Method Blank (MB) and Laboratory Control Spike (LCS) Report

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Method Blank (MB) and Laboratory Control Spike (LCS) Report

The quality control term Method / Laboratory Blank refers to an analyte free matrix to which all reagents are added in the same volumes or proportions as used in standard sample preparation. The purpose of this QC

parameter is to monitor potential laboratory contamination. The quality control term Laboratory Control Spike (LCS) refers to a certified reference material, or a known interference free matrix spiked with target

analytes. The purpose of this QC parameter is to monitor method precision and accuracy independent of sample matrix. Dynamic Recovery Limits are based on statistical evaluation of processed LCS.

Sub-Matrix: WATER Method Blank (MB)

Report

Laboratory Control Spike (LCS) Report

Spike Spike Recovery (%) Recovery Limits (%)

Result Concentration HighLowLCSMethod: Compound CAS Number LOR Unit

EA005P: pH by PC Titrator (QCLot: 1476071)

EA005-P: pH Value ---- ---- pH Unit ---- 1014 pH Unit 10298

---- 1007 pH Unit 10298

EA010P: Conductivity by PC Titrator (QCLot: 1476070)

EA010-P: Electrical Conductivity @ 25°C ---- 1 µS/cm <1 104147 µS/cm 10791

<1 10112890 µS/cm 10791

EA015: Total Dissolved Solids dried at 180 ± 5 °C (QCLot: 1475502)

EA015H: Total Dissolved Solids @180°C ---- 10 mg/L <10 102293 mg/L 11288

<10 1012000 mg/L 11288

EA025: Total Suspended Solids dried at 104 ± 2°C (QCLot: 1475501)

EA025H: Suspended Solids (SS) ---- 5 mg/L <5 97.3150 mg/L 12083

<5 98.41000 mg/L 12083

EA045: Turbidity (QCLot: 1475538)

EA045: Turbidity ---- 0.1 NTU <0.1 95.24 NTU 11387

<0.1 10040 NTU 10595

<0.1 100400 NTU 10397

ED037P: Alkalinity by PC Titrator (QCLot: 1476069)

ED037-P: Total Alkalinity as CaCO3 ---- ---- mg/L ---- 103200 mg/L 11287

ED041G: Sulfate (Turbidimetric) as SO4 2- by DA (QCLot: 1476059)

ED041G: Sulfate as SO4 - Turbidimetric 14808-79-8 1 mg/L <1 96.8100 mg/L 12080

<1 10225 mg/L 12080

ED045G: Chloride by Discrete Analyser (QCLot: 1476060)

ED045G: Chloride 16887-00-6 1 mg/L <1 97.31000 mg/L 12080

<1 10710 mg/L 12080

ED093F: Dissolved Major Cations (QCLot: 1477160)

ED093F: Calcium 7440-70-2 1 mg/L <1 -------- --------

ED093F: Magnesium 7439-95-4 1 mg/L <1 -------- --------

ED093F: Sodium 7440-23-5 1 mg/L <1 -------- --------

ED093F: Potassium 7440-09-7 1 mg/L <1 -------- --------

EG020F: Dissolved Metals by ICP-MS (QCLot: 1477161)

EG020A-F: Aluminium 7429-90-5 0.01 mg/L <0.01 1000.5 mg/L 11879

EG020A-F: Manganese 7439-96-5 0.001 mg/L <0.001 1020.1 mg/L 12089

EG020A-F: Iron 7439-89-6 0.05 mg/L <0.05 97.40.5 mg/L 11482


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EG020F: Dissolved Metals by ICP-MS (QCLot: 1477163) - continued

EG020A-F: Aluminium 7429-90-5 0.01 mg/L <0.01 1010.5 mg/L 11879


EG020A-F: Iron 7439-89-6 0.05 mg/L <0.05 96.70.5 mg/L 11482

EG051G: Ferrous Iron by Discrete Analyser (QCLot: 1480664)

EG051G: Ferrous Iron ---- 0.05 mg/L <0.05 1072 mg/L 12085

EK040P: Fluoride by PC Titrator (QCLot: 1476068)

EK040P: Fluoride 16984-48-8 0.1 mg/L <0.1 94.85 mg/L 12080

EK055G: Ammonia as N by Discrete Analyser (QCLot: 1492350)

EK055G: Ammonia as N 7664-41-7 0.01 mg/L <0.01 92.21 mg/L 12080

EK057G: Nitrite as N by Discrete Analyser (QCLot: 1476058)

EK057G: Nitrite as N 14797-65-0 0.01 mg/L <0.01 93.20.5 mg/L 12080

EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser (QCLot: 1492351)

EK059G: Nitrite + Nitrate as N ---- 0.01 mg/L <0.01 1050.5 mg/L 11589

EK061G: Total Kjeldahl Nitrogen By Discrete Analyser (QCLot: 1491152)

EK061G: Total Kjeldahl Nitrogen as N ---- 0.1 mg/L <0.1 89.710 mg/L 11170

EK067G: Total Phosphorus as P by Discrete Analyser (QCLot: 1491151)

EK067G: Total Phosphorus as P ---- 0.01 mg/L <0.01 92.04.42 mg/L 10977

EK071G: Reactive Phosphorus as P by discrete analyser (QCLot: 1476057)

EK071G: Reactive Phosphorus as P 14265-44-2 0.01 mg/L <0.01 1010.5 mg/L 12080

EP005: Total Organic Carbon (TOC) (QCLot: 1475212)

EP005: Total Organic Carbon ---- 1 mg/L <1 99.810 mg/L 11379

<1 102100 mg/L 11379

EP026SP: Chemical Oxygen Demand (Spectrophotometric) (QCLot: 1494077)

EP026SP: Chemical Oxygen Demand ---- 10 mg/L <10 98.050 mg/L 11286

<10 94.4500 mg/L 11286

EP030: Biochemical Oxygen Demand (BOD) (QCLot: 1479266)

EP030: Biochemical Oxygen Demand ---- 2 mg/L <2 89.0198 mg/L 11577



EP231A: Perfluoroalkyl Sulfonic Acids (QCLot: 1478848)

EP231X-ST: Perfluorobutane sulfonic acid (PFBS) 375-73-5 0.0005 µg/L <0.0005 63.40.01 µg/L 13050

EP231X-ST: Perfluoropentane sulfonic acid (PFPeS) 2706-91-4 0.0005 µg/L <0.0005 76.80.01 µg/L 13050

EP231X-ST: Perfluorohexane sulfonic acid (PFHxS) 355-46-4 0.0005 µg/L <0.0005 63.20.01 µg/L 13050

EP231X-ST: Perfluoroheptane sulfonic acid (PFHpS) 375-92-8 0.0005 µg/L <0.0005 92.00.01 µg/L 13050

EP231X-ST: Perfluorooctane sulfonic acid (PFOS) 1763-23-1 0.0003 µg/L <0.0003 85.80.01 µg/L 13050

EP231X-ST: Perfluorodecane sulfonic acid (PFDS) 335-77-3 0.0005 µg/L <0.0005 92.00.01 µg/L 13050


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EP231A: Perfluoroalkyl Sulfonic Acids (QCLot: 1481815) - continued







EP231B: Perfluoroalkyl Carboxylic Acids (QCLot: 1478848)

EP231X-ST: Perfluorobutanoic acid (PFBA) 375-22-4 0.002 µg/L <0.002 92.60.05 µg/L 13030

EP231X-ST: Perfluoropentanoic acid (PFPeA) 2706-90-3 0.0005 µg/L <0.0005 96.80.01 µg/L 13050

EP231X-ST: Perfluorohexanoic acid (PFHxA) 307-24-4 0.0005 µg/L <0.0005 88.00.01 µg/L 13050

EP231X-ST: Perfluoroheptanoic acid (PFHpA) 375-85-9 0.0005 µg/L <0.0005 1010.01 µg/L 13050

EP231X-ST: Perfluorooctanoic acid (PFOA) 335-67-1 0.0005 µg/L <0.0005 96.00.01 µg/L 13050

EP231X-ST: Perfluorononanoic acid (PFNA) 375-95-1 0.0005 µg/L <0.0005 77.80.01 µg/L 13050

EP231X-ST: Perfluorodecanoic acid (PFDA) 335-76-2 0.0005 µg/L <0.0005 83.00.01 µg/L 13050

EP231X-ST: Perfluoroundecanoic acid (PFUnDA) 2058-94-8 0.0005 µg/L <0.0005 91.40.01 µg/L 13040

EP231X-ST: Perfluorododecanoic acid (PFDoDA) 307-55-1 0.0005 µg/L <0.0005 1180.01 µg/L 13040

EP231X-ST: Perfluorotridecanoic acid (PFTrDA) 72629-94-8 0.0005 µg/L <0.0005 1060.01 µg/L 13040

EP231X-ST: Perfluorotetradecanoic acid (PFTeDA) 376-06-7 0.0005 µg/L <0.0005 1090.025 µg/L 13040



EP231X-ST: Perfluoropentanoic acid (PFPeA) 2706-90-3 0.0005 µg/L <0.0005 1030.01 µg/L 13050


EP231X-ST: Perfluoroheptanoic acid (PFHpA) 375-85-9 0.0005 µg/L <0.0005 78.40.01 µg/L 13050

EP231X-ST: Perfluorooctanoic acid (PFOA) 335-67-1 0.0005 µg/L <0.0005 1010.01 µg/L 13050




EP231X-ST: Perfluorododecanoic acid (PFDoDA) 307-55-1 0.0005 µg/L <0.0005 49.80.01 µg/L 13040

EP231X-ST: Perfluorotridecanoic acid (PFTrDA) 72629-94-8 0.0005 µg/L <0.0005 79.40.01 µg/L 13040

EP231X-ST: Perfluorotetradecanoic acid (PFTeDA) 376-06-7 0.0005 µg/L <0.0005 88.00.025 µg/L 13040

EP231C: Perfluoroalkyl Sulfonamides (QCLot: 1478848)

EP231X-ST: Perfluorooctane sulfonamide (FOSA) 754-91-6 0.0005 µg/L <0.0005 99.00.01 µg/L 13040

EP231X-ST: N-Methyl perfluorooctane sulfonamide

(MeFOSA)

31506-32-8 0.001 µg/L <0.001 95.80.025 µg/L 13040

EP231X-ST: N-Ethyl perfluorooctane sulfonamide (EtFOSA) 4151-50-2 0.001 µg/L <0.001 76.30.025 µg/L 13040

EP231X-ST: N-Methyl perfluorooctane sulfonamidoethanol

(MeFOSE)

24448-09-7 0.001 µg/L <0.001 81.40.025 µg/L 13040

EP231X-ST: N-Ethyl perfluorooctane sulfonamidoethanol

(EtFOSE)

1691-99-2 0.001 µg/L <0.001 89.60.025 µg/L 13040

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EP231C: Perfluoroalkyl Sulfonamides (QCLot: 1478848) - continued

EP231X-ST: N-Methyl perfluorooctane sulfonamidoacetic

acid (MeFOSAA)

2355-31-9 0.0005 µg/L <0.0005 87.40.01 µg/L 13040

EP231X-ST: N-Ethyl perfluorooctane sulfonamidoacetic

acid (EtFOSAA)

2991-50-6 0.0005 µg/L <0.0005 1080.01 µg/L 13040




(MeFOSA)

31506-32-8 0.001 µg/L <0.001 1030.025 µg/L 13040



(MeFOSE)

24448-09-7 0.001 µg/L <0.001 1220.025 µg/L 13040


(EtFOSE)

1691-99-2 0.001 µg/L <0.001 76.10.025 µg/L 13040


acid (MeFOSAA)

2355-31-9 0.0005 µg/L <0.0005 43.40.01 µg/L 13040


acid (EtFOSAA)

2991-50-6 0.0005 µg/L <0.0005 66.60.01 µg/L 13040

EP231D: (n:2) Fluorotelomer Sulfonic Acids (QCLot: 1478848)

EP231X-ST: 4:2 Fluorotelomer sulfonic acid (4:2 FTS) 757124-72-4 0.001 µg/L <0.001 1150.01 µg/L 13050


EP231X-ST: 8:2 Fluorotelomer sulfonic acid (8:2 FTS) 39108-34-4 0.001 µg/L <0.001 82.20.01 µg/L 13050







EP231P: PFAS Sums (QCLot: 1478848)

EP231X-ST: Sum of PFAS ---- 0.0003 µg/L <0.0003 -------- --------



Matrix Spike (MS) ReportThe quality control term Matrix Spike (MS) refers to an intralaboratory split sample spiked with a representative set of target analytes. The purpose of this QC parameter is to monitor potential matrix effects on

analyte recoveries. Static Recovery Limits as per laboratory Data Quality Objectives (DQOs). Ideal recovery ranges stated may be waived in the event of sample matrix interference.

Sub-Matrix: WATER Matrix Spike (MS) Report

SpikeRecovery(%) Recovery Limits (%)Spike

HighLowMSConcentrationLaboratory sample ID Client sample ID Method: Compound CAS Number

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0874_SW123_180305 ET1800563-002 14808-79-8ED041G: Sulfate as SO4 - Turbidimetric 90.820 mg/L 13070


0874_SW123_180305 ET1800563-002 16887-00-6ED045G: Chloride 79.8400 mg/L 13070


Anonymous ET1800553-002 7429-90-5EG020A-F: Aluminium 96.50.5 mg/L 13070

7439-96-5EG020A-F: Manganese 98.70.1 mg/L 13070


0874_SW131_180305 ET1800563-003 7429-90-5EG020A-F: Aluminium 96.30.5 mg/L 13070



0874_SW132_180305 ET1800563-001 ----EG051G: Ferrous Iron 1082 mg/L 13070


0874_SW123_180305 ET1800563-002 16984-48-8EK040P: Fluoride 1011.92 mg/L 12080


0874_SW123_180305 ET1800563-002 7664-41-7EK055G: Ammonia as N 91.60.4 mg/L 13070


Anonymous ET1800561-002 14797-65-0EK057G: Nitrite as N 90.20.4 mg/L 13070


0874_SW123_180305 ET1800563-002 ----EK059G: Nitrite + Nitrate as N 98.00.4 mg/L 13070


Anonymous EB1804009-002 ----EK061G: Total Kjeldahl Nitrogen as N # Not

Determined

5 mg/L 13070


Anonymous EB1804009-002 ----EK067G: Total Phosphorus as P # Not

Determined

1 mg/L 13070


Anonymous ET1800561-002 14265-44-2EK071G: Reactive Phosphorus as P 98.00.4 mg/L 13070


Anonymous ET1800561-002 ----EP005: Total Organic Carbon 101100 mg/L 13070


Anonymous EB1806321-001 ----EP026SP: Chemical Oxygen Demand 94.547.6 mg/L 13070


0874_SW123_180305 ET1800563-002 375-73-5EP231X-ST: Perfluorobutane sulfonic acid (PFBS) # Not

Determined

0.01 µg/L 13050

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0874_SW123_180305 ET1800563-002 2706-91-4EP231X-ST: Perfluoropentane sulfonic acid (PFPeS) # Not

Determined

0.01 µg/L 13050

355-46-4EP231X-ST: Perfluorohexane sulfonic acid (PFHxS) # Not

Determined

0.01 µg/L 13050

375-92-8EP231X-ST: Perfluoroheptane sulfonic acid (PFHpS) # Not

Determined

0.01 µg/L 13050

1763-23-1EP231X-ST: Perfluorooctane sulfonic acid (PFOS) # Not

Determined

0.01 µg/L 13050

335-77-3EP231X-ST: Perfluorodecane sulfonic acid (PFDS) 92.40.01 µg/L 13030


0874_QC5TB_180305 ET1800563-008 375-73-5EP231X-ST: Perfluorobutane sulfonic acid (PFBS) 98.20.01 µg/L 13050

2706-91-4EP231X-ST: Perfluoropentane sulfonic acid (PFPeS) 1010.01 µg/L 13050

355-46-4EP231X-ST: Perfluorohexane sulfonic acid (PFHxS) 90.40.01 µg/L 13050

375-92-8EP231X-ST: Perfluoroheptane sulfonic acid (PFHpS) 90.40.01 µg/L 13050

1763-23-1EP231X-ST: Perfluorooctane sulfonic acid (PFOS) 68.40.01 µg/L 13050



0874_SW123_180305 ET1800563-002 375-22-4EP231X-ST: Perfluorobutanoic acid (PFBA) # Not

Determined

0.05 µg/L 13030

2706-90-3EP231X-ST: Perfluoropentanoic acid (PFPeA) # Not

Determined

0.01 µg/L 13050

307-24-4EP231X-ST: Perfluorohexanoic acid (PFHxA) # Not

Determined

0.01 µg/L 13050

375-85-9EP231X-ST: Perfluoroheptanoic acid (PFHpA) # Not

Determined

0.01 µg/L 13050

335-67-1EP231X-ST: Perfluorooctanoic acid (PFOA) # Not

Determined

0.01 µg/L 13050

375-95-1EP231X-ST: Perfluorononanoic acid (PFNA) # Not

Determined

0.01 µg/L 13050

335-76-2EP231X-ST: Perfluorodecanoic acid (PFDA) 82.80.01 µg/L 13050

2058-94-8EP231X-ST: Perfluoroundecanoic acid (PFUnDA) 44.20.01 µg/L 13030

307-55-1EP231X-ST: Perfluorododecanoic acid (PFDoDA) 39.40.01 µg/L 13030

72629-94-8EP231X-ST: Perfluorotridecanoic acid (PFTrDA) 35.40.01 µg/L 13030

376-06-7EP231X-ST: Perfluorotetradecanoic acid (PFTeDA) 51.40.025 µg/L 13030


0874_QC5TB_180305 ET1800563-008 375-22-4EP231X-ST: Perfluorobutanoic acid (PFBA) 63.50.05 µg/L 13030

2706-90-3EP231X-ST: Perfluoropentanoic acid (PFPeA) 1010.01 µg/L 13050

307-24-4EP231X-ST: Perfluorohexanoic acid (PFHxA) 1010.01 µg/L 13050

375-85-9EP231X-ST: Perfluoroheptanoic acid (PFHpA) 1090.01 µg/L 13050

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EP231B: Perfluoroalkyl Carboxylic Acids (QCLot: 1481815) - continued

0874_QC5TB_180305 ET1800563-008 335-67-1EP231X-ST: Perfluorooctanoic acid (PFOA) 95.20.01 µg/L 13050

375-95-1EP231X-ST: Perfluorononanoic acid (PFNA) 71.80.01 µg/L 13050







0874_SW123_180305 ET1800563-002 754-91-6EP231X-ST: Perfluorooctane sulfonamide (FOSA) # Not

Determined

0.01 µg/L 13030

31506-32-8EP231X-ST: N-Methyl perfluorooctane sulfonamide

(MeFOSA)

30.70.025 µg/L 13030

4151-50-2EP231X-ST: N-Ethyl perfluorooctane sulfonamide

(EtFOSA)

33.60.025 µg/L 13030

24448-09-7EP231X-ST: N-Methyl perfluorooctane

sulfonamidoethanol (MeFOSE)

# 25.00.025 µg/L 13030

1691-99-2EP231X-ST: N-Ethyl perfluorooctane

sulfonamidoethanol (EtFOSE)

34.60.025 µg/L 13030


sulfonamidoacetic acid (MeFOSAA)

45.00.01 µg/L 13030

2991-50-6EP231X-ST: N-Ethyl perfluorooctane sulfonamidoacetic

acid (EtFOSAA)

52.00.01 µg/L 13030


0874_QC5TB_180305 ET1800563-008 754-91-6EP231X-ST: Perfluorooctane sulfonamide (FOSA) 83.60.01 µg/L 13030


(MeFOSA)

67.80.025 µg/L 13030


(EtFOSA)

66.30.025 µg/L 13030



86.60.025 µg/L 13030



78.20.025 µg/L 13030



57.80.01 µg/L 13030


acid (EtFOSAA)

84.20.01 µg/L 13030


0874_SW123_180305 ET1800563-002 757124-72-4EP231X-ST: 4:2 Fluorotelomer sulfonic acid (4:2 FTS) 57.80.01 µg/L 13050

27619-97-2EP231X-ST: 6:2 Fluorotelomer sulfonic acid (6:2 FTS) 77.40.01 µg/L 13050

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EP231D: (n:2) Fluorotelomer Sulfonic Acids (QCLot: 1478848) - continued

0874_SW123_180305 ET1800563-002 39108-34-4EP231X-ST: 8:2 Fluorotelomer sulfonic acid (8:2 FTS) # 18.40.01 µg/L 13050



0874_QC5TB_180305 ET1800563-008 757124-72-4EP231X-ST: 4:2 Fluorotelomer sulfonic acid (4:2 FTS) 95.40.01 µg/L 13050

27619-97-2EP231X-ST: 6:2 Fluorotelomer sulfonic acid (6:2 FTS) 1000.01 µg/L 13050



True

Environmental

QA/QC Compliance Assessment to assist with Quality ReviewWork Order : ET1800563 Page : 1 of 13

:: LaboratoryClient Environmental Division TownsvilleWSP Australia Pty Ltd

:Contact KATIE MCPHERSON Telephone : +61 7 4796 0600

:Project QLD_0874_PFAS Date Samples Received : 05-Mar-2018

Site : ---- Issue Date : 15-Mar-2018

KATIE MCPHERSON:Sampler No. of samples received : 14

:Order number PS102571 - 102 No. of samples analysed : 14

This report is automatically generated by the ALS LIMS through interpretation of the ALS Quality Control Report and several Quality Assurance parameters measured by ALS. This automated

reporting highlights any non-conformances, facilitates faster and more accurate data validation and is designed to assist internal expert and external Auditor review. Many components of this

report contribute to the overall DQO assessment and reporting for guideline compliance.

Brief method summaries and references are also provided to assist in traceability.

Summary of Outliers

Outliers : Quality Control Samples

This report highlights outliers flagged in the Quality Control (QC) Report.

l NO Method Blank value outliers occur.

l NO Duplicate outliers occur.

l NO Laboratory Control outliers occur.

l Matrix Spike outliers exist - please see following pages for full details.

l For all regular sample matrices, NO surrogate recovery outliers occur.

Outliers : Analysis Holding Time Compliance

l Analysis Holding Time Outliers exist - please see following pages for full details.

Outliers : Frequency of Quality Control Samples

l NO Quality Control Sample Frequency Outliers exist.

R I G H T S O L U T I O N S | R I G H T P A R T N E R

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Duplicates, Method Blanks, Laboratory Control Samples and Matrix Spikes

Matrix: WATER

Compound Group Name CommentLimitsDataAnalyteClient Sample IDLaboratory Sample ID CAS Number

Matrix Spike (MS) Recoveries

EB1804009--002 ----Total Kjeldahl Nitrogen

as N

Anonymous MS recovery not determined,

background level greater than or

equal to 4x spike level.

----Not

Determined

EK061G: Total Kjeldahl Nitrogen By Discrete Analyser

EB1804009--002 ----Total Phosphorus as PAnonymous MS recovery not determined,



----Not

Determined

EK067G: Total Phosphorus as P by Discrete Analyser

ET1800563--002 375-73-5Perfluorobutane

sulfonic acid (PFBS)

0874_SW123_180305 MS recovery not determined,



----Not

Determined

EP231A: Perfluoroalkyl Sulfonic Acids

ET1800563--002 2706-91-4Perfluoropentane

sulfonic acid

(PFPeS)




----Not

Determined


ET1800563--002 355-46-4Perfluorohexane

sulfonic acid

(PFHxS)




----Not

Determined


ET1800563--002 375-92-8Perfluoroheptane

sulfonic acid

(PFHpS)




----Not

Determined


ET1800563--002 1763-23-1Perfluorooctane

sulfonic acid (PFOS)




----Not

Determined


ET1800563--002 375-22-4Perfluorobutanoic acid

(PFBA)




----Not

Determined

EP231B: Perfluoroalkyl Carboxylic Acids

ET1800563--002 2706-90-3Perfluoropentanoic

acid (PFPeA)




----Not

Determined


ET1800563--002 307-24-4Perfluorohexanoic acid

(PFHxA)




----Not

Determined


ET1800563--002 375-85-9Perfluoroheptanoic

acid (PFHpA)




----Not

Determined


ET1800563--002 335-67-1Perfluorooctanoic acid

(PFOA)




----Not

Determined


ET1800563--002 24448-09-7N-Methyl

perfluorooctane

sulfonamidoethanol

(MeFOSE)

0874_SW123_180305 Recovery less than lower data quality

objective

30-130%25.0 %EP231C: Perfluoroalkyl Sulfonamides

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Matrix: WATER


Matrix Spike (MS) Recoveries - Continued

ET1800563--002 39108-34-48:2 Fluorotelomer

sulfonic acid (8:2

FTS)


objective

50-130%18.4 %EP231D: (n:2) Fluorotelomer Sulfonic Acids


Matrix: WATER

AnalysisExtraction / Preparation

Date analysedDate extractedContainer / Client Sample ID(s) Days

overdue

Days

overdue

Due for extraction Due for analysis

Method

EA005P: pH by PC Titrator

Clear Plastic Bottle - Natural

05-Mar-2018----0874_SW132_180305, 0874_SW123_180305,

0874_SW131_180305, 0874_SW102_180305,

0874_QC1SW_180305

06-Mar-2018---- ---- 1

EG051G: Ferrous Iron by Discrete Analyser

Clear Plastic Bottle - HCl

06-Mar-2018----0874_SW132_180305, 0874_SW123_180305,

0874_SW131_180305, 0874_SW102_180305,

0874_QC1SW_180305

08-Mar-2018---- ---- 2

Analysis Holding Time Compliance

Holding times for VOC in soils vary according to analytes of interest. Vinyl Chloride and Styrene holding time is 7 days; others 14 days. A recorded breach does not guarantee a breach for all VOC analytes and

should be verified in case the reported breach is a false positive or Vinyl Chloride and Styrene are not key analytes of interest/concern.

Holding time for leachate methods (e.g. TCLP) vary according to the analytes reported. Assessment compares the leach date with the shortest analyte holding time for the equivalent soil method. These are: organics

14 days, mercury 28 days & other metals 180 days. A recorded breach does not guarantee a breach for all non-volatile parameters.

If samples are identified below as having been analysed or extracted outside of recommended holding times, this should be taken into consideration when interpreting results.

This report summarizes extraction / preparation and analysis times and compares each with ALS recommended holding times (referencing USEPA SW 846, APHA, AS and NEPM) based on the sample container

provided. Dates reported represent first date of extraction or analysis and preclude subsequent dilutions and reruns. A listing of breaches (if any) is provided herein.

Matrix: WATER Evaluation: û = Holding time breach ; ü = Within holding time.

AnalysisExtraction / PreparationSample DateMethod

EvaluationDue for analysisDate analysedEvaluationDue for extractionDate extractedContainer / Client Sample ID(s)


Clear Plastic Bottle - Natural (EA005-P)

0874_SW132_180305, 0874_SW123_180305,

0874_SW131_180305, 0874_SW102_180305,

0874_QC1SW_180305

05-Mar-2018---- 06-Mar-2018----05-Mar-2018 ---- û

EA006: Sodium Adsorption Ratio (SAR)

Clear Plastic Bottle - Filtered; Lab-acidified (ED093F)

0874_SW132_180305, 0874_SW123_180305,

0874_SW131_180305, 0874_SW102_180305,

0874_QC1SW_180305

02-Apr-2018---- 07-Mar-2018----05-Mar-2018 ---- ü

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EA010P: Conductivity by PC Titrator


0874_SW132_180305, 0874_SW123_180305,

0874_SW131_180305, 0874_SW102_180305,

0874_QC1SW_180305

02-Apr-2018---- 06-Mar-2018----05-Mar-2018 ---- ü

EA015: Total Dissolved Solids dried at 180 ± 5 °C

Clear Plastic Bottle - Natural (EA015H)

0874_SW132_180305, 0874_SW123_180305,

0874_SW131_180305, 0874_SW102_180305,

0874_QC1SW_180305

12-Mar-2018---- 06-Mar-2018----05-Mar-2018 ---- ü

EA025: Total Suspended Solids dried at 104 ± 2°C


0874_SW132_180305, 0874_SW123_180305,

0874_SW131_180305, 0874_SW102_180305,

0874_QC1SW_180305

12-Mar-2018---- 06-Mar-2018----05-Mar-2018 ---- ü

EA045: Turbidity

Clear Plastic Bottle - Natural (EA045)

0874_SW132_180305, 0874_SW123_180305,

0874_SW131_180305, 0874_SW102_180305,

0874_QC1SW_180305

07-Mar-2018---- 06-Mar-2018----05-Mar-2018 ---- ü

EA065: Total Hardness as CaCO3


0874_SW132_180305, 0874_SW123_180305,

0874_SW131_180305, 0874_SW102_180305,

0874_QC1SW_180305

02-Apr-2018---- 07-Mar-2018----05-Mar-2018 ---- ü

ED037P: Alkalinity by PC Titrator

Clear Plastic Bottle - Natural (ED037-P)

0874_SW132_180305, 0874_SW123_180305,

0874_SW131_180305, 0874_SW102_180305,

0874_QC1SW_180305

19-Mar-2018---- 06-Mar-2018----05-Mar-2018 ---- ü

ED041G: Sulfate (Turbidimetric) as SO4 2- by DA

Clear Plastic Bottle - Natural (ED041G)

0874_SW132_180305, 0874_SW123_180305,

0874_SW131_180305, 0874_SW102_180305,

0874_QC1SW_180305

02-Apr-2018---- 07-Mar-2018----05-Mar-2018 ---- ü

ED045G: Chloride by Discrete Analyser


0874_SW132_180305, 0874_SW123_180305,

0874_SW131_180305, 0874_SW102_180305,

0874_QC1SW_180305

02-Apr-2018---- 07-Mar-2018----05-Mar-2018 ---- ü

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ED093F: Dissolved Major Cations


0874_SW132_180305, 0874_SW123_180305,

0874_SW131_180305, 0874_SW102_180305,

0874_QC1SW_180305

02-Apr-2018---- 07-Mar-2018----05-Mar-2018 ---- ü

EG020F: Dissolved Metals by ICP-MS

Clear Plastic Bottle - Filtered; Lab-acidified (EG020A-F)

0874_SW132_180305, 0874_SW123_180305,

0874_SW131_180305, 0874_SW102_180305,

0874_QC1SW_180305, 0874_QC3R1_180305

01-Sep-2018---- 07-Mar-2018----05-Mar-2018 ---- ü


Clear Plastic Bottle - HCl (EG051G)

0874_SW132_180305, 0874_SW123_180305,

0874_SW131_180305, 0874_SW102_180305,

0874_QC1SW_180305

06-Mar-2018---- 08-Mar-2018----05-Mar-2018 ---- û

EK040P: Fluoride by PC Titrator

Clear Plastic Bottle - Natural (EK040P)

0874_SW132_180305, 0874_SW123_180305,

0874_SW131_180305, 0874_SW102_180305,

0874_QC1SW_180305

02-Apr-2018---- 06-Mar-2018----05-Mar-2018 ---- ü

EK055G: Ammonia as N by Discrete Analyser

Clear Plastic Bottle - Sulfuric Acid (EK055G)

0874_SW132_180305, 0874_SW123_180305,

0874_SW131_180305, 0874_SW102_180305,

0874_QC1SW_180305

02-Apr-2018---- 13-Mar-2018----05-Mar-2018 ---- ü

EK057G: Nitrite as N by Discrete Analyser

Clear Plastic Bottle - Natural (EK057G)

0874_SW132_180305, 0874_SW123_180305,

0874_SW131_180305, 0874_SW102_180305,

0874_QC1SW_180305

07-Mar-2018---- 07-Mar-2018----05-Mar-2018 ---- ü

EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser


0874_SW132_180305, 0874_SW123_180305,

0874_SW131_180305, 0874_SW102_180305,

0874_QC1SW_180305

02-Apr-2018---- 13-Mar-2018----05-Mar-2018 ---- ü



0874_SW132_180305, 0874_SW123_180305,

0874_SW131_180305, 0874_SW102_180305,

0874_QC1SW_180305

02-Apr-201802-Apr-2018 13-Mar-201813-Mar-201805-Mar-2018 ü ü

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0874_SW132_180305, 0874_SW123_180305,

0874_SW131_180305, 0874_SW102_180305,

0874_QC1SW_180305

02-Apr-201802-Apr-2018 13-Mar-201813-Mar-201805-Mar-2018 ü ü

EK071G: Reactive Phosphorus as P by discrete analyser


0874_SW132_180305, 0874_SW123_180305,

0874_SW131_180305, 0874_SW102_180305,

0874_QC1SW_180305

07-Mar-2018---- 07-Mar-2018----05-Mar-2018 ---- ü

EP005: Total Organic Carbon (TOC)

Amber TOC Vial - Sulfuric Acid (EP005)

0874_SW132_180305, 0874_SW123_180305,

0874_SW131_180305, 0874_SW102_180305,

0874_QC1SW_180305

02-Apr-2018---- 06-Mar-2018----05-Mar-2018 ---- ü

EP026SP: Chemical Oxygen Demand (Spectrophotometric)

Clear Plastic Bottle - Sulfuric Acid (EP026SP)

0874_SW132_180305, 0874_SW123_180305,

0874_SW131_180305, 0874_SW102_180305,

0874_QC1SW_180305

02-Apr-2018---- 14-Mar-2018----05-Mar-2018 ---- ü

EP030: Biochemical Oxygen Demand (BOD)

Clear Plastic Bottle - Natural (EP030)

0874_SW132_180305, 0874_SW123_180305,

0874_SW131_180305, 0874_SW102_180305,

0874_QC1SW_180305

07-Mar-2018---- 07-Mar-2018----05-Mar-2018 ---- ü


HDPE (no PTFE) (EP231X-ST)

0874_SW132_180305, 0874_SW123_180305,

0874_SW131_180305, 0874_SW102_180305,

0874_QC1SW_180305, 0874_QC3R1_180305

01-Sep-201801-Sep-2018 08-Mar-201807-Mar-201805-Mar-2018 ü ü


0874_QC4FB_180305, 0874_QC5TB_180305,

0874_SW132_180305_F - Filtered, 0874_SW123_180305_F - Filtered,


0874_QC5TB_180305_F - Filtered, 0874_QC1SW_180305_F - Filtered


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0874_SW132_180305, 0874_SW123_180305,

0874_SW131_180305, 0874_SW102_180305,

0874_QC1SW_180305, 0874_QC3R1_180305



0874_QC4FB_180305, 0874_QC5TB_180305,





EP231C: Perfluoroalkyl Sulfonamides


0874_SW132_180305, 0874_SW123_180305,

0874_SW131_180305, 0874_SW102_180305,

0874_QC1SW_180305, 0874_QC3R1_180305



0874_QC4FB_180305, 0874_QC5TB_180305,





EP231D: (n:2) Fluorotelomer Sulfonic Acids


0874_SW132_180305, 0874_SW123_180305,

0874_SW131_180305, 0874_SW102_180305,

0874_QC1SW_180305, 0874_QC3R1_180305



0874_QC4FB_180305, 0874_QC5TB_180305,





EP231P: PFAS Sums


0874_SW132_180305, 0874_SW123_180305,

0874_SW131_180305, 0874_SW102_180305,

0874_QC1SW_180305, 0874_QC3R1_180305



0874_QC4FB_180305, 0874_QC5TB_180305,





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Quality Control Parameter Frequency ComplianceThe following report summarises the frequency of laboratory QC samples analysed within the analytical lot(s) in which the submitted sample(s) was(were) processed. Actual rate should be greater than or equal to

the expected rate. A listing of breaches is provided in the Summary of Outliers.

Matrix: WATER Evaluation: û = Quality Control frequency not within specification ; ü = Quality Control frequency within specification.

Quality Control SpecificationQuality Control Sample Type

ExpectedQC Regular Actual

Rate (%)Quality Control Sample Type CountEvaluationAnalytical Methods Method

Laboratory Duplicates (DUP)

NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üAlkalinity by PC Titrator ED037-P

NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üAmmonia as N by Discrete analyser EK055G

NEPM 2013 B3 & ALS QC Standard 10.71 10.003 28 üBiochemical Oxygen Demand (BOD) EP030

NEPM 2013 B3 & ALS QC Standard 12.50 10.002 16 üChemical Oxygen Demand (COD) (Spectrophotometric) EP026SP

NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üChloride by Discrete Analyser ED045G

NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üConductivity by PC Titrator EA010-P

NEPM 2013 B3 & ALS QC Standard 16.67 10.002 12 üDissolved Metals by ICP-MS - Suite A EG020A-F

NEPM 2013 B3 & ALS QC Standard 16.67 10.001 6 üFerrous Iron by Discrete Analyser EG051G

NEPM 2013 B3 & ALS QC Standard 14.29 10.002 14 üFluoride by PC Titrator EK040P

NEPM 2013 B3 & ALS QC Standard 16.67 10.002 12 üMajor Cations - Dissolved ED093F

NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üNitrite and Nitrate as N (NOx) by Discrete Analyser EK059G

NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üNitrite as N by Discrete Analyser EK057G

NEPM 2013 B3 & ALS QC Standard 11.11 10.003 27 üPer- and Polyfluoroalkyl Substances (PFAS) by LCMSMS EP231X-ST

NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üpH by PC Titrator EA005-P

NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üReactive Phosphorus as P-By Discrete Analyser EK071G

NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üSulfate (Turbidimetric) as SO4 2- by Discrete Analyser ED041G

NEPM 2013 B3 & ALS QC Standard 18.18 10.002 11 üSuspended Solids (High Level) EA025H

NEPM 2013 B3 & ALS QC Standard 18.18 10.002 11 üTotal Dissolved Solids (High Level) EA015H

NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üTotal Kjeldahl Nitrogen as N By Discrete Analyser EK061G

NEPM 2013 B3 & ALS QC Standard 15.38 10.002 13 üTotal Organic Carbon EP005

NEPM 2013 B3 & ALS QC Standard 14.29 10.002 14 üTotal Phosphorus as P By Discrete Analyser EK067G

NEPM 2013 B3 & ALS QC Standard 10.00 10.002 20 üTurbidity EA045

Laboratory Control Samples (LCS)














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Laboratory Control Samples (LCS) - Continued









Method Blanks (MB)





















Matrix Spikes (MS)











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Matrix Spikes (MS) - Continued





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Brief Method SummariesThe analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the US EPA, APHA, AS and NEPM. In house

developed procedures are employed in the absence of documented standards or by client request. The following report provides brief descriptions of the analytical procedures employed for results reported in the

Certificate of Analysis. Sources from which ALS methods have been developed are provided within the Method Descriptions.

Analytical Methods Method DescriptionsMatrixMethod

In house: Referenced to APHA 4500 H+ B. This procedure determines pH of water samples by automated ISE.

This method is compliant with NEPM (2013) Schedule B(3)

pH by PC Titrator EA005-P WATER

In house: Referenced to APHA 2510 B. This procedure determines conductivity by automated ISE. This method

is compliant with NEPM (2013) Schedule B(3)

Conductivity by PC Titrator EA010-P WATER

In house: Referenced to APHA 2540C. A gravimetric procedure that determines the amount of `filterable` residue

in an aqueous sample. A well-mixed sample is filtered through a glass fibre filter (1.2um). The filtrate is

evaporated to dryness and dried to constant weight at 180+/-5C. This method is compliant with NEPM (2013)

Schedule B(3)

Total Dissolved Solids (High Level) EA015H WATER

In house: Calculation from Electrical Conductivity (APHA 2510 B) using a conversion factor specified in the

analytical report. This method is compliant with NEPM (2013) Schedule B(3)

Calculated TDS (from Electrical

Conductivity)

EA016 WATER

In house: Referenced to APHA 2540D. A gravimetric procedure employed to determine the amount of

`non-filterable` residue in a aqueous sample. The prescribed GFC (1.2um) filter is rinsed with deionised water,

oven dried and weighed prior to analysis. A well-mixed sample is filtered through a glass fibre filter (1.2um).

The residue on the filter paper is dried at 104+/-2C . This method is compliant with NEPM (2013) Schedule B(3)

Suspended Solids (High Level) EA025H WATER

In house: Referenced to APHA 2130 B. This method is compliant with NEPM (2013) Schedule B(3)Turbidity EA045 WATER

In house: Referenced to APHA 2320 B This procedure determines alkalinity by automated measurement (e.g. PC

Titrate) using pH 4.5 for indicating the total alkalinity end-point. This method is compliant with NEPM (2013)

Schedule B(3)

Alkalinity by PC Titrator ED037-P WATER

In house: Referenced to APHA 4500-SO4. Dissolved sulfate is determined in a 0.45um filtered sample. Sulfate

ions are converted to a barium sulfate suspension in an acetic acid medium with barium chloride. Light

absorbance of the BaSO4 suspension is measured by a photometer and the SO4-2 concentration is determined

by comparison of the reading with a standard curve. This method is compliant with NEPM (2013) Schedule B(3)

Sulfate (Turbidimetric) as SO4 2- by

Discrete Analyser

ED041G WATER

In house: Referenced to APHA 4500 Cl - G.The thiocyanate ion is liberated from mercuric thiocyanate through

sequestration of mercury by the chloride ion to form non-ionised mercuric chloride.in the presence of ferric ions

the librated thiocynate forms highly-coloured ferric thiocynate which is measured at 480 nm APHA 21st edition

seal method 2 017-1-L april 2003

Chloride by Discrete Analyser ED045G WATER

In house: Referenced to APHA 3120 and 3125; USEPA SW 846 - 6010 and 6020; Cations are determined by

either ICP-AES or ICP-MS techniques. This method is compliant with NEPM (2013) Schedule B(3)

Sodium Adsorption Ratio is calculated from Ca, Mg and Na which determined by ALS in house method

QWI-EN/ED093F. This method is compliant with NEPM (2013) Schedule B(3)

Hardness parameters are calculated based on APHA 2340 B. This method is compliant with NEPM (2013)

Schedule B(3)

Major Cations - Dissolved ED093F WATER

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In house: Referenced to APHA 3125; USEPA SW846 - 6020, ALS QWI-EN/EG020. Samples are 0.45µm filtered

prior to analysis. The ICPMS technique utilizes a highly efficient argon plasma to ionize selected elements. Ions

are then passed into a high vacuum mass spectrometer, which separates the analytes based on their distinct

mass to charge ratios prior to their measurement by a discrete dynode ion detector.

Dissolved Metals by ICP-MS - Suite A EG020A-F WATER

In house: Referenced to APHA 3500 Fe-B. A colorimetric determination based on the reaction between

phenanthroline and ferrous iron at pH 3.2-3.3 to form an orange-red complex that is measured against a

five-point calibration curve. This method is compliant with NEPM (2013) Schedule B(3)

Ferrous Iron by Discrete Analyser EG051G WATER

In house: Referenced to APHA 4500-F C: CDTA is added to the sample to provide a uniform ionic strength

background, adjust pH, and break up complexes. Fluoride concentration is determined by either manual or

automatic ISE measurement. This method is compliant with NEPM (2013) Schedule B(3)

Fluoride by PC Titrator EK040P WATER

In house: Referenced to APHA 4500-NH3 G Ammonia is determined by direct colorimetry by Discrete Analyser.


Ammonia as N by Discrete analyser EK055G WATER

In house: Referenced to APHA 4500-NO2- B. Nitrite is determined by direct colourimetry by Discrete Analyser.


Nitrite as N by Discrete Analyser EK057G WATER

In house: Referenced to APHA 4500-NO3- F. Nitrate is reduced to nitrite by way of a chemical reduction followed

by quantification by Discrete Analyser. Nitrite is determined seperately by direct colourimetry and result for Nitrate

calculated as the difference between the two results. This method is compliant with NEPM (2013) Schedule B(3)

Nitrate as N by Discrete Analyser EK058G WATER

In house: Referenced to APHA 4500-NO3- F. Combined oxidised Nitrogen (NO2+NO3) is determined by

Chemical Reduction and direct colourimetry by Discrete Analyser. This method is compliant with NEPM (2013)

Schedule B(3)

Nitrite and Nitrate as N (NOx) by Discrete

Analyser

EK059G WATER

In house: Referenced to APHA 4500-Norg D (In house). An aliquot of sample is digested using a high

temperature Kjeldahl digestion to convert nitrogenous compounds to ammonia. Ammonia is determined

colorimetrically by discrete analyser. This method is compliant with NEPM (2013) Schedule B(3)

Total Kjeldahl Nitrogen as N By Discrete

Analyser

EK061G WATER

In house: Referenced to APHA 4500-Norg / 4500-NO3-. This method is compliant with NEPM (2013) Schedule

B(3)

Total Nitrogen as N (TKN + Nox) By

Discrete Analyser

EK062G WATER

In house: Referenced to APHA 4500-P H, Jirka et al (1976), Zhang et al (2006). This procedure involves

sulphuric acid digestion of a sample aliquot to break phosphorus down to orthophosphate. The orthophosphate

reacts with ammonium molybdate and antimony potassium tartrate to form a complex which is then reduced and

its concentration measured at 880nm using discrete analyser. This method is compliant with NEPM (2013)

Schedule B(3)

Total Phosphorus as P By Discrete

Analyser

EK067G WATER

In house: Referenced to APHA 4500-P F Ammonium molybdate and potassium antimonyl tartrate reacts in acid

medium with othophosphate to form a heteropoly acid -phosphomolybdic acid - which is reduced to intensely

coloured molybdenum blue by ascorbic acid. Quantification is by Discrete Analyser. This method is compliant

with NEPM (2013) Schedule B(3)

Reactive Phosphorus as P-By Discrete

Analyser

EK071G WATER

In house: Referenced to APHA 1030F. This method is compliant with NEPM (2013) Schedule B(3)Ionic Balance by PCT DA and Turbi SO4

DA

EN055 - PG WATER

In house: Referenced to APHA 5310 B, The automated TOC analyzer determines Total and Inorganic Carbon by

IR cell. TOC is calculated as the difference. This method is compliant with NEPM (2013) Schedule B(3)

Total Organic Carbon EP005 WATER

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In house: Referenced to APHA 5220 D. Samples are digested with a known excess of an acidic potassium

dichromate solution using silver sulfate as a catalyst. The chromium is reduced from the Cr (VI) oxidation state

to the Cr (III) state by the oxygen present in the organic material. Both of these chromium species are coloued

and absorb in the visible region of (400nm & 600nm) the spectrum. The oxidisable organic matter can be

calculated in terms of oxygen equivalents.

Chemical Oxygen Demand (COD)

(Spectrophotometric)

EP026SP WATER

In house: Referenced to APHA 5210 B. The 5-Day BOD test provides an empirical measure of the oxygen

consumption capacity of a given water. A portion of the sample is diluted into oxygenated, nutrient rich water, and

a seed added to begin biological decay. The initial dissolved oxygen content is measured, then the bottle is

sealed and incubated for five days. The remaining dissolved oxygen is measured, and from the difference, the

demand for oxygen, by biological decay, is determined. This method is compliant with NEPM (2013) Schedule

B(3)

Biochemical Oxygen Demand (BOD) EP030 WATER

In-house: Analysis of fresh and saline waters by solid phase extraction and LC-Electrospray-MS-MS, Negative

Mode using MRM. This method is targetted to pristine environmental and drinking waters reportin at sub-parts

per trillion. Where commercially available, isotopically labelled analogues of the target analytes are used as

internal standards for quantification. Where a labelled analogue is not commercially available, the internal

standard with similar chemistry and the closest retention time to the target is used for quantification. PFOS is

quantified using a certified, traceable standard consisting of linear and branched PFOS isomers.

Per- and Polyfluoroalkyl Substances

(PFAS) by LCMSMS

EP231X-ST WATER

Preparation Methods Method DescriptionsMatrixMethod

In house: Referenced to APHA 4500 Norg - D; APHA 4500 P - H. This method is compliant with NEPM (2013)

Schedule B(3)

TKN/TP Digestion EK061/EK067 WATER

In houseSPE preparation for LL and saline PFCs EP231-SPE WATER

Environmental

SAMPLE RECEIPT NOTIFICATION (SRN)Work Order : ET1800563


: :ContactContact KATIE MCPHERSON John Pickering

:: AddressAddress MOBIL

C/O GPO BOX 2907

BRISBANE QLD, AUSTRALIA 4000

14-15 Desma Ct, Bohle Townsville

QLD AUSTRALIA 4814

:: E-mailE-mail [email protected] [email protected]

:: TelephoneTelephone ---- +61 7 4796 0600

:: FacsimileFacsimile ---- +61 7 4796 0620

::Project QLD_0874_PFAS Page 1 of 3

:Order number PS102571 - 102 :Quote number EB2016PARBRIQLD0003 (TV/077/16

V3)

:C-O-C number ---- :QC Level NEPM 2013 B3 & ALS QC Standard

Site : ----

Sampler : KATIE MCPHERSON

DatesDate Samples Received : Issue Date : 06-Mar-201805-Mar-2018 12:25

Scheduled Reporting Date: 15-Mar-2018:Client Requested Due

Date

15-Mar-2018

Delivery DetailsMode of Delivery : :Client Drop Off Not AvailableSecurity Seal

No. of coolers/boxes : :2 Temperature 0.9, 7.6°C - Ice present

: : 14 / 14MEDIUM ESKIESReceipt Detail No. of samples received / analysed

General Comments

This report contains the following information:l

- Sample Container(s)/Preservation Non-Compliances

- Summary of Sample(s) and Requested Analysis

- Proactive Holding Time Report

- Requested Deliverables

l Please be advised that an extra sample "0874_QC1SW_180305_F" was received in addition to the

samples listed on the COC. This sample has been added to the end of the work order, filtered and

assigned EP231X-ST analysis. Please contact client services at

[email protected] if this is incorrect.l Discounted Package Prices apply only when specific ALS Group Codes ('W', 'S', 'NT' suites) are referenced on COCs.

l EA016, EK058G, EA045, EA005-P, EA010-P, EA015H, EA025H, ED037-P, ED041G, ED045G, EK040P, EK055G, EK057G, EK059G,

EK071G conducted by ALS Townsville, NATA accreditation no. 825, (Site no. 23313)

l EP231X-ST conducted by ALS Sydney, NATA accreditation no. 825, site no 10911.

l Please direct any turn around / technical queries to the laboratory contact designated above.

l Sample Disposal - Aqueous (3 weeks), Solid (2 months) from receipt of samples.

l Additional charges of $5.00 will apply to each sample requiring laboratory filtration.l All remaining analysis will be conducted by ALS Environmental, Brisbane, NATA accreditation no. 825, Site No. 818.


:Client WSP Australia Pty Ltd

Work Order : ET1800563 Amendment 02 of 3:Page

06-Mar-2018:Issue Date

Sample Container(s)/Preservation Non-Compliances

All comparisons are made against pretreatment/preservation AS, APHA, USEPA standards.

l No sample container / preservation non-compliance exists.

Any sample identifications that cannot be displayed entirely in the analysis summary table will be listed below.

ET1800563-009 : [ 05-Mar-2018 ] : 0874_SW132_180305_F - Filtered




ET1800563-013 : [ 05-Mar-2018 ] : 0874_QC5TB_180305_F - Filtered

ET1800563-014 : [ 05-Mar-2018 ] : 0874_QC1SW_180305_F - Filtered

Summary of Sample(s) and Requested Analysis

Some items described below may be part of a laboratory

process necessary for the execution of client requested

tasks. Packages may contain additional analyses, such

as the determination of moisture content and preparation

tasks, that are included in the package.

If no sampling time is provided, the sampling time will

default 00:00 on the date of sampling. If no sampling date

is provided, the sampling date will be assumed by the

laboratory and displayed in brackets without a time

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ET1800563-001 05-Mar-2018 00:00 0874_SW132_180305 ü ü ü ü ü ü ü

ET1800563-002 05-Mar-2018 00:00 0874_SW123_180305 ü ü ü ü ü ü ü

ET1800563-003 05-Mar-2018 00:00 0874_SW131_180305 ü ü ü ü ü ü ü

ET1800563-004 05-Mar-2018 00:00 0874_SW102_180305 ü ü ü ü ü ü ü

ET1800563-005 05-Mar-2018 00:00 0874_QC1SW_180305 ü ü ü ü ü ü ü

ET1800563-006 05-Mar-2018 00:00 0874_QC3R1_180305 ü ü

ET1800563-007 05-Mar-2018 00:00 0874_QC4FB_180305 ü

ET1800563-008 05-Mar-2018 00:00 0874_QC5TB_180305 ü

ET1800563-009 05-Mar-2018 00:00 0874_SW132_180305_F ... ü

ET1800563-010 05-Mar-2018 00:00 0874_SW123_180305_F ... ü

ET1800563-011 05-Mar-2018 00:00 0874_SW131_180305_F ... ü

ET1800563-012 05-Mar-2018 00:00 0874_SW102_180305_F ... ü

ET1800563-013 05-Mar-2018 00:00 0874_QC5TB_180305_F ... ü

ET1800563-014 05-Mar-2018 00:00 0874_QC1SW_180305_F .. ü

Matrix: WATER

Client sample IDLaboratory sample

ID

Client sampling

date / time

WA

TE

R -

EA

015H

Tota

l Dis

solv

ed S

olid

s -

Sta

ndard

Leve

l

WA

TE

R -

EA

045

Turb

idity

WA

TE

R -

EP

005

Tota

l Org

anic

Carb

on (

TO

C)

ET1800563-001 05-Mar-2018 00:00 0874_SW132_180305 ü ü ü

ET1800563-002 05-Mar-2018 00:00 0874_SW123_180305 ü ü ü

ET1800563-003 05-Mar-2018 00:00 0874_SW131_180305 ü ü ü

ET1800563-004 05-Mar-2018 00:00 0874_SW102_180305 ü ü ü

Matrix: WATER


ID

Client sampling

date / time




WA

TE

R -

EA

01

5H

Tota

l Dis

solv

ed

Solid

s -

Sta

nda

rd L

eve

l

WA

TE

R -

EA

04

5

Turb

idity

WA

TE

R -

EP

00

5

Tota

l Org

an

ic C

arb

on

(T

OC

)

ET1800563-005 05-Mar-2018 00:00 0874_QC1SW_180305 ü ü ü

Proactive Holding Time Report

Sample(s) have been received within the recommended holding times for the requested analysis.

