) coordination compounds. II. Electroreduction of trimetallic

dimetalliobis(isocyanide)platinum(II) complexes. J. Organomet. Chem. 1980, 202, 455. 36. R. BENDER, P. BRAUNSTEIN, J. FISCHER, L. RICARD, A. MITSCHLER High yield preparation of Pt5(CO)6[P(C6H5)3]4; its use in mixed metal clusters synthesis. Preparation and

molecular structure of PtCo2(CO)8[P(C6H5)3]. Nouv. J. Chim. 1981, 5, 81. 37. P. BRAUNSTEIN, D. MATT, O. BARS, M. LOUER, D. GRANDJEAN, J. FISCHER, A. MITSCHLER Organometallic complexes with metal-metal bonds. XVI. Synthesis of new tri- and tetrametallic platinum-

manganese complexes. Crystal structures of (OC)4Mn(µ2-PPh2)Pt(CO)(µ2-PPh2)Mn(CO)4, (OC)4Mn(µ2-PPh2)PtH(µ2-PPh2)2Mn(CO)4 and (OC)4Mn(µ2-PPh2)Pt(µ2-PPh2)2Pt(µ-PPh2)Mn(CO)4.

J. Organomet. Chem. 1981, 213, 79. 38. P. BRAUNSTEIN, D. MATT, Y. DUSAUSOY, J. FISCHER, A. MITSCHLER, L. RICARD Complexes of functional phosphines. 4. Coordination properties of (diphenylphosphino)acetonitrile, ethyl

(diphenylphosphino)acetate, and corresponding carbanions. Characterization of a new facile reversible CO2 insertion into palladium(II) complexes.

J. Am. Chem. Soc. 1981, 103, 5115. 39. P. LEMOINE, A. GIRAUDEAU, M. GROSS, R. BENDER, P. BRAUNSTEIN Redox behaviour of triangular platinum-cobalt clusters. Electrochemically induced generation of the

tetranuclear cluster [Pt2Co2(µ-CO)3(CO)5(PPh3)2]. J. Chem. Soc., Dalton Trans. 1981, 2059.

P. Braunstein - p 8

40. P. BRAUNSTEIN, A. TIRIPICCHIO, M. TIRIPICCHIO CAMELLINI, E. SAPPA Synthesis and structural characterization of a new chromium-iron-sulfur cluster (η5-C5H5)2Cr2Fe2(µ3-CO)2

(µ3-S)2(CO)6 . Inorg. Chem. 1981, 20, 3586. 41. G. MAIRE, O. ZAHRAA, F. GARIN, C. CROUZET, S. AEIYACH, P. LEGARE, P. BRAUNSTEIN Skeletal rearrangements of hydrocarbons on "ideal surfaces" (single crystals), "classical" and "inorganic

complexes derived" catalysts of platinum. J. Chim. Phys. 1981, 78, 951. 42. P. BRAUNSTEIN Die CO2 -Aktivierung durch Metallkomplexe. Nachr. Chem. Tech. Lab. 1981, 29, 695. 43. P. BRAUNSTEIN, J.-M. JUD, A. TIRIPICCHIO, M. TIRIPICCHIO CAMELLINI, E. SAPPA A new type of iron-molybdenum-sulfur cluster: synthesis and structure of

[Fe2Mo2(η5-C5H5)2(µ3-S)2(µ3-CO)2(CO)6 ] . Angew. Chem., Int. Ed. Engl. 1982, 21, 307; Angew. Chem. 1982, 94, 318. 44. O. BARS, P. BRAUNSTEIN Synthesis and structure of a heterodimetallic complex containing a terminal hydrido ligand:

[(PPh3)2(H)PtMo(CO)3(η5-C5H5)]. Angew. Chem., Int. Ed. Engl. 1982, 21, 308; Angew. Chem. 1982, 94, 319. 45. P. BRAUNSTEIN, J. ROSE, Y. DUSAUSOY, J. P. MANGEOT Complexes à liaisons métal-métal. XXI. Synthèse et structure du "cluster" (Ph3P)AuRuCo3(CO)12: une

bipyramide trigonale à trois métaux différents. C.R. Acad. Sc. Paris, Ser. II, 1982, 967. 46. A. FUSI, R. UGO, R. PSARO, P. BRAUNSTEIN, J. DEHAND Homogeneous catalysis with transition metal complexes. Heteronuclear platinum clusters as hydrogenation

catalysts of carbon-carbon multiple bonds. J. Mol. Catal. 1982, 16, 217. 47. A. GIRAUDEAU, P. LEMOINE, M. GROSS, J. ROSÉ, P. BRAUNSTEIN Influence of organic ligands and fac-mer isomerization on the redox behaviour of Ru(III) chloro complexes. Inorg. Chim. Acta 1982, 62, 117. 48. P. BRAUNSTEIN, R. BENDER, J. KERVENNAL Selective carbonylation of nitrobenzene over a mixed Pd-Mo cluster-derived catalyst. Organometallics 1982, 1, 1236. 49. P. BRAUNSTEIN, G. PREDIERI, A. TIRIPICCHIO, E. SAPPA The reactivity of HRu3(CO)9C2(t-Bu). The synthesis and crystal structure of (PPh3)AuRu3(CO)9C2(t-Bu), a

new ruthenium-gold cluster. Inorg. Chim. Acta 1982, 63, 113. 50. A. FUSI, R. UGO, R. PSARO, P. BRAUNSTEIN, J. DEHAND The homogeneous hydrogenation of carbon-carbon multiple bonds with heteronuclear platinum clusters. Phil. Trans. R. Soc. London, Ser. A 1982, 308, 125. 51. P. BRAUNSTEIN, J.-M. JUD, Y. DUSAUSOY, J. FISCHER Syntheses of the first mixed-metal clusters with Ph2PCH2PPh2. Crystal structures of the metalloligated

triangulo clusters Pd2Co2(CO)7(Ph2PCH2PPh2)2 and Pt2Mo2(η5-C5H5)2(CO)6(Ph2PCH2CH2PPh2). Organometallics 1983, 2, 180. 52. P. BRAUNSTEIN, J.-M. JUD, J. FISCHER Synthesis and structure of mixed palladium-manganese complexes with the Ph2PCH2PPh2 ligand. J. Chem. Soc., Chem. Commun. 1983, 5. 53. R. JUND, P. LEMOINE, M. GROSS, R. BENDER, P. BRAUNSTEIN Electrochemical behaviour of mixed tetrametallic clusters with Pd2M2 and Pt2M2 cores (M = Cr, Mo, W). J. Chem. Soc., Chem. Commun. 1983, 86.

P. Braunstein - p 9

54. R. BENDER, P. BRAUNSTEIN Transformation of the cluster Pt3(µ-CO)3(PPh3)4 into Pt5(µ-CO)5(CO)(PPh3)4 upon impregnation onto

inorganic supports. J. Chem. Soc., Chem. Commun. 1983, 334. 55. P. BRAUNSTEIN, I. PRUSKIL, G. PREDIERI, A. TIRIPICCHIO Reactions of NiX2(dppe) (X = Cl, Br) with Na[Co(CO)4]. Synthesis and crystal structure of Co2(µ-CO)2(CO)4

(dppe) (dppe = Ph2PCH2CH2PPh2 ). J. Organomet. Chem. 1983, 247, 227. 56. P. BRAUNSTEIN, D. MATT, Y. DUSAUSOY Complexes of functional phosphines. 5. Rhodium(III) and ruthenium(II) complexes ethyl(diphenylphosphino)

acetate. Synthesis, dynamic behavior, and crystal structure of trans-RuCl2[Ph2PCH2C(O)OC2H5] [Ph2PCH2C(O)OC2H5]2. Reversible CO coordination on a ruthenium(II) complex.

Inorg. Chem. 1983, 22, 2043. 57. P. BRAUNSTEIN, J. ROSE, O. BARS Synthesis and structure of the mixed-metal ruthenium-cobalt alkyne clusters NEt4[RuCo3(µ-CO)2(CO)8(µ4-

η2-PhC≡CPh)] and RuCo2(CO)9(µ3-η2-PhC≡CPh). J. Organomet. Chem. 1983, 252, C101. 58. P. BRAUNSTEIN, D. MATT, Y. DUSAUSOY, J. FISCHER Complexes of functional phosphines. Part VI. Five membered palladium or platinum metallocycles resulting

from nucleophilic attack of α-phosphino carbanions on organonitriles. Synthesis and crystal structure of trans-

Pt[Ph2PC(COOC2H5)C(Ph)NH]2 and Pd Cl[µ-Ph2PCH2C(NH)C(CN)PPh2]Pd [ = o-C6H4CH2N(CH3)2].

Organometallics 1983, 2, 1410. 59. P. BRAUNSTEIN, J. ROSE, Y. DUSAUSOY, J. P. MANGEOT Role of the cation in the reaction of Co(CO)4- with RuCl3,xH2O. Synthesis and molecular structure of the

ruthenium cluster [N(PPh3)2]2[Ru4(µ-Cl)4(µ-CO)2(CO)8]. J. Organomet. Chem. 1983, 253, 125. 60. R. BENDER, P. BRAUNSTEIN, J.-M. JUD, Y. DUSAUSOY Synthesis of tetrametallic planar, triangulated mixed-metal palladium clusters. X-Ray crystal structures of

Pd2M2(η5-C5H5)2(µ3-CO)2(µ2-CO)4(PEt3 )2 with M = Cr, Mo, W. Inorg. Chem. 1983, 22, 3394. 61. R. BENDER, P. BRAUNSTEIN, A. TIRIPICCHIO, M. TIRIPICCHIO CAMELLINI Synthesis of homo and hetero palladium-platinum bimetallic complexes; crystal structure of

Pt2Cl2(µ-CO)(PPh3)3. J. Chem. Soc., Chem. Commun. 1984, 42. 62. P. BRAUNSTEIN, J. FISCHER, D. MATT, M. PFEFFER Relevance to synthetic polynuclear chemistry of novel µ3-coordination modes for the anions

[Ph2PCHC(O)OC2H5]- and [Mo(CO)3Cp]-. Synthesis and X-ray structure of Pd(8-mq)Br [Ph2PCH2C(O)OC2H5], [{Pd(8-mq)}3{µ3-Ph2PCHC(O)OC2H5}(µ3-OH)]PF6 and [{Pd(8-mq)}3{µ3-Mo(CO)3Cp}](µ3-Cl)]BF4.

J. Am. Chem. Soc. 1984, 106, 410. 63. R. BENDER, P. BRAUNSTEIN, B. METZ, P. LEMOINE Unusual four-electron donor bridging [Co(CO)3PPh3]- fragment in the triangulo cluster CoPt2(µ-PPh2)(µ-

CO)2(CO)(PPh3)3: synthesis, structure and electrochemistry. Organometallics 1984, 3, 381. 64. P. BRAUNSTEIN, J. ROSÉ Synthesis of heteropentametallic clusters containing three different metals: MCo3(CO)12M'L (M = Fe, Ru; M'

= Cu, Ag). J. Organomet. Chem. 1984, 262, 223.

P. Braunstein - p 10

65. P. BRAUNSTEIN, C. DE MERIC DE BELLEFON, M. RIES Rational synthesis of mixed-metal clusters with three or four different metals and containing the

Ph2PCH2PPh2 (dppm) ligand. J. Organomet. Chem. 1984, 262, C14. 66. P. BRAUNSTEIN, U. SCHUBERT, M. BURGARD Synthesis and spectroscopic studies of metal-metal-bonded linear heterotrimetallic gold(I) complexes. Crystal

structure of [n-Bu4N][Au{Cr(CO)3(η-C5H5)}2]. Inorg. Chem. 1984, 23, 4057. 67. R. BENDER, P. BRAUNSTEIN, J. M. JUD, Y. DUSAUSOY A comparison of two strategies towards the syntheses of platinum-mixed metal clusters. X-Ray crystal

structure of Pt2M2(η5-C5H5)2(µ3-CO)2(µ2-CO)4(PEt3)2 with M = Cr, Mo and W. Inorg. Chem. 1984, 23, 4489. 68. P. LEMOINE, M. GROSS, P. BRAUNSTEIN, F. MATHEY, B. DESCHAMPS, J. H. NELSON Electrochemistry of phosphaferrocenes. I. Comparison of the redox properties of ferrocene, diphospha-

ferrocene, 3,4-dimethyl-1-phosphaferrocene and 3,3',4,4'-tetramethyl-1,1'-diphosphaferrocene. Organometallics 1984, 3, 1303. 69. P. BRAUNSTEIN, J. ROSÉ, A. TIRIPICCHIO, M. TIRIPICCHIO CAMELLINI Novel co-ordination modes for bimetallic HgCo and HgMo fragments when bonded to clusters; X-ray crystal

structure of RuCo3(µ-CO)3(CO)9[µ3-HgCo(CO)4]. J. Chem. Soc., Chem. Commun. 1984, 391. 70. P. BRAUNSTEIN, H. LEHNER, D. MATT, A. TIRIPICCHIO, M. TIRIPICCHIO CAMELLINI Synthesis of the first Pt-Au cluster by an unexpected H+-substitution at trans-PtH(Cl)L2. Angew. Chem., Int. Ed. Engl. 1984, 23, 304; Angew. Chem. 1984, 96, 307. 71. O. ROSSELL, M. SECO, P. BRAUNSTEIN Chlorinated organic derivatives containing Mo-Hg and W-Hg bonds: importance of the steric effects in their

stabilization. J. Organomet. Chem. 1984, 273, 233. 72. P. BRAUNSTEIN, J. ROSÉ, A. M. MANOTTI-LANFREDI, A. TIRIPICCHIO, E. SAPPA

The replacement of one hydrido-ligand in [ (η -C5H5)NiOs3(µ-H)3(CO)9 ] by MPPh3+ (M = Cu or Au). Crystal structure of [ (η -C5H5)NiOs3(µ-H)2(µ-AuPPh3) (CO)9 ] , the first gold-nickel osmium cluster.

J. Chem. Soc., Dalton Trans. 1984, 1843. 73. P. BRAUNSTEIN, C. DE MÉRIC DE BELLEFON, M. LANFRANCHI, A. TIRIPICCHIO First heterobimetallic complexes with bridging and chelating Ph2PCH2PPh2(dppm): crystal structure of [(η-

C5H4Me)Mo(CO)2(µ-dppm)Pt(dppm)]2[Mo2O7]. Air oxidation of the anions [(η-C5H4R)Mo(CO)3]- into [Mo2O7]2 -.

Organometallics 1984, 3, 1772. 74. O. BARS, P. BRAUNSTEIN, J.-M. JUD PtMn2(CO)12 , a "pure" carbonylheterotrimetallic chain complex. Nouv. J. Chim. 1984, 8, 771. 75. R. JUND, P. LEMOINE, M. GROSS, R. BENDER, P. BRAUNSTEIN Redox behaviour of tetrametallic clusters [M12M22(η5-C5H5 )2(µ3-CO)2(µ-CO)4(PR3)2] (M1 = Pt or Pd; M2 =

Cr, Mo or W; R = Me, Et, nBu or Ph). J. Chem. Soc., Dalton Trans. 1985, 711. 76. P. BRAUNSTEIN, G. L. GEOFFROY, B. METZ Synthesis, structure and dynamic stereochemistry of the bimetallic complex MnPt(µ-H)(µ-CO)(CO)4(PEt3)2

(Mn-Pt). Apparent rotation of a PtL2 unit about a Mn-H bond. Nouv. J. Chim. 1985, 9, 221.


77. P. BRAUNSTEIN, G. PREDIERI, F. J. LAHOZ, A. TIRIPICCHIO Synthesis and crystal structure of trans-[Pt{Fe(CO)3(NO)}2(NCPh)2], a complex containing a linear metal

chain. J. Organomet. Chem. 1985, 288, C13. 78. C. U. PITTMAN, Jr., W. HONNICK, M. ABSI-HALABI, M. G. RICHMOND, R. BENDER, P. BRAUNSTEIN The catalytic activity of low oxidation state platinum- and palladium-containing mixed-metal clusters. J. Mol. Catal. 1985, 32, 177. 79. P. BRAUNSTEIN, H. LEHNER, D. MATT, A. TIRIPICCHIO, M. TIRIPICCHIO CAMELLINI Syntheses and crystal structures of Co2Rh2(η5-C5Me5)2(µ3-CO)2(µ-CO)(CO)4 and Rh(η5-C5Me5)(CO)2. Nouv. J. Chim. 1985, 9, 597. 80. P. BRAUNSTEIN, J. ROSÉ, A. TIRIPICCHIO, M. TIRIPICCHIO CAMELLINI Novel high-nuclearity HgCoRu and HgCoFe sandwich complexes. Synthesis and structure of [Hg{RuCo3

(µ-CO)3(CO)9}]. Angew. Chem., Int. Ed. Engl. 1985, 24, 767; Angew. Chem. 1985, 97, 761. 81. P. BRAUNSTEIN, J. KERVENNAL, J.-L. RICHERT Reductive carbonylation of o-nitrophenol with a Fe-Pd cluster derived heterogeneous catalyst; CO migration

in [FePdPt(CO)4(Ph2 PCH2PPh2)2]. Angew. Chem., Int. Ed. Engl. 1985, 24, 768; Angew. Chem. 1985, 97, 762. 82. P. LEMOINE, M. GROSS, P. BRAUNSTEIN, F. MATHEY, B. DESCHAMPS, J. H. NELSON Electrochemistry of phosphaferrocenes. II. Electrochemical behavior of 3,3',4,4'-tetramethyl 1,1'-diphospha-

ferrocene bonded to M(CO)5 (M = Cr, Mo, W) fragments forming heterometallic complexes with multiple redox centers.

J. Organomet. Chem. 1985, 295, 189. 83. R. BENDER, P. BRAUNSTEIN, A. TIRIPICCHIO, M. TIRIPICCHIO CAMELLINI Skeletal isomerization of the [Pt3(µ-PPh2)3Ph(PPh3)2] cluster by recrystallization in various solvents. Angew. Chem., Int. Ed. Engl. 1985, 24, 861; Angew. Chem. 1985, 97, 862. 84. P. BRAUNSTEIN, J. ROSÉ, A. DEDIEU, Y. DUSAUSOY, J.-P. MANGEOT, A. TIRIPICCHIO, M.

TIRIPICCHIO CAMELLINI Syntheses, structures, and bonding of heteropentametallic clusters [MCo3(CO)12{µ3-M'(EPh3 )}] (M = Fe or

Ru; M' = Cu or Au; E = P or As): X-ray crystal structures of [RuCo3(CO)12{µ3-M'(PPh3)}] (M' = Cu or Au). J. Chem. Soc., Dalton Trans. 1986, 225. 85. P. BRAUNSTEIN, D. MATT, D. NOBEL, S.-E. BOUAOUD, B. CARLUER, D. GRANDJEAN, P. LEMOINE Complexes with functional phosphines. Part 8. Interconversion study of [RuCl2{Ph2PCH2C(O)OEt}L2],

[RuCl2(CO){Ph2PCH2C(O)OEt}L] and [RuCl2(CO)2L2] [L = Ph2PCH2C(O)OEt] under CO. Synthesis and X-ray structure of mer-[RuCl3{Ph2PCH2C(O)OEt}L].

J. Chem. Soc., Dalton Trans. 1986, 415. 86. P. BRAUNSTEIN, D. MATT, D. NOBEL, S.-E. BOUAOUD, D. GRANDJEAN Complexes of functional phosphines. Part 9. Palladium and rhodium complexes with [R2PCH2CO2]- (R = Ph,

c-C6H11) ligands. Crystal and molecular structure of [(o-C6H4CH2NMe2)Pd{Ph2PCH2C(O)O}]. J. Organomet. Chem. 1986, 301, 401. 87. G. NEMRA, P. LEMOINE, P. BRAUNSTEIN, C. DE MÉRIC DE BELLEFON, M. RIES Electrochemistry of clusters. V. Study of binuclear complexes and trinuclear clusters with Pd-Pd and Pd-Pt

bonds stabilized by Ph2PCH2PPh2 ligands. J. Organomet. Chem. 1986, 304, 245. 88. P. BRAUNSTEIN, O. ROSSELL, M. SECO, I. TORRA, X. SOLANS, C. MIRAVITLES Synthesis of heterotrinuclear complexes containing Pt-Hg-M (M = Mo, W) chains via platinum(0) insertion

reactions. Crystal structure of (PPh3)2(C6Cl5)Pt-Hg-W(CO)3)(η-C5H5). Organometallics 1986, 5, 1113.


89. G. PREDIERI, A. TIRIPICCHIO, C. VIGNALI, E. SAPPA, P. BRAUNSTEIN The crystal structure and reactivity of [ (η -C5H5)NiOs3(µ-H)3(CO)8(PPh2H) ] ; 1H and 31P Nuclear

Magnetic Resonance spectroscopic characterization of [ (η -C5H5)NiOs3(µ-H)2(µ-HgBr) (CO)8(PPh2H) ] and related complexes.

