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File No: NA/803

26 October, 2000

NATIONAL INDUSTRIAL CHEMICALS NOTIFICATION

AND ASSESSMENT SCHEME

FULL PUBLIC REPORT

Oximosilyl perfluoroalkylsulphonamide

This Assessment has been compiled in accordance with the provisions of the Industrial Chemicals (Notification and Assessment) Act 1989 (the Act) and Regulations. This legislation is an Act of the Commonwealth of Australia. The National Industrial Chemicals Notification and Assessment Scheme (NICNAS) is administered by the National Occupational Health and Safety Commission which also conducts the occupational health & safety assessment. The assessment of environmental hazard is conducted by the Department of the Environment and the assessment of public health is conducted by the Department of Health and Aged Care.

For the purposes of subsection 78(1) of the Act, copies of this full public report may be inspected by the public at the Library, National Occupational Health and Safety Commission, 92-94 Parramatta Road, Camperdown NSW 2050, between the following hours:

Monday - Wednesday8.30 am - 5.00 pm

Thursday8.30 am - 8.00 pm

Friday8.30 am - 5.00 pm

Copies of this full public report may also be requested, free of charge, by contacting the Administration Coordinator on the fax number below.

For enquiries please contact the Administration Coordinator at:

Street Address: 92 -94 Parramatta Rd CAMPERDOWN NSW 2050, AUSTRALIA

Postal Address: GPO Box 58, SYDNEY NSW 2001, AUSTRALIA

Telephone: (61) (02) 9577 9514 FAX (61) (02) 9577 9465

Director

Chemicals Notification and Assessment

NA/803

FULL PUBLIC REPORT

Oximosilyl perfluoroalkylsulphonamide

1.APPLICANT

Dow Corning Australia Pty Ltd of 21 Tattersall Road, BLACKTOWN NSW 2148 has submitted a standard notification statement in support of their application for an assessment certificate for Oximosilyl perfluoroalkylsulphonamide.

2.IDENTITY OF THE CHEMICAL

The chemical name, molecular and structural formulae, molecular weight and spectral data have been exempted from publication in the Full Public Report and the Summary Report.

Other Name:

Oximosilyl perfluoroalkylsulphonamide

Marketing Name:

DOW CORNING 991 Silicone Hi-Performance Sealant, the product to be imported, contains the notified chemical, Dow Corning 3-0118 Intermediate at 0.3%.

Method of Detection and Determination:

Infra-Red (IR) spectroscopy; 13C Nuclear Magnetic Resonance (13C NMR) spectroscopy; (29Si NMR); Gas Chromatography (GC).

Spectral Data:

IR and NMR spectra were provided.

3.PHYSICAL AND CHEMICAL PROPERTIES

Appearance at 20C & 101.3 kPa:

Amber coloured liquid

Boiling Point:

No well quantified data provided, but the chemical is liquid at 25C.

Specific Gravity:

1000 kg/m3 at 25C.

Vapour Pressure:

No data provided - see notes below.

Water Solubility:

No data provided - see notes below.

Partition Co-efficient(n-octanol/water):

No data provided - see notes below.

Hydrolysis as a Function of pH:

Hydrolytic breakdown over wide pH range see notes below.

Adsorption/Desorption:

No data provided - see notes below.

Dissociation Constant:

No data provided - see notes below.

Flash Point:

68C (closed cup)

Particle Size:

Not relevant as the notified chemical is introduced in a fluid form.

Flammability Limits:

Not determined.

Autoignition Temperature:

Not determined.

Explosive Properties:

Not determined.

Reactivity/Stability:

Reacts with water and moisture

Comments on Physico-Chemical Properties

The chemical is moisture sensitive and the notifier submitted that realistic data on the environmentally significant physico-chemical properties such as water solubility, partition coefficient, adsorption/desorption and dissociation constant would be difficult or impossible to obtain. Although the ASTER (Assessment Tools for the Evaluation of Risk) database of the US EPA was consulted in an attempt to obtain estimates of physico-chemical data calculated on the basis of Quantitative Structure Activity Relationships, no data could be obtained probably due to the complexity of the molecule.