Requested Deliverables

AU ACCOUNTS PAYABLE

- A4 - AU Tax Invoice (INV) Email [email protected]

DAVID HARRIS

- *AU Certificate of Analysis - NATA (COA) Email [email protected]

- *AU Interpretive QC Report - DEFAULT (Anon QCI Rep) (QCI) Email [email protected]

- *AU QC Report - DEFAULT (Anon QC Rep) - NATA (QC) Email [email protected]

- A4 - AU Sample Receipt Notification - Environmental HT (SRN) Email [email protected]

- Chain of Custody (CoC) (COC) Email [email protected]

- EDI Format - ESDAT (ESDAT) Email [email protected]

- EDI Format - XTab (XTAB) Email [email protected]

DERP LABREPORTS


KATIE MCPHERSON








PHIL SCHULZ








RESULTS RESULTS








0 0.00 True

Environmental

CERTIFICATE OF ANALYSISWork Order : Page : 1 of 9ET1800572

:: LaboratoryClient WSP Australia Pty Ltd Environmental Division Townsville

: :ContactContact MR PHIL SCHULZ John Pickering


C/O GPO BOX 2907


14-15 Desma Ct, Bohle Townsville QLD AUSTRALIA 4814

:Telephone +61 07 3368 6642 :Telephone +61 7 4796 0600

:Project QLD_0874_PFAS Date Samples Received : 05-Mar-2018 12:25

:Order number PS102571 - 102 Date Analysis Commenced : 06-Mar-2018

:C-O-C number ---- Issue Date : 14-Mar-2018 14:26


Site : ----

Quote number : TV/077/16 V4

12:No. of samples received

12:No. of samples analysed

This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted. This document shall not be reproduced, except in full.

This Certificate of Analysis contains the following information:

l General Comments

l Analytical Results

l Surrogate Control Limits

Additional information pertinent to this report will be found in the following separate attachments: Quality Control Report, QA/QC Compliance Assessment to assist with

Quality Review and Sample Receipt Notification.

SignatoriesThis document has been electronically signed by the authorized signatories below. Electronic signing is carried out in compliance with procedures specified in 21 CFR Part 11.

Signatories Accreditation CategoryPosition

Alex Rossi Organic Chemist Sydney Organics, Smithfield, NSW

Franco Lentini Sydney Organics, Smithfield, NSW

Kim McCabe Townsville Inorganics, Townsville, QLD


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:Client

ET1800572



General Comments

The analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the USEPA, APHA, AS and NEPM. In house

developed procedures are employed in the absence of documented standards or by client request.

Where moisture determination has been performed, results are reported on a dry weight basis.

Where a reported less than (<) result is higher than the LOR, this may be due to primary sample extract/digestate dilution and/or insufficient sample for analysis.

Where the LOR of a reported result differs from standard LOR, this may be due to high moisture content, insufficient sample (reduced weight employed) or matrix interference.

When sampling time information is not provided by the client, sampling dates are shown without a time component. In these instances, the time component has been assumed by the laboratory for processing

purposes.

Where a result is required to meet compliance limits the associated uncertainty must be considered. Refer to the ALS Contact for details.

CAS Number = CAS registry number from database maintained by Chemical Abstracts Services. The Chemical Abstracts Service is a division of the American Chemical Society.

LOR = Limit of reporting

^ = This result is computed from individual analyte detections at or above the level of reporting

ø = ALS is not NATA accredited for these tests.

~ = Indicates an estimated value.

Key :

PFAS conducted by ALS Sydney, NATA accreditation no. 825, site no 10911.l

EP231: Poor matrix spike recovery due to matrix interference and the presence of high level contaminantsl

TDS by method EA-015 may bias high due to colour and the presence of fine particulate matter, which may pass through the prescribed GF/C paper.l

EA045, EA015H, EA025H conducted by ALS Townsville, NATA accreditation no. 825, (Site no. 23313)l

EP231X: Particular samples required dilution due to the presence of high level contaminants. LOR values have been adjusted accordingly.l

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:Client

ET1800572



Analytical Results

0874_QC3R1_1803040874_SW102_1803040874_SW131_1803040874_SW123_1803040874_SW132_180304Client sample IDSub-Matrix: WATER

(Matrix: WATER)

04-Mar-2018 00:0004-Mar-2018 00:0004-Mar-2018 00:0004-Mar-2018 00:0004-Mar-2018 00:00Client sampling date / time

ET1800572-005ET1800572-004ET1800572-003ET1800572-002ET1800572-001UnitLORCAS NumberCompound

Result Result Result Result Result


988 322 350 200 ----mg/L10----Total Dissolved Solids @180°C


<5 6 <5 <5 ----mg/L5----Suspended Solids (SS)

EA045: Turbidity

1.1 2.6 2.9 2.0 ----NTU0.1----Turbidity


3.46Perfluorobutane sulfonic acid

(PFBS)

2.72 0.208 0.0264 <0.0005µg/L0.0005375-73-5

2.66Perfluoropentane sulfonic acid

(PFPeS)

1.91 0.168 0.0199 <0.0005µg/L0.00052706-91-4

18.8Perfluorohexane sulfonic acid

(PFHxS)

15.5 1.90 0.281 <0.0005µg/L0.0005355-46-4

1.38Perfluoroheptane sulfonic acid

(PFHpS)

1.24 0.139 0.0164 <0.0005µg/L0.0005375-92-8

27.6Perfluorooctane sulfonic acid

(PFOS)

19.9 4.98 0.506 <0.0003µg/L0.00031763-23-1

0.0557Perfluorodecane sulfonic acid

(PFDS)

<0.0200 0.0098 <0.0005 <0.0005µg/L0.0005335-77-3


0.390Perfluorobutanoic acid (PFBA) 0.350 0.023 0.004 <0.002µg/L0.002375-22-4

1.83Perfluoropentanoic acid (PFPeA) 0.740 0.113 0.0098 <0.0005µg/L0.00052706-90-3

9.05Perfluorohexanoic acid (PFHxA) 3.82 0.486 0.0471 <0.0005µg/L0.0005307-24-4

1.73Perfluoroheptanoic acid (PFHpA) 0.466 0.0536 0.0060 <0.0005µg/L0.0005375-85-9

3.72Perfluorooctanoic acid (PFOA) 1.04 0.142 0.0230 <0.0005µg/L0.0005335-67-1

0.0620Perfluorononanoic acid (PFNA) <0.0200 <0.0020 <0.0005 <0.0005µg/L0.0005375-95-1

<0.0200Perfluorodecanoic acid (PFDA) <0.0200 <0.0020 <0.0005 <0.0005µg/L0.0005335-76-2

<0.0200Perfluoroundecanoic acid

(PFUnDA)

<0.0200 <0.0020 <0.0005 <0.0005µg/L0.00052058-94-8

<0.0200Perfluorododecanoic acid

(PFDoDA)

<0.0200 <0.0020 <0.0005 <0.0005µg/L0.0005307-55-1

<0.0200Perfluorotridecanoic acid

(PFTrDA)

<0.0200 <0.0020 <0.0005 <0.0005µg/L0.000572629-94-8

<0.0500Perfluorotetradecanoic acid

(PFTeDA)

<0.0500 <0.0050 <0.0005 <0.0005µg/L0.0005376-06-7


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Analytical Results


(Matrix: WATER)




EP231C: Perfluoroalkyl Sulfonamides - Continued

<0.0200Perfluorooctane sulfonamide

(FOSA)

<0.0200 0.0046 <0.0005 <0.0005µg/L0.0005754-91-6

<0.050N-Methyl perfluorooctane

sulfonamide (MeFOSA)

<0.050 <0.005 <0.001 <0.001µg/L0.00131506-32-8

<0.050N-Ethyl perfluorooctane

sulfonamide (EtFOSA)

<0.050 <0.005 <0.001 <0.001µg/L0.0014151-50-2



<0.050 <0.005 <0.001 <0.001µg/L0.00124448-09-7



<0.050 <0.005 <0.001 <0.001µg/L0.0011691-99-2


sulfonamidoacetic acid

(MeFOSAA)

<0.0200 <0.0020 <0.0005 <0.0005µg/L0.00052355-31-9



(EtFOSAA)

<0.0200 <0.0020 <0.0005 <0.0005µg/L0.00052991-50-6


<0.0204:2 Fluorotelomer sulfonic acid

(4:2 FTS)

<0.020 <0.002 <0.001 <0.001µg/L0.001757124-72-4

0.0926:2 Fluorotelomer sulfonic acid

(6:2 FTS)

<0.020 0.019 <0.001 <0.001µg/L0.00127619-97-2


(8:2 FTS)

0.024 <0.002 <0.001 <0.001µg/L0.00139108-34-4


(10:2 FTS)

<0.020 <0.002 <0.001 <0.001µg/L0.001120226-60-0

EP231P: PFAS Sums

70.8 47.7 8.25 0.940 <0.0003µg/L0.0003----Sum of PFAS

46.4Sum of PFHxS and PFOS 35.4 6.88 0.787 <0.0003µg/L0.0003355-46-4/1763-23-

1

66.7 44.6 7.92 0.903 <0.0003µg/L0.0003----Sum of PFAS (WA DER List)

EP231S: PFAS Surrogate

93.4 63.2 116 92.4 61.1%0.0005----13C4-PFOS

90.0 77.5 89.6 65.3 91.3%0.0005----13C8-PFOA

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Analytical Results

0874_SW131_180304

_F

Filtered

0874_SW123_180304

_F

Filtered

0874_SW132_180304

_F

Filtered

0874_QC5TB_1803040874_QC4FB_180304Client sample IDSub-Matrix: WATER

(Matrix: WATER)





<0.0005Perfluorobutane sulfonic acid

(PFBS)

<0.0005 3.44 2.78 0.196µg/L0.0005375-73-5

<0.0005Perfluoropentane sulfonic acid

(PFPeS)

<0.0005 2.58 1.86 0.149µg/L0.00052706-91-4

<0.0005Perfluorohexane sulfonic acid

(PFHxS)

<0.0005 19.8 16.5 2.14µg/L0.0005355-46-4

<0.0005Perfluoroheptane sulfonic acid

(PFHpS)

<0.0005 1.20 1.34 0.131µg/L0.0005375-92-8

<0.0003Perfluorooctane sulfonic acid

(PFOS)

<0.0003 26.8 20.3 5.02µg/L0.00031763-23-1

<0.0005Perfluorodecane sulfonic acid

(PFDS)

<0.0005 <0.0200 <0.0200 0.0078µg/L0.0005335-77-3


<0.002Perfluorobutanoic acid (PFBA) <0.002 0.294 0.198 0.020µg/L0.002375-22-4

<0.0005Perfluoropentanoic acid (PFPeA) <0.0005 1.62 0.806 0.110µg/L0.00052706-90-3

<0.0005Perfluorohexanoic acid (PFHxA) <0.0005 8.91 3.99 0.476µg/L0.0005307-24-4

<0.0005Perfluoroheptanoic acid (PFHpA) <0.0005 1.77 0.506 0.0542µg/L0.0005375-85-9

<0.0005Perfluorooctanoic acid (PFOA) <0.0005 3.71 0.984 0.133µg/L0.0005335-67-1

<0.0005Perfluorononanoic acid (PFNA) <0.0005 0.0580 <0.0200 <0.0020µg/L0.0005375-95-1



(PFUnDA)

<0.0005 <0.0200 <0.0200 <0.0020µg/L0.00052058-94-8


(PFDoDA)

<0.0005 <0.0200 <0.0200 <0.0020µg/L0.0005307-55-1


(PFTrDA)

<0.0005 <0.0200 <0.0200 <0.0020µg/L0.000572629-94-8


(PFTeDA)

<0.0005 <0.0500 <0.0500 <0.0050µg/L0.0005376-06-7



(FOSA)

<0.0005 <0.0200 <0.0200 <0.0020µg/L0.0005754-91-6



<0.001 <0.050 <0.050 <0.005µg/L0.00131506-32-8

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Analytical Results

0874_SW131_180304

_F

Filtered

0874_SW123_180304

_F

Filtered

0874_SW132_180304

_F

Filtered


(Matrix: WATER)







<0.001 <0.050 <0.050 <0.005µg/L0.0014151-50-2



<0.001 <0.050 <0.050 <0.005µg/L0.00124448-09-7



<0.001 <0.050 <0.050 <0.005µg/L0.0011691-99-2



(MeFOSAA)

<0.0005 <0.0200 <0.0200 <0.0020µg/L0.00052355-31-9



(EtFOSAA)

<0.0005 <0.0200 <0.0200 <0.0020µg/L0.00052991-50-6



(4:2 FTS)

<0.001 <0.020 <0.020 <0.002µg/L0.001757124-72-4


(6:2 FTS)

<0.001 0.094 <0.020 0.013µg/L0.00127619-97-2


(8:2 FTS)

<0.001 <0.020 <0.020 <0.002µg/L0.00139108-34-4


(10:2 FTS)

<0.001 <0.020 <0.020 <0.002µg/L0.001120226-60-0

EP231P: PFAS Sums

<0.0003 <0.0003 70.3 49.3 8.45µg/L0.0003----Sum of PFAS

<0.0003Sum of PFHxS and PFOS <0.0003 46.6 36.8 7.16µg/L0.0003355-46-4/1763-23-

1

<0.0003 <0.0003 66.4 46.1 8.16µg/L0.0003----Sum of PFAS (WA DER List)


74.8 76.6 90.4 77.7 106%0.0005----13C4-PFOS

84.7 83.8 102 97.9 78.7%0.0005----13C8-PFOA

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Analytical Results

------------0874_QC5TB_180304

_F

Filtered

0874_SW102_180304

_F

Filtered

Client sample IDSub-Matrix: WATER

(Matrix: WATER)

------------04-Mar-2018 00:0004-Mar-2018 00:00Client sampling date / time

------------------------ET1800572-012ET1800572-011UnitLORCAS NumberCompound

Result Result ---- ---- ----



(PFBS)

<0.0005 ---- ---- ----µg/L0.0005375-73-5


(PFPeS)

<0.0005 ---- ---- ----µg/L0.00052706-91-4


(PFHxS)

<0.0005 ---- ---- ----µg/L0.0005355-46-4


(PFHpS)

<0.0005 ---- ---- ----µg/L0.0005375-92-8


(PFOS)

<0.0003 ---- ---- ----µg/L0.00031763-23-1


(PFDS)

<0.0005 ---- ---- ----µg/L0.0005335-77-3


0.003Perfluorobutanoic acid (PFBA) <0.002 ---- ---- ----µg/L0.002375-22-4

0.0082Perfluoropentanoic acid (PFPeA) <0.0005 ---- ---- ----µg/L0.00052706-90-3

0.0416Perfluorohexanoic acid (PFHxA) <0.0005 ---- ---- ----µg/L0.0005307-24-4

0.0051Perfluoroheptanoic acid (PFHpA) <0.0005 ---- ---- ----µg/L0.0005375-85-9

0.0195Perfluorooctanoic acid (PFOA) <0.0005 ---- ---- ----µg/L0.0005335-67-1

<0.0005Perfluorononanoic acid (PFNA) <0.0005 ---- ---- ----µg/L0.0005375-95-1

<0.0005Perfluorodecanoic acid (PFDA) <0.0005 ---- ---- ----µg/L0.0005335-76-2


(PFUnDA)

<0.0005 ---- ---- ----µg/L0.00052058-94-8


(PFDoDA)

<0.0005 ---- ---- ----µg/L0.0005307-55-1


(PFTrDA)

<0.0005 ---- ---- ----µg/L0.000572629-94-8


(PFTeDA)

<0.0005 ---- ---- ----µg/L0.0005376-06-7



(FOSA)

<0.0005 ---- ---- ----µg/L0.0005754-91-6



<0.001 ---- ---- ----µg/L0.00131506-32-8

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Analytical Results

------------0874_QC5TB_180304

_F

Filtered

0874_SW102_180304

_F

Filtered


(Matrix: WATER)







<0.001 ---- ---- ----µg/L0.0014151-50-2



<0.001 ---- ---- ----µg/L0.00124448-09-7



<0.001 ---- ---- ----µg/L0.0011691-99-2



(MeFOSAA)

<0.0005 ---- ---- ----µg/L0.00052355-31-9



(EtFOSAA)

<0.0005 ---- ---- ----µg/L0.00052991-50-6



(4:2 FTS)

<0.001 ---- ---- ----µg/L0.001757124-72-4


(6:2 FTS)

<0.001 ---- ---- ----µg/L0.00127619-97-2


(8:2 FTS)

<0.001 ---- ---- ----µg/L0.00139108-34-4


(10:2 FTS)

<0.001 ---- ---- ----µg/L0.001120226-60-0

EP231P: PFAS Sums

0.794 <0.0003 ---- ---- ----µg/L0.0003----Sum of PFAS

0.666Sum of PFHxS and PFOS <0.0003 ---- ---- ----µg/L0.0003355-46-4/1763-23-

1

0.766 <0.0003 ---- ---- ----µg/L0.0003----Sum of PFAS (WA DER List)


78.2 85.7 ---- ---- ----%0.0005----13C4-PFOS

62.3 107 ---- ---- ----%0.0005----13C8-PFOA

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ET1800572



Surrogate Control Limits

Recovery Limits (%)Sub-Matrix: WATER

Compound CAS Number Low High


13C4-PFOS ---- 60 120

13C8-PFOA ---- 60 120

False

3 3.00True

Environmental

QUALITY CONTROL REPORTWork Order : ET1800572 Page : 1 of 13


:Contact MR PHIL SCHULZ :Contact John Pickering

:Address MOBIL

C/O GPO BOX 2907


Address : 14-15 Desma Ct, Bohle Townsville QLD AUSTRALIA 4814

::Telephone +61 07 3368 6642 +61 7 4796 0600:Telephone



:C-O-C number ---- Issue Date : 14-Mar-2018


Site : ----


No. of samples received 12:

No. of samples analysed 12:


This Quality Control Report contains the following information:

l Laboratory Duplicate (DUP) Report; Relative Percentage Difference (RPD) and Acceptance Limits

l Method Blank (MB) and Laboratory Control Spike (LCS) Report ; Recovery and Acceptance Limits

l Matrix Spike (MS) Report; Recovery and Acceptance Limits







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ET1800572



General Comments




Where a reported less than (<) result is higher than the LOR, this may be due to primary sample extract/digestate dilution and/or insufficient sample for analysis. Where the LOR of a reported result differs from standard LOR, this may be due to high moisture c

Anonymous = Refers to samples which are not specifically part of this work order but formed part of the QC process lot



RPD = Relative Percentage Difference

# = Indicates failed QC

Key :

Laboratory Duplicate (DUP) Report

The quality control term Laboratory Duplicate refers to a randomly selected intralaboratory split. Laboratory duplicates provide information regarding method precision and sample heterogeneity. The permitted ranges

for the Relative Percent Deviation (RPD) of Laboratory Duplicates are specified in ALS Method QWI -EN/38 and are dependent on the magnitude of results in comparison to the level of reporting: Result < 10 times LOR:

No Limit; Result between 10 and 20 times LOR: 0% - 50%; Result > 20 times LOR: 0% - 20%.

Sub-Matrix: WATER Laboratory Duplicate (DUP) Report

Original Result RPD (%)Laboratory sample ID Client sample ID Method: Compound CAS Number LOR Unit Duplicate Result Recovery Limits (%)

EA015: Total Dissolved Solids dried at 180 ± 5 °C (QC Lot: 1475502)

EA015H: Total Dissolved Solids @180°C ---- 10 mg/L 75 76 1.65 No LimitAnonymous ET1800553-004

EA015H: Total Dissolved Solids @180°C ---- 10 mg/L 200 204 1.98 0% - 20%0874_SW102_180304 ET1800572-004

EA025: Total Suspended Solids dried at 104 ± 2°C (QC Lot: 1475501)

EA025H: Suspended Solids (SS) ---- 5 mg/L <5 <5 0.00 No LimitAnonymous ET1800553-004

EA025H: Suspended Solids (SS) ---- 5 mg/L <5 <5 0.00 No Limit0874_SW102_180304 ET1800572-004

EA045: Turbidity (QC Lot: 1475538)

EA045: Turbidity ---- 0.1 NTU 4.1 4.2 0.00 0% - 20%Anonymous ET1800553-001


EP231A: Perfluoroalkyl Sulfonic Acids (QC Lot: 1478405)

EP231X-ST: Perfluorooctane sulfonic acid

(PFOS)

1763-23-1 0.0003 µg/L <0.0020 <0.0020 0.00 No LimitAnonymous ET1800561-001

EP231X-ST: Perfluorobutane sulfonic acid

(PFBS)

375-73-5 0.0005 µg/L <0.0020 <0.0020 0.00 No Limit

EP231X-ST: Perfluoropentane sulfonic acid

(PFPeS)

2706-91-4 0.0005 µg/L <0.0020 <0.0020 0.00 No Limit

EP231X-ST: Perfluorohexane sulfonic acid

(PFHxS)

355-46-4 0.0005 µg/L <0.0020 <0.0020 0.00 No Limit

EP231X-ST: Perfluoroheptane sulfonic acid

(PFHpS)

375-92-8 0.0005 µg/L <0.0020 <0.0020 0.00 No Limit

EP231X-ST: Perfluorodecane sulfonic acid

(PFDS)

335-77-3 0.0005 µg/L <0.0020 <0.0020 0.00 No Limit


(PFOS)

1763-23-1 0.0003 µg/L 4.98 5.30 6.15 0% - 20%0874_SW131_180304 ET1800572-003


(PFBS)

375-73-5 0.0005 µg/L 0.208 0.186 11.4 0% - 20%

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EP231A: Perfluoroalkyl Sulfonic Acids (QC Lot: 1478405) - continued


(PFPeS)

2706-91-4 0.0005 µg/L 0.168 0.154 8.46 0% - 20%0874_SW131_180304 ET1800572-003


(PFHxS)

355-46-4 0.0005 µg/L 1.90 1.92 0.691 0% - 20%


(PFHpS)

375-92-8 0.0005 µg/L 0.139 0.132 5.18 0% - 20%


(PFDS)

335-77-3 0.0005 µg/L 0.0098 0.0102 4.00 No Limit



(PFOS)

1763-23-1 0.0003 µg/L 25.2 25.2 0.119 0% - 20%Anonymous ET1800563-001


(PFBS)

375-73-5 0.0005 µg/L 1.82 1.79 1.83 0% - 20%


(PFPeS)

2706-91-4 0.0005 µg/L 1.80 1.74 3.50 0% - 20%


(PFHxS)

355-46-4 0.0005 µg/L 14.5 14.4 0.693 0% - 20%


(PFHpS)

375-92-8 0.0005 µg/L 0.984 0.907 8.14 0% - 20%


(PFDS)

335-77-3 0.0005 µg/L <0.0100 <0.0100 0.00 No Limit


(PFOS)

1763-23-1 0.0003 µg/L 0.308 0.288 6.71 0% - 20%Anonymous ET1800576-004


(PFBS)

375-73-5 0.0005 µg/L 0.0140 0.0130 7.41 No Limit


(PFPeS)

2706-91-4 0.0005 µg/L 0.0130 0.0100 26.1 No Limit


(PFHxS)

355-46-4 0.0005 µg/L 0.129 0.108 17.7 0% - 50%


(PFHpS)

375-92-8 0.0005 µg/L <0.0100 <0.0100 0.00 No Limit


(PFDS)

335-77-3 0.0005 µg/L <0.0100 <0.0100 0.00 No Limit

EP231B: Perfluoroalkyl Carboxylic Acids (QC Lot: 1478405)

EP231X-ST: Perfluoropentanoic acid (PFPeA) 2706-90-3 0.0005 µg/L <0.0020 <0.0020 0.00 No LimitAnonymous ET1800561-001

EP231X-ST: Perfluorohexanoic acid (PFHxA) 307-24-4 0.0005 µg/L <0.0020 <0.0020 0.00 No Limit

EP231X-ST: Perfluoroheptanoic acid (PFHpA) 375-85-9 0.0005 µg/L <0.0020 <0.0020 0.00 No Limit

EP231X-ST: Perfluorooctanoic acid (PFOA) 335-67-1 0.0005 µg/L <0.0020 <0.0020 0.00 No Limit

EP231X-ST: Perfluorononanoic acid (PFNA) 375-95-1 0.0005 µg/L <0.0020 <0.0020 0.00 No Limit

EP231X-ST: Perfluorodecanoic acid (PFDA) 335-76-2 0.0005 µg/L <0.0020 <0.0020 0.00 No Limit

EP231X-ST: Perfluoroundecanoic acid (PFUnDA) 2058-94-8 0.0005 µg/L <0.0020 <0.0020 0.00 No Limit

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EP231B: Perfluoroalkyl Carboxylic Acids (QC Lot: 1478405) - continued

EP231X-ST: Perfluorododecanoic acid (PFDoDA) 307-55-1 0.0005 µg/L <0.0020 <0.0020 0.00 No LimitAnonymous ET1800561-001

EP231X-ST: Perfluorotridecanoic acid (PFTrDA) 72629-94-8 0.0005 µg/L <0.0020 <0.0020 0.00 No Limit

EP231X-ST: Perfluorotetradecanoic acid

(PFTeDA)

376-06-7 0.0005 µg/L <0.0050 <0.0050 0.00 No Limit

EP231X-ST: Perfluorobutanoic acid (PFBA) 375-22-4 0.002 µg/L <0.002 <0.002 0.00 No Limit

EP231X-ST: Perfluoropentanoic acid (PFPeA) 2706-90-3 0.0005 µg/L 0.113 0.102 10.4 0% - 20%0874_SW131_180304 ET1800572-003

EP231X-ST: Perfluorohexanoic acid (PFHxA) 307-24-4 0.0005 µg/L 0.486 0.434 11.4 0% - 20%

EP231X-ST: Perfluoroheptanoic acid (PFHpA) 375-85-9 0.0005 µg/L 0.0536 0.0506 5.76 0% - 20%

EP231X-ST: Perfluorooctanoic acid (PFOA) 335-67-1 0.0005 µg/L 0.142 0.135 4.92 0% - 20%




EP231X-ST: Perfluorododecanoic acid (PFDoDA) 307-55-1 0.0005 µg/L <0.0020 <0.0020 0.00 No Limit



(PFTeDA)

376-06-7 0.0005 µg/L <0.0050 <0.0050 0.00 No Limit

EP231X-ST: Perfluorobutanoic acid (PFBA) 375-22-4 0.002 µg/L 0.023 0.019 17.0 0% - 50%


EP231X-ST: Perfluoropentanoic acid (PFPeA) 2706-90-3 0.0005 µg/L 1.27 1.21 4.93 0% - 20%Anonymous ET1800563-001




EP231X-ST: Perfluorononanoic acid (PFNA) 375-95-1 0.0005 µg/L 0.0540 0.0500 7.69 No Limit






(PFTeDA)

376-06-7 0.0005 µg/L <0.0250 <0.0250 0.00 No Limit



EP231X-ST: Perfluorohexanoic acid (PFHxA) 307-24-4 0.0005 µg/L 0.0370 0.0440 17.3 No Limit


EP231X-ST: Perfluorooctanoic acid (PFOA) 335-67-1 0.0005 µg/L <0.0100 0.0100 0.00 No Limit






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(PFTeDA)



EP231C: Perfluoroalkyl Sulfonamides (QC Lot: 1478405)

EP231X-ST: Perfluorooctane sulfonamide

(FOSA)


EP231X-ST: N-Methyl perfluorooctane


2355-31-9 0.0005 µg/L <0.0020 <0.0020 0.00 No Limit

EP231X-ST: N-Ethyl perfluorooctane

sulfonamidoacetic acid (EtFOSAA)

2991-50-6 0.0005 µg/L <0.0020 <0.0020 0.00 No Limit



31506-32-8 0.001 µg/L <0.005 <0.005 0.00 No Limit

EP231X-ST: N-Ethyl perfluorooctane sulfonamide

(EtFOSA)

4151-50-2 0.001 µg/L <0.005 <0.005 0.00 No Limit



24448-09-7 0.001 µg/L <0.005 <0.005 0.00 No Limit



1691-99-2 0.001 µg/L <0.005 <0.005 0.00 No Limit


(FOSA)

754-91-6 0.0005 µg/L 0.0046 0.0038 19.0 No Limit0874_SW131_180304 ET1800572-003



2355-31-9 0.0005 µg/L <0.0020 <0.0020 0.00 No Limit



2991-50-6 0.0005 µg/L <0.0020 <0.0020 0.00 No Limit



31506-32-8 0.001 µg/L <0.005 <0.005 0.00 No Limit


(EtFOSA)

4151-50-2 0.001 µg/L <0.005 <0.005 0.00 No Limit



24448-09-7 0.001 µg/L <0.005 <0.005 0.00 No Limit



1691-99-2 0.001 µg/L <0.005 <0.005 0.00 No Limit



(FOSA)

754-91-6 0.0005 µg/L 0.0200 0.0200 0.00 No LimitAnonymous ET1800563-001



2355-31-9 0.0005 µg/L <0.0100 <0.0100 0.00 No Limit



2991-50-6 0.0005 µg/L <0.0100 <0.0100 0.00 No Limit



31506-32-8 0.001 µg/L <0.025 <0.025 0.00 No Limit

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EP231C: Perfluoroalkyl Sulfonamides (QC Lot: 1478848) - continued


(EtFOSA)




24448-09-7 0.001 µg/L <0.025 <0.025 0.00 No Limit



1691-99-2 0.001 µg/L <0.025 <0.025 0.00 No Limit


(FOSA)




2355-31-9 0.0005 µg/L <0.0100 <0.0100 0.00 No Limit



2991-50-6 0.0005 µg/L <0.0100 <0.0100 0.00 No Limit



31506-32-8 0.001 µg/L <0.025 <0.025 0.00 No Limit


(EtFOSA)

4151-50-2 0.001 µg/L <0.025 <0.025 0.00 No Limit



24448-09-7 0.001 µg/L <0.025 <0.025 0.00 No Limit



1691-99-2 0.001 µg/L <0.025 <0.025 0.00 No Limit

EP231D: (n:2) Fluorotelomer Sulfonic Acids (QC Lot: 1478405)

EP231X-ST: 4:2 Fluorotelomer sulfonic acid (4:2

FTS)



FTS)

27619-97-2 0.001 µg/L <0.002 <0.002 0.00 No Limit


FTS)

39108-34-4 0.001 µg/L <0.002 <0.002 0.00 No Limit

EP231X-ST: 10:2 Fluorotelomer sulfonic acid

(10:2 FTS)

120226-60-0 0.001 µg/L <0.002 <0.002 0.00 No Limit


FTS)

757124-72-4 0.001 µg/L <0.002 <0.002 0.00 No Limit0874_SW131_180304 ET1800572-003


FTS)

27619-97-2 0.001 µg/L 0.019 0.011 51.9 No Limit


FTS)

39108-34-4 0.001 µg/L <0.002 <0.002 0.00 No Limit


(10:2 FTS)

120226-60-0 0.001 µg/L <0.002 <0.002 0.00 No Limit



FTS)


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EP231D: (n:2) Fluorotelomer Sulfonic Acids (QC Lot: 1478848) - continued


FTS)



FTS)

39108-34-4 0.001 µg/L <0.010 <0.010 0.00 No Limit


(10:2 FTS)

120226-60-0 0.001 µg/L <0.010 <0.010 0.00 No Limit


FTS)



FTS)

27619-97-2 0.001 µg/L <0.010 <0.010 0.00 No Limit


FTS)

39108-34-4 0.001 µg/L <0.010 <0.010 0.00 No Limit


(10:2 FTS)

120226-60-0 0.001 µg/L <0.010 <0.010 0.00 No Limit

EP231P: PFAS Sums (QC Lot: 1478405)

EP231X-ST: Sum of PFAS ---- 0.0003 µg/L <0.0020 <0.0020 0.00 No LimitAnonymous ET1800561-001

EP231X-ST: Sum of PFAS ---- 0.0003 µg/L 8.25 8.46 2.53 0% - 20%0874_SW131_180304 ET1800572-003


EP231X-ST: Sum of PFAS ---- 0.0003 µg/L 58.4 57.4 1.67 0% - 20%Anonymous ET1800563-001


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Report





EA015H: Total Dissolved Solids @180°C ---- 10 mg/L <10 102293 mg/L 11288

<10 1012000 mg/L 11288



<5 98.41000 mg/L 12083



<0.1 10040 NTU 10595

<0.1 100400 NTU 10397



EP231X-ST: Perfluoropentane sulfonic acid (PFPeS) 2706-91-4 0.0005 µg/L <0.0005 1220.01 µg/L 13050

EP231X-ST: Perfluorohexane sulfonic acid (PFHxS) 355-46-4 0.0005 µg/L <0.0005 1050.01 µg/L 13050

EP231X-ST: Perfluoroheptane sulfonic acid (PFHpS) 375-92-8 0.0005 µg/L <0.0005 1100.01 µg/L 13050













EP231X-ST: Perfluorohexanoic acid (PFHxA) 307-24-4 0.0005 µg/L <0.0005 1010.01 µg/L 13050








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Report





















(MeFOSA)

31506-32-8 0.001 µg/L <0.001 86.60.025 µg/L 13040



(MeFOSE)

24448-09-7 0.001 µg/L <0.001 1060.025 µg/L 13040


(EtFOSE)

1691-99-2 0.001 µg/L <0.001 97.70.025 µg/L 13040


acid (MeFOSAA)

2355-31-9 0.0005 µg/L <0.0005 52.20.01 µg/L 13040


acid (EtFOSAA)

2991-50-6 0.0005 µg/L <0.0005 72.00.01 µg/L 13040




(MeFOSA)

31506-32-8 0.001 µg/L <0.001 95.80.025 µg/L 13040



(MeFOSE)

24448-09-7 0.001 µg/L <0.001 81.40.025 µg/L 13040


(EtFOSE)

1691-99-2 0.001 µg/L <0.001 89.60.025 µg/L 13040


acid (MeFOSAA)

2355-31-9 0.0005 µg/L <0.0005 87.40.01 µg/L 13040


acid (EtFOSAA)

2991-50-6 0.0005 µg/L <0.0005 1080.01 µg/L 13040

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Report

























Determined

0.01 µg/L 13050

2706-91-4EP231X-ST: Perfluoropentane sulfonic acid (PFPeS) # Not

Determined

0.01 µg/L 13050


Determined

0.01 µg/L 13050


Determined

0.01 µg/L 13050


Determined

0.01 µg/L 13050

335-77-3EP231X-ST: Perfluorodecane sulfonic acid (PFDS) # Not

Determined

0.01 µg/L 13030


Anonymous ET1800563-002 375-73-5EP231X-ST: Perfluorobutane sulfonic acid (PFBS) # Not

Determined

0.01 µg/L 13050

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Anonymous ET1800563-002 2706-91-4EP231X-ST: Perfluoropentane sulfonic acid (PFPeS) # Not

Determined

0.01 µg/L 13050


Determined

0.01 µg/L 13050


Determined

0.01 µg/L 13050


Determined

0.01 µg/L 13050




Determined

0.05 µg/L 13030


Determined

0.01 µg/L 13050


Determined

0.01 µg/L 13050


Determined

0.01 µg/L 13050


Determined

0.01 µg/L 13050


Determined

0.01 µg/L 13050







Anonymous ET1800563-002 375-22-4EP231X-ST: Perfluorobutanoic acid (PFBA) # Not

Determined

0.05 µg/L 13030


Determined

0.01 µg/L 13050


Determined

0.01 µg/L 13050


Determined

0.01 µg/L 13050


Determined

0.01 µg/L 13050

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Anonymous ET1800563-002 375-95-1EP231X-ST: Perfluorononanoic acid (PFNA) # Not

Determined

0.01 µg/L 13050







0874_SW132_180304 ET1800572-001 754-91-6EP231X-ST: Perfluorooctane sulfonamide (FOSA) 53.60.01 µg/L 13030


(MeFOSA)

53.00.025 µg/L 13030


(EtFOSA)

48.20.025 µg/L 13030



59.20.025 µg/L 13030



58.50.025 µg/L 13030



42.80.01 µg/L 13030


acid (EtFOSAA)

30.60.01 µg/L 13030


Anonymous ET1800563-002 754-91-6EP231X-ST: Perfluorooctane sulfonamide (FOSA) # Not

Determined

0.01 µg/L 13030


(MeFOSA)

30.70.025 µg/L 13030


(EtFOSA)

33.60.025 µg/L 13030



# 25.00.025 µg/L 13030



34.60.025 µg/L 13030



45.00.01 µg/L 13030


acid (EtFOSAA)

52.00.01 µg/L 13030


0874_SW132_180304 ET1800572-001 757124-72-4EP231X-ST: 4:2 Fluorotelomer sulfonic acid (4:2 FTS) 82.40.01 µg/L 13050

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0874_SW132_180304 ET1800572-001 27619-97-2EP231X-ST: 6:2 Fluorotelomer sulfonic acid (6:2 FTS) # Not

Determined

0.01 µg/L 13050




Anonymous ET1800563-002 757124-72-4EP231X-ST: 4:2 Fluorotelomer sulfonic acid (4:2 FTS) 57.80.01 µg/L 13050


39108-34-4EP231X-ST: 8:2 Fluorotelomer sulfonic acid (8:2 FTS) # 18.40.01 µg/L 13050


True

Environmental



:Contact MR PHIL SCHULZ Telephone : +61 7 4796 0600









Summary of Outliers









l NO Analysis Holding Time Outliers exist.




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Matrix: WATER








----Not

Determined







----Not

Determined



sulfonic acid

(PFPeS)




----Not

Determined



sulfonic acid

(PFPeS)




----Not

Determined



sulfonic acid

(PFHxS)




----Not

Determined



sulfonic acid

(PFHxS)




----Not

Determined



sulfonic acid

(PFHpS)




----Not

Determined



sulfonic acid

(PFHpS)




----Not

Determined







----Not

Determined







----Not

Determined


ET1800572--001 335-77-3Perfluorodecane

sulfonic acid (PFDS)




----Not

Determined



(PFBA)




----Not

Determined



(PFBA)




----Not

Determined


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Matrix: WATER




acid (PFPeA)




----Not

Determined



acid (PFPeA)




----Not

Determined



(PFHxA)




----Not

Determined



(PFHxA)




----Not

Determined



acid (PFHpA)




----Not

Determined



acid (PFHpA)




----Not

Determined



(PFOA)




----Not

Determined



(PFOA)




----Not

Determined


ET1800572--001 375-95-1Perfluorononanoic acid

(PFNA)




----Not

Determined


ET1800563--002 24448-09-7N-Methyl

perfluorooctane

sulfonamidoethanol

(MeFOSE)

Anonymous Recovery less than lower data quality

objective



sulfonic acid (6:2

FTS)




----Not

Determined



sulfonic acid (8:2

FTS)


objective


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0874_SW132_180304, 0874_SW123_180304,

0874_SW131_180304, 0874_SW102_180304

11-Mar-2018---- 06-Mar-2018----04-Mar-2018 ---- ü



0874_SW132_180304, 0874_SW123_180304,

0874_SW131_180304, 0874_SW102_180304

11-Mar-2018---- 06-Mar-2018----04-Mar-2018 ---- ü

EA045: Turbidity


0874_SW132_180304, 0874_SW123_180304,

0874_SW131_180304, 0874_SW102_180304

06-Mar-2018---- 06-Mar-2018----04-Mar-2018 ---- ü



0874_SW132_180304, 0874_SW123_180304,

0874_SW131_180304, 0874_SW102_180304,

0874_QC3R1_180304, 0874_QC4FB_180304,

0874_QC5TB_180304, 0874_SW132_180304_F - Filtered,


0874_SW102_180304_F - Filtered, 0874_QC5TB_180304_F - Filtered

31-Aug-201831-Aug-2018 08-Mar-201807-Mar-201804-Mar-2018 ü ü



0874_SW132_180304, 0874_SW123_180304,

0874_SW131_180304, 0874_SW102_180304,

0874_QC3R1_180304, 0874_QC4FB_180304,





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0874_SW132_180304, 0874_SW123_180304,

0874_SW131_180304, 0874_SW102_180304,

0874_QC3R1_180304, 0874_QC4FB_180304,







0874_SW132_180304, 0874_SW123_180304,

0874_SW131_180304, 0874_SW102_180304,

0874_QC3R1_180304, 0874_QC4FB_180304,





EP231P: PFAS Sums


0874_SW132_180304, 0874_SW123_180304,

0874_SW131_180304, 0874_SW102_180304,

0874_QC3R1_180304, 0874_QC4FB_180304,





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Method Blanks (MB)





Matrix Spikes (MS)


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Schedule B(3)















(PFAS) by LCMSMS

EP231X-ST WATER



Environmental





C/O GPO BOX 2907



QLD AUSTRALIA 4814


:: TelephoneTelephone +61 07 3368 6642 +61 7 4796 0600

:: FacsimileFacsimile +61 07 38314223 +61 7 4796 0620



V3)


Site : ----




Date

15-Mar-2018




General Comments






l Please be advised that the containers for ALS sample #5 to #12 are labelled with sampling date

as '04.03.18' instead of '03.03.18' as per the COC. The sampling date in the container was used and

assigned to the samples since there is another workorder submitted that is sampled on 3.3.18.

Please contact client services at [email protected] if this is incorrect.l Discounted Package Prices apply only when specific ALS Group Codes ('W', 'S', 'NT' suites) are referenced on COCs.

l EA045, EA015H, EA025H conducted by ALS Townsville, NATA accreditation no. 825, (Site no. 23313)



l Additional charges of $5.00 will apply to each sample requiring laboratory filtration.

l All remaining analysis will be conducted by ALS Environmental, Brisbane, NATA accreditation no. 825, Site No. 818.













ET1800572-012 : [ 04-Mar-2018 ] : 0874_QC5TB_180304_F - Filtered











component

WA

TE

R -

EA

01

5H

To

tal D

isso

lve

d S

olid

s -

Sta

nd

ard

Le

vel

WA

TE

R -

EA

02

5H

Su

spe

nd

ed

So

lids

- S

tand

ard

Le

vel

WA

TE

R -

EA

04

5

Tu

rbid

ity

WA

TE

R -

EP

23

1X

-ST

PF

AS

- S

up

er

Tra

ce W

ate

rs L

ong

Su

ite (

28

ET1800572-001 04-Mar-2018 00:00 0874_SW132_180304 ü ü ü ü

ET1800572-002 04-Mar-2018 00:00 0874_SW123_180304 ü ü ü ü

ET1800572-003 04-Mar-2018 00:00 0874_SW131_180304 ü ü ü ü

ET1800572-004 04-Mar-2018 00:00 0874_SW102_180304 ü ü ü ü

ET1800572-005 04-Mar-2018 00:00 0874_QC3R1_180304 ü

ET1800572-006 04-Mar-2018 00:00 0874_QC4FB_180304 ü

ET1800572-007 04-Mar-2018 00:00 0874_QC5TB_180304 ü

ET1800572-008 04-Mar-2018 00:00 0874_SW132_180304_F ... ü

ET1800572-009 04-Mar-2018 00:00 0874_SW123_180304_F ... ü

ET1800572-010 04-Mar-2018 00:00 0874_SW131_180304_F ... ü

ET1800572-011 04-Mar-2018 00:00 0874_SW102_180304_F ... ü

ET1800572-012 04-Mar-2018 00:00 0874_QC5TB_180304_F ... ü

Matrix: WATER


ID

Client sampling

date / time







AU ACCOUNTS PAYABLE


DAVID HARRIS








DERP LABREPORTS


KATIE MCPHERSON








PHIL SCHULZ








RESULTS RESULTS








0 0.00 True

Environmental





C/O GPO BOX 2907


14-15 Desma Ct, Bohle Townsville QLD AUSTRALIA 4814


:Project QLD_0874_PFAS Date Samples Received : 05-Mar-2018 12:25


:C-O-C number ---- Issue Date : 14-Mar-2018 14:27


Site : ----






l General Comments








Greg Vogel Townsville Inorganics, Townsville, QLD



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General Comments







purposes.







Key :

PFAS conducted by ALS Sydney, NATA accreditation no. 825, site no 10911.l

EP231: Poor matrix spike recovery due to matrix interference and the presence of high level contaminantsl

EA045, EA015H, EA025H conducted by ALS Townsville, NATA accreditation no. 825, (Site no. 23313)l

EP231: Particular samples required dilution due to the presence of high level contaminants. LOR values have been adjusted accordingly.l

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Analytical Results


(Matrix: WATER)





812 142 354 98 ----mg/L10----Total Dissolved Solids @180°C


<5 <5 <5 <5 ----mg/L5----Suspended Solids (SS)

EA045: Turbidity

1.4 3.9 6.6 1.8 ----NTU0.1----Turbidity



(PFBS)

0.489 0.106 0.0140 <0.0005µg/L0.0005375-73-5


(PFPeS)

0.409 0.0970 0.0130 <0.0005µg/L0.00052706-91-4


(PFHxS)

2.87 1.04 0.129 <0.0005µg/L0.0005355-46-4


(PFHpS)

0.346 0.0920 <0.0100 <0.0005µg/L0.0005375-92-8


(PFOS)

7.02 3.50 0.308 <0.0003µg/L0.00031763-23-1


(PFDS)

<0.0100 <0.0100 <0.0100 <0.0005µg/L0.0005335-77-3


0.899Perfluorobutanoic acid (PFBA) 0.148 0.078 <0.010 <0.002µg/L0.002375-22-4

1.07Perfluoropentanoic acid (PFPeA) 0.254 0.0750 <0.0100 <0.0005µg/L0.00052706-90-3

6.62Perfluorohexanoic acid (PFHxA) 1.21 0.439 0.0370 <0.0005µg/L0.0005307-24-4

1.08Perfluoroheptanoic acid (PFHpA) 0.109 0.0330 <0.0100 <0.0005µg/L0.0005375-85-9

2.69Perfluorooctanoic acid (PFOA) 0.307 0.111 <0.0100 <0.0005µg/L0.0005335-67-1

0.0490Perfluorononanoic acid (PFNA) <0.0100 <0.0100 <0.0100 <0.0005µg/L0.0005375-95-1



(PFUnDA)

<0.0100 <0.0100 <0.0100 <0.0005µg/L0.00052058-94-8


(PFDoDA)

<0.0100 <0.0100 <0.0100 <0.0005µg/L0.0005307-55-1


(PFTrDA)

<0.0100 <0.0100 <0.0100 <0.0005µg/L0.000572629-94-8


(PFTeDA)

<0.0250 <0.0250 <0.0250 <0.0005µg/L0.0005376-06-7


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Analytical Results


(Matrix: WATER)





0.0180Perfluorooctane sulfonamide

(FOSA)

<0.0100 <0.0100 <0.0100 <0.0005µg/L0.0005754-91-6



<0.025 <0.025 <0.025 <0.001µg/L0.00131506-32-8



<0.025 <0.025 <0.025 <0.001µg/L0.0014151-50-2



<0.025 <0.025 <0.025 <0.001µg/L0.00124448-09-7



<0.025 <0.025 <0.025 <0.001µg/L0.0011691-99-2



(MeFOSAA)

<0.0100 <0.0100 <0.0100 <0.0005µg/L0.00052355-31-9



(EtFOSAA)

<0.0100 <0.0100 <0.0100 <0.0005µg/L0.00052991-50-6



(4:2 FTS)

<0.010 <0.010 <0.010 <0.001µg/L0.001757124-72-4


(6:2 FTS)

<0.010 <0.010 <0.010 <0.001µg/L0.00127619-97-2


(8:2 FTS)

<0.010 <0.010 <0.010 <0.001µg/L0.00139108-34-4


(10:2 FTS)

<0.010 <0.010 <0.010 <0.001µg/L0.001120226-60-0

EP231P: PFAS Sums

56.8 13.2 5.57 0.501 <0.0003µg/L0.0003----Sum of PFAS

40.5Sum of PFHxS and PFOS 9.89 4.54 0.437 <0.0003µg/L0.0003355-46-4/1763-23-

1

54.3 12.4 5.38 0.488 <0.0003µg/L0.0003----Sum of PFAS (WA DER List)


103 102 103 99.3 71.8%0.0005----13C4-PFOS

92.5 102 113 107 101%0.0005----13C8-PFOA

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ET1800576



Analytical Results

0874_SW131_180303

_F

Filtered

0874_SW123_180303

_F

Filtered

0874_SW132_180303

_F

Filtered


(Matrix: WATER)






(PFBS)

<0.0005 1.63 0.544 0.101µg/L0.0005375-73-5


(PFPeS)

<0.0005 1.55 0.463 0.0930µg/L0.00052706-91-4


(PFHxS)

<0.0005 14.7 3.54 1.05µg/L0.0005355-46-4


(PFHpS)

<0.0005 1.05 0.376 0.0880µg/L0.0005375-92-8


(PFOS)

<0.0003 35.6 7.33 3.16µg/L0.00031763-23-1


(PFDS)

<0.0005 <0.0100 <0.0100 <0.0100µg/L0.0005335-77-3


<0.002Perfluorobutanoic acid (PFBA) <0.002 1.04 0.220 0.076µg/L0.002375-22-4





<0.0005Perfluorononanoic acid (PFNA) <0.0005 0.0630 <0.0100 <0.0100µg/L0.0005375-95-1



(PFUnDA)

<0.0005 <0.0100 <0.0100 <0.0100µg/L0.00052058-94-8


(PFDoDA)

<0.0005 <0.0100 <0.0100 <0.0100µg/L0.0005307-55-1


(PFTrDA)

<0.0005 <0.0100 <0.0100 <0.0100µg/L0.000572629-94-8


(PFTeDA)

<0.0005 <0.0250 <0.0250 <0.0250µg/L0.0005376-06-7



(FOSA)

<0.0005 <0.0100 0.0120 <0.0100µg/L0.0005754-91-6



<0.001 <0.025 <0.025 <0.025µg/L0.00131506-32-8

6 of 9:Page

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ET1800576



Analytical Results

0874_SW131_180303

_F

Filtered

0874_SW123_180303

_F

Filtered

0874_SW132_180303

_F

Filtered


(Matrix: WATER)







<0.001 <0.025 <0.025 <0.025µg/L0.0014151-50-2



<0.001 <0.025 <0.025 <0.025µg/L0.00124448-09-7



<0.001 <0.025 <0.025 <0.025µg/L0.0011691-99-2



(MeFOSAA)

<0.0005 <0.0100 <0.0100 <0.0100µg/L0.00052355-31-9



(EtFOSAA)

<0.0005 <0.0100 <0.0100 <0.0100µg/L0.00052991-50-6



(4:2 FTS)

<0.001 <0.010 <0.010 <0.010µg/L0.001757124-72-4


(6:2 FTS)

<0.001 0.092 <0.010 <0.010µg/L0.00127619-97-2


(8:2 FTS)

<0.001 0.016 <0.010 <0.010µg/L0.00139108-34-4


(10:2 FTS)

<0.001 <0.010 <0.010 <0.010µg/L0.001120226-60-0

EP231P: PFAS Sums

<0.0003 <0.0003 69.3 14.6 5.24µg/L0.0003----Sum of PFAS


1

<0.0003 <0.0003 66.7 13.8 5.06µg/L0.0003----Sum of PFAS (WA DER List)


83.3 79.7 99.5 76.7 105%0.0005----13C4-PFOS

108 108 116 97.8 87.9%0.0005----13C8-PFOA

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Analytical Results

------------0874_QC3R1_180303

_F

Filtered

0874_SW102_180303

_F

Filtered


(Matrix: WATER)






(PFBS)

0.0006 ---- ---- ----µg/L0.0005375-73-5


(PFPeS)

0.0006 ---- ---- ----µg/L0.00052706-91-4


(PFHxS)

0.0032 ---- ---- ----µg/L0.0005355-46-4


(PFHpS)

<0.0005 ---- ---- ----µg/L0.0005375-92-8


(PFOS)

0.0090 ---- ---- ----µg/L0.00031763-23-1


(PFDS)

<0.0005 ---- ---- ----µg/L0.0005335-77-3


<0.010Perfluorobutanoic acid (PFBA) <0.002 ---- ---- ----µg/L0.002375-22-4

<0.0100Perfluoropentanoic acid (PFPeA) <0.0005 ---- ---- ----µg/L0.00052706-90-3

0.0630Perfluorohexanoic acid (PFHxA) 0.0011 ---- ---- ----µg/L0.0005307-24-4

<0.0100Perfluoroheptanoic acid (PFHpA) <0.0005 ---- ---- ----µg/L0.0005375-85-9

0.0160Perfluorooctanoic acid (PFOA) 0.0006 ---- ---- ----µg/L0.0005335-67-1




(PFUnDA)

