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Advanced Gas Processing
A. ShahsavandA. Shahsavand
Chemical Engineering DepartmentChemical Engineering Department
Faculty of EngineeringFaculty of Engineering
Ferdowsi University of MashadFerdowsi University of Mashad
20102010
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Feedstock & Product
Receives associated gases from
crude oil production units orwellhead separators.
Produces sale gas, Ethane (as
petrochemical feed stock), LPG (C3 -
C4) and light naphtha (C5+)
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Onshore and Offshore
NGL plant facilities
Gas Compression
Onshore
Associated
Gases
Offshore
Associated
Gases
Acid Gas Removal
NGL Recovery Unit
Acid Gas
incineration
or SRU
Sale Gas C2 C5+C4
CondensateC3
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NGL Recovery Unit
A conventional natural gas liquid plantincludes a separator that receives a cooled lowpressure feed gas (heavy HC separation).
The separator is coupled to an absorber (ordistillation column) and a demethanizer.Refrigeration duty of the absorber anddemethanizer are provided at least in part by
expansion of a liquid portion of the cooled lowpressure feed gas and an expansion of a liquidabsorber bottom product.
Propane recovery is at least 99 mol %.
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Ethane Recovery
As ethane recovery becomes increasinglyeconomically attractive, various
configurations have been developed toimprove the recovery of ethane from natural
gas liquids (NGL).
Most commonly, numerous processesemploy either cooling of feed gases via turbo
expansion or a sub-cooled absorptionprocess to enhance ethane recovery.
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Typical NGL unitSlug
CatcherDehumidificationCondensate
Separator
Feed
gas
Water
Refrigeration
LPG Absorber
C5+
Recovery
Recovery
Refrigeration
& Compression
C2
C5+
C3 & C4
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Conventional NGL unit
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Ideas
Can we use new separationprocesses such as PSA or
membrane instead of conventionalRefrigeration process.
These new processes are more
energy efficient and may beattractive from economical point of
view.
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60 MMSCFD NGL Plant,
Alberta, Canada (Start up: January 1998 )
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Hawiyah NGL Recovery
Project, Saudi ArabiaThe Hawiyah NGL Recovery Program produces
310,000 bbl/d of ethane and NGL products from around
four billion SCFD of associated gas.
This project is completed in early 2008..
This plant also produces 170,000 bbl/d of condensate,
and 1,000 t/d of sulphur.
Facilities at the plant, in addition to the four gas-
processing trains that perform gas dehydration, dew-
point control and sales-gas compression, include two gas
sweetening and sulphur recovery trains, two condensate
stabilizers and two sour-water strippers.
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Supply and Demand
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NIOC associated
gas gathering systems
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AMAK Project
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Environmental Issues
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AMAK Products
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Economic Aspects
Annual Product Value:
Total Cost : 530 MMUSD
Payback period: 2 years
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AMAK Gas Treating Unit
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AMAK Compressor Station
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Kharg NGL recovery unit
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Kharg NGL recovery unit
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Approximate Location
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Approximate Location
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Kharg NGL unit Project
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Kharg Associated Gas
Gathering Project
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Onshore Acid Gas
303 MMSCFD303 MMSCFD
Containing Following Impurities:Containing Following Impurities:
H2S : 12.7 mole % (38.5 MMSCFD)
CO2 : 5.5 mole % (16.7 MMSCFD)
COS : 222 ppm
RSH : 217 ppm
RSR : 34 ppm
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Offshore Acid Gas
297 MMSCFD297 MMSCFD
Containing Following Impurities:Containing Following Impurities:
H2S : 3.8 mole % (11.3 MMSCFD)
CO2 : 4.6 mole % (13.7 MMSCFD)
COS : 88 ppm
RSH : 46 ppm
RSR : 4 ppm
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Problems & Solution
80 MMSCFD Acid Gas Removed
H2S : 50 MMSCFD (2034 tone sulfur) Problems: Sales and Marketing,
Warehousing
CO2 : 30 MMSCFD (Emission To Atm.) Problems: Greenhouse Gas, Environmental
Concerns
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Acid Gas Injection
Sour Gas Acid Gas
Sweet Gas
AGRAGR
C&CC&CDisposal
Well
T=40 C
P=180 Bar
Pipeline
Disposal
Layer
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Acid Gas Injection
Injection Depth: 4500m under seabed
In ection Time: 25 ears
Total Injection volume : 128 MMbbl
THE BIGGEST ACID GAS INJECTION
PLANT IN THE WORLD!
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Economical aspect
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Price Per Unit (2004)
Sales Gas 25 $/MSCM
Ethane 65 $/Tone
Price Correlation
Butane 406 $/Tone
Pentane 30 $/BarrelCondensate 35 $/Barrel
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Economical aspect
Annual product value: 720 MMUSD
Onshore NGL facilities cost: 1200 MMUSD
Onshore GC facilities cost: 67 MMUSD
Offshore pipeline: 90 MMUSD
Total Cost : 1357 MMUSD
Payback period: 2 years
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Sox Emission by Flares
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Nox Emission by Flares
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NOx and Sox emission Comparison
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Siri NGL recovery unit
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Siri NGL unit Project
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Economical aspect
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Siri Island Associated Gas
Gathering Project
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Economical Aspect
Annual product value: 180 MMUSD
Onshore NGL facilities cost: 216 MMUSD
Onshore GC facilities cost: 12 MMUSD
Offshore pipeline: 72 MMUSD
Total Cost : 300 MMUSD
Payback period: 2 years
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Environmental Aspect
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Project Schedules (Jan 2005)
Siri Onshore NGL plant:
40 months (ongoing)
s ore p pe ne pro ect:
Executed
Offshore Gas compression platform:
12 months (ongoing)
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Sirri NGL plant to be completed
in two years (Jan 2007)Sirri NGL Plant will collect 140 MMSCFD of associated gases, of
which 40 mcf will be used to produce condensates. This is equal to the
production of 12,000 barrels per day of condensates,
-
construct the plant have so far progressed by 20 percent and expected
to come on stream over the next two years.
Gases from the fields are to be sent to power plants at Qeshm and
Kish, while the extracted gas condensates are to be exported. The gas
transfer pipelines from Sirri to Qeshm and Kish have been completed
in offshore part.
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Canadian NGL Prices
C4 ($/m3)C3 (US/US gal.)C3 ($/m3)Date
245.0090.75 ( 40 US$/bbl)282.3602/07...
255.0088.95269.7412/06
380.48103.44307.2308/06
345.1693.63279.1005/06
334.03107.60332.7712/05
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Iranian NGL units
NGL 100, 200, 300 (Aghajari)
NGL 400, 500, 600 (Ahwaz)
NGL 700, 800, 900 (Ahwaz)
NGL 1000, 1100, 1200 (Ahwaz)
NGL 1300, 1400 (Ahwaz)
NGL 1500 (Karanj)