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MATERIAL SAFETY DATA SHEET

MANGANESE VIOLET MSDS1. PRODUCT NAME AND COMPANY IDENTIFICATION1. PRODUCT NAME AND COMPANY IDENTIFICATION1. PRODUCT NAME AND COMPANY IDENTIFICATION1. PRODUCT NAME AND COMPANY IDENTIFICATIONProduct Name: MANGANESE VIOLETMANGANESE VIOLETMANGANESE VIOLETTrade Name: Manganese VioletManganese VioletManganese VioletChemical Family: Manganese Ammonium PyrophosphateManganese Ammonium PyrophosphateManganese Ammonium PyrophosphateCAS Number: 10101-66-310101-66-310101-66-3Formula: MnNH4P2O7MnNH4P2O7MnNH4P2O7Product Use: Personal Care FormulationsPersonal Care FormulationsPersonal Care FormulationsCompany Name: Natural SourcingNatural SourcingNatural SourcingCompany Address: 341 Christian Street, Oxford, CT 06478, USA341 Christian Street, Oxford, CT 06478, USA341 Christian Street, Oxford, CT 06478, USADate Issued: 10/09/201210/09/201210/09/2012Emergency Telephone Number: Chemtrec Tel: (800) 262-8200Chemtrec Tel: (800) 262-8200Chemtrec Tel: (800) 262-8200

2. COMPOSITION/INGREDIENT INFORMATION2. COMPOSITION/INGREDIENT INFORMATION2. COMPOSITION/INGREDIENT INFORMATION2. COMPOSITION/INGREDIENT INFORMATIONIngredient Name CAS Number CAS Number PercentageManganese Ammonium Pyrophosphate 10101-66-310101-66-3 100%

3. HAZARDS IDENTIFICATION3. HAZARDS IDENTIFICATION3. HAZARDS IDENTIFICATION3. HAZARDS IDENTIFICATION

Physical/Chemical Hazards: Contact with strong alkali liberates ammonia, a flammable and toxic gas.Contact with strong alkali liberates ammonia, a flammable and toxic gas.Contact with strong alkali liberates ammonia, a flammable and toxic gas.

Environmental Hazards: NoneNoneNoneHuman Health Hazards: Can create nuisance dust.Can create nuisance dust.Can create nuisance dust.

Eye Contact: May cause irritation to eyes.May cause irritation to eyes.May cause irritation to eyes.Skin Contact: May cause irritation to sensitive skin.May cause irritation to sensitive skin.May cause irritation to sensitive skin.Ingestion: NoneNoneNoneInhalation: Low health risk by inhalation. Treat as nuisance dust.Low health risk by inhalation. Treat as nuisance dust.Low health risk by inhalation. Treat as nuisance dust.

4. FIRST AID MEASURES4. FIRST AID MEASURES4. FIRST AID MEASURES4. FIRST AID MEASURES

Eyes: Remove contacts. Flush with plenty of water for 15 minutes. Get medical attention if irritation persists.Remove contacts. Flush with plenty of water for 15 minutes. Get medical attention if irritation persists.Remove contacts. Flush with plenty of water for 15 minutes. Get medical attention if irritation persists.

Skin: Wash with soap and water. Seek medical attention if symptoms persist. Wash with soap and water. Seek medical attention if symptoms persist. Wash with soap and water. Seek medical attention if symptoms persist.

Ingestion: Non-toxic; No necessary action.Non-toxic; No necessary action.Non-toxic; No necessary action.

Inhalation:Remove to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. If symptoms persist, seek medical attention.

Remove to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. If symptoms persist, seek medical attention.

Remove to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. If symptoms persist, seek medical attention.

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5. FIRE FIGHTING MEASURES5. FIRE FIGHTING MEASURES5. FIRE FIGHTING MEASURES5. FIRE FIGHTING MEASURESFlammability of Product: Non-flammableNon-flammableNon-flammableExtinguishing Media: Use extinguishing material applicable to surrounding fire.Use extinguishing material applicable to surrounding fire.Use extinguishing material applicable to surrounding fire.