<0.0005 ---- ---- ----µg/L0.00052058-94-8


(PFDoDA)

<0.0005 ---- ---- ----µg/L0.0005307-55-1


(PFTrDA)

<0.0005 ---- ---- ----µg/L0.000572629-94-8


(PFTeDA)

<0.0005 ---- ---- ----µg/L0.0005376-06-7



(FOSA)

<0.0005 ---- ---- ----µg/L0.0005754-91-6



<0.001 ---- ---- ----µg/L0.00131506-32-8

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ET1800576



Analytical Results

------------0874_QC3R1_180303

_F

Filtered

0874_SW102_180303

_F

Filtered


(Matrix: WATER)







<0.001 ---- ---- ----µg/L0.0014151-50-2



<0.001 ---- ---- ----µg/L0.00124448-09-7



<0.001 ---- ---- ----µg/L0.0011691-99-2



(MeFOSAA)

<0.0005 ---- ---- ----µg/L0.00052355-31-9



(EtFOSAA)

<0.0005 ---- ---- ----µg/L0.00052991-50-6



(4:2 FTS)

<0.001 ---- ---- ----µg/L0.001757124-72-4


(6:2 FTS)

<0.001 ---- ---- ----µg/L0.00127619-97-2


(8:2 FTS)

<0.001 ---- ---- ----µg/L0.00139108-34-4


(10:2 FTS)

<0.001 ---- ---- ----µg/L0.001120226-60-0

EP231P: PFAS Sums

0.702 0.0151 ---- ---- ----µg/L0.0003----Sum of PFAS

0.574Sum of PFHxS and PFOS 0.0122 ---- ---- ----µg/L0.0003355-46-4/1763-23-

1

0.671 0.0145 ---- ---- ----µg/L0.0003----Sum of PFAS (WA DER List)


93.1 84.0 ---- ---- ----%0.0005----13C4-PFOS

109 118 ---- ---- ----%0.0005----13C8-PFOA

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ET1800576







13C4-PFOS ---- 60 120

13C8-PFOA ---- 60 120

False

3 3.00True

Environmental




:Address MOBIL

C/O GPO BOX 2907


Address : 14-15 Desma Ct, Bohle Townsville QLD AUSTRALIA 4814




:C-O-C number ---- Issue Date : 14-Mar-2018


Site : ----















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ET1800576



General Comments










Key :









EA015H: Total Dissolved Solids @180°C ---- 10 mg/L 298 302 1.33 0% - 20%Anonymous ET1800579-007


EA025H: Suspended Solids (SS) ---- 5 mg/L <5 <5 0.00 No Limit0874_SW132_180303 ET1800576-001

EA025H: Suspended Solids (SS) ---- 5 mg/L 118 120 1.68 0% - 20%Anonymous ET1800579-007


EA045: Turbidity ---- 0.1 NTU 538 553 2.75 0% - 20%Anonymous ET1800575-003




(PFOS)

1763-23-1 0.0003 µg/L 25.2 25.2 0.119 0% - 20%Anonymous ET1800563-001


(PFBS)

375-73-5 0.0005 µg/L 1.82 1.79 1.83 0% - 20%


(PFPeS)

2706-91-4 0.0005 µg/L 1.80 1.74 3.50 0% - 20%


(PFHxS)

355-46-4 0.0005 µg/L 14.5 14.4 0.693 0% - 20%


(PFHpS)

375-92-8 0.0005 µg/L 0.984 0.907 8.14 0% - 20%


(PFDS)

335-77-3 0.0005 µg/L <0.0100 <0.0100 0.00 No Limit


(PFOS)

1763-23-1 0.0003 µg/L 0.308 0.288 6.71 0% - 20%0874_SW102_180303 ET1800576-004


(PFBS)

375-73-5 0.0005 µg/L 0.0140 0.0130 7.41 No Limit

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(PFPeS)

2706-91-4 0.0005 µg/L 0.0130 0.0100 26.1 No Limit0874_SW102_180303 ET1800576-004


(PFHxS)

355-46-4 0.0005 µg/L 0.129 0.108 17.7 0% - 50%


(PFHpS)

375-92-8 0.0005 µg/L <0.0100 <0.0100 0.00 No Limit


(PFDS)

335-77-3 0.0005 µg/L <0.0100 <0.0100 0.00 No Limit


EP231X-ST: Perfluoropentanoic acid (PFPeA) 2706-90-3 0.0005 µg/L 1.27 1.21 4.93 0% - 20%Anonymous ET1800563-001










(PFTeDA)

376-06-7 0.0005 µg/L <0.0250 <0.0250 0.00 No Limit


EP231X-ST: Perfluoropentanoic acid (PFPeA) 2706-90-3 0.0005 µg/L <0.0100 <0.0100 0.00 No Limit0874_SW102_180303 ET1800576-004

EP231X-ST: Perfluorohexanoic acid (PFHxA) 307-24-4 0.0005 µg/L 0.0370 0.0440 17.3 No Limit


EP231X-ST: Perfluorooctanoic acid (PFOA) 335-67-1 0.0005 µg/L <0.0100 0.0100 0.00 No Limit







(PFTeDA)

376-06-7 0.0005 µg/L <0.0250 <0.0250 0.00 No Limit




(FOSA)




2355-31-9 0.0005 µg/L <0.0100 <0.0100 0.00 No Limit



2991-50-6 0.0005 µg/L <0.0100 <0.0100 0.00 No Limit

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(EtFOSA)

4151-50-2 0.001 µg/L <0.025 <0.025 0.00 No Limit



24448-09-7 0.001 µg/L <0.025 <0.025 0.00 No Limit



1691-99-2 0.001 µg/L <0.025 <0.025 0.00 No Limit


(FOSA)

754-91-6 0.0005 µg/L <0.0100 <0.0100 0.00 No Limit0874_SW102_180303 ET1800576-004



2355-31-9 0.0005 µg/L <0.0100 <0.0100 0.00 No Limit



2991-50-6 0.0005 µg/L <0.0100 <0.0100 0.00 No Limit



31506-32-8 0.001 µg/L <0.025 <0.025 0.00 No Limit


(EtFOSA)

4151-50-2 0.001 µg/L <0.025 <0.025 0.00 No Limit



24448-09-7 0.001 µg/L <0.025 <0.025 0.00 No Limit



1691-99-2 0.001 µg/L <0.025 <0.025 0.00 No Limit



FTS)



FTS)

27619-97-2 0.001 µg/L 0.076 0.057 28.6 No Limit


FTS)

39108-34-4 0.001 µg/L <0.010 <0.010 0.00 No Limit


(10:2 FTS)

120226-60-0 0.001 µg/L <0.010 <0.010 0.00 No Limit


FTS)

757124-72-4 0.001 µg/L <0.010 <0.010 0.00 No Limit0874_SW102_180303 ET1800576-004


FTS)

27619-97-2 0.001 µg/L <0.010 <0.010 0.00 No Limit


FTS)

39108-34-4 0.001 µg/L <0.010 <0.010 0.00 No Limit


(10:2 FTS)

120226-60-0 0.001 µg/L <0.010 <0.010 0.00 No Limit



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EP231P: PFAS Sums (QC Lot: 1478848) - continued


6 of 8:Page

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ET1800576








Report





EA015H: Total Dissolved Solids @180°C ---- 10 mg/L <10 92.2293 mg/L 11288

<10 97.82000 mg/L 11288



<5 99.01000 mg/L 12083



<0.1 99.040 NTU 10595

<0.1 100400 NTU 10397























(MeFOSA)

31506-32-8 0.001 µg/L <0.001 95.80.025 µg/L 13040


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Report






(MeFOSE)

24448-09-7 0.001 µg/L <0.001 81.40.025 µg/L 13040


(EtFOSE)

1691-99-2 0.001 µg/L <0.001 89.60.025 µg/L 13040


acid (MeFOSAA)

2355-31-9 0.0005 µg/L <0.0005 87.40.01 µg/L 13040


acid (EtFOSAA)

2991-50-6 0.0005 µg/L <0.0005 1080.01 µg/L 13040














Anonymous ET1800563-002 375-73-5EP231X-ST: Perfluorobutane sulfonic acid (PFBS) # Not

Determined

0.01 µg/L 13050


Determined

0.01 µg/L 13050


Determined

0.01 µg/L 13050


Determined

0.01 µg/L 13050


Determined

0.01 µg/L 13050



Anonymous ET1800563-002 375-22-4EP231X-ST: Perfluorobutanoic acid (PFBA) # Not

Determined

0.05 µg/L 13030

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ET1800576







Anonymous ET1800563-002 2706-90-3EP231X-ST: Perfluoropentanoic acid (PFPeA) # Not

Determined

0.01 µg/L 13050


Determined

0.01 µg/L 13050


Determined

0.01 µg/L 13050


Determined

0.01 µg/L 13050


Determined

0.01 µg/L 13050







Anonymous ET1800563-002 754-91-6EP231X-ST: Perfluorooctane sulfonamide (FOSA) # Not

Determined

0.01 µg/L 13030


(MeFOSA)

30.70.025 µg/L 13030


(EtFOSA)

33.60.025 µg/L 13030



# 25.00.025 µg/L 13030



34.60.025 µg/L 13030



45.00.01 µg/L 13030


acid (EtFOSAA)

52.00.01 µg/L 13030


Anonymous ET1800563-002 757124-72-4EP231X-ST: 4:2 Fluorotelomer sulfonic acid (4:2 FTS) 57.80.01 µg/L 13050


39108-34-4EP231X-ST: 8:2 Fluorotelomer sulfonic acid (8:2 FTS) # 18.40.01 µg/L 13050


True

Environmental












Summary of Outliers













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:Client

ET1800576





Matrix: WATER








----Not

Determined



sulfonic acid

(PFPeS)




----Not

Determined



sulfonic acid

(PFHxS)




----Not

Determined



sulfonic acid

(PFHpS)




----Not

Determined







----Not

Determined



(PFBA)




----Not

Determined



acid (PFPeA)




----Not

Determined



(PFHxA)




----Not

Determined



acid (PFHpA)




----Not

Determined



(PFOA)




----Not

Determined


ET1800563--002 24448-09-7N-Methyl

perfluorooctane

sulfonamidoethanol

(MeFOSE)


objective



sulfonic acid (8:2

FTS)


objective



Matrix: WATER

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ET1800576



Matrix: WATER



overdue

Days

overdue


Method

EA045: Turbidity


05-Mar-2018----0874_SW132_180303, 0874_SW123_180303,

0874_SW131_180303, 0874_SW102_180303

06-Mar-2018---- ---- 1














0874_SW132_180303, 0874_SW123_180303,

0874_SW131_180303, 0874_SW102_180303

10-Mar-2018---- 07-Mar-2018----03-Mar-2018 ---- ü



0874_SW132_180303, 0874_SW123_180303,

0874_SW131_180303, 0874_SW102_180303

10-Mar-2018---- 07-Mar-2018----03-Mar-2018 ---- ü

EA045: Turbidity


0874_SW132_180303, 0874_SW123_180303,

0874_SW131_180303, 0874_SW102_180303

05-Mar-2018---- 06-Mar-2018----03-Mar-2018 ---- û



0874_SW132_180303, 0874_SW123_180303,

0874_SW131_180303, 0874_SW102_180303,

0874_QC3R1_180303, 0874_QC4FB_180303,



0874_SW102_180303_F - Filtered, 0874_QC3R1_180303_F - Filtered


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ET1800576








0874_SW132_180303, 0874_SW123_180303,

0874_SW131_180303, 0874_SW102_180303,

0874_QC3R1_180303, 0874_QC4FB_180303,







0874_SW132_180303, 0874_SW123_180303,

0874_SW131_180303, 0874_SW102_180303,

0874_QC3R1_180303, 0874_QC4FB_180303,







0874_SW132_180303, 0874_SW123_180303,

0874_SW131_180303, 0874_SW102_180303,

0874_QC3R1_180303, 0874_QC4FB_180303,





EP231P: PFAS Sums


0874_SW132_180303, 0874_SW123_180303,

0874_SW131_180303, 0874_SW102_180303,

0874_QC3R1_180303, 0874_QC4FB_180303,





5 of 6:Page

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ET1800576



















Method Blanks (MB)





Matrix Spikes (MS)


6 of 6:Page

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:Client

ET1800576










Schedule B(3)















(PFAS) by LCMSMS

EP231X-ST WATER



Environmental





C/O GPO BOX 2907



QLD AUSTRALIA 4814



:: FacsimileFacsimile +61 07 38314223 +61 7 4796 0620



V3)


Site : ----




Date

15-Mar-2018




General Comments






l Please be advised that an extra sample "0874_QC3R1_180303_F" was received in addition to the

samples listed on the COC. This sample has been added to the end of the work order, filtered and

assigned EP231X-ST analysis. Please contact client services at

[email protected] if this is incorrect.l Please be advised that sample "0874_QC5TB_180303_F" was not received at the laboratory

(denoted SNR on the scanned COC).l Discounted Package Prices apply only when specific ALS Group Codes ('W', 'S', 'NT' suites) are referenced on COCs.

l EA045, EA015H, EA025H conducted by ALS Townsville, NATA accreditation no. 825, (Site no. 23313)



l Additional charges of $5.00 will apply to each sample requiring laboratory filtration.l All remaining analysis will be conducted by ALS Environmental, Brisbane, NATA accreditation no. 825, Site No. 818.













ET1800576-012 : [ 03-Mar-2018 ] : 0874_QC3R1_180303_F - Filtered











component

WA

TE

R -

EA

01

5H

To

tal D

isso

lve

d S

olid

s -

Sta

nd

ard

Le

vel

WA

TE

R -

EA

02

5H

Su

spe

nd

ed

So

lids

- S

tand

ard

Le

vel

WA

TE

R -

EA

04

5

Tu

rbid

ity

WA

TE

R -

EP

23

1X

-ST

PF

AS

- S

up

er

Tra

ce W

ate

rs L

ong

Su

ite (

28

ET1800576-001 03-Mar-2018 00:00 0874_SW132_180303 ü ü ü ü

ET1800576-002 03-Mar-2018 00:00 0874_SW123_180303 ü ü ü ü

ET1800576-003 03-Mar-2018 00:00 0874_SW131_180303 ü ü ü ü

ET1800576-004 03-Mar-2018 00:00 0874_SW102_180303 ü ü ü ü

ET1800576-005 03-Mar-2018 00:00 0874_QC3R1_180303 ü

ET1800576-006 03-Mar-2018 00:00 0874_QC4FB_180303 ü

ET1800576-007 03-Mar-2018 00:00 0874_QC5TB_180303 ü

ET1800576-008 03-Mar-2018 00:00 0874_SW132_180303_F ... ü

ET1800576-009 03-Mar-2018 00:00 0874_SW123_180303_F ... ü

ET1800576-010 03-Mar-2018 00:00 0874_SW131_180303_F ... ü

ET1800576-011 03-Mar-2018 00:00 0874_SW102_180303_F ... ü

ET1800576-012 03-Mar-2018 00:00 0874_QC3R1_180303_F ... ü

Matrix: WATER


ID

Client sampling

date / time







ACCOUNTS PAYABLE


AU ACCOUNTS PAYABLE


DAVID HARRIS








DERP LABREPORTS


KATIE MCPHERSON








PHIL SCHULZ








RESULTS RESULTS








0 0.00 True

Environmental





C/O GPO BOX 2907


13 Carlton Street, Kirwan Townsville QLD AUSTRALIA 4814


:Project QLD_0874_PFAS Date Samples Received : 11-Apr-2018 08:50

:Order number PS102571 - 102 Date Analysis Commenced : 11-Apr-2018

:C-O-C number ---- Issue Date : 19-Apr-2018 09:30

Sampler : Andi Carnall

Site : ----






l General Comments








Andrew Epps Townsville Inorganics, Townsville, QLD

Andrew Epps Senior Inorganic Chemist Brisbane Inorganics, Stafford, QLD



Kim McCabe Senior Inorganic Chemist Brisbane Inorganics, Stafford, QLD


2 of 17:Page

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:Client

ET1800983



General Comments







purposes.







Key :

EP231X, EP231X-ST, EP231X(TOP) conducted by ALS Sydney, NATA accreditation no. 825, site no 10911.l

ED037-P, ED041G, ED045G conducted by ALS Townsville, NATA accreditation no. 825, (Site no. 23313)l

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Analytical Results

0874_SW118_1804100874_SW114_1804100874_SW208_1804100874_SW210_1804100874_SW108_180410Client sample IDSub-Matrix: WATER

(Matrix: WATER)

10-Apr-2018 00:0010-Apr-2018 00:0010-Apr-2018 00:0010-Apr-2018 00:0010-Apr-2018 00:00Client sampling date / time




<1Hydroxide Alkalinity as CaCO3 <1 <1 <1 <1mg/L1DMO-210-001

29Carbonate Alkalinity as CaCO3 <1 <1 <1 <1mg/L13812-32-6

113Bicarbonate Alkalinity as CaCO3 145 130 305 84mg/L171-52-3

142 145 130 305 84mg/L1----Total Alkalinity as CaCO3


558Sulfate as SO4 - Turbidimetric 1590 977 290 17mg/L114808-79-8


5160Chloride 12200 7460 3410 320mg/L116887-00-6


151Calcium 323 185 68 15mg/L17440-70-2

351Magnesium 957 521 193 21mg/L17439-95-4

2960Sodium 8320 4260 2010 200mg/L17440-23-5

98Potassium 286 156 75 4mg/L17440-09-7

EN055: Ionic Balance

160 380 233 108 11.0meq/L0.01----Total Anions

168 464 241 109 11.3meq/L0.01----Total Cations

2.34 9.94 1.69 0.14 0.98%0.01----Ionic Balance



(PFBS)

0.0085 0.0428 0.0292 ----µg/L0.0005375-73-5

----Perfluorobutane sulfonic acid

(PFBS)

---- ---- ---- 0.55µg/L0.02375-73-5


(PFPeS)

0.0053 0.0367 0.0067 ----µg/L0.00052706-91-4

----Perfluoropentane sulfonic acid

(PFPeS)

---- ---- ---- 0.52µg/L0.022706-91-4


(PFHxS)

0.0383 0.191 0.0551 ----µg/L0.0005355-46-4

----Perfluorohexane sulfonic acid

(PFHxS)

---- ---- ---- 6.14µg/L0.02355-46-4


(PFHpS)

0.0012 0.0128 0.0038 ----µg/L0.0005375-92-8

----Perfluoroheptane sulfonic acid

(PFHpS)

---- ---- ---- 0.22µg/L0.02375-92-8

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ET1800983



Analytical Results


(Matrix: WATER)




EP231A: Perfluoroalkyl Sulfonic Acids - Continued


(PFOS)

0.0381 0.368 0.215 ----µg/L0.00031763-23-1


(PFDS)

<0.0005 <0.0005 <0.0005 ----µg/L0.0005335-77-3

----Perfluorooctane sulfonic acid

(PFOS)

---- ---- ---- 7.04µg/L0.011763-23-1

----Perfluorodecane sulfonic acid

(PFDS)

---- ---- ---- <0.02µg/L0.02335-77-3


<0.002Perfluorobutanoic acid (PFBA) <0.002 <0.002 <0.002 ----µg/L0.002375-22-4

----Perfluorobutanoic acid (PFBA) ---- ---- ---- <0.1µg/L0.1375-22-4

0.0117Perfluoropentanoic acid (PFPeA) 0.0036 0.0171 0.0084 ----µg/L0.00052706-90-3

----Perfluoropentanoic acid (PFPeA) ---- ---- ---- 0.30µg/L0.022706-90-3

0.0520Perfluorohexanoic acid (PFHxA) 0.0081 0.0681 0.0110 ----µg/L0.0005307-24-4

----Perfluorohexanoic acid (PFHxA) ---- ---- ---- 1.37µg/L0.02307-24-4

0.0058Perfluoroheptanoic acid (PFHpA) 0.0023 0.0148 0.0051 ----µg/L0.0005375-85-9

----Perfluoroheptanoic acid (PFHpA) ---- ---- ---- 0.32µg/L0.02375-85-9

0.0097Perfluorooctanoic acid (PFOA) 0.0028 0.0270 0.0123 ----µg/L0.0005335-67-1

----Perfluorooctanoic acid (PFOA) ---- ---- ---- 0.50µg/L0.01335-67-1

<0.0005Perfluorononanoic acid (PFNA) <0.0005 0.0013 0.0016 ----µg/L0.0005375-95-1

----Perfluorononanoic acid (PFNA) ---- ---- ---- <0.02µg/L0.02375-95-1

<0.0005Perfluorodecanoic acid (PFDA) <0.0005 <0.0005 0.0009 ----µg/L0.0005335-76-2

----Perfluorodecanoic acid (PFDA) ---- ---- ---- <0.02µg/L0.02335-76-2


(PFUnDA)

<0.0005 <0.0005 <0.0005 ----µg/L0.00052058-94-8

----Perfluoroundecanoic acid

(PFUnDA)

---- ---- ---- <0.02µg/L0.022058-94-8


(PFDoDA)

<0.0005 <0.0005 <0.0005 ----µg/L0.0005307-55-1

----Perfluorododecanoic acid

(PFDoDA)

---- ---- ---- <0.02µg/L0.02307-55-1


(PFTrDA)

<0.0005 <0.0005 <0.0005 ----µg/L0.000572629-94-8

----Perfluorotridecanoic acid

(PFTrDA)

---- ---- ---- <0.02µg/L0.0272629-94-8

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ET1800983



Analytical Results


(Matrix: WATER)




EP231B: Perfluoroalkyl Carboxylic Acids - Continued


(PFTeDA)

<0.0005 <0.0005 <0.0005 ----µg/L0.0005376-06-7

----Perfluorotetradecanoic acid

(PFTeDA)

---- ---- ---- <0.05µg/L0.05376-06-7



(FOSA)

<0.0005 <0.0005 <0.0005 ----µg/L0.0005754-91-6

----Perfluorooctane sulfonamide

(FOSA)

---- ---- ---- <0.02µg/L0.02754-91-6



<0.001 <0.001 <0.001 ----µg/L0.00131506-32-8

----N-Methyl perfluorooctane


---- ---- ---- <0.05µg/L0.0531506-32-8



<0.001 <0.001 <0.001 ----µg/L0.0014151-50-2

----N-Ethyl perfluorooctane


---- ---- ---- <0.05µg/L0.054151-50-2



<0.001 <0.001 <0.001 ----µg/L0.00124448-09-7



---- ---- ---- <0.05µg/L0.0524448-09-7



<0.001 <0.001 <0.001 ----µg/L0.0011691-99-2



---- ---- ---- <0.05µg/L0.051691-99-2



(MeFOSAA)

<0.0005 <0.0005 <0.0005 ----µg/L0.00052355-31-9



(MeFOSAA)

---- ---- ---- <0.02µg/L0.022355-31-9



(EtFOSAA)

<0.0005 <0.0005 <0.0005 ----µg/L0.00052991-50-6

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ET1800983



Analytical Results


(Matrix: WATER)







(EtFOSAA)

---- ---- ---- <0.02µg/L0.022991-50-6



(4:2 FTS)

<0.001 <0.001 <0.001 ----µg/L0.001757124-72-4

----4:2 Fluorotelomer sulfonic acid

(4:2 FTS)

---- ---- ---- <0.05µg/L0.05757124-72-4


(6:2 FTS)

<0.001 <0.001 <0.001 ----µg/L0.00127619-97-2


(6:2 FTS)

---- ---- ---- <0.05µg/L0.0527619-97-2


(8:2 FTS)

<0.001 <0.001 <0.001 ----µg/L0.00139108-34-4


(8:2 FTS)

---- ---- ---- <0.05µg/L0.0539108-34-4


(10:2 FTS)

<0.001 <0.001 <0.001 ----µg/L0.001120226-60-0


(10:2 FTS)

---- ---- ---- <0.05µg/L0.05120226-60-0

EP231P: PFAS Sums

0.500 0.108 0.780 0.349 ----µg/L0.0003----Sum of PFAS

---- ---- ---- ---- 17.0µg/L0.01----Sum of PFAS

0.335Sum of PFHxS and PFOS 0.0764 0.559 0.270 ----µg/L0.0003355-46-4/1763-23-

1

----Sum of PFHxS and PFOS ---- ---- ---- 13.2µg/L0.01355-46-4/1763-23-

1

0.457 0.102 0.729 0.336 ----µg/L0.0003----Sum of PFAS (WA DER List)

---- ---- ---- ---- 16.2µg/L0.01----Sum of PFAS (WA DER List)


80.9 69.2 79.9 80.6 ----%0.0005----13C4-PFOS

---- ---- ---- ---- 97.4%0.02----13C4-PFOS

104 112 119 98.7 ----%0.0005----13C8-PFOA

---- ---- ---- ---- 122%0.02----13C8-PFOA

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ET1800983



Analytical Results

0874_QC1SW_1804100874_SW113_1804100874_SW115_1804100874_SW116_1804100874_SW130_180410Client sample IDSub-Matrix: WATER

(Matrix: WATER)





<1Hydroxide Alkalinity as CaCO3 <1 <1 <1 ----mg/L1DMO-210-001

<1Carbonate Alkalinity as CaCO3 <1 <1 <1 ----mg/L13812-32-6

88Bicarbonate Alkalinity as CaCO3 102 79 157 ----mg/L171-52-3

88 102 79 157 ----mg/L1----Total Alkalinity as CaCO3


11Sulfate as SO4 - Turbidimetric 411 32 8 ----mg/L114808-79-8


26Chloride 3230 236 314 ----mg/L116887-00-6


22Calcium 91 24 32 ----mg/L17440-70-2

4Magnesium 220 18 17 ----mg/L17439-95-4

30Sodium 1830 141 207 ----mg/L17440-23-5

2Potassium 69 6 2 ----mg/L17440-09-7


2.72 102 8.90 12.2 ----meq/L0.01----Total Anions

2.78 104 8.96 12.0 ----meq/L0.01----Total Cations

---- 1.12 0.36 0.45 ----%0.01----Ionic Balance

EP231_TOP_A: Perfluoroalkyl Sulfonic Acids


(PFBS)

---- ---- ---- ----µg/L0.02375-73-5


(PFPeS)

---- ---- ---- ----µg/L0.022706-91-4


(PFHxS)

---- ---- ---- ----µg/L0.02355-46-4


(PFHpS)

---- ---- ---- ----µg/L0.02375-92-8


(PFOS)

---- ---- ---- ----µg/L0.011763-23-1


(PFDS)

---- ---- ---- ----µg/L0.02335-77-3

EP231_TOP_B: Perfluoroalkyl Carboxylic Acids

<0.1Perfluorobutanoic acid (PFBA) ---- ---- ---- ----µg/L0.1375-22-4

<0.02Perfluoropentanoic acid (PFPeA) ---- ---- ---- ----µg/L0.022706-90-3

<0.02Perfluorohexanoic acid (PFHxA) ---- ---- ---- ----µg/L0.02307-24-4

<0.02Perfluoroheptanoic acid (PFHpA) ---- ---- ---- ----µg/L0.02375-85-9

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ET1800983



Analytical Results


(Matrix: WATER)




EP231_TOP_B: Perfluoroalkyl Carboxylic Acids - Continued

<0.01Perfluorooctanoic acid (PFOA) ---- ---- ---- ----µg/L0.01335-67-1

<0.02Perfluorononanoic acid (PFNA) ---- ---- ---- ----µg/L0.02375-95-1

<0.02Perfluorodecanoic acid (PFDA) ---- ---- ---- ----µg/L0.02335-76-2


(PFUnDA)

---- ---- ---- ----µg/L0.022058-94-8


(PFDoDA)

---- ---- ---- ----µg/L0.02307-55-1


(PFTrDA)

---- ---- ---- ----µg/L0.0272629-94-8


(PFTeDA)

---- ---- ---- ----µg/L0.05376-06-7

EP231_TOP_C: Perfluoroalkyl Sulfonamides


(FOSA)

---- ---- ---- ----µg/L0.02754-91-6



---- ---- ---- ----µg/L0.0531506-32-8



---- ---- ---- ----µg/L0.054151-50-2



---- ---- ---- ----µg/L0.0524448-09-7



---- ---- ---- ----µg/L0.051691-99-2



(MeFOSAA)

---- ---- ---- ----µg/L0.022355-31-9



(EtFOSAA)

---- ---- ---- ----µg/L0.022991-50-6

EP231_TOP_D: (n:2) Fluorotelomer Sulfonic Acids


(4:2 FTS)

---- ---- ---- ----µg/L0.05757124-72-4


(6:2 FTS)

---- ---- ---- ----µg/L0.0527619-97-2


(8:2 FTS)

---- ---- ---- ----µg/L0.0539108-34-4

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ET1800983



Analytical Results


(Matrix: WATER)




EP231_TOP_D: (n:2) Fluorotelomer Sulfonic Acids - Continued


(10:2 FTS)

---- ---- ---- ----µg/L0.05120226-60-0

EP231_TOP_P: PFAS Sums

0.03 ---- ---- ---- ----µg/L0.01----Sum of PFAS

0.03Sum of PFHxS and PFOS ---- ---- ---- ----µg/L0.01355-46-4/1763-23-

1

0.03 ---- ---- ---- ----µg/L0.01----Sum of TOP C4 - C14 Carboxylates and C4

- C8 Sulfonates

0.02^ ---- ---- ---- ----µg/L0.01----Sum of TOP C4 - C14 as Fluorine



(PFBS)

0.0747 0.125 ---- 0.0282µg/L0.0005375-73-5


(PFBS)

---- ---- 0.47 ----µg/L0.02375-73-5


(PFPeS)

0.0696 0.150 ---- 0.0047µg/L0.00052706-91-4


(PFPeS)

---- ---- 0.45 ----µg/L0.022706-91-4


(PFHxS)

0.383 0.784 ---- 0.0458µg/L0.0005355-46-4


(PFHxS)

---- ---- 5.33 ----µg/L0.02355-46-4


(PFHpS)

0.0203 0.0501 ---- 0.0037µg/L0.0005375-92-8


(PFHpS)

---- ---- 0.14 ----µg/L0.02375-92-8


(PFOS)

0.489 1.06 ---- 0.161µg/L0.00031763-23-1


(PFDS)

<0.0005 <0.0005 ---- <0.0005µg/L0.0005335-77-3


(PFOS)

---- ---- 3.08 ----µg/L0.011763-23-1


(PFDS)

---- ---- <0.02 ----µg/L0.02335-77-3


----Perfluorobutanoic acid (PFBA) <0.002 <0.002 ---- <0.002µg/L0.002375-22-4

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Analytical Results


(Matrix: WATER)





<0.1Perfluorobutanoic acid (PFBA) ---- ---- <0.1 ----µg/L0.1375-22-4

----Perfluoropentanoic acid (PFPeA) 0.0317 0.0639 ---- 0.0068µg/L0.00052706-90-3

<0.02Perfluoropentanoic acid (PFPeA) ---- ---- 0.20 ----µg/L0.022706-90-3

----Perfluorohexanoic acid (PFHxA) 0.127 0.276 ---- 0.0096µg/L0.0005307-24-4

<0.02Perfluorohexanoic acid (PFHxA) ---- ---- 0.96 ----µg/L0.02307-24-4

----Perfluoroheptanoic acid (PFHpA) 0.0265 0.0526 ---- 0.0052µg/L0.0005375-85-9

<0.02Perfluoroheptanoic acid (PFHpA) ---- ---- 0.18 ----µg/L0.02375-85-9

----Perfluorooctanoic acid (PFOA) 0.0448 0.0908 ---- 0.0105µg/L0.0005335-67-1

<0.01Perfluorooctanoic acid (PFOA) ---- ---- 0.25 ----µg/L0.01335-67-1

----Perfluorononanoic acid (PFNA) 0.0020 0.0026 ---- 0.0015µg/L0.0005375-95-1

<0.02Perfluorononanoic acid (PFNA) ---- ---- <0.02 ----µg/L0.02375-95-1

----Perfluorodecanoic acid (PFDA) <0.0005 <0.0005 ---- 0.0008µg/L0.0005335-76-2

<0.02Perfluorodecanoic acid (PFDA) ---- ---- <0.02 ----µg/L0.02335-76-2


(PFUnDA)

<0.0005 <0.0005 ---- <0.0005µg/L0.00052058-94-8


(PFUnDA)

---- ---- <0.02 ----µg/L0.022058-94-8


(PFDoDA)

<0.0005 <0.0005 ---- <0.0005µg/L0.0005307-55-1


(PFDoDA)

---- ---- <0.02 ----µg/L0.02307-55-1


(PFTrDA)

<0.0005 <0.0005 ---- <0.0005µg/L0.000572629-94-8


(PFTrDA)

---- ---- <0.02 ----µg/L0.0272629-94-8


(PFTeDA)

<0.0005 <0.0005 ---- <0.0005µg/L0.0005376-06-7


(PFTeDA)

---- ---- <0.05 ----µg/L0.05376-06-7



(FOSA)

<0.0005 <0.0005 ---- <0.0005µg/L0.0005754-91-6


(FOSA)

---- ---- <0.02 ----µg/L0.02754-91-6



<0.001 <0.001 ---- <0.001µg/L0.00131506-32-8

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Analytical Results


(Matrix: WATER)







---- ---- <0.05 ----µg/L0.0531506-32-8



<0.001 <0.001 ---- <0.001µg/L0.0014151-50-2



---- ---- <0.05 ----µg/L0.054151-50-2



<0.001 <0.001 ---- <0.001µg/L0.00124448-09-7



---- ---- <0.05 ----µg/L0.0524448-09-7



<0.001 <0.001 ---- <0.001µg/L0.0011691-99-2



---- ---- <0.05 ----µg/L0.051691-99-2



(MeFOSAA)

<0.0005 <0.0005 ---- <0.0005µg/L0.00052355-31-9



(MeFOSAA)

---- ---- <0.02 ----µg/L0.022355-31-9



(EtFOSAA)

<0.0005 <0.0005 ---- <0.0005µg/L0.00052991-50-6



(EtFOSAA)

---- ---- <0.02 ----µg/L0.022991-50-6



(4:2 FTS)

<0.001 <0.001 ---- <0.001µg/L0.001757124-72-4


(4:2 FTS)

---- ---- <0.05 ----µg/L0.05757124-72-4


(6:2 FTS)

0.001 0.004 ---- <0.001µg/L0.00127619-97-2


(6:2 FTS)

---- ---- <0.05 ----µg/L0.0527619-97-2

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ET1800983



Analytical Results


(Matrix: WATER)




EP231D: (n:2) Fluorotelomer Sulfonic Acids - Continued


(8:2 FTS)

<0.001 <0.001 ---- <0.001µg/L0.00139108-34-4


(8:2 FTS)

---- ---- <0.05 ----µg/L0.0539108-34-4


(10:2 FTS)

<0.001 <0.001 ---- <0.001µg/L0.001120226-60-0


(10:2 FTS)

---- ---- <0.05 ----µg/L0.05120226-60-0

EP231P: PFAS Sums

---- 1.27 2.66 ---- 0.278µg/L0.0003----Sum of PFAS

0.06 ---- ---- 11.1 ----µg/L0.01----Sum of PFAS

----Sum of PFHxS and PFOS 0.872 1.84 ---- 0.207µg/L0.0003355-46-4/1763-23-

1

0.06Sum of PFHxS and PFOS ---- ---- 8.41 ----µg/L0.01355-46-4/1763-23-

1

---- 1.18 2.46 ---- 0.267µg/L0.0003----Sum of PFAS (WA DER List)

0.06 ---- ---- 10.5 ----µg/L0.01----Sum of PFAS (WA DER List)

EP231_TOP_S: PFAS Surrogate

126 ---- ---- ---- ----%0.02----13C4-PFOS

120 ---- ---- ---- ----%0.02----13C8-PFOA


---- 86.5 81.5 ---- 77.2%0.0005----13C4-PFOS

90.8 ---- ---- 91.5 ----%0.02----13C4-PFOS

---- 98.5 113 ---- 100%0.0005----13C8-PFOA

117 ---- ---- 112 ----%0.02----13C8-PFOA

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ET1800983



Analytical Results

----0874_SW109_1804100874_QC5SW_180410

_02

0874_QC5SW_180410

_01

0874_QC3SW_180410Client sample IDSub-Matrix: WATER

(Matrix: WATER)

----10-Apr-2018 00:0010-Apr-2018 00:0010-Apr-2018 00:0010-Apr-2018 00:00Client sampling date / time

--------ET1800983-014ET1800983-013ET1800983-012ET1800983-011UnitLORCAS NumberCompound

Result Result Result Result ----


----Hydroxide Alkalinity as CaCO3 ---- ---- <1 ----mg/L1DMO-210-001

----Carbonate Alkalinity as CaCO3 ---- ---- <1 ----mg/L13812-32-6

----Bicarbonate Alkalinity as CaCO3 ---- ---- 119 ----mg/L171-52-3

---- ---- ---- 119 ----mg/L1----Total Alkalinity as CaCO3


----Sulfate as SO4 - Turbidimetric ---- ---- 1550 ----mg/L114808-79-8


----Chloride ---- ---- 10500 ----mg/L116887-00-6


----Calcium ---- ---- 321 ----mg/L17440-70-2

----Magnesium ---- ---- 877 ----mg/L17439-95-4

----Sodium ---- ---- 6940 ----mg/L17440-23-5

----Potassium ---- ---- 275 ----mg/L17440-09-7


---- ---- ---- 331 ----meq/L0.01----Total Anions

---- ---- ---- 397 ----meq/L0.01----Total Cations

---- ---- ---- 9.10 ----%0.01----Ionic Balance



(PFBS)

---- ---- 0.0200 ----µg/L0.0005375-73-5


(PFBS)

<0.02 <0.02 ---- ----µg/L0.02375-73-5


(PFPeS)

---- ---- 0.0182 ----µg/L0.00052706-91-4


(PFPeS)

<0.02 <0.02 ---- ----µg/L0.022706-91-4


(PFHxS)

---- ---- 0.118 ----µg/L0.0005355-46-4


(PFHxS)

<0.02 <0.02 ---- ----µg/L0.02355-46-4


(PFHpS)

---- ---- 0.0056 ----µg/L0.0005375-92-8


(PFHpS)

<0.02 <0.02 ---- ----µg/L0.02375-92-8

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Analytical Results

----0874_SW109_1804100874_QC5SW_180410

_02

0874_QC5SW_180410

_01


(Matrix: WATER)






(PFOS)

---- ---- 0.157 ----µg/L0.00031763-23-1


(PFDS)

---- ---- <0.0005 ----µg/L0.0005335-77-3


(PFOS)

<0.01 <0.01 ---- ----µg/L0.011763-23-1


(PFDS)

<0.02 <0.02 ---- ----µg/L0.02335-77-3


----Perfluorobutanoic acid (PFBA) ---- ---- <0.002 ----µg/L0.002375-22-4

<0.1Perfluorobutanoic acid (PFBA) <0.1 <0.1 ---- ----µg/L0.1375-22-4

----Perfluoropentanoic acid (PFPeA) ---- ---- 0.0084 ----µg/L0.00052706-90-3

<0.02Perfluoropentanoic acid (PFPeA) <0.02 <0.02 ---- ----µg/L0.022706-90-3

----Perfluorohexanoic acid (PFHxA) ---- ---- 0.0332 ----µg/L0.0005307-24-4

<0.02Perfluorohexanoic acid (PFHxA) <0.02 <0.02 ---- ----µg/L0.02307-24-4

----Perfluoroheptanoic acid (PFHpA) ---- ---- 0.0081 ----µg/L0.0005375-85-9

<0.02Perfluoroheptanoic acid (PFHpA) <0.02 <0.02 ---- ----µg/L0.02375-85-9

----Perfluorooctanoic acid (PFOA) ---- ---- 0.0149 ----µg/L0.0005335-67-1

<0.01Perfluorooctanoic acid (PFOA) <0.01 <0.01 ---- ----µg/L0.01335-67-1

----Perfluorononanoic acid (PFNA) ---- ---- 0.0005 ----µg/L0.0005375-95-1

<0.02Perfluorononanoic acid (PFNA) <0.02 <0.02 ---- ----µg/L0.02375-95-1

----Perfluorodecanoic acid (PFDA) ---- ---- <0.0005 ----µg/L0.0005335-76-2

<0.02Perfluorodecanoic acid (PFDA) <0.02 <0.02 ---- ----µg/L0.02335-76-2


(PFUnDA)

---- ---- <0.0005 ----µg/L0.00052058-94-8


(PFUnDA)

<0.02 <0.02 ---- ----µg/L0.022058-94-8


(PFDoDA)

---- ---- <0.0005 ----µg/L0.0005307-55-1


(PFDoDA)

<0.02 <0.02 ---- ----µg/L0.02307-55-1


(PFTrDA)

---- ---- <0.0005 ----µg/L0.000572629-94-8


(PFTrDA)

<0.02 <0.02 ---- ----µg/L0.0272629-94-8

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ET1800983



Analytical Results

----0874_SW109_1804100874_QC5SW_180410

_02

0874_QC5SW_180410

_01


(Matrix: WATER)






(PFTeDA)

---- ---- <0.0005 ----µg/L0.0005376-06-7


(PFTeDA)

<0.05 <0.05 ---- ----µg/L0.05376-06-7



(FOSA)

---- ---- <0.0005 ----µg/L0.0005754-91-6


(FOSA)

<0.02 <0.02 ---- ----µg/L0.02754-91-6



---- ---- <0.001 ----µg/L0.00131506-32-8



<0.05 <0.05 ---- ----µg/L0.0531506-32-8



---- ---- <0.001 ----µg/L0.0014151-50-2



<0.05 <0.05 ---- ----µg/L0.054151-50-2



---- ---- <0.001 ----µg/L0.00124448-09-7



<0.05 <0.05 ---- ----µg/L0.0524448-09-7



---- ---- <0.001 ----µg/L0.0011691-99-2



<0.05 <0.05 ---- ----µg/L0.051691-99-2



(MeFOSAA)

---- ---- <0.0005 ----µg/L0.00052355-31-9



(MeFOSAA)

<0.02 <0.02 ---- ----µg/L0.022355-31-9



(EtFOSAA)

---- ---- <0.0005 ----µg/L0.00052991-50-6

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ET1800983



Analytical Results

----0874_SW109_1804100874_QC5SW_180410

_02

0874_QC5SW_180410

_01


(Matrix: WATER)







(EtFOSAA)

<0.02 <0.02 ---- ----µg/L0.022991-50-6



(4:2 FTS)

---- ---- <0.001 ----µg/L0.001757124-72-4


(4:2 FTS)

<0.05 <0.05 ---- ----µg/L0.05757124-72-4


(6:2 FTS)

---- ---- <0.001 ----µg/L0.00127619-97-2


(6:2 FTS)

<0.05 <0.05 ---- ----µg/L0.0527619-97-2


(8:2 FTS)

---- ---- <0.001 ----µg/L0.00139108-34-4


(8:2 FTS)

<0.05 <0.05 ---- ----µg/L0.0539108-34-4


(10:2 FTS)

---- ---- <0.001 ----µg/L0.001120226-60-0


(10:2 FTS)

<0.05 <0.05 ---- ----µg/L0.05120226-60-0

EP231P: PFAS Sums

---- ---- ---- 0.384 ----µg/L0.0003----Sum of PFAS

<0.01 <0.01 <0.01 ---- ----µg/L0.01----Sum of PFAS

----Sum of PFHxS and PFOS ---- ---- 0.275 ----µg/L0.0003355-46-4/1763-23-

1

<0.01Sum of PFHxS and PFOS <0.01 <0.01 ---- ----µg/L0.01355-46-4/1763-23-

1

---- ---- ---- 0.360 ----µg/L0.0003----Sum of PFAS (WA DER List)

<0.01 <0.01 <0.01 ---- ----µg/L0.01----Sum of PFAS (WA DER List)


---- ---- ---- 66.8 ----%0.0005----13C4-PFOS

93.1 83.1 87.4 ---- ----%0.02----13C4-PFOS

---- ---- ---- 117 ----%0.0005----13C8-PFOA

105 93.1 104 ---- ----%0.02----13C8-PFOA

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ET1800983







13C4-PFOS ---- 60 130

13C8-PFOA ---- 60 130


13C4-PFOS ---- 60 120

13C8-PFOA ---- 60 120

False

6 6.00False

Environmental




:Address MOBIL

C/O GPO BOX 2907


Address : 13 Carlton Street, Kirwan Townsville QLD AUSTRALIA 4814


:Project QLD_0874_PFAS Date Samples Received : 11-Apr-2018


:C-O-C number ---- Issue Date : 19-Apr-2018


Site : ----


















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General Comments










Key :







ED037P: Alkalinity by PC Titrator (QC Lot: 1560214)

ED037-P: Hydroxide Alkalinity as CaCO3 DMO-210-001 1 mg/L <1 <1 0.00 No Limit0874_SW108_180410 ET1800983-001

ED037-P: Carbonate Alkalinity as CaCO3 3812-32-6 1 mg/L 29 29 0.00 0% - 20%

ED037-P: Bicarbonate Alkalinity as CaCO3 71-52-3 1 mg/L 113 109 3.60 0% - 20%

ED037-P: Total Alkalinity as CaCO3 ---- 1 mg/L 142 138 3.02 0% - 20%

ED037-P: Hydroxide Alkalinity as CaCO3 DMO-210-001 1 mg/L <1 <1 0.00 No LimitAnonymous ET1800988-001

ED037-P: Carbonate Alkalinity as CaCO3 3812-32-6 1 mg/L <1 <1 0.00 No Limit



ED041G: Sulfate (Turbidimetric) as SO4 2- by DA (QC Lot: 1561670)

ED041G: Sulfate as SO4 - Turbidimetric 14808-79-8 1 mg/L 558 558 0.00 0% - 20%0874_SW108_180410 ET1800983-001

ED041G: Sulfate as SO4 - Turbidimetric 14808-79-8 1 mg/L 54 53 2.30 0% - 20%Anonymous ET1800988-001

ED045G: Chloride by Discrete Analyser (QC Lot: 1561671)

ED045G: Chloride 16887-00-6 1 mg/L 5160 5160 0.00 0% - 20%0874_SW108_180410 ET1800983-001

ED045G: Chloride 16887-00-6 1 mg/L 277 274 0.969 0% - 20%Anonymous ET1800988-001

ED093F: Dissolved Major Cations (QC Lot: 1568268)

ED093F: Calcium 7440-70-2 1 mg/L 24 24 0.00 0% - 20%0874_SW115_180410 ET1800983-008

ED093F: Magnesium 7439-95-4 1 mg/L 18 19 0.00 0% - 50%

ED093F: Sodium 7440-23-5 1 mg/L 141 145 2.73 0% - 20%

ED093F: Potassium 7440-09-7 1 mg/L 6 6 0.00 No Limit

ED093F: Calcium 7440-70-2 1 mg/L 18 18 0.00 0% - 50%Anonymous ET1800753-002


ED093F: Sodium 7440-23-5 1 mg/L 43 45 2.96 0% - 20%


EP231_TOP_A: Perfluoroalkyl Sulfonic Acids (QC Lot: 1564711)

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EP231_TOP_A: Perfluoroalkyl Sulfonic Acids (QC Lot: 1564711) - continued

EP231X: Perfluorooctane sulfonic acid (PFOS) 1763-23-1 0.01 µg/L 60.2 61.2 1.65 0% - 20%Anonymous ES1810459-001

EP231X: Perfluorobutane sulfonic acid (PFBS) 375-73-5 0.02 µg/L 0.93 0.85 9.08 0% - 20%

EP231X: Perfluoropentane sulfonic acid (PFPeS) 2706-91-4 0.02 µg/L 1.56 1.50 4.32 0% - 20%

EP231X: Perfluorohexane sulfonic acid (PFHxS) 355-46-4 0.02 µg/L 30.2 28.3 6.49 0% - 20%

EP231X: Perfluoroheptane sulfonic acid (PFHpS) 375-92-8 0.02 µg/L 0.85 0.80 5.32 0% - 20%

EP231X: Perfluorodecane sulfonic acid (PFDS) 335-77-3 0.02 µg/L <0.02 <0.02 0.00 No Limit

EP231_TOP_B: Perfluoroalkyl Carboxylic Acids (QC Lot: 1564711)

EP231X: Perfluorooctanoic acid (PFOA) 335-67-1 0.01 µg/L 4.40 4.24 3.94 0% - 20%Anonymous ES1810459-001

EP231X: Perfluoropentanoic acid (PFPeA) 2706-90-3 0.02 µg/L 11.0 11.3 2.52 0% - 20%

EP231X: Perfluorohexanoic acid (PFHxA) 307-24-4 0.02 µg/L 132 122 7.20 0% - 20%

EP231X: Perfluoroheptanoic acid (PFHpA) 375-85-9 0.02 µg/L 1.07 0.97 10.0 0% - 20%

EP231X: Perfluorononanoic acid (PFNA) 375-95-1 0.02 µg/L <0.02 <0.02 0.00 No Limit

EP231X: Perfluorodecanoic acid (PFDA) 335-76-2 0.02 µg/L <0.02 <0.02 0.00 No Limit

EP231X: Perfluoroundecanoic acid (PFUnDA) 2058-94-8 0.02 µg/L <0.02 <0.02 0.00 No Limit

EP231X: Perfluorododecanoic acid (PFDoDA) 307-55-1 0.02 µg/L <0.02 <0.02 0.00 No Limit

EP231X: Perfluorotridecanoic acid (PFTrDA) 72629-94-8 0.02 µg/L <0.02 <0.02 0.00 No Limit

EP231X: Perfluorotetradecanoic acid (PFTeDA) 376-06-7 0.05 µg/L <0.05 <0.05 0.00 No Limit

EP231X: Perfluorobutanoic acid (PFBA) 375-22-4 0.1 µg/L 5.0 5.3 5.34 0% - 20%

EP231_TOP_C: Perfluoroalkyl Sulfonamides (QC Lot: 1564711)

EP231X: Perfluorooctane sulfonamide (FOSA) 754-91-6 0.02 µg/L <0.02 <0.02 0.00 No LimitAnonymous ES1810459-001

EP231X: N-Methyl perfluorooctane


2355-31-9 0.02 µg/L <0.02 <0.02 0.00 No Limit

EP231X: N-Ethyl perfluorooctane


2991-50-6 0.02 µg/L <0.02 <0.02 0.00 No Limit

EP231X: N-Methyl perfluorooctane sulfonamide

(MeFOSA)

31506-32-8 0.05 µg/L <0.05 <0.05 0.00 No Limit

EP231X: N-Ethyl perfluorooctane sulfonamide

(EtFOSA)

4151-50-2 0.05 µg/L <0.05 <0.05 0.00 No Limit



24448-09-7 0.05 µg/L <0.05 <0.05 0.00 No Limit



1691-99-2 0.05 µg/L <0.05 <0.05 0.00 No Limit

EP231_TOP_D: (n:2) Fluorotelomer Sulfonic Acids (QC Lot: 1564711)

EP231X: 4:2 Fluorotelomer sulfonic acid (4:2

FTS)

757124-72-4 0.05 µg/L <0.05 <0.05 0.00 No LimitAnonymous ES1810459-001


FTS)

27619-97-2 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

39108-34-4 0.05 µg/L <0.05 <0.05 0.00 No Limit

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EP231_TOP_D: (n:2) Fluorotelomer Sulfonic Acids (QC Lot: 1564711) - continued


FTS)


EP231_TOP_P: PFAS Sums (QC Lot: 1564711)

EP231X: Sum of PFAS ---- 0.01 µg/L 247 236 4.44 0% - 20%Anonymous ES1810459-001

EP231X: Sum of PFHxS and PFOS 355-46-4/1763-

23-1

0.01 µg/L 90.4 89.5 1.00 0% - 20%

EP231X: Sum of TOP C4 - C14 Carboxylates and

C4 - C8 Sulfonates

---- 0.01 µg/L 247 236 4.44 0% - 20%



EP231X: Perfluorobutane sulfonic acid (PFBS) 375-73-5 0.02 µg/L <0.02 <0.02 0.00 No Limit

EP231X: Perfluoropentane sulfonic acid (PFPeS) 2706-91-4 0.02 µg/L <0.02 <0.02 0.00 No Limit

EP231X: Perfluorohexane sulfonic acid (PFHxS) 355-46-4 0.02 µg/L <0.02 <0.02 0.00 No Limit

EP231X: Perfluoroheptane sulfonic acid (PFHpS) 375-92-8 0.02 µg/L <0.02 <0.02 0.00 No Limit


EP231X: Perfluorooctane sulfonic acid (PFOS) 1763-23-1 0.01 µg/L 7.04 7.14 1.31 0% - 20%0874_SW118_180410 ET1800983-005








(PFOS)



(PFBS)

375-73-5 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFPeS)

2706-91-4 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFHxS)

355-46-4 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFHpS)

375-92-8 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFDS)

335-77-3 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFOS)

1763-23-1 0.0003 µg/L 0.0381 0.0396 3.91 0% - 20%0874_SW210_180410 ET1800983-002


(PFBS)

375-73-5 0.0005 µg/L 0.0085 0.0087 2.10 0% - 50%


(PFPeS)