J. Chem. Soc., Dalton Trans. 1986, 1135. 90. P. BRAUNSTEIN, A. MÜLLER, H. BÖGGE Crystal structures of the tetra-n-butylammonium salts of the AuCl2-, AuBr2-, and AuI2- ions. Inorg. Chem. 1986, 25, 2104. 91. G. NEMRA, P. LEMOINE, M. GROSS, P. BRAUNSTEIN, C. DE MÉRIC DE BELLEFON, M. RIES Comportement électrochimique de clusters mixtes trinucléaires à squelettes PtCoPd et PdCoPd. Electrochim. Acta 1986, 31, 1205. 92. P. BRAUNSTEIN, T. M. GOMES CARNEIRO, D. MATT, A. TIRIPICCHIO, M. TIRIPICCHIO CAMELLINI Synthesis and structure of [(Ph3P)3Ir(µ3-H)(µ-H)2Ag2(OSO2CF3)(H2O)][CF3SO3), a complex with a bent Ag-

Ir-Ag chain. Angew. Chem., Int. Ed. Engl. 1986, 25, 748; Angew. Chem. 1986, 98, 721. 93. S.-E. BOUAOUD, P. BRAUNSTEIN, D. GRANDJEAN, D. MATT, D. NOBEL Complexes of functional phosphines. 10. Palladium complexes with the ligands Ph2PCH2C(O)Ph,

(Ph2PCH⋅⋅⋅C(⋅⋅⋅O)Ph)-, and Ph2PCH=C(Ph)OPPh2. Crystal and molecular structure of cis- [PdCl2{Ph2PCH=C(Ph)OPPh2}] .

Inorg. Chem. 1986, 25, 3765. 94. O. BARS, P. BRAUNSTEIN, G. L. GEOFFROY, B. METZ Syntheses and dynamic stereochemistry of hydrido-carbonyl heterobinuclear metal-metal bonded complexes.

Crystal structures of MoPt(H)(η-C5H5)(CO)3(PPh3)2 (Mo-Pt) and MnPt(µ-H)(µ-CO)(CO)4(PEt3)2 (Mn-Pt). Organometallics 1986, 5, 2021. 95. J. CALVET, O. ROSSELL, M. SECO, P. BRAUNSTEIN Synthesis and properties of heterotrimetallic complexes containing M-Pt-Hg (M = Mo, W, Fe, Mn or Co)

arrays. J. Chem. Soc., Dalton Trans. 1987, 119. 96. P. BRAUNSTEIN, N. GUARINO, C. DE MERIC DE BELLEFON, J.-L. RICHERT Mixed-metal cluster formation by carbonylmetalate-induced Pt-P bond cleavage in PtCl2(Ph2PCH2PPh2). Angew. Chem., Int. Ed. Engl. 1987, 26, 88. 97. S.-E. BOUAOUD, P. BRAUNSTEIN, D. GRANDJEAN, D. MATT, D. NOBEL Synthesis of a new bifunctional hemilabile ligand by insertion of PhNCO into a co-ordinated β-

phosphinoketonate. Crystal structure of [(o-C4H4CH2NMe2)Pd(Ph2PC[C(O)NHPh][C(Ph)O])] . J. Chem. Soc., Chem. Commun. 1987, 488. 98. P. BRAUNSTEIN, M. A. LUKE, A. TIRIPICCHIO, M. TIRIPICCHIO CAMELLINI Reactions of [Pd2(µ-dppm)2Cl]2 with electrophilic complexes of copper and gold. Synthesis of the Pd4 cluster

[Pd4(µ-Cl)2(µ-dppm)4](PF6)2•2(CH3)2CO. Angew. Chem., Int. Ed. Engl. 1987, 26, 768. 99. P. BRAUNSTEIN, B. OSWALD Reactivity of anionic metal carbonyl hydrides toward bis(diphenylphosphino)methane complexes of palladium

and platinum. J. Organomet. Chem. 1987, 328, 229. 100. P. BRAUNSTEIN, D. MATT, D. NOBEL, J. FISCHER Phosphorus double fonctionalisation by template condensations; formation of P-C and P-O bonds from

metallocycles. Synthesis and crystal structure of cis-[PdCl2{Ph2PCH=C(Ph)OP(Ph)(o-C6H4CH2 NMe2H)}]Cl. J. Chem. Soc., Chem. Commun. 1987, 1530. 101. P. BRAUNSTEIN, M. LAKKIS, D. MATT, S. LECOLIER Synthesis of anisole by Lewis-acid catalyzed decarboxylation of methyl phenyl carbonate. J. Mol. Catal. 1987, 42, 353.


102. P. BRAUNSTEIN, C. DE MERIC DE BELLEFON, M. RIES, J. FISCHER Synthesis and reactivity of Pd2Mn, MPdFe, MPdMn2, and MPdFe2 clusters (M = Pd, Pt) stabilized by

Ph2PCH2PPh2(dppm) ligands. Crystal structure of [Pd2Mn2(µ3-CO)(µ-CO)(CO)7(µ-dppm)2]. Organometallics 1988, 7, 332. 103. P. BRAUNSTEIN, D. MATT, D. NOBEL, F. BALEGROUNE, S.-E. BOUAOUD, D. GRANDJEAN, J. FISCHER Complexes of functional phosphines. Part 11. β-Ketophosphine complexes of nickel, palladium and platinum.

Crystal structures of trans-NiX2L2 (X = Cl or I; HL = Ph2PCH2C(O)Ph). J. Chem. Soc., Dalton Trans. 1988, 353. 104. P. BRAUNSTEIN, D. MATT, D. NOBEL Carbon dioxyde activation and catalytic lactone synthesis by telomerization of butadiene and CO2. J. Am. Chem. Soc. 1988, 110, 3207. 105. P. BRAUNSTEIN, C. DE MERIC DE BELLEFON, M. RIES, J. FISCHER, S.-E. BOUAOUD, D. GRANDJEAN Tri- and tetranuclear palladium-cobalt clusters containing bridging Ph2PCH2(dppm) ligands. Crystal

structures of [Pd2Co2(µ3-CO)2(CO)5(µ-dppm)2] and [Pd2Co2(µ3-CO)2(µ-dppm)2][PF6]. Inorg. Chem. 1988, 27, 1327. 106. P. BRAUNSTEIN, C. DE MERIC DE BELLEFON, M. RIES Synthesis and reactivity of Ph2PCH2PPh2(dppm)-stabilized Pd-Co and Pd-Pt-Co clusters. Effect of platinum

vs. palladium on the neighboring Pd-center. Inorg. Chem. 1988, 27, 1338. 107. S.-E. BOUAOUD, P. BRAUNSTEIN, D. GRANDJEAN, D. MATT, D. NOBEL Complexes with functional phosphines. Part XII. Carbon-carbon coupling reactions by isocyanate insertion

into nickel, palladium and platinum-coordinated β-phosphino-enolates. Molecular structures of [(C10H8N)Pd(Ph2PC{C(O)OEt}{C(O)NHPh})] and cis-[Ni(Ph2PC{C(O)Ph}{C(O)NH(p-MeC6H4)})2]•CH2Cl2.

Inorg. Chem. 1988, 27, 2279. 108. P. BRAUNSTEIN, R. DEVENISH, P. GALLEZOT, B. T. HEATON, C. J. HUMPHREYS, J. KERVENNAL, S.

MULLEY, M. RIES Formation, catalytic activity of silica-supported, mixed-metal cluster-derived, Fe-Pd bimetallic particles and

their fate during the catalytic carbonylation of aromatic nitro compounds. Angew. Chem., Int. Ed. Engl. 1988, 27, 927; Angew. Chem. 1988, 100, 972. 109. P. BRAUNSTEIN, S. FREYBURGER, O. BARS Synthesis of Pt-Cu, Pt-Ag and Pt-Au clusters and crystal structure of the copper(I)-platinum(0) cluster

[CuPt3(µ-CO)3(PPh3)5]BF4. J. Organomet. Chem. 1988, 352, C29. 110. P. BRAUNSTEIN, M. A. LUKE, A. TIRIPICCHIO, M. TIRIPICCHIO CAMELLINI An unusual mixed-valence palladium(I)-palladium(II) cluster: crystal structure of [Pd4(µ-Cl)3(µ-dppm)2Cl2]

[BF4] (dppm = Ph2PCH2PPh2) New J. Chem. 1988, 12, 429. 111. Th. BLUM, P. BRAUNSTEIN, A. TIRIPICCHIO, M. TIRIPICCHIO CAMELLINI Heterometallic complexes containing a µ-PCy2 bridge. Synthesis and crystal structure of the tungsten-

platinum-gold complex [Cp(OC)2W(µ-PCy2)(µ-AuPPh3)Pt(CO)(PCy2H)][PF6] (Cy = c-C6H11; Cp = η-C5H5). New J. Chem. 1988, 12, 539. 112. F. BALEGROUNE, P. BRAUNSTEIN, D. GRANDJEAN, D. MATT, D. NOBEL Reactivity of coordinated phosphino enolates and metallacycles toward chlorophosphines with

diastereoselective formation of P-O and P-C bonds. Alkaline hydrolysis of coordinated phosphinites leading to oxodiarylphosphinoranido ligands. Synthesis and molecular structure of cis-[Pd{Ph2PCH=C(O)Ph} {PhP(O)(CH2C9H6N)}].

Inorg. Chem. 1988, 27, 3320. 113. P. BRAUNSTEIN, M. RIES, C. DE MERIC DE BELLEFON, Y. DUSAUSOY, J.-P. MANGEOT Synthesis and reactivity of mixed-metal Pd2Mo, PdPtMo and Pd2W clusters containing Ph2PCH2PPh2

(dppm) ligands. Molecular structure of [Pd2MoCl(η -C5H5) (µ3-CO)2(µ-dppm)2 ] . J. Organomet. Chem. 1988, 355, 533.


114. M. FERRER, O. ROSSELL, M. SECO, P. BRAUNSTEIN Syntheses and dynamic stereochemistry of methyl- and phenyl carbonyl heterobinuclear metal-metal bonded

complexes. J. Chem. Soc., Dalton Trans. 1989, 379. 115. M. FERRER, O. ROSSELL, M. SECO, P. BRAUNSTEIN Synthesis of anionic antimony-iron and bismuth-iron clusters. J. Organomet. Chem. 1989, 364, C5. 116. P. BRAUNSTEIN, T. M. GOMES CARNEIRO, D. MATT, F. BALEGROUNE, D. GRANDJEAN β-Keto phosphines derived from ferrocene. Syntheses and structures of [Ph2PCH2C(O)(η5-C5H4)Fe(η5-

C5H5] (L1) and trans-[PdCl2L12]. J. Organomet. Chem. 1989, 367, 117. 117. P. BRAUNSTEIN, E. DE JESUS The metallophosphine Ph2PW(CO)3Cp as precursor of the "Ph2PW(CO)2Cp" fragment; its ethylene-like

displacement from its complexes with platinum(0). J. Organomet. Chem. 1989, 365, C19. 118. P. BRAUNSTEIN, E. DE JESUS, A. TIRIPICCHIO, M. TIRIPICCHIO CAMELLINI Phosphido-bridged heterodinuclear complexes of CrPd, MoPd, WPd, and MnPd. X-Ray crystal structures of

[Cp(CO)2Mo(µ-PCy2)Pd(PCy2H)2] and [(CO)4Mn(µ-PCy2)Pd(PCy2H)2]. J. Organomet. Chem. 1989, 368, C5. 119. R. BENDER, P. BRAUNSTEIN, A. DEDIEU, Y. DUSAUSOY Agostic-type gold ligand and incipient µ3-PPh2 coordination in the Au2Pt2P6 "Hammock" skeleton of the

cluster [Au2Pt2(µ-PPh2)2(PPh3)4][PF6]2.. Angew. Chem., Int. Ed. Engl. 1989, 28, 923; Angew. Chem. 1989, 101, 931. 120. F. CASTAGNO, M. CASTIGLIONI, E. SAPPA, A. TIRIPICCHIO, M. TIRIPICCHIO CAMELLINI, P.

BRAUNSTEIN, J. ROSÉ Synthesis and crystal structure of [NiOs3(η-C5H5)(µ-H)2{µ-Cu(PPh3)}(CO)9]. Hydrogenation-

dehydrogenation reactions of dienes and alcohols with heterogeneous catalysts derived from [NiM3(η-C5H5) (µ-H)2(µ-X)(CO)9] [M = Ru, X = H ; M = Os, X = Cu(PPh)3].

J. Chem. Soc., Dalton Trans. 1989, 1477. 121. P. BRAUNSTEIN, M. KNORR, A. TIRIPICCHIO, M. TIRIPICCHIO CAMELLINI Complexes with an η2-µ2-SiO bridge. Structure of the bimetallic complex [Fe(CO)3{µ-Si(OMe)2OMe}

(µ-dppm)PdCl] (Fe-Pd). Angew. Chem., Int. Ed. Engl. 1989, 28, 1361; Angew. Chem. 1989, 101, 1414. 122. P. BRAUNSTEIN, T. M. GOMES CARNEIRO, D. MATT Complexes with functional phosphines. 14. Coupling reactions of MeO2CC≡CCO2Me with β-phosphino

ketonate complexes leading to nickel, palladium, and platinum alkenyl complexes. Organometallics 1989, 8, 1737. 123. T. BLUM, P. BRAUNSTEIN Reactivity of tungsten-platinum bimetallic dicyclohexylphosphido-bridged complexes. Synthesis of W—Pt—

Cu and W—Pt—Ag clusters from the electron-rich complex [Cp(OC)2W(µ-PCy2)Pt(CO)(PCy2H)]. Organometallics 1989, 8, 2497. 124. T. BLUM, P. BRAUNSTEIN, A. TIRIPICCHIO, M. TIRIPICCHIO CAMELLINI Reactivity of molybdenum-platinum bonds toward PPh2H: Synthesis of phosphido-bridged, heterometallic

complexes. Molecular structures of [(η-C5H5)2Mo2Pt(µ-PPh2)2(CO)5]⋅1/2C7H8 and of the hydrido, tetranuclear, bent-chain complex [(η-C5H5)MoPt(H)(µ-PPh2)2(CO)2]2 (Ph = C6H5).

Organometallics 1989, 8, 2504. 125. P. BRAUNSTEIN, R. BENDER, J.-M. JUD Cyclopentadienylsodium and some mono-, tri-, and tetranuclear metal carbonyl derivatives and cluster

complexes. Inorg. Synth. 1989, 26, 341-350.


126. P. BRAUNSTEIN, J. ROSÉ Stepwise syntheses of ruthenium mixed-metal cluster complexes. Inorg. Synth. 1989, 26, 356-360. 127. R. BENDER, P. BRAUNSTEIN, D. BAYEUL, Y. DUSAUSOY An unusual mixed-metal cluster: synthesis and molecular structure of FePt5(CO)9)(PEt3)4. Inorg. Chem. 1989, 28, 2381. 128. F. BALEGROUNE, P. BRAUNSTEIN, T. M. GOMES CARNEIRO, D. GRANDJEAN, D. MATT Bis-alkenyl complexes of nickel, palladium and platinum from co-ordinated phosphino-enolates: X-ray

structures of (R,S)-cis-[Pd{Ph2PCH[C(O)Ph][(MeO2C)C=C(CO2Me)]}2] and [(o-C6H4CH2NMe2) Pd{Ph2PC[=C(O)Ph][(MeO2C)C=C(H)(CO2Me)]}].

J. Chem. Soc., Chem. Commun. 1989, 582. 129. R. BENDER, P. BRAUNSTEIN, J.-L. RICHERT, Y. DUSAUSOY Synthesis and reactivity of iron-platinum carbonyl clusters containing monodentate phosphine ligands.

Molecular structure of [Fe2Pt(CO)8(PEt3)2]. New. J. Chem. 1990, 14, 569. 130. P. BRAUNSTEIN, M. KNORR, B. E. VILLARROYA, J. FISCHER Occurrence of an η2-µ2-SiO bridge in bimetallic complexes. Synthesis of dppm-stabilized Si-Fe-M (M = Rh,

Cu, Hg) complexes and crystal structure of Fe(CO)3{Si(OMe)3}(µ-dppm)Cu(AsPh3) (dppm = Ph2PCH2PPh2). New. J. Chem. 1990, 14, 583. 131. P. BRAUNSTEIN, C. DE MÉRIC DE BELLEFON, M. RIES Stepwise synthesis and reactivity of Ph2PCH2PPh2-stabilized mixed-metal clusters containing three or four

different metals. Inorg. Chem. 1990, 29, 1181. 132. P. BRAUNSTEIN, B. OSWALD, A. TIRIPICCHIO, M. TIRIPICCHIO CAMELLINI Novel bonding mode for a cyanometallate ligand: synthesis and crystal structure of the Pd4Mn4 cluster

[(OC)Pd(µ-CN)Mn(η-C5H4Me)(CO)2]4 containing a meso arrangement of helical units. Angew. Chem., Int. Ed. Engl. 1990, 29, 1140; Angew. Chem. 1990, 102, 1206. 133. P. BRAUNSTEIN, J.-L. RICHERT, Y. DUSAUSOY Bis(diphenylphosphinomethane)-assisted synthesis of iron-platinum and iron-palladium clusters. Crystal

structures of [Fe2Pt(µ-dppm)(CO)8] and [FePt2(µ-dppm)(CO)6] (dppm = Ph2PCH2PPh2). J. Chem. Soc., Dalton Trans. 1990, 3801. 134. P. BRAUNSTEIN, H. LEHNER, D. MATT A platinum-gold cluster: chloro-1κCl bis(triethylphosphine)-1κP)bis-triethylphosphine)-2κP, 3κP-triangulo

digold-platinum (1+) trifluoromethanesulfonate). Inorg. Synth. 1990, 27, 218. 135. P. BRAUNSTEIN, M. KNORR, H. PIANA, U. SCHUBERT Synthesis and structure of bimetallic allyl, alkoxysilyl complexes [Fe{Si(OMe)3}(CO)3(µ-dppm)M(η3-2-

RC3H4)] (M = Pd, Pt; R = H, Me), and of [Fe{µ-Si(OMe)2(OMe)}(CO)3(µ-dppm)Pd(SnPh3)], a Sn-Pd-Fe-Si chain complex with an µ2-η2-SiO bridge.

Organometallics 1991, 10, 828. 136. P. BERNO, P. BRAUNSTEIN, C. FLORIANI, A. CHIESI-VILLA, C. GUASTINI Diastereoselective synthesis of the bis(phosphinoenolato)nickel(II) complex cis-{Ni[Ph2PCH=C(O)Fe(η-

C5H5)(CO)(PPh3)]2}, derived from (η-C5H5)Fe(CO)(PPh3)C(O)CH2PPh2 and the corresponding crystal structures.

Inorg. Chem. 1991, 30, 1407. 137. P. BRAUNSTEIN, M. KNORR, U. SCHUBERT, M. LANFRANCHI, A. TIRIPICCHIO Synthesis and reactivity of phosphine-substituted, hydrido silyl complexes mer-

[HFe(SiR3)(CO)3{Ph2P(CH2)nPPh2}] (n = 1, 4), mer-[HFe{Si(OMe)3}(CO)3(Ph2PH)] and mer HFe{Si(OMe)3}(CO)3{Ph2PCH2C(O)Ph}]. Synthesis of bimetallic Cu-Fe, Ag-Fe and Au-Fe complexes and crystal structure of mer-[(Ph3P)Cu(µ-dppm)Fe{Si(OMe)3}(CO)3].

J. Chem. Soc., Dalton Trans. 1991, 1507.


138. P. BRAUNSTEIN, C. DE MÉRIC DE BELLEFON, S.-E. BOUAOUD, D. GRANDJEAN, J.-F. HALET, J.-Y. SAILLARD

Cluster core isomerization from planar to tetrahedral: experimental and theoretical aspects. steric control by the ligands of cluster geometry. Synthesis and crystal structure of [Pt2Mo2(η-C5H4CH3)2(CO)6(PCy3)2].

J. Am. Chem. Soc. 1991, 113, 5282. 139. P. BRAUNSTEIN, J. ROSÉ, P. GRANGER, T. RICHERT 59Co and 99Ru NMR investigation of heterometallic carbonyl clusters. Reactivity of [MCo3(CO)12]- (M = Fe,

Ru) towards NO+; Formation of RuCo3(CO)11(NO) and FeCo2(µ3-NH)(CO)9. Magn. Reson. Chem. 1991, 29, S31-37. 140. P. BRAUNSTEIN, J. ROSÉ, P. GRANGER, J. RAYA, S.-E. BOUAOUD, D. GRANDJEAN 59Co NMR study of cluster reactions: solvent and ligand effects in mixed-metal, tetrahedral MCo3 (M = Fe,

Ru) carbonyl clusters. Crystal structure of FeCo3(µ3-H)(µ-CO)3(CO)8(PPh2H). Organometallics 1991, 10, 3686. 141. P. BRAUNSTEIN, M. KNORR, E. VILLARROYA, A. DECIAN, J. FISCHER Synthesis and reactivity of bimetallic alkoxysilyl complexes. Structure of [Fe(CO)3{µ-Si(OMe)2(OMe)}(µ-

dppm)Rh(CO)] (dppm = Ph2PCH2PPh2): a complex with a µ2-η2-SiO bridge between iron and rhodium. Organometallics 1991, 10, 3714. 142. P. BRAUNSTEIN, B. OSWALD, A. DECIAN, J. FISCHER Synthesis and reactivity of bis(diphenylphosphino)methane (dppm)-bridged Pd-Mo and Pd-W complexes.

