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Monomers Product Guide - Home | · PDF fileMonomers Product Guide Acid Containing Monomers Acrylic Monomers Adhesion Promoting Monomers Amine Containing Monomers Crosslinking Acrylic

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  • Monomers Product Guide

    Acid Containing MonomersAcrylic MonomersAdhesion Promoting MonomersAmine Containing MonomersCrosslinking Acrylic MonomersDual Reactive Acrylic MonomersEpoxides / Anhydrides / ImidesFluorescent Acrylic MonomersFluorinated Acrylic MonomersHigh / Low Refractive Index MonomersHydroxy Containing MonomersMono & Difunctional Glycol Oligomeric MonomersPolymerization Inhibitors for MonomersStyrenic MonomersUV Light Active MonomersVinyl & Ethenyl Monomers

  • 3For more information please call (800) 523-2575 / (215) 343-6484 or visit polysciences.com

    MonomersPolysciences stocks a wide portfolio of monomers. Such variety offers the synthetic chemist the tools to make a rich array of polymer compositions. Our Monomers Selection Guide organizes this set of reactive monomers into various groupings. These summary sets of data will quickly enable the scientist to determine which specific monomer can be used to synthesize custom polymers. In reviewing the data in these selection guides, you will be able to compare and contrast monomer alternatives quickly. More detailed information and chemical structures are included in the alphabetical listing which follows.

    Monomer Selection Guide At-A-Glance

    Acid Containing Monomers 4

    Acid Containing Monomers, Metal Salts 4

    Acrylic Monomers (Neutral, Monofunctional) 5

    Adhesion Promoting Monomers 7

    Amine Containing Monomers 7

    Crosslinking Acrylic Monomers - Difunctional 8

    Crosslinking Acrylic Monomers - Multifunctional 10

    Dual Reactive Acrylic Monomers 10

    Epoxides / Anhydrides / Imides 12

    Fluorescent Acrylic Monomers 12

    Fluorinated Acrylic Monomers 13

    High / Low Refractive Index Monomers 13

    Hydroxy Containing Monomers 14

    Mono and Difunctional Glycol Oligomeric Monomers 15

    Polymerization Inhibitors for Monomers 16

    Styrenic Monomers 16

    UV (light) Active Monomers 17

    Vinyl and Ethenyl Monomers 18

  • 4 For technical questions, [email protected] or (800) 523-2575 / (215) 343-6484

    Acrylic acid mono acrylic carboxylic acid makes water sluble polymers

    Acrylic anhydride mono acrylic carboxylic acid (protected) not a crosslinker

    Beta-Carboxyethyl Acrylate, >98% Active

    mono acrylic carboxylic acid high purity, hydrophilic

    t-Butyl methacrylate mono acrylic carboxylic acid (protected) acid formed by thermal elimination of isobutylene, homopolymer Tg = 230C

    Methacrylic acid mono acrylic carboxylic acid offers latex stability, homopolymer Tg =185C

    Methacrylic Acid, 99.9% mono acrylic carboxylic acid high purity, hydrophilic

    4-Methacryloxyethyl trimellitic anhydride

    mono acrylic anhydride adhesion promoter throughanhydride

    3-Methacryloyl-(l)-lysine mono acrylic amino acid zwitterionic, can derivatize acidor amine

    o-Nitrobenzyl methacrylate mono acrylic carboxylic acid (protected) acid formed by photolabile deprotection

    2-Propene-1-sulfonic acid, Na salt (35% in water)

    mono acrylic sulfonic acid salt water soluble

    2-Sulfoethyl methacrylate mono acrylic sulfonic acid water soluble

    Trichloroacrylic acid mono acrylic carboxylic acid carboxylic acid

    4-Vinylbenzoic acid(4-carboxystyrene)

    mono styrenic carboxylic acid aromatic acid

    00020-250 250g

    00488-50 50g

    24891-100 100g

    02058-100 100g

    00212-450 450g

    24897-250 250g

    17285-10 10g

    24315-5 5g

    24360-10 10g

    00064-10 10g

    02597-50 50g

    02686-10 10g

    04485-5 5g

    Acid Containing MonomersAcidic groups are often used to convey solubility to polymers in aqueous media. These moieties can be converted to a wide range of alternative functional groups. Acid groups can be utilized as catalysts for chemical reactions. Additionally they are employed in polymers as a functional group which enables improved adhesion to a variety of substrates through hydrogen bonding or metal chelation.

    Lead methacrylate2-ethylhexanoate in MMA(.54/.46 mol ratio)

    mono acrylic heavy metal salt x-ray opacity and capture

    Lithium methacrylate mono acrylic metal salt water soluble

    Sodium acrylate mono acrylic metal salt can make high Tg salt polymers

    3-Sulfopropyl acrylate,salt potassium

    mono acrylic sulfonic acid salt water soluble

    3-Sulfopropyl methacrylate,salt potassium

    mono acrylic sulfonic acid salt water soluble

    Barium methacrylate dual acrylic metal salt water soluble

    Magnesium acrylate dual acrylic metal salt ionomeric crosslinking, high Tg polymers

    Zinc dimethacrylate dual acrylic metal salt ionomeric crosslinking

    Acid Containing Monomers, Metal Salts

    16382-100 100g

    17117-50 50g

    01207-50 50g

    17209-100 100g

    17210-100 100g

    01994-50 50g

    02467-10 10g

    03011-100 100g

    Product Name PolymerizableSites

    Polymerization Synthon

    Form of Acid Special Features Catalog # Size

    Product Name PolymerizableSites

    Polymerization Synthon

    Form of Acid Special Features Catalog # Size

  • 5For more information please call (800) 523-2575 / (215) 343-6484 or visit polysciences.com