2706-91-4 0.0005 µg/L 0.0053 0.0058 8.94 0% - 50%

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(PFHxS)

355-46-4 0.0005 µg/L 0.0383 0.0389 1.66 0% - 20%0874_SW210_180410 ET1800983-002


(PFHpS)

375-92-8 0.0005 µg/L 0.0012 0.0012 0.00 No Limit


(PFDS)

335-77-3 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


EP231X: Perfluorooctanoic acid (PFOA) 335-67-1 0.01 µg/L <0.01 <0.01 0.00 No LimitAnonymous ES1810438-001

EP231X: Perfluoropentanoic acid (PFPeA) 2706-90-3 0.02 µg/L <0.02 <0.02 0.00 No Limit

EP231X: Perfluorohexanoic acid (PFHxA) 307-24-4 0.02 µg/L <0.02 <0.02 0.00 No Limit

EP231X: Perfluoroheptanoic acid (PFHpA) 375-85-9 0.02 µg/L <0.02 <0.02 0.00 No Limit







EP231X: Perfluorobutanoic acid (PFBA) 375-22-4 0.1 µg/L 0.3 0.2 0.00 No Limit

EP231X: Perfluorooctanoic acid (PFOA) 335-67-1 0.01 µg/L 0.50 0.53 4.64 0% - 20%0874_SW118_180410 ET1800983-005


EP231X: Perfluorohexanoic acid (PFHxA) 307-24-4 0.02 µg/L 1.37 1.42 3.22 0% - 20%








EP231X: Perfluorobutanoic acid (PFBA) 375-22-4 0.1 µg/L <0.1 <0.1 0.00 No Limit


EP231X-ST: Perfluoropentanoic acid (PFPeA) 2706-90-3 0.0005 µg/L <0.0005 <0.0005 0.00 No LimitAnonymous ES1810551-001









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(PFTeDA)



EP231X-ST: Perfluoropentanoic acid (PFPeA) 2706-90-3 0.0005 µg/L 0.0036 0.0033 10.5 No Limit0874_SW210_180410 ET1800983-002


EP231X-ST: Perfluoroheptanoic acid (PFHpA) 375-85-9 0.0005 µg/L 0.0023 0.0020 16.0 No Limit

EP231X-ST: Perfluorooctanoic acid (PFOA) 335-67-1 0.0005 µg/L 0.0028 0.0026 7.41 No Limit







(PFTeDA)

376-06-7 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit






2355-31-9 0.02 µg/L <0.02 <0.02 0.00 No Limit



2991-50-6 0.02 µg/L <0.02 <0.02 0.00 No Limit


(MeFOSA)

31506-32-8 0.05 µg/L <0.05 <0.05 0.00 No Limit


(EtFOSA)

4151-50-2 0.05 µg/L <0.05 <0.05 0.00 No Limit



24448-09-7 0.05 µg/L <0.05 <0.05 0.00 No Limit



1691-99-2 0.05 µg/L <0.05 <0.05 0.00 No Limit

EP231X: Perfluorooctane sulfonamide (FOSA) 754-91-6 0.02 µg/L <0.02 <0.02 0.00 No Limit0874_SW118_180410 ET1800983-005



2355-31-9 0.02 µg/L <0.02 <0.02 0.00 No Limit



2991-50-6 0.02 µg/L <0.02 <0.02 0.00 No Limit


(MeFOSA)

31506-32-8 0.05 µg/L <0.05 <0.05 0.00 No Limit


(EtFOSA)

4151-50-2 0.05 µg/L <0.05 <0.05 0.00 No Limit



24448-09-7 0.05 µg/L <0.05 <0.05 0.00 No Limit

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1691-99-2 0.05 µg/L <0.05 <0.05 0.00 No Limit0874_SW118_180410 ET1800983-005



(FOSA)




2355-31-9 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit



2991-50-6 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit



31506-32-8 0.001 µg/L <0.001 <0.001 0.00 No Limit


(EtFOSA)

4151-50-2 0.001 µg/L <0.001 <0.001 0.00 No Limit



24448-09-7 0.001 µg/L <0.001 <0.001 0.00 No Limit



1691-99-2 0.001 µg/L <0.001 <0.001 0.00 No Limit


(FOSA)

754-91-6 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit0874_SW210_180410 ET1800983-002



2355-31-9 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit



2991-50-6 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit



31506-32-8 0.001 µg/L <0.001 <0.001 0.00 No Limit


(EtFOSA)

4151-50-2 0.001 µg/L <0.001 <0.001 0.00 No Limit



24448-09-7 0.001 µg/L <0.001 <0.001 0.00 No Limit



1691-99-2 0.001 µg/L <0.001 <0.001 0.00 No Limit



FTS)



FTS)

27619-97-2 0.05 µg/L 0.15 0.15 0.00 No Limit


FTS)

39108-34-4 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

120226-60-0 0.05 µg/L <0.05 <0.05 0.00 No Limit

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FTS)

757124-72-4 0.05 µg/L <0.05 <0.05 0.00 No Limit0874_SW118_180410 ET1800983-005


FTS)

27619-97-2 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

39108-34-4 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

120226-60-0 0.05 µg/L <0.05 <0.05 0.00 No Limit



FTS)



FTS)

27619-97-2 0.001 µg/L <0.001 <0.001 0.00 No Limit


FTS)

39108-34-4 0.001 µg/L <0.001 <0.001 0.00 No Limit


(10:2 FTS)

120226-60-0 0.001 µg/L <0.001 <0.001 0.00 No Limit


FTS)

757124-72-4 0.001 µg/L <0.001 <0.001 0.00 No Limit0874_SW210_180410 ET1800983-002


FTS)

27619-97-2 0.001 µg/L <0.001 <0.001 0.00 No Limit


FTS)

39108-34-4 0.001 µg/L <0.001 <0.001 0.00 No Limit


(10:2 FTS)

120226-60-0 0.001 µg/L <0.001 <0.001 0.00 No Limit


EP231X: Sum of PFAS ---- 0.01 µg/L 0.60 0.50 18.2 0% - 20%Anonymous ES1810438-001

EP231X: Sum of PFAS ---- 0.01 µg/L 17.0 17.9 5.62 0% - 20%0874_SW118_180410 ET1800983-005


EP231X-ST: Sum of PFAS ---- 0.0003 µg/L <0.0003 <0.0003 0.00 No LimitAnonymous ES1810551-001


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Report





ED037-P: Total Alkalinity as CaCO3 ---- ---- mg/L ---- 88.3200 mg/L 11287



<1 98.825 mg/L 12080



<1 95.910 mg/L 12080


ED093F: Calcium 7440-70-2 1 mg/L <1 -------- --------


ED093F: Sodium 7440-23-5 1 mg/L <1 -------- --------


EP231_TOP_A: Perfluoroalkyl Sulfonic Acids (QCLot: 1564711)

EP231X: Perfluorobutane sulfonic acid (PFBS) 375-73-5 0.02 µg/L <0.02 -------- --------

EP231X: Perfluoropentane sulfonic acid (PFPeS) 2706-91-4 0.02 µg/L <0.02 -------- --------

EP231X: Perfluorohexane sulfonic acid (PFHxS) 355-46-4 0.02 µg/L <0.02 53.31 µg/L 15050

EP231X: Perfluoroheptane sulfonic acid (PFHpS) 375-92-8 0.02 µg/L <0.02 -------- --------

EP231X: Perfluorooctane sulfonic acid (PFOS) 1763-23-1 0.01 µg/L <0.01 82.51 µg/L 15050

EP231X: Perfluorodecane sulfonic acid (PFDS) 335-77-3 0.02 µg/L <0.02 -------- --------

EP231_TOP_B: Perfluoroalkyl Carboxylic Acids (QCLot: 1564711)

EP231X: Perfluorobutanoic acid (PFBA) 375-22-4 0.1 µg/L <0.1 -------- --------

EP231X: Perfluoropentanoic acid (PFPeA) 2706-90-3 0.02 µg/L <0.02 -------- --------

EP231X: Perfluorohexanoic acid (PFHxA) 307-24-4 0.02 µg/L <0.02 -------- --------

EP231X: Perfluoroheptanoic acid (PFHpA) 375-85-9 0.02 µg/L <0.02 -------- --------

EP231X: Perfluorooctanoic acid (PFOA) 335-67-1 0.01 µg/L <0.01 87.11 µg/L 15050

EP231X: Perfluorononanoic acid (PFNA) 375-95-1 0.02 µg/L <0.02 -------- --------

EP231X: Perfluorodecanoic acid (PFDA) 335-76-2 0.02 µg/L <0.02 -------- --------

EP231X: Perfluoroundecanoic acid (PFUnDA) 2058-94-8 0.02 µg/L <0.02 -------- --------

EP231X: Perfluorododecanoic acid (PFDoDA) 307-55-1 0.02 µg/L <0.02 -------- --------

EP231X: Perfluorotridecanoic acid (PFTrDA) 72629-94-8 0.02 µg/L <0.02 -------- --------

EP231X: Perfluorotetradecanoic acid (PFTeDA) 376-06-7 0.05 µg/L <0.05 -------- --------

EP231_TOP_C: Perfluoroalkyl Sulfonamides (QCLot: 1564711)

EP231X: Perfluorooctane sulfonamide (FOSA) 754-91-6 0.02 µg/L <0.02 -------- --------

EP231X: N-Methyl perfluorooctane sulfonamide (MeFOSA) 31506-32-8 0.05 µg/L <0.05 -------- --------

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EP231_TOP_C: Perfluoroalkyl Sulfonamides (QCLot: 1564711) - continued

EP231X: N-Ethyl perfluorooctane sulfonamide (EtFOSA) 4151-50-2 0.05 µg/L <0.05 -------- --------

EP231X: N-Methyl perfluorooctane sulfonamidoethanol

(MeFOSE)

24448-09-7 0.05 µg/L <0.05 -------- --------

EP231X: N-Ethyl perfluorooctane sulfonamidoethanol

(EtFOSE)

1691-99-2 0.05 µg/L <0.05 -------- --------

EP231X: N-Methyl perfluorooctane sulfonamidoacetic acid

(MeFOSAA)

2355-31-9 0.02 µg/L <0.02 -------- --------

EP231X: N-Ethyl perfluorooctane sulfonamidoacetic acid

(EtFOSAA)

2991-50-6 0.02 µg/L <0.02 -------- --------

EP231_TOP_D: (n:2) Fluorotelomer Sulfonic Acids (QCLot: 1564711)

EP231X: 4:2 Fluorotelomer sulfonic acid (4:2 FTS) 757124-72-4 0.05 µg/L <0.05 -------- --------

EP231X: 6:2 Fluorotelomer sulfonic acid (6:2 FTS) 27619-97-2 0.05 µg/L <0.05 14.00.05 µg/L 2000



EP231_TOP_P: PFAS Sums (QCLot: 1564711)

EP231X: Sum of PFAS ---- 0.01 µg/L <0.01 -------- --------

EP231X: Sum of PFHxS and PFOS 355-46-4/17

63-23-1

0.01 µg/L <0.01 -------- --------

EP231X: Sum of TOP C4 - C14 Carboxylates and C4 - C8

Sulfonates

---- 0.01 µg/L <0.01 -------- --------


EP231X: Perfluorobutane sulfonic acid (PFBS) 375-73-5 0.02 µg/L <0.02 1000.5 µg/L 13070

EP231X: Perfluoropentane sulfonic acid (PFPeS) 2706-91-4 0.02 µg/L <0.02 1050.5 µg/L 13070


EP231X: Perfluoroheptane sulfonic acid (PFHpS) 375-92-8 0.02 µg/L <0.02 1050.5 µg/L 13070


EP231X: Perfluorodecane sulfonic acid (PFDS) 335-77-3 0.02 µg/L <0.02 1100.5 µg/L 13070









EP231X: Perfluorobutanoic acid (PFBA) 375-22-4 0.1 µg/L <0.1 1042.5 µg/L 13070

EP231X: Perfluoropentanoic acid (PFPeA) 2706-90-3 0.02 µg/L <0.02 1230.5 µg/L 13070

EP231X: Perfluorohexanoic acid (PFHxA) 307-24-4 0.02 µg/L <0.02 1130.5 µg/L 13070

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EP231X: Perfluoroheptanoic acid (PFHpA) 375-85-9 0.02 µg/L <0.02 97.80.5 µg/L 13070


EP231X: Perfluorononanoic acid (PFNA) 375-95-1 0.02 µg/L <0.02 1100.5 µg/L 13070

EP231X: Perfluorodecanoic acid (PFDA) 335-76-2 0.02 µg/L <0.02 1100.5 µg/L 13070

EP231X: Perfluoroundecanoic acid (PFUnDA) 2058-94-8 0.02 µg/L <0.02 74.60.5 µg/L 13070

EP231X: Perfluorododecanoic acid (PFDoDA) 307-55-1 0.02 µg/L <0.02 1000.5 µg/L 13070

EP231X: Perfluorotridecanoic acid (PFTrDA) 72629-94-8 0.02 µg/L <0.02 1100.5 µg/L 13070

EP231X: Perfluorotetradecanoic acid (PFTeDA) 376-06-7 0.05 µg/L <0.05 1281.25 µg/L 15070














EP231X: Perfluorooctane sulfonamide (FOSA) 754-91-6 0.02 µg/L <0.02 1160.5 µg/L 13070

EP231X: N-Methyl perfluorooctane sulfonamide (MeFOSA) 31506-32-8 0.05 µg/L <0.05 1221.25 µg/L 15070

EP231X: N-Ethyl perfluorooctane sulfonamide (EtFOSA) 4151-50-2 0.05 µg/L <0.05 1141.25 µg/L 15070


(MeFOSE)

24448-09-7 0.05 µg/L <0.05 1191.25 µg/L 15070


(EtFOSE)

1691-99-2 0.05 µg/L <0.05 1271.25 µg/L 15070


(MeFOSAA)

2355-31-9 0.02 µg/L <0.02 86.00.5 µg/L 13070


(EtFOSAA)

2991-50-6 0.02 µg/L <0.02 92.20.5 µg/L 13070




(MeFOSA)

31506-32-8 0.001 µg/L <0.001 52.30.025 µg/L 13040



(MeFOSE)

24448-09-7 0.001 µg/L <0.001 63.90.025 µg/L 13040

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(EtFOSE)

1691-99-2 0.001 µg/L <0.001 62.30.025 µg/L 13040


acid (MeFOSAA)

2355-31-9 0.0005 µg/L <0.0005 45.60.01 µg/L 13040


acid (EtFOSAA)

2991-50-6 0.0005 µg/L <0.0005 40.60.01 µg/L 13040


EP231X: 4:2 Fluorotelomer sulfonic acid (4:2 FTS) 757124-72-4 0.05 µg/L <0.05 1110.5 µg/L 13070

















0874_SW210_180410 ET1800983-002 14808-79-8ED041G: Sulfate as SO4 - Turbidimetric # Not

Determined

20 mg/L 13070


0874_SW210_180410 ET1800983-002 16887-00-6ED045G: Chloride # Not

Determined

400 mg/L 13070


Anonymous ES1810438-001 375-73-5EP231X: Perfluorobutane sulfonic acid (PFBS) 91.40.5 µg/L 13050

2706-91-4EP231X: Perfluoropentane sulfonic acid (PFPeS) 80.00.5 µg/L 13050

355-46-4EP231X: Perfluorohexane sulfonic acid (PFHxS) 1010.5 µg/L 13050

375-92-8EP231X: Perfluoroheptane sulfonic acid (PFHpS) 1130.5 µg/L 13050

1763-23-1EP231X: Perfluorooctane sulfonic acid (PFOS) 1270.5 µg/L 13050

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Anonymous ES1810438-001 335-77-3EP231X: Perfluorodecane sulfonic acid (PFDS) 1230.5 µg/L 13050


Anonymous ES1810551-002 375-73-5EP231X-ST: Perfluorobutane sulfonic acid (PFBS) 75.00.01 µg/L 13050

2706-91-4EP231X-ST: Perfluoropentane sulfonic acid (PFPeS) 83.80.01 µg/L 13050






Anonymous ES1810438-001 375-22-4EP231X: Perfluorobutanoic acid (PFBA) 1082.5 µg/L 13050

2706-90-3EP231X: Perfluoropentanoic acid (PFPeA) 1030.5 µg/L 13050

307-24-4EP231X: Perfluorohexanoic acid (PFHxA) 1060.5 µg/L 13050

375-85-9EP231X: Perfluoroheptanoic acid (PFHpA) 1170.5 µg/L 13050

335-67-1EP231X: Perfluorooctanoic acid (PFOA) 1020.5 µg/L 13050

375-95-1EP231X: Perfluorononanoic acid (PFNA) 1140.5 µg/L 13050

335-76-2EP231X: Perfluorodecanoic acid (PFDA) 83.40.5 µg/L 13050

2058-94-8EP231X: Perfluoroundecanoic acid (PFUnDA) 83.00.5 µg/L 13050

307-55-1EP231X: Perfluorododecanoic acid (PFDoDA) 69.80.5 µg/L 13050

72629-94-8EP231X: Perfluorotridecanoic acid (PFTrDA) 58.20.5 µg/L 13050

376-06-7EP231X: Perfluorotetradecanoic acid (PFTeDA) 87.21.25 µg/L 15050


Anonymous ES1810551-002 375-22-4EP231X-ST: Perfluorobutanoic acid (PFBA) 46.30.05 µg/L 13030

2706-90-3EP231X-ST: Perfluoropentanoic acid (PFPeA) 74.80.01 µg/L 13050

307-24-4EP231X-ST: Perfluorohexanoic acid (PFHxA) 71.20.01 µg/L 13050


335-67-1EP231X-ST: Perfluorooctanoic acid (PFOA) 80.40.01 µg/L 13050








Anonymous ES1810438-001 754-91-6EP231X: Perfluorooctane sulfonamide (FOSA) 1050.5 µg/L 13050

31506-32-8EP231X: N-Methyl perfluorooctane sulfonamide

(MeFOSA)

1141.25 µg/L 15050

4151-50-2EP231X: N-Ethyl perfluorooctane sulfonamide (EtFOSA) 83.81.25 µg/L 15050

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Anonymous ES1810438-001 24448-09-7EP231X: N-Methyl perfluorooctane sulfonamidoethanol

(MeFOSE)

1281.25 µg/L 15050

1691-99-2EP231X: N-Ethyl perfluorooctane sulfonamidoethanol

(EtFOSE)

90.31.25 µg/L 15050

2355-31-9EP231X: N-Methyl perfluorooctane sulfonamidoacetic

acid (MeFOSAA)

97.40.5 µg/L 13050

2991-50-6EP231X: N-Ethyl perfluorooctane sulfonamidoacetic

acid (EtFOSAA)

90.60.5 µg/L 13050


Anonymous ES1810551-002 754-91-6EP231X-ST: Perfluorooctane sulfonamide (FOSA) 53.20.01 µg/L 13030


(MeFOSA)

46.00.025 µg/L 13030


(EtFOSA)

59.20.025 µg/L 13030



39.90.025 µg/L 13030



34.20.025 µg/L 13030



41.20.01 µg/L 13030


acid (EtFOSAA)

30.20.01 µg/L 13030


Anonymous ES1810438-001 757124-72-4EP231X: 4:2 Fluorotelomer sulfonic acid (4:2 FTS) 1100.5 µg/L 13050

27619-97-2EP231X: 6:2 Fluorotelomer sulfonic acid (6:2 FTS) 76.60.5 µg/L 13050

39108-34-4EP231X: 8:2 Fluorotelomer sulfonic acid (8:2 FTS) 1150.5 µg/L 13050



Anonymous ES1810551-002 757124-72-4EP231X-ST: 4:2 Fluorotelomer sulfonic acid (4:2 FTS) 93.20.01 µg/L 13050




True

Environmental





Site : ---- Issue Date : 19-Apr-2018

Andi Carnall:Sampler No. of samples received : 14






Summary of Outliers













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Matrix: WATER



ET1800983--002 14808-79-8Sulfate as SO4 -

Turbidimetric




----Not

Determined


ET1800983--002 16887-00-6Chloride0874_SW210_180410 MS recovery not determined,



----Not

Determined















0874_SW108_180410, 0874_SW210_180410,

0874_SW208_180410, 0874_SW114_180410,

0874_SW118_180410, 0874_SW130_180410,

0874_SW116_180410, 0874_SW115_180410,

0874_SW113_180410, 0874_SW109_180410

24-Apr-2018---- 11-Apr-2018----10-Apr-2018 ---- ü



0874_SW108_180410, 0874_SW210_180410,

0874_SW208_180410, 0874_SW114_180410,

0874_SW118_180410, 0874_SW130_180410,

0874_SW116_180410, 0874_SW115_180410,

0874_SW113_180410, 0874_SW109_180410

08-May-2018---- 12-Apr-2018----10-Apr-2018 ---- ü



0874_SW108_180410, 0874_SW210_180410,

0874_SW208_180410, 0874_SW114_180410,

0874_SW118_180410, 0874_SW130_180410,

0874_SW116_180410, 0874_SW115_180410,

0874_SW113_180410, 0874_SW109_180410

08-May-2018---- 12-Apr-2018----10-Apr-2018 ---- ü

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Clear Plastic Bottle - Natural (ED093F)

0874_SW108_180410, 0874_SW210_180410,

0874_SW208_180410, 0874_SW114_180410,

0874_SW118_180410, 0874_SW130_180410,

0874_SW116_180410, 0874_SW115_180410,

0874_SW113_180410, 0874_SW109_180410

17-Apr-2018---- 16-Apr-2018----10-Apr-2018 ---- ü


HDPE (no PTFE) (EP231X (TOP))

0874_SW130_180410 07-Oct-201807-Oct-2018 13-Apr-201813-Apr-201810-Apr-2018 ü üEP231_TOP_B: Perfluoroalkyl Carboxylic Acids


0874_SW130_180410 07-Oct-201807-Oct-2018 13-Apr-201813-Apr-201810-Apr-2018 ü üEP231_TOP_C: Perfluoroalkyl Sulfonamides


0874_SW130_180410 07-Oct-201807-Oct-2018 13-Apr-201813-Apr-201810-Apr-2018 ü üEP231_TOP_D: (n:2) Fluorotelomer Sulfonic Acids


0874_SW130_180410 07-Oct-201807-Oct-2018 13-Apr-201813-Apr-201810-Apr-2018 ü üEP231_TOP_P: PFAS Sums


0874_SW130_180410 07-Oct-201807-Oct-2018 13-Apr-201813-Apr-201810-Apr-2018 ü üEP231A: Perfluoroalkyl Sulfonic Acids

HDPE (no PTFE) (EP231X)

0874_SW118_180410, 0874_SW130_180410,

0874_SW113_180410, 0874_QC3SW_180410,

0874_QC5SW_180410_01, 0874_QC5SW_180410_02

07-Oct-2018---- 17-Apr-2018----10-Apr-2018 ---- ü


0874_SW108_180410, 0874_SW210_180410,

0874_SW208_180410, 0874_SW114_180410,

0874_SW116_180410, 0874_SW115_180410,

0874_QC1SW_180410, 0874_SW109_180410

07-Oct-201807-Oct-2018 13-Apr-201813-Apr-201810-Apr-2018 ü ü



0874_SW118_180410, 0874_SW130_180410,

0874_SW113_180410, 0874_QC3SW_180410,

0874_QC5SW_180410_01, 0874_QC5SW_180410_02

07-Oct-2018---- 17-Apr-2018----10-Apr-2018 ---- ü


0874_SW108_180410, 0874_SW210_180410,

0874_SW208_180410, 0874_SW114_180410,

0874_SW116_180410, 0874_SW115_180410,

0874_QC1SW_180410, 0874_SW109_180410


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0874_SW118_180410, 0874_SW130_180410,

0874_SW113_180410, 0874_QC3SW_180410,

0874_QC5SW_180410_01, 0874_QC5SW_180410_02

07-Oct-2018---- 17-Apr-2018----10-Apr-2018 ---- ü


0874_SW108_180410, 0874_SW210_180410,

0874_SW208_180410, 0874_SW114_180410,

0874_SW116_180410, 0874_SW115_180410,

0874_QC1SW_180410, 0874_SW109_180410




0874_SW118_180410, 0874_SW130_180410,

0874_SW113_180410, 0874_QC3SW_180410,

0874_QC5SW_180410_01, 0874_QC5SW_180410_02

07-Oct-2018---- 17-Apr-2018----10-Apr-2018 ---- ü


0874_SW108_180410, 0874_SW210_180410,

0874_SW208_180410, 0874_SW114_180410,

0874_SW116_180410, 0874_SW115_180410,

0874_QC1SW_180410, 0874_SW109_180410


EP231P: PFAS Sums


0874_SW118_180410, 0874_SW130_180410,

0874_SW113_180410, 0874_QC3SW_180410,

0874_QC5SW_180410_01, 0874_QC5SW_180410_02

07-Oct-2018---- 17-Apr-2018----10-Apr-2018 ---- ü


0874_SW108_180410, 0874_SW210_180410,

0874_SW208_180410, 0874_SW114_180410,

0874_SW116_180410, 0874_SW115_180410,

0874_QC1SW_180410, 0874_SW109_180410


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NEPM 2013 B3 & ALS QC Standard 11.11 10.002 18 üPer- and Polyfluoroalkyl Substances (PFAS) by LCMSMS EP231X


NEPM 2013 B3 & ALS QC Standard 16.67 10.001 6 üPFAS by LCMSMS after oxidation (TOP) EP231X (TOP)









Method Blanks (MB)







Matrix Spikes (MS)





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Schedule B(3)







Discrete Analyser

ED041G WATER











Schedule B(3)



DA

EN055 - PG WATER

In house: Direct injection analysis of fresh waters after dilution (1:1) with methanol. Analysis by

LC-Electrospray-MS-MS, Negative Mode using MRM. Where commercially available, isotopically labelled

analogues of the target analytes are used as internal standards for quantification. Where a labelled analogue is

not commercially available, the internal standard with similar chemistry and the closest retention time to the

target is used for quantification. The DQO for internal standard response is 50-150% of that established at initial

calibration. PFOS is quantified using a certified, traceable standard consisting of linear and branched PFOS

isomers. This method complies with the quality control definitions as stated in QSM 5.1. Data is reviewed in line

with the DQOs as stated in QSM5.1


(PFAS) by LCMSMS

EP231X WATER

In house, following oxidation per Houtz,Erika F.; Sedlak,David L. (2012): Oxidative Conversion as a Means of

Detecting Precursors to Perfluoroalkyl Acids in Urban Runoff. In Environmental Science & Technology 46 (17),pp.

9342¿9349.: A portion of the oxidised sample is mixed with methanol (1:1) prior to analysis by

LC-Electrospray-MS-MS,Negative Mode using MRM. Where commercially available, isotopically labelled



target is used for quantification. PFOS is quantified using a certified, traceable standard consisting of linear and

branched PFOS isomers.

PFAS by LCMSMS after oxidation (TOP) EP231X (TOP) WATER

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standard with similar chemistry and the closest retention time to the target is used for quantification. The DQO

for internal standard response is 50-150% of that established at initial calibration. PFOS is quantified using a

certified, traceable standard consisting of linear and branched PFOS isomers. This method complies with the

quality control definitions as stated in QSM 5.1. Data is reviewed in line with the DQOs as stated in QSM5.1


(PFAS) by LCMSMS

EP231X-ST WATER



In-House with oxidation per Houtz, Erika F.; Sedlak, David L. (2012): Oxidative Conversion as a Means of

Detecting Precursors to Perfluoroalkyl Acids in Urban Runoff. In Environmental Science & Technology 46 (17),

pp. 9342¿9349:

A 5 mL sample is digested with persulfate under alkaline conditions, neutralised and prepared for analysis per

EP231.

Total Oxidisable Precursor Digest for

PFAS

* ORG70-W WATER

Environmental





C/O GPO BOX 2907


13 Carlton Street, Kirwan Townsville

QLD AUSTRALIA 4814



:: FacsimileFacsimile +61 07 38314223



V4)


Site : ----


DatesDate Samples Received : Issue Date : 11-Apr-201811-Apr-2018 08:50

Scheduled Reporting Date: 19-Apr-2018:Client Requested Due

Date

19-Apr-2018


No. of coolers/boxes : :2 Temperature 16.1°C - Ice present


General Comments






l EP231X, EP231X-ST, EP231X(TOP) analysis will be conducted by ALS Sydney, NATA accreditation no. 825, site no 10911.

l Please be advised that an extra sample "0874_SW109_180410" was received in addition to the

samples listed on the COC. This sample has been added to the end of the work order and was

assigned for EP231X-ST, NT-1 and NT-2 analysis as confirmed by David via phone call 11.04.18.l Please be advised that the analysis assigned for ALS samples #11, #12, and #13 is 'EP231X'

instead of 'EP231X-ST' as per the COC. This is confirmed by David via phone call 11.04.18.l Discounted Package Prices apply only when specific ALS Group Codes ('W', 'S', 'NT' suites) are referenced on COCs.

l ED037-P, ED041G, ED045G conducted by ALS Townsville, NATA accreditation no. 825, (Site no. 23313)







11-Apr-2018:Issue Date





ET1800983-012 : [ 10-Apr-2018 ] : 0874_QC5SW_180410_01

ET1800983-013 : [ 10-Apr-2018 ] : 0874_QC5SW_180410_02











componentW

AT

ER

- E

P2

31X

(T

OP

)

PF

AS

- T

ota

l Oxi

dis

able

Pre

curs

or

(TO

P)

Ass

ay

WA

TE

R -

EP

231X

PF

AS

- F

ull

Su

ite (

28 a

na

lyte

s)

WA

TE

R -

EP

231X

-ST

PF

AS

- S

up

er

Tra

ce W

ate

rs L

ong

Su

ite (

28

WA

TE

R -

NT

-01 &

02

Ca

, M

g, N

a, K

, C

l, S

O4

, A

lka

linity

ET1800983-001 10-Apr-2018 00:00 0874_SW108_180410 ü ü

ET1800983-002 10-Apr-2018 00:00 0874_SW210_180410 ü ü

ET1800983-003 10-Apr-2018 00:00 0874_SW208_180410 ü ü

ET1800983-004 10-Apr-2018 00:00 0874_SW114_180410 ü ü

ET1800983-005 10-Apr-2018 00:00 0874_SW118_180410 ü ü

ET1800983-006 10-Apr-2018 00:00 0874_SW130_180410 ü ü ü

ET1800983-007 10-Apr-2018 00:00 0874_SW116_180410 ü ü

ET1800983-008 10-Apr-2018 00:00 0874_SW115_180410 ü ü

ET1800983-009 10-Apr-2018 00:00 0874_SW113_180410 ü ü

ET1800983-010 10-Apr-2018 00:00 0874_QC1SW_180410 ü

ET1800983-011 10-Apr-2018 00:00 0874_QC3SW_180410 ü

ET1800983-012 10-Apr-2018 00:00 0874_QC5SW_180410_01 ü

ET1800983-013 10-Apr-2018 00:00 0874_QC5SW_180410_02 ü

ET1800983-014 10-Apr-2018 00:00 0874_SW109_180410 ü ü

Matrix: WATER


ID

Client sampling

date / time







ACCOUNTS PAYABLE


AU ACCOUNTS PAYABLE


DAVID HARRIS








DERP LABREPORTS


PHIL SCHULZ









RESULTS RESULTS








0 0.00 True

Environmental





C/O GPO BOX 2907







Sampler : JM

Site : ----






l General Comments












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General Comments







purposes.







Key :


EP231X-ST and EP231X conducted by ALS Sydney, NATA accreditation no. 825, site no 10911.l

EP231: Particular samples required dilution due to sample matrix . LOR values have been adjusted accordingly.l

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Analytical Results

0874_MW236_S_1804

10

0874_MW257_S_1804

10

0874_MW258_S_1804

10

0874_MW225_S_1804

10

0874_MW259_S_1804

10


(Matrix: WATER)






<1Carbonate Alkalinity as CaCO3 <1 <1 <1 <1mg/L13812-32-6






277Chloride 746 657 46 3400mg/L116887-00-6


21Calcium 42 37 5 116mg/L17440-70-2

17Magnesium 34 29 5 167mg/L17439-95-4

286Sodium 595 568 370 1880mg/L17440-23-5

<1Potassium <1 <1 <1 27mg/L17440-09-7


15.2 30.8 29.6 16.8 108meq/L0.01----Total Anions

14.9 30.8 28.9 16.8 102meq/L0.01----Total Cations

1.21 0.06 1.19 0.04 2.80%0.01----Ionic Balance



(PFBS)

---- ---- 0.0267 0.0050µg/L0.0005375-73-5


(PFBS)

0.04 0.04 ---- ----µg/L0.02375-73-5


(PFPeS)

---- ---- 0.0022 0.0010µg/L0.00052706-91-4


(PFPeS)

<0.02 <0.02 ---- ----µg/L0.022706-91-4


(PFHxS)

---- ---- 0.0292 0.0051µg/L0.0005355-46-4


(PFHxS)

0.20 0.26 ---- ----µg/L0.02355-46-4


(PFHpS)

---- ---- 0.0019 <0.0005µg/L0.0005375-92-8


(PFHpS)

<0.02 <0.02 ---- ----µg/L0.02375-92-8

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Analytical Results

0874_MW236_S_1804

10

0874_MW257_S_1804

10

0874_MW258_S_1804

10

0874_MW225_S_1804

10

0874_MW259_S_1804

10


(Matrix: WATER)






(PFOS)

---- ---- 0.0622 0.0035µg/L0.00031763-23-1


(PFDS)

---- ---- <0.0005 <0.0005µg/L0.0005335-77-3


(PFOS)

0.23 0.23 ---- ----µg/L0.011763-23-1


(PFDS)

<0.02 <0.02 ---- ----µg/L0.02335-77-3


----Perfluorobutanoic acid (PFBA) ---- ---- <0.002 <0.002µg/L0.002375-22-4


----Perfluoropentanoic acid (PFPeA) ---- ---- 0.0023 <0.0005µg/L0.00052706-90-3


----Perfluorohexanoic acid (PFHxA) ---- ---- 0.0015 0.0010µg/L0.0005307-24-4


----Perfluoroheptanoic acid (PFHpA) ---- ---- 0.0018 0.0017µg/L0.0005375-85-9


----Perfluorooctanoic acid (PFOA) ---- ---- 0.0034 0.0051µg/L0.0005335-67-1

<0.01Perfluorooctanoic acid (PFOA) <0.01 0.02 ---- ----µg/L0.01335-67-1

----Perfluorononanoic acid (PFNA) ---- ---- 0.0007 0.0010µg/L0.0005375-95-1


----Perfluorodecanoic acid (PFDA) ---- ---- <0.0005 0.0022µg/L0.0005335-76-2



(PFUnDA)

---- ---- <0.0005 <0.0005µg/L0.00052058-94-8


(PFUnDA)

<0.02 <0.02 ---- ----µg/L0.022058-94-8


(PFDoDA)

---- ---- <0.0005 <0.0005µg/L0.0005307-55-1


(PFDoDA)

<0.02 <0.02 ---- ----µg/L0.02307-55-1


(PFTrDA)

---- ---- <0.0005 <0.0005µg/L0.000572629-94-8


(PFTrDA)

<0.02 <0.02 ---- ----µg/L0.0272629-94-8

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Analytical Results

0874_MW236_S_1804

10

0874_MW257_S_1804

10

0874_MW258_S_1804

10

0874_MW225_S_1804

10

0874_MW259_S_1804

10


(Matrix: WATER)






(PFTeDA)

---- ---- <0.0005 <0.0005µg/L0.0005376-06-7


(PFTeDA)

<0.05 <0.05 ---- ----µg/L0.05376-06-7



(FOSA)

---- ---- <0.0005 <0.0005µg/L0.0005754-91-6


(FOSA)

<0.02 <0.02 ---- ----µg/L0.02754-91-6



---- ---- <0.001 <0.001µg/L0.00131506-32-8



<0.05 <0.05 ---- ----µg/L0.0531506-32-8



---- ---- <0.001 <0.001µg/L0.0014151-50-2



<0.05 <0.05 ---- ----µg/L0.054151-50-2



---- ---- <0.001 <0.001µg/L0.00124448-09-7



<0.05 <0.05 ---- ----µg/L0.0524448-09-7



---- ---- <0.001 <0.001µg/L0.0011691-99-2



<0.05 <0.05 ---- ----µg/L0.051691-99-2



(MeFOSAA)

---- ---- <0.0005 <0.0005µg/L0.00052355-31-9



(MeFOSAA)

<0.02 <0.02 ---- ----µg/L0.022355-31-9



(EtFOSAA)

---- ---- <0.0005 <0.0005µg/L0.00052991-50-6

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Analytical Results

0874_MW236_S_1804

10

0874_MW257_S_1804

10

0874_MW258_S_1804

10

0874_MW225_S_1804

10

0874_MW259_S_1804

10


(Matrix: WATER)







(EtFOSAA)

<0.02 <0.02 ---- ----µg/L0.022991-50-6



(4:2 FTS)

---- ---- <0.001 <0.001µg/L0.001757124-72-4


(4:2 FTS)

<0.05 <0.05 ---- ----µg/L0.05757124-72-4


(6:2 FTS)

---- ---- <0.001 <0.001µg/L0.00127619-97-2


(6:2 FTS)

<0.05 <0.05 ---- ----µg/L0.0527619-97-2


(8:2 FTS)

---- ---- <0.001 <0.001µg/L0.00139108-34-4


(8:2 FTS)

<0.05 <0.05 ---- ----µg/L0.0539108-34-4


(10:2 FTS)

---- ---- <0.001 <0.001µg/L0.001120226-60-0


(10:2 FTS)

<0.05 <0.05 ---- ----µg/L0.05120226-60-0

EP231P: PFAS Sums

---- ---- ---- 0.132 0.0256µg/L0.0003----Sum of PFAS

0.28 0.47 0.55 ---- ----µg/L0.01----Sum of PFAS

----Sum of PFHxS and PFOS ---- ---- 0.0914 0.0086µg/L0.0003355-46-4/1763-23-

1

0.25Sum of PFHxS and PFOS 0.43 0.49 ---- ----µg/L0.01355-46-4/1763-23-

1

---- ---- ---- 0.127 0.0214µg/L0.0003----Sum of PFAS (WA DER List)

0.28 0.47 0.55 ---- ----µg/L0.01----Sum of PFAS (WA DER List)


---- ---- ---- 102 84.6%0.0005----13C4-PFOS

93.3 119 97.7 ---- ----%0.02----13C4-PFOS

---- ---- ---- 106 102%0.0005----13C8-PFOA

112 107 112 ---- ----%0.02----13C8-PFOA

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Analytical Results

0874_MW219_S_1804

10

0874_MW260_S_1804

10

0874_MW268_S_1804

10

0874_MW218_S_1804

10

0874_MW269_S_1804

10


(Matrix: WATER)












24Chloride 10700 6550 1080 2560mg/L116887-00-6


6Calcium 411 437 72 137mg/L17440-70-2

4Magnesium 727 376 61 94mg/L17439-95-4

17Sodium 6990 3520 834 1800mg/L17440-23-5

1Potassium 170 23 5 2mg/L17440-09-7


1.44 339 199 42.7 95.3meq/L0.01----Total Anions

1.39 389 206 45.0 92.9meq/L0.01----Total Cations

---- 6.87 1.79 2.61 1.28%0.01----Ionic Balance



(PFBS)

---- <0.0005 ---- 0.0056µg/L0.0005375-73-5


(PFBS)

<0.05 ---- <0.02 ----µg/L0.02375-73-5


(PFPeS)

---- <0.0005 ---- 0.0017µg/L0.00052706-91-4


(PFPeS)

<0.05 ---- <0.02 ----µg/L0.022706-91-4


(PFHxS)

---- 0.0011 ---- 0.0098µg/L0.0005355-46-4


(PFHxS)

0.13 ---- 0.14 ----µg/L0.02355-46-4


(PFHpS)

---- <0.0005 ---- <0.0005µg/L0.0005375-92-8


(PFHpS)

<0.05 ---- <0.02 ----µg/L0.02375-92-8

8 of 23:Page

Work Order :

:Client

ET1800988



Analytical Results

0874_MW219_S_1804

10

0874_MW260_S_1804

10

0874_MW268_S_1804

10

0874_MW218_S_1804

10

0874_MW269_S_1804

10


(Matrix: WATER)






(PFOS)

---- <0.0003 ---- 0.0042µg/L0.00031763-23-1


(PFDS)

---- <0.0005 ---- <0.0005µg/L0.0005335-77-3


(PFOS)

<0.05 ---- 0.10 ----µg/L0.011763-23-1


(PFDS)

<0.05 ---- <0.02 ----µg/L0.02335-77-3


<0.002Perfluorobutanoic acid (PFBA) ---- <0.002 ---- <0.002µg/L0.002375-22-4

----Perfluorobutanoic acid (PFBA) <0.2 ---- <0.1 ----µg/L0.1375-22-4

<0.0005Perfluoropentanoic acid (PFPeA) ---- <0.0005 ---- <0.0005µg/L0.00052706-90-3

----Perfluoropentanoic acid (PFPeA) <0.05 ---- <0.02 ----µg/L0.022706-90-3

<0.0005Perfluorohexanoic acid (PFHxA) ---- <0.0005 ---- <0.0005µg/L0.0005307-24-4

----Perfluorohexanoic acid (PFHxA) <0.05 ---- <0.02 ----µg/L0.02307-24-4

<0.0005Perfluoroheptanoic acid (PFHpA) ---- <0.0005 ---- <0.0005µg/L0.0005375-85-9

----Perfluoroheptanoic acid (PFHpA) <0.05 ---- <0.02 ----µg/L0.02375-85-9

0.0027Perfluorooctanoic acid (PFOA) ---- 0.0023 ---- <0.0005µg/L0.0005335-67-1

----Perfluorooctanoic acid (PFOA) <0.05 ---- <0.01 ----µg/L0.01335-67-1

<0.0005Perfluorononanoic acid (PFNA) ---- <0.0005 ---- <0.0005µg/L0.0005375-95-1

----Perfluorononanoic acid (PFNA) <0.05 ---- <0.02 ----µg/L0.02375-95-1

<0.0005Perfluorodecanoic acid (PFDA) ---- <0.0005 ---- <0.0005µg/L0.0005335-76-2

----Perfluorodecanoic acid (PFDA) <0.05 ---- <0.02 ----µg/L0.02335-76-2


(PFUnDA)

---- <0.0005 ---- <0.0005µg/L0.00052058-94-8


(PFUnDA)

<0.05 ---- <0.02 ----µg/L0.022058-94-8


(PFDoDA)

---- <0.0005 ---- <0.0005µg/L0.0005307-55-1


(PFDoDA)

<0.05 ---- <0.02 ----µg/L0.02307-55-1


(PFTrDA)

---- <0.0005 ---- <0.0005µg/L0.000572629-94-8


(PFTrDA)

<0.05 ---- <0.02 ----µg/L0.0272629-94-8

9 of 23:Page

Work Order :

:Client

ET1800988



Analytical Results

0874_MW219_S_1804

10

0874_MW260_S_1804

10

0874_MW268_S_1804

10

0874_MW218_S_1804

10

0874_MW269_S_1804

10


(Matrix: WATER)






(PFTeDA)

---- <0.0005 ---- <0.0005µg/L0.0005376-06-7


(PFTeDA)

<0.12 ---- <0.05 ----µg/L0.05376-06-7



(FOSA)

---- <0.0005 ---- <0.0005µg/L0.0005754-91-6


(FOSA)

<0.05 ---- <0.02 ----µg/L0.02754-91-6



---- <0.001 ---- <0.001µg/L0.00131506-32-8



<0.12 ---- <0.05 ----µg/L0.0531506-32-8



---- <0.001 ---- <0.001µg/L0.0014151-50-2



<0.12 ---- <0.05 ----µg/L0.054151-50-2



---- <0.001 ---- <0.001µg/L0.00124448-09-7



<0.12 ---- <0.05 ----µg/L0.0524448-09-7



---- <0.001 ---- <0.001µg/L0.0011691-99-2



<0.12 ---- <0.05 ----µg/L0.051691-99-2



(MeFOSAA)

---- <0.0005 ---- <0.0005µg/L0.00052355-31-9



(MeFOSAA)

<0.05 ---- <0.02 ----µg/L0.022355-31-9



(EtFOSAA)

---- <0.0005 ---- <0.0005µg/L0.00052991-50-6

10 of 23:Page

Work Order :

:Client

ET1800988



Analytical Results

0874_MW219_S_1804

10

0874_MW260_S_1804

10

0874_MW268_S_1804

10

0874_MW218_S_1804

10

0874_MW269_S_1804

10


(Matrix: WATER)







(EtFOSAA)

<0.05 ---- <0.02 ----µg/L0.022991-50-6



(4:2 FTS)

---- <0.001 ---- <0.001µg/L0.001757124-72-4


(4:2 FTS)

<0.05 ---- <0.05 ----µg/L0.05757124-72-4


(6:2 FTS)

---- <0.001 ---- <0.001µg/L0.00127619-97-2


(6:2 FTS)

<0.05 ---- <0.05 ----µg/L0.0527619-97-2


(8:2 FTS)

---- <0.001 ---- <0.001µg/L0.00139108-34-4


(8:2 FTS)

<0.05 ---- <0.05 ----µg/L0.0539108-34-4


(10:2 FTS)

---- <0.001 ---- <0.001µg/L0.001120226-60-0


(10:2 FTS)

<0.05 ---- <0.05 ----µg/L0.05120226-60-0

EP231P: PFAS Sums

0.0562 ---- 0.0034 ---- 0.0213µg/L0.0003----Sum of PFAS

---- 0.13 ---- 0.24 ----µg/L0.01----Sum of PFAS

0.0407Sum of PFHxS and PFOS ---- 0.0011 ---- 0.0140µg/L0.0003355-46-4/1763-23-

1

----Sum of PFHxS and PFOS 0.13 ---- 0.24 ----µg/L0.01355-46-4/1763-23-

1

0.0562 ---- 0.0034 ---- 0.0196µg/L0.0003----Sum of PFAS (WA DER List)

---- 0.13 ---- 0.24 ----µg/L0.01----Sum of PFAS (WA DER List)


93.4 ---- 91.6 ---- 86.9%0.0005----13C4-PFOS

---- 113 ---- 108 ----%0.02----13C4-PFOS

120 ---- 99.2 ---- 98.0%0.0005----13C8-PFOA

---- 113 ---- 122 ----%0.02----13C8-PFOA

11 of 23:Page

Work Order :

:Client

ET1800988



Analytical Results

0874_MW221_S_1804

10

0874_MW263_S_1804

10

0874_MW270_S_1804

10

0874_MW267_S_1804

10

0874_MW220_S_1804

10


(Matrix: WATER)












3550Chloride 1440 4190 224 5460mg/L116887-00-6


311Calcium 121 370 25 324mg/L17440-70-2

200Magnesium 90 226 22 316mg/L17439-95-4

1750Sodium 909 2160 135 2850mg/L17440-23-5

5Potassium 4 1 3 14mg/L17440-09-7


111 52.0 131 9.16 173meq/L0.01----Total Anions

108 53.1 131 9.01 166meq/L0.01----Total Cations

1.38 1.07 <0.01 0.82 1.88%0.01----Ionic Balance



(PFBS)

---- 0.0024 ---- ----µg/L0.0005375-73-5


(PFBS)

0.09 ---- 0.10 0.64µg/L0.02375-73-5


(PFPeS)

---- 0.0007 ---- ----µg/L0.00052706-91-4


(PFPeS)

0.07 ---- 0.07 0.46µg/L0.022706-91-4


(PFHxS)

---- 0.0019 ---- ----µg/L0.0005355-46-4


(PFHxS)

0.58 ---- 0.68 5.12µg/L0.02355-46-4


(PFHpS)

---- <0.0005 ---- ----µg/L0.0005375-92-8


(PFHpS)

<0.02 ---- <0.02 0.15µg/L0.02375-92-8

12 of 23:Page

Work Order :

:Client

ET1800988



Analytical Results

0874_MW221_S_1804

10

0874_MW263_S_1804

10

0874_MW270_S_1804

10

0874_MW267_S_1804

10

0874_MW220_S_1804

10


(Matrix: WATER)






(PFOS)

---- 0.0013 ---- ----µg/L0.00031763-23-1


(PFDS)

---- <0.0005 ---- ----µg/L0.0005335-77-3


(PFOS)

0.32 ---- 0.41 1.72µg/L0.011763-23-1


(PFDS)

<0.02 ---- <0.02 <0.05µg/L0.02335-77-3


<0.002Perfluorobutanoic acid (PFBA) ---- <0.002 ---- ----µg/L0.002375-22-4

----Perfluorobutanoic acid (PFBA) <0.1 ---- <0.1 <0.2µg/L0.1375-22-4

0.0168Perfluoropentanoic acid (PFPeA) ---- <0.0005 ---- ----µg/L0.00052706-90-3

----Perfluoropentanoic acid (PFPeA) 0.06 ---- <0.02 0.15µg/L0.022706-90-3

0.0153Perfluorohexanoic acid (PFHxA) ---- 0.0005 ---- ----µg/L0.0005307-24-4

----Perfluorohexanoic acid (PFHxA) 0.09 ---- 0.04 0.89µg/L0.02307-24-4

0.0053Perfluoroheptanoic acid (PFHpA) ---- 0.0007 ---- ----µg/L0.0005375-85-9

----Perfluoroheptanoic acid (PFHpA) 0.04 ---- 0.02 <0.05µg/L0.02375-85-9

0.0049Perfluorooctanoic acid (PFOA) ---- 0.0056 ---- ----µg/L0.0005335-67-1

----Perfluorooctanoic acid (PFOA) 0.02 ---- 0.03 0.08µg/L0.01335-67-1

<0.0005Perfluorononanoic acid (PFNA) ---- <0.0005 ---- ----µg/L0.0005375-95-1

----Perfluorononanoic acid (PFNA) <0.02 ---- <0.02 <0.05µg/L0.02375-95-1

<0.0005Perfluorodecanoic acid (PFDA) ---- 0.0007 ---- ----µg/L0.0005335-76-2

----Perfluorodecanoic acid (PFDA) <0.02 ---- <0.02 <0.05µg/L0.02335-76-2


(PFUnDA)

---- <0.0005 ---- ----µg/L0.00052058-94-8


(PFUnDA)

<0.02 ---- <0.02 <0.05µg/L0.022058-94-8


(PFDoDA)

---- <0.0005 ---- ----µg/L0.0005307-55-1


(PFDoDA)

<0.02 ---- <0.02 <0.05µg/L0.02307-55-1


(PFTrDA)

---- <0.0005 ---- ----µg/L0.000572629-94-8


(PFTrDA)

<0.02 ---- <0.02 <0.05µg/L0.0272629-94-8

13 of 23:Page

Work Order :

:Client

ET1800988



Analytical Results

0874_MW221_S_1804

10

0874_MW263_S_1804

10

0874_MW270_S_1804

10

0874_MW267_S_1804

10

0874_MW220_S_1804

10


(Matrix: WATER)






(PFTeDA)

---- <0.0005 ---- ----µg/L0.0005376-06-7


(PFTeDA)

<0.05 ---- <0.05 <0.12µg/L0.05376-06-7



(FOSA)

---- <0.0005 ---- ----µg/L0.0005754-91-6


(FOSA)

<0.02 ---- <0.02 <0.05µg/L0.02754-91-6



---- <0.001 ---- ----µg/L0.00131506-32-8



<0.05 ---- <0.05 <0.12µg/L0.0531506-32-8



---- <0.001 ---- ----µg/L0.0014151-50-2



<0.05 ---- <0.05 <0.12µg/L0.054151-50-2



---- <0.001 ---- ----µg/L0.00124448-09-7



<0.05 ---- <0.05 <0.12µg/L0.0524448-09-7



---- <0.001 ---- ----µg/L0.0011691-99-2



<0.05 ---- <0.05 <0.12µg/L0.051691-99-2



(MeFOSAA)

---- <0.0005 ---- ----µg/L0.00052355-31-9



(MeFOSAA)

<0.02 ---- <0.02 <0.05µg/L0.022355-31-9



(EtFOSAA)

---- <0.0005 ---- ----µg/L0.00052991-50-6

14 of 23:Page

Work Order :

:Client

ET1800988



Analytical Results

0874_MW221_S_1804

10

0874_MW263_S_1804

10

0874_MW270_S_1804

10

0874_MW267_S_1804

10

0874_MW220_S_1804

10


(Matrix: WATER)







(EtFOSAA)

<0.02 ---- <0.02 <0.05µg/L0.022991-50-6



(4:2 FTS)

---- <0.001 ---- ----µg/L0.001757124-72-4


(4:2 FTS)

<0.05 ---- <0.05 <0.05µg/L0.05757124-72-4


(6:2 FTS)

---- <0.001 ---- ----µg/L0.00127619-97-2


(6:2 FTS)

<0.05 ---- <0.05 <0.05µg/L0.0527619-97-2


(8:2 FTS)

---- <0.001 ---- ----µg/L0.00139108-34-4


(8:2 FTS)

<0.05 ---- <0.05 <0.05µg/L0.0539108-34-4


(10:2 FTS)

---- <0.001 ---- ----µg/L0.001120226-60-0


(10:2 FTS)