Crystal structure of [Pd(µ-CO)(µ-dppm)2Mo(Cp)(CO)][PF6] (Cp = η5-C5H5). J. Chem. Soc., Dalton Trans. 1991, 2685. 143. F.-Y. JIAO, Y.-Q. YIN, P. BRAUNSTEIN, J. ROSÉ Syntheses and characterization of heteronuclear clusters Co3Ru(CO)11(NO) and (RC≡CR)Co3Ru(CO)9(NO). Acta Chim. Sinica 1991, 49, 711. 144. P. BRAUNSTEIN, L. DOUCE, M. KNORR, M. STRAMPFER, M. LANFRANCHI, A. TIRIPICCHIO Synthesis of dppm-Stabilized Si-Fe-M (M = Zn, Cd, Hg or Tl) Complexes and Crystal Structure of a

Heterotetranuclear Fe2Cd2 Complex (dppm = Ph2PCH2PPh2). J. Chem. Soc., Dalton Trans. 1992, 331. 145. P. BRAUNSTEIN, S. COCO CEA, M. I. BRUCE, B. W. SKELTON, A. H. WHITE Synthesis and Characterization of Ruthenium Clusters with Ketophosphine Ligands. Crystal Structure of the

Cluster [Ru3(µ-H){µ-η1(O):η2(P,O)-O(...CPh)...CHPPh2}(CO)9] Containing a Bridging Phosphinoenolate Ligand.

J. Organomet. Chem. 1992, 423, C38. 146. P. BRAUNSTEIN, E. de JESUS, A. DEDIEU, M. LANFRANCHI, A. TIRIPICCHIO Phosphido-bridged Heterodi-, Heterotri-, and Heterotetranuclear Complexes of Palladium and Platinum with

Transition Metals. Crystal Structure of [{(CO)4Mn(µ-PPh2)}2Pt(PPh3)] (Mn-Mn, 2Mn-Pt). Inorg. Chem. 1992, 31, 399. 147. P. BRAUNSTEIN, E. de JESUS, M. LANFRANCHI, A. TIRIPICCHIO, F. UGOZZOLI Electrophilic Additions to Phosphido-Bridged Palladium and Platinum-Transition Metal Bonds. Synthesis and

Crystal Structure of the Heterotetranuclear Cluster [{Cp(OC)2W(µ-CO)(µ-PPh2)}{Cp(OC)2W(µ-AuPPh3)(µ-PPh2)}Pt][PF6].2THF (Au-Pt, Au-W, 2W-Pt) (THF = Tetrahydrofuran).

Inorg. Chem. 1992, 31, 411. 148. P. BRAUNSTEIN, E. COLOMER, M. KNORR, A. TIRIPICCHIO, M. TIRIPICCHIO-CAMELLINI Occurrence of a µ2-η2-Si-F Interaction in Bimetallic Trifluorosilyl Complexes. J. Chem. Soc., Dalton Trans. 1992, 903. 149. P. BRAUNSTEIN, J. ROSÉ, A. TIRIPICCHIO, M. TIRIPICCHIO CAMELLINI Hexa- and Nona-nuclear Heterometallic Clusters Based on Mercury-capped MCo3 (M = Fe or Ru)

Tetrahedral Units. J. Chem. Soc., Dalton Trans. 1992, 911.


150. P. BRAUNSTEIN, L. DOUCE, J. FISCHER, N. C. CRAIG, G. GOETZ-GRANDMONT, D. MATT Synthesis and crystal structure of cis-[Pd{Ph2PCH2C(O)Ph}2][BF4][B2F7]. Unexpected formation and first

structural characterisation of the heptafluorodiborate anion [B2F7]-. Inorg. Chim. Acta 1992, 194, 151. 151. P. BRAUNSTEIN, L. MOUREY, J. ROSÉ, P. GRANGER, T. RICHERT, F. BALEGROUNE, D. GRANDJEAN Selectivity in Substitution Chemistry of Mixed-Metal, Tetrahedral MCo3 (M = Fe, Ru) Carbonyl Clusters: 59Co

NMR Study and Crystal Structure of RuCo3(µ3-H)(µ-CO)3(CO)8(NMe3). Organometallics 1992, 11, 2628. 152. P. BRAUNSTEIN, S. COCO CEA, M. I. BRUCE, B. W. SKELTON, A. H. WHITE Complexes with Functional Phosphines. Part 18. Ruthenium Complexes and Clusters with Ketophosphine or

Phosphino Enolate Ligands. Crystal Structure of [Ru(µ-Cl){Ph2PCH...C(...O)Ph}(CO)2]2. J. Chem. Soc., Dalton Trans. 1992, 2539. 153. P. BRAUNSTEIN, F.-Y. JIAO, J. ROSÉ, P. GRANGER, F. BALEGROUNE, O. BARS, D. GRANDJEAN Structural and 59Co NMR Study of Heterosite Reactivities of Alkynes in Ru-Co Carbonyl, Nitrosyl Clusters. J. Chem. Soc., Dalton Trans. 1992, 2543. 154. P. BRAUNSTEIN, M. KNORR, A. TIRIPICCHIO, M. TIRIPICCHIO CAMELLINI Competing Metal-Metal Bonding in Heterometallic Complexes of Au and Hg. Synthesis of Contrasting Fe-Au-

Au-Fe and Fe-Hg-Fe Complexes. Inorg. Chem. 1992, 31, 3685. 155. P. BRAUNSTEIN, L. DOUCE, F. BALEGROUNE, D. GRANDJEAN, D. BAYEUL, Y. DUSAUSOY, P.

ZANELLO Complexes with Functional Phosphines. Part 19. Synthesis and Electrochemistry of Rhenium Complexes

with Ketophosphine and Phosphinoenolate Ligands. Crystal Structures of fac-[ReBr(CO)3{Ph2PCH2C(O)(η5-C5H4)Fe(η5-C5H5)} ] and [Me4N] [ fac -ReClBr {Ph2PCH. . .C( . . .O)Ph}(CO)2 ] .

New. J. Chem. 1992, 16, 925. 156. P. BRAUNSTEIN, S. COCO CEA, A. DECIAN, J. FISCHER Complexes with Functional Phosphines. Part 20. Synthesis of Iron Complexes with Ketophosphine Ligands

and Crystal Structure of the Bis(phosphinoenolato) Complex cis-[Fe{Ph2PCH...C(...O)Ph}(CO)2]. Inorg. Chem. 1992, 31, 4203. 157. P. BRAUNSTEIN, M. KNORR, B. HIRLE, G. REINHARD, U. SCHUBERT First Metal to Metal Silyl Migration in a Heterometallic Complex. Crystal Structure of [(OC)4Fe(µ-PPh2)

Pt{Si(OMe)3}(PPh3)] Angew. Chem., Int. Ed. Engl. 1992, 31, 1583; Angew. Chem. 1992, 104, 1641. 158. M. KNORR, P. BRAUNSTEIN Synthesis of Siloxane-Substituted Heterometallic Fe-Pd, Fe-Pt and Fe-Re Complexes. Bull. Soc. Chim. Fr. 1992, 129, 663-666. 159. F. BALEGROUNE, P. BRAUNSTEIN, L. DOUCE, Y. DUSAUSOY, D. GRANDJEAN, M. KNORR, M.

STRAMPFER Complexes with Functional Phosphines. Part 21. Synthesis and Crystal Structures of Heterobimetallic Fe-Cd,

Fe-Zn and Fe-In Complexes Containing Hemilabile Phosphorus/Oxygen and Silicon/Oxygen Bridging Ligands.

J. Cluster Sc. 1992, 3, 275-296. 160. F. JIAO, Y. YUANQI, P. BRAUNSTEIN, J. ROSE Synthesis and characterization of the mixed-metal clusters of (PhC≡CPh), (PhCH=CPh)Co3Ru(CO)9 and

(PPh3)Fe2Co(CO)7(NO)S. Wuji Huaxue Xuebao 1992, 8, 459-461. 161. G. REINHARD, M. KNORR, P. BRAUNSTEIN, U. SCHUBERT, S. KHAN, C. E. STROUSE, H. D. KAESZ, A.

ZINN Darstellung der zweikernigen Silyl-Komplexe (CO)3(R3Si)Fe(µ-PR'R")Pt(PPh3)2 (Fe-Pt) durch oxidative

Addition von (CO)3(R'R"HP)Fe(H)SiR3 an (C2H4)Pt(PPh3)2. Chem. Ber. 1993, 126, 17-21.


162. M. KNORR, T. FAURE, P. BRAUNSTEIN Reactions of Electrophiles with the Heterobimetallic Fe-Pt Complex [(OC)3Fe{µ-CN(2,6-xylyl)}(µ-dppm)

Pt(PPh3)] Containing a Bridging Isonitrile Ligand and its Transformation to µ-Aminocarbyne Complexes. J. Organomet. Chem. 1993, 447, C4-C6. 163. P. BRAUNSTEIN, C. DE MÉRIC DE BELLEFON, B. OSWALD, M. RIES, M. LANFRANCHI, A. TIRIPICCHIO Dppm-Assisted Synthesis and Reactivity of Bimetallic M-Mo, M-W, M-Co, M-Mn (M = Pt or Pd) Complexes.

Crystal Structure of [(η-C5H5)(CO)2W(µ-dppm)Pt(η2-dppm)][PF6].CH2Cl2 (dppm = Ph2PCH2PPh2). Inorg. Chem. 1993, 32, 1638-1648. 164. P. BRAUNSTEIN, C. DE MÉRIC DE BELLEFON, B. OSWALD Carbonylmetalate-Induced Phosphorus Migration and Ph2PCH2PPh2 (dppm)-Assisted Synthesis of

Bimetallic Complexes and Clusters of Pd and Pt with Mo, W, Mn and Co. Inorg. Chem. 1993, 32, 1649-1655. 165. G. REINHARD, B. HIRLE, U. SCHUBERT, M. KNORR, P. BRAUNSTEIN, A. DECIAN, J. FISCHER Reaction of Anionic Silyl Complexes [Fe(CO)3(SiR3)(PR'3)]- with CdX2 (X = Cl, Br) to Probe the Influence of

PR'3 and X on Nuclearity and Geometry of the Resulting Polynuclear Complexes. Inorg. Chem. 1993, 32, 1656-1661. 166. P. BRAUNSTEIN, D. CAUZZI, D. KELLY, M. LANFRANCHI, A. TIRIPICCHIO Reactivity of the Cyanometalate Na[Cp'Mn(CO)2CN] with Titanium, Zirconium, and Hafnium Halides. Crystal

and Molecular Structure of the µ-Cyano µ-Oxo Tetranuclear Complex [Cp2Zr{(µ-NC)MnCp'(CO)2}]2(µ-O) (Cp = η-C5H5; Cp' = η-MeC5H4).

Inorg. Chem. 1993, 32, 3373-3377. 167. P. BRAUNSTEIN, M. KNORR, T. STÄHRFELDT, A. DECIAN, J. FISCHER Electrophilic additions to the bimetallic silyl complexes [(OC)3{(MeO)3Si}Fe(µ-PR2)Pt(1,5-COD)] (R = Ph,

Cy). Crystal Structure of [(OC)3Fe(µ-PCy2)(µ-Au(PPh3)Pt(1,5-COD)][PF6] (Cy = c-C6H11). J. Organomet. Chem. 1993, 459, C1-C5 (invited paper, volume dédié à E. O. Fischer). 168. J. ANDRIEU, P. BRAUNSTEIN, A. D. BURROWS The Synthesis of Ph2PCH2C(O)NPh2 and the Coordination of Functional Phosphines with Pd(dba)2 and

Pd(0) Complexes. J. Chem. Res. (S) 1993, 380-381. 169. P. BRAUNSTEIN, T. FAURE, M. KNORR, F. BALEGROUNE, D. GRANDJEAN Bimetallic alkoxysilyl complexes with bis(diphenylphosphino)methane, 2-(diphenylphosphino)pyridine or

(diphenylphosphino)acetophenone ligands: crystal structure of [Fe{µ-Si(OMe)2(OMe)}(CO)3(µ-dppm) Pt(C≡NR][PF6] (R = 2,6-xylyl).

J. Organomet. Chem. 1993, 462, 271-286 (invited paper, volume dédié à M. F. Lappert). 170. P. BRAUNSTEIN, D. G. KELLY, A. TIRIPICCHIO, F. UGOZZOLI Complexes with Functional Phosphines. Cobalt(II) Complexes with ß-Keto Phosphines and Corresponding

Cobalt(III) Enolates. Crystal and Molecular Structures of the fac and mer Isomers of [Co{Ph2PCH...C(...O)Ph}3].

Inorg. Chem. 1993, 32, 4845-4852. 171. P. VEYA, C. FLORIANI, A. CHIESI-VILLA, C. GUASTINI, A. DEDIEU, F. INGOLD, P. BRAUNSTEIN Complexes with Functional Phosphines. Experimental and Theoretical Studies on the Reactivity of α-

Phosphino Enolates. Crystal Structures of [K(18-crown-6)][Ph2PCH...C(...O)Ph] and [K(Kryptofix-2,2,2)] [Ph2PCH...C(...O)Ph].

Organometallics 1993, 12, 4359-4367. 172. M. M. HARDING, B. KARIUKI, A. J. MATHEWS, A. K. SMITH, P. BRAUNSTEIN Reaction of the Unsaturated Triosmium Cluster [Os3H(CO)8{Ph2PCH2P(Ph)C6H4}] with HBF4 and

[Au(PPh3)]PF6; Crystal Structure of [Os3AuH(CO)8{Ph2PCH2P(Ph)C6H4}(PPh3)]PF6. J. Chem. Soc., Dalton Trans. 1994, 33-36.


173. P. BRAUNSTEIN, M. KNORR, M. STRAMPFER, A. DECIAN, J. FISCHER Synthetic, Spectroscopic and Structural Studies on Phosphine-stabilised [PPh3, Ph2PCH2PPh2,

Ph2P(CH2)4PPh2, (Ph2P)C5H4N] Main Group Element-Iron-Silicon Chain Complexes. J. Chem. Soc., Dalton Trans. 1994, 117-134. 174. P. BRAUNSTEIN, D. G. KELLY, Y. DUSAUSOY, D. BAYEUL, M. LANFRANCHI, A. TIRIPICCHIO Complexes with Functional Phosphines. PPh3 and ß-Ketophosphine Complexes of Cobalt(II). Crystal and

Molecular Structures of CoCl2[Ph2PCH2C(O)Ph]2 and Co2(CO)6[Ph2PCH2C(O)Ph]2 and of the Trinuclear, Mixed-Metal Complex [(Ph3P)2Ag(µ-Cl)2Co(µ-Cl)2Ag(PPh3)2].0.5 OEt2.

Inorg. Chem. 1994, 33, 233-242. 175. M. KNORR, T. STÄHRFELDT, P. BRAUNSTEIN, G. REINHARD, P. HAUENSTEIN, B. MAYER, U.

SCHUBERT, S. KHAN, H. D. KAESZ Synthese neuartiger heteronuklearer Silyl-zweikernkomplexe (OC)3(R3Si)Fe(µ-PR'R")Pt(1,5COD)(Fe-Pt),

Phosphan-Austauschreaktionen an (OC)3(R3Si)Fe(µ-PR'R")Pt(PPh3)2(Fe-Pt) und Darstellung der Dihydrido-Komplexe [(OC)3Fe(µ-PPh2)(µ-H)2Pt(PR3)2][BF4](Fe-Pt).

Chem. Ber. 1994, 127, 295-304. 176. C. J. ADAMS, M. I. BRUCE, P. A. DUCKWORTH, P. A. HUMPHREY, O. KÜHL, E. R. T. TIEKINK, W. R.

CULLEN, P. BRAUNSTEIN, S. COCO CEA, B. W. SKELTON, A. H. WHITE Some Complexes Obtained from Reactions between M3(CO)12 (M = Ru or Os) or Ru3(µ-dppm)(CO)10 and

2-substituted Triphenylphosphines and Related Keto-Phosphine Ligands. J. Organomet. Chem. 1994, 467, 251-281. 177. P. BRAUNSTEIN, M. KNORR, M. STRAMPFER, Y. DUSAUSOY, D. BAYEUL, A. DECIAN, J. FISCHER, P.

ZANELLO Synthesis, Structure and Electrochemistry of Ph2PCH2PPh2-Bridged Heterometallic Complexes containing a

(η-C5H4Me)Mn(CO)2 Fragment. J. Chem. Soc., Dalton Trans. 1994, 1533-1547. 178. P. BRAUNSTEIN, J. ROSÉ, D. TOUSSAINT, S. JÄÄSKELÄINEN, M. AHLGREN, T. A. PAKKANEN, J.

PURSIAINEN, L. TOUPET, D. GRANDJEAN Site-Selective Substitution Reactions and Isomerizations in Tetrahedral MCo3 Carbonyl Clusters (M = Fe, Ru)

with N, P, S and Te Donor Ligands. Crystal Structure of HRuCo3(CO)10(PMe2Ph)2 and HRuCo3(CO)9(PMe2Ph)3.

Organometallics 1994, 13, 2472-2479. 179. P. BRAUNSTEIN, M. KNORR, M. STRAMPFER, A. TIRIPICCHIO, F. UGOZZOLI Chain Core Isomerism in dppm-Bridged Polymetallic Complexes. Synthesis, Reactivity and Structure of Fe-

Hg-Pt, Fe-Sn-Pt, and Fe-Pd-Sn Arrays (dppm = Ph2PCH2PPh2). Organometallics 1994, 13, 3038-3053. 180. J. B. BALLIF, P. BRAUNSTEIN, A. D. BURROWS, R. D. ADAMS, W. WU The Synthesis of Platinum and Palladium Cluster Compounds with Isonitrile or Functionalised Phosphine

Ligands. Crystal Structures of [Pt5(CO)(µ-CO)5{Ph2PCH2C(O)Ph}4] and [Pt5(µ-CNC6H3Me2-2,6)3 (CNC6H3Me2-2,6)5{Ph2PCH2C(O)Ph}2]

J. Cluster Sc. 1994, 5, 443-466. 181. P. BRAUNSTEIN, M. KNORR, T. STÄHRFELDT Heterobimetallic Templates for Carbon-Carbon Bond Formation by Migratory Insertion Reactions Involving

CO, Isonitriles or Olefins. J. Chem. Soc., Chem. Commun. 1994, 1913-1914. 182. P. BRAUNSTEIN, Y. CHAUVIN, S. MERCIER, L. SAUSSINE, A. DECIAN, J. FISCHER Intramolecular O-H..O-Ni and N-H..O-Ni Hydrogen Bonding in Nickel Diphenylphosphinoenolate Complexes:

Role in Catalytic Ethene Oligomerisation; Crystal Structure of [NiPh{Ph2PCH...C(...O)(o-C6H4NHPh)}(PPh3)]. J. Chem. Soc., Chem. Commun. 1994, 2203-2204. 183. U. BODENSIECK, P. BRAUNSTEIN, W. DECK, T. FAURE, M. KNORR, C. STERN Platinum-Iron Silylene Complexes and Metal-Promoted Substituent Exchange between Si(NMe2)3 and

P(OEt)3 Ligands Angew. Chem., Int. Ed. Engl. 1994, 33, 2440-2442; Angew. Chem. 1994, 106, 2561-2564.