Special Firefighting Procedures: Wear NIOSH approved, positive pressure, self-contained breathing apparatus and full protective clothing. Wear NIOSH approved, positive pressure, self-contained breathing apparatus and full protective clothing. Wear NIOSH approved, positive pressure, self-contained breathing apparatus and full protective clothing.

Unusual Fire & Explosion Hazards: NoneNoneNone

Hazard Thermal Decomposition Products:

Toxic irritating ammonia gas can be generated if this product undergoes chemical decomposition during a fire sustained by other combustible materials.

Toxic irritating ammonia gas can be generated if this product undergoes chemical decomposition during a fire sustained by other combustible materials.

Toxic irritating ammonia gas can be generated if this product undergoes chemical decomposition during a fire sustained by other combustible materials.

6. ACCIDENTAL RELEASE MEASURES (STEPS FOR SPILLS)6. ACCIDENTAL RELEASE MEASURES (STEPS FOR SPILLS)6. ACCIDENTAL RELEASE MEASURES (STEPS FOR SPILLS)6. ACCIDENTAL RELEASE MEASURES (STEPS FOR SPILLS)

Personal Precautions:Personal Precautions:No special precautions are necessary unless contact with strong alkalis may occur, in which case suitable breathing apparatus should be worn.

No special precautions are necessary unless contact with strong alkalis may occur, in which case suitable breathing apparatus should be worn.

Environmental Precautions:Environmental Precautions: Do not flush into surface water or sanitary sewer systems.Do not flush into surface water or sanitary sewer systems.

Methods for Cleaning Up:Methods for Cleaning Up:Scoop spilled material into appropriately labeled containers for proper disposal. Flush with copious amounts of water to dilute any alkali conditions which may prevail.

Scoop spilled material into appropriately labeled containers for proper disposal. Flush with copious amounts of water to dilute any alkali conditions which may prevail.

7. HANDLING AND STORAGE7. HANDLING AND STORAGE7. HANDLING AND STORAGE7. HANDLING AND STORAGE

HandlingHandling Good Industrial Hygiene Practice Requires That Employee Exposure be Maintained Below TLV.Good Industrial Hygiene Practice Requires That Employee Exposure be Maintained Below TLV.

Safe Handling:Safe Handling:

Avoid generating dust. Avoid breathing dust. Use only with adequate ventilation so exposure is maintained below TLV. Use personal respiratory protection when necessary. Avoid prolonged, contact with skin. Avoid contact with eyes. Keep container closed. Wash thoroughly after handling.

Avoid generating dust. Avoid breathing dust. Use only with adequate ventilation so exposure is maintained below TLV. Use personal respiratory protection when necessary. Avoid prolonged, contact with skin. Avoid contact with eyes. Keep container closed. Wash thoroughly after handling.

StorageStorageStore in a well ventilated, clean, dry area in sealed containers. Do not store where there is risk of fire. Do not mix or store with alkalis. Avoid excessive dust generation.

Store in a well ventilated, clean, dry area in sealed containers. Do not store where there is risk of fire. Do not mix or store with alkalis. Avoid excessive dust generation.

8. EXPOSURE CONTROL/PERSONAL PROTECTION8. EXPOSURE CONTROL/PERSONAL PROTECTION8. EXPOSURE CONTROL/PERSONAL PROTECTION8. EXPOSURE CONTROL/PERSONAL PROTECTION

National Occupational Exposure Limits:National Occupational Exposure Limits:

No specific OEL for product, only for nuisance dust.Threshold Limit Values: 10 mg/cu.m (Total Dust), 5 mg/cu.m. (Respirable Dust)

No specific OEL for product, only for nuisance dust.Threshold Limit Values: 10 mg/cu.m (Total Dust), 5 mg/cu.m. (Respirable Dust)

Eye:Eye: Safety glasses, goggles or face shieldsSafety glasses, goggles or face shieldsSkin/Body:Skin/Body: Leather or rubber gloves & lab coats Leather or rubber gloves & lab coats

Respiratory:Respiratory:

Use adequate ventilation or NIOSH-approved respiratory devices to prevent inhalation of dust. Use additional appropriate respiratory protection if there is potential to exceed the exposure limits.