<0.05 ---- <0.05 <0.05µg/L0.05120226-60-0

EP231P: PFAS Sums

0.151 ---- 0.0138 ---- ----µg/L0.0003----Sum of PFAS

---- 1.27 ---- 1.35 9.21µg/L0.01----Sum of PFAS

0.0776Sum of PFHxS and PFOS ---- 0.0032 ---- ----µg/L0.0003355-46-4/1763-23-

1

----Sum of PFHxS and PFOS 0.90 ---- 1.09 6.84µg/L0.01355-46-4/1763-23-

1

0.140 ---- 0.0124 ---- ----µg/L0.0003----Sum of PFAS (WA DER List)

---- 1.20 ---- 1.28 8.60µg/L0.01----Sum of PFAS (WA DER List)


82.7 ---- 86.9 ---- ----%0.0005----13C4-PFOS

---- 107 ---- 113 108%0.02----13C4-PFOS

88.8 ---- 95.0 ---- ----%0.0005----13C8-PFOA

---- 107 ---- 102 120%0.02----13C8-PFOA

15 of 23:Page

Work Order :

:Client

ET1800988



Analytical Results

0874_QC5MW_18041

0_04

0874_QC4MW_18041

0

0874_QC3MW_18041

0

0874_QC1MW_18041

0_02

0874_QC1MW_18041

0_01


(Matrix: WATER)





<1Hydroxide Alkalinity as CaCO3 <1 ---- ---- ----mg/L1DMO-210-001

<1Carbonate Alkalinity as CaCO3 <1 ---- ---- ----mg/L13812-32-6

325Bicarbonate Alkalinity as CaCO3 280 ---- ---- ----mg/L171-52-3

325 280 ---- ---- ----mg/L1----Total Alkalinity as CaCO3


52Sulfate as SO4 - Turbidimetric 273 ---- ---- ----mg/L114808-79-8


272Chloride 3640 ---- ---- ----mg/L116887-00-6


21Calcium 323 ---- ---- ----mg/L17440-70-2

17Magnesium 207 ---- ---- ----mg/L17439-95-4

290Sodium 1820 ---- ---- ----mg/L17440-23-5

<1Potassium 5 ---- ---- ----mg/L17440-09-7


15.2 114 ---- ---- ----meq/L0.01----Total Anions

15.1 112 ---- ---- ----meq/L0.01----Total Cations

0.62 0.67 ---- ---- ----%0.01----Ionic Balance



(PFBS)

0.0210 <0.0005 <0.0005 <0.0005µg/L0.0005375-73-5


(PFBS)

---- ---- ---- ----µg/L0.02375-73-5


(PFPeS)

0.0084 <0.0005 <0.0005 <0.0005µg/L0.00052706-91-4


(PFPeS)

---- ---- ---- ----µg/L0.022706-91-4


(PFHxS)

0.0355 <0.0005 <0.0005 <0.0005µg/L0.0005355-46-4


(PFHxS)

---- ---- ---- ----µg/L0.02355-46-4


(PFHpS)

0.0024 <0.0005 <0.0005 <0.0005µg/L0.0005375-92-8


(PFHpS)

---- ---- ---- ----µg/L0.02375-92-8

16 of 23:Page

Work Order :

:Client

ET1800988



Analytical Results

0874_QC5MW_18041

0_04

0874_QC4MW_18041

0

0874_QC3MW_18041

0

0874_QC1MW_18041

0_02

0874_QC1MW_18041

0_01


(Matrix: WATER)






(PFOS)

0.0450 <0.0003 <0.0003 <0.0003µg/L0.00031763-23-1


(PFDS)

<0.0005 <0.0005 <0.0005 <0.0005µg/L0.0005335-77-3


(PFOS)

---- ---- ---- ----µg/L0.011763-23-1


(PFDS)

---- ---- ---- ----µg/L0.02335-77-3


----Perfluorobutanoic acid (PFBA) <0.002 <0.002 <0.002 <0.002µg/L0.002375-22-4


----Perfluoropentanoic acid (PFPeA) 0.0179 <0.0005 <0.0005 <0.0005µg/L0.00052706-90-3


----Perfluorohexanoic acid (PFHxA) 0.0155 <0.0005 <0.0005 <0.0005µg/L0.0005307-24-4


----Perfluoroheptanoic acid (PFHpA) 0.0055 <0.0005 <0.0005 <0.0005µg/L0.0005375-85-9


----Perfluorooctanoic acid (PFOA) 0.0050 <0.0005 <0.0005 <0.0005µg/L0.0005335-67-1


----Perfluorononanoic acid (PFNA) <0.0005 <0.0005 <0.0005 <0.0005µg/L0.0005375-95-1


----Perfluorodecanoic acid (PFDA) <0.0005 <0.0005 <0.0005 <0.0005µg/L0.0005335-76-2



(PFUnDA)

<0.0005 <0.0005 <0.0005 <0.0005µg/L0.00052058-94-8


(PFUnDA)

---- ---- ---- ----µg/L0.022058-94-8


(PFDoDA)

<0.0005 <0.0005 <0.0005 <0.0005µg/L0.0005307-55-1


(PFDoDA)

---- ---- ---- ----µg/L0.02307-55-1


(PFTrDA)

<0.0005 <0.0005 <0.0005 <0.0005µg/L0.000572629-94-8


(PFTrDA)

---- ---- ---- ----µg/L0.0272629-94-8

17 of 23:Page

Work Order :

:Client

ET1800988



Analytical Results

0874_QC5MW_18041

0_04

0874_QC4MW_18041

0

0874_QC3MW_18041

0

0874_QC1MW_18041

0_02

0874_QC1MW_18041

0_01


(Matrix: WATER)






(PFTeDA)

<0.0005 <0.0005 <0.0005 <0.0005µg/L0.0005376-06-7


(PFTeDA)

---- ---- ---- ----µg/L0.05376-06-7



(FOSA)

<0.0005 <0.0005 <0.0005 <0.0005µg/L0.0005754-91-6


(FOSA)

---- ---- ---- ----µg/L0.02754-91-6



<0.001 <0.001 <0.001 <0.001µg/L0.00131506-32-8



---- ---- ---- ----µg/L0.0531506-32-8



<0.001 <0.001 <0.001 <0.001µg/L0.0014151-50-2



---- ---- ---- ----µg/L0.054151-50-2



<0.001 <0.001 <0.001 <0.001µg/L0.00124448-09-7



---- ---- ---- ----µg/L0.0524448-09-7



<0.001 <0.001 <0.001 <0.001µg/L0.0011691-99-2



---- ---- ---- ----µg/L0.051691-99-2



(MeFOSAA)

<0.0005 <0.0005 <0.0005 <0.0005µg/L0.00052355-31-9



(MeFOSAA)

---- ---- ---- ----µg/L0.022355-31-9



(EtFOSAA)

<0.0005 <0.0005 <0.0005 <0.0005µg/L0.00052991-50-6

18 of 23:Page

Work Order :

:Client

ET1800988



Analytical Results

0874_QC5MW_18041

0_04

0874_QC4MW_18041

0

0874_QC3MW_18041

0

0874_QC1MW_18041

0_02

0874_QC1MW_18041

0_01


(Matrix: WATER)







(EtFOSAA)

---- ---- ---- ----µg/L0.022991-50-6



(4:2 FTS)

<0.001 <0.001 <0.001 <0.001µg/L0.001757124-72-4


(4:2 FTS)

---- ---- ---- ----µg/L0.05757124-72-4


(6:2 FTS)

<0.001 <0.001 <0.001 <0.001µg/L0.00127619-97-2


(6:2 FTS)

---- ---- ---- ----µg/L0.0527619-97-2


(8:2 FTS)

<0.001 <0.001 <0.001 <0.001µg/L0.00139108-34-4


(8:2 FTS)

---- ---- ---- ----µg/L0.0539108-34-4


(10:2 FTS)

<0.001 <0.001 <0.001 <0.001µg/L0.001120226-60-0


(10:2 FTS)

---- ---- ---- ----µg/L0.05120226-60-0

EP231P: PFAS Sums

---- 0.156 <0.0003 <0.0003 <0.0003µg/L0.0003----Sum of PFAS

0.27 ---- ---- ---- ----µg/L0.01----Sum of PFAS

----Sum of PFHxS and PFOS 0.0805 <0.0003 <0.0003 <0.0003µg/L0.0003355-46-4/1763-23-

1


1

---- 0.145 <0.0003 <0.0003 <0.0003µg/L0.0003----Sum of PFAS (WA DER List)

0.27 ---- ---- ---- ----µg/L0.01----Sum of PFAS (WA DER List)


---- 91.2 88.6 66.9 65.7%0.0005----13C4-PFOS

119 ---- ---- ---- ----%0.02----13C4-PFOS

---- 93.2 116 99.6 100%0.0005----13C8-PFOA

96.9 ---- ---- ---- ----%0.02----13C8-PFOA

19 of 23:Page

Work Order :

:Client

ET1800988



Analytical Results

------------0874_MW266_S_1804

10

0874_QC5MW_18041

0_03


(Matrix: WATER)

------------10-Apr-2018 00:0010-Apr-2018 00:00Client sampling date / time




----Hydroxide Alkalinity as CaCO3 <1 ---- ---- ----mg/L1DMO-210-001

----Carbonate Alkalinity as CaCO3 <1 ---- ---- ----mg/L13812-32-6

----Bicarbonate Alkalinity as CaCO3 327 ---- ---- ----mg/L171-52-3

---- 327 ---- ---- ----mg/L1----Total Alkalinity as CaCO3


----Sulfate as SO4 - Turbidimetric 785 ---- ---- ----mg/L114808-79-8


----Chloride 7420 ---- ---- ----mg/L116887-00-6


----Calcium 398 ---- ---- ----mg/L17440-70-2

----Magnesium 503 ---- ---- ----mg/L17439-95-4

----Sodium 4340 ---- ---- ----mg/L17440-23-5

----Potassium 68 ---- ---- ----mg/L17440-09-7


---- 232 ---- ---- ----meq/L0.01----Total Anions

---- 252 ---- ---- ----meq/L0.01----Total Cations

---- 4.05 ---- ---- ----%0.01----Ionic Balance



(PFBS)

0.0127 ---- ---- ----µg/L0.0005375-73-5


(PFBS)

---- ---- ---- ----µg/L0.02375-73-5


(PFPeS)

<0.0005 ---- ---- ----µg/L0.00052706-91-4


(PFPeS)

---- ---- ---- ----µg/L0.022706-91-4


(PFHxS)

0.0030 ---- ---- ----µg/L0.0005355-46-4


(PFHxS)

---- ---- ---- ----µg/L0.02355-46-4


(PFHpS)

<0.0005 ---- ---- ----µg/L0.0005375-92-8


(PFHpS)

---- ---- ---- ----µg/L0.02375-92-8

20 of 23:Page

Work Order :

:Client

ET1800988



Analytical Results

------------0874_MW266_S_1804

10

0874_QC5MW_18041

0_03


(Matrix: WATER)






(PFOS)

0.0044 ---- ---- ----µg/L0.00031763-23-1


(PFDS)

<0.0005 ---- ---- ----µg/L0.0005335-77-3


(PFOS)

---- ---- ---- ----µg/L0.011763-23-1


(PFDS)

---- ---- ---- ----µg/L0.02335-77-3


----Perfluorobutanoic acid (PFBA) <0.002 ---- ---- ----µg/L0.002375-22-4


----Perfluoropentanoic acid (PFPeA) <0.0005 ---- ---- ----µg/L0.00052706-90-3


----Perfluorohexanoic acid (PFHxA) 0.0008 ---- ---- ----µg/L0.0005307-24-4


----Perfluoroheptanoic acid (PFHpA) 0.0009 ---- ---- ----µg/L0.0005375-85-9


----Perfluorooctanoic acid (PFOA) 0.0024 ---- ---- ----µg/L0.0005335-67-1


----Perfluorononanoic acid (PFNA) <0.0005 ---- ---- ----µg/L0.0005375-95-1


----Perfluorodecanoic acid (PFDA) <0.0005 ---- ---- ----µg/L0.0005335-76-2



(PFUnDA)

<0.0005 ---- ---- ----µg/L0.00052058-94-8


(PFUnDA)

---- ---- ---- ----µg/L0.022058-94-8


(PFDoDA)

<0.0005 ---- ---- ----µg/L0.0005307-55-1


(PFDoDA)

---- ---- ---- ----µg/L0.02307-55-1


(PFTrDA)

<0.0005 ---- ---- ----µg/L0.000572629-94-8


(PFTrDA)

---- ---- ---- ----µg/L0.0272629-94-8

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Analytical Results

------------0874_MW266_S_1804

10

0874_QC5MW_18041

0_03


(Matrix: WATER)






(PFTeDA)

<0.0005 ---- ---- ----µg/L0.0005376-06-7


(PFTeDA)

---- ---- ---- ----µg/L0.05376-06-7



(FOSA)

<0.0005 ---- ---- ----µg/L0.0005754-91-6


(FOSA)

---- ---- ---- ----µg/L0.02754-91-6



<0.001 ---- ---- ----µg/L0.00131506-32-8



---- ---- ---- ----µg/L0.0531506-32-8



<0.001 ---- ---- ----µg/L0.0014151-50-2



---- ---- ---- ----µg/L0.054151-50-2



<0.001 ---- ---- ----µg/L0.00124448-09-7



---- ---- ---- ----µg/L0.0524448-09-7



<0.001 ---- ---- ----µg/L0.0011691-99-2



---- ---- ---- ----µg/L0.051691-99-2



(MeFOSAA)

<0.0005 ---- ---- ----µg/L0.00052355-31-9



(MeFOSAA)

---- ---- ---- ----µg/L0.022355-31-9



(EtFOSAA)

<0.0005 ---- ---- ----µg/L0.00052991-50-6

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Analytical Results

------------0874_MW266_S_1804

10

0874_QC5MW_18041

0_03


(Matrix: WATER)







(EtFOSAA)

---- ---- ---- ----µg/L0.022991-50-6



(4:2 FTS)

<0.001 ---- ---- ----µg/L0.001757124-72-4


(4:2 FTS)

---- ---- ---- ----µg/L0.05757124-72-4


(6:2 FTS)

<0.001 ---- ---- ----µg/L0.00127619-97-2


(6:2 FTS)

---- ---- ---- ----µg/L0.0527619-97-2


(8:2 FTS)

<0.001 ---- ---- ----µg/L0.00139108-34-4


(8:2 FTS)

---- ---- ---- ----µg/L0.0539108-34-4


(10:2 FTS)

<0.001 ---- ---- ----µg/L0.001120226-60-0


(10:2 FTS)

---- ---- ---- ----µg/L0.05120226-60-0

EP231P: PFAS Sums

---- 0.0242 ---- ---- ----µg/L0.0003----Sum of PFAS

<0.01 ---- ---- ---- ----µg/L0.01----Sum of PFAS

----Sum of PFHxS and PFOS 0.0074 ---- ---- ----µg/L0.0003355-46-4/1763-23-

1

<0.01Sum of PFHxS and PFOS ---- ---- ---- ----µg/L0.01355-46-4/1763-23-

1

---- 0.0242 ---- ---- ----µg/L0.0003----Sum of PFAS (WA DER List)

<0.01 ---- ---- ---- ----µg/L0.01----Sum of PFAS (WA DER List)


---- 97.3 ---- ---- ----%0.0005----13C4-PFOS

94.5 ---- ---- ---- ----%0.02----13C4-PFOS

---- 77.1 ---- ---- ----%0.0005----13C8-PFOA

97.7 ---- ---- ---- ----%0.02----13C8-PFOA

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ET1800988







13C4-PFOS ---- 60 130

13C8-PFOA ---- 60 130

False

4 4.00True

Environmental




:Address MOBIL

C/O GPO BOX 2907







Sampler : JM

Site : ----
















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General Comments










Key :









ED037-P: Carbonate Alkalinity as CaCO3 3812-32-6 1 mg/L 29 29 0.00 0% - 20%



ED037-P: Hydroxide Alkalinity as CaCO3 DMO-210-001 1 mg/L <1 <1 0.00 No Limit0874_MW259_S_180410 ET1800988-001











ED041G: Sulfate as SO4 - Turbidimetric 14808-79-8 1 mg/L 54 53 2.30 0% - 20%0874_MW259_S_180410 ET1800988-001





ED045G: Chloride 16887-00-6 1 mg/L 277 274 0.969 0% - 20%0874_MW259_S_180410 ET1800988-001




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ED093F: Dissolved Major Cations (QC Lot: 1564895) - continued



ED093F: Sodium 7440-23-5 1 mg/L 64 65 0.00 0% - 20%




ED093F: Sodium 7440-23-5 1 mg/L 42 42 0.00 0% - 20%



ED093F: Calcium 7440-70-2 1 mg/L 37 38 0.00 0% - 20%0874_MW258_S_180410 ET1800988-003


ED093F: Sodium 7440-23-5 1 mg/L 568 578 1.70 0% - 20%

ED093F: Potassium 7440-09-7 1 mg/L <1 <1 0.00 No Limit



ED093F: Sodium 7440-23-5 1 mg/L 909 909 0.00 0% - 20%









EP231X: Perfluorooctane sulfonic acid (PFOS) 1763-23-1 0.01 µg/L 7.04 7.14 1.31 0% - 20%Anonymous ET1800983-005







EP231X: Perfluorooctane sulfonic acid (PFOS) 1763-23-1 0.01 µg/L 0.23 0.23 0.00 0% - 20%0874_MW225_S_180410 ET1800988-002

EP231X: Perfluorobutane sulfonic acid (PFBS) 375-73-5 0.02 µg/L 0.04 0.05 0.00 No Limit






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(PFOS)



(PFBS)

375-73-5 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFPeS)

2706-91-4 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFHxS)

355-46-4 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFHpS)

375-92-8 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFDS)

335-77-3 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFOS)

1763-23-1 0.0003 µg/L 0.0381 0.0396 3.91 0% - 20%Anonymous ET1800983-002


(PFBS)

375-73-5 0.0005 µg/L 0.0085 0.0087 2.10 0% - 50%


(PFPeS)

2706-91-4 0.0005 µg/L 0.0053 0.0058 8.94 0% - 50%


(PFHxS)

355-46-4 0.0005 µg/L 0.0383 0.0389 1.66 0% - 20%


(PFHpS)

375-92-8 0.0005 µg/L 0.0012 0.0012 0.00 No Limit


(PFDS)

335-77-3 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit



(PFOS)

1763-23-1 0.0003 µg/L <0.0003 <0.0003 0.00 No Limit0874_QC3MW_180410 ET1800988-018


(PFBS)

375-73-5 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFPeS)

2706-91-4 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFHxS)

355-46-4 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFHpS)

375-92-8 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFDS)

335-77-3 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFOS)

1763-23-1 0.0003 µg/L <0.0003 <0.0003 0.00 No Limit0874_QC5MW_180410_04 ET1800988-020


(PFBS)

375-73-5 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit

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(PFPeS)



(PFHxS)

355-46-4 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFHpS)

375-92-8 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFDS)

335-77-3 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit













EP231X: Perfluorooctanoic acid (PFOA) 335-67-1 0.01 µg/L 0.50 0.53 4.64 0% - 20%Anonymous ET1800983-005












EP231X: Perfluorooctanoic acid (PFOA) 335-67-1 0.01 µg/L <0.01 <0.01 0.00 No Limit0874_MW225_S_180410 ET1800988-002








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EP231X: Perfluorotridecanoic acid (PFTrDA) 72629-94-8 0.02 µg/L <0.02 <0.02 0.00 No Limit0874_MW225_S_180410 ET1800988-002














(PFTeDA)

376-06-7 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


EP231X-ST: Perfluoropentanoic acid (PFPeA) 2706-90-3 0.0005 µg/L 0.0036 0.0033 10.5 No LimitAnonymous ET1800983-002


EP231X-ST: Perfluoroheptanoic acid (PFHpA) 375-85-9 0.0005 µg/L 0.0023 0.0020 16.0 No Limit

EP231X-ST: Perfluorooctanoic acid (PFOA) 335-67-1 0.0005 µg/L 0.0028 0.0026 7.41 No Limit







(PFTeDA)

376-06-7 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit



EP231X-ST: Perfluoropentanoic acid (PFPeA) 2706-90-3 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit0874_QC3MW_180410 ET1800988-018










(PFTeDA)

376-06-7 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit

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EP231X-ST: Perfluorobutanoic acid (PFBA) 375-22-4 0.002 µg/L <0.002 <0.002 0.00 No Limit0874_QC3MW_180410 ET1800988-018

EP231X-ST: Perfluoropentanoic acid (PFPeA) 2706-90-3 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit0874_QC5MW_180410_04 ET1800988-020










(PFTeDA)

376-06-7 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit






2355-31-9 0.02 µg/L <0.02 <0.02 0.00 No Limit



2991-50-6 0.02 µg/L <0.02 <0.02 0.00 No Limit


(MeFOSA)

31506-32-8 0.05 µg/L <0.05 <0.05 0.00 No Limit


(EtFOSA)

4151-50-2 0.05 µg/L <0.05 <0.05 0.00 No Limit



24448-09-7 0.05 µg/L <0.05 <0.05 0.00 No Limit



1691-99-2 0.05 µg/L <0.05 <0.05 0.00 No Limit

EP231X: Perfluorooctane sulfonamide (FOSA) 754-91-6 0.02 µg/L <0.02 <0.02 0.00 No LimitAnonymous ET1800983-005



2355-31-9 0.02 µg/L <0.02 <0.02 0.00 No Limit



2991-50-6 0.02 µg/L <0.02 <0.02 0.00 No Limit


(MeFOSA)

31506-32-8 0.05 µg/L <0.05 <0.05 0.00 No Limit


(EtFOSA)

4151-50-2 0.05 µg/L <0.05 <0.05 0.00 No Limit



24448-09-7 0.05 µg/L <0.05 <0.05 0.00 No Limit



1691-99-2 0.05 µg/L <0.05 <0.05 0.00 No Limit


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EP231X: Perfluorooctane sulfonamide (FOSA) 754-91-6 0.02 µg/L <0.02 <0.02 0.00 No Limit0874_MW225_S_180410 ET1800988-002



2355-31-9 0.02 µg/L <0.02 <0.02 0.00 No Limit



2991-50-6 0.02 µg/L <0.02 <0.02 0.00 No Limit


(MeFOSA)

31506-32-8 0.05 µg/L <0.05 <0.05 0.00 No Limit


(EtFOSA)

4151-50-2 0.05 µg/L <0.05 <0.05 0.00 No Limit



24448-09-7 0.05 µg/L <0.05 <0.05 0.00 No Limit



1691-99-2 0.05 µg/L <0.05 <0.05 0.00 No Limit



(FOSA)




2355-31-9 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit



2991-50-6 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit



31506-32-8 0.001 µg/L <0.001 <0.001 0.00 No Limit


(EtFOSA)

4151-50-2 0.001 µg/L <0.001 <0.001 0.00 No Limit



24448-09-7 0.001 µg/L <0.001 <0.001 0.00 No Limit



1691-99-2 0.001 µg/L <0.001 <0.001 0.00 No Limit


(FOSA)




2355-31-9 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit



2991-50-6 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit



31506-32-8 0.001 µg/L <0.001 <0.001 0.00 No Limit


(EtFOSA)

4151-50-2 0.001 µg/L <0.001 <0.001 0.00 No Limit



24448-09-7 0.001 µg/L <0.001 <0.001 0.00 No Limit

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(FOSA)




2355-31-9 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit



2991-50-6 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit



31506-32-8 0.001 µg/L <0.001 <0.001 0.00 No Limit


(EtFOSA)

4151-50-2 0.001 µg/L <0.001 <0.001 0.00 No Limit



24448-09-7 0.001 µg/L <0.001 <0.001 0.00 No Limit



1691-99-2 0.001 µg/L <0.001 <0.001 0.00 No Limit


(FOSA)




2355-31-9 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit



2991-50-6 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit



31506-32-8 0.001 µg/L <0.001 <0.001 0.00 No Limit


(EtFOSA)

4151-50-2 0.001 µg/L <0.001 <0.001 0.00 No Limit



24448-09-7 0.001 µg/L <0.001 <0.001 0.00 No Limit



1691-99-2 0.001 µg/L <0.001 <0.001 0.00 No Limit



FTS)



FTS)

27619-97-2 0.05 µg/L 0.15 0.15 0.00 No Limit


FTS)

39108-34-4 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

120226-60-0 0.05 µg/L <0.05 <0.05 0.00 No Limit

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FTS)



FTS)

27619-97-2 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

39108-34-4 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

120226-60-0 0.05 µg/L <0.05 <0.05 0.00 No Limit



FTS)

757124-72-4 0.05 µg/L <0.05 <0.05 0.00 No Limit0874_MW225_S_180410 ET1800988-002


FTS)

27619-97-2 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

39108-34-4 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

120226-60-0 0.05 µg/L <0.05 <0.05 0.00 No Limit



FTS)



FTS)

27619-97-2 0.001 µg/L <0.001 <0.001 0.00 No Limit


FTS)

39108-34-4 0.001 µg/L <0.001 <0.001 0.00 No Limit


(10:2 FTS)

120226-60-0 0.001 µg/L <0.001 <0.001 0.00 No Limit


FTS)



FTS)

27619-97-2 0.001 µg/L <0.001 <0.001 0.00 No Limit


FTS)

39108-34-4 0.001 µg/L <0.001 <0.001 0.00 No Limit


(10:2 FTS)

120226-60-0 0.001 µg/L <0.001 <0.001 0.00 No Limit



FTS)



FTS)

27619-97-2 0.001 µg/L <0.001 <0.001 0.00 No Limit


FTS)

39108-34-4 0.001 µg/L <0.001 <0.001 0.00 No Limit

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(10:2 FTS)



FTS)



FTS)

27619-97-2 0.001 µg/L <0.001 <0.001 0.00 No Limit


FTS)

39108-34-4 0.001 µg/L <0.001 <0.001 0.00 No Limit


(10:2 FTS)

120226-60-0 0.001 µg/L <0.001 <0.001 0.00 No Limit


EP231X: Sum of PFAS ---- 0.01 µg/L 0.60 0.50 18.2 0% - 20%Anonymous ES1810438-001

EP231X: Sum of PFAS ---- 0.01 µg/L 17.0 17.9 5.62 0% - 20%Anonymous ET1800983-005


EP231X: Sum of PFAS ---- 0.01 µg/L 0.47 0.49 4.17 0% - 20%0874_MW225_S_180410 ET1800988-002


EP231X-ST: Sum of PFAS ---- 0.0003 µg/L <0.0003 <0.0003 0.00 No LimitAnonymous ES1810551-001



EP231X-ST: Sum of PFAS ---- 0.0003 µg/L <0.0003 <0.0003 0.00 No Limit0874_QC3MW_180410 ET1800988-018

EP231X-ST: Sum of PFAS ---- 0.0003 µg/L <0.0003 <0.0003 0.00 No Limit0874_QC5MW_180410_04 ET1800988-020

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Report










<1 98.825 mg/L 12080



<1 10325 mg/L 12080



<1 95.910 mg/L 12080



<1 88.110 mg/L 12080


ED093F: Calcium 7440-70-2 1 mg/L <1 -------- --------


ED093F: Sodium 7440-23-5 1 mg/L <1 -------- --------



ED093F: Calcium 7440-70-2 1 mg/L <1 -------- --------


ED093F: Sodium 7440-23-5 1 mg/L <1 -------- --------










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Report







EP231X: Perfluorohexane sulfonic acid (PFHxS) 355-46-4 0.02 µg/L <0.02 99.80.5 µg/L 13070

EP231X: Perfluoroheptane sulfonic acid (PFHpS) 375-92-8 0.02 µg/L <0.02 94.80.5 µg/L 13070

































EP231X: Perfluoroheptanoic acid (PFHpA) 375-85-9 0.02 µg/L <0.02 1110.5 µg/L 13070


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Report







EP231X: Perfluoroundecanoic acid (PFUnDA) 2058-94-8 0.02 µg/L <0.02 1040.5 µg/L 13070

EP231X: Perfluorododecanoic acid (PFDoDA) 307-55-1 0.02 µg/L <0.02 88.60.5 µg/L 13070

EP231X: Perfluorotridecanoic acid (PFTrDA) 72629-94-8 0.02 µg/L <0.02 99.00.5 µg/L 13070

EP231X: Perfluorotetradecanoic acid (PFTeDA) 376-06-7 0.05 µg/L <0.05 74.71.25 µg/L 15070






























(MeFOSE)

24448-09-7 0.05 µg/L <0.05 1191.25 µg/L 15070


(EtFOSE)

1691-99-2 0.05 µg/L <0.05 1271.25 µg/L 15070

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Report






(MeFOSAA)

2355-31-9 0.02 µg/L <0.02 86.00.5 µg/L 13070


(EtFOSAA)

2991-50-6 0.02 µg/L <0.02 92.20.5 µg/L 13070




EP231X: N-Ethyl perfluorooctane sulfonamide (EtFOSA) 4151-50-2 0.05 µg/L <0.05 96.21.25 µg/L 15070


(MeFOSE)

24448-09-7 0.05 µg/L <0.05 1241.25 µg/L 15070


(EtFOSE)

1691-99-2 0.05 µg/L <0.05 96.51.25 µg/L 15070


(MeFOSAA)

2355-31-9 0.02 µg/L <0.02 1070.5 µg/L 13070


(EtFOSAA)

2991-50-6 0.02 µg/L <0.02 85.20.5 µg/L 13070




(MeFOSA)

31506-32-8 0.001 µg/L <0.001 52.30.025 µg/L 13040



(MeFOSE)

24448-09-7 0.001 µg/L <0.001 63.90.025 µg/L 13040


(EtFOSE)

1691-99-2 0.001 µg/L <0.001 62.30.025 µg/L 13040


acid (MeFOSAA)

2355-31-9 0.0005 µg/L <0.0005 45.60.01 µg/L 13040


acid (EtFOSAA)

2991-50-6 0.0005 µg/L <0.0005 40.60.01 µg/L 13040




(MeFOSA)

31506-32-8 0.001 µg/L <0.001 51.40.025 µg/L 13040



(MeFOSE)

24448-09-7 0.001 µg/L <0.001 57.90.025 µg/L 13040


(EtFOSE)

1691-99-2 0.001 µg/L <0.001 49.80.025 µg/L 13040

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Report






acid (MeFOSAA)

2355-31-9 0.0005 µg/L <0.0005 50.60.01 µg/L 13040


acid (EtFOSAA)

2991-50-6 0.0005 µg/L <0.0005 46.40.01 µg/L 13040































Anonymous ET1800983-002

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ED041G: Sulfate (Turbidimetric) as SO4 2- by DA (QCLot: 1561670) - continued

Anonymous ET1800983-002 14808-79-8ED041G: Sulfate as SO4 - Turbidimetric # Not

Determined

20 mg/L 13070


0874_MW267_S_180410 ET1800988-012 14808-79-8ED041G: Sulfate as SO4 - Turbidimetric # Not

Determined

20 mg/L 13070


Anonymous ET1800983-002 16887-00-6ED045G: Chloride # Not

Determined

400 mg/L 13070


0874_MW267_S_180410 ET1800988-012 16887-00-6ED045G: Chloride 89.0400 mg/L 13070


Anonymous ES1810438-001 375-73-5EP231X: Perfluorobutane sulfonic acid (PFBS) 91.40.5 µg/L 13050





335-77-3EP231X: Perfluorodecane sulfonic acid (PFDS) 1230.5 µg/L 13050


0874_MW225_S_180410 ET1800988-002 375-73-5EP231X: Perfluorobutane sulfonic acid (PFBS) 1040.5 µg/L 13050

2706-91-4EP231X: Perfluoropentane sulfonic acid (PFPeS) 1130.5 µg/L 13050













0874_QC4MW_180410 ET1800988-019 375-73-5EP231X-ST: Perfluorobutane sulfonic acid (PFBS) 77.20.01 µg/L 13050





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0874_QC4MW_180410 ET1800988-019 335-77-3EP231X-ST: Perfluorodecane sulfonic acid (PFDS) 52.40.01 µg/L 13030














0874_MW225_S_180410 ET1800988-002 375-22-4EP231X: Perfluorobutanoic acid (PFBA) 1042.5 µg/L 13050







2058-94-8EP231X: Perfluoroundecanoic acid (PFUnDA) 1150.5 µg/L 13050

307-55-1EP231X: Perfluorododecanoic acid (PFDoDA) 1130.5 µg/L 13050

72629-94-8EP231X: Perfluorotridecanoic acid (PFTrDA) 1200.5 µg/L 13050















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0874_QC4MW_180410 ET1800988-019 375-22-4EP231X-ST: Perfluorobutanoic acid (PFBA) 59.40.05 µg/L 13030



375-85-9EP231X-ST: Perfluoroheptanoic acid (PFHpA) 85.80.01 µg/L 13050

335-67-1EP231X-ST: Perfluorooctanoic acid (PFOA) 1060.01 µg/L 13050








Anonymous ES1810438-001 754-91-6EP231X: Perfluorooctane sulfonamide (FOSA) 1050.5 µg/L 13050


(MeFOSA)

1141.25 µg/L 15050


24448-09-7EP231X: N-Methyl perfluorooctane sulfonamidoethanol

(MeFOSE)

1281.25 µg/L 15050


(EtFOSE)

90.31.25 µg/L 15050


acid (MeFOSAA)

97.40.5 µg/L 13050


acid (EtFOSAA)

90.60.5 µg/L 13050


0874_MW225_S_180410 ET1800988-002 754-91-6EP231X: Perfluorooctane sulfonamide (FOSA) 95.60.5 µg/L 13050


(MeFOSA)

1281.25 µg/L 15050



(MeFOSE)

1151.25 µg/L 15050


(EtFOSE)

97.81.25 µg/L 15050


acid (MeFOSAA)

1170.5 µg/L 13050


acid (EtFOSAA)

82.60.5 µg/L 13050



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Anonymous ES1810551-002 31506-32-8EP231X-ST: N-Methyl perfluorooctane sulfonamide

(MeFOSA)

46.00.025 µg/L 13030


(EtFOSA)

59.20.025 µg/L 13030



39.90.025 µg/L 13030



34.20.025 µg/L 13030



41.20.01 µg/L 13030


acid (EtFOSAA)

30.20.01 µg/L 13030


0874_QC4MW_180410 ET1800988-019 754-91-6EP231X-ST: Perfluorooctane sulfonamide (FOSA) 69.40.01 µg/L 13030


(MeFOSA)

47.00.025 µg/L 13030


(EtFOSA)

42.70.025 µg/L 13030



60.80.025 µg/L 13030



49.80.025 µg/L 13030



50.60.01 µg/L 13030


acid (EtFOSAA)

52.00.01 µg/L 13030







0874_MW225_S_180410 ET1800988-002 757124-72-4EP231X: 4:2 Fluorotelomer sulfonic acid (4:2 FTS) 93.20.5 µg/L 13050






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Anonymous ES1810551-002 27619-97-2EP231X-ST: 6:2 Fluorotelomer sulfonic acid (6:2 FTS) 1030.01 µg/L 13050




0874_QC4MW_180410 ET1800988-019 757124-72-4EP231X-ST: 4:2 Fluorotelomer sulfonic acid (4:2 FTS) 84.00.01 µg/L 13050




True

Environmental






JM:Sampler No. of samples received : 22






Summary of Outliers













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Matrix: WATER



ET1800983--002 14808-79-8Sulfate as SO4 -

Turbidimetric




----Not

Determined


ET1800988--012 14808-79-8Sulfate as SO4 -

Turbidimetric

0874_MW267_S_180410 MS recovery not determined,



----Not

Determined


ET1800983--002 16887-00-6ChlorideAnonymous MS recovery not determined,



----Not

Determined















0874_MW259_S_180410, 0874_MW225_S_180410,

0874_MW258_S_180410, 0874_MW257_S_180410,

0874_MW236_S_180410, 0874_MW269_S_180410,

0874_MW218_S_180410, 0874_MW268_S_180410,

0874_MW260_S_180410, 0874_MW219_S_180410,

0874_MW220_S_180410, 0874_MW267_S_180410,

0874_MW270_S_180410, 0874_MW263_S_180410,

0874_MW221_S_180410, 0874_QC1MW_180410_01,

0874_QC1MW_180410_02, 0874_MW266_S_180410

24-Apr-2018---- 11-Apr-2018----10-Apr-2018 ---- ü

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0874_MW259_S_180410, 0874_MW225_S_180410,

0874_MW258_S_180410, 0874_MW257_S_180410,

0874_MW236_S_180410, 0874_MW269_S_180410,

0874_MW218_S_180410, 0874_MW268_S_180410,

0874_MW260_S_180410, 0874_MW219_S_180410,

0874_MW220_S_180410, 0874_MW267_S_180410,

0874_MW270_S_180410, 0874_MW263_S_180410,

0874_MW221_S_180410, 0874_QC1MW_180410_01,

0874_QC1MW_180410_02, 0874_MW266_S_180410

08-May-2018---- 12-Apr-2018----10-Apr-2018 ---- ü



0874_MW259_S_180410, 0874_MW225_S_180410,

0874_MW258_S_180410, 0874_MW257_S_180410,

0874_MW236_S_180410, 0874_MW269_S_180410,

0874_MW218_S_180410, 0874_MW268_S_180410,

0874_MW260_S_180410, 0874_MW219_S_180410,

0874_MW220_S_180410, 0874_MW267_S_180410,

0874_MW270_S_180410, 0874_MW263_S_180410,

0874_MW221_S_180410, 0874_QC1MW_180410_01,

0874_QC1MW_180410_02, 0874_MW266_S_180410

08-May-2018---- 12-Apr-2018----10-Apr-2018 ---- ü



0874_MW259_S_180410, 0874_MW225_S_180410,

0874_MW258_S_180410, 0874_MW257_S_180410,

0874_MW236_S_180410, 0874_MW269_S_180410,

0874_MW218_S_180410, 0874_MW268_S_180410,

0874_MW260_S_180410, 0874_MW219_S_180410,

0874_MW220_S_180410, 0874_MW267_S_180410,

0874_MW270_S_180410, 0874_MW263_S_180410,

0874_MW221_S_180410, 0874_QC1MW_180410_01,

0874_QC1MW_180410_02, 0874_MW266_S_180410

17-Apr-2018---- 13-Apr-2018----10-Apr-2018 ---- ü

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0874_MW259_S_180410, 0874_MW225_S_180410,

0874_MW258_S_180410, 0874_MW218_S_180410,

0874_MW260_S_180410, 0874_MW267_S_180410,

0874_MW263_S_180410, 0874_MW221_S_180410,

0874_QC1MW_180410_01, 0874_QC5MW_180410_03

07-Oct-2018---- 17-Apr-2018----10-Apr-2018 ---- ü


0874_MW257_S_180410, 0874_MW236_S_180410 07-Oct-201807-Oct-2018 13-Apr-201813-Apr-201810-Apr-2018 ü üHDPE (no PTFE) (EP231X-ST)

0874_MW269_S_180410, 0874_MW268_S_180410,

0874_MW219_S_180410, 0874_MW220_S_180410,

0874_MW270_S_180410, 0874_QC1MW_180410_02,

0874_QC3MW_180410, 0874_QC4MW_180410,

0874_QC5MW_180410_04, 0874_MW266_S_180410




0874_MW259_S_180410, 0874_MW225_S_180410,

0874_MW258_S_180410, 0874_MW218_S_180410,

0874_MW260_S_180410, 0874_MW267_S_180410,

0874_MW263_S_180410, 0874_MW221_S_180410,

0874_QC1MW_180410_01, 0874_QC5MW_180410_03

07-Oct-2018---- 17-Apr-2018----10-Apr-2018 ---- ü



0874_MW269_S_180410, 0874_MW268_S_180410,

0874_MW219_S_180410, 0874_MW220_S_180410,

0874_MW270_S_180410, 0874_QC1MW_180410_02,

0874_QC3MW_180410, 0874_QC4MW_180410,

0874_QC5MW_180410_04, 0874_MW266_S_180410


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0874_MW259_S_180410, 0874_MW225_S_180410,

0874_MW258_S_180410, 0874_MW218_S_180410,

0874_MW260_S_180410, 0874_MW267_S_180410,

0874_MW263_S_180410, 0874_MW221_S_180410,

0874_QC1MW_180410_01, 0874_QC5MW_180410_03

07-Oct-2018---- 17-Apr-2018----10-Apr-2018 ---- ü



0874_MW269_S_180410, 0874_MW268_S_180410,

0874_MW219_S_180410, 0874_MW220_S_180410,

0874_MW270_S_180410, 0874_QC1MW_180410_02,

0874_QC3MW_180410, 0874_QC4MW_180410,

0874_QC5MW_180410_04, 0874_MW266_S_180410




0874_MW259_S_180410, 0874_MW225_S_180410,

0874_MW258_S_180410, 0874_MW218_S_180410,

0874_MW260_S_180410, 0874_MW267_S_180410,

0874_MW263_S_180410, 0874_MW221_S_180410,

0874_QC1MW_180410_01, 0874_QC5MW_180410_03

07-Oct-2018---- 17-Apr-2018----10-Apr-2018 ---- ü



0874_MW269_S_180410, 0874_MW268_S_180410,

0874_MW219_S_180410, 0874_MW220_S_180410,

0874_MW270_S_180410, 0874_QC1MW_180410_02,

0874_QC3MW_180410, 0874_QC4MW_180410,

0874_QC5MW_180410_04, 0874_MW266_S_180410


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EP231P: PFAS Sums


0874_MW259_S_180410, 0874_MW225_S_180410,

0874_MW258_S_180410, 0874_MW218_S_180410,

0874_MW260_S_180410, 0874_MW267_S_180410,

0874_MW263_S_180410, 0874_MW221_S_180410,

0874_QC1MW_180410_01, 0874_QC5MW_180410_03

07-Oct-2018---- 17-Apr-2018----10-Apr-2018 ---- ü



0874_MW269_S_180410, 0874_MW268_S_180410,

0874_MW219_S_180410, 0874_MW220_S_180410,

0874_MW270_S_180410, 0874_QC1MW_180410_02,

0874_QC3MW_180410, 0874_QC4MW_180410,

0874_QC5MW_180410_04, 0874_MW266_S_180410


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Method Blanks (MB)






Matrix Spikes (MS)





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Schedule B(3)







Discrete Analyser

ED041G WATER











Schedule B(3)



DA

EN055 - PG WATER










(PFAS) by LCMSMS

EP231X WATER










(PFAS) by LCMSMS

EP231X-ST WATER

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Environmental





C/O GPO BOX 2907



QLD AUSTRALIA 4814






V4)


Site : ----

Sampler : JM



Date

19-Apr-2018




General Comments






l Please be advised that for sample "0874_QC5MW_180410_03" ALS #21 EP231X-ST cannot be

assigned due to volume received (only 60ml PFAS water bottle was received). Thus, EP231X

analysis was assigned for this sample. Please contact client services at

[email protected] if this is incorrect.l Please be advised that an extra sample "0874_MW266_S_180410" was received in addition to the

samples listed on the COC. This sample has been added to the end of the work order and was

assigned with EP231X-ST and NT1+NT2 analysis as confirmed by Phil Schulz via email 11.4.18.l Discounted Package Prices apply only when specific ALS Group Codes ('W', 'S', 'NT' suites) are referenced on COCs.


l EP231X-ST and EP231X conducted by ALS Sydney, NATA accreditation no. 825, site no 10911.












ET1800988-016 : [ 10-Apr-2018 ] : 0874_QC1MW_180410_01

ET1800988-017 : [ 10-Apr-2018 ] : 0874_QC1MW_180410_02

ET1800988-020 : [ 10-Apr-2018 ] : 0874_QC5MW_180410_04

ET1800988-021 : [ 10-Apr-2018 ] : 0874_QC5MW_180410_03











component

WA

TE

R -

EP

23

1X

PF

AS

- F

ull

Su

ite (

28 a

na

lyte

s)

WA

TE

R -

EP

23

1X

-ST

PF

AS

- S

up

er

Tra

ce W

ate

rs L

ong

Su

ite (

28

WA

TE

R -

NT

-01

& 0

2

Ca

, M

g, N

a, K

, C

l, S

O4

, A

lka

linity

ET1800988-001 10-Apr-2018 00:00 0874_MW259_S_180410 ü ü

ET1800988-002 10-Apr-2018 00:00 0874_MW225_S_180410 ü ü

ET1800988-003 10-Apr-2018 00:00 0874_MW258_S_180410 ü ü

ET1800988-004 10-Apr-2018 00:00 0874_MW257_S_180410 ü ü

ET1800988-005 10-Apr-2018 00:00 0874_MW236_S_180410 ü ü

ET1800988-006 10-Apr-2018 00:00 0874_MW269_S_180410 ü ü

ET1800988-007 10-Apr-2018 00:00 0874_MW218_S_180410 ü ü

ET1800988-008 10-Apr-2018 00:00 0874_MW268_S_180410 ü ü

ET1800988-009 10-Apr-2018 00:00 0874_MW260_S_180410 ü ü

ET1800988-010 10-Apr-2018 00:00 0874_MW219_S_180410 ü ü

ET1800988-011 10-Apr-2018 00:00 0874_MW220_S_180410 ü ü

ET1800988-012 10-Apr-2018 00:00 0874_MW267_S_180410 ü ü

ET1800988-013 10-Apr-2018 00:00 0874_MW270_S_180410 ü ü

ET1800988-014 10-Apr-2018 00:00 0874_MW263_S_180410 ü ü

ET1800988-015 10-Apr-2018 00:00 0874_MW221_S_180410 ü ü

ET1800988-016 10-Apr-2018 00:00 0874_QC1MW_180410_01 ü ü

ET1800988-017 10-Apr-2018 00:00 0874_QC1MW_180410_02 ü ü

ET1800988-018 10-Apr-2018 00:00 0874_QC3MW_180410 ü

ET1800988-019 10-Apr-2018 00:00 0874_QC4MW_180410 ü

ET1800988-020 10-Apr-2018 00:00 0874_QC5MW_180410_04 ü

ET1800988-021 10-Apr-2018 00:00 0874_QC5MW_180410_03 ü

ET1800988-022 10-Apr-2018 00:00 0874_MW266_S_180410 ü ü

Matrix: WATER


ID

Client sampling

date / time







ACCOUNTS PAYABLE


AU ACCOUNTS PAYABLE


DAVID HARRIS








DERP LABREPORTS


PHIL SCHULZ









RESULTS RESULTS








0 0.00 True

Environmental





C/O GPO BOX 2907








Site : ----






l General Comments












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General Comments







purposes.