184. R. HASSELBRING, P. BRAUNSTEIN New Cyclic and Spirocyclic Metal-Containing Phosphazenes Phosphorus, Sulfur, and Silicon 1994, 93-94, 423-424. 185. M. XU, J. ROSÉ, P. BRAUNSTEIN The reaction of [RuCo3(CO)12]- with monodentate P donor ligands (L = PPh3, PPh2H. Shanxi Daxue Xuebao, Ziran Kexueban 1995, 18, 421-425. 186. P. BRAUNSTEIN, R. HASSELBRING, A. TIRIPICCHIO, F. UGOZZOLI Polyfunctional Ligands: Comparative Oxidative Coupling of [E(PPh2)2]- (E = CH, N) with Iodine. J. Chem. Soc., Chem. Commun. 1995, 37-38. 187. P. BRAUNSTEIN, D. CAUZZI, G. PREDIERI, A. TIRIPICCHIO Composition-tunable Metal-Alkyl Xerogels as Precursors for Homogeneously Dispersed Metals in

Amorphous Silica Matrix J. Chem. Soc., Chem. Commun. 1995, 229-230. 188. P. BRAUNSTEIN, Y. CHAUVIN, J. NÄHRING, Y. DUSAUSOY, D. BAYEUL, A. TIRIPICCHIO, F. UGOZZOLI Synthesis, Crystal Structures and Reactivity of Ruthenium-(II) and -(III) Complexes containing ß-Keto

phosphine or Phosphino Enolate Ligands. J. Chem. Soc., Dalton Trans. 1995, 851-862. 189. P. BRAUNSTEIN, Y. CHAUVIN, J. NÄHRING, A. DECIAN, J. FISCHER Synthesis, Crystal Structures and Reactivity of Rhodium(III) Complexes containing ß-Ketophosphine or

Phosphino Enolate Ligands. J. Chem. Soc., Dalton Trans. 1995, 863-873. 190. P. BRAUNSTEIN, C. de BELLEFON, Y. DUSAUSOY, D. BAYEUL Further Studies on dppm-stabilized Mixed-Metal Clusters: X-Ray Structure of PdPtCoCl(CO)3(µ-dppm)2

(dppm = Ph2PCH2PPh2). J. Cluster Sc. 1995, 6, 175-185 (Invited paper for the Special Issue L. F. Dahl). 191. P. BRAUNSTEIN, T. FAURE, M. KNORR, T. STÄHRFELDT, A. DECIAN, J. FISCHER Synthesis and Reactivity of Silylated Dinuclear Iron-Platinum Complexes Containing a Pt-C Bond. Crystal

Structures of [(OC)3Fe{µ-Si(OMe)2(OMe)}(µ-dppm)Pt(nbn] (dppm = Ph2PCH2PPh2, nbn = norbornyl, C7H11), [(OC)3Fe{(MeO)3Si}Fe(µ-dppm)Pt(η3-C8H13] and [(OC)3Fe{(MeO)3Si}Fe(µPPh2)Pt(η4-1,5-cod)].

Gazz. Chim. Ital. 1995, 125, 35-50 (invited paper, volume dédié à Sacconi). 192. M. KNORR, P. BRAUNSTEIN, A. DECIAN, J. FISCHER Phosphine-Induced Silyl Migration in Heterodinuclear Acyl Complexes [(OC)3Fe{µ-Si(OMe)2(OMe)}(µ-

dppm)Pt{C(O)R}](Fe-Pt) leading to µ-Siloxycarbene Complexes. Crystal Structure of [(OC)3Fe{µ-C(Et)OSi(OMe)3}(µ-dppm)Pt(PPh3)]

Organometallics 1995, 14, 1302-1309. 193. P. BRAUNSTEIN, U. ENGLERT, G. E. HERBERICH, M. NEUSCHÜTZ First Mixed-Metal Borole Cluster; Stabilization of Formally 14e Pd Centers in the Re2Pd2 Electron Deficient

[{η5-C4H4BPh)(CO)3Re}Pd]2 Cluster. Angew. Chem., Int. Ed. Engl. 1995, 34, 1010; Angew. Chem. 1995, 107, 1090. 194. J. ANDRIEU, P. BRAUNSTEIN Synthesis of Phosphinoenolate (alkyl) and (aryl) palladium(II) complexes, analogues to the nickel SHOP

catalyst. C. R. Acad. Sc. Paris, Serie IIb, 1995, 320, 661-666. 195. P. BRAUNSTEIN, R. HASSELBRING, A. DECIAN, J. FISCHER Polyfunctional Ligands: Carbon-Carbon Oxidative Coupling of [HC(PPh2)2]- and Crystal Structure of the New

Tetraphosphine Ligand (Ph2P)CH-CH(PPh2)2 Bull. Soc. Chim. Fr. 1995, 132, 691.


196. M. KNORR, P. BRAUNSTEIN, A. TIRIPICCHIO, F. UGOZZOLI Novel CO-Induced Silyl Migration in Heterobimetallic Fe-Pd Methyl Complexes leading to µ-Siloxycarbene

Complexes. Crystal Structures of the Metallasiloxanes [(OC)3Fe{µ-Si(OSiMe3)2(OSiMe3)}(µ-dppm)PdCl] and [(OC)3{(Me3SiO)3Si}Fe(µ-dppm)Pt(η3-C3H5].

Organometallics 1995, 14, 4910. 197. P. BRAUNSTEIN, X. MORISE, J. BLIN Reactivity of Heterobimetallic Alkoxysilyl and Siloxyl Complexes in the Dehydrogenative Coupling of

Stannanes. J. Chem. Soc., Chem. Commun. 1995, 1455-1456. 198. P. BRAUNSTEIN, D. G. KELLY, A. TIRIPICCHIO, F. UGOZZOLI Complexes with Functional Phosphines. Manganese(II) Complexes containing ß-Keto- and 2-Pyridyl-

Phosphine Ligands. Molecular Structure of MnI2(Ph2py)2. Bull. Soc. Chim. Fr. 1995, 132, 1083-1086. 199. P. BRAUNSTEIN, R. HASSELBRING, D. STALKE New functional ligand systems with a pure phosphorus-nitrogen chain. Crystal structures of the aluminium

complex [(Ph2P)NN(SiMe3)AlMe2] and of [(Ph2PN(SiMe3)PPh2=NSiMe3]. New. J. Chem. 1996, 20, 337-344. 200. R. BENDER, P. BRAUNSTEIN, A. DEDIEU, P. D. ELLIS, B. HUGGINS, P. HARVEY, E. SAPPA, A.

TIRIPICCHIO Synthetic, structural, spectroscopic and theoretical studies on structural isomers of the cluster [Pt3(µ-

PPh2)3Ph(PPh3)2]. A unique example of core isomerism in phosphine, phosphido-rich clusters. Inorg. Chem. 1996, 35, 1223-1234. 201. P. BRAUNSTEIN, C. CHARLES, R. D. ADAMS, R. LAYLAND The Synthesis of [Fe(CO)3(η1-dppm){Sn(n-Bu)2}]2 by Silicon-Tin Exchange; Its Crystal Structure and Its Use

as a Metallodiphosphine Ligand. J. Cluster Sc. 1996, 7, 145. 202. J. ANDRIEU, P. BRAUNSTEIN, F. NAUD Synthesis and Reactivity of Aryl- and Alkyl Palladium (II) Complexes with Functional Phosphine and

Phosphinoenolate Ligands: First Analogues of Model Nickel Catalysts. J. Chem. Soc., Dalton Trans. 1996, 2903-2909. 203. P. BRAUNSTEIN, J. PIETSCH, Y. CHAUVIN, S. MERCIER, L. SAUSSINE, A. DECIAN, J. FISCHER Phenyl Nickel Complexes with a Chelating P,N Ligand. Structures of Ph3P=CHC(=NPh)Ph and

[NiPh{Ph2PCH...C(...NPh)Ph}{Ph3PCH=C(=NPh)Ph-N}]. J. Chem. Soc., Dalton Trans. 1996, 3571-3574. 204. T. RICHERT, K. ELBAYED, J. RAYA, P. GRANGER, P. BRAUNSTEIN, J. ROSE 59Co NMR in tetrahedral clusters. Magn. Reson. Chem. 1996, 34, 689-696. 205. P. BRAUNSTEIN, V. HUCH, C. STERN, M. VEITH Stannylene insertion into an amino-stabilized iron-silylene complex. Synthesis of

[(OC)3{(Me2N)2(RO)P}}Fe{[NMe2Si(OR)2(SnNButSiMe2NHBut)]}] (R = Me, Et). J. Chem. Soc., Chem. Commun. 1996, 2041-2042. 206. M. KNORR, E. HALLAUER, V. HUCH, M. VEITH, P. BRAUNSTEIN Reactions of Heterodinuclear Fe-Pt and Fe-Pd Complexes with Cyclic Bis(amino)-germylenes and -

stannylenes: Bridging Metal(II) Amide Unit between Two Different Transition Metal Centers and Donor-Stabilization of Terminal Germylene and Stannylene Ligands by Si(OMe)3.

Organometallics 1996, 15, 3868-3875. 207. J. ANDRIEU, P. BRAUNSTEIN, F. NAUD, R. D. ADAMS, R. LAYLAND Ligand Redistribution Reactions leading to New Phosphinoenolate, Methyl Palladium Complexes. Crystal

Structure of [Pd(Me){Ph2PCH...C(...O)Ph}(PPh3)]. Bull. Soc. Chim. Fr. 1996, 133, 669-672.


208. P. BRAUNSTEIN, C. STERN, C. STROHMANN, N. TONG First Aminosilyl Bridging Ligand in a Bimetallic Complex: Structure of [(OC)3{(Me2N)2(MeO)P}Fe{µ-

Si(OMe)2(NMe2}Cu(PPh3)]. J. Chem. Soc., Chem. Commun. 1996, 2237-2238. 209. I. BACHERT, P. BRAUNSTEIN, R. HASSELBRING Alkoxysilyl-Functionalized Mixed-Metal Carbonyl Clusters. New J. Chem. 1996, 20, 993-995. 210. P. BRAUNSTEIN, C. CHARLES, A. TIRIPICCHIO, F. UGOZZOLI Mixed Iron-Silicon-Tin Complexes Stabilized by a Phosphinoenolate Bridging Ligand. Crystal Structure of

[(OC)3{(MeO)3Si}Fe{µ-Ph2PCH=C(O)Ph}SnBun2]. J. Chem. Soc., Dalton Trans. 1996, 4365-4368. 211. P. HARVEY, K. HIERSO, P. BRAUNSTEIN, X. MORISE Comparison in Halide Binding Ability between the unsaturated Clusters [Pd3(µ-dppm)3(CO)]+ and [PdPtCo(µ-

dppm)2(CO)3(CNtBu)]+ (dppm = Ph2PCH2PPh2). Inorg. Chim. Acta 1996, 250, 337-343. 212. J. ANDRIEU, P. BRAUNSTEIN, A. TIRIPICCHIO, F. UGOZZOLI Chemoselective Reactions of the Phosphinoenolate Li[Ph2PCH...C(...O)NPh2] with Ph2PCl and M-Cl Bonds

(M = Pd, Pt). Coordination Properties of the New Functional, Diphosphine Ligand (Ph2P)2CHC(O)NPh2. Coordination Properties of [Cu2{(Ph2P)2CHC(O)NPh2-P,P,O}2](BF4)2. Reactivity and Molecular Structure of [(8-mq)Pd{Ph2PCH...C(...O)NPh2}].

Inorg. Chem. 1996, 35, 5975-5985. 213. P. BRAUNSTEIN, Y. CHAUVIN, J. NÄHRING, A. DECIAN, J. FISCHER, A. TIRIPICCHIO, F. UGOZZOLI Rhodium(I) and Iridium(I) Complexes with ß-Ketophosphine or Phosphino Enolate Ligands. Catalytic

Transfer-Dehydrogenation of Cyclooctane. Organometallics 1996, 15, 5551-5567. 214. J. ANDRIEU, P. BRAUNSTEIN, M. DRILLON, Y. DUSAUSOY, F. INGOLD, P. RABU, A. TIRIPICCHIO, F.

UGOZZOLI Reactivity of α-Phosphinoenolate Complexes of Ni(II) and Pd(II) towards Electrophilic Metal Centres.

Synthesis and Crystal Structures of the Bimetallic Pd(II)-Au(I) Complex [(dmba)Pd{Ph2PCH(AuPPh3)C(O)Ph}](BF4) and of the Ni(II)-Co(II) Paramagnetic Complex cis-[Ni{Ph2PCH...C(...O)(p-C6H4CH3}2]CoI2.

Inorg. Chem. 1996, 35, 5986-5994. 215. J. ANDRIEU, P. BRAUNSTEIN, Y. DUSAUSOY, N.-E. GHERMANI Iodination of α-Phosphino Enolate Complexes of Palladium(II) and Platinum(II). Synthesis and Crystal

Structures of [(dmba)Pd{Ph2PC(I)...C(...O)Ph}] and of the Dipalladium(II) Complex [(dmba)Pd-{Ph2PC...C(...O)Ph}Pd(I)(tmeda)] Obtained by Palladium(0) Insertion into the Carbon-Iodine Bond.

Inorg. Chem. 1996, 35, 7174-7180. 216. M. KNORR, P. BRAUNSTEIN, A. TIRIPICCHIO, F. UGOZZOLI Synthesis and Reactivity of Bimetallic Fe-Re Silyl Complexes. Crystal Structures of [(OC)3{(MeO)3Si}Fe(µ-

dppm)Re(CO)4] and [(OC)3Fe(µ-Br)(µ-dppm)Re(CO)3]. J. Organomet. Chem. 1996, 526, 105-116. 217. C. ARCHAMBAULT, R. BENDER, P. BRAUNSTEIN, A. DECIAN, J. FISCHER Oxidatively-induced Reductive Coupling of PPh2 and Ph Groups Mediated by a Platinum Cluster: Synthesis

and Crystal Structure of the Butterfly Cluster [Pt3(µ3-AgO2CCF3)(µ-PPh2)3Ph (PPh3)2].C6H6. J. Chem. Soc., Chem. Commun. 1996, 2729-2730. 218. M. KNORR, C. STROHMANN, P. BRAUNSTEIN Reactivity of Silylated Dinuclear Iron-Platinum Acyl Complexes: Formation of µ-Vinylidene Complexes and

Crystal Structures of the Acyl Complex [(OC)3{(MeO)3Si}Fe(µ-dppm)Pt{C(O)Me}(t-BuNC)] and the µ-Vinylidene Complex [(OC)3Fe{µ-C=C(H)Ph}(µ-dppm)Pt(PPh3)].

Organometallics 1996, 15, 5653-5663.


219. P. BRAUNSTEIN, J. PIETSCH, Y. CHAUVIN, A. DECIAN, J. FISCHER Synthesis of Nickel Phenyl Complexes with New Chelating κ2-P,N Ligands derived from α-iminoaza

triphenylphoshoranes. J. Organomet. Chem. 1997, 529, 387-393. Corrigendum du fait dʼerreurs de lʼimprimeur: J. Organomet.

Chem. 1999, 582, 371-377. 220. D. MATT, M. HUHN, P. BRAUNSTEIN β-Ketophosphines: Ligands of Catalytic Relevance Inorg. Synth. 1997, 31, 138-143. 221. V. RUFFIEUX, G. SCHMID, P. BRAUNSTEIN, J. ROSE T8-OSS-Ethyldiphenylphosphine: a New Functional Oligosilsesquioxane Ligand. Chem. Eur. J. 1997, 3, 900-903 222. P. BRAUNSTEIN, C. GRAIFF, X. MORISE, A. TIRIPICCHIO Carbonyl Clusters with a Capping Methylidyne Phosphonate Ligand. Crystal Structure of [Co3(CO)9{η1-µ3-

[CP(O)(OEt)2]}]. J. Organomet. Chem. 1997, 541, 417-422. 223. P. BRAUNSTEIN, C. CHARLES, G. KICKELBICK, U. SCHUBERT Different degrees of five-coordination for similar tin atoms in the polymetallic complex [(OC)3Fe(µ-Ph2Ppy)

(SnPh2)(µ-Cl)(SnClPh2)] J. Chem. Soc., Chem. Commun. 1997, 1911-1912. 224. P. BRAUNSTEIN, C. CHARLES, G. KICKELBICK, U. SCHUBERT Palladium-induced rearrangement of a Fe2Sn2 metal core leading to the first Fe-Pd-Sn cluster [(OC)3Fe(µ-

SnBu2)(µ-dppm)Pd(µ-dppm)Fe(CO)3] J. Chem. Soc., Chem. Commun. 1997, 2093-2094. 225. P. GRANGER, T. RICHERT, K. ELBAYED, P. KEMPGENS, J. HIRSCHINGER, J. RAYA, J. ROSÉ, P.

BRAUNSTEIN Microdynamic Motion of Tetrahedral Clusters Studied by 59Co and 99Ru NMR Relaxation. Molecular Physics 1997, 92, 895-902. 226. P. BRAUNSTEIN, J. R. GALSWORTHY, W. MASSA Synthesis, Characterisation and Reactivity of Siloxyl-substituted Derivatives of [Ru3(CO)12]. Crystal Structure

of trans-[Ru2{Si(OSiMe3)}2(CO)8] J. Chem. Soc., Dalton Trans. 1997, 4677-4681. 227. M. BÉNARD, U. BODENSIECK, P. BRAUNSTEIN, M. KNORR, M. STRAMPFER, C. STROHMANN Conformation Control in Polymetallic Mesocycles by Metal-Metal Bonding: The first Example of an Hg-Cu

Interaction. Angew. Chem., Int. Ed. Engl. 1997, 36, 2758-2760; Angew. Chem. 1997, 109, 2890-2893. 228. P. BRAUNSTEIN, J. R. GALSWORTHY, B. J. HENDAN, H. C. MARSMANN Reactions of thiol-functionalized silsesquioxanes with metal carbonyl clusters: syntheses and characterization

of [Si8O12(Prn)7{(µ2-SC3H6)M3(µ-H)(CO)10}] (M = Ru, Os; Prn = C3H7), [Si8O12(Prn)6{(µ2-SC3H6)M3(µ-H)(CO)10}2] and [Si8O12(C3H6SH)x){(µ2-SC3H6)Ru3(µ-H)(CO)10}8-x] (x = 6, 0)

J. Organomet. Chem. 1998, 551, 125-131. 229. P. BRAUNSTEIN, X. MORISE Reactivity of Heterobimetallic Alkoxysilyl and Siloxy Complexes in the Catalytic Dehydrogenative Coupling of

Tin Hydrides. Organometallics 1998, 17, 540-550. 230. P. BRAUNSTEIN, G. E. HERBERICH, M. NEUSCHÜTZ, M. U. SCHMIDT, U. ENGLERT, P. LECANTE, A. MOSSET Heterometallic Borole Complexes of Iron and Gold. Organometallics 1998, 17, 2177-2182. 231. J. PIETSCH, P. BRAUNSTEIN, Y. CHAUVIN Nickel Phenyl Complexes with Chelating k2-P, O Ligands as catalysts for the Oligomerization of Ethylene into

Linear α-Olefins. New J. Chem. 1998, 22, 467-472.


232. I. BACHERT, P. BRAUNSTEIN, M. K. McCART, F. FABRIZI DE BIANI, F. LASCHI, P. ZANELLO, G. KICKELBICK, U. SCHUBERT Synthesis, Structure and Electrochemical Studies of the First Mixed-Metal Clusters with the P-N-P

Assembling Ligands (Ph2P)2NH (dppa), (Ph2P)2N(CH3) (dppam) and (Ph2P)2N(CH2)3Si(OEt)3 (dppaSi). J. Organomet. Chem. 1999, 573, 47-59. 233. P. BRAUNSTEIN, M. D. FRYZUK, F. NAUD, S. J. RETTIG Catalytic Transfer Hydrogenation of Ketones by the Use of Ruthenium Complexes Incorporating the New

Tridentate Ligand, Bis(2-oxazolin-2-ylmethyl)phenylphosphine. J. Chem. Soc., Dalton Trans. 1999, 589-594. 234. R. BENDER, S.-E. BOUAOUD, P. BRAUNSTEIN, Y. DUSAUSOY, N. MERABET, J. RAYA, D. ROUAG Thermal C-P and C-H Cleavage in Coordinated Phosphines leading to Dinuclear Platinum Complexes and

Contrasting Reactions with M(PPh3)+ (M = Cu, Ag, Au) and HgCl2. J. Chem. Soc., Dalton Trans. 1999, 735-741. 235. P. BRAUNSTEIN, T. FAURE, M. KNORR Silyl Migration from Iron to Platinum in dppm-bridged Bimetallic Complexes. Organometallics 1999, 18, 1791-1794. 236. P. BRAUNSTEIN, G.E. HERBERICH, M. NEUSCHÜTZ, M. U. SCHMIDT Cyano-Bridged Fe-CN-Pt-NC-Fe Chain Complexes. Structural and Spectroscopic Characterization of Four

Isomers of [{η5-(1-phenylborole)Fe(CO)2(µ-CN)}2Pt(PEt3)2]. J. Organomet. Chem. 1999, 580, 66-71. 237. I. BACHERT, I. BARTUSSECK, P. BRAUNSTEIN, E. GUILLON, J. ROSÉ, G. KICKELBICK Synthesis of Co2Pd and MoPd2 mixed-metal clusters with the P-N-P assembling ligands (Ph2P)2NH (dppa)

and (Ph2P)2NMe (dppaMe). Crystal structure of [Co2Pt(µ3-CO)(CO)6(µ-dppa)]. J. Organomet. Chem. 1999, 580, 257-264. Corrigendum du fait dʼerreurs de lʼimprimeur: J. Organomet.

Chem. 1999, 588, 144-151. 238. J. BLIN, P. BRAUNSTEIN, J. FISCHER, G. KICKELBICK, M. KNORR, X. MORISE, T. WIRTH Heterobimetallic alkoxysilyl cationic complexes: investigations into the displacement of a µ-η2-Si,O bridge by

functional phosphine ligands. J. Chem. Soc., Dalton Trans. 1999, 2159-2169. 239. I. BACHERT, P. BRAUNSTEIN, E. GUILLON, C. MASSERA, J. ROSÉ, A. DECIAN, J. FISCHER Synthesis of Palladium Clusters with the Assembling Ligands (Ph2P)2CH2 (dppm) and (Ph2P)2NH (dppa).