Use adequate ventilation or NIOSH-approved respiratory devices to prevent inhalation of dust. Use additional appropriate respiratory protection if there is potential to exceed the exposure limits.

Other:Other: Evaluate need based on application. Evaluate need based on application.

Personal Protection in Case of Large Spills:Personal Protection in Case of Large Spills:

Splash goggles, synthetic apron, gloves, NIOSH approved self-contained breathing apparatus or equivalent and full protective gear.

Splash goggles, synthetic apron, gloves, NIOSH approved self-contained breathing apparatus or equivalent and full protective gear.

9. PHYSICAL AND CHEMICAL PROPERTIES9. PHYSICAL AND CHEMICAL PROPERTIES9. PHYSICAL AND CHEMICAL PROPERTIES9. PHYSICAL AND CHEMICAL PROPERTIESAppearance:Appearance: VioletVioletOdor:Odor: OdorlessOdorlesspH: pH: 2.5-4.72.5-4.7

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Specific Gravity:Specific Gravity: 2.7-2.92.7-2.9Solubility:Solubility: Insoluble in water and organic solventsInsoluble in water and organic solvents

10. STABILITY AND REACTIVITY10. STABILITY AND REACTIVITY10. STABILITY AND REACTIVITY10. STABILITY AND REACTIVITY

Stability:Stability: Stable in air less than 250℃. Above this temperature loss of organic material occurs.Stable in air less than 250℃. Above this temperature loss of organic material occurs.

Hazardous Decomposition or Byproducts:Hazardous Decomposition or Byproducts: Ammonia or its combustion products.Ammonia or its combustion products.

Conditions to Avoid:Conditions to Avoid: Contact with alkalis and fire.Contact with alkalis and fire.

11. TOXICOLOGICAL INFORMATION11. TOXICOLOGICAL INFORMATION11. TOXICOLOGICAL INFORMATION11. TOXICOLOGICAL INFORMATIONManganese violet pigments are classified as non toxic.Manganese violet pigments are classified as non toxic.Manganese violet pigments are classified as non toxic.Manganese violet pigments are classified as non toxic.

12. ECOLOGICAL INFORMATION12. ECOLOGICAL INFORMATION12. ECOLOGICAL INFORMATION12. ECOLOGICAL INFORMATION

Ecotoxicity:Ecotoxicity: Manganese violet pigments pose no threat to the environment if disposed of as indicated in Section 13.Manganese violet pigments pose no threat to the environment if disposed of as indicated in Section 13.

Persistence and Degradability:Persistence and Degradability: Manganese violet pigments are stable (except in alkali situations).Manganese violet pigments are stable (except in alkali situations).

13. DISPOSAL CONSIDERATIONS13. DISPOSAL CONSIDERATIONS13. DISPOSAL CONSIDERATIONS13. DISPOSAL CONSIDERATIONSDispose of according to all federal, state and local regulations. This material should not be disposed of where there is a risk of contact with strong alkalis.Dispose of according to all federal, state and local regulations. This material should not be disposed of where there is a risk of contact with strong alkalis.Dispose of according to all federal, state and local regulations. This material should not be disposed of where there is a risk of contact with strong alkalis.Dispose of according to all federal, state and local regulations. This material should not be disposed of where there is a risk of contact with strong alkalis.

14. TRANSPORT INFORMATION14. TRANSPORT INFORMATION14. TRANSPORT INFORMATION14. TRANSPORT INFORMATION

DOT Description:DOT Description:Manganese violet pigments are not classified as dangerous substances for supply or conveyance under international regulations.

Manganese violet pigments are not classified as dangerous substances for supply or conveyance under international regulations.