Key :

EP231: Matrix spike recovery bias low due to matrix interferencel


EP231X and EP231X-ST conducted by ALS Sydney, NATA accreditation no. 825, site no 10911.l

EP231: Particular samples required dilution due to sample matrix . LOR values have been adjusted accordingly.l

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Analytical Results


(Matrix: WATER)












555Chloride 151 234 729 14mg/L116887-00-6


42Calcium 20 23 70 45mg/L17440-70-2

38Magnesium 14 18 45 3mg/L17439-95-4

328Sodium 102 149 547 22mg/L17440-23-5

15Potassium 7 6 2 3mg/L17440-09-7


18.5 6.47 8.57 29.0 3.88meq/L0.01----Total Anions

19.9 6.77 9.26 31.0 3.53meq/L0.01----Total Cations

3.63 2.26 3.90 3.44 4.82%0.01----Ionic Balance



(PFBS)

---- ---- ---- 0.0191µg/L0.0005375-73-5


(PFBS)

0.19 0.37 0.02 ----µg/L0.02375-73-5


(PFPeS)

---- ---- ---- 0.0017µg/L0.00052706-91-4


(PFPeS)

0.14 0.32 <0.02 ----µg/L0.022706-91-4


(PFHxS)

---- ---- ---- 0.0199µg/L0.0005355-46-4


(PFHxS)

1.44 2.87 0.11 ----µg/L0.02355-46-4


(PFHpS)

---- ---- ---- 0.0007µg/L0.0005375-92-8


(PFHpS)

0.09 0.16 <0.02 ----µg/L0.02375-92-8

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Analytical Results


(Matrix: WATER)






(PFOS)

---- ---- ---- 0.0253µg/L0.00031763-23-1


(PFDS)

---- ---- ---- <0.0005µg/L0.0005335-77-3


(PFOS)

2.73 3.45 0.10 ----µg/L0.011763-23-1


(PFDS)

<0.02 <0.02 <0.02 ----µg/L0.02335-77-3


<0.002Perfluorobutanoic acid (PFBA) ---- ---- ---- <0.002µg/L0.002375-22-4

----Perfluorobutanoic acid (PFBA) <0.1 <0.1 <0.1 ----µg/L0.1375-22-4

0.0248Perfluoropentanoic acid (PFPeA) ---- ---- ---- <0.0005µg/L0.00052706-90-3

----Perfluoropentanoic acid (PFPeA) 0.10 0.19 <0.02 ----µg/L0.022706-90-3

0.0840Perfluorohexanoic acid (PFHxA) ---- ---- ---- 0.0033µg/L0.0005307-24-4

----Perfluorohexanoic acid (PFHxA) 0.43 0.96 <0.02 ----µg/L0.02307-24-4

0.0078Perfluoroheptanoic acid (PFHpA) ---- ---- ---- <0.0005µg/L0.0005375-85-9

----Perfluoroheptanoic acid (PFHpA) 0.05 0.10 <0.02 ----µg/L0.02375-85-9

0.0212Perfluorooctanoic acid (PFOA) ---- ---- ---- 0.0027µg/L0.0005335-67-1

----Perfluorooctanoic acid (PFOA) 0.11 0.23 <0.01 ----µg/L0.01335-67-1

<0.0020Perfluorononanoic acid (PFNA) ---- ---- ---- <0.0005µg/L0.0005375-95-1

----Perfluorononanoic acid (PFNA) <0.02 <0.02 <0.02 ----µg/L0.02375-95-1

<0.0020Perfluorodecanoic acid (PFDA) ---- ---- ---- <0.0005µg/L0.0005335-76-2

----Perfluorodecanoic acid (PFDA) <0.02 <0.02 <0.02 ----µg/L0.02335-76-2


(PFUnDA)

---- ---- ---- <0.0005µg/L0.00052058-94-8


(PFUnDA)

<0.02 <0.02 <0.02 ----µg/L0.022058-94-8


(PFDoDA)

---- ---- ---- <0.0005µg/L0.0005307-55-1


(PFDoDA)

<0.02 <0.02 <0.02 ----µg/L0.02307-55-1


(PFTrDA)

---- ---- ---- <0.0005µg/L0.000572629-94-8


(PFTrDA)

<0.02 <0.02 <0.02 ----µg/L0.0272629-94-8

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Analytical Results


(Matrix: WATER)






(PFTeDA)

---- ---- ---- <0.0005µg/L0.0005376-06-7


(PFTeDA)

<0.05 <0.05 <0.05 ----µg/L0.05376-06-7



(FOSA)

---- ---- ---- <0.0005µg/L0.0005754-91-6


(FOSA)

<0.02 <0.02 <0.02 ----µg/L0.02754-91-6



---- ---- ---- <0.001µg/L0.00131506-32-8



<0.05 <0.05 <0.05 ----µg/L0.0531506-32-8



---- ---- ---- <0.001µg/L0.0014151-50-2



<0.05 <0.05 <0.05 ----µg/L0.054151-50-2



---- ---- ---- <0.001µg/L0.00124448-09-7



<0.05 <0.05 <0.05 ----µg/L0.0524448-09-7



---- ---- ---- <0.001µg/L0.0011691-99-2



<0.05 <0.05 <0.05 ----µg/L0.051691-99-2



(MeFOSAA)

---- ---- ---- <0.0005µg/L0.00052355-31-9



(MeFOSAA)

<0.02 <0.02 <0.02 ----µg/L0.022355-31-9



(EtFOSAA)

---- ---- ---- <0.0005µg/L0.00052991-50-6

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Analytical Results


(Matrix: WATER)







(EtFOSAA)

<0.02 <0.02 <0.02 ----µg/L0.022991-50-6



(4:2 FTS)

---- ---- ---- <0.001µg/L0.001757124-72-4


(4:2 FTS)

<0.05 <0.05 <0.05 ----µg/L0.05757124-72-4


(6:2 FTS)

---- ---- ---- <0.001µg/L0.00127619-97-2


(6:2 FTS)

<0.05 <0.05 <0.05 ----µg/L0.0527619-97-2


(8:2 FTS)

---- ---- ---- <0.001µg/L0.00139108-34-4


(8:2 FTS)

<0.05 <0.05 <0.05 ----µg/L0.0539108-34-4


(10:2 FTS)

---- ---- ---- <0.001µg/L0.001120226-60-0


(10:2 FTS)

<0.05 <0.05 <0.05 ----µg/L0.05120226-60-0

EP231P: PFAS Sums

1.30 ---- ---- ---- 0.0727µg/L0.0003----Sum of PFAS

---- 5.28 8.65 0.23 ----µg/L0.01----Sum of PFAS

1.04Sum of PFHxS and PFOS ---- ---- ---- 0.0452µg/L0.0003355-46-4/1763-23-

1

----Sum of PFHxS and PFOS 4.17 6.32 0.21 ----µg/L0.01355-46-4/1763-23-

1

1.24 ---- ---- ---- 0.0703µg/L0.0003----Sum of PFAS (WA DER List)

---- 5.05 8.17 0.23 ----µg/L0.01----Sum of PFAS (WA DER List)


103 ---- ---- ---- 101%0.0005----13C4-PFOS

---- 106 108 104 ----%0.02----13C4-PFOS

95.0 ---- ---- ---- 120%0.0005----13C8-PFOA

---- 117 113 112 ----%0.02----13C8-PFOA

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Analytical Results

--------0874_QC5SW_180411

_04

0874_QC5SW_180411

_03


(Matrix: WATER)

--------11-Apr-2018 00:0011-Apr-2018 00:0011-Apr-2018 00:00Client sampling date / time

----------------ET1801005-008ET1801005-007ET1801005-006UnitLORCAS NumberCompound

Result Result Result ---- ----



(PFBS)

<0.0005 <0.0005 ---- ----µg/L0.0005375-73-5


(PFPeS)

<0.0005 <0.0005 ---- ----µg/L0.00052706-91-4


(PFHxS)

<0.0005 <0.0005 ---- ----µg/L0.0005355-46-4


(PFHpS)

<0.0005 <0.0005 ---- ----µg/L0.0005375-92-8


(PFOS)

<0.0003 <0.0003 ---- ----µg/L0.00031763-23-1


(PFDS)

<0.0005 <0.0005 ---- ----µg/L0.0005335-77-3










(PFUnDA)

<0.0005 <0.0005 ---- ----µg/L0.00052058-94-8


(PFDoDA)

<0.0005 <0.0005 ---- ----µg/L0.0005307-55-1


(PFTrDA)

<0.0005 <0.0005 ---- ----µg/L0.000572629-94-8


(PFTeDA)

<0.0005 <0.0005 ---- ----µg/L0.0005376-06-7



(FOSA)

<0.0005 <0.0005 ---- ----µg/L0.0005754-91-6



<0.001 <0.001 ---- ----µg/L0.00131506-32-8



<0.001 <0.001 ---- ----µg/L0.0014151-50-2

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Analytical Results

--------0874_QC5SW_180411

_04

0874_QC5SW_180411

_03


(Matrix: WATER)







<0.001 <0.001 ---- ----µg/L0.00124448-09-7



<0.001 <0.001 ---- ----µg/L0.0011691-99-2



(MeFOSAA)

<0.0005 <0.0005 ---- ----µg/L0.00052355-31-9



(EtFOSAA)

<0.0005 <0.0005 ---- ----µg/L0.00052991-50-6



(4:2 FTS)

<0.001 <0.001 ---- ----µg/L0.001757124-72-4


(6:2 FTS)

<0.001 <0.001 ---- ----µg/L0.00127619-97-2


(8:2 FTS)

<0.001 <0.001 ---- ----µg/L0.00139108-34-4


(10:2 FTS)

<0.001 <0.001 ---- ----µg/L0.001120226-60-0

EP231P: PFAS Sums

<0.0003 <0.0003 <0.0003 ---- ----µg/L0.0003----Sum of PFAS


1



81.3 73.6 73.0 ---- ----%0.0005----13C4-PFOS

91.2 74.3 73.0 ---- ----%0.0005----13C8-PFOA

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13C4-PFOS ---- 60 120

13C8-PFOA ---- 60 120

False

4 4.00True

Environmental




:Address MOBIL

C/O GPO BOX 2907








Site : ----
















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General Comments










Key :













ED041G: Sulfate as SO4 - Turbidimetric 14808-79-8 1 mg/L <1 <1 0.00 No LimitAnonymous ET1800753-001








ED093F: Sodium 7440-23-5 1 mg/L 328 325 0.836 0% - 20%

ED093F: Potassium 7440-09-7 1 mg/L 15 14 0.00 0% - 50%



ED093F: Sodium 7440-23-5 1 mg/L 1570 1580 0.530 0% - 20%




(PFOS)



(PFBS)

375-73-5 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit

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(PFPeS)

2706-91-4 0.0005 µg/L 0.0008 0.0007 0.00 No LimitAnonymous ES1810721-001


(PFHxS)

355-46-4 0.0005 µg/L 0.0062 0.0059 4.93 0% - 50%


(PFHpS)

375-92-8 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFDS)

335-77-3 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFOS)



(PFBS)

375-73-5 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFPeS)

2706-91-4 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFHxS)

355-46-4 0.0005 µg/L 0.0012 0.0015 21.2 No Limit


(PFHpS)

375-92-8 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFDS)

335-77-3 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit




EP231X: Perfluoropentane sulfonic acid (PFPeS) 2706-91-4 0.02 µg/L 0.14 0.16 7.36 No Limit


EP231X: Perfluoroheptane sulfonic acid (PFHpS) 375-92-8 0.02 µg/L 0.09 0.09 0.00 No Limit


EP231X: Perfluorooctane sulfonic acid (PFOS) 1763-23-1 0.01 µg/L 0.06 0.06 0.00 No LimitAnonymous ET1801006-011



EP231X: Perfluorohexane sulfonic acid (PFHxS) 355-46-4 0.02 µg/L 0.09 0.10 0.00 No Limit










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EP231X-ST: Perfluoroundecanoic acid (PFUnDA) 2058-94-8 0.0005 µg/L <0.0005 <0.0005 0.00 No LimitAnonymous ES1810721-001




(PFTeDA)

376-06-7 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit












(PFTeDA)

376-06-7 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit




EP231X: Perfluoropentanoic acid (PFPeA) 2706-90-3 0.02 µg/L 0.10 0.10 0.00 No Limit


EP231X: Perfluoroheptanoic acid (PFHpA) 375-85-9 0.02 µg/L 0.05 0.04 0.00 No Limit








EP231X: Perfluorooctanoic acid (PFOA) 335-67-1 0.01 µg/L <0.01 <0.01 0.00 No LimitAnonymous ET1801006-011










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EP231X: Perfluorobutanoic acid (PFBA) 375-22-4 0.1 µg/L <0.1 <0.1 0.00 No LimitAnonymous ET1801006-011



(FOSA)




2355-31-9 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit



2991-50-6 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit



31506-32-8 0.001 µg/L <0.001 <0.001 0.00 No Limit


(EtFOSA)

4151-50-2 0.001 µg/L <0.001 <0.001 0.00 No Limit



24448-09-7 0.001 µg/L <0.001 <0.001 0.00 No Limit



1691-99-2 0.001 µg/L <0.001 <0.001 0.00 No Limit


(FOSA)




2355-31-9 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit



2991-50-6 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit



31506-32-8 0.001 µg/L <0.001 <0.001 0.00 No Limit


(EtFOSA)

4151-50-2 0.001 µg/L <0.001 <0.001 0.00 No Limit



24448-09-7 0.001 µg/L <0.001 <0.001 0.00 No Limit



1691-99-2 0.001 µg/L <0.001 <0.001 0.00 No Limit





2355-31-9 0.02 µg/L <0.02 <0.02 0.00 No Limit



2991-50-6 0.02 µg/L <0.02 <0.02 0.00 No Limit


(MeFOSA)

31506-32-8 0.05 µg/L <0.05 <0.05 0.00 No Limit


(EtFOSA)

4151-50-2 0.05 µg/L <0.05 <0.05 0.00 No Limit

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24448-09-7 0.05 µg/L <0.05 <0.05 0.00 No Limit0874_SW111_180411 ET1801005-002



1691-99-2 0.05 µg/L <0.05 <0.05 0.00 No Limit




2355-31-9 0.02 µg/L <0.02 <0.02 0.00 No Limit



2991-50-6 0.02 µg/L <0.02 <0.02 0.00 No Limit


(MeFOSA)

31506-32-8 0.05 µg/L <0.05 <0.05 0.00 No Limit


(EtFOSA)

4151-50-2 0.05 µg/L <0.05 <0.05 0.00 No Limit



24448-09-7 0.05 µg/L <0.05 <0.05 0.00 No Limit



1691-99-2 0.05 µg/L <0.05 <0.05 0.00 No Limit



FTS)



FTS)

27619-97-2 0.001 µg/L <0.001 <0.001 0.00 No Limit


FTS)

39108-34-4 0.001 µg/L <0.001 <0.001 0.00 No Limit


(10:2 FTS)

120226-60-0 0.001 µg/L <0.001 <0.001 0.00 No Limit


FTS)



FTS)

27619-97-2 0.001 µg/L <0.001 <0.001 0.00 No Limit


FTS)

39108-34-4 0.001 µg/L <0.001 <0.001 0.00 No Limit


(10:2 FTS)

120226-60-0 0.001 µg/L <0.001 <0.001 0.00 No Limit



FTS)

757124-72-4 0.05 µg/L <0.05 <0.05 0.00 No Limit0874_SW111_180411 ET1801005-002


FTS)

27619-97-2 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

39108-34-4 0.05 µg/L <0.05 <0.05 0.00 No Limit

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FTS)

120226-60-0 0.05 µg/L <0.05 <0.05 0.00 No Limit0874_SW111_180411 ET1801005-002


FTS)



FTS)

27619-97-2 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

39108-34-4 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

120226-60-0 0.05 µg/L <0.05 <0.05 0.00 No Limit


EP231X-ST: Sum of PFAS ---- 0.0003 µg/L 0.0070 0.0066 5.88 0% - 20%Anonymous ES1810721-001

EP231X-ST: Sum of PFAS ---- 0.0003 µg/L 0.0021 0.0024 13.3 No LimitAnonymous ET1801006-003




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Report








<1 10025 mg/L 12080



<1 91.710 mg/L 12080


ED093F: Calcium 7440-70-2 1 mg/L <1 -------- --------


ED093F: Sodium 7440-23-5 1 mg/L <1 -------- --------










EP231X: Perfluorobutane sulfonic acid (PFBS) 375-73-5 0.02 µg/L <0.02 94.40.5 µg/L 13070

EP231X: Perfluoropentane sulfonic acid (PFPeS) 2706-91-4 0.02 µg/L <0.02 95.80.5 µg/L 13070













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Report










EP231X: Perfluorobutanoic acid (PFBA) 375-22-4 0.1 µg/L <0.1 93.02.5 µg/L 13070





EP231X: Perfluorononanoic acid (PFNA) 375-95-1 0.02 µg/L <0.02 97.20.5 µg/L 13070









(MeFOSA)

31506-32-8 0.001 µg/L <0.001 61.80.025 µg/L 13040



(MeFOSE)

24448-09-7 0.001 µg/L <0.001 70.40.025 µg/L 13040


(EtFOSE)

1691-99-2 0.001 µg/L <0.001 1100.025 µg/L 13040


acid (MeFOSAA)

2355-31-9 0.0005 µg/L <0.0005 60.40.01 µg/L 13040


acid (EtFOSAA)

2991-50-6 0.0005 µg/L <0.0005 61.80.01 µg/L 13040






(MeFOSE)

24448-09-7 0.05 µg/L <0.05 92.11.25 µg/L 15070


(EtFOSE)

1691-99-2 0.05 µg/L <0.05 1101.25 µg/L 15070


(MeFOSAA)

2355-31-9 0.02 µg/L <0.02 1090.5 µg/L 13070

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Report






(EtFOSAA)

2991-50-6 0.02 µg/L <0.02 90.60.5 µg/L 13070



















Anonymous ET1800753-002 14808-79-8ED041G: Sulfate as SO4 - Turbidimetric 98.520 mg/L 13070


Anonymous ET1800753-002 16887-00-6ED045G: Chloride 96.9400 mg/L 13070





Determined

0.01 µg/L 13050

375-92-8EP231X-ST: Perfluoroheptane sulfonic acid (PFHpS) 1020.01 µg/L 13050




0874_SW111_180411 ET1801005-002 375-73-5EP231X: Perfluorobutane sulfonic acid (PFBS) 87.40.5 µg/L 13050


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0874_SW111_180411 ET1801005-002 355-46-4EP231X: Perfluorohexane sulfonic acid (PFHxS) 98.20.5 µg/L 13050


1763-23-1EP231X: Perfluorooctane sulfonic acid (PFOS) # Not

Determined

0.5 µg/L 13050















0874_SW111_180411 ET1801005-002 375-22-4EP231X: Perfluorobutanoic acid (PFBA) 1012.5 µg/L 13050

2706-90-3EP231X: Perfluoropentanoic acid (PFPeA) 82.60.5 µg/L 13050


375-85-9EP231X: Perfluoroheptanoic acid (PFHpA) 97.00.5 µg/L 13050


375-95-1EP231X: Perfluorononanoic acid (PFNA) 88.20.5 µg/L 13050





376-06-7EP231X: Perfluorotetradecanoic acid (PFTeDA) 1011.25 µg/L 15050




(MeFOSA)

# 29.60.025 µg/L 13030


(EtFOSA)

34.40.025 µg/L 13030



41.60.025 µg/L 13030



36.80.025 µg/L 13030

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Anonymous ES1810721-002 2355-31-9EP231X-ST: N-Methyl perfluorooctane


64.00.01 µg/L 13030


acid (EtFOSAA)

60.00.01 µg/L 13030


0874_SW111_180411 ET1801005-002 754-91-6EP231X: Perfluorooctane sulfonamide (FOSA) 1100.5 µg/L 13050


(MeFOSA)

1131.25 µg/L 15050

4151-50-2EP231X: N-Ethyl perfluorooctane sulfonamide (EtFOSA) 1171.25 µg/L 15050


(MeFOSE)

93.51.25 µg/L 15050


(EtFOSE)

1121.25 µg/L 15050


acid (MeFOSAA)

89.20.5 µg/L 13050


acid (EtFOSAA)

86.40.5 µg/L 13050







0874_SW111_180411 ET1801005-002 757124-72-4EP231X: 4:2 Fluorotelomer sulfonic acid (4:2 FTS) 96.20.5 µg/L 13050




True

Environmental












Summary of Outliers













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Matrix: WATER








----Not

Determined


ES1810721--002 355-46-4Perfluorohexane

sulfonic acid

(PFHxS)




----Not

Determined


ES1810721--002 31506-32-8N-Methyl

perfluorooctane

sulfonamide

(MeFOSA)


objective















0874_SW101_180411, 0874_SW111_180411,

0874_SW110_180411, 0874_SW017_180411,

0874_SW020_180411

25-Apr-2018---- 12-Apr-2018----11-Apr-2018 ---- ü



0874_SW101_180411, 0874_SW111_180411,

0874_SW110_180411, 0874_SW017_180411,

0874_SW020_180411

09-May-2018---- 12-Apr-2018----11-Apr-2018 ---- ü



0874_SW101_180411, 0874_SW111_180411,

0874_SW110_180411, 0874_SW017_180411,

0874_SW020_180411

09-May-2018---- 12-Apr-2018----11-Apr-2018 ---- ü

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0874_SW101_180411, 0874_SW111_180411,

0874_SW110_180411, 0874_SW017_180411,

0874_SW020_180411

18-Apr-2018---- 17-Apr-2018----11-Apr-2018 ---- ü



0874_SW111_180411, 0874_SW110_180411,

0874_SW017_180411

08-Oct-2018---- 19-Apr-2018----11-Apr-2018 ---- ü


0874_SW101_180411, 0874_SW020_180411,

0874_QC3SW_180411, 0874_QC5SW_180411_03,

0874_QC5SW_180411_04




0874_SW111_180411, 0874_SW110_180411,

0874_SW017_180411

08-Oct-2018---- 19-Apr-2018----11-Apr-2018 ---- ü


0874_SW101_180411, 0874_SW020_180411,

0874_QC3SW_180411, 0874_QC5SW_180411_03,

0874_QC5SW_180411_04




0874_SW111_180411, 0874_SW110_180411,

0874_SW017_180411

08-Oct-2018---- 19-Apr-2018----11-Apr-2018 ---- ü


0874_SW101_180411, 0874_SW020_180411,

0874_QC3SW_180411, 0874_QC5SW_180411_03,

0874_QC5SW_180411_04




0874_SW111_180411, 0874_SW110_180411,

0874_SW017_180411

08-Oct-2018---- 19-Apr-2018----11-Apr-2018 ---- ü


0874_SW101_180411, 0874_SW020_180411,

0874_QC3SW_180411, 0874_QC5SW_180411_03,

0874_QC5SW_180411_04


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EP231P: PFAS Sums


0874_SW111_180411, 0874_SW110_180411,

0874_SW017_180411

08-Oct-2018---- 19-Apr-2018----11-Apr-2018 ---- ü


0874_SW101_180411, 0874_SW020_180411,

0874_QC3SW_180411, 0874_QC5SW_180411_03,

0874_QC5SW_180411_04


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Method Blanks (MB)






Matrix Spikes (MS)





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Schedule B(3)







Discrete Analyser

ED041G WATER











Schedule B(3)



DA

EN055 - PG WATER










(PFAS) by LCMSMS

EP231X WATER










(PFAS) by LCMSMS

EP231X-ST WATER

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Environmental





C/O GPO BOX 2907



QLD AUSTRALIA 4814






V4)


Site : ----




Date

20-Apr-2018



: : 8 / 8SMALL ESKIESReceipt Detail No. of samples received / analysed

General Comments






l Discounted Package Prices apply only when specific ALS Group Codes ('W', 'S', 'NT' suites) are referenced on COCs.


l EP231X and EP231X-ST conducted by ALS Sydney, NATA accreditation no. 825, site no 10911.












ET1801005-007 : [ 11-Apr-2018 ] : 0874_QC5SW_180411_03

ET1801005-008 : [ 11-Apr-2018 ] : 0874_QC5SW_180411_04











componentW

AT

ER

- E

P2

31X

PF

AS

- F

ull

Su

ite (

28 a

na

lyte

s)

WA

TE

R -

EP

231X

-ST

PF

AS

- S

up

er

Tra

ce W

ate

rs L

ong

Su

ite (

28

WA

TE

R -

NT

-01 &

02

Ca

, M

g, N

a, K

, C

l, S

O4

, A

lka

linity

ET1801005-001 11-Apr-2018 00:00 0874_SW101_180411 ü ü

ET1801005-002 11-Apr-2018 00:00 0874_SW111_180411 ü ü

ET1801005-003 11-Apr-2018 00:00 0874_SW110_180411 ü ü

ET1801005-004 11-Apr-2018 00:00 0874_SW017_180411 ü ü

ET1801005-005 11-Apr-2018 00:00 0874_SW020_180411 ü ü

ET1801005-006 11-Apr-2018 00:00 0874_QC3SW_180411 ü

ET1801005-007 11-Apr-2018 00:00 0874_QC5SW_180411_03 ü

ET1801005-008 11-Apr-2018 00:00 0874_QC5SW_180411_04 ü

Matrix: WATER


ID

Client sampling

date / time







ACCOUNTS PAYABLE


AU ACCOUNTS PAYABLE


DAVID HARRIS








DERP LABREPORTS


PHIL SCHULZ









RESULTS RESULTS








0 0.00 True

Environmental




:: AddressAddress GPO BOX 2907







Sampler : MICHAEL AITKEN

Site : ----






l General Comments












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General Comments







purposes.







Key :

EP231: Matrix spike recovery bias low due to matrix interferencel

ED037-P, ED041G, ED045G will be conducted by ALS Townsville, NATA accreditation no. 825, (Site no. 23313)l

EP231X, EP231X ST will be conducted by ALS Sydney, NATA accreditation no. 825, (Site no. 10911)l

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Analytical Results

0874_MW215_S_1804

11

0874_MW216_S_1804

11

0874_MW217_S_1804

11

0874_MW256_S_1804

11

0874_MW261_S_1804

11


(Matrix: WATER)












63Chloride 67 7020 104 2410mg/L116887-00-6


76Calcium 24 209 36 85mg/L17440-70-2

25Magnesium 12 430 11 140mg/L17439-95-4

83Sodium 86 4300 65 1570mg/L17440-23-5

6Potassium 2 136 10 23mg/L17440-09-7


9.07 5.63 222 5.52 82.9meq/L0.01----Total Anions

9.61 5.98 236 5.78 84.6meq/L0.01----Total Cations

2.93 3.01 3.11 2.31 1.05%0.01----Ionic Balance



(PFBS)

0.0178 <0.0005 ---- 0.0677µg/L0.0005375-73-5


(PFBS)

---- ---- 0.06 ----µg/L0.02375-73-5


(PFPeS)

0.0014 <0.0005 ---- 0.0044µg/L0.00052706-91-4


(PFPeS)

---- ---- <0.02 ----µg/L0.022706-91-4


(PFHxS)

0.0144 0.0012 ---- 0.0314µg/L0.0005355-46-4


(PFHxS)

---- ---- 0.38 ----µg/L0.02355-46-4


(PFHpS)

0.0014 <0.0005 ---- <0.0005µg/L0.0005375-92-8


(PFHpS)

---- ---- <0.02 ----µg/L0.02375-92-8

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Analytical Results

0874_MW215_S_1804

11

0874_MW216_S_1804

11

0874_MW217_S_1804

11

0874_MW256_S_1804

11

0874_MW261_S_1804

11


(Matrix: WATER)






(PFOS)

0.0806 0.0009 ---- 0.0163µg/L0.00031763-23-1


(PFDS)

<0.0005 <0.0005 ---- <0.0005µg/L0.0005335-77-3


(PFOS)

---- ---- 0.19 ----µg/L0.011763-23-1


(PFDS)

---- ---- <0.02 ----µg/L0.02335-77-3


<0.002Perfluorobutanoic acid (PFBA) <0.002 <0.002 ---- <0.002µg/L0.002375-22-4


<0.0005Perfluoropentanoic acid (PFPeA) <0.0005 <0.0005 ---- <0.0005µg/L0.00052706-90-3

----Perfluoropentanoic acid (PFPeA) ---- ---- <0.02 ----µg/L0.022706-90-3

<0.0005Perfluorohexanoic acid (PFHxA) 0.0016 <0.0005 ---- <0.0005µg/L0.0005307-24-4

----Perfluorohexanoic acid (PFHxA) ---- ---- <0.02 ----µg/L0.02307-24-4

<0.0005Perfluoroheptanoic acid (PFHpA) 0.0014 <0.0005 ---- <0.0005µg/L0.0005375-85-9

----Perfluoroheptanoic acid (PFHpA) ---- ---- <0.02 ----µg/L0.02375-85-9

0.0025Perfluorooctanoic acid (PFOA) 0.0118 <0.0005 ---- 0.0014µg/L0.0005335-67-1


<0.0005Perfluorononanoic acid (PFNA) <0.0005 <0.0005 ---- <0.0005µg/L0.0005375-95-1

----Perfluorononanoic acid (PFNA) ---- ---- <0.02 ----µg/L0.02375-95-1

<0.0005Perfluorodecanoic acid (PFDA) <0.0005 <0.0005 ---- <0.0005µg/L0.0005335-76-2



(PFUnDA)

<0.0005 <0.0005 ---- <0.0005µg/L0.00052058-94-8


(PFUnDA)

---- ---- <0.02 ----µg/L0.022058-94-8


(PFDoDA)

<0.0005 <0.0005 ---- <0.0005µg/L0.0005307-55-1


(PFDoDA)

---- ---- <0.02 ----µg/L0.02307-55-1


(PFTrDA)

<0.0005 <0.0005 ---- <0.0005µg/L0.000572629-94-8


(PFTrDA)

---- ---- <0.02 ----µg/L0.0272629-94-8

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Analytical Results

0874_MW215_S_1804

11

0874_MW216_S_1804

11

0874_MW217_S_1804

11

0874_MW256_S_1804

11

0874_MW261_S_1804

11


(Matrix: WATER)






(PFTeDA)

<0.0005 <0.0005 ---- <0.0005µg/L0.0005376-06-7


(PFTeDA)

---- ---- <0.05 ----µg/L0.05376-06-7



(FOSA)

<0.0005 <0.0005 ---- <0.0005µg/L0.0005754-91-6


(FOSA)

---- ---- <0.02 ----µg/L0.02754-91-6



<0.001 <0.001 ---- <0.001µg/L0.00131506-32-8



---- ---- <0.05 ----µg/L0.0531506-32-8



<0.001 <0.001 ---- <0.001µg/L0.0014151-50-2



---- ---- <0.05 ----µg/L0.054151-50-2



<0.001 <0.001 ---- <0.001µg/L0.00124448-09-7



---- ---- <0.05 ----µg/L0.0524448-09-7



<0.001 <0.001 ---- <0.001µg/L0.0011691-99-2



---- ---- <0.05 ----µg/L0.051691-99-2



(MeFOSAA)

<0.0005 <0.0005 ---- <0.0005µg/L0.00052355-31-9



(MeFOSAA)

---- ---- <0.02 ----µg/L0.022355-31-9



(EtFOSAA)

<0.0005 <0.0005 ---- <0.0005µg/L0.00052991-50-6

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Analytical Results

0874_MW215_S_1804

11

0874_MW216_S_1804

11

0874_MW217_S_1804

11

0874_MW256_S_1804

11

0874_MW261_S_1804

11


(Matrix: WATER)







(EtFOSAA)

---- ---- <0.02 ----µg/L0.022991-50-6



(4:2 FTS)

<0.001 <0.001 ---- <0.001µg/L0.001757124-72-4


(4:2 FTS)

---- ---- <0.05 ----µg/L0.05757124-72-4


(6:2 FTS)

<0.001 <0.001 ---- <0.001µg/L0.00127619-97-2


(6:2 FTS)

---- ---- <0.05 ----µg/L0.0527619-97-2


(8:2 FTS)

<0.001 <0.001 ---- <0.001µg/L0.00139108-34-4


(8:2 FTS)

---- ---- <0.05 ----µg/L0.0539108-34-4


(10:2 FTS)

<0.001 <0.001 ---- <0.001µg/L0.001120226-60-0


(10:2 FTS)

---- ---- <0.05 ----µg/L0.05120226-60-0

EP231P: PFAS Sums

0.0550 0.130 0.0021 ---- 0.121µg/L0.0003----Sum of PFAS

---- ---- ---- 0.64 ----µg/L0.01----Sum of PFAS

0.0391Sum of PFHxS and PFOS 0.0950 0.0021 ---- 0.0477µg/L0.0003355-46-4/1763-23-

1


1

0.0533 0.128 0.0021 ---- 0.117µg/L0.0003----Sum of PFAS (WA DER List)



101 93.2 95.1 ---- 111%0.0005----13C4-PFOS

---- ---- ---- 104 ----%0.02----13C4-PFOS

118 108 118 ---- 112%0.0005----13C8-PFOA

---- ---- ---- 110 ----%0.02----13C8-PFOA

7 of 17:Page

Work Order :

:Client

ET1801006



Analytical Results

0874_MW210_S_1804

11

0874_MW211_S_1804

11

0874_MW212_S_1804

11

0874_MW213_S_1804

11

0874_MW214_S_1804

11


(Matrix: WATER)












10900Chloride 4720 132 158 65mg/L116887-00-6


284Calcium 417 37 80 87mg/L17440-70-2

815Magnesium 418 15 16 14mg/L17439-95-4

7010Sodium 2230 150 133 54mg/L17440-23-5

261Potassium 60 5 6 2mg/L17440-09-7


338 149 9.36 10.8 7.48meq/L0.01----Total Anions

393 154 9.73 11.2 7.89meq/L0.01----Total Cations

7.52 1.51 1.97 1.88 2.72%0.01----Ionic Balance



(PFBS)

0.0038 ---- ---- ----µg/L0.0005375-73-5


(PFBS)

---- 0.02 0.03 <0.02µg/L0.02375-73-5


(PFPeS)

0.0014 ---- ---- ----µg/L0.00052706-91-4


(PFPeS)

---- <0.02 <0.02 <0.02µg/L0.022706-91-4


(PFHxS)

0.0085 ---- ---- ----µg/L0.0005355-46-4


(PFHxS)

---- <0.02 0.04 0.02µg/L0.02355-46-4


(PFHpS)

<0.0005 ---- ---- ----µg/L0.0005375-92-8


(PFHpS)

---- <0.02 <0.02 <0.02µg/L0.02375-92-8

8 of 17:Page

Work Order :

:Client

ET1801006



Analytical Results

0874_MW210_S_1804

11

0874_MW211_S_1804

11

0874_MW212_S_1804

11

0874_MW213_S_1804

11

0874_MW214_S_1804

11


(Matrix: WATER)






(PFOS)

0.0022 ---- ---- ----µg/L0.00031763-23-1


(PFDS)

<0.0005 ---- ---- ----µg/L0.0005335-77-3


(PFOS)

---- <0.01 0.11 0.05µg/L0.011763-23-1


(PFDS)

---- <0.02 <0.02 <0.02µg/L0.02335-77-3



----Perfluorobutanoic acid (PFBA) ---- <0.1 <0.1 <0.1µg/L0.1375-22-4


----Perfluoropentanoic acid (PFPeA) ---- 0.02 <0.02 <0.02µg/L0.022706-90-3


----Perfluorohexanoic acid (PFHxA) ---- <0.02 <0.02 <0.02µg/L0.02307-24-4


----Perfluoroheptanoic acid (PFHpA) ---- <0.02 <0.02 <0.02µg/L0.02375-85-9


----Perfluorooctanoic acid (PFOA) ---- <0.01 <0.01 <0.01µg/L0.01335-67-1


----Perfluorononanoic acid (PFNA) ---- <0.02 <0.02 <0.02µg/L0.02375-95-1


----Perfluorodecanoic acid (PFDA) ---- <0.02 <0.02 <0.02µg/L0.02335-76-2


(PFUnDA)

<0.0005 ---- ---- ----µg/L0.00052058-94-8


(PFUnDA)

---- <0.02 <0.02 <0.02µg/L0.022058-94-8


(PFDoDA)

<0.0005 ---- ---- ----µg/L0.0005307-55-1


(PFDoDA)

---- <0.02 <0.02 <0.02µg/L0.02307-55-1


(PFTrDA)

<0.0005 ---- ---- ----µg/L0.000572629-94-8


(PFTrDA)

---- <0.02 <0.02 <0.02µg/L0.0272629-94-8

9 of 17:Page

Work Order :

:Client

ET1801006



Analytical Results

0874_MW210_S_1804

11

0874_MW211_S_1804

11

0874_MW212_S_1804

11

0874_MW213_S_1804

11

0874_MW214_S_1804

11


(Matrix: WATER)






(PFTeDA)

<0.0005 ---- ---- ----µg/L0.0005376-06-7


(PFTeDA)

---- <0.05 <0.05 <0.05µg/L0.05376-06-7



(FOSA)

<0.0005 ---- ---- ----µg/L0.0005754-91-6


(FOSA)

---- <0.02 <0.02 <0.02µg/L0.02754-91-6



<0.001 ---- ---- ----µg/L0.00131506-32-8



---- <0.05 <0.05 <0.05µg/L0.0531506-32-8



<0.001 ---- ---- ----µg/L0.0014151-50-2



---- <0.05 <0.05 <0.05µg/L0.054151-50-2



<0.001 ---- ---- ----µg/L0.00124448-09-7



---- <0.05 <0.05 <0.05µg/L0.0524448-09-7



<0.001 ---- ---- ----µg/L0.0011691-99-2



---- <0.05 <0.05 <0.05µg/L0.051691-99-2



(MeFOSAA)

<0.0005 ---- ---- ----µg/L0.00052355-31-9



(MeFOSAA)

---- <0.02 <0.02 <0.02µg/L0.022355-31-9



(EtFOSAA)

<0.0005 ---- ---- ----µg/L0.00052991-50-6

10 of 17:Page

Work Order :

:Client

ET1801006



Analytical Results

0874_MW210_S_1804

11

0874_MW211_S_1804

11

0874_MW212_S_1804

11

0874_MW213_S_1804

11

0874_MW214_S_1804

11


(Matrix: WATER)







(EtFOSAA)

---- <0.02 <0.02 <0.02µg/L0.022991-50-6



(4:2 FTS)

<0.001 ---- ---- ----µg/L0.001757124-72-4


(4:2 FTS)

---- <0.05 <0.05 <0.05µg/L0.05757124-72-4


(6:2 FTS)

<0.001 ---- ---- ----µg/L0.00127619-97-2


(6:2 FTS)

---- <0.05 <0.05 <0.05µg/L0.0527619-97-2


(8:2 FTS)

<0.001 ---- ---- ----µg/L0.00139108-34-4


(8:2 FTS)

---- <0.05 <0.05 <0.05µg/L0.0539108-34-4


(10:2 FTS)

<0.001 ---- ---- ----µg/L0.001120226-60-0


(10:2 FTS)

---- <0.05 <0.05 <0.05µg/L0.05120226-60-0

EP231P: PFAS Sums

0.149 0.0179 ---- ---- ----µg/L0.0003----Sum of PFAS

---- ---- 0.04 0.18 0.07µg/L0.01----Sum of PFAS


1

----Sum of PFHxS and PFOS ---- <0.01 0.15 0.07µg/L0.01355-46-4/1763-23-

1


---- ---- 0.04 0.18 0.07µg/L0.01----Sum of PFAS (WA DER List)


101 97.1 ---- ---- ----%0.0005----13C4-PFOS

---- ---- 109 117 118%0.02----13C4-PFOS

120 112 ---- ---- ----%0.0005----13C8-PFOA

---- ---- 112 114 108%0.02----13C8-PFOA

11 of 17:Page

Work Order :

:Client

ET1801006



Analytical Results

0874_QC4MW_18041

1_01

0874_QC3MW_18041

1_01

0874_QC1MW_18041

1_01

0874_MW209_S_1804

11

0874_MW208_S_1804

11


(Matrix: WATER)












277Chloride 285 ---- ---- ----mg/L116887-00-6


130Calcium 79 ---- ---- ----mg/L17440-70-2

20Magnesium 15 ---- ---- ----mg/L17439-95-4

172Sodium 243 ---- ---- ----mg/L17440-23-5

4Potassium 4 ---- ---- ----mg/L17440-09-7


15.3 15.1 ---- ---- ----meq/L0.01----Total Anions

15.7 15.8 ---- ---- ----meq/L0.01----Total Cations

1.44 2.27 ---- ---- ----%0.01----Ionic Balance



(PFBS)

---- 0.0166 <0.0005 <0.0005µg/L0.0005375-73-5


(PFBS)

0.12 ---- ---- ----µg/L0.02375-73-5


(PFPeS)

---- 0.0027 <0.0005 <0.0005µg/L0.00052706-91-4


(PFPeS)

<0.02 ---- ---- ----µg/L0.022706-91-4


(PFHxS)

---- 0.0226 <0.0005 <0.0005µg/L0.0005355-46-4


(PFHxS)

0.22 ---- ---- ----µg/L0.02355-46-4


(PFHpS)

---- 0.0025 <0.0005 <0.0005µg/L0.0005375-92-8


(PFHpS)

<0.02 ---- ---- ----µg/L0.02375-92-8

12 of 17:Page

Work Order :

:Client

ET1801006



Analytical Results

0874_QC4MW_18041

1_01

0874_QC3MW_18041

1_01

0874_QC1MW_18041

1_01

0874_MW209_S_1804

11

0874_MW208_S_1804

11


(Matrix: WATER)






(PFOS)

---- 0.0701 <0.0003 <0.0003µg/L0.00031763-23-1


(PFDS)

---- <0.0005 <0.0005 <0.0005µg/L0.0005335-77-3


(PFOS)

0.22 ---- ---- ----µg/L0.011763-23-1


(PFDS)

<0.02 ---- ---- ----µg/L0.02335-77-3




----Perfluoropentanoic acid (PFPeA) ---- 0.0021 <0.0005 <0.0005µg/L0.00052706-90-3

<0.02Perfluoropentanoic acid (PFPeA) 0.03 ---- ---- ----µg/L0.022706-90-3

----Perfluorohexanoic acid (PFHxA) ---- 0.0053 <0.0005 <0.0005µg/L0.0005307-24-4

<0.02Perfluorohexanoic acid (PFHxA) 0.03 ---- ---- ----µg/L0.02307-24-4

----Perfluoroheptanoic acid (PFHpA) ---- 0.0015 <0.0005 <0.0005µg/L0.0005375-85-9


----Perfluorooctanoic acid (PFOA) ---- 0.0044 <0.0005 <0.0005µg/L0.0005335-67-1

<0.01Perfluorooctanoic acid (PFOA) 0.02 ---- ---- ----µg/L0.01335-67-1






(PFUnDA)

---- <0.0005 <0.0005 <0.0005µg/L0.00052058-94-8


(PFUnDA)

<0.02 ---- ---- ----µg/L0.022058-94-8


(PFDoDA)

---- <0.0005 <0.0005 <0.0005µg/L0.0005307-55-1


(PFDoDA)

<0.02 ---- ---- ----µg/L0.02307-55-1


(PFTrDA)

---- <0.0005 <0.0005 <0.0005µg/L0.000572629-94-8


(PFTrDA)

<0.02 ---- ---- ----µg/L0.0272629-94-8

13 of 17:Page

Work Order :

:Client

ET1801006



Analytical Results

0874_QC4MW_18041

1_01

0874_QC3MW_18041

1_01

0874_QC1MW_18041

1_01

0874_MW209_S_1804

11

0874_MW208_S_1804

11


(Matrix: WATER)






(PFTeDA)

---- <0.0005 <0.0005 <0.0005µg/L0.0005376-06-7


(PFTeDA)

<0.05 ---- ---- ----µg/L0.05376-06-7



(FOSA)

---- <0.0005 <0.0005 <0.0005µg/L0.0005754-91-6


(FOSA)

<0.02 ---- ---- ----µg/L0.02754-91-6



---- <0.001 <0.001 <0.001µg/L0.00131506-32-8



<0.05 ---- ---- ----µg/L0.0531506-32-8



---- <0.001 <0.001 <0.001µg/L0.0014151-50-2



<0.05 ---- ---- ----µg/L0.054151-50-2



---- <0.001 <0.001 <0.001µg/L0.00124448-09-7



<0.05 ---- ---- ----µg/L0.0524448-09-7



---- <0.001 <0.001 <0.001µg/L0.0011691-99-2



<0.05 ---- ---- ----µg/L0.051691-99-2



(MeFOSAA)

---- <0.0005 <0.0005 <0.0005µg/L0.00052355-31-9



(MeFOSAA)

<0.02 ---- ---- ----µg/L0.022355-31-9



(EtFOSAA)

---- <0.0005 <0.0005 <0.0005µg/L0.00052991-50-6

14 of 17:Page

Work Order :

:Client

ET1801006



Analytical Results

0874_QC4MW_18041

1_01

0874_QC3MW_18041

1_01

0874_QC1MW_18041

1_01

0874_MW209_S_1804

11

0874_MW208_S_1804

11


(Matrix: WATER)







(EtFOSAA)

<0.02 ---- ---- ----µg/L0.022991-50-6



(4:2 FTS)

---- <0.001 <0.001 <0.001µg/L0.001757124-72-4


(4:2 FTS)

<0.05 ---- ---- ----µg/L0.05757124-72-4


(6:2 FTS)

---- <0.001 <0.001 <0.001µg/L0.00127619-97-2


(6:2 FTS)

<0.05 ---- ---- ----µg/L0.0527619-97-2


(8:2 FTS)

---- <0.001 <0.001 <0.001µg/L0.00139108-34-4


(8:2 FTS)

<0.05 ---- ---- ----µg/L0.0539108-34-4


(10:2 FTS)

---- <0.001 <0.001 <0.001µg/L0.001120226-60-0


(10:2 FTS)

<0.05 ---- ---- ----µg/L0.05120226-60-0

EP231P: PFAS Sums

---- ---- 0.128 <0.0003 <0.0003µg/L0.0003----Sum of PFAS

0.23 0.64 ---- ---- ----µg/L0.01----Sum of PFAS

----Sum of PFHxS and PFOS ---- 0.0927 <0.0003 <0.0003µg/L0.0003355-46-4/1763-23-

1


1

---- ---- 0.123 <0.0003 <0.0003µg/L0.0003----Sum of PFAS (WA DER List)



---- ---- 103 74.3 87.9%0.0005----13C4-PFOS

111 103 ---- ---- ----%0.02----13C4-PFOS

---- ---- 119 84.6 82.6%0.0005----13C8-PFOA

120 105 ---- ---- ----%0.02----13C8-PFOA

15 of 17:Page

Work Order :

:Client

ET1801006



Analytical Results

------------0874_QC5MW_18041

1_02

0874_QC5MW_18041

1_01


(Matrix: WATER)






(PFBS)

<0.0005 ---- ---- ----µg/L0.0005375-73-5


(PFPeS)

<0.0005 ---- ---- ----µg/L0.00052706-91-4


(PFHxS)

<0.0005 ---- ---- ----µg/L0.0005355-46-4


(PFHpS)

<0.0005 ---- ---- ----µg/L0.0005375-92-8


(PFOS)

<0.0003 ---- ---- ----µg/L0.00031763-23-1


(PFDS)

<0.0005 ---- ---- ----µg/L0.0005335-77-3




<0.0005Perfluorohexanoic acid (PFHxA) <0.0005 ---- ---- ----µg/L0.0005307-24-4


<0.0005Perfluorooctanoic acid (PFOA) <0.0005 ---- ---- ----µg/L0.0005335-67-1




(PFUnDA)

<0.0005 ---- ---- ----µg/L0.00052058-94-8


(PFDoDA)

<0.0005 ---- ---- ----µg/L0.0005307-55-1


(PFTrDA)

<0.0005 ---- ---- ----µg/L0.000572629-94-8


(PFTeDA)

<0.0005 ---- ---- ----µg/L0.0005376-06-7



(FOSA)

<0.0005 ---- ---- ----µg/L0.0005754-91-6



<0.001 ---- ---- ----µg/L0.00131506-32-8



<0.001 ---- ---- ----µg/L0.0014151-50-2

16 of 17:Page

Work Order :

:Client

ET1801006



Analytical Results

------------0874_QC5MW_18041

1_02

0874_QC5MW_18041

1_01


(Matrix: WATER)







<0.001 ---- ---- ----µg/L0.00124448-09-7



<0.001 ---- ---- ----µg/L0.0011691-99-2



(MeFOSAA)

<0.0005 ---- ---- ----µg/L0.00052355-31-9



(EtFOSAA)

<0.0005 ---- ---- ----µg/L0.00052991-50-6



(4:2 FTS)

<0.001 ---- ---- ----µg/L0.001757124-72-4


(6:2 FTS)

<0.001 ---- ---- ----µg/L0.00127619-97-2


(8:2 FTS)

<0.001 ---- ---- ----µg/L0.00139108-34-4


(10:2 FTS)

<0.001 ---- ---- ----µg/L0.001120226-60-0

EP231P: PFAS Sums

<0.0003 <0.0003 ---- ---- ----µg/L0.0003----Sum of PFAS

<0.0003Sum of PFHxS and PFOS <0.0003 ---- ---- ----µg/L0.0003355-46-4/1763-23-

1

<0.0003 <0.0003 ---- ---- ----µg/L0.0003----Sum of PFAS (WA DER List)


81.9 74.3 ---- ---- ----%0.0005----13C4-PFOS

84.6 87.1 ---- ---- ----%0.0005----13C8-PFOA

17 of 17:Page

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ET1801006







13C4-PFOS ---- 60 120

13C8-PFOA ---- 60 120

False

4 4.00True

Environmental




:Address GPO BOX 2907








Site : ----
















2 of 12:Page

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:Client

ET1801006



General Comments










Key :

























ED093F: Sodium 7440-23-5 1 mg/L 328 325 0.836 0% - 20%




ED093F: Sodium 7440-23-5 1 mg/L 1570 1580 0.530 0% - 20%



3 of 12:Page

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ET1801006







(PFOS)



(PFBS)

375-73-5 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFPeS)

2706-91-4 0.0005 µg/L 0.0008 0.0007 0.00 No Limit


(PFHxS)

355-46-4 0.0005 µg/L 0.0062 0.0059 4.93 0% - 50%


(PFHpS)

375-92-8 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFDS)

335-77-3 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFOS)

1763-23-1 0.0003 µg/L 0.0009 0.0009 0.00 No Limit0874_MW217_S_180411 ET1801006-003


(PFBS)

375-73-5 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFPeS)

2706-91-4 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFHxS)

355-46-4 0.0005 µg/L 0.0012 0.0015 21.2 No Limit


(PFHpS)

375-92-8 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFDS)

335-77-3 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit








EP231X: Perfluorooctane sulfonic acid (PFOS) 1763-23-1 0.01 µg/L 0.06 0.06 0.00 No Limit0874_MW208_S_180411 ET1801006-011










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ET1801006






EP231X-ST: Perfluorooctanoic acid (PFOA) 335-67-1 0.0005 µg/L <0.0005 <0.0005 0.00 No LimitAnonymous ES1810721-001







(PFTeDA)

376-06-7 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


EP231X-ST: Perfluoropentanoic acid (PFPeA) 2706-90-3 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit0874_MW217_S_180411 ET1801006-003










(PFTeDA)

376-06-7 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit





















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ET1801006






EP231X: Perfluorododecanoic acid (PFDoDA) 307-55-1 0.02 µg/L <0.02 <0.02 0.00 No Limit0874_MW208_S_180411 ET1801006-011






(FOSA)




2355-31-9 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit



2991-50-6 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit



31506-32-8 0.001 µg/L <0.001 <0.001 0.00 No Limit


(EtFOSA)

4151-50-2 0.001 µg/L <0.001 <0.001 0.00 No Limit



24448-09-7 0.001 µg/L <0.001 <0.001 0.00 No Limit



1691-99-2 0.001 µg/L <0.001 <0.001 0.00 No Limit


(FOSA)




2355-31-9 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit



2991-50-6 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit



31506-32-8 0.001 µg/L <0.001 <0.001 0.00 No Limit


(EtFOSA)

4151-50-2 0.001 µg/L <0.001 <0.001 0.00 No Limit



24448-09-7 0.001 µg/L <0.001 <0.001 0.00 No Limit



1691-99-2 0.001 µg/L <0.001 <0.001 0.00 No Limit





2355-31-9 0.02 µg/L <0.02 <0.02 0.00 No Limit



2991-50-6 0.02 µg/L <0.02 <0.02 0.00 No Limit


(MeFOSA)

31506-32-8 0.05 µg/L <0.05 <0.05 0.00 No Limit

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ET1801006







(EtFOSA)




24448-09-7 0.05 µg/L <0.05 <0.05 0.00 No Limit



1691-99-2 0.05 µg/L <0.05 <0.05 0.00 No Limit




2355-31-9 0.02 µg/L <0.02 <0.02 0.00 No Limit



2991-50-6 0.02 µg/L <0.02 <0.02 0.00 No Limit


(MeFOSA)

31506-32-8 0.05 µg/L <0.05 <0.05 0.00 No Limit


(EtFOSA)

4151-50-2 0.05 µg/L <0.05 <0.05 0.00 No Limit



24448-09-7 0.05 µg/L <0.05 <0.05 0.00 No Limit



1691-99-2 0.05 µg/L <0.05 <0.05 0.00 No Limit



FTS)



FTS)

27619-97-2 0.001 µg/L <0.001 <0.001 0.00 No Limit


FTS)

39108-34-4 0.001 µg/L <0.001 <0.001 0.00 No Limit


(10:2 FTS)

120226-60-0 0.001 µg/L <0.001 <0.001 0.00 No Limit


FTS)



FTS)

27619-97-2 0.001 µg/L <0.001 <0.001 0.00 No Limit


FTS)

39108-34-4 0.001 µg/L <0.001 <0.001 0.00 No Limit


(10:2 FTS)

120226-60-0 0.001 µg/L <0.001 <0.001 0.00 No Limit



FTS)



FTS)

27619-97-2 0.05 µg/L <0.05 <0.05 0.00 No Limit

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ET1801006







FTS)



FTS)

120226-60-0 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)



FTS)

27619-97-2 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

39108-34-4 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

120226-60-0 0.05 µg/L <0.05 <0.05 0.00 No Limit


EP231X-ST: Sum of PFAS ---- 0.0003 µg/L 0.0070 0.0066 5.88 0% - 20%Anonymous ES1810721-001

EP231X-ST: Sum of PFAS ---- 0.0003 µg/L 0.0021 0.0024 13.3 No Limit0874_MW217_S_180411 ET1801006-003




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Report








<1 10025 mg/L 12080



<1 96.410 mg/L 12080


ED093F: Calcium 7440-70-2 1 mg/L <1 -------- --------


ED093F: Sodium 7440-23-5 1 mg/L <1 -------- --------
























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Report
























(MeFOSA)

31506-32-8 0.001 µg/L <0.001 61.80.025 µg/L 13040



(MeFOSE)

24448-09-7 0.001 µg/L <0.001 70.40.025 µg/L 13040


(EtFOSE)

1691-99-2 0.001 µg/L <0.001 1100.025 µg/L 13040


acid (MeFOSAA)

2355-31-9 0.0005 µg/L <0.0005 60.40.01 µg/L 13040


acid (EtFOSAA)

2991-50-6 0.0005 µg/L <0.0005 61.80.01 µg/L 13040






(MeFOSE)

24448-09-7 0.05 µg/L <0.05 92.11.25 µg/L 15070


(EtFOSE)

1691-99-2 0.05 µg/L <0.05 1101.25 µg/L 15070


(MeFOSAA)

2355-31-9 0.02 µg/L <0.02 1090.5 µg/L 13070

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Report






(EtFOSAA)

2991-50-6 0.02 µg/L <0.02 90.60.5 µg/L 13070



















0874_MW256_S_180411 ET1801006-002 14808-79-8ED041G: Sulfate as SO4 - Turbidimetric 87.220 mg/L 13070







Determined

0.01 µg/L 13050

375-92-8EP231X-ST: Perfluoroheptane sulfonic acid (PFHpS) 1020.01 µg/L 13050




Anonymous ET1801005-002 375-73-5EP231X: Perfluorobutane sulfonic acid (PFBS) 87.40.5 µg/L 13050


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Anonymous ET1801005-002 355-46-4EP231X: Perfluorohexane sulfonic acid (PFHxS) 98.20.5 µg/L 13050



Determined

0.5 µg/L 13050















Anonymous ET1801005-002 375-22-4EP231X: Perfluorobutanoic acid (PFBA) 1012.5 µg/L 13050














(MeFOSA)

# 29.60.025 µg/L 13030


(EtFOSA)

34.40.025 µg/L 13030



41.60.025 µg/L 13030



36.80.025 µg/L 13030

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Anonymous ES1810721-002 2355-31-9EP231X-ST: N-Methyl perfluorooctane


64.00.01 µg/L 13030


acid (EtFOSAA)

60.00.01 µg/L 13030


Anonymous ET1801005-002 754-91-6EP231X: Perfluorooctane sulfonamide (FOSA) 1100.5 µg/L 13050


(MeFOSA)

1131.25 µg/L 15050



(MeFOSE)

93.51.25 µg/L 15050


(EtFOSE)

1121.25 µg/L 15050


acid (MeFOSAA)

89.20.5 µg/L 13050


acid (EtFOSAA)

86.40.5 µg/L 13050







Anonymous ET1801005-002 757124-72-4EP231X: 4:2 Fluorotelomer sulfonic acid (4:2 FTS) 96.20.5 µg/L 13050




True

Environmental






MICHAEL AITKEN:Sampler No. of samples received : 17






Summary of Outliers













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Matrix: WATER








----Not

Determined


ES1810721--002 355-46-4Perfluorohexane

sulfonic acid

(PFHxS)




----Not

Determined


ES1810721--002 31506-32-8N-Methyl

perfluorooctane

sulfonamide

(MeFOSA)


objective















0874_MW261_S_180411, 0874_MW256_S_180411,

0874_MW217_S_180411, 0874_MW216_S_180411,

0874_MW215_S_180411, 0874_MW214_S_180411,

0874_MW213_S_180411, 0874_MW212_S_180411,

0874_MW211_S_180411, 0874_MW210_S_180411,

0874_MW208_S_180411, 0874_MW209_S_180411

25-Apr-2018---- 13-Apr-2018----11-Apr-2018 ---- ü



0874_MW261_S_180411, 0874_MW256_S_180411,

0874_MW217_S_180411, 0874_MW216_S_180411,

0874_MW215_S_180411, 0874_MW214_S_180411,

0874_MW213_S_180411, 0874_MW212_S_180411,

0874_MW211_S_180411, 0874_MW210_S_180411,

0874_MW208_S_180411, 0874_MW209_S_180411

09-May-2018---- 13-Apr-2018----11-Apr-2018 ---- ü

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0874_MW261_S_180411, 0874_MW256_S_180411,

0874_MW217_S_180411, 0874_MW216_S_180411,

0874_MW215_S_180411, 0874_MW214_S_180411,

0874_MW213_S_180411, 0874_MW212_S_180411,

0874_MW211_S_180411, 0874_MW210_S_180411,

0874_MW208_S_180411, 0874_MW209_S_180411

09-May-2018---- 13-Apr-2018----11-Apr-2018 ---- ü



0874_MW261_S_180411, 0874_MW256_S_180411,

0874_MW217_S_180411, 0874_MW216_S_180411,

0874_MW215_S_180411, 0874_MW214_S_180411,

0874_MW213_S_180411, 0874_MW212_S_180411,

0874_MW211_S_180411, 0874_MW210_S_180411,

0874_MW208_S_180411, 0874_MW209_S_180411

18-Apr-2018---- 17-Apr-2018----11-Apr-2018 ---- ü



0874_MW216_S_180411, 0874_MW212_S_180411,

0874_MW211_S_180411, 0874_MW210_S_180411,

0874_MW208_S_180411, 0874_MW209_S_180411

08-Oct-2018---- 19-Apr-2018----11-Apr-2018 ---- ü


0874_MW261_S_180411, 0874_MW256_S_180411,

0874_MW217_S_180411, 0874_MW215_S_180411,

0874_MW214_S_180411, 0874_MW213_S_180411,

0874_QC1MW_180411_01, 0874_QC3MW_180411_01,

0874_QC4MW_180411_01, 0874_QC5MW_180411_01,

0874_QC5MW_180411_02




0874_MW216_S_180411, 0874_MW212_S_180411,

0874_MW211_S_180411, 0874_MW210_S_180411,

0874_MW208_S_180411, 0874_MW209_S_180411

08-Oct-2018---- 19-Apr-2018----11-Apr-2018 ---- ü


0874_MW261_S_180411, 0874_MW256_S_180411,

0874_MW217_S_180411, 0874_MW215_S_180411,

0874_MW214_S_180411, 0874_MW213_S_180411,

0874_QC1MW_180411_01, 0874_QC3MW_180411_01,

0874_QC4MW_180411_01, 0874_QC5MW_180411_01,

0874_QC5MW_180411_02


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0874_MW216_S_180411, 0874_MW212_S_180411,

0874_MW211_S_180411, 0874_MW210_S_180411,

0874_MW208_S_180411, 0874_MW209_S_180411

08-Oct-2018---- 19-Apr-2018----11-Apr-2018 ---- ü


0874_MW261_S_180411, 0874_MW256_S_180411,

0874_MW217_S_180411, 0874_MW215_S_180411,

0874_MW214_S_180411, 0874_MW213_S_180411,

0874_QC1MW_180411_01, 0874_QC3MW_180411_01,

0874_QC4MW_180411_01, 0874_QC5MW_180411_01,

0874_QC5MW_180411_02




0874_MW216_S_180411, 0874_MW212_S_180411,

0874_MW211_S_180411, 0874_MW210_S_180411,

0874_MW208_S_180411, 0874_MW209_S_180411

08-Oct-2018---- 19-Apr-2018----11-Apr-2018 ---- ü


0874_MW261_S_180411, 0874_MW256_S_180411,

0874_MW217_S_180411, 0874_MW215_S_180411,

0874_MW214_S_180411, 0874_MW213_S_180411,

0874_QC1MW_180411_01, 0874_QC3MW_180411_01,

0874_QC4MW_180411_01, 0874_QC5MW_180411_01,

0874_QC5MW_180411_02


EP231P: PFAS Sums


0874_MW216_S_180411, 0874_MW212_S_180411,

0874_MW211_S_180411, 0874_MW210_S_180411,

0874_MW208_S_180411, 0874_MW209_S_180411

08-Oct-2018---- 19-Apr-2018----11-Apr-2018 ---- ü


0874_MW261_S_180411, 0874_MW256_S_180411,

0874_MW217_S_180411, 0874_MW215_S_180411,

0874_MW214_S_180411, 0874_MW213_S_180411,

0874_QC1MW_180411_01, 0874_QC3MW_180411_01,

0874_QC4MW_180411_01, 0874_QC5MW_180411_01,

0874_QC5MW_180411_02


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Method Blanks (MB)






Matrix Spikes (MS)





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Schedule B(3)







Discrete Analyser

ED041G WATER











Schedule B(3)



DA

EN055 - PG WATER










(PFAS) by LCMSMS

EP231X WATER










(PFAS) by LCMSMS

EP231X-ST WATER

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Environmental




:: AddressAddress GPO BOX 2907



QLD AUSTRALIA 4814






V4)


Site : ----




Date

20-Apr-2018


No. of coolers/boxes : :2 Temperature 7.7°, 8.1°C - Ice present

: : 17 / 171 SMALL ESKY + 1 MEDIUM

ESKY

Receipt Detail No. of samples received / analysed

General Comments






l Please note that only 1 PFAS bottle was provided for sample ALS ID #13

"0874_QC1MW_180411_01". Therefor we can not conduct the Major anions and cations analysis

requested on the COC.l Discounted Package Prices apply only when specific ALS Group Codes ('W', 'S', 'NT' suites) are referenced on COCs.

l ED037-P, ED041G, ED045G will be conducted by ALS Townsville, NATA accreditation no. 825, (Site no. 23313)

l EP231X, EP231X ST will be conducted by ALS Sydney, NATA accreditation no. 825, (Site no. 10911)












ET1801006-013 : [ 11-Apr-2018 ] : 0874_QC1MW_180411_01

ET1801006-014 : [ 11-Apr-2018 ] : 0874_QC3MW_180411_01

ET1801006-015 : [ 11-Apr-2018 ] : 0874_QC4MW_180411_01

ET1801006-016 : [ 11-Apr-2018 ] : 0874_QC5MW_180411_01

ET1801006-017 : [ 11-Apr-2018 ] : 0874_QC5MW_180411_02











component

WA

TE

R -

EP

23

1X

PF

AS

- F

ull

Su

ite (

28

ana

lyte

s)

WA

TE

R -

EP

23

1X

-ST

PF

AS

- S

up

er

Tra

ce W

ate

rs L

ong

Su

ite (

28

WA

TE

R -

NT

-01

& 0

2

Ca

, M

g, N

a, K

, C

l, S

O4

, A

lka

linity

ET1801006-001 11-Apr-2018 00:00 0874_MW261_S_180411 ü ü

ET1801006-002 11-Apr-2018 00:00 0874_MW256_S_180411 ü ü

ET1801006-003 11-Apr-2018 00:00 0874_MW217_S_180411 ü ü

ET1801006-004 11-Apr-2018 00:00 0874_MW216_S_180411 ü ü

ET1801006-005 11-Apr-2018 00:00 0874_MW215_S_180411 ü ü

ET1801006-006 11-Apr-2018 00:00 0874_MW214_S_180411 ü ü

ET1801006-007 11-Apr-2018 00:00 0874_MW213_S_180411 ü ü

ET1801006-008 11-Apr-2018 00:00 0874_MW212_S_180411 ü ü

ET1801006-009 11-Apr-2018 00:00 0874_MW211_S_180411 ü ü

ET1801006-010 11-Apr-2018 00:00 0874_MW210_S_180411 ü ü

ET1801006-011 11-Apr-2018 00:00 0874_MW208_S_180411 ü ü

ET1801006-012 11-Apr-2018 00:00 0874_MW209_S_180411 ü ü

ET1801006-013 11-Apr-2018 00:00 0874_QC1MW_180411_01 ü

ET1801006-014 11-Apr-2018 00:00 0874_QC3MW_180411_01 ü

ET1801006-015 11-Apr-2018 00:00 0874_QC4MW_180411_01 ü

ET1801006-016 11-Apr-2018 00:00 0874_QC5MW_180411_01 ü

ET1801006-017 11-Apr-2018 00:00 0874_QC5MW_180411_02 ü

Matrix: WATER


ID

Client sampling

date / time







ACCOUNTS PAYABLE


DAVID HARRIS








DERP LABREPORTS


PHIL SCHULZ








0 0.00 True

Environmental





C/O GPO BOX 2907








Site : ----






l General Comments











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General Comments







purposes.