Crystal Structure of [Pd4(µ-Cl)2(µ-dppm)2(µ-dppa)2](PF6)2. J. Cluster Sc. 1999, 10, 445-458. 240. P. BRAUNSTEIN, T. STÄHRFELDT, J. FISCHER Heterobimetallic Iron-Platinum Phosphino Enolate, Silyl Complexes. C.R. Acad. Sci. Paris, Série IIc 1999, 273-282. 241. P. BRAUNSTEIN, U. ENGLERT, G. E. HERBERICH, M. NEUSCHÜTZ, M. U. SCHMIDT Heterometallic Complexes with Borole Ligands. J. Chem. Soc., Dalton Trans. 1999, 2807-2812. 242. R. BENDER, P. BRAUNSTEIN, S.-E. BOUAOUD, N. MERABET, D. ROUAG, P. ZANELLO, M. FONTANI First Platinum Clusters Containing a Direct Pt-Si Bond; Molecular Structure of [Pt3{Si(OSiMe3}3}(µ-

PPh2)3(PPh3)2 and Electrochemical Studies. New J. Chem. 1999, 23, 1045-1047. 243. S. BOUHEROUR, P. BRAUNSTEIN, J. ROSÉ, L. TOUPET Metallosite Selectivity Studies in Reactions of Tetrahedral MCo3 Carbonyl Clusters (M = Fe, Ru) with

Cyclohexylphosphine. Skeletal Rearrangements Leading to Tri- and Pentanuclear Phosphinidene Clusters and Crystal Structures of RuCo4(µ4-PCy)(µ-CO)2(CO)11 and RuCo2(µ3-PCy)(CO)9.

Organometallics 1999, 18, 4908-4915.


244. P. BRAUNSTEIN, M. KNORR, J. COSSY, P. VOGEL, C. STROHMANN Migratory Insertion Reactions of Norbornene, Norbornadiene and 7-Oxanorbornene Derivatives into the

Palladium-Carbon Bond of Heterodinuclear Fe-Pd-Acyl Complexes. Substrate Influence on the Pd Coordination Sphere and Crystal Structure of [(OC)3Fe{µ-Si(OMe)2(OMe)}(µ-dppa)Pd{C9H9NO3C(=O)Me)}].

New. J. Chem., 1999, 23, 1215-1222. 245. P. BRAUNSTEIN, J. DURAND, G. KICKELBICK, M. KNORR, X. MORISE, R. PUGIN, A. TIRIPICCHIO, F. UGOZZOLI Hydrocarbyl Derivatives of dppm- or dppa-bridged Alkoxysilyl Heterobimetallic Fe-Pd Complexes and CO

Insertion Reactions. Crystal Structures of [(OC)3{(MeO)3Si}Fe(µ-dppm)Pd(8-mq)] (dppm = Ph2PCH2PPh2), [(OC)3Fe{µ-Si(OMe)2(OMe)}(µ-dppa)PdCl] and [(OC)3Fe{µ-Si(OMe)2(OMe)}(µ-dppa)PdPh] (dppa = Ph2PNHPPh2).

J. Chem. Soc., Dalton Trans. 1999, 4175-4186. 246. P. KEMPGENS, J. RAYA, K. ELBAYED, P. GRANGER, J. ROSÉ, P. BRAUNSTEIN Theoretical Study of Two-Dimensional COSY Experiments for S = 7/2 Spins: Application to 59Co in the

Tetrahedral Cluster HFeCo3(CO)11(PPh2H). J. Magn. Res. 2000, 142, 64-73. 247. P. BRAUNSTEIN, J. DURAND, X. MORISE, A. TIRIPICCHIO, F. UGOZZOLI Catalytic dehydrogenative coupling of stannanes by alkoxysilyl heterobimetallic complexes; influence of the

assembling ligand. Organometallics 2000, 19, 444-450. 248. P. BRAUNSTEIN, M. D. FRYZUK, M. Le DALL, F. NAUD, S. J. RETTIG, F. SPEISER Synthesis and structure of Pd(II) complexes containing chelating (phosphinomethyl)oxazoline P,N-type

ligands; copolymerisation of ethylene/CO. J. Chem. Soc., Dalton Trans. 2000, 1067-1074. 249. J. ANDRIEU, P. BRAUNSTEIN, F. NAUD, R. D. ADAMS Cationic Palladium Complexes with Ketophosphine and Phosphino Enolate Ligands and their Reactivity

towards C-C Coupling Reactions. Crystal Structures of [PdMe{Ph2PCH2C(O)Ph}(PCy3)](PF6) and [Pd{Ph2PCH...C(...O)Ph}(SMe2)2](PF6).

J. Organomet. Chem. 2000, 601, 43-50. 250. P. BRAUNSTEIN, F. NAUD, C. GRAIFF, A. TIRIPICCHIO Unexpected and then rational synthesis of a new class of anionic phosphino-oxazoline ligands; structure and

catalytic properties of a ruthenium complex. Chem. Commun. 2000, 897-898. 251. P. BRAUNSTEIN, Y. CHAUVIN, J. FISCHER, H. OLIVIER, C. STROHMANN, D. V. TORONTO Oxidative Addition of Iodine, Iodomethane and Iodobenzene to the Rhodium Phosphino Enolate Complex

[Rh{Ph2PCH...C(...O)Ph}(CO)(PPh3)] and Carbon Monoxide Insertion into the Resulting Rh-Carbon Bond of [Rh{Ph2PCH...C(...O)Ph}Me(I)(CO)(PPh3)].

New. J. Chem. 2000, 24, 437-445. 252. P. BRAUNSTEIN, F. NAUD, A. PFALTZ, S. J. RETTIG Ruthenium Complexes with Novel Tridentate N,P,N Ligands Containing a Phosphonite Bridge Between Two

Chiral Oxazolines. Catalytic Activity in Cyclopropanation of Olefins and Transfer Hydrogenation of Acetophenone.

Organometallics 2000, 19, 2676-2683. 253. P. BRAUNSTEIN, C. FRISON, X. MORISE, R. D. ADAMS Coordination properties of novel hemilabile acetamide-derived P,O phosphine ligands. Crystal structures of

Ph2PNHC(O)Me and [PdMe{PPh2NHC(O)Me}{PPh2NHC(O)Me}][O3SCF3]. J. Chem. Soc., Dalton Trans. 2000, 2205-2214. 254. F. SCHWEYER, P. BRAUNSTEIN, C. ESTOURNÈS, J. GUILLE, H. KESSLER, J.-L. PAILLAUD, J. ROSÉ Metallic nanoparticles from heterometallic Co-Ru carbonyl clusters in mesoporous silica xerogels and MCM-

41-type materials. Chem. Commun. 2000, 1271-1272.


255. P. BRAUNSTEIN, B. OSWALD, A. TIRIPICCHIO, F. UGOZZOLI Carbonylcyanometalates as building blocks : heterometallic complexes containing Mn(µ-C≡N)M (M = Cu, Au,

Ni, Pd or Pt), Mn(µ-C≡N)Pd(µ-dppm)2Mn and Mn(µ-C≡N)M(µ-dppm)2Pd((µ-N≡C)-Mn (M = Pt or Pd) chains of atoms and crystal structure of the mixed-metal cluster [Ru3{(µ3-NC)MnCp(CO)2}(µ-AuPPh3)(CO)10].

J. Chem. Soc., Dalton Trans. 2000, 2195-2203. 256. J.-M. CAMUS, D. MORALES, J. ANDRIEU, P. RICHARD, R. POLI, P. BRAUNSTEIN, F. NAUD Half-sandwich complexes of molybdenum-(III), -(IV) and -(V) with P-O and P-N bifunctional ligands

Ph2PCH2X (X = 2-oxazolinyl, or C(O)NPh2). J. Chem. Soc., Dalton Trans. 2000, 2577-2585. 257. P. BRAUNSTEIN, C. GRAIFF, F. NAUD, A. PFALTZ, A. TIRIPICCHIO Synthesis and Crystal Structures of Ru(II) Complexes Containing Chelating (Phosphinomethyl)oxazoline P,N-

type Ligands and Asymmetric Catalytic Transfer Hydrogenation of Acetophenone in Propan-2-oI. Inorg. Chem. 2000, 39, 4468-4475. 258. P. BRAUNSTEIN, C. FRISON, X. MORISE Stepwise Ethene and/or Methyl Acrylate/CO Insertions into the Pd-C Bond of Cationic Palladium(II)

Complexes Stabilized by a (P,O) Chelate Angew. Chem. Int. Ed. 2000, 39, 2867-2870. 259. O. SIRI, P. BRAUNSTEIN First binuclear complex of an N, N', N", N"'-tetraalkyl 2,5-diamino-1,4-benzoquinonediimine. Chem. Commun. 2000, 2223-2224. 260. P. BRAUNSTEIN, M. KNORR, G. REINHARD, U. SCHUBERT, T. STÄHRFELDT Novel Metal-to-Metal Silyl-Migration Reactions in Heterometallic Complexes. Chem. Eur. J. 2000, 6, 4265-4278. 261. P. BRAUNSTEIN, H.-P. KORMANN, W. MEYER-ZAIKA, R. PUGIN, G. SCHMID Strategies for the Anchoring of Metal Complexes, Clusters and Colloids Inside Nanoporous Alumina

Membranes. Chem. Eur. J. 2000, 6, 4637-4646. 262. P. BRAUNSTEIN, F. NAUD, S. J. RETTIG A new class of anionic phosphinooxazoline ligands in palladium and ruthenium complexes: catalytic

properties for the transfer hydrogenation of acetophenone. New J. Chem. 2001, 25, 32-39. 263. C. MATTHEIS, P. BRAUNSTEIN Chelating behaviour of a phosphinoalcohol leading to a stable alcohol palladium complex J. Organomet. Chem. 2001, 621, 218-223. 264. P. BRAUNSTEIN, M. VEITH, J. BLIN, V. HUCH New Mono- and Polynuclear Iron Silylene and Stannylene Complexes Organometallics 2001, 20, 627-633. 265. P. BRAUNSTEIN, J. DURAND, M. KNORR, C. STROHMANN Heterobimetallic Intermediates in Alkene Insertion Reactions into a Pd-acetyl Bond. Chem. Commun. 2001, 211-212. 266. C. MATTHEIS, P. BRAUNSTEIN, A. FISCHER A New Chiral Metalladiphosphine for Early-Late Chemistry. Crystal Structure of a D-Camphor-Based

Zirconium Enolato Phosphine and Rearrangement of Heterobimetallic Zr/Pd Complexes. J. Chem. Soc., Dalton Trans. 2001, 800-805.

267. C. ARCHAMBAULT, R. BENDER, P. BRAUNSTEIN, S.-E. BOUAOUD, D. ROUAG, S. GOLHEN, L.

OUAHAB Unexpected bonding similarities between the bridging metalloligands [MoCp(CO)3]- and [PtI(CO)2(PPh3)]-

acting as 4-electron donors in metal clusters. Crystal structures of [Pt2Mo(µ-CO)3(µ-PPh2)Cp(PPh3)2] and [Pt3(µ-CO)2(µ-PPh2)I(PPh3)3].

Chem. Commun. 2001, 849-850. 268. P. BRAUNSTEIN, E. CURA, G. E. HERBERICH Heterometallic complexes and clusters with 2-boratanaphtalene ligands. J. Chem. Soc., Dalton Trans. 2001, 1754-1760.


269. P. BRAUNSTEIN, F. NAUD, A. DEDIEU, M.-M. ROHMER, A. DECIAN, S. J. RETTIG Palladium Complexes with a New Hemilabile Bis(oxazoline)phenylphosphonite Ligand. Characterization of an

Unprecedented Chloro Palladium(II)-(η1-Allyl) Complex. Organometallics 2001, 20, 2966-2981. 270. F. BALEGROUNE, P. BRAUNSTEIN, J. DURAND, T. FAURE, D. GRANDJEAN, M. KNORR, M. LANFRANCHI, C. MASSERA, X. MORISE, A. TIRIPICCHIO Iodo derivatives of Bimetallic Fe-Pd and Fe-Pt Complexes. Crystal Structures of [(OC)3Fe(µ-I)(µ-dppm)PdI],

[(OC)3Fe{µ-Si(OMe)2(OMe)}(µ-dppa)PdI], and [(OC)3Fe{µ-Si(OMe)2(OMe})(µ-dppm)PdI]. Monatsh. Chem. 2001, 132, 885-896. 271. P. BRAUNSTEIN, M.J. CHETCUTI, R. WELTER Bimetallic-induced tail-to-tail dimerization and C-H activation for methyl acrylate. Chem. Commun. 2001, 2508-2509. 272. P. BRAUNSTEIN, G. CLERC, X. MORISE Synthesis and Reactivity of Heterodinuclear Fe-Ni Complexes with a Bridging Alkoxysilyl Ligand. Crystal

Structure of [(OC)3Fe{µ-Si(OMe)2(OMe)}(µ-dppm)NiMe]. Organometallics 2001, 20, 5036-5043. 273. O. SIRI, P. BRAUNSTEIN Unprecedented Zwitterion in Quinonoid Chemistry. Chem. Commun. 2002, 208-209. 274. P. BRAUNSTEIN, M. J. CHETCUTI, R. WELTER Improved syntheses of the electronically unsaturated heterobimetallic complexes [(η-C5Me5)NiM(CO)3(η-

C5H5)] (M = Mo, W), and their use as cluster building blocks: X-ray structure of the chiral trimetallic cluster [FeNiMo(µ3-CO)(µ2-CO)(CO)5(η-C5H5)(η-C5Me5)].

C.R. Chimie 2002, 5, 67-72. 275. P. BRAUNSTEIN, C. GRAIFF, C. MASSERA, G. PREDIERI, J. ROSE, A. TIRIPICCHIO Reactivity of the Heterometallic clusters [HMCo3(CO)12] and [Et4N][MCo3(CO)12] (M = Fe, Ru) towards

phosphine selenides, including selenium transfer. Crystal structures of [HRuCo3(CO)7(µ-CO)3(µ-dppy)], [MCo2(µ3-Se)(CO)7(µ-dppy)] and [RuCo2(µ3-Se)(CO)7(µ-dppm)] [dppy = Ph2(2-C5H4N)P, dppm = Ph2PCH2PPh2].

Inorg. Chem. 2002, 41, 1372-1382. 276. P. BRAUNSTEIN, C. FRISON, X. MORISE Synthesis and crystal structure of [PdMe{PPh2NHC(O)Me}{O=C(NH2)Me}][BF4], a palladium complex

containing the acetamide ligand. C.R. Chimie 2002, 5, 131-135. 277. N. G. JONES, M. L. H. GREEN, I. C. VEI, A. COWLEY, X. MORISE, P. BRAUNSTEIN Synthesis of molybdenum arene complexes containing amide-derived heterodifunctional P,O ligands. J. Chem. Soc., Dalton Trans. 2002, 1487-1493. 278. R. BENDER, P. BRAUNSTEIN, S.-E. BOUAOUD, D. ROUAG, P. D. HARVEY, S. GOLHEN, L. OUAHAB Bonding Behavior of Co(CO)3L (L = CO, PPh3) Building Blocks in Platinum-Cobalt Carbonyl Clusters. Inorg. Chem. 2002, 41, 1739-1746. 279. N. G. JONES, M. L. H. GREEN, I. C. VEI, L. H. REES, S. I. PASCU, D. WATKIN, A. COWLEY, X. MORISE,

P. BRAUNSTEIN Synthesis of η6-arene complexes of molybdenum containing ß-ketophosphine and related P,O mixed-donor

ligands. J. Chem. Soc., Dalton Trans. 2002, 2491-2500. 280. C. ARCHAMBAULT, R. BENDER, P. BRAUNSTEIN, Y. DUSAUSOY

Reactivity of Phosphido-Bridged Diplatinum Complexes towards Electrophiles: Synthesis of New Hydrides and Related Pt2Cu and Pt2Ag Clusters. Crystal Structures of [Pt2{µ-Cu(PPh3)}(µ-PPh2)(µ-o-C6H4PPh2) (PPh3)2]PF6 and [Pt2(µ-H)(µ-PPh2)(OPOF2)(PPh3)3](PF6)·0.5CH2Cl2 J. Chem. Soc., Dalton Trans. 2002, 4084-4090.


281. X. MORISE, M. L. H. GREEN, P. BRAUNSTEIN, L. H. REES, I. C. VEI Monocyclopentadienyl complexes of niobium, tantalum and tungsten containing heterodifunctional P,O

ligands. New J. Chem. 2003, 27, 32-38.

282. P. BRAUNSTEIN, G. CLERC, X. MORISE Cyclopropanation and Diels-Alder reactions catalyzed by the first heterobimetallic complexes with bridging

phosphinooxazoline ligands New J. Chem. 2003, 27, 68-72.

283. N. AUVRAY, P. BRAUNSTEIN, S. MATHUR, M. VEITH, H. SHEN, S. HÜFNER Thin Films by Metal Organic Deposition of Fe-Mo-S Molecular Clusters: Synthesis and Crystal Structure of [Cp2MoFe2(µ3-S)2(CO)6] New J. Chem. 2003, 27, 155-160.

284. F. SCHWEYER-TIHAY, P. BRAUNSTEIN, C. ESTOURNÈS, J. L. GUILLE, B. LEBEAU, J.-L. PAILLAUD, M.

RICHARD-PLOUET, J. ROSÉ Synthesis and Characterization of Supported Co2P Nanoparticles by Grafting of Molecular Clusters into

Mesoporous Silica Matrices. Chem. Mater. 2003, 15, 57-62. 285. P. BRAUNSTEIN, J. ZHANG, R. WELTER

Monohapto-allyl Pd(II) Complexes with Bidentate Hybrid P,N Ligands. J. Chem. Soc., Dalton Trans. 2003, 507-509.

286. P. BRAUNSTEIN, X. MORISE, M. BÉNARD, M.-M. ROHMER, R. WELTER A quasi-covalent metal-metal bond in an early-late heterobimetallic Ti-Pt complex stabilized by bridging and chelating phosphinoenolate ligands. Chem. Commun. 2003, 610-611.

287. P. BRAUNSTEIN, B. T. HEATON, C. JACOB, L. MANZI, X. MORISE

Rhodium complexes containing the hybrid P,O ligand PPh2NHC(O)Me or its anion, [PPh2N···C(···O)Me]-

J. Chem. Soc., Dalton Trans. 2003, 1396-1401. 288. W. SCHUH, P. BRAUNSTEIN, R. WELTER

Heterometallic metal-metal chain complexes as metalloligands C. R. Chimie, 2003, 6, 59-65.

289. X. MORISE, P. BRAUNSTEIN, R. WELTER Metal-Assisted Deprotonation of a β-Phosphonato-phosphine Ligand. X-ray structure of Pd(II) Complexes with New P,O Donor Ligands. C. R. Chimie, 2003, 6, 91-97.

290. P. BRAUNSTEIN, G. CLERC, X. MORISE, R. WELTER, G. MANTOVANI

Phosphinooxazolines as new assembling ligands in heterometallic complexes. J. Chem. Soc., Dalton Trans. 2003, 1601-1605.

291. A. APFELBACHER, P. BRAUNSTEIN, L. BRISSIEUX, R. WELTER

New phosphino-oxazoline and related phosphino-iminolate palladium complexes; structure of an unusual zwitterionic dinuclear Pd(II) complex. J. Chem. Soc., Dalton Trans. 2003, 1669-1674.

292. W. SCHUH, P. BRAUNSTEIN, M. BÉNARD, M.-M. ROHMER, R. WELTER

An Unusual Dynamic Fe-Hg-Pd Cluster with a Palladium(0) Fragment Stabilized by d10-d10 Heterometallic Bonding. Angew. Chem. Int. Ed. 2003, 42, 2161-2164.

293. E. FINOT, E. BOURILLOT, R. MEUNIER-PREST, Y. LACROUTE, G. LEGAY, M. CHERKAOUI-MALKI, N. LATRUFFE, O. SIRI, P. BRAUNSTEIN, A. DEREUX Performance of Interdigitated Nanoelectrodes for Electrochemical DNA Biosensor. Ultramicroscopy, 2003, 97, 441-449.


294. CHOUALEB, J. ROSÉ, P. BRAUNSTEIN, R. WELTER

Routes to Ruthenium-Cobalt Clusters and Dicobalt Complexes with New Alkoxysilyl- or Sulfur-Functionalized Alkynes. X-ray structures of [NEt4][RuCo3(CO)10{µ4-η2-HC2(CH2)2OC(O)NH(CH2)3Si(OEt)3}] and [Co2(CO)6{µ2-η2-HC2CH2NHC(O)NH(CH2)3Si(OEt)3}] Organometallics, 2003, 22, 2688-2693.

295. P. BRAUNSTEIN, O. SIRI, J.-P. TAQUET, M.-M. ROHMER, M. BÉNARD, R. WELTER

A 6π + 6π Potentially Antiaromatic Zwitterion preferred to a Quinoidal Structure: Its Reactivity Towards Organic and Inorganic Reagents. J. Am. Chem. Soc. 2003, 125, 12246-12256.