In the presence of water the notified chemical hydrolyses to a reactive amine and an alkylsilanol. Although no hydrolytic degradation data specific to the notified chemical was given in the dossier, the notifier provided a report (Chandra, 1993) which discussed the hydrolysis of reactive alkoxysilanes as a function of pH and other variables. These materials undergo bond cleavage to an amine or other simple compound and a reactive silanol species, but the half life for this process depends very strongly on the nature of the groups bonded to the silicon atom, and varies over 5 orders of magnitude (0.04 - 340 minutes at 25oC). The list of substituents provided in the report did not include reactive imido groups such as the C(CH3) = N O R group which is of relevance for the present compound, and so its hydrolysis half-life is uncertain. Nevertheless, hydrolysis of the imido linkages will produce a perfluorinated organosilane and 2-butylamine. The fluorinated derivative would be expected to have low water solubility, while 2-butylamine is appreciably water soluble.

No data were provided on the n-octanol/water partition coefficient, or on soil adsorption /desorption. However, the perfluorinated moiety would be expected to have very low affinity for water and some affinity for the oil phase. Also, while the fluorinated moiety may have some affinity for the organic component of soils and sediments there is no information on the strength of binding, and it may be mobile in these media.

4.PURITY OF THE CHEMICAL

Degree of Purity:

Approximately 72.9%

Hazardous Impurities:

Chemical name:

2-Butanone, oxime

Synonyms:

Ethyl methyl ketoxime; Ethyl methyl ketone oxime; MEKO

CAS No.:

96-29-7

Weight percentage:

6.2%

Toxic properties:

Xi- R36; R43; R40(3) see below

Other oxime impurities are present at a concentration of 17.4% and unidentified impurities at 3.5%.

Non-hazardous Impurities (> 1% by weight):

None

Additives/Adjuvants:

None

5.USE, VOLUME AND FORMULATION

The notified chemical will not be manufactured in Australia, but will be imported as a component, at a concentration of less than 1%, in ready-to-use silicone sealants in which the chemical will act as a cross-linker. The ready-to-use silicone sealant may be repackaged in Australia. A representative sealant: Dow Corning 991 Silicone Hi-Performance Sealant (see attached Material Safety Data Sheet (MSDS)) contains approximately 0.3% of the notified chemical, 4.7% oxime impurities and major components: dimethyl siloxane, hydroxy-terminated (30 60%) and calcium carbonate treated with stearic acid (30 60%). The projected import volume for the notified chemical is 5 tonnes per year for the first five years.

6.OCCUPATIONAL EXPOSURE

The notified chemical, as a component of a silicone sealant, will be imported in 20 L or 200L metal drums or tubes for repackaging or in 100 500 g polyethylene/polypropylene ready-to-use cartridges and 500 mL foil sausages.

Worker exposure during transport and storage will be limited to accidental spillage.

The notified chemical and silicone sealant are moisture sensitive so the sealant must be repackaged in an air-tight system. Approximately 20 50 workers are involved in transport and repackaging for a maximum of 8 hours/day, 5 days/week. The repackaging involves the use of a positive displacement pump equipped with a follower plate. The sealant is pumped under pressure to the cartridges via a flexible hose. The packaging system is airtight but also has a mechanical exhaust system placed over it to remove any escaping vapours. Under these conditions, exposure of workers is unlikely.

The method of application of the silicone sealant was described in the current notification and in a previous submission by the same notifier. The following description is taken from both sources. The notifier estimates that 200 500 workers in the building industry may be involved in application of the sealant containing the notified chemical and could be using the sealant 8 hours/day, 5 days/week. The method of use is first to prepare the surface then extrude beads of sealant either by hand from the cartridge or by using a compressor operated gun to force beads from the cartridge. Once extruded, the beads are spread by means of a spatula or a finger dipped in soapy water (to prevent sticking) although the latter is not recommended with the current product. Dermal exposure to the sealant can, therefore, be frequent. Some secondary exposure of the eyes and mouth may occur by transfer from fingers. Uncured sealant is typically removed using solvents such as white spirit or acetone. Cured material can only be removed with a blade. Most of the work will be conducted on outdoor building sites where vapours are unlikely to accumulate. The Material Safety Data Sheet (MSDS) for the sealant states that methyl ethyl ketoxime is formed on contact with water or humid air although the atmospheric levels are unknown. The notifier stated that goggles, rubber gloves and overalls would be worn during application.

Waste is commonly collected and disposed of to landfill. At this point the sealant should be cured and, although dermal exposure may occur, the notified che

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