15. REGULATORY INFORMATION15. REGULATORY INFORMATION15. REGULATORY INFORMATION15. REGULATORY INFORMATIONManganese violet pigments are not classified as dangerous substances

SARA Section 313: This product is subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act and 40CFR372.

Manganese violet pigments are not classified as dangerous substances

SARA Section 313: This product is subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act and 40CFR372.

Manganese violet pigments are not classified as dangerous substances

SARA Section 313: This product is subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act and 40CFR372.

Manganese violet pigments are not classified as dangerous substances

SARA Section 313: This product is subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act and 40CFR372.National Inventory Numbers:TSCA (US): 10101-66-3 EINECS: 2-332-574AICS (Australia): 10101-66-3DSL (Canada): 10101-66-3

National Inventory Numbers:TSCA (US): 10101-66-3 EINECS: 2-332-574AICS (Australia): 10101-66-3DSL (Canada): 10101-66-3

National Inventory Numbers:TSCA (US): 10101-66-3 EINECS: 2-332-574AICS (Australia): 10101-66-3DSL (Canada): 10101-66-3

National Inventory Numbers:TSCA (US): 10101-66-3 EINECS: 2-332-574AICS (Australia): 10101-66-3DSL (Canada): 10101-66-3

16. ADDITIONAL INFORMATION16. ADDITIONAL INFORMATION16. ADDITIONAL INFORMATION16. ADDITIONAL INFORMATION

The complete range of conditions or methods of use are beyond our control therefore we do not assume any responsibility and expressly disclaim any liability for any use of this product. Information contained herein is believed to be true and accurate however, all statements or suggestions are made without warranty, expressed or implied, regarding accuracy of the information, the hazards connected with the use of the material or the results to be obtained from the use thereof. Compliance with all applicable federal, state, and local laws and local regulations remains the responsibility of the user.

This safety sheet cannot cover all possible situations which the user may experience during processing. Each aspect of your operation should be examined to determine if, or where, additional precautions may be necessary.  All health and safety information contained in this bulletin should be provided to your employees or customers.

The complete range of conditions or methods of use are beyond our control therefore we do not assume any responsibility and expressly disclaim any liability for any use of this product. Information contained herein is believed to be true and accurate however, all statements or suggestions are made without warranty, expressed or implied, regarding accuracy of the information, the hazards connected with the use of the material or the results to be obtained from the use thereof. Compliance with all applicable federal, state, and local laws and local regulations remains the responsibility of the user.

This safety sheet cannot cover all possible situations which the user may experience during processing. Each aspect of your operation should be examined to determine if, or where, additional precautions may be necessary.  All health and safety information contained in this bulletin should be provided to your employees or customers.

The complete range of conditions or methods of use are beyond our control therefore we do not assume any responsibility and expressly disclaim any liability for any use of this product. Information contained herein is believed to be true and accurate however, all statements or suggestions are made without warranty, expressed or implied, regarding accuracy of the information, the hazards connected with the use of the material or the results to be obtained from the use thereof. Compliance with all applicable federal, state, and local laws and local regulations remains the responsibility of the user.

This safety sheet cannot cover all possible situations which the user may experience during processing. Each aspect of your operation should be examined to determine if, or where, additional precautions may be necessary.  All health and safety information contained in this bulletin should be provided to your employees or customers.

The complete range of conditions or methods of use are beyond our control therefore we do not assume any responsibility and expressly disclaim any liability for any use of this product. Information contained herein is believed to be true and accurate however, all statements or suggestions are made without warranty, expressed or implied, regarding accuracy of the information, the hazards connected with the use of the material or the results to be obtained from the use thereof. Compliance with all applicable federal, state, and local laws and local regulations remains the responsibility of the user.

This safety sheet cannot cover all possible situations which the user may experience during processing. Each aspect of your operation should be examined to determine if, or where, additional precautions may be necessary.  All health and safety information contained in this bulletin should be provided to your employees or customers.

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