Key :



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Analytical Results

--------0874_QC3SW_1804120874_SW104_1804120874_SW103_180412Client sample IDSub-Matrix: WATER

(Matrix: WATER)












405Chloride 433 ---- ---- ----mg/L116887-00-6


50Calcium 65 ---- ---- ----mg/L17440-70-2

29Magnesium 32 ---- ---- ----mg/L17439-95-4

224Sodium 260 ---- ---- ----mg/L17440-23-5

11Potassium 11 ---- ---- ----mg/L17440-09-7




0.91 2.72 ---- ---- ----%0.01----Ionic Balance



(PFBS)

0.146 <0.0005 ---- ----µg/L0.0005375-73-5


(PFBS)

---- ---- ---- ----µg/L0.02375-73-5


(PFPeS)

0.185 <0.0005 ---- ----µg/L0.00052706-91-4


(PFPeS)

---- ---- ---- ----µg/L0.022706-91-4


(PFHxS)

1.15 <0.0005 ---- ----µg/L0.0005355-46-4


(PFHxS)

---- ---- ---- ----µg/L0.02355-46-4


(PFHpS)

0.0351 <0.0005 ---- ----µg/L0.0005375-92-8


(PFHpS)

---- ---- ---- ----µg/L0.02375-92-8

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Analytical Results


(Matrix: WATER)






(PFOS)

0.0933 <0.0003 ---- ----µg/L0.00031763-23-1


(PFDS)

<0.0005 <0.0005 ---- ----µg/L0.0005335-77-3


(PFOS)

---- ---- ---- ----µg/L0.011763-23-1


(PFDS)

---- ---- ---- ----µg/L0.02335-77-3


----Perfluorobutanoic acid (PFBA) <0.002 <0.002 ---- ----µg/L0.002375-22-4


----Perfluoropentanoic acid (PFPeA) 0.0996 <0.0005 ---- ----µg/L0.00052706-90-3


----Perfluorohexanoic acid (PFHxA) 0.200 <0.0005 ---- ----µg/L0.0005307-24-4

0.15Perfluorohexanoic acid (PFHxA) ---- ---- ---- ----µg/L0.02307-24-4

----Perfluoroheptanoic acid (PFHpA) 0.0406 <0.0005 ---- ----µg/L0.0005375-85-9


----Perfluorooctanoic acid (PFOA) 0.0239 <0.0005 ---- ----µg/L0.0005335-67-1

0.03Perfluorooctanoic acid (PFOA) ---- ---- ---- ----µg/L0.01335-67-1

----Perfluorononanoic acid (PFNA) <0.0005 <0.0005 ---- ----µg/L0.0005375-95-1


----Perfluorodecanoic acid (PFDA) <0.0005 <0.0005 ---- ----µg/L0.0005335-76-2



(PFUnDA)

<0.0005 <0.0005 ---- ----µg/L0.00052058-94-8


(PFUnDA)

---- ---- ---- ----µg/L0.022058-94-8


(PFDoDA)

<0.0005 <0.0005 ---- ----µg/L0.0005307-55-1


(PFDoDA)

---- ---- ---- ----µg/L0.02307-55-1


(PFTrDA)

<0.0005 <0.0005 ---- ----µg/L0.000572629-94-8


(PFTrDA)

---- ---- ---- ----µg/L0.0272629-94-8

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Analytical Results


(Matrix: WATER)






(PFTeDA)

<0.0005 <0.0005 ---- ----µg/L0.0005376-06-7


(PFTeDA)

---- ---- ---- ----µg/L0.05376-06-7



(FOSA)

<0.0005 <0.0005 ---- ----µg/L0.0005754-91-6


(FOSA)

---- ---- ---- ----µg/L0.02754-91-6



<0.001 <0.001 ---- ----µg/L0.00131506-32-8



---- ---- ---- ----µg/L0.0531506-32-8



<0.001 <0.001 ---- ----µg/L0.0014151-50-2



---- ---- ---- ----µg/L0.054151-50-2



<0.001 <0.001 ---- ----µg/L0.00124448-09-7



---- ---- ---- ----µg/L0.0524448-09-7



<0.001 <0.001 ---- ----µg/L0.0011691-99-2



---- ---- ---- ----µg/L0.051691-99-2



(MeFOSAA)

<0.0005 <0.0005 ---- ----µg/L0.00052355-31-9



(MeFOSAA)

---- ---- ---- ----µg/L0.022355-31-9



(EtFOSAA)

<0.0005 <0.0005 ---- ----µg/L0.00052991-50-6

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Analytical Results


(Matrix: WATER)







(EtFOSAA)

---- ---- ---- ----µg/L0.022991-50-6



(4:2 FTS)

<0.001 <0.001 ---- ----µg/L0.001757124-72-4


(4:2 FTS)

---- ---- ---- ----µg/L0.05757124-72-4


(6:2 FTS)

<0.001 <0.001 ---- ----µg/L0.00127619-97-2


(6:2 FTS)

---- ---- ---- ----µg/L0.0527619-97-2


(8:2 FTS)

<0.001 <0.001 ---- ----µg/L0.00139108-34-4


(8:2 FTS)

---- ---- ---- ----µg/L0.0539108-34-4


(10:2 FTS)

<0.001 <0.001 ---- ----µg/L0.001120226-60-0


(10:2 FTS)

---- ---- ---- ----µg/L0.05120226-60-0

EP231P: PFAS Sums

---- 1.97 <0.0003 ---- ----µg/L0.0003----Sum of PFAS

1.81 ---- ---- ---- ----µg/L0.01----Sum of PFAS

----Sum of PFHxS and PFOS 1.24 <0.0003 ---- ----µg/L0.0003355-46-4/1763-23-

1


1

---- 1.75 <0.0003 ---- ----µg/L0.0003----Sum of PFAS (WA DER List)



---- 75.2 60.9 ---- ----%0.0005----13C4-PFOS

83.5 ---- ---- ---- ----%0.02----13C4-PFOS

---- 80.0 82.2 ---- ----%0.0005----13C8-PFOA

107 ---- ---- ---- ----%0.02----13C8-PFOA

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13C4-PFOS ---- 60 130

13C8-PFOA ---- 60 130

False

3 3.00True

Environmental




:Address MOBIL

C/O GPO BOX 2907








Site : ----















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General Comments










Key :

























ED093F: Sodium 7440-23-5 1 mg/L 224 224 0.00 0% - 20%




ED093F: Sodium 7440-23-5 1 mg/L 2170 2180 0.480 0% - 20%



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(PFOS)

1763-23-1 0.0003 µg/L <0.0003 <0.0003 0.00 No LimitAnonymous EB1809230-007


(PFBS)

375-73-5 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFPeS)

2706-91-4 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFHxS)

355-46-4 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFHpS)

375-92-8 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFDS)

335-77-3 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFOS)



(PFBS)

375-73-5 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFPeS)

2706-91-4 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFHxS)

355-46-4 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFHpS)

375-92-8 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFDS)

335-77-3 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


EP231X: Perfluorooctane sulfonic acid (PFOS) 1763-23-1 0.01 µg/L <0.01 <0.01 0.00 No LimitAnonymous ES1810944-002






EP231X: Perfluorooctane sulfonic acid (PFOS) 1763-23-1 0.01 µg/L 0.02 0.02 0.00 No LimitAnonymous ES1811130-008







EP231X-ST: Perfluoropentanoic acid (PFPeA) 2706-90-3 0.0005 µg/L <0.0005 <0.0005 0.00 No LimitAnonymous EB1809230-007



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EP231X-ST: Perfluorooctanoic acid (PFOA) 335-67-1 0.0005 µg/L <0.0005 <0.0005 0.00 No LimitAnonymous EB1809230-007







(PFTeDA)

376-06-7 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit












(PFTeDA)

376-06-7 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit





















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EP231X: Perfluorododecanoic acid (PFDoDA) 307-55-1 0.02 µg/L <0.02 <0.02 0.00 No LimitAnonymous ES1811130-008






(FOSA)




2355-31-9 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit



2991-50-6 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit



31506-32-8 0.001 µg/L <0.001 <0.001 0.00 No Limit


(EtFOSA)

4151-50-2 0.001 µg/L <0.001 <0.001 0.00 No Limit



24448-09-7 0.001 µg/L <0.001 <0.001 0.00 No Limit



1691-99-2 0.001 µg/L <0.001 <0.001 0.00 No Limit


(FOSA)




2355-31-9 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit



2991-50-6 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit



31506-32-8 0.001 µg/L <0.001 <0.001 0.00 No Limit


(EtFOSA)

4151-50-2 0.001 µg/L <0.001 <0.001 0.00 No Limit



24448-09-7 0.001 µg/L <0.001 <0.001 0.00 No Limit



1691-99-2 0.001 µg/L <0.001 <0.001 0.00 No Limit





2355-31-9 0.02 µg/L <0.02 <0.02 0.00 No Limit



2991-50-6 0.02 µg/L <0.02 <0.02 0.00 No Limit


(MeFOSA)

31506-32-8 0.05 µg/L <0.05 <0.05 0.00 No Limit

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(EtFOSA)




24448-09-7 0.05 µg/L <0.05 <0.05 0.00 No Limit



1691-99-2 0.05 µg/L <0.05 <0.05 0.00 No Limit




2355-31-9 0.02 µg/L <0.02 <0.02 0.00 No Limit



2991-50-6 0.02 µg/L <0.02 <0.02 0.00 No Limit


(MeFOSA)

31506-32-8 0.05 µg/L <0.05 <0.05 0.00 No Limit


(EtFOSA)

4151-50-2 0.05 µg/L <0.05 <0.05 0.00 No Limit



24448-09-7 0.05 µg/L <0.05 <0.05 0.00 No Limit



1691-99-2 0.05 µg/L <0.05 <0.05 0.00 No Limit



FTS)



FTS)

27619-97-2 0.001 µg/L <0.001 <0.001 0.00 No Limit


FTS)

39108-34-4 0.001 µg/L <0.001 <0.001 0.00 No Limit


(10:2 FTS)

120226-60-0 0.001 µg/L <0.001 <0.001 0.00 No Limit


FTS)



FTS)

27619-97-2 0.001 µg/L <0.001 <0.001 0.00 No Limit


FTS)

39108-34-4 0.001 µg/L <0.001 <0.001 0.00 No Limit


(10:2 FTS)

120226-60-0 0.001 µg/L <0.001 <0.001 0.00 No Limit



FTS)



FTS)

27619-97-2 0.05 µg/L <0.05 <0.05 0.00 No Limit

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FTS)



FTS)

120226-60-0 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)



FTS)

27619-97-2 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

39108-34-4 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

120226-60-0 0.05 µg/L <0.05 <0.05 0.00 No Limit


EP231X-ST: Sum of PFAS ---- 0.0003 µg/L <0.0003 <0.0003 0.00 No LimitAnonymous EB1809230-007



EP231X: Sum of PFAS ---- 0.01 µg/L <0.01 <0.01 0.00 No LimitAnonymous ES1810944-002

EP231X: Sum of PFAS ---- 0.01 µg/L 0.02 0.02 0.00 No LimitAnonymous ES1811130-008

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Report








<1 10025 mg/L 12080



<1 96.410 mg/L 12080


ED093F: Calcium 7440-70-2 1 mg/L <1 -------- --------


ED093F: Sodium 7440-23-5 1 mg/L <1 -------- --------







EP231X-ST: Perfluorooctane sulfonic acid (PFOS) 1763-23-1 0.0003 µg/L <0.0003 1170.01 µg/L 13050

















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Report
























(MeFOSA)

31506-32-8 0.001 µg/L <0.001 41.40.025 µg/L 13040



(MeFOSE)

24448-09-7 0.001 µg/L <0.001 48.00.025 µg/L 13040


(EtFOSE)

1691-99-2 0.001 µg/L <0.001 58.90.025 µg/L 13040


acid (MeFOSAA)

2355-31-9 0.0005 µg/L <0.0005 53.20.01 µg/L 13040


acid (EtFOSAA)

2991-50-6 0.0005 µg/L <0.0005 51.40.01 µg/L 13040


EP231X: Perfluorooctane sulfonamide (FOSA) 754-91-6 0.02 µg/L <0.02 77.80.5 µg/L 13070




(MeFOSE)

24448-09-7 0.05 µg/L <0.05 1031.25 µg/L 15070


(EtFOSE)

1691-99-2 0.05 µg/L <0.05 99.81.25 µg/L 15070


(MeFOSAA)

2355-31-9 0.02 µg/L <0.02 1250.5 µg/L 13070

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Report






(EtFOSAA)

2991-50-6 0.02 µg/L <0.02 1200.5 µg/L 13070























Anonymous EB1809230-009 375-73-5EP231X-ST: Perfluorobutane sulfonic acid (PFBS) 58.60.01 µg/L 13050







Anonymous ES1810944-002 375-73-5EP231X: Perfluorobutane sulfonic acid (PFBS) 1100.5 µg/L 13050


355-46-4EP231X: Perfluorohexane sulfonic acid (PFHxS) 85.80.5 µg/L 13050

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Anonymous ES1810944-002 375-92-8EP231X: Perfluoroheptane sulfonic acid (PFHpS) 1120.5 µg/L 13050




Anonymous EB1809230-009 375-22-4EP231X-ST: Perfluorobutanoic acid (PFBA) 78.80.05 µg/L 13030














307-24-4EP231X: Perfluorohexanoic acid (PFHxA) 95.40.5 µg/L 13050




335-76-2EP231X: Perfluorodecanoic acid (PFDA) 1040.5 µg/L 13050






Anonymous EB1809230-009 754-91-6EP231X-ST: Perfluorooctane sulfonamide (FOSA) 70.60.01 µg/L 13030


(MeFOSA)

31.50.025 µg/L 13030


(EtFOSA)

41.80.025 µg/L 13030



39.00.025 µg/L 13030



56.60.025 µg/L 13030



45.20.01 µg/L 13030

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Anonymous EB1809230-009 2991-50-6EP231X-ST: N-Ethyl perfluorooctane sulfonamidoacetic

acid (EtFOSAA)

51.20.01 µg/L 13030


Anonymous ES1810944-002 754-91-6EP231X: Perfluorooctane sulfonamide (FOSA) 82.20.5 µg/L 13050


(MeFOSA)

1041.25 µg/L 15050



(MeFOSE)

1151.25 µg/L 15050


(EtFOSE)

98.81.25 µg/L 15050


acid (MeFOSAA)

1200.5 µg/L 13050


acid (EtFOSAA)

96.00.5 µg/L 13050


Anonymous EB1809230-009 757124-72-4EP231X-ST: 4:2 Fluorotelomer sulfonic acid (4:2 FTS) 98.80.01 µg/L 13050









True

Environmental












Summary of Outliers






l NO Matrix Spike outliers occur.







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0874_SW103_180412, 0874_SW104_180412 26-Apr-2018---- 13-Apr-2018----12-Apr-2018 ---- üED041G: Sulfate (Turbidimetric) as SO4 2- by DA


0874_SW103_180412, 0874_SW104_180412 10-May-2018---- 13-Apr-2018----12-Apr-2018 ---- üED045G: Chloride by Discrete Analyser


0874_SW103_180412, 0874_SW104_180412 10-May-2018---- 13-Apr-2018----12-Apr-2018 ---- üED093F: Dissolved Major Cations


0874_SW103_180412, 0874_SW104_180412 19-Apr-2018---- 18-Apr-2018----12-Apr-2018 ---- üEP231A: Perfluoroalkyl Sulfonic Acids


0874_SW103_180412 09-Oct-2018---- 23-Apr-2018----12-Apr-2018 ---- üHDPE (no PTFE) (EP231X-ST)

0874_SW104_180412, 0874_QC3SW_180412 09-Oct-201809-Oct-2018 23-Apr-201822-Apr-201812-Apr-2018 ü üEP231B: Perfluoroalkyl Carboxylic Acids



0874_SW104_180412, 0874_QC3SW_180412 09-Oct-201809-Oct-2018 23-Apr-201822-Apr-201812-Apr-2018 ü üEP231C: Perfluoroalkyl Sulfonamides



0874_SW104_180412, 0874_QC3SW_180412 09-Oct-201809-Oct-2018 23-Apr-201822-Apr-201812-Apr-2018 ü üEP231D: (n:2) Fluorotelomer Sulfonic Acids



0874_SW104_180412, 0874_QC3SW_180412 09-Oct-201809-Oct-2018 23-Apr-201822-Apr-201812-Apr-2018 ü ü

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EP231P: PFAS Sums



0874_SW104_180412, 0874_QC3SW_180412 09-Oct-201809-Oct-2018 23-Apr-201822-Apr-201812-Apr-2018 ü ü

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Method Blanks (MB)






Matrix Spikes (MS)





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Schedule B(3)







Discrete Analyser

ED041G WATER











Schedule B(3)



DA

EN055 - PG WATER










(PFAS) by LCMSMS

EP231X WATER










(PFAS) by LCMSMS

EP231X-ST WATER

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Environmental





C/O GPO BOX 2907



QLD AUSTRALIA 4814






V4)


Site : ----




Date

24-Apr-2018



: : 3 / 3SMALL ESKYReceipt Detail No. of samples received / analysed

General Comments





























component

WA

TE

R -

EP

231X

PF

AS

- F

ull

Su

ite (

28 a

na

lyte

s)

WA

TE

R -

EP

231X

-ST

PF

AS

- S

up

er

Tra

ce W

ate

rs L

ong

Suite

(2

8

WA

TE

R -

NT

-01 &

02

Ca, M

g, N

a, K

, C

l, S

O4

, A

lka

linity

ET1801010-001 12-Apr-2018 00:00 0874_SW103_180412 ü ü

ET1801010-002 12-Apr-2018 00:00 0874_SW104_180412 ü ü

ET1801010-003 12-Apr-2018 00:00 0874_QC3SW_180412 ü

Matrix: WATER


ID

Client sampling

date / time




ACCOUNTS PAYABLE


AU ACCOUNTS PAYABLE


DAVID HARRIS








DERP LABREPORTS


PHIL SCHULZ









RESULTS RESULTS








0 0.00 True

Environmental





C/O GPO BOX 2907







Sampler : Andi Carnall, JACK MCBAIN, MA

Site : ----






l General Comments













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General Comments







purposes.







Key :



EP231X: Particular samples required dilution due to sample matrix . LOR values have been adjusted accordingly.l

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Analytical Results

0874_MW466_S_1804

12

0874_MW463_S_1804

12

0874_MW465_S_1804

12

0874_MW455_S_1804

12

0874_MW456_S_1804

12


(Matrix: WATER)










35Sulfate as SO4 - Turbidimetric 75 12 <1 4mg/L114808-79-8


34Chloride 254 7 93 66mg/L116887-00-6


1Calcium 8 11 21 34mg/L17440-70-2

<1Magnesium 7 2 10 12mg/L17439-95-4

78Sodium 370 45 345 68mg/L17440-23-5

<1Potassium 3 <1 3 2mg/L17440-09-7




0.53 0.84 ---- 1.39 0.07%0.01----Ionic Balance



(PFBS)

---- ---- 0.0342 ----µg/L0.0005375-73-5


(PFBS)

0.03 <0.02 ---- <0.02µg/L0.02375-73-5


(PFPeS)

---- ---- 0.0581 ----µg/L0.00052706-91-4


(PFPeS)

<0.02 <0.02 ---- <0.02µg/L0.022706-91-4


(PFHxS)

---- ---- 0.720 ----µg/L0.0005355-46-4


(PFHxS)

0.14 <0.02 ---- <0.02µg/L0.02355-46-4


(PFHpS)

---- ---- 0.0376 ----µg/L0.0005375-92-8


(PFHpS)

<0.02 <0.02 ---- <0.02µg/L0.02375-92-8

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Analytical Results

0874_MW466_S_1804

12

0874_MW463_S_1804

12

0874_MW465_S_1804

12

0874_MW455_S_1804

12

0874_MW456_S_1804

12


(Matrix: WATER)






(PFOS)

---- ---- 0.103 ----µg/L0.00031763-23-1


(PFDS)

---- ---- <0.0005 ----µg/L0.0005335-77-3


(PFOS)

0.51 0.02 ---- <0.01µg/L0.011763-23-1


(PFDS)

<0.02 <0.02 ---- <0.02µg/L0.02335-77-3



<0.1Perfluorobutanoic acid (PFBA) <0.1 <0.1 ---- <0.1µg/L0.1375-22-4


<0.02Perfluoropentanoic acid (PFPeA) <0.02 <0.02 ---- <0.02µg/L0.022706-90-3


0.03Perfluorohexanoic acid (PFHxA) <0.02 <0.02 ---- <0.02µg/L0.02307-24-4


<0.02Perfluoroheptanoic acid (PFHpA) <0.02 <0.02 ---- <0.02µg/L0.02375-85-9


0.01Perfluorooctanoic acid (PFOA) <0.01 <0.01 ---- <0.01µg/L0.01335-67-1


<0.02Perfluorononanoic acid (PFNA) <0.02 <0.02 ---- <0.02µg/L0.02375-95-1

----Perfluorodecanoic acid (PFDA) ---- ---- 0.0010 ----µg/L0.0005335-76-2

<0.02Perfluorodecanoic acid (PFDA) <0.02 <0.02 ---- <0.02µg/L0.02335-76-2


(PFUnDA)

---- ---- <0.0005 ----µg/L0.00052058-94-8


(PFUnDA)

<0.02 <0.02 ---- <0.02µg/L0.022058-94-8


(PFDoDA)

---- ---- <0.0005 ----µg/L0.0005307-55-1


(PFDoDA)

<0.02 <0.02 ---- <0.02µg/L0.02307-55-1


(PFTrDA)

---- ---- <0.0005 ----µg/L0.000572629-94-8


(PFTrDA)

<0.02 <0.02 ---- <0.02µg/L0.0272629-94-8

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Analytical Results

0874_MW466_S_1804

12

0874_MW463_S_1804

12

0874_MW465_S_1804

12

0874_MW455_S_1804

12

0874_MW456_S_1804

12


(Matrix: WATER)






(PFTeDA)

---- ---- <0.0005 ----µg/L0.0005376-06-7


(PFTeDA)

<0.05 <0.05 ---- <0.05µg/L0.05376-06-7



(FOSA)

---- ---- <0.0005 ----µg/L0.0005754-91-6


(FOSA)

<0.02 <0.02 ---- <0.02µg/L0.02754-91-6



---- ---- <0.001 ----µg/L0.00131506-32-8



<0.05 <0.05 ---- <0.05µg/L0.0531506-32-8



---- ---- <0.001 ----µg/L0.0014151-50-2



<0.05 <0.05 ---- <0.05µg/L0.054151-50-2



---- ---- <0.001 ----µg/L0.00124448-09-7



<0.05 <0.05 ---- <0.05µg/L0.0524448-09-7



---- ---- <0.001 ----µg/L0.0011691-99-2



<0.05 <0.05 ---- <0.05µg/L0.051691-99-2



(MeFOSAA)

---- ---- <0.0005 ----µg/L0.00052355-31-9



(MeFOSAA)

<0.02 <0.02 ---- <0.02µg/L0.022355-31-9



(EtFOSAA)

---- ---- <0.0005 ----µg/L0.00052991-50-6

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Analytical Results

0874_MW466_S_1804

12

0874_MW463_S_1804

12

0874_MW465_S_1804

12

0874_MW455_S_1804

12

0874_MW456_S_1804

12


(Matrix: WATER)







(EtFOSAA)

<0.02 <0.02 ---- <0.02µg/L0.022991-50-6



(4:2 FTS)

---- ---- <0.001 ----µg/L0.001757124-72-4


(4:2 FTS)

<0.05 <0.05 ---- <0.05µg/L0.05757124-72-4


(6:2 FTS)

---- ---- <0.001 ----µg/L0.00127619-97-2


(6:2 FTS)

<0.05 <0.05 ---- <0.05µg/L0.0527619-97-2


(8:2 FTS)

---- ---- <0.001 ----µg/L0.00139108-34-4


(8:2 FTS)

<0.05 <0.05 ---- <0.05µg/L0.0539108-34-4


(10:2 FTS)

---- ---- <0.001 ----µg/L0.001120226-60-0


(10:2 FTS)

<0.05 <0.05 ---- <0.05µg/L0.05120226-60-0

EP231P: PFAS Sums

---- ---- ---- 1.07 ----µg/L0.0003----Sum of PFAS

1.12 0.68 0.02 ---- <0.01µg/L0.01----Sum of PFAS


1

0.99Sum of PFHxS and PFOS 0.65 0.02 ---- <0.01µg/L0.01355-46-4/1763-23-

1


1.08 0.68 0.02 ---- <0.01µg/L0.01----Sum of PFAS (WA DER List)


---- ---- ---- 66.4 ----%0.0005----13C4-PFOS

89.7 99.7 105 ---- 95.2%0.02----13C4-PFOS

---- ---- ---- 77.9 ----%0.0005----13C8-PFOA

105 109 114 ---- 110%0.02----13C8-PFOA

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Analytical Results

0874_MW437_S_1804

12

0874_MW439_S_1804

12

0874_MW415_S_1804

12

0874_MW414_S_1804

12

0874_MW422_S_1804

12


(Matrix: WATER)












7000Chloride 33 2610 8610 496mg/L116887-00-6


192Calcium 6 47 226 12mg/L17440-70-2

267Magnesium 9 82 430 7mg/L17439-95-4

4220Sodium 476 2170 5820 444mg/L17440-23-5

52Potassium 3 22 88 7mg/L17440-09-7


220 22.0 107 271 21.0meq/L0.01----Total Anions

216 21.8 104 302 20.7meq/L0.01----Total Cations

0.86 0.42 1.37 5.45 0.78%0.01----Ionic Balance



(PFBS)

0.06 0.35 0.10 0.08µg/L0.02375-73-5


(PFPeS)

0.03 0.52 0.10 0.05µg/L0.022706-91-4


(PFHxS)

0.39 2.93 0.58 0.25µg/L0.02355-46-4


(PFHpS)

0.03 0.12 <0.05 <0.02µg/L0.02375-92-8


(PFOS)

1.21 1.41 0.08 0.06µg/L0.011763-23-1


(PFDS)

<0.02 <0.02 <0.05 <0.02µg/L0.02335-77-3


<0.1Perfluorobutanoic acid (PFBA) 1.2 0.2 <0.2 <0.1µg/L0.1375-22-4

<0.02Perfluoropentanoic acid (PFPeA) 1.02 0.04 <0.05 <0.02µg/L0.022706-90-3

<0.02Perfluorohexanoic acid (PFHxA) 0.59 0.20 0.09 0.03µg/L0.02307-24-4

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Analytical Results

0874_MW437_S_1804

12

0874_MW439_S_1804

12

0874_MW415_S_1804

12

0874_MW414_S_1804

12

0874_MW422_S_1804

12


(Matrix: WATER)





<0.02Perfluoroheptanoic acid (PFHpA) 0.55 0.06 <0.05 <0.02µg/L0.02375-85-9

<0.01Perfluorooctanoic acid (PFOA) 0.38 0.16 <0.05 <0.01µg/L0.01335-67-1

<0.02Perfluorononanoic acid (PFNA) 0.08 <0.02 <0.05 <0.02µg/L0.02375-95-1



(PFUnDA)

<0.02 <0.02 <0.05 <0.02µg/L0.022058-94-8


(PFDoDA)

<0.02 <0.02 <0.05 <0.02µg/L0.02307-55-1


(PFTrDA)

<0.02 <0.02 <0.05 <0.02µg/L0.0272629-94-8


(PFTeDA)

<0.05 <0.05 <0.12 <0.05µg/L0.05376-06-7



(FOSA)

<0.02 <0.02 <0.05 <0.02µg/L0.02754-91-6



<0.05 <0.05 <0.12 <0.05µg/L0.0531506-32-8



<0.05 <0.05 <0.12 <0.05µg/L0.054151-50-2



<0.05 <0.05 <0.12 <0.05µg/L0.0524448-09-7



<0.05 <0.05 <0.12 <0.05µg/L0.051691-99-2



(MeFOSAA)

<0.02 <0.02 <0.05 <0.02µg/L0.022355-31-9



(EtFOSAA)

<0.02 <0.02 <0.05 <0.02µg/L0.022991-50-6



(4:2 FTS)

<0.05 <0.05 <0.05 <0.05µg/L0.05757124-72-4


(6:2 FTS)

<0.05 <0.05 <0.05 <0.05µg/L0.0527619-97-2


(8:2 FTS)

<0.05 <0.05 <0.05 <0.05µg/L0.0539108-34-4

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Analytical Results

0874_MW437_S_1804

12

0874_MW439_S_1804

12

0874_MW415_S_1804

12

0874_MW414_S_1804

12

0874_MW422_S_1804

12


(Matrix: WATER)






(10:2 FTS)

<0.05 <0.05 <0.05 <0.05µg/L0.05120226-60-0

EP231P: PFAS Sums

0.12 5.54 5.99 0.95 0.47µg/L0.01----Sum of PFAS

0.05Sum of PFHxS and PFOS 1.60 4.34 0.66 0.31µg/L0.01355-46-4/1763-23-

1

0.09 5.40 5.35 0.85 0.42µg/L0.01----Sum of PFAS (WA DER List)


94.1 94.8 94.7 92.9 94.1%0.02----13C4-PFOS

111 111 108 101 96.6%0.02----13C8-PFOA

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Analytical Results

0874_MW006_S_1804

12

0874_MW457_S_1804

12

0874_MW459_S_1804

12

0874_MW460_S_1804

12

0874_MW140_D_1804

12


(Matrix: WATER)












19300Chloride 7540 1640 328 7760mg/L116887-00-6


438Calcium 632 86 114 657mg/L17440-70-2

1260Magnesium 502 72 22 519mg/L17439-95-4

11300Sodium 3510 1260 156 3720mg/L17440-23-5

353Potassium 6 1 <1 15mg/L17440-09-7


606 237 65.0 14.3 232meq/L0.01----Total Anions

626 226 65.0 14.3 238meq/L0.01----Total Cations

1.61 2.50 0.06 0.08 1.22%0.01----Ionic Balance



(PFBS)

0.490 ---- ---- ----µg/L0.0005375-73-5


(PFBS)

---- 0.41 0.46 <0.05µg/L0.02375-73-5


(PFPeS)

0.451 ---- ---- ----µg/L0.00052706-91-4


(PFPeS)

---- 0.39 0.49 <0.05µg/L0.022706-91-4


(PFHxS)

3.91 ---- ---- ----µg/L0.0005355-46-4


(PFHxS)

---- 2.13 2.12 0.19µg/L0.02355-46-4


(PFHpS)

0.284 ---- ---- ----µg/L0.0005375-92-8


(PFHpS)

---- 0.24 0.25 <0.05µg/L0.02375-92-8

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Analytical Results

0874_MW006_S_1804

12

0874_MW457_S_1804

12

0874_MW459_S_1804

12

0874_MW460_S_1804

12

0874_MW140_D_1804

12


(Matrix: WATER)






(PFOS)

0.145 ---- ---- ----µg/L0.00031763-23-1


(PFDS)

<0.0005 ---- ---- ----µg/L0.0005335-77-3


(PFOS)

---- 4.53 6.13 0.20µg/L0.011763-23-1


(PFDS)

---- <0.02 <0.02 <0.05µg/L0.02335-77-3


0.003Perfluorobutanoic acid (PFBA) 0.030 ---- ---- ----µg/L0.002375-22-4

----Perfluorobutanoic acid (PFBA) ---- 0.2 0.3 <0.2µg/L0.1375-22-4

0.0029Perfluoropentanoic acid (PFPeA) 0.204 ---- ---- ----µg/L0.00052706-90-3

----Perfluoropentanoic acid (PFPeA) ---- 0.12 0.22 <0.05µg/L0.022706-90-3


----Perfluorohexanoic acid (PFHxA) ---- 0.58 1.07 <0.05µg/L0.02307-24-4

0.0008Perfluoroheptanoic acid (PFHpA) 0.165 ---- ---- ----µg/L0.0005375-85-9

----Perfluoroheptanoic acid (PFHpA) ---- 0.06 0.19 <0.05µg/L0.02375-85-9


----Perfluorooctanoic acid (PFOA) ---- 0.13 0.39 <0.05µg/L0.01335-67-1

<0.0005Perfluorononanoic acid (PFNA) 0.0007 ---- ---- ----µg/L0.0005375-95-1

----Perfluorononanoic acid (PFNA) ---- <0.02 0.05 <0.05µg/L0.02375-95-1




(PFUnDA)

<0.0005 ---- ---- ----µg/L0.00052058-94-8


(PFUnDA)

---- <0.02 <0.02 <0.05µg/L0.022058-94-8


(PFDoDA)

<0.0005 ---- ---- ----µg/L0.0005307-55-1


(PFDoDA)

---- <0.02 <0.02 <0.05µg/L0.02307-55-1


(PFTrDA)

<0.0005 ---- ---- ----µg/L0.000572629-94-8


(PFTrDA)

---- <0.02 <0.02 <0.05µg/L0.0272629-94-8

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Analytical Results

0874_MW006_S_1804

12

0874_MW457_S_1804

12

0874_MW459_S_1804

12

0874_MW460_S_1804

12

0874_MW140_D_1804

12


(Matrix: WATER)






(PFTeDA)

<0.0005 ---- ---- ----µg/L0.0005376-06-7


(PFTeDA)

---- <0.05 <0.05 <0.12µg/L0.05376-06-7



(FOSA)

<0.0005 ---- ---- ----µg/L0.0005754-91-6


(FOSA)

---- <0.02 <0.02 <0.05µg/L0.02754-91-6



<0.001 ---- ---- ----µg/L0.00131506-32-8



---- <0.05 <0.05 <0.12µg/L0.0531506-32-8



<0.001 ---- ---- ----µg/L0.0014151-50-2



---- <0.05 <0.05 <0.12µg/L0.054151-50-2



<0.001 ---- ---- ----µg/L0.00124448-09-7



---- <0.05 <0.05 <0.12µg/L0.0524448-09-7



<0.001 ---- ---- ----µg/L0.0011691-99-2



---- <0.05 <0.05 <0.12µg/L0.051691-99-2



(MeFOSAA)

<0.0005 ---- ---- ----µg/L0.00052355-31-9



(MeFOSAA)

---- <0.02 <0.02 <0.05µg/L0.022355-31-9



(EtFOSAA)

<0.0005 ---- ---- ----µg/L0.00052991-50-6

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Analytical Results

0874_MW006_S_1804

12

0874_MW457_S_1804

12

0874_MW459_S_1804

12

0874_MW460_S_1804

12

0874_MW140_D_1804

12


(Matrix: WATER)







(EtFOSAA)

---- <0.02 <0.02 <0.05µg/L0.022991-50-6



(4:2 FTS)

<0.001 ---- ---- ----µg/L0.001757124-72-4


(4:2 FTS)

---- <0.05 <0.05 <0.05µg/L0.05757124-72-4


(6:2 FTS)

<0.001 ---- ---- ----µg/L0.00127619-97-2


(6:2 FTS)

---- <0.05 <0.05 <0.05µg/L0.0527619-97-2


(8:2 FTS)

<0.001 ---- ---- ----µg/L0.00139108-34-4


(8:2 FTS)

---- <0.05 <0.05 <0.05µg/L0.0539108-34-4


(10:2 FTS)

<0.001 ---- ---- ----µg/L0.001120226-60-0


(10:2 FTS)

---- <0.05 <0.05 <0.05µg/L0.05120226-60-0

EP231P: PFAS Sums

0.194 6.57 ---- ---- ----µg/L0.0003----Sum of PFAS

---- ---- 8.79 11.7 0.39µg/L0.01----Sum of PFAS


1

----Sum of PFHxS and PFOS ---- 6.66 8.25 0.39µg/L0.01355-46-4/1763-23-

1


---- ---- 8.16 10.9 0.39µg/L0.01----Sum of PFAS (WA DER List)


71.0 75.4 ---- ---- ----%0.0005----13C4-PFOS

---- ---- 97.7 91.3 92.2%0.02----13C4-PFOS

101 115 ---- ---- ----%0.0005----13C8-PFOA

---- ---- 103 107 102%0.02----13C8-PFOA

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Analytical Results

0874_QC5MW_18041

2_01

0874_QC4MW_18041

2_01

0874_QC3MW_18041

2_01

0874_MW241_S_1804

12

0874_MW049_S_1804

12


(Matrix: WATER)












91Chloride 4870 ---- ---- ----mg/L116887-00-6


13Calcium 517 ---- ---- ----mg/L17440-70-2

3Magnesium 298 ---- ---- ----mg/L17439-95-4

113Sodium 3000 ---- ---- ----mg/L17440-23-5

3Potassium 114 ---- ---- ----mg/L17440-09-7


5.79 190 ---- ---- ----meq/L0.01----Total Anions

5.89 184 ---- ---- ----meq/L0.01----Total Cations

0.82 1.63 ---- ---- ----%0.01----Ionic Balance



(PFBS)

0.384 <0.0005 <0.0005 <0.0005µg/L0.0005375-73-5


(PFBS)

---- ---- ---- ----µg/L0.02375-73-5


(PFPeS)

0.0334 <0.0005 <0.0005 <0.0005µg/L0.00052706-91-4


(PFPeS)

---- ---- ---- ----µg/L0.022706-91-4


(PFHxS)

2.23 <0.0005 <0.0005 <0.0005µg/L0.0005355-46-4


(PFHxS)

---- ---- ---- ----µg/L0.02355-46-4


(PFHpS)

0.0287 <0.0005 <0.0005 <0.0005µg/L0.0005375-92-8


(PFHpS)

---- ---- ---- ----µg/L0.02375-92-8

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Analytical Results

0874_QC5MW_18041

2_01

0874_QC4MW_18041

2_01

0874_QC3MW_18041

2_01

0874_MW241_S_1804

12

0874_MW049_S_1804

12


(Matrix: WATER)






(PFOS)

0.0739 <0.0003 <0.0003 <0.0003µg/L0.00031763-23-1


(PFDS)

<0.0005 <0.0005 <0.0005 <0.0005µg/L0.0005335-77-3


(PFOS)

---- ---- ---- ----µg/L0.011763-23-1


(PFDS)

---- ---- ---- ----µg/L0.02335-77-3


----Perfluorobutanoic acid (PFBA) 0.018 <0.002 <0.002 <0.002µg/L0.002375-22-4

0.1Perfluorobutanoic acid (PFBA) ---- ---- ---- ----µg/L0.1375-22-4

----Perfluoropentanoic acid (PFPeA) 0.0386 <0.0005 <0.0005 <0.0005µg/L0.00052706-90-3

0.40Perfluoropentanoic acid (PFPeA) ---- ---- ---- ----µg/L0.022706-90-3

----Perfluorohexanoic acid (PFHxA) 0.0887 <0.0005 <0.0005 <0.0005µg/L0.0005307-24-4

0.33Perfluorohexanoic acid (PFHxA) ---- ---- ---- ----µg/L0.02307-24-4

----Perfluoroheptanoic acid (PFHpA) 0.0120 <0.0005 <0.0005 <0.0005µg/L0.0005375-85-9

0.47Perfluoroheptanoic acid (PFHpA) ---- ---- ---- ----µg/L0.02375-85-9

----Perfluorooctanoic acid (PFOA) 0.0046 <0.0005 <0.0005 <0.0005µg/L0.0005335-67-1

1.16Perfluorooctanoic acid (PFOA) ---- ---- ---- ----µg/L0.01335-67-1

----Perfluorononanoic acid (PFNA) <0.0005 <0.0005 <0.0005 <0.0005µg/L0.0005375-95-1

0.77Perfluorononanoic acid (PFNA) ---- ---- ---- ----µg/L0.02375-95-1


1.11Perfluorodecanoic acid (PFDA) ---- ---- ---- ----µg/L0.02335-76-2


(PFUnDA)

<0.0005 <0.0005 <0.0005 <0.0005µg/L0.00052058-94-8

0.16Perfluoroundecanoic acid

(PFUnDA)

---- ---- ---- ----µg/L0.022058-94-8


(PFDoDA)

<0.0005 <0.0005 <0.0005 <0.0005µg/L0.0005307-55-1

0.20Perfluorododecanoic acid

(PFDoDA)

---- ---- ---- ----µg/L0.02307-55-1


(PFTrDA)

<0.0005 <0.0005 <0.0005 <0.0005µg/L0.000572629-94-8

0.02Perfluorotridecanoic acid

(PFTrDA)

---- ---- ---- ----µg/L0.0272629-94-8

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Analytical Results

0874_QC5MW_18041

2_01

0874_QC4MW_18041

2_01

0874_QC3MW_18041

2_01

0874_MW241_S_1804

12

0874_MW049_S_1804

12


(Matrix: WATER)






(PFTeDA)

<0.0005 <0.0005 <0.0005 <0.0005µg/L0.0005376-06-7


(PFTeDA)

---- ---- ---- ----µg/L0.05376-06-7



(FOSA)

<0.0005 <0.0005 <0.0005 <0.0005µg/L0.0005754-91-6


(FOSA)

---- ---- ---- ----µg/L0.02754-91-6



<0.001 <0.001 <0.001 <0.001µg/L0.00131506-32-8



---- ---- ---- ----µg/L0.0531506-32-8



<0.001 <0.001 <0.001 <0.001µg/L0.0014151-50-2



---- ---- ---- ----µg/L0.054151-50-2



<0.001 <0.001 <0.001 <0.001µg/L0.00124448-09-7



---- ---- ---- ----µg/L0.0524448-09-7



<0.001 <0.001 <0.001 <0.001µg/L0.0011691-99-2



---- ---- ---- ----µg/L0.051691-99-2



(MeFOSAA)

<0.0005 <0.0005 <0.0005 <0.0005µg/L0.00052355-31-9



(MeFOSAA)

---- ---- ---- ----µg/L0.022355-31-9



(EtFOSAA)

<0.0005 <0.0005 <0.0005 <0.0005µg/L0.00052991-50-6

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Analytical Results

0874_QC5MW_18041

2_01

0874_QC4MW_18041

2_01

0874_QC3MW_18041

2_01

0874_MW241_S_1804

12

0874_MW049_S_1804

12


(Matrix: WATER)







(EtFOSAA)

---- ---- ---- ----µg/L0.022991-50-6



(4:2 FTS)

<0.001 <0.001 <0.001 <0.001µg/L0.001757124-72-4


(4:2 FTS)

---- ---- ---- ----µg/L0.05757124-72-4


(6:2 FTS)

<0.001 <0.001 <0.001 <0.001µg/L0.00127619-97-2


(6:2 FTS)

---- ---- ---- ----µg/L0.0527619-97-2


(8:2 FTS)

<0.001 <0.001 <0.001 <0.001µg/L0.00139108-34-4


(8:2 FTS)

---- ---- ---- ----µg/L0.0539108-34-4


(10:2 FTS)

<0.001 <0.001 <0.001 <0.001µg/L0.001120226-60-0


(10:2 FTS)

---- ---- ---- ----µg/L0.05120226-60-0

EP231P: PFAS Sums

---- 2.91 <0.0003 <0.0003 <0.0003µg/L0.0003----Sum of PFAS

6.48 ---- ---- ---- ----µg/L0.01----Sum of PFAS

----Sum of PFHxS and PFOS 2.30 <0.0003 <0.0003 <0.0003µg/L0.0003355-46-4/1763-23-

1


1

---- 2.85 <0.0003 <0.0003 <0.0003µg/L0.0003----Sum of PFAS (WA DER List)



---- 77.5 70.3 60.7 62.3%0.0005----13C4-PFOS

93.4 ---- ---- ---- ----%0.02----13C4-PFOS

---- 118 93.5 93.8 95.0%0.0005----13C8-PFOA

111 ---- ---- ---- ----%0.02----13C8-PFOA

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Analytical Results

----------------0874_QC5MW_18041

2_02


(Matrix: WATER)

----------------12-Apr-2018 00:00Client sampling date / time

--------------------------------ET1801011-021UnitLORCAS NumberCompound

Result ---- ---- ---- ----



(PFBS)

---- ---- ---- ----µg/L0.0005375-73-5


(PFPeS)

---- ---- ---- ----µg/L0.00052706-91-4


(PFHxS)

---- ---- ---- ----µg/L0.0005355-46-4


(PFHpS)

---- ---- ---- ----µg/L0.0005375-92-8


(PFOS)

---- ---- ---- ----µg/L0.00031763-23-1


(PFDS)

---- ---- ---- ----µg/L0.0005335-77-3










(PFUnDA)

---- ---- ---- ----µg/L0.00052058-94-8


(PFDoDA)

---- ---- ---- ----µg/L0.0005307-55-1


(PFTrDA)

---- ---- ---- ----µg/L0.000572629-94-8


(PFTeDA)

---- ---- ---- ----µg/L0.0005376-06-7



(FOSA)

---- ---- ---- ----µg/L0.0005754-91-6



---- ---- ---- ----µg/L0.00131506-32-8



---- ---- ---- ----µg/L0.0014151-50-2

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Analytical Results

----------------0874_QC5MW_18041

2_02


(Matrix: WATER)

----------------12-Apr-2018 00:00Client sampling date / time

--------------------------------ET1801011-021UnitLORCAS NumberCompound

Result ---- ---- ---- ----




---- ---- ---- ----µg/L0.00124448-09-7



---- ---- ---- ----µg/L0.0011691-99-2



(MeFOSAA)

---- ---- ---- ----µg/L0.00052355-31-9



(EtFOSAA)

---- ---- ---- ----µg/L0.00052991-50-6



(4:2 FTS)

---- ---- ---- ----µg/L0.001757124-72-4


(6:2 FTS)

---- ---- ---- ----µg/L0.00127619-97-2


(8:2 FTS)

---- ---- ---- ----µg/L0.00139108-34-4


(10:2 FTS)

---- ---- ---- ----µg/L0.001120226-60-0

EP231P: PFAS Sums

<0.0003 ---- ---- ---- ----µg/L0.0003----Sum of PFAS

<0.0003Sum of PFHxS and PFOS ---- ---- ---- ----µg/L0.0003355-46-4/1763-23-

1

<0.0003 ---- ---- ---- ----µg/L0.0003----Sum of PFAS (WA DER List)


70.5 ---- ---- ---- ----%0.0005----13C4-PFOS

104 ---- ---- ---- ----%0.0005----13C8-PFOA

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13C4-PFOS ---- 60 130

13C8-PFOA ---- 60 130

False

5 5.00True

Environmental




:Address MOBIL

C/O GPO BOX 2907








Site : ----

















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General Comments










Key :
