296. O. SIRI, P. BRAUNSTEIN, M.-M. ROHMER, M. BÉNARD, R. WELTER

Novel « Potentially Antiaromatic », Acidichromic Quinonediimines with Tunable Delocalization of their 6π electron subunits

J. Am. Chem. Soc. 2003, 125, 13793-13803. 297. X. MORISE, P. BRAUNSTEIN, R. WELTER

Enolphosphatophosphines : A new class of P,O ligands. Inorg. Chem. 2003, 42, 7752-7765.

298. A. CHOUALEB, P. BRAUNSTEIN, J. ROSÉ, S.-E. BOUAOUD, R. WELTER

Reactions of Diphosphine-Stabilized Tetracobalt Carbonyl Clusters with –Si(OR)3-Functionalized Alkynes. Organometallics, 2003, 22, 4405-4417.

299. M. ELHABIRI, O. SIRI, A. SORNOSA-TENT, A.-M. ALBRECHT-GARY, P. BRAUNSTEIN

Acid-Base Sensors Based on Novel Quinone-Type Dyes Chem. Eur. J. 2004, 10, 134-141.

300. A. CHOUALEB, P. BRAUNSTEIN, J. ROSÉ, R. WELTER

Reactions of the Tetrahedral Clusters [MCo3(CO)12]- (M = Ru, Fe) with Functional Mono- and Diynes. Inorg. Chem. 2004, 43, 57-71.

301. F. SPEISER, P. BRAUNSTEIN, L. SAUSSINE, R. WELTER Nickel Complexes with New Bidentate P,N Phosphinito-Oxazoline and –Pyridine Ligands; Application for the

Catalytic Oligomerization of Ethylene. Inorg. Chem. 2004, 43, 1649-1658. 302 F. SPEISER, P. BRAUNSTEIN, L. SAUSSINE Nickel Complexes with Oxazoline-Based P,N-Chelate Ligands: Synthesis, Structures and Catalytic Ethylene

Oligomerization Behavior. Organometallics, 2004, 23, 2613-2624. 303. F. SPEISER, P. BRAUNSTEIN, L. SAUSSINE New Nickel Ethylene Oligomerization Catalysts Bearing Bidentate P,N-Phosphinopyridine Ligands with

Different Substituents α to Phosphorus. Organometallics, 2004, 23, 2625-2632. 304. F. SPEISER P. BRAUNSTEIN, L. SAUSSINE

Nickel Complexes Bearing New P,N-Phosphinopyridine Ligands for the Catalytic Oligomerization of Ethylene. Organometallics, 2004, 23, 2633-2640.

305. F. SPEISER, P. BRAUNSTEIN, L. SAUSSINE

Nickel and Iron Complexes with Oxazoline- or Pyridine-Phosphonite Ligands; Synthesis, Structure and Application for the Catalytic Oligomerisation of Ethylene. Dalton Trans. 2004, 1539-1545.

306. J. ZHANG, P. BRAUNSTEIN, R. WELTER Stable, Chloride-Induced Monohapto-Bonding Mode for an Allyl Ligand in a Pd(II) Complex Bearing a New Bidentate Phosphonite-Oxazoline Ligand. Inorg. Chem. 2004, 43, 4172-4177.

307. F. SPEISER, P. BRAUNSTEIN, L. SAUSSINE Dinuclear Nickel Complexes with Bidentate N,O Ligands: Synthesis, Structure and Catalytic Oligomerization of Ethylene. Inorg. Chem. 2004, 43, 4234-4240.


308. P. BRAUNSTEIN, O. SIRI, J.-p. TAQUET, Q.-Z. YANG Toward a 6π + 6π Zwitterion or a Bioinhibitors-Related OH-Substituted Aminoquinone: Identification of a Key Intermediate in their pH Controled Synthesis Chem. Eur. J. 2004, 10, 3817-3821.

309. P. BRAUNSTEIN, A. DEMESSENCE, O. SIRI, J.-p. TAQUET

Relocalization of the π system in benzoquinonediimines induced by metal coordination C. R. Chimie, 2004, 7, 909-913.

310. J.-p. TAQUET, O. SIRI, P. BRAUNSTEIN, R. WELTER

Stepwise Synthesis, Structures and Reactivity of Mono-, Di-, and Trimetallic Metal Complexes with a 6π + 6π Quinonoid Zwitterion Inorg. Chem. 2004, 43, 6944-6953.

311. P. BRAUNSTEIN, O. SIRI, J.-p. TAQUET, R. WELTER

Supramolecular, Bifurcated N-H-OC-M Bonding Explains Unusually Low ν(CO) Frequencies in Metal Carbonyls: A Case Study. Angew. Chem. Int. Ed. 2004, 43, 5922-5925.

312. P. BRAUNSTEIN, C. FRISON, N. OBERBECKMANN-WINTER, X. MORISE, A. MESSAOUDI, M. BÉNARD, M.-M. ROHMER, R. WELTER An oriented 1-D Coordination/Organometallic Dimetallic Molecular Wire with Ag-Pd Metal-Metal Bonds Angew. Chem. Int. Ed. 2004, 43, 6120-6125.

313. N. OBERBECKMANN-WINTER, P. BRAUNSTEIN, R. WELTER Electrophilic Activation : Unexpected Metal-Metal Bond-Assisted Tl+ Chelation by a Pt-Benzyl Moiety Instead

of Chloride Abstraction Organometallics, 2004, 23, 6311-6318. 314. O. SIRI, P. BRAUNSTEIN

Tuning the synthesis of a dinitroaromatic towards a new trinitroaromatic stabilized energetic material New J. Chem. 2005, 29, 75-79.

315. J.-p. TAQUET, O. SIRI, J.-P. COLLIN, A. MESSAOUDI, P. BRAUNSTEIN

One-electron oxidation-induced dimerizing C-C coupling of a 2,5-diamino-1,4-benzoquinonediimine: a chemical and electrochemical investigation New J. Chem. 2005, 29, 188-192.

316. P. BRAUNSTEIN, Y. CHAUVIN, S. MERCIER, L. SAUSSINE Influence of Intramolecular N-H⋅⋅⋅O-Ni Hydrogen Bonding in Nickel(II) Diphenylphosphinoenolate Phenyl

Complexes on the Catalytic Oligomerization of Ethylene. C. R. Chimie 2005, 8, 31-38. 317. M. VEITH, N. AUVRAY, V. HUCH, P. BRAUNSTEIN An Iron-Sulfur-Tin Cluster with Amino-Ligands and its Reactions with Thiols. C. R. Chimie 2005, 8, 57-64. 318. C. S. J. CAZIN, M. VEITH, P. BRAUNSTEIN, R. B. BEDFORD

Versatile Methods for the Synthesis of –Si(OR)3-Functionalised Imidazolium Salts, Potential Precursors for Heterogeneous NHC Catalysts and Composite Materials. Synthesis, 2005, 622-626.

319. N. OBERBECKMANN-WINTER, X. MORISE, P. BRAUNSTEIN, R. WELTER Synthesis and Structure of Pt(II) Phosphonato-Phosphine Complexes and of a P,O-Stabilized Metal-Metal-

Bonded Pt2Ag2 Complex. Inorg. Chem. 2005, 44, 1391-1403. 320. Q.-Z. YANG, O. SIRI, P. BRAUNSTEIN

First Transamination Reactions for the One-Pot Synthesis of Substituted Zwitterionic Quinones. Chem. Commun. 2005, 2660-2662. 321. N. OBERBECKMANN-WINTER, P. BRAUNSTEIN, R. WELTER Palladium Phosphino-Iminolate Complexes as Metalloligands for Coinage Metals: A Versatile, Ambivalent

Behavior. Organometallics, 2005, 24, 3149-3157.


322. P. BRAUNSTEIN, C. CHARLES, R. D. ADAMS Iron, Silicon, Tin Polymetallic Complexes: Formation of trans,cis,cis-[Fe(CO)2(dppm-P,P)(SnClPh2)2] by

Silicon-Tin Exchange and Its Crystal Structure. C. R. Chimie 2005, 8, 1873-1877. 323. W. SCHUH, P. BRAUNSTEIN, M. BÉNARD, M.-M. ROHMER, R. WELTER Metal « Capture» by a Heterotrimetalloligand, Heterometallic d10-d10 Interactions, and Unexpected Iron-to-

Platinum Silyl Ligand Migration: a Combined Experimental and Theoretical Study. J. Am. Chem. Soc. 2005, 127, 10250-10258. 324. Q.-Z. YANG, O. SIRI, P. BRAUNSTEIN Tunable N-substitution in Zwitterionic Benzoquinonemonoimine Derivatives : Metal Coordination,

Tandemlike Synthesis of Zwitterionic Metal Complexes, and Supramolecular Structures. Chem. Eur. J. 2005, 11, 7237-7246.

325. O. SIRI, J.-p. TAQUET, J.-P. COLLIN, M.-M. ROHMER, M. BÉNARD, P. BRAUNSTEIN Tunable Charge Delocalization in Dinickel Quinonoid Complexes

Chem. Eur. J. 2005, 11, 7247-7253. 326. M. AGOSTINHO, A. BANU, P. BRAUNSTEIN, R. WELTER, X. MORISE New palladium complexes with phosphino- and phosphinitopyridine ligands Acta Cryst. 2006, C62, m81-m86. 327. P. BRAUNSTEIN, O. SIRI, J.-p. TAQUET, Q.-Z. YANG

Regioselective Carbon-Carbon Bond Formation Reactions between TCNE or TCNQ and a Quinonoid Ring Angew. Chem. Int. Ed. 2006, 45, 1393-1397; Angew. Chem. 2006, 118, 1358-1367.

328. V. GALLO, P. MASTRORILLI, C. F. NOBILE, P. BRAUNSTEIN, U. ENGLERT Chelating versus bridging bonding mode of N-substituted bis(diphenylphosphanyl)amine ligands in Pt

complexes and Co2Pt clusters Dalton Trans., 2006, 2342-2349.

329. P. KEMPGENS, K. ELBAYED, J. RAYA, P. GRANGER, J. ROSÉ, P. BRAUNSTEIN

Investigations of Tetrahedral Mixed-Metal Carbonyl Clusters by Two Dimensional 59Co COSY and DQFCOSY NMR Experiments. Inorg. Chem. 2006, 45, 3378-3383.

330. N. AUVRAY, T. S. BASU BAUL, P. BRAUNSTEIN, P. CROIZAT, U. ENGLERT, G. E. HERBERICH, R.

WELTER Organometallic Building Blocks with Amino-Substituted Cyclopentadienyl and Boratabenzene Ligands for

the Synthesis of Heterometallic Complexes and Clusters Dalton Trans. 2006, 2950-2958.

331. J.-p. TAQUET, O. SIRI, P. BRAUNSTEIN, R. WELTER Dinuclear Nickel and Palladium Complexes with Bridging 2,5-Diamino-1,4-benzoquinonediimines :

Synthesis, Structures, and Catalytic Oligomerization of Ethylene. Inorg. Chem. 2006, 45, 4668-4676.

332. P. CROIZAT, N. AUVRAY, P. BRAUNSTEIN, R. WELTER Comparative Bonding Behavior of Functional Cyclopentadienyl Ligands and Boron-Containing Analogues in Heterometallic Complexes and Clusters. Inorg. Chem. 2006, 45, 5852-5866.

333. G. MARGRAF, R. PATTACINI, A. MESSAOUDI, P. BRAUNSTEIN Intra- and Inter-molecular Phosphoryl Migration in Phosphinothiazolines; Precursors to Polynuclear

Complexes and Bimetallic Coordination Polymers. Chem. Commun., 2006, 3098-3100.

334. Q.-Z. YANG, O. SIRI, H. BRISSET, P. BRAUNSTEIN Synthesis and first characterization of N-alkyldiaminoresorcinols Tetrahedron Lett. 2006, 47, 5727-5731.


335. F. SCHWEYER-TIHAY, C. ESTOURNÈS, P. BRAUNSTEIN, J. GUILLE, J.-L. PAILLAUD, M. RICHARD-PLOUET, J. ROSÉ On the nature of metallic nanoparticles obtained from molecular Co3Ru carbonyl clusters in mesoporous silica matrices Phys. Chem. Chem. Phys. 2006, 8, 4018-4028.

336. Q.-Z. YANG, A. KERMAGORET, M. AGOSTINHO, O. SIRI, P. BRAUNSTEIN

Nickel Complexes with Functional Zwitterionic N,O-Benzoquinonemonoimine-type Ligands: Synthesis, Structures and Catalytic Oligomerization of Ethylene. Organometallics, 2006, 25, 5518-5527.

337. M. KNORR, I. JOURDAIN, P. BRAUNSTEIN, C. STROHMANN, A. TIRIPICCHIO, F. UGOZZOLI Insertion Reactions of Alkynes and Organic Isocyanides into the Palladium-Carbon Bond of Dimetallic Fe-Pd Alkoxysilyl Complexes Dalton Trans. 2006, 5248-5258.

338. P. BRAUNSTEIN, O. SIRI, P. STEFFANUT, M. WINTER, Q.-Z. YANG Synthesis and Properties of Copper Quinonoid Complexes for Optical Recording Application C. R. Chimie, 2006, 9, 1493-1499.

339. M. AGOSTINHO, P. BRAUNSTEIN

Structurally Characterized Intermediates in the Stepwise Insertion of CO/Ethylene or CO/Methyl Acrylate into the Metal-Carbon Bond of Pd(II) Complexes Stabilized by (Phosphinomethyl)Oxazoline Ligands.

Chem. Commun., 2007, 58-60. 340. D. BELLETTI, P. BRAUNSTEIN, A. MESSAOUDI, R. PATTACINI, G. PREDIERI, A. TIRIPICCHIO.

Trapping a pseudo-Hofmann rearrangement on a ruthenium cluster Chem. Commun., 2007, 141-143.

341. M. AGOSTINHO, P. BRAUNSTEIN, R. WELTER

Phosphinito- and Phosphonito-oxazoline Pd(II) Complexes as CO/Ethylene Insertion Intermediates : Synthesis and Structural Characterization.

Dalton Trans. 2007, 759-770. 342. M. KNORR, P. BRAUNSTEIN, A. MESSAOUDI, A. TIRIPICCHIO, F. UGOZZOLI Synthesis and Crystal Structure of a Heteronuclear Fe-Ru Silyl Complex J. Cluster Sci. 2007, 18, 289-301. 343. O. SIRI, P. BRAUNSTEIN, J.-P.-TAQUET, J.-P. COLLIN, R. WELTER Tetranuclear Palladium Complexes with Benzoquinonediimine Ligands: Synthesis, Molecular Structure and

Electrochemistry. Dalton Trans. 2007, 1481-1483. 344. M. AGOSTINHO, P. BRAUNSTEIN

Palladium(II) Complexes with the New P,N-type Ligand (2-oxazoline-2-ylmethyl)di-isopropylphosphine as Intermediates in CO/Ethylene Insertion or CO/Methyl Acrylate Insertion. C. R. Chimie, 2007, 10, 666-676.

345. S. GROSSHANS-VIELES, F. TIHAY-SCHWEYER, P. RABU, J.-L. PAILLAUD, P. BRAUNSTEIN, B.

LEBEAU, C. ESTOURNES, J.-L. GUILLE, J.-M. RUEFF Direct synthesis of mesoporous silica containing cobalt: A new strategy using a cobalt soap as a co-template. Micropor. Mesopor. Mater. 2007, 106, 17-27.

346. A. KERMAGORET, R. PATTACINI, P. CHAVEZ-VASQUEZ, G. ROGEZ, R. WELTER, P. BRAUNSTEIN

Unprecedented Tetranuclear Complexes with 20-Electron Ni(II) Centers : The Role of Pressure and Temperature on Their Solid-State and Solution Fragmentation. Angew. Chem. Int. Ed. 2007, 46, 6438-6441.

347. A. MESSAOUDI, P. DEGLMANN, P. BRAUNSTEIN, P. HOFFMANN

Investigations on a Novel Silyl Transfer Reaction in Heterodimetalic Chemistry Inorg. Chem. 2007, 46, 7899-7909.

348. S. JIE, M. AGOSTINHO, A. KERMAGORET, C. S. J. CAZIN, P. BRAUNSTEIN Mono- and Dinuclear Cobalt Complexes with Bidentate P,N Phosphino- and Phosphinito-oxazoline Ligands: Structures and Catalytic Ethylene Oligomerisation. Dalton Trans. 2007, 4472-4482.


349. R. PATTACINI, C. GIANSANTE, P. CERONI, M. MAESTRI, P. BRAUNSTEIN

Phosphino-Aminothiazoline Platinum(II) and Platinum(II)/Gold(I) Complexes. Structural, Chemical and Vapoluminescent Properties. Chem. Eur. J. 2007, 13, 10117-10128.

350. M. RODRIGUEZ-ZUBIRI, V. GALLO, J. ROSÉ, R. WELTER, P. BRAUNSTEIN Assembling Metals and Clusters around an Octaphosphine Ligand Based on N-substituted Bis(diphenylphosphanyl)amines: Structural Characterization of Dendrimer-like Co12 and Co16 Branched Clusters. Chem. Commun., 2008, 64-66.

351. S. GROSSHANS-VIÈLES, P. CROIZAT, J.-L. PAILLAUD, P. BRAUNSTEIN, O. ERSEN, J. ROSÉ, B. LEBEAU, P. RABU, C. ESTOURNÈS. Molecular Clusters in Mesoporous Materials as Precursors to Nanoparticles of a New Lacunar Ternary Compound Pd1.7Mo0.4P.

J. Cluster Sci. Cotton Memorial Special Issue, 2008, 19, 73-88.

352. A. KERMAGORET, P. BRAUNSTEIN Mono- and Dinuclear Nickel Complexes with Phosphino-, Phosphinito- and Phosphonito-pyridine Ligands: Synthesis, Structures and Catalytic Oligomerization of Ethylene. Organometallics, 2008, 27, 88-99.

353. A. KERMAGORET, P. BRAUNSTEIN Contrasting Bonding Modes of a Tridentate Bis(oxazoline)phosphine Ligand in Cobalt and Iron vs. Palladium

Complexes: Unprecedented N,N-coordination for a N,P,N Ligand. Dalton Trans. 2008, 585-587.

354. A. KERMAGORET, P. BRAUNSTEIN SHOP-Type Nickel Complexes with Alkyl Substituents on Phosphorus, Synthesis and Catalytic Ethylene

Oligomerization. Dalton Trans. 2008, 822-831.

355. A. NAITABDI, O. TOULEMONDE, J . P. BUCHER, J. ROSÉ, P. BRAUNSTEIN, R. WELTER, M. DRILLON Grafting and Thermal Stripping of Organo-Bimetallic Clusters on Au Surfaces: Towards Controlled Co/Ru Aggregates Chem. Eur. J. 2008, 14, 2355-2362.

356. R. PAOLILLO, V. GALLO, P. MASTRORILLI, C. F. NOBILE, J. ROSÉ, P. BRAUNSTEIN Tri- and Tetranuclear Homo- and Heterometallic Clusters as Precatalysts for the Pauson-Khand Reaction

Organometallics, 2008, 27, 741-746.

357. A. KERMAGORET, P. BRAUNSTEIN Synthesis of Nickel Complexes with Bidentate N,O-type Ligands and Application in the Catalytic

Oligomerization of Ethylene. Dalton Trans. 2008, 1564-1573.

358. S. CLAPHAM, P. BRAUNSTEIN, N. M. BOAG, R. WELTER, M. J. CHETCUTI

Carbon-Phosphorus Bond Cleavage in Allyldiphenylphosphine by a Heterobimetallic Ni=Mo Complex and Formation of an Unsaturated NiMo2 µ-Diphenylphosphido Cluster. Organometallics, 2008, 27, 1758-1764.

359. C. SEILLAN, P. BRAUNSTEIN, O. SIRI Selective Reduction of Carbonyl Amides: Toward the first Unsymmetrical Bischelating N-substituted 1,2-Diamino-4,5-diamidobenzene. Eur. J. Org. Chem. 2008, 3113-3117.

360. A. KERMAGORET, F. TOMICKI, P. BRAUNSTEIN

Nickel and iron complexes with N,P,N-type ligands: synthesis, structure and catalytic oligomerization of ethylene. Dalton Trans. 2008, 2945-2955.

361. A. HAMADA, P. BRAUNSTEIN Lithium-Palladium Complex Supported by Phosphonatophosphine and Chloride Ligands. Inorg. Chem. 2008, 47, 3934-3936.


362. M. HMADEH, H. TRABOULSI, M. ELHABIRI, P. BRAUNSTEIN, A.-M. ALBRECHT-GARY, O. SIRI Synthesis, characterization and photophysical properties of benzidine-based compounds. Tetrahedron, 2008, 64, 6522-6529. 363. O. DIEBOLT, P. BRAUNSTEIN, S. P. NOLAN, C. S. J. CAZIN

Room temperature activation of aryl chlorides in Suzuki-Miyaura coupling using an air- and moisture-stable [PdCl2(NHC)]2 complex (NHC = N-heterocyclic carbene). Chem. Commun., 2008, 3190-3192.