    04673-10 10g

    00019-100 100g

    21192-50 50g

    06127-10 10g

    24286-10 10g

    01997-100 100g

    02000-100 100g

    17969-25 25g

    02034-100 100g

    02039-250 250g

    02037-500 500g

    02058-100 100g

    02056-500 500g

    02059-500 500g

    02057-10 10g

    01331-10 10g

    02109-100 100g

    01837-100 100g

    03008-100 100g

    22493-100 100g

    23344-25 25g

    00871-25 25g

    02255-100 100g

    02270-25 25g

    19663-25 25g

    02460-50 50g

    02461-250 250g

    04135-10 10g

    Catalog # Size

    N-(n-Octadecyl)acrylamide hydrophobic

    Acrylamide (UltraPure) 165 hydrophilic, hydrogel synthesis

    N-Acryloylmorpholine hydrophilic

    t-Amyl methacrylate hydrophobic

    Benzhydryl methacrylate high refractive index, aromatic

    Benzyl acrylate 6 high refractive index, aromatic

    Benzyl methacrylate 54 high refractive index, aromatic

    N-Benzylmethacrylamide high refractive index, aromatic

    2-n-Butoxyethyl methacrylate moderate polarity

    t-Butyl acrylate 43 hydrocarbon building block monomer

    n-Butyl acrylate -54 hydrocarbon building block monomer

    t-Butyl methacrylate hydrophobic / protected acid

    iso-Butyl methacrylate 53 hydrocarbon building block monomer

    n-Butyl methacrylate 20 hydrocarbon building block monomer

    sec-Butyl methacrylate 60 hydrocarbon building block monomer

    4-Chlorophenyl acrylate 58 high refractive index, aromatic

    Cyclohexyl acrylate 19 aliphatic, hydrophobic

    Cyclohexyl methacrylate 83 aliphatic, hydrophobic

    iso-Decyl acrylate -55 hydrophobic, low Tg

    iso-Decyl methacrylate hydropobic

    n-Decyl methacrylate -30 hydropobic

    N,N-Diethylacrylamide polar building block

    N,N-Dimethylacrylamide 89 useful for chromatographic resins

    N,N-Dimethylmethacrylamide hydrolytic stability, useful for hydrogels

    N,N-Diphenyl methacrylamide bulky aromatic, hydrolytic stability

    n-Dodecyl acrylate -3 hydrophobic, long chain alkyl

    n-Dodecyl methacrylate -55 hydrophobic. Low Tg , long chain alkyl

    N(n-Dodecyl)methacrylamid 15 hydrophobic, hydrolytic stability

    Acrylic Monomers (Neutral, Monofunctional)Monofunctional acrylics shape the type and nature of the main chain polymer backbone. Monomers are chosen to obtain the desired glass transition temperature, flexibility, mechanical strength, polarity, and hydrophilic/hydrophobic character of the resulting polymer. Generally, acrylamides exhibit improved resistance to hydrolysis compared to acrylic/methacrylic esters.

    Product Name Homopolymer Tg (C) Special Features

  • 6 For technical questions, [email protected] or (800) 523-2575 / (215) 343-6484

    Acrylic Monomers (Neutral, Monofunctional) continued

    2-(2-Ethoxyethoxy)ethyl acrylate -70 hydrophilic , low Tg

    2-Ethylhexyl acrylate -50 hydrophobic

    N-Ethylmethacrylamide hydrolytic stability, useful for hydrogels

    1-Hexadecyl methacrylate 22 hydrophobic, aliphatic

    n-Hexyl acrylate -45 hydrophobic, aliphatic

    2-Methoxyethyl acrylate -50 low Tg monomer

    2-Methoxyethyl methacrylate 16 moderate polarity

    Methyl methacrylate 105 versatile building block monomer

    2-Naphthyl acrylate 24 fluorescent, hydrophobic, aromatic

    n-Octyl methacrylate -20 hydrophobic

    N-(tert-Octyl)acrylamide hydrophobic, hydrolytic stability

    Pentabromophenyl acrylate brominated, high refractive index

    Pentabromophenyl methacrylate brominated, high refractive index

    Pentafluorophenyl acrylate perfluorophenyl, low surface energy

    Pentafluorophenyl methacrylate perfluorophenyl, low surface energy

    2-Phenoxyethyl methacrylate 54 aromatic, hydrophobic

    Phenyl acrylate 57 aromatic, UV absorbing

    Phenyl methacrylate 110 moderate UV absorbing, aromatic, hydrophobic

    2-Phenylethyl acrylate -3 moderate UV absorbing, aromatic, hydrophobic

    2-Phenylethyl methacrylate 26 moderate UV absorbing, aromatic, hydrophobic

    n-Propyl acrylate -37 building block monomer

    n-Propyl methacrylate 35 building block monomer

    N-iso-propylacrylamide hydrophilic

    Stearyl acrylate (mixture of C16/C18) hydrophobic, can form crystal domains

    Tribromoneopentyl methacrylate bromo aromatic

    2,4,6-Tribromophenyl acrylate bromo aromatic

    Triethylene glycol monomethyl ether mono-methacrylate

    hydrophilic

    3,3,5-Trimethylcyclohexyl methacrylate aliphatic, bulky

    Undecyl methacrylate hydrophobic

    02626-100 100g

    00587-250 250g

    02322-10 10g

    02396-25 25g

    0241

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