364. C. LI, R. PATTACINI, R. GRAFF, P. BRAUNSTEIN Diphosphinite Ag(I) and Pd(II) Dinuclear Complexes as Adaptable Anion Receptors: An Unprecedented

Bridging Mode for the PF6- Ion.

Angew. Chem. Int. Ed. 2008, 47, 6856-6859.

365. M. RAYNAL, C. S. J. CAZIN, C. VALLÉE, H. OLIVIER-BOURBIGOU, P. BRAUNSTEIN An unprecedented, figure-of-eight, dinuclear iridium(I) dicarbene and iridium(III) « pincer » complexes.

Chem. Commun., 2008, 3983-3985.

366. J. ZHANG, P. BRAUNSTEIN, T. S. A. HOR Highly efficient and selective Cr(III) ethylene trimerization catalysts with [NON] and [NSN]-heteroscorpionate

ligands. Organometallics, 2008, 27, 4277-4279. 367. R. PATTACINI, G. MARGRAF, A. MESSAOUDI, N. OBERBECKMANN-WINTER, P. BRAUNSTEIN Formation of P-C Bonds under Unexpectedly Mild Conditions. Phosphoryl Migration and Metal Coordination

of Diphenylphosphinomethyl-oxazolines and –thiazolines. Inorg. Chem. 2008, 47, 9886-9897. 368. S. JIE, R. PATTACINI, G. ROGEZ, C. LOOSE, J. KORTUS, P. BRAUNSTEIN Synthesis, Structure, Magnetic and Catalytic Properties of New Dinuclear Chromium(III) Complexes with

Oxazoline Alocholate Ligands. Dalton Trans. 2009, 97-105. 369. M. AGOSTINHO, V. ROSA, T. AVILÉS, R. WELTER, P. BRAUNSTEIN Synthesis and characterization of Co and Ni complexes stabilized by keto- and acetamide-derived P,O-type

phosphine ligands. Dalton Trans. 2009, 814-822. 370. C. RANGHEARD, D. PROPRIOL, H. OLIVIER-BOURBIGOU, P. BRAUNSTEIN Direct synthesis of a new class of N,N,N ligands based on 1,2-dihydro-1,10-phenanthroline backbone and

their coordination to Pd complexes. Dalton Trans. 2009, 770-772. 371. R. PATTACINI, S. JIE, P. BRAUNSTEIN Facile dichloromethane activation and phosphine methylation. Isolation of unprecedented zwitterionic

organozinc and organocobalt intermediates. Chem. Commun. 2009, 890-892. 372. P. CROIZAT, F. MÜLLER, H. MANTZ, A. ENGLISCH, R. WELTER, S. HÜFNER, P. BRAUNSTEIN

Synthesis of functional heterometallic complexes and clusters containing molybdenum and palladium or platinum, their self-assembly on gold surfaces and X-ray photoelectron spectroscopic studies. C. R. Chimie, 2009, 12, 1228-1247.

373. A. HAMADA, P. BRAUNSTEIN Bis(diphenylphosphino)methane-Phosphonate Ligands and Their Pd(II), Ni(II) and Cu(I) Complexes. catalytic

Oligomerization of Ethylene. Inorg. Chem. 2009, 48, 1624-1637. 374. P. BRAUNSTEIN, D. BUBRIN, B. SARKAR Synthesis of Bis(phosphinoferrocenyl) Copper Complexes from Zwitterionic Quinonoid Ligands and Their

Structural and Redox Properties. Inorg. Chem. 2009, 48, 2534-2540.

375. A. HAMADA, P. BRAUNSTEIN

Palladium Alkyl Complexes Containing Phosphonato Phosphine P,O Ligands and Their Reactivity toward CO-Ethylene or Acrylate Insertion. Organometallics, 2009, 28, 1688-1696.


376. P. CHAVEZ, I. GUERRERO RIOS, A. KERMAGORET, R. PATTACINI, A. MELI, C. BIANCHINI, G.

GIAMBASTIANI, P. BRAUNSTEIN Nickel Complexes with Phosphinito-Oxazoline Ligands: Temperature-Controlled Formation of Mono- or Dinuclear Complexes and Catalytic Oligomerization of Ethylene and Propylene. Organometallics, 2009, 28, 1776-1784.

377. C. FLIEDEL, G. SCHNEE, P. BRAUNSTEIN Versatile coordination modes of novel hemilabile S-NHC ligands. Dalton Trans. 2009, 2474-2476. 378. M. RAYNAL, C. S. J. CAZIN, C. VALLÉE, H. OLIVIER-BOURBIGOU, P. BRAUNSTEIN

A new stable CNHC^CH^CNHC N-heterocyclic dicarbene ligand: its mono- and dinuclear Ir(I) and Ir(I)-Rh(I) complexes. Dalton Trans. 2009, 3824-3832.

379. M. RAYNAL, C. S. J. CAZIN, C. VALLÉE, H. OLIVIER-BOURBIGOU, P. BRAUNSTEIN Remarkable Base Effect in the Synthesis of Mono- and Dinuclear Iridium(I) NHC Complexes. Organometallics, 2009, 28, 2460-2470.

380. R. BENDER, C. OKIO, R. WELTER, P. BRAUNSTEIN

Di- and trinuclear phosphido-bridged platinum complexes. Crystal structures of [Pt{CH2=CHC(O)OMe}(PPh3)2], trans-[Pt2(µ-PPh2)2I2(PPh3)2] and cis,cis,cis-[Pt3(µ-I)2(µ-PPh2)2Cl0.5I1.5 (PPh3)2]. Dalton Trans. 2009, 4901-4907.

381. F. B. TAMBOURA, C. S. J. CAZIN, R. PATTACINI, P. BRAUNSTEIN Reactions of Amines with Zwitterionic Quinoneimines: Synthesis of New Anionic and Zwitterionic Quinonoids Eur. J. Org. Chem. 2009, 3340-3350. 382. M. RAYNAL, R. PATTACINI, C. S. J. CAZIN, C. VALLÉE, H. OLIVIER-BOURBIGOU, P. BRAUNSTEIN

Reaction Intermediates in the Synthesis of New Hydrido, N-Heterocyclic Dicarbene Iridium(III) Pincer Complexes. Organometallics, 2009, 28, 4028-4047.

383. M. OʼREILLY, R. PATTACINI, P. BRAUNSTEIN

Anion Effect in the Diastereoselective Formation of Bischelated Ni(II) Complexes with a Novel, Chiral Phosphine Derived from 1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU). Dalton Trans. 2009, 6092-6095.

384. J.-B. CAZAUX, P. BRAUNSTEIN, L. MAGNA, L. SAUSSINE, H. OLIVIER-BOURBIGOU Mono(aryloxido)-Titanium(IV) Complexes and Their Application in the Selective Dimerization of Ethylene. Eur. J. Inorg. Chem. 2009, 2942-2950.

385. H. S. DAS, A. K. DAS, R. PATTACINI, R. HÜBNER, B. SARKAR, P. BRAUNSTEIN

First Structurally Characterised Mono- and Dinuclear Ruthenium Complexes Derived from Zwitterionic Quinonoid Ligands. Chem. Commun. 2009, 4387-4389.

386. M. RAYNAL, X. LIU, R. PATTACINI, C. VALLÉE, H. OLIVIER-BOURBIGOU, P. BRAUNSTEIN

Unprecedented cubane-type silver cluster with a novel phosphinite functionalized N-heterocyclic carbene ligand Dalton Trans., 2009, 7288–7293.

387. R. PELOSO, R. PATTACINI, C. S. J. CAZIN, P. BRAUNSTEIN Structure and Reactivity of New Iridium Complexes with Bis(Oxazoline)-Phosphonito Ligands Inorg. Chem. 2009, 48, 11415-11424. 388. S. SCULFORT, P. CROIZAT, A. MESSAOUDI, M. BÉNARD, M.-M. ROHMER, R. WELTER, P.

BRAUNSTEIN 2-Dimensional Triangular and Square Heterometallic Clusters: the Influence of the Close-Shell d10 Electronic Configuration Angew. Chem. Int. Ed. 2009, 48, 9663-9667.


389. J. ZHANG, R. PATTACINI, P. BRAUNSTEIN Tridentete Assembling Ligands Based on Oxazoline and Phosphorus Donors in Dinuclear Pd(I)-Pd(I)

Complexes Inorg. Chem. 2009, 48, 11954-11962. 390. C. C. CARMONA, S. CLAPHAM, M. GONIDEC, V. RITLENG, P. BRAUNSTEIN, R. WELTER, M. J.

CHETCUTI Reactions of Unsaturated Nickel-Molybdenum and -Tungsten Complexes with Primary Amines:

Chemoselective N-Coordination to Nickel to Give the First Structurally Characterized Primary Amine-Organonickel Complexes. Eur. J. Inorg. Chem. 2010, 403-409.

391. S. LIU, R. PELOSO, P. BRAUNSTEIN Palladium and Iridium Complexes with a N,P,N-bis(pyridine)phenylphosphine Ligand Dalton Trans. 2010, 39, 2563-2572. 392. A. PARETZKI, R. PATTACINI, R. HÜBNER, P. BRAUNSTEIN, B. SARKAR

Stabilising a Quinonoid-Bridged Dicopper(I) Complex by Use of a dppf (dppf = (diphenylphosphino)ferrocene) Backbone. Chem. Commun. 2010, 1497-1499.

393. S. SCULFORT, R. WELTER, P. BRAUNSTEIN Heterometallic Chains and Clusters with Gold-Transition Metal Bonds: Synthesis and Interconversion Inorg. Chem. 2010, 49, 2372-2382.

394. O. DIEBOLT, V. JURCIK, R. CORREA da COSTA, P. BRAUNSTEIN, L. CAVELLO, S. P. NOLAN, A. M. Z. SLAWIN, C. S. J. CAZIN

Mixed Phosphite/N-Hetrocyclic Carbene Complexes: Synthesis, Characterization and Catalytic Studies Organometallics, 2010, 29, 1443-1450. 395. J. ZHANG, P. TEO, R. PATTACINI, A. KERMAGORET, R. WELTER, G. ROGEZ, T. S. A. HOR, P.

BRAUNSTEIN Structural Effects of Sodium Cations in Polynuclear, Multicubane-Type Mixed Na-Ni Complexes. Angew. Chem. Int. Ed. 2010, 49, 4443-4446.

396. J. XIAO, Z. ZHANG, D. WU, L. ROUTABOUL, P. BRAUNSTEIN, B. DOUDIN, Y. B. LOSOVYJ, O.

KIZILKAYA, L. G. ROSA, C. N. BORCA, A. GRUVERMAN, P. A. DOWBEN The interface bonding and orientation of a quinonoid zwitterion. Phys. Chem. Chem. Phys. 2010, 12, 10329-10340.

397. C. FLIEDEL, R. PATTACINI, P. BRAUNSTEIN Mono-, Di- and Tetranuclear Complexes and Clusters with Bromine-Functionalized Bis(diphenylphosphino)amine Ligands. J. Cluster Sci. 2010, 21, 397-415 (Special Issue dedicated to M. H. Chisholm)

398. C. LI, R. PATTACINI, P. BRAUNSTEIN A Fluorene-based Diphosphinite Ligand, its Ni, Pd, Pt, Fe, Co and Zn Complexes and the First Structurally

Characterized Diphosphinate Metal Chelates Inorg. Chim. Acta 2010, 363, 4337-4345 (Special issue dedicated to A. Müller) 399. C. FLIEDEL, A. SABBATINI, P. BRAUNSTEIN

Synthesis of N,Nʼ-bis(thioether)-functionalized imidazolium salts: their reactivity towards Ag and Pd complexes and first S,CNHC,S free carbene. Dalton Trans. 2010, 39, 8820-8828.

400. L. KAYSER, R. PATTACINI, G. ROGEZ, P. BRAUNSTEIN Nuclearity of Nickel and Mixed Sodium-Nickel Complexes: Dependence on the Spacer in Chelating Pyridine-Alcoholate Ligands Chem. Commun. 2010, 46, 6461-6463.

401. W. ZUO, P. BRAUNSTEIN

Evidence for C–H···X–Ir (X = Cl or I) Hydrogen Bonding between Imidazolium Salts and Iridium-bound Halides and Formation of Ir(I) NHC Complexes Organometallics, 2010, 29, 5535-5543.


402. C. FLIEDEL, P. BRAUNSTEIN Thioether-functionalized N-Heterocyclic Carbenes: Mono-, and Bis-(S,CNHC) Palladium Complexes, Catalytic C-C coupling, and Characterization of a Unique Ag4I4(S,CNHC)2 Planar Cluster. Organometallics, 2010, 29, 5614-5626.

403. S. ZHANG, R. PATTACINI, P. BRAUNSTEIN

Reactions of a Phosphinoimino-thiazoline-Based Metalloligand with Organic and Inorganic Electrophiles and Metal-Induced Ligand Rearrangements. Organometallics, 2010, 29, 6660-6667.

404. S. LIU, R. PELOSO, R. PATTACINI, P. BRAUNSTEIN

Electrophilic activation and the formation of an unusual Tl+/Cr3+ tetranuclear ion-complex adduct Dalton Trans. 2010, 39, 7881-7883.

405. N. DEIBEL, D. SCHWEINFURTH, R. HUEBNER, P. BRAUNSTEIN, B. SARKAR

“Double redox-activity” in azobenzene-quinonoid palladium(II) complexes: a combined structural, electrochemical and spectroscopic study. Dalton Trans. 2011, 40, 431-436.

406. Z. ZHANG, J. ALVIRA, X. BARBOSA, L. G. ROSA, L. ROUTABOUL, P. BRAUNSTEIN, B. DOUDIN, P. A.

DOWBEN Lock and Key Adsorption Chemistry: Preferential Absorption of an Isomer of Di-iodobenzene on Molecular Films of Quinonoid Zwitterions J. Phys. Chem. C, 2011, 115, 2812-2818.


Unexpected metal-induced isomerisms and phosphoryl migrations in Pt(II) and Pd(II) complexes of the functional phosphine 2-(bis(diphenylphosphino)methyl)-oxazoline. Inorg. Chem. 2011, 50, 3511-3522.


Chelating or bridging Pd(II) and Pt(II) metalloligands from the functional phosphine ligand N-(diphenylphosphino)-1,3,4-thiadiazol-2-amine. New heterometallic Pd(II)/Pt(II) and Pt(II)/Au(I) complexes. Dalton Trans., 2011, 40, 5711-5719.

409. P. de FRÉMONT, H. CLAVIER, V. ROSA, T. AVILES, P. BRAUNSTEIN Synthesis, Characterization and Reactivity of Cationic Gold(I) α-Diimine Complexes Organometallics, 2011, 30, 2241-2251.

410. A. BOUDIER, P.-A. R. BREUIL, L. MAGNA, C. RANGHEARD, J. PONTHUS, H. OLIVIER-BOURBIGOU, P. BRAUNSTEIN Novel Catalytic System for Ethylene Oligomerization: an Iron(III) Complex with an Anionic N,N,N Ligand. Organometallics, 2011, 30, 2640-2642.

411. X. LIU, R. PATTACINI, P. DEGLMANN, P. BRAUNSTEIN

Do short C-H-M (M = Cu(I), Ag(I)) distances represent agostic interactions in pincer-type complexes? Unusual NHC transmetalation from Cu(I) to Ag(I). Organometallics, 2011, 30, 3302-3310.

412. S. LIU, R. PATTACINI, P. BRAUNSTEIN

Reactions between an ethylene oligomerization Cr(III) pre-catalyst and Al-based activators: alkyl and cationic complexes with a tridentate N,P,N ligand. Organometallics, 2011, 30, 3549-3558.

413. R. PATTACINI, P. TEO, J. ZHANG, Y. LAN, A. K. POWELL, J. NEHRKORN, O. WALDMANN, T. S. A. HOR,

P. BRAUNSTEIN Synthesis, Characterization, and Single-Molecule Metamagnetism of New Co(II) Polynuclear Complexes of Pyridine-2-ylmethanol. Dalton Trans. 2011, 40, 10526-10534.

414. T. KAUF, P. BRAUNSTEIN Contrasting Behaviour of TCNE and TCNQ Zwitterionic benzoquinonemonoimine derivatives and coordination of tricyanoethenyl substituent to Pd(0). Dalton Trans. 2011, 40, 9967-9970.


415. T. KAUF, P. BRAUNSTEIN Reactivity of TCNE or TCNQ Derivatives of Quinonoid Zwitterions: Platinum-Induced HCN Elimination vs. Oxidative-Addition Inorg. Chem. 2011, 50, 11472-11480.

416. A. DANOPOULOS, P. BRAUNSTEIN, N. STYLIANIDES M. WESOLEK Aminolysis of Bis[bis(trimethylsilyl)amido]-Iron and -Cobalt as a Versatile Route to N-Heterocyclic Carbene Complexes Organometallics, 2011, 30, 6514-6517.

417. W. ZUO, P. BRAUNSTEIN N-Heterocyclic Dicarbene Iridium(III) Pincer Complexes Featuring Mixed NHC/abnormal NHC Ligands and Their Applications in the Transfer Dehydrogenation of Cyclooctane Organometallics, 2012, 31, 2606-2615.

418. J. ZHANG, R. PATTACINI, S. JIE, P. BRAUNSTEIN A Phosphino-Oxazoline Ligand as P,N-Bridge in Palladium/Cobalt or P,N-Chelate in Nickel Complexes;

Catalytic Ethylene Oligomerization. Dalton Trans. 2012, 379-386.

419. X. LIU, J. LACOUR, P. BRAUNSTEIN Chiral Anions-Based NMR Enantiodiscrimination of a Dinuclear, Cationic Ir(I) NHC Complex with a Figure-of-Eight Loop Structure Dalton Trans. 2012, 41, 138-142.

420. W. ZUO, P. BRAUNSTEIN

Stepwise Synthesis of a Hydrido, N-Heterocyclic Dicarbene Iridium(III) Pincer Complex Featuring Mixed NHC/abnormal NHC Ligands Dalton Trans. 2012, 636-643.

421. C. VOSS, R. PATTACINI, P. BRAUNSTEIN Intramolecular d10-d10 Interactions in neutral, dinuclear Au(I) complexes supported by amino-thiazoline- and -

thiazole-based P,N-phosphine ligands C. R. Chimie, 2012, 15, 229-236

422. S. HOHLOCH, S. SCHUSTER, E. KLEMM, P. BRAUNSTEIN, B. SARKAR Ruthenium Hydride Complexes with Zwitterionic Quinonoid Ligands: Isomer Separation, Structural Properties, Electrochemistry and Catalysis Eur. J. Inorg. Chem. 2012, 546-553.

423. K. Yu. MONAKHOV, C. GOULAOUEN, R. PATTACINI, P. BRAUNSTEIN

Heptabismuthate [Bi7I24]3-: A Main Group Element Anderson-Type Structure and Its Relationships with the Polyoxometalates Inorg. Chem. 2012, 51, 1562-1568.

424. L. KONG, G. J. PEREZ MEDINA, J. A. COLÓN SANTANA, F. WONG, M. BONILLA, D. A. COLÓN AMILL, L.

G. ROSA, L. ROUTABOUL, P. BRAUNSTEIN, B. DOUDIN, C.-M. LEE, J. CHOI, J. XIAO, P. A. DOWBEN Weak Screening of a Large Dipolar Molecule Adsorbed on Graphene Carbon, 2012, 50, 1981-1986.

425. L. G. ROSA, J. VELEV, Z. ZHANG, J. ALVIRA, O. VEGA, G. DIAZ, L. ROUTABOUL, P. BRAUNSTEIN, B.

DOUDIN, Y. B. LOSOVYJ, P. A. DOWBEN

Approaching an Organic Semi-metal: Electron Pockets at the Fermi Level for p-benzoquinonemonoimine Zwitterion Phys. Status Solidi B, 2012, 249, 1571-1576.

426. L. ROUTABOUL, P. BRAUNSTEIN, J. XIAO, Z. ZHANG, P. A. DOWBEN, G. DELMAS, V. DACOSTA, O.

FELIX, G. DECHER, L. G. ROSA, B. DOUDIN Altering the Static Dipole on Surfaces Through Chemistry: Molecular Films of p-benzoquinonemonoimine Zwitterions J. Am. Chem. Soc. 2012, 134, 8494-8506.

427. A. DANOPOULOS, P. BRAUNSTEIN, M. WESOLEK, K. Yu. MONAKHOV, P. RABU, V. ROBERT Three-Coordinate Iron(II) N-Heterocyclic Carbene Alkyl Complexes Organometallics, 2012, 31, 4102-4105.


428. D. KUNKEL, S. SIMPSON, J. NITZ, G. ROJAS, E. ZUREK, L. ROUTABOUL, B. DOUDIN, P. BRAUNSTEIN, P. DOWBEN, A. ENDERS Dipole-Driven Bonding Schemes of Quinonoid Zwitterions on Surfaces Chem. Commun. 2012, 48, 7143-7145.

429. B. JACQUES, J. KIRSCH, P. de FRÉMONT, P. BRAUNSTEIN

NHC Gold(III) Triflimidate Complexes Organometallics, 2012, 31, 4654-4657.

430. F. HASANAYN, P. ACHORD, P. BRAUNSTEIN, H. J. MAGNIER, K. KROGH-JESPERSEN, A. S. GOLDMAN

Theoretical Structure-Reactivity Study of Ethylene Insertion into Nickel Alkyl Bonds. A Kinetically Significant and Unanticipated Role of trans Influence in Determining Agstic Bond Strength Organometallics, 2012, 31,4680-4692.

431. F. GRASSET, J.-B. CAZAUX, L. MAGNA, P. BRAUNSTEIN, H. OLIVIER-BOURBIGOU

New bis(aryloxido)Ti(IV) Complexes and Their Use for the Selective Dimerization of Ethylene to But-1-ene Dalton Trans. 2012, 41, 10396-10404.

432. K. Yu. MONAKHOV, C. GOURLAOUEN, P. BRAUNSTEIN

Stabilisation of a Triply-Bridging Cyclopentadienyl Ligand in a Tetrapalladium Cluster Chem. Commun. 2012, 48, 8317-8319.

433. A. BOUDIER, P.-A. R. BREUIL, L. MAGNA, H. OLIVIER-BOURBIGOU, P. BRAUNSTEIN Nickel(II) complexes with imino-imidazole chelating ligands bearing pendant donor groups (SR, OR, NR2, PR2) as precatalysts in ethylene oligomerisation J. Organomet. Chem. 2012, 718, 31-37.

434. S. CONDE-GUADANO, M. HANTON, R. P. TOOZE, A. A. DANOPOULOS, P. BRAUNSTEIN Amidine- and amidinate-functionalised N-heterocyclic carbene complexes of silver and chromium Dalton Trans. 2012, 41, 12558-12567.

435. D. SCHWEINFURTH, C.-Y. SU, S.-C. WEI, P. BRAUNSTEIN, B. SARKAR

Nickel complexes with ʻclickʼ-derived pyridyl-triazoles ligands: weak intermolecular interactions and catalytic ethylene oligomerisation Dalton Trans. 2012, 41, 12984-12990.

436. P. MASTRORILLI, S. TODISCO, M. LATRONICO, V. GALLO, N. RE, F. CREATI, P. BRAUNSTEIN

Pt-Mo and Pt-W Mixed-Metal Clusters with Chelating or Bridging Diphosphine Short-Bite Ligands (Ph2P)2NH and (Ph2P)2N(CH2)9CH3: a Combined Synthetic and Theoretical Study Inorg. Chem. 2012, 51, 11549-11561.

437. A. A. DANOPOULOS, K. Yu. MONAKHOV, P. BRAUNSTEIN Anionic NHC Ligands from Mesoionic Imidazolium Precursors: Remote Backbone Arylimino Substitution

Directs Carbene Coordination. Chem. Eur. J. 2013, 19, 450-455. 438. C. ARCHAMBAULT, R. BENDER, Y. DUSAUSOY, R. WELTER, P. BRAUNSTEIN

Diplatinum complexes: Chemoselective reactions of the µ-orthometalated, metal–metal bonded complex [Pt2(µ-o-C6H4PPh2)(µ-PPh2)(PPh3)2] with acids. Crystal structures of [Pt2Cl(µ-PPh2)(PPh3)3], [Pt2I(µ-PPh2) (PPh3)3], [Pt2(µ-H)(µ-PPh2)I2(PPh3)2] and cis,cis-[Pt2(µ-I)(µ-PPh2)I2(PPh3)2] Polyhedron, 2013, 52, 545-552. Special Issue « Alfred Werner »

439. A. G. ALGARRA, P. BRAUNSTEIN, S. A. MACGREGOR Computational Study of the Double C-Cl Bond Activation of Dichloromethane and Phosphine Alkylation at [CoCl(PR3)3]. Dalton Trans. 2013, 42, 4208-4217.

440. S.HAMEURY, L. KAYSER, R. PATTACINI, G. ROGEZ, W. WERNSDORFER, P. BRAUNSTEIN Synthesis of Cubane-type Ni(II) Complexes from Pyridyl-Alcohol Ligands; their Single-Molecule Magnet Behaviour Dalton Trans. 2013, 42, 5013-5024.

441. A. A. DANOPOULOS, K. YU. MONAKHOV, V. ROBERT, P. BRAUNSTEIN, R. PATTACINI, S. CONDE-

GUADAÑO, M. HANTON, R. P. TOOZE Angular Distortions at Benzylic Carbons due to Intra-molecular Polarization-Induced Metal–Arene Interactions: a Case Study with Open-Shell Cr(II) NHC Complexes Organometallics, 2013, 32, 1842-1850.


442. A. A. DANOPOULOS, P. BRAUNSTEIN Mono N-heterocyclic carbene amido and alkyl complexes. Cobalt mediated C-H activation and C-C coupling reactions involving benzyl ligands on a 3-coordinate intermediate Dalton Trans. 2013, 42, 7276-7280.

443. L. KONG, L. ROUTABOUL, P. BRAUNSTEIN, H.-G. PARK, J. CHOI, J. P. COLÓN-CÓRDOVA, E. VEGA, L.

G. ROSA, B. DOUDIN, P. A. DOWBEN Adsorption of TCNQH-functionalized quinonoid zwitterions on gold and graphene: evidence for dominant intermolecular interactions. RCS Adv. 2013, 3, 10956-10961.

444. X. LIU, P. BRAUNSTEIN

Complexes with Hybrid Phosphorus-NHC Ligands. Pincer-type Ir Hydrides, Dinuclear Ag and Ir and Tetranuclear Cu and Ag Complexes Inorg. Chem. 2013, 52, 7367-7379.

445. V. ROSA, C. FLIEDEL, A. GHISOLFI, R. PATTACINI, T. AVILES, P. BRAUNSTEIN

Influence of a thioether function in short-bite diphosphine ligands on the nature of their silver complexes: structure of a trinuclear complex and of a coordination polymer. Dalton Trans. 2013, 42, 12019-12119.

446. P. A. DOWBEN, D. A. KUNKEL, A. ENDERS, L. G. ROSA, L. ROUTABOUL, B. DOUDIN, P. BRAUNSTEIN

The Dipole Mediated Surface Chemistry of p-Benzoquinonemonoimine Zwitterions Top. Catal. 2013, 56, 1096-1103.

447. S. SIMPSON, D. A. KUNKEL, J. HOOPER, J. NITZ, P. A. DOWBEN, L. ROUTABOUL, P. BRAUNSTEIN, B.

DOUDIN, A. ENDERS, E. ZUREK Coverage-Dependent Interactions at the Organics-Metal Interface: Quinonoid Zwitterions on Au(111). J. Phys. Chem. C, 2013, 117, 16406-16415.

448. S. ORBISAGLIA, B. JACQUES, P. BRAUNSTEIN, D. HUEBER, P. PALE, A. BLANC, P. DE FRÉMONT

Synthesis, Characterization and Catalytic Activity of Cationic NHC Gold(III) Pyridine Complexes Organometallics, 2013, 32, 4153-4164.

449. A. GHISOLFI, C. FLIEDEL, V. ROSA, R. PATTACINI, A. THIBON, K. Yu. MONAKHOV, P. BRAUNSTEIN

Solvent-Dependent Reversible Ligand Exchange in Nickel Complexes of a Monosulfide Bis(diphenylphosphino)(N-thioether)amine. Chem. Asian J. 2013, 8, 1795-1805.

450. N. DARMAWAN, C.-H. YANG, M. MAURO, M. RAYNAL, S. HEUN, J. PAN, H. BUCHHOLZ, P.

BRAUNSTEIN, L. DE COLA Efficient Near-UV Emitters Based on Cationic Bis-Pincer Iridium(III)-Carbene Complexes.

Inorg. Chem. 2013, 52, 10756-10765. 451. P. LIU, M. WESOLEK, A. A. DANOPOULOS, P. BRAUNSTEIN Elusive Free Bisimino-N-heterocyclic Carbene and Its Rearrangement by C-C Coupling. Characteriztion of

Relevant Iridium(I) and Chromium(II) Complexes. Organometallics, 2013, 32, 6286-6297.

452. N. DEIBEL, S. HOHLOCH, M. G. SOMMER, D. SCHWEINFURTH, F. EHRET, P. BRAUNSTEIN, B. SARKAR Electrochromic Platinum(II) Complexes Derived from Azobenzene and Zwitterionic Quinonoid Ligands: Electronic and Geometric Structures. Organometallics, 2013, 32, 7366-7375.

453. P. BUCHWALTER, J. ROSÉ, B. LEBEAU, P. RABU, P. BRAUNSTEIN, J.-L. PAILLAUD Stoichiometric molecular single source precursors to cobalt phosphides Inorg. Chim. Acta, 2014, 409, 330-341. 454. P. AI, A. A. DANOPOULOS, P. BRAUNSTEIN, K. Yu. MONAKHOV A novel, rigid diphosphine with an active NHC spacer; di- and trinuclear complexes of d10 coinage metals. Chem. Commun. 2013, 49, 103-105. 455. P. BUCHWALTER, J. ROSÉ, B. LEBEAU, O. ERSEN, M. GIRLEANU, P. RABU, P. BRAUNSTEIN, J.-L.

PAILLAUD Characterization of cobalt phosphide nanoparticles derived from molecular clusters in mesoporous silica. J. Nanopart. Res. 2013, 15:2132, 1-21.


456. A. MASSARD, G. ROGEZ, P. BRAUNSTEIN

Synthesis and Characterization of a New Nonanuclear Ni(II) Cluster from a Pyridyl-Alcohol Ligand . Dalton Trans. 2014, 43, 42-46

457. P. AI, A. A. DANOPOULOS, P. BRAUNSTEIN

Non-symmetric diphosphines based on the imidazole scaffold: an unusual group interchange involving Pd-CH3 and (imidazole)P-Ph cleavage Dalton Trans. 2014, 43, 1957-1960.

458. C. FLIEDEL, V. FARAMARZI, V. ROSA, B. DOUDIN, P. BRAUNSTEIN Coordination-Driven Assembling of Micro-objects with Metalloligands Chem. Eur. J. 2014, 20, 1263-1266. 459. S. HAMEURY, P. de FRÉMONT, P.-A. R. BREUIL, H. OLIVIER-BOURBIGOU, P. BRAUNSTEIN

Synthesis and characterization of oxygen-functionalized-NHC silver(I) complexes and NHC transmetallation to nickel(II) Dalton Trans. 2014, 43, 4700-4710.

460. A. A. DANOPOULOS, P. BRAUNSTEIN « Janus-type » Organopotassium Chemistry by Deprotonation of Mesoionic Imidazolium Aminides and Amino N-Heterocyclic Carbenes: Coordination and Organometallic Polymers Chem. Commun. 2014, 50, 3055-3057.

461. K. Yu. MONAKHOV, X. LÓPEZ, M. SPELDRICH, J. van LEUSEN, P. KÖGERLER, P. BRAUNSTEIN, J. M.

POBLET Magnetochemical Complexity of Hexa- and Heptanuclear Wheel Complexes of Late-3d Ions Supported by N,O-Donor Pyridyl-Methanolate Ligands Chem. Eur. J. 2014, 20, 3769-3781.

462. A. GHISOLFI, K. Yu. MONAKHOV, R. PATTACINI, P. BRAUNSTEIN, X. LÓPEZ, C. de GRAAF, M.

SPELDRICH, J. van LEUSEN, H. SCHILDER, P. KÖGERLER A comparative synthetic, magnetic and theoretical study of functional M4Cl4 cubane-type Co(II) and Ni(II) complexes Dalton Trans. 2014, 43, 7847-7859.

463. C. ARCHAMBAULT, R. BENDER, P. BRAUNSTEIN, Y. DUSAUSOY, R. WELTER

Reactions of trinuclear platinum clusters with electrophiles: an example of ionisation isomerism with [Pt3(µ2-I)(µ-PPh2)2(PPh3)3]I and [Pt3(µ-PPh2)2I2(PPh3)3]. Structures of [Pt3(µ2-Cl)(µ-PPh2)2(PPh3)3]PF6, [Pt3(µ-PPh2)2I2(PPh3)3] and of the Pt-Ag cluster [Pt3(µ3-AgBF4)(µ2-I)(µ-PPh2)2(PPh3)3]BF4. Dalton Trans. 2014, 43, 8609-8619.

464. S. HAMEURY, P. de FRÉMONT, P.-A. R. BREUIL, H. OLIVIER-BOURBIGOU, P. BRAUNSTEIN

Synthesis and Characterization of Palladium(II) and Nickel(II) Alcoholate-Functionalized NHC Complexes and of Mixed Nickel(II)-Li(I) Complexes Inorg. Chem. 2014, 53, 5189-5200.

465. B. JACQUES, D. HUEBER, S. HAMEURY, P. BRAUNSTEIN, P. PALE, A. BLANC, P. de FRÉMONT

Synthesis, Characterization and Catalytic Activity of Alcohol-Functionalized NHC Gold(I/III) Complexes Organometallics, 2014, 33, 2326-2335.

466. A. GHISOLFI, A. WALDVOGEL, L. ROUTABOUL, P. BRAUNSTEIN

Reversible Switching of the Coordination Modes of a Pyridine-Functionalized Quinonoid Zwitterion; Its Di- and Tetranuclear Palladium Complexes Inorg. Chem. 2014, 53, 5515-5526.

467. T. BERNARDI, S. BADEL, P. MAYER, J. GROELLY, P. de FRÉMONT, B. JACQUES, P. BRAUNSTEIN, M.-

L. TEYSSOT, C. GAULIER, F. CISNETTI, A. GAUTIER, S. ROLAND High Throughput Screening of Metal-N-Heterocyclic Carbene Complexes Against Biofilm Formation of Pathogenic Bacteria ChemMedChem. 2014, 9, 1140-1144.

468. A. GHISOLFI, C. FLIEDEL, V. ROSA, K. Yu. MONAKHOV, P. BRAUNSTEIN

Combined Experimental and Theoretical Study of Bis(diphenylphosphino)(N-thioether)amine-Type Ligands in Nickel(II) Complexes for Catalytic Ethylene Oligomerization. Organometallics, 2014, 33, 2523-2534.


469. D. SCHIEFER, T. WEN, Y. WANG, P. GOURSOT, H. KOMBER, R. HANSELMANN, P. BRAUNSTEIN, G. REITER, M. SOMMER Nickel Catalyst with a Hybrid P,N Ligand for Kumada Catalyst Transfer Polycondensation of Sterically Hindered Thiophenes ACS Macro Lett. 2014, 3, 617-621.

470. M. YUAN, F. WEISSER, B. SARKAR, A. GARCI, P. BRAUNSTEIN, L. ROUTABOUL, B. THERRIEN

Synthesis and Electrochemical Behavior of a Zwitterion-Bridged Metalla-Cage Organometallics, 2014, 33, 5043-5045.

471. M. JAGENBREIN, A. A. DANOPOULOS, P. BRAUNSTEIN

Bis-N-heterocyclic carbene ʻpincerʼ ligands and iridium complexes with CF3-substituted phenylene backbone J. Organomet. Chem. 2015, 775, 169-172.

472. F. HE, P. BRAUNSTEIN, M. WESOLEK, A. A. DANOPOULOS

Imine-functionalised protic NHC complexes of Ir: direct formation by C–H activation Chem. Commun., 2015, 51, 2814-2817.

473. A. A. DANOPOULOS, P. BRAUNSTEIN, E. REZABAL, G. FRISON

Unprecedented directed lateral lithiations of tertiary carbons on NHC platforms Chem. Commun. 2015, 51, 3049-3052.

474. T. KAUF, V. ROSA, C. FLIEDEL, R. PATTACINI, N. DEIBEL, T. AVILES, B. SARKAR, P. BRAUNSTEIN

Reactivity of TCNE and TCNQ derivatives of quinonoid zwitterions with Cu(I) Dalton Trans. 2015, 44,

475. D. A. KUNKEL, J. HOOPER, S. SIMPSON, D. P. MILLER, L. ROUTABOUL, P. BRAUNSTEIN, B. DOUDIN,

S. BENIWAL, P. DOWBEN, R. SKOMSKI, E. ZUREK, A. ENDERS Self-assembly of strongly dipolar molecules on metal surfaces J. Chem. Phys. 2015,

476. A. MASSARD, P. BRAUNSTEIN, A. A. DANOPOULOS, S. CHOUA, P. RABU

Studies on Three-coordinate [Co{N(SiMe3)2}2L] Complexes, L = N-heterocyclic Carbene Organometallics, 2015, 34,

477. V. CHARRA, P. de FRÉMONT, P.-A. R. BREUIL, H. OLIVIER-BOURBIGOU, P. BRAUNSTEIN

Silver(I) and copper(I) complexes with bis-NHC ligands: Dinuclear complexes, cubanes and coordination polymers J. Organomet. Chem. (ICCC41 special issue), 2015,


PATENTS

1. J. KERVENNAL, J.-M. GOGNION, P. BRAUNSTEIN Procédé de fabrication d'isocyanates aromatiques par carbonylation des dérivés nitrés en présence de

catalyseurs supportés préparés à partir de complexes hétéropolymétalliques. (Aromatic isocyanates by carbonylation of nitro compounds in the presence of supported catalysts prepared from heteropolymetallic complexes)

FR 2 515 640 - U.S. 4. 478. 757 (1982) - Eur. Pat. Appl. EP 78729 A1 (1983) (PCUK) 2. P. BRAUNSTEIN, J. KERVENNAL, J.-L. RICHERT, M. RIES Clusters mixtes à base de palladium et fer utilisables comme catalyseurs; leur procédé de fabrication.

(Palladium-iron mixed clusters used as a catalyst) FR 2 558 074 - US. 4.609.639 (1985) - Eur. Pat. Appl. EP 150137 A2 (1985) (ATOCHEM). 3. D. NOBEL, D. MATT, P. BRAUNSTEIN Procédé de préparation de la lactone éthylidène-2-heptène-6-olide-5, par télomérisation du butadiène et du

dioxyde de carbone. (Preparation of 2-ethylidene-6-vinyltetrahydro-2-pyranone) FR 2617163 A1 (1988) (Université Louis Pasteur). 4. P. BRAUNSTEIN, O. SIRI Zwitterionic derivatives of benzoquinone monoimines, coloring compositions containing same, and use

thereof as dyes, particularly as hair dyes (Dérivés zwitterioniques de benzoquinonemonoimines, compositions colorantes les contenant et utilisation de ces dernières)

FR2001-03473 (12/03/2001) (Université Louis Pasteur et CNRS) – PCT Int. Appl. WO 2002072533 A1 (2002)

5. F. SPEISER, P. BRAUNSTEIN, L. SAUSSINE Organometallic complexes comprising phosphonite ligands and their use for catalyzing olefin oligomerization.

(Complexes organométalliques comportant des ligands phosphonites et leur utilisation pour catalyser l'oligomérisation des oléfines). FR 2837725 A1 (29/03/2002) (Institut Français du Pétrole)

6. F. SPEISER, P. BRAUNSTEIN, L. SAUSSINE Catalysts containing organometallic complexes containing nitrogen-heterocyclic alcohol bidentate chelating

ligands for olefin oligomerization. (Complexes organométalliques comportant des ligands chélatants bidentés associant un hétérocycle azoté avec un alcool et leur utilisation pour catalyser l'oligomérisation des oléfines).

EP 1366816 (priority FR 28/05/2002) (Institut Français du Pétrole) 7. P. BRAUNSTEIN, O. SIRI, J.-P. TAQUET Dérivés cationiques de benzoquinonemonoimines, compositions colorantes les contenant et utilisation de ces

dernières. FR/2002-09144 (18/07/2002) (Université Louis Pasteur et CNRS). 8. P. BRAUNSTEIN, O. SIRI, Q.-Z. YANG Process for synthesis of zwitterionic derivatives of benzoquinone monoimines colorants from 2,4-

diaminoresorcinol and primary amines. FR 2877337 A1 (Université Louis Pasteur et CNRS). 9. P. STEFFANUT, P. BRAUNSTEIN, O. SIRI

Use of zwitterionic or cationic benzoquinonemonoimine-based dyes in optical layers for optical data recording (12/10/2004)) (Clariant International). 10. B. DOUDIN, P. BRAUNSTEIN, L. ROUTABOUL, G. DALMAS, Z. ZHANG, P. DOWBEN

Utilisation de molécules à caractere zwitterionique pour la formation dʼune couche de transport de trous ou dʼelectrons F644-292 (2010) (Centre National le la Recherche Scientifique, Université de Strasbourg, University of Nebraska Lincoln)

Documents

Pierre BRAUNSTEIN - Academia Europaea...P. Braunstein - p 1 PUBLICATION LIST Pierre BRAUNSTEIN Laboratoire de Chimie de Coordination Institut de Chimie (UMR 7177 CNRS) Université