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ED045G: Chloride by Discrete Analyser (QC Lot: 1566284) - continued









ED093F: Sodium 7440-23-5 1 mg/L 224 224 0.00 0% - 20%




ED093F: Sodium 7440-23-5 1 mg/L 2170 2180 0.480 0% - 20%




(PFOS)



(PFBS)

375-73-5 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFPeS)

2706-91-4 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFHxS)

355-46-4 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFHpS)

375-92-8 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFDS)

335-77-3 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFOS)



(PFBS)

375-73-5 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFPeS)

2706-91-4 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFHxS)

355-46-4 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFHpS)

375-92-8 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFDS)

335-77-3 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


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EP231X: Perfluorooctane sulfonic acid (PFOS) 1763-23-1 0.01 µg/L 0.02 0.02 0.00 No LimitAnonymous ES1811130-008







EP231X: Perfluorooctane sulfonic acid (PFOS) 1763-23-1 0.01 µg/L 0.06 0.06 0.00 No Limit0874_MW437_S_180412 ET1801011-010























(PFTeDA)

376-06-7 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


EP231X-ST: Perfluoropentanoic acid (PFPeA) 2706-90-3 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit0874_QC4MW_180412_01 ET1801011-019


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EP231X-ST: Perfluoroheptanoic acid (PFHpA) 375-85-9 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit0874_QC4MW_180412_01 ET1801011-019








(PFTeDA)

376-06-7 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit




























EP231X: Perfluorohexanoic acid (PFHxA) 307-24-4 0.02 µg/L 0.03 0.03 0.00 No Limit




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EP231X: Perfluoroundecanoic acid (PFUnDA) 2058-94-8 0.02 µg/L <0.02 <0.02 0.00 No Limit0874_MW437_S_180412 ET1801011-010


















(FOSA)




2355-31-9 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit



2991-50-6 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit



31506-32-8 0.001 µg/L <0.001 <0.001 0.00 No Limit


(EtFOSA)

4151-50-2 0.001 µg/L <0.001 <0.001 0.00 No Limit



24448-09-7 0.001 µg/L <0.001 <0.001 0.00 No Limit



1691-99-2 0.001 µg/L <0.001 <0.001 0.00 No Limit


(FOSA)




2355-31-9 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit



2991-50-6 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit



31506-32-8 0.001 µg/L <0.001 <0.001 0.00 No Limit


(EtFOSA)

4151-50-2 0.001 µg/L <0.001 <0.001 0.00 No Limit

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1691-99-2 0.001 µg/L <0.001 <0.001 0.00 No Limit





2355-31-9 0.02 µg/L <0.02 <0.02 0.00 No Limit



2991-50-6 0.02 µg/L <0.02 <0.02 0.00 No Limit


(MeFOSA)

31506-32-8 0.05 µg/L <0.05 <0.05 0.00 No Limit


(EtFOSA)

4151-50-2 0.05 µg/L <0.05 <0.05 0.00 No Limit



24448-09-7 0.05 µg/L <0.05 <0.05 0.00 No Limit



1691-99-2 0.05 µg/L <0.05 <0.05 0.00 No Limit




2355-31-9 0.02 µg/L <0.02 <0.02 0.00 No Limit



2991-50-6 0.02 µg/L <0.02 <0.02 0.00 No Limit


(MeFOSA)

31506-32-8 0.05 µg/L <0.05 <0.05 0.00 No Limit


(EtFOSA)

4151-50-2 0.05 µg/L <0.05 <0.05 0.00 No Limit



24448-09-7 0.05 µg/L <0.05 <0.05 0.00 No Limit



1691-99-2 0.05 µg/L <0.05 <0.05 0.00 No Limit





2355-31-9 0.02 µg/L <0.02 <0.02 0.00 No Limit



2991-50-6 0.02 µg/L <0.02 <0.02 0.00 No Limit


(MeFOSA)

31506-32-8 0.05 µg/L <0.05 <0.05 0.00 No Limit


(EtFOSA)

4151-50-2 0.05 µg/L <0.05 <0.05 0.00 No Limit

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1691-99-2 0.05 µg/L <0.05 <0.05 0.00 No Limit




2355-31-9 0.02 µg/L <0.02 <0.02 0.00 No Limit



2991-50-6 0.02 µg/L <0.02 <0.02 0.00 No Limit


(MeFOSA)

31506-32-8 0.05 µg/L <0.05 <0.05 0.00 No Limit


(EtFOSA)

4151-50-2 0.05 µg/L <0.05 <0.05 0.00 No Limit



24448-09-7 0.05 µg/L <0.05 <0.05 0.00 No Limit



1691-99-2 0.05 µg/L <0.05 <0.05 0.00 No Limit



FTS)



FTS)

27619-97-2 0.001 µg/L <0.001 <0.001 0.00 No Limit


FTS)

39108-34-4 0.001 µg/L <0.001 <0.001 0.00 No Limit


(10:2 FTS)

120226-60-0 0.001 µg/L <0.001 <0.001 0.00 No Limit


FTS)



FTS)

27619-97-2 0.001 µg/L <0.001 <0.001 0.00 No Limit


FTS)

39108-34-4 0.001 µg/L <0.001 <0.001 0.00 No Limit


(10:2 FTS)

120226-60-0 0.001 µg/L <0.001 <0.001 0.00 No Limit



FTS)



FTS)

27619-97-2 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

39108-34-4 0.05 µg/L <0.05 <0.05 0.00 No Limit

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FTS)



FTS)



FTS)

27619-97-2 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

39108-34-4 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

120226-60-0 0.05 µg/L <0.05 <0.05 0.00 No Limit



FTS)



FTS)

27619-97-2 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

39108-34-4 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

120226-60-0 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)



FTS)

27619-97-2 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

39108-34-4 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

120226-60-0 0.05 µg/L <0.05 <0.05 0.00 No Limit



EP231X-ST: Sum of PFAS ---- 0.0003 µg/L <0.0003 <0.0003 0.00 No Limit0874_QC4MW_180412_01 ET1801011-019



EP231X: Sum of PFAS ---- 0.01 µg/L 0.02 0.02 0.00 No LimitAnonymous ES1811130-008




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Report










<1 10025 mg/L 12080



<1 10025 mg/L 12080



<1 96.410 mg/L 12080



<1 97.710 mg/L 12080


ED093F: Calcium 7440-70-2 1 mg/L <1 -------- --------


ED093F: Sodium 7440-23-5 1 mg/L <1 -------- --------















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Report











EP231X: Perfluorooctane sulfonic acid (PFOS) 1763-23-1 0.01 µg/L <0.01 99.80.5 µg/L 13070





























EP231X: Perfluorohexanoic acid (PFHxA) 307-24-4 0.02 µg/L <0.02 99.00.5 µg/L 13070



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Report














(MeFOSA)

31506-32-8 0.001 µg/L <0.001 41.40.025 µg/L 13040



(MeFOSE)

24448-09-7 0.001 µg/L <0.001 48.00.025 µg/L 13040


(EtFOSE)

1691-99-2 0.001 µg/L <0.001 58.90.025 µg/L 13040


acid (MeFOSAA)

2355-31-9 0.0005 µg/L <0.0005 53.20.01 µg/L 13040


acid (EtFOSAA)

2991-50-6 0.0005 µg/L <0.0005 51.40.01 µg/L 13040






(MeFOSE)

24448-09-7 0.05 µg/L <0.05 1031.25 µg/L 15070


(EtFOSE)

1691-99-2 0.05 µg/L <0.05 99.81.25 µg/L 15070


(MeFOSAA)

2355-31-9 0.02 µg/L <0.02 1250.5 µg/L 13070


(EtFOSAA)

2991-50-6 0.02 µg/L <0.02 1200.5 µg/L 13070






(MeFOSE)

24448-09-7 0.05 µg/L <0.05 1021.25 µg/L 15070


(EtFOSE)

1691-99-2 0.05 µg/L <0.05 1031.25 µg/L 15070

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Report






(MeFOSAA)

2355-31-9 0.02 µg/L <0.02 1210.5 µg/L 13070


(EtFOSAA)

2991-50-6 0.02 µg/L <0.02 1130.5 µg/L 13070



























Determined

20 mg/L 13070




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ED045G: Chloride by Discrete Analyser (QCLot: 1566285) - continued

0874_MW415_S_180412 ET1801011-008 16887-00-6ED045G: Chloride # Not

Determined

400 mg/L 13070









Anonymous ES1810944-002 375-73-5EP231X: Perfluorobutane sulfonic acid (PFBS) 1100.5 µg/L 13050







0874_MW437_S_180412 ET1801011-010 375-73-5EP231X: Perfluorobutane sulfonic acid (PFBS) 90.20.5 µg/L 13050



375-92-8EP231X: Perfluoroheptane sulfonic acid (PFHpS) 99.40.5 µg/L 13050

1763-23-1EP231X: Perfluorooctane sulfonic acid (PFOS) 97.00.5 µg/L 13050

335-77-3EP231X: Perfluorodecane sulfonic acid (PFDS) 98.80.5 µg/L 13050
















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Anonymous ES1810944-002 307-24-4EP231X: Perfluorohexanoic acid (PFHxA) 95.40.5 µg/L 13050










0874_MW437_S_180412 ET1801011-010 375-22-4EP231X: Perfluorobutanoic acid (PFBA) 1142.5 µg/L 13050














(MeFOSA)

31.50.025 µg/L 13030


(EtFOSA)

41.80.025 µg/L 13030



39.00.025 µg/L 13030



56.60.025 µg/L 13030



45.20.01 µg/L 13030


acid (EtFOSAA)

51.20.01 µg/L 13030


Anonymous ES1810944-002 754-91-6EP231X: Perfluorooctane sulfonamide (FOSA) 82.20.5 µg/L 13050


(MeFOSA)

1041.25 µg/L 15050

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Anonymous ES1810944-002 4151-50-2EP231X: N-Ethyl perfluorooctane sulfonamide (EtFOSA) 98.41.25 µg/L 15050


(MeFOSE)

1151.25 µg/L 15050


(EtFOSE)

98.81.25 µg/L 15050


acid (MeFOSAA)

1200.5 µg/L 13050


acid (EtFOSAA)

96.00.5 µg/L 13050




(MeFOSA)

1121.25 µg/L 15050



(MeFOSE)

1181.25 µg/L 15050


(EtFOSE)

1111.25 µg/L 15050


acid (MeFOSAA)

1180.5 µg/L 13050


acid (EtFOSAA)

75.20.5 µg/L 13050












0874_MW437_S_180412 ET1801011-010 757124-72-4EP231X: 4:2 Fluorotelomer sulfonic acid (4:2 FTS) 90.40.5 µg/L 13050




True

Environmental






Andi Carnall, JACK MCBAIN, MA:Sampler No. of samples received : 21






Summary of Outliers













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Matrix: WATER



ET1801011--008 14808-79-8Sulfate as SO4 -

Turbidimetric




----Not

Determined


ET1801011--008 16887-00-6Chloride0874_MW415_S_180412 MS recovery not determined,



----Not

Determined















0874_MW456_S_180412, 0874_MW455_S_180412,

0874_MW465_S_180412, 0874_MW463_S_180412,

0874_MW466_S_180412, 0874_MW422_S_180412,

0874_MW414_S_180412, 0874_MW415_S_180412,

0874_MW439_S_180412, 0874_MW437_S_180412,

0874_MW140_D_180412, 0874_MW460_S_180412,

0874_MW459_S_180412, 0874_MW457_S_180412,

0874_MW006_S_180412, 0874_MW049_S_180412,

0874_MW241_S_180412

26-Apr-2018---- 13-Apr-2018----12-Apr-2018 ---- ü

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0874_MW456_S_180412, 0874_MW455_S_180412,

0874_MW465_S_180412, 0874_MW463_S_180412,

0874_MW466_S_180412, 0874_MW422_S_180412,

0874_MW414_S_180412, 0874_MW415_S_180412,

0874_MW439_S_180412, 0874_MW437_S_180412,

0874_MW140_D_180412, 0874_MW460_S_180412,

0874_MW459_S_180412, 0874_MW457_S_180412,

0874_MW006_S_180412, 0874_MW049_S_180412,

0874_MW241_S_180412

10-May-2018---- 13-Apr-2018----12-Apr-2018 ---- ü



0874_MW456_S_180412, 0874_MW455_S_180412,

0874_MW465_S_180412, 0874_MW463_S_180412,

0874_MW466_S_180412, 0874_MW422_S_180412,

0874_MW414_S_180412, 0874_MW415_S_180412,

0874_MW439_S_180412, 0874_MW437_S_180412,

0874_MW140_D_180412, 0874_MW460_S_180412,

0874_MW459_S_180412, 0874_MW457_S_180412,

0874_MW006_S_180412, 0874_MW049_S_180412,

0874_MW241_S_180412

10-May-2018---- 13-Apr-2018----12-Apr-2018 ---- ü



0874_MW456_S_180412, 0874_MW455_S_180412,

0874_MW465_S_180412, 0874_MW463_S_180412,

0874_MW466_S_180412, 0874_MW422_S_180412,

0874_MW414_S_180412, 0874_MW415_S_180412,

0874_MW439_S_180412, 0874_MW437_S_180412,

0874_MW140_D_180412, 0874_MW460_S_180412,

0874_MW459_S_180412, 0874_MW457_S_180412,

0874_MW006_S_180412, 0874_MW049_S_180412,

0874_MW241_S_180412

19-Apr-2018---- 18-Apr-2018----12-Apr-2018 ---- ü

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0874_MW456_S_180412, 0874_MW455_S_180412,

0874_MW465_S_180412, 0874_MW466_S_180412,

0874_MW422_S_180412, 0874_MW414_S_180412,

0874_MW415_S_180412, 0874_MW439_S_180412,

0874_MW437_S_180412, 0874_MW459_S_180412,

0874_MW457_S_180412, 0874_MW006_S_180412,

0874_MW049_S_180412

09-Oct-2018---- 23-Apr-2018----12-Apr-2018 ---- ü


0874_MW463_S_180412, 0874_MW140_D_180412,

0874_MW460_S_180412, 0874_MW241_S_180412,

0874_QC3MW_180412_01, 0874_QC4MW_180412_01,

0874_QC5MW_180412_01, 0874_QC5MW_180412_02




0874_MW456_S_180412, 0874_MW455_S_180412,

0874_MW465_S_180412, 0874_MW466_S_180412,

0874_MW422_S_180412, 0874_MW414_S_180412,

0874_MW415_S_180412, 0874_MW439_S_180412,

0874_MW437_S_180412, 0874_MW459_S_180412,

0874_MW457_S_180412, 0874_MW006_S_180412,

0874_MW049_S_180412

09-Oct-2018---- 23-Apr-2018----12-Apr-2018 ---- ü


0874_MW463_S_180412, 0874_MW140_D_180412,

0874_MW460_S_180412, 0874_MW241_S_180412,

0874_QC3MW_180412_01, 0874_QC4MW_180412_01,

0874_QC5MW_180412_01, 0874_QC5MW_180412_02




0874_MW456_S_180412, 0874_MW455_S_180412,

0874_MW465_S_180412, 0874_MW466_S_180412,

0874_MW422_S_180412, 0874_MW414_S_180412,

0874_MW415_S_180412, 0874_MW439_S_180412,

0874_MW437_S_180412, 0874_MW459_S_180412,

0874_MW457_S_180412, 0874_MW006_S_180412,

0874_MW049_S_180412

09-Oct-2018---- 23-Apr-2018----12-Apr-2018 ---- ü


0874_MW463_S_180412, 0874_MW140_D_180412,

0874_MW460_S_180412, 0874_MW241_S_180412,

0874_QC3MW_180412_01, 0874_QC4MW_180412_01,

0874_QC5MW_180412_01, 0874_QC5MW_180412_02


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0874_MW456_S_180412, 0874_MW455_S_180412,

0874_MW465_S_180412, 0874_MW466_S_180412,

0874_MW422_S_180412, 0874_MW414_S_180412,

0874_MW415_S_180412, 0874_MW439_S_180412,

0874_MW437_S_180412, 0874_MW459_S_180412,

0874_MW457_S_180412, 0874_MW006_S_180412,

0874_MW049_S_180412

09-Oct-2018---- 23-Apr-2018----12-Apr-2018 ---- ü


0874_MW463_S_180412, 0874_MW140_D_180412,

0874_MW460_S_180412, 0874_MW241_S_180412,

0874_QC3MW_180412_01, 0874_QC4MW_180412_01,

0874_QC5MW_180412_01, 0874_QC5MW_180412_02


EP231P: PFAS Sums


0874_MW456_S_180412, 0874_MW455_S_180412,

0874_MW465_S_180412, 0874_MW466_S_180412,

0874_MW422_S_180412, 0874_MW414_S_180412,

0874_MW415_S_180412, 0874_MW439_S_180412,

0874_MW437_S_180412, 0874_MW459_S_180412,

0874_MW457_S_180412, 0874_MW006_S_180412,

0874_MW049_S_180412

09-Oct-2018---- 23-Apr-2018----12-Apr-2018 ---- ü


0874_MW463_S_180412, 0874_MW140_D_180412,

0874_MW460_S_180412, 0874_MW241_S_180412,

0874_QC3MW_180412_01, 0874_QC4MW_180412_01,

0874_QC5MW_180412_01, 0874_QC5MW_180412_02


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Method Blanks (MB)






Matrix Spikes (MS)





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ET1801011









Schedule B(3)







Discrete Analyser

ED041G WATER











Schedule B(3)



DA

EN055 - PG WATER










(PFAS) by LCMSMS

EP231X WATER










(PFAS) by LCMSMS

EP231X-ST WATER

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Environmental





C/O GPO BOX 2907



QLD AUSTRALIA 4814






V4)


Site : ----




Date

24-Apr-2018




General Comments




















ET1801011-018 : [ 12-Apr-2018 ] : 0874_QC3MW_180412_01

ET1801011-019 : [ 12-Apr-2018 ] : 0874_QC4MW_180412_01

ET1801011-020 : [ 12-Apr-2018 ] : 0874_QC5MW_180412_01

ET1801011-021 : [ 12-Apr-2018 ] : 0874_QC5MW_180412_02











component

WA

TE

R -

EP

23

1X

PF

AS

- F

ull

Su

ite (

28 a

na

lyte

s)

WA

TE

R -

EP

23

1X

-ST

PF

AS

- S

up

er

Tra

ce W

ate

rs L

ong

Su

ite (

28

WA

TE

R -

NT

-01

& 0

2

Ca

, M

g, N

a, K

, C

l, S

O4

, A

lka

linity

ET1801011-001 12-Apr-2018 00:00 0874_MW456_S_180412 ü ü

ET1801011-002 12-Apr-2018 00:00 0874_MW455_S_180412 ü ü

ET1801011-003 12-Apr-2018 00:00 0874_MW465_S_180412 ü ü

ET1801011-004 12-Apr-2018 00:00 0874_MW463_S_180412 ü ü

ET1801011-005 12-Apr-2018 00:00 0874_MW466_S_180412 ü ü

ET1801011-006 12-Apr-2018 00:00 0874_MW422_S_180412 ü ü

ET1801011-007 12-Apr-2018 00:00 0874_MW414_S_180412 ü ü

ET1801011-008 12-Apr-2018 00:00 0874_MW415_S_180412 ü ü

ET1801011-009 12-Apr-2018 00:00 0874_MW439_S_180412 ü ü

ET1801011-010 12-Apr-2018 00:00 0874_MW437_S_180412 ü ü

ET1801011-011 12-Apr-2018 00:00 0874_MW140_D_180412 ü ü

ET1801011-012 12-Apr-2018 00:00 0874_MW460_S_180412 ü ü

ET1801011-013 12-Apr-2018 00:00 0874_MW459_S_180412 ü ü

ET1801011-014 12-Apr-2018 00:00 0874_MW457_S_180412 ü ü

ET1801011-015 12-Apr-2018 00:00 0874_MW006_S_180412 ü ü

ET1801011-016 12-Apr-2018 00:00 0874_MW049_S_180412 ü ü

ET1801011-017 12-Apr-2018 00:00 0874_MW241_S_180412 ü ü

ET1801011-018 12-Apr-2018 00:00 0874_QC3MW_180412_01 ü

ET1801011-019 12-Apr-2018 00:00 0874_QC4MW_180412_01 ü

ET1801011-020 12-Apr-2018 00:00 0874_QC5MW_180412_01 ü

ET1801011-021 12-Apr-2018 00:00 0874_QC5MW_180412_02 ü

Matrix: WATER


ID

Client sampling

date / time







ACCOUNTS PAYABLE


AU ACCOUNTS PAYABLE


DAVID HARRIS








DERP LABREPORTS


PHIL SCHULZ









RESULTS RESULTS








0 0.00 True

Environmental





C/O GPO BOX 2907







Sampler : JACK MCBAIN

Site : ----






l General Comments









Diana Mesa 2IC Organic Chemist Brisbane Organics, Stafford, QLD






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General Comments







purposes.







Key :

TDS by method EA-015 may bias high due to the presence of fine particulate matter, which may pass through the prescribed GF/C paper.l

EA016, EK058G, EA045, EA005-P, EA010-P, EA015H, EA025H, ED037-P, ED041G, ED045G, EK040P, EK055G, EK057G, EK059G, EK071G conducted by ALS Townsville, NATA accreditation no. 825, (Site no.

23313)

l


EP231X: Particular samples required dilution due to sample matrix . LOR values have been adjusted accordingly.l

EA016: Calculated TDS is determined from Electrical conductivity using a conversion factor of 0.65.l

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Analytical Results

0874_MW262_S_1804

13

0874_MWRB2_S_180

413

0874_MW226_S_1804

13

0874_MW227_S_1804

13

0874_MW228_S_1804

13


(Matrix: WATER)












5070Chloride 3070 3920 41 41600mg/L116887-00-6


264Calcium 188 186 56 774mg/L17440-70-2

347Magnesium 161 207 7 5190mg/L17439-95-4

2390Sodium 1560 2090 34 26200mg/L17440-23-5

3Potassium 5 3 7 608mg/L17440-09-7


149 95.0 122 4.84 1420meq/L0.01----Total Anions

146 90.6 117 5.03 1620meq/L0.01----Total Cations

1.26 2.38 1.98 1.88 6.57%0.01----Ionic Balance



(PFBS)

0.0622 0.0576 0.0138 0.0028µg/L0.0005375-73-5


(PFPeS)

0.0185 0.0053 0.0016 0.0014µg/L0.00052706-91-4


(PFHxS)

0.160 0.0710 0.0267 0.0062µg/L0.0005355-46-4


(PFHpS)

0.0008 <0.0005 <0.0005 <0.0005µg/L0.0005375-92-8


(PFOS)

0.0239 0.0201 0.0309 <0.0003µg/L0.00031763-23-1


(PFDS)

<0.0005 <0.0005 <0.0005 <0.0005µg/L0.0005335-77-3


<0.002Perfluorobutanoic acid (PFBA) 0.003 0.002 <0.002 <0.002µg/L0.002375-22-4

0.0019Perfluoropentanoic acid (PFPeA) 0.0024 0.0023 <0.0005 0.0050µg/L0.00052706-90-3

0.0030Perfluorohexanoic acid (PFHxA) 0.0039 0.0026 0.0006 0.0058µg/L0.0005307-24-4

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Analytical Results

0874_MW262_S_1804

13

0874_MWRB2_S_180

413

0874_MW226_S_1804

13

0874_MW227_S_1804

13

0874_MW228_S_1804

13


(Matrix: WATER)





0.0008Perfluoroheptanoic acid (PFHpA) 0.0008 0.0008 <0.0005 <0.0005µg/L0.0005375-85-9

0.0014Perfluorooctanoic acid (PFOA) 0.0016 0.0013 0.0006 0.0005µg/L0.0005335-67-1

<0.0005Perfluorononanoic acid (PFNA) <0.0005 <0.0005 <0.0005 <0.0005µg/L0.0005375-95-1



(PFUnDA)

<0.0005 <0.0005 <0.0005 <0.0005µg/L0.00052058-94-8


(PFDoDA)

<0.0005 <0.0005 <0.0005 <0.0005µg/L0.0005307-55-1


(PFTrDA)

<0.0005 <0.0005 <0.0005 <0.0005µg/L0.000572629-94-8


(PFTeDA)

<0.0005 <0.0005 <0.0005 <0.0005µg/L0.0005376-06-7



(FOSA)

<0.0005 <0.0005 <0.0005 <0.0005µg/L0.0005754-91-6



<0.001 <0.001 <0.001 <0.001µg/L0.00131506-32-8



<0.001 <0.001 <0.001 <0.001µg/L0.0014151-50-2



<0.001 <0.001 <0.001 <0.001µg/L0.00124448-09-7



<0.001 <0.001 <0.001 <0.001µg/L0.0011691-99-2



(MeFOSAA)

<0.0005 <0.0005 <0.0005 <0.0005µg/L0.00052355-31-9



(EtFOSAA)

<0.0005 <0.0005 <0.0005 <0.0005µg/L0.00052991-50-6



(4:2 FTS)

<0.001 <0.001 <0.001 <0.001µg/L0.001757124-72-4


(6:2 FTS)

<0.001 <0.001 <0.001 <0.001µg/L0.00127619-97-2


(8:2 FTS)

<0.001 <0.001 <0.001 <0.001µg/L0.00139108-34-4

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Analytical Results

0874_MW262_S_1804

13

0874_MWRB2_S_180

413

0874_MW226_S_1804

13

0874_MW227_S_1804

13

0874_MW228_S_1804

13


(Matrix: WATER)






(10:2 FTS)

<0.001 <0.001 <0.001 <0.001µg/L0.001120226-60-0

EP231P: PFAS Sums

0.174 0.277 0.163 0.0742 0.0217µg/L0.0003----Sum of PFAS


1



93.5 100 85.7 84.4 67.5%0.0005----13C4-PFOS

108 115 113 119 112%0.0005----13C8-PFOA

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Analytical Results

0874_MW207_S_1804

13

0874_MW205_S_1804

13

0874_MW204_S_1804

13

0874_MW264_S_1804

13

0874_MW254_S_1804

13


(Matrix: WATER)







316Bicarbonate Alkalinity as CaCO3 777 67 142 <1mg/L171-52-3

316 777 67 142 <1mg/L1----Total Alkalinity as CaCO3




22000Chloride 4000 13 4850 8600mg/L116887-00-6


417Calcium 485 40 611 886mg/L17440-70-2

1710Magnesium 179 3 629 838mg/L17439-95-4

13500Sodium 3490 15 2960 4990mg/L17440-23-5

404Potassium 19 1 81 97mg/L17440-09-7


687 196 2.75 218 347meq/L0.01----Total Anions

759 191 2.92 213 333meq/L0.01----Total Cations

4.98 1.24 ---- 1.03 2.15%0.01----Ionic Balance



(PFBS)

0.351 ---- ---- ----µg/L0.0005375-73-5


(PFBS)

---- <0.02 <0.05 <0.05µg/L0.02375-73-5


(PFPeS)

0.222 ---- ---- ----µg/L0.00052706-91-4


(PFPeS)

---- <0.02 <0.05 <0.05µg/L0.022706-91-4


(PFHxS)

0.904 ---- ---- ----µg/L0.0005355-46-4


(PFHxS)

---- <0.02 <0.05 <0.05µg/L0.02355-46-4


(PFHpS)

0.0132 ---- ---- ----µg/L0.0005375-92-8


(PFHpS)

---- <0.02 <0.05 <0.05µg/L0.02375-92-8

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Analytical Results

0874_MW207_S_1804

13

0874_MW205_S_1804

13

0874_MW204_S_1804

13

0874_MW264_S_1804

13

0874_MW254_S_1804

13


(Matrix: WATER)






(PFOS)

0.0438 ---- ---- ----µg/L0.00031763-23-1


(PFDS)

<0.0005 ---- ---- ----µg/L0.0005335-77-3


(PFOS)

---- <0.01 <0.05 <0.05µg/L0.011763-23-1


(PFDS)

---- <0.02 <0.05 <0.05µg/L0.02335-77-3


<0.002Perfluorobutanoic acid (PFBA) 0.030 ---- ---- ----µg/L0.002375-22-4


<0.0005Perfluoropentanoic acid (PFPeA) 0.103 ---- ---- ----µg/L0.00052706-90-3

----Perfluoropentanoic acid (PFPeA) ---- <0.02 <0.05 <0.05µg/L0.022706-90-3

<0.0005Perfluorohexanoic acid (PFHxA) 0.0760 ---- ---- ----µg/L0.0005307-24-4

----Perfluorohexanoic acid (PFHxA) ---- <0.02 <0.05 <0.05µg/L0.02307-24-4

<0.0005Perfluoroheptanoic acid (PFHpA) 0.0310 ---- ---- ----µg/L0.0005375-85-9

----Perfluoroheptanoic acid (PFHpA) ---- <0.02 <0.05 <0.05µg/L0.02375-85-9


----Perfluorooctanoic acid (PFOA) ---- <0.01 <0.05 <0.05µg/L0.01335-67-1






(PFUnDA)

<0.0005 ---- ---- ----µg/L0.00052058-94-8


(PFUnDA)

---- <0.02 <0.05 <0.05µg/L0.022058-94-8


(PFDoDA)

<0.0005 ---- ---- ----µg/L0.0005307-55-1


(PFDoDA)

---- <0.02 <0.05 <0.05µg/L0.02307-55-1


(PFTrDA)

<0.0005 ---- ---- ----µg/L0.000572629-94-8


(PFTrDA)

---- <0.02 <0.05 <0.05µg/L0.0272629-94-8

8 of 22:Page

Work Order :

:Client

ET1801024



Analytical Results

0874_MW207_S_1804

13

0874_MW205_S_1804

13

0874_MW204_S_1804

13

0874_MW264_S_1804

13

0874_MW254_S_1804

13


(Matrix: WATER)






(PFTeDA)

<0.0005 ---- ---- ----µg/L0.0005376-06-7


(PFTeDA)

---- <0.05 <0.12 <0.12µg/L0.05376-06-7



(FOSA)

<0.0005 ---- ---- ----µg/L0.0005754-91-6


(FOSA)

---- <0.02 <0.05 <0.05µg/L0.02754-91-6



<0.001 ---- ---- ----µg/L0.00131506-32-8



---- <0.05 <0.12 <0.12µg/L0.0531506-32-8



<0.001 ---- ---- ----µg/L0.0014151-50-2



---- <0.05 <0.12 <0.12µg/L0.054151-50-2



<0.001 ---- ---- ----µg/L0.00124448-09-7



---- <0.05 <0.12 <0.12µg/L0.0524448-09-7



<0.001 ---- ---- ----µg/L0.0011691-99-2



---- <0.05 <0.12 <0.12µg/L0.051691-99-2



(MeFOSAA)

<0.0005 ---- ---- ----µg/L0.00052355-31-9



(MeFOSAA)

---- <0.02 <0.05 <0.05µg/L0.022355-31-9



(EtFOSAA)

<0.0005 ---- ---- ----µg/L0.00052991-50-6

9 of 22:Page

Work Order :

:Client

ET1801024



Analytical Results

0874_MW207_S_1804

13

0874_MW205_S_1804

13

0874_MW204_S_1804

13

0874_MW264_S_1804

13

0874_MW254_S_1804

13


(Matrix: WATER)







(EtFOSAA)

---- <0.02 <0.05 <0.05µg/L0.022991-50-6



(4:2 FTS)

<0.001 ---- ---- ----µg/L0.001757124-72-4


(4:2 FTS)

---- <0.05 <0.05 <0.05µg/L0.05757124-72-4


(6:2 FTS)

<0.001 ---- ---- ----µg/L0.00127619-97-2


(6:2 FTS)

---- <0.05 <0.05 <0.05µg/L0.0527619-97-2


(8:2 FTS)

<0.001 ---- ---- ----µg/L0.00139108-34-4


(8:2 FTS)

---- <0.05 <0.05 <0.05µg/L0.0539108-34-4


(10:2 FTS)

<0.001 ---- ---- ----µg/L0.001120226-60-0


(10:2 FTS)

---- <0.05 <0.05 <0.05µg/L0.05120226-60-0

EP231P: PFAS Sums

0.0095 1.79 ---- ---- ----µg/L0.0003----Sum of PFAS

---- ---- <0.01 <0.05 <0.05µg/L0.01----Sum of PFAS


1

----Sum of PFHxS and PFOS ---- <0.01 <0.05 <0.05µg/L0.01355-46-4/1763-23-

1


---- ---- <0.01 <0.05 <0.05µg/L0.01----Sum of PFAS (WA DER List)


81.2 72.3 ---- ---- ----%0.0005----13C4-PFOS

---- ---- 98.9 88.6 88.8%0.02----13C4-PFOS

113 120 ---- ---- ----%0.0005----13C8-PFOA

---- ---- 108 101 106%0.02----13C8-PFOA

10 of 22:Page

Work Order :

:Client

ET1801024



Analytical Results

0874_MWRB5_S_180

413

0874_MWRB3_S_180

413

0874_MW233_S_1804

13

0874_MW252_S_1804

13

0874_MW253_S_1804

13


(Matrix: WATER)





---- ---- ---- ---- 6.21pH Unit0.01----pH Value


----^ ---- ---- ---- 0.97-0.01----Sodium Adsorption Ratio


---- ---- ---- ---- 130µS/cm1----Electrical Conductivity @ 25°C


---- ---- ---- ---- 164mg/L10----Total Dissolved Solids @180°C

EA016: Calculated TDS (from Electrical Conductivity)

---- ---- ---- ---- 84mg/L1----Total Dissolved Solids (Calc.)


---- ---- ---- ---- 48mg/L5----Suspended Solids (SS)

EA045: Turbidity

---- ---- ---- ---- 43.4NTU0.1----Turbidity


---- ---- ---- ---- 34mg/L1----Total Hardness as CaCO3









3410Chloride 114 8 4 8mg/L116887-00-6


145Calcium 112 34 4 12mg/L17440-70-2

237Magnesium 20 4 <1 1mg/L17439-95-4

1970Sodium 106 12 8 13mg/L17440-23-5

61Potassium 5 1 3 2mg/L17440-09-7


----Aluminium ---- ---- ---- 0.02mg/L0.017429-90-5

----Manganese ---- ---- ---- 0.052mg/L0.0017439-96-5

----Iron ---- ---- ---- <0.05mg/L0.057439-89-6

11 of 22:Page

Work Order :

:Client

ET1801024



Analytical Results

0874_MWRB5_S_180

413

0874_MWRB3_S_180

413

0874_MW233_S_1804

13

0874_MW252_S_1804

13

0874_MW253_S_1804

13


(Matrix: WATER)





---- ---- ---- ---- <0.05mg/L0.05----Ferrous Iron


----Fluoride ---- ---- ---- <0.1mg/L0.116984-48-8


----Ammonia as N ---- ---- ---- 0.03mg/L0.017664-41-7


----Nitrite as N ---- ---- ---- <0.01mg/L0.0114797-65-0

EK058G: Nitrate as N by Discrete Analyser

----Nitrate as N ---- ---- ---- 2.68mg/L0.0114797-55-8


---- ---- ---- ---- 2.68mg/L0.01----Nitrite + Nitrate as N


---- ---- ---- ---- 2.1mg/L0.1----Total Kjeldahl Nitrogen as N

EK062G: Total Nitrogen as N (TKN + NOx) by Discrete Analyser

----^ ---- ---- ---- 4.8mg/L0.1----Total Nitrogen as N


---- ---- ---- ---- 7.36mg/L0.01----Total Phosphorus as P


----Reactive Phosphorus as P ---- ---- ---- 2.86mg/L0.0114265-44-2


---- ---- ---- ---- 1.19meq/L0.01----Total Anions

118 11.9 2.52 0.58 ----meq/L0.01----Total Anions

114 12.0 2.57 0.62 1.30meq/L0.01----Total Cations

1.78 0.37 ---- ---- ----%0.01----Ionic Balance


---- ---- ---- ---- 14mg/L1----Total Organic Carbon


---- ---- ---- ---- 58mg/L10----Chemical Oxygen Demand


---- ---- ---- ---- <2mg/L2----Biochemical Oxygen Demand



(PFBS)

0.0042 ---- 0.0063 ----µg/L0.0005375-73-5

12 of 22:Page

Work Order :

:Client

ET1801024



Analytical Results

0874_MWRB5_S_180

413

0874_MWRB3_S_180

413

0874_MW233_S_1804

13

0874_MW252_S_1804

13

0874_MW253_S_1804

13


(Matrix: WATER)






(PFBS)

---- <0.02 ---- <0.02µg/L0.02375-73-5


(PFPeS)

<0.0005 ---- <0.0005 ----µg/L0.00052706-91-4


(PFPeS)

---- <0.02 ---- <0.02µg/L0.022706-91-4


(PFHxS)

0.0051 ---- 0.0067 ----µg/L0.0005355-46-4


(PFHxS)

---- <0.02 ---- 0.07µg/L0.02355-46-4


(PFHpS)

<0.0005 ---- <0.0005 ----µg/L0.0005375-92-8


(PFHpS)

---- <0.02 ---- <0.02µg/L0.02375-92-8


(PFOS)

0.0063 ---- 0.0244 ----µg/L0.00031763-23-1


(PFDS)

<0.0005 ---- <0.0005 ----µg/L0.0005335-77-3


(PFOS)

---- 0.01 ---- 0.07µg/L0.011763-23-1


(PFDS)

---- <0.02 ---- <0.02µg/L0.02335-77-3


<0.002Perfluorobutanoic acid (PFBA) <0.002 ---- <0.002 ----µg/L0.002375-22-4

----Perfluorobutanoic acid (PFBA) ---- <0.1 ---- <0.1µg/L0.1375-22-4

<0.0005Perfluoropentanoic acid (PFPeA) <0.0005 ---- <0.0005 ----µg/L0.00052706-90-3

----Perfluoropentanoic acid (PFPeA) ---- <0.02 ---- <0.02µg/L0.022706-90-3

<0.0005Perfluorohexanoic acid (PFHxA) <0.0005 ---- <0.0005 ----µg/L0.0005307-24-4

----Perfluorohexanoic acid (PFHxA) ---- <0.02 ---- 0.02µg/L0.02307-24-4

<0.0005Perfluoroheptanoic acid (PFHpA) <0.0005 ---- 0.0005 ----µg/L0.0005375-85-9

----Perfluoroheptanoic acid (PFHpA) ---- <0.02 ---- <0.02µg/L0.02375-85-9

<0.0005Perfluorooctanoic acid (PFOA) <0.0005 ---- 0.0021 ----µg/L0.0005335-67-1

----Perfluorooctanoic acid (PFOA) ---- <0.01 ---- <0.01µg/L0.01335-67-1

<0.0005Perfluorononanoic acid (PFNA) <0.0005 ---- 0.0016 ----µg/L0.0005375-95-1

----Perfluorononanoic acid (PFNA) ---- <0.02 ---- <0.02µg/L0.02375-95-1

13 of 22:Page

Work Order :

:Client

ET1801024



Analytical Results

0874_MWRB5_S_180

413

0874_MWRB3_S_180

413

0874_MW233_S_1804

13

0874_MW252_S_1804

13

0874_MW253_S_1804

13


(Matrix: WATER)





<0.0005Perfluorodecanoic acid (PFDA) <0.0005 ---- <0.0005 ----µg/L0.0005335-76-2

----Perfluorodecanoic acid (PFDA) ---- <0.02 ---- <0.02µg/L0.02335-76-2


(PFUnDA)

<0.0005 ---- <0.0005 ----µg/L0.00052058-94-8


(PFUnDA)

---- <0.02 ---- <0.02µg/L0.022058-94-8


(PFDoDA)

<0.0005 ---- <0.0005 ----µg/L0.0005307-55-1


(PFDoDA)

---- <0.02 ---- <0.02µg/L0.02307-55-1


(PFTrDA)

<0.0005 ---- <0.0005 ----µg/L0.000572629-94-8


(PFTrDA)

---- <0.02 ---- <0.02µg/L0.0272629-94-8


(PFTeDA)

<0.0005 ---- <0.0005 ----µg/L0.0005376-06-7


(PFTeDA)

---- <0.05 ---- <0.05µg/L0.05376-06-7



(FOSA)

<0.0005 ---- <0.0005 ----µg/L0.0005754-91-6


(FOSA)

---- <0.02 ---- <0.02µg/L0.02754-91-6



<0.001 ---- <0.001 ----µg/L0.00131506-32-8



---- <0.05 ---- <0.05µg/L0.0531506-32-8



<0.001 ---- <0.001 ----µg/L0.0014151-50-2



---- <0.05 ---- <0.05µg/L0.054151-50-2



<0.001 ---- <0.001 ----µg/L0.00124448-09-7



---- <0.05 ---- <0.05µg/L0.0524448-09-7

14 of 22:Page

Work Order :

:Client

ET1801024



Analytical Results

0874_MWRB5_S_180

413

0874_MWRB3_S_180

413

0874_MW233_S_1804

13

0874_MW252_S_1804

13

0874_MW253_S_1804

13


(Matrix: WATER)







<0.001 ---- <0.001 ----µg/L0.0011691-99-2



---- <0.05 ---- <0.05µg/L0.051691-99-2



(MeFOSAA)

<0.0005 ---- <0.0005 ----µg/L0.00052355-31-9



(MeFOSAA)

---- <0.02 ---- <0.02µg/L0.022355-31-9



(EtFOSAA)

<0.0005 ---- <0.0005 ----µg/L0.00052991-50-6



(EtFOSAA)

---- <0.02 ---- <0.02µg/L0.022991-50-6



(4:2 FTS)

<0.001 ---- <0.001 ----µg/L0.001757124-72-4


(4:2 FTS)

---- <0.05 ---- <0.05µg/L0.05757124-72-4


(6:2 FTS)

<0.001 ---- <0.001 ----µg/L0.00127619-97-2


(6:2 FTS)

---- <0.05 ---- <0.05µg/L0.0527619-97-2


(8:2 FTS)

<0.001 ---- <0.001 ----µg/L0.00139108-34-4


(8:2 FTS)

---- <0.05 ---- <0.05µg/L0.0539108-34-4


(10:2 FTS)

<0.001 ---- <0.001 ----µg/L0.001120226-60-0


(10:2 FTS)

---- <0.05 ---- <0.05µg/L0.05120226-60-0

EP231P: PFAS Sums

0.0078 0.0156 ---- 0.0416 ----µg/L0.0003----Sum of PFAS

---- ---- 0.01 ---- 0.16µg/L0.01----Sum of PFAS

15 of 22:Page

Work Order :

:Client

ET1801024



Analytical Results

0874_MWRB5_S_180

413

0874_MWRB3_S_180

413

0874_MW233_S_1804

13

0874_MW252_S_1804

13

0874_MW253_S_1804

13


(Matrix: WATER)




EP231P: PFAS Sums - Continued

0.0055Sum of PFHxS and PFOS 0.0114 ---- 0.0311 ----µg/L0.0003355-46-4/1763-23-

1

----Sum of PFHxS and PFOS ---- 0.01 ---- 0.14µg/L0.01355-46-4/1763-23-

1

0.0078 0.0156 ---- 0.0400 ----µg/L0.0003----Sum of PFAS (WA DER List)

---- ---- 0.01 ---- 0.16µg/L0.01----Sum of PFAS (WA DER List)


79.5 88.0 ---- 76.1 ----%0.0005----13C4-PFOS

---- ---- 90.1 ---- 95.8%0.02----13C4-PFOS

113 113 ---- 106 ----%0.0005----13C8-PFOA

---- ---- 110 ---- 118%0.02----13C8-PFOA

16 of 22:Page

Work Order :

:Client

ET1801024



Analytical Results

0874_QC3MW_18041

3

0874_QC1MW_18041

3_03

0874_QC1MW_18041

3_02

0874_QC1MW_18041

3_01

0874_MWRB5_S_180

413_F


(Matrix: WATER)





----Hydroxide Alkalinity as CaCO3 <1 <1 <1 <1mg/L1DMO-210-001

----Carbonate Alkalinity as CaCO3 <1 <1 <1 <1mg/L13812-32-6

----Bicarbonate Alkalinity as CaCO3 71 123 414 3mg/L171-52-3

---- 71 123 414 3mg/L1----Total Alkalinity as CaCO3


----Sulfate as SO4 - Turbidimetric 51 4060 643 <1mg/L114808-79-8


----Chloride 12 4890 3410 <1mg/L116887-00-6


----Calcium 39 634 143 <1mg/L17440-70-2

----Magnesium 3 652 235 <1mg/L17439-95-4

----Sodium 14 2990 1990 <1mg/L17440-23-5

----Potassium 1 83 60 <1mg/L17440-09-7


---- 2.82 225 118 0.06meq/L0.01----Total Anions

---- 2.83 217 114 <0.01meq/L0.01----Total Cations

---- ---- 1.68 1.41 ----%0.01----Ionic Balance



(PFBS)

---- ---- 0.0023 <0.0005µg/L0.0005375-73-5


(PFBS)

<0.02 <0.05 ---- ----µg/L0.02375-73-5


(PFPeS)

---- ---- <0.0005 <0.0005µg/L0.00052706-91-4


(PFPeS)

<0.02 <0.05 ---- ----µg/L0.022706-91-4


(PFHxS)

---- ---- 0.0038 <0.0005µg/L0.0005355-46-4


(PFHxS)

<0.02 <0.05 ---- ----µg/L0.02355-46-4


(PFHpS)

---- ---- <0.0005 <0.0005µg/L0.0005375-92-8


(PFHpS)

<0.02 <0.05 ---- ----µg/L0.02375-92-8

17 of 22:Page

Work Order :

:Client

ET1801024



Analytical Results

0874_QC3MW_18041

3

0874_QC1MW_18041

3_03

0874_QC1MW_18041

3_02

0874_QC1MW_18041

3_01

0874_MWRB5_S_180

413_F


(Matrix: WATER)






(PFOS)

---- ---- 0.0017 <0.0003µg/L0.00031763-23-1


(PFDS)

---- ---- <0.0005 <0.0005µg/L0.0005335-77-3


(PFOS)

<0.01 <0.05 ---- ----µg/L0.011763-23-1


(PFDS)

<0.02 <0.05 ---- ----µg/L0.02335-77-3


----Perfluorobutanoic acid (PFBA) ---- ---- <0.002 <0.002µg/L0.002375-22-4


----Perfluoropentanoic acid (PFPeA) ---- ---- <0.0005 <0.0005µg/L0.00052706-90-3


----Perfluorohexanoic acid (PFHxA) ---- ---- <0.0005 <0.0005µg/L0.0005307-24-4

0.03Perfluorohexanoic acid (PFHxA) <0.02 <0.05 ---- ----µg/L0.02307-24-4

----Perfluoroheptanoic acid (PFHpA) ---- ---- <0.0005 <0.0005µg/L0.0005375-85-9


----Perfluorooctanoic acid (PFOA) ---- ---- <0.0005 <0.0005µg/L0.0005335-67-1


----Perfluorononanoic acid (PFNA) ---- ---- <0.0005 <0.0005µg/L0.0005375-95-1


----Perfluorodecanoic acid (PFDA) ---- ---- <0.0005 <0.0005µg/L0.0005335-76-2



(PFUnDA)

---- ---- <0.0005 <0.0005µg/L0.00052058-94-8


(PFUnDA)

<0.02 <0.05 ---- ----µg/L0.022058-94-8


(PFDoDA)

---- ---- <0.0005 <0.0005µg/L0.0005307-55-1


(PFDoDA)

<0.02 <0.05 ---- ----µg/L0.02307-55-1


(PFTrDA)

---- ---- <0.0005 <0.0005µg/L0.000572629-94-8


(PFTrDA)

<0.02 <0.05 ---- ----µg/L0.0272629-94-8

18 of 22:Page

Work Order :

:Client

ET1801024



Analytical Results

0874_QC3MW_18041

3

0874_QC1MW_18041

3_03

0874_QC1MW_18041

3_02

0874_QC1MW_18041

3_01

0874_MWRB5_S_180

413_F


(Matrix: WATER)






(PFTeDA)

---- ---- <0.0005 <0.0005µg/L0.0005376-06-7


(PFTeDA)

<0.05 <0.12 ---- ----µg/L0.05376-06-7



(FOSA)

---- ---- <0.0005 <0.0005µg/L0.0005754-91-6


(FOSA)

<0.02 <0.05 ---- ----µg/L0.02754-91-6



---- ---- <0.001 <0.001µg/L0.00131506-32-8



<0.05 <0.12 ---- ----µg/L0.0531506-32-8



---- ---- <0.001 <0.001µg/L0.0014151-50-2



<0.05 <0.12 ---- ----µg/L0.054151-50-2



---- ---- <0.001 <0.001µg/L0.00124448-09-7



<0.05 <0.12 ---- ----µg/L0.0524448-09-7



---- ---- <0.001 <0.001µg/L0.0011691-99-2



<0.05 <0.12 ---- ----µg/L0.051691-99-2



(MeFOSAA)

---- ---- <0.0005 <0.0005µg/L0.00052355-31-9



(MeFOSAA)

<0.02 <0.05 ---- ----µg/L0.022355-31-9



(EtFOSAA)

---- ---- <0.0005 <0.0005µg/L0.00052991-50-6

19 of 22:Page

Work Order :

:Client

ET1801024



Analytical Results

0874_QC3MW_18041

3

0874_QC1MW_18041

3_03

0874_QC1MW_18041

3_02

0874_QC1MW_18041

3_01

0874_MWRB5_S_180

413_F


(Matrix: WATER)







(EtFOSAA)

<0.02 <0.05 ---- ----µg/L0.022991-50-6



(4:2 FTS)

---- ---- <0.001 <0.001µg/L0.001757124-72-4


(4:2 FTS)

<0.05 <0.05 ---- ----µg/L0.05757124-72-4


(6:2 FTS)

---- ---- <0.001 <0.001µg/L0.00127619-97-2


(6:2 FTS)

<0.05 <0.05 ---- ----µg/L0.0527619-97-2


(8:2 FTS)

---- ---- <0.001 <0.001µg/L0.00139108-34-4


(8:2 FTS)

<0.05 <0.05 ---- ----µg/L0.0539108-34-4


(10:2 FTS)

---- ---- <0.001 <0.001µg/L0.001120226-60-0


(10:2 FTS)

<0.05 <0.05 ---- ----µg/L0.05120226-60-0

EP231P: PFAS Sums

---- ---- ---- 0.0078 <0.0003µg/L0.0003----Sum of PFAS

0.07 <0.01 <0.05 ---- ----µg/L0.01----Sum of PFAS

----Sum of PFHxS and PFOS ---- ---- 0.0055 <0.0003µg/L0.0003355-46-4/1763-23-

1

0.04Sum of PFHxS and PFOS <0.01 <0.05 ---- ----µg/L0.01355-46-4/1763-23-

1

---- ---- ---- 0.0078 <0.0003µg/L0.0003----Sum of PFAS (WA DER List)

0.07 <0.01 <0.05 ---- ----µg/L0.01----Sum of PFAS (WA DER List)


---- ---- ---- 71.3 64.1%0.0005----13C4-PFOS

96.6 95.9 89.2 ---- ----%0.02----13C4-PFOS

---- ---- ---- 106 95.4%0.0005----13C8-PFOA

119 107 106 ---- ----%0.02----13C8-PFOA

20 of 22:Page

Work Order :

:Client

ET1801024



Analytical Results

--------0874_QC5MW_18041

3_02

0874_QC5MW_18041

3_01

0874_QC4MW_18041

3


(Matrix: WATER)






(PFBS)

<0.0005 <0.0005 ---- ----µg/L0.0005375-73-5


(PFPeS)

<0.0005 <0.0005 ---- ----µg/L0.00052706-91-4


(PFHxS)

<0.0005 <0.0005 ---- ----µg/L0.0005355-46-4


(PFHpS)

<0.0005 <0.0005 ---- ----µg/L0.0005375-92-8


(PFOS)

<0.0003 <0.0003 ---- ----µg/L0.00031763-23-1


(PFDS)

<0.0005 <0.0005 ---- ----µg/L0.0005335-77-3










(PFUnDA)

<0.0005 <0.0005 ---- ----µg/L0.00052058-94-8


(PFDoDA)

<0.0005 <0.0005 ---- ----µg/L0.0005307-55-1


(PFTrDA)

<0.0005 <0.0005 ---- ----µg/L0.000572629-94-8


(PFTeDA)

<0.0005 <0.0005 ---- ----µg/L0.0005376-06-7



(FOSA)

<0.0005 <0.0005 ---- ----µg/L0.0005754-91-6



<0.001 <0.001 ---- ----µg/L0.00131506-32-8



<0.001 <0.001 ---- ----µg/L0.0014151-50-2

21 of 22:Page

Work Order :

:Client

ET1801024



Analytical Results

--------0874_QC5MW_18041

3_02

0874_QC5MW_18041

3_01

0874_QC4MW_18041

3


(Matrix: WATER)







<0.001 <0.001 ---- ----µg/L0.00124448-09-7



<0.001 <0.001 ---- ----µg/L0.0011691-99-2



(MeFOSAA)

<0.0005 <0.0005 ---- ----µg/L0.00052355-31-9



(EtFOSAA)

<0.0005 <0.0005 ---- ----µg/L0.00052991-50-6



(4:2 FTS)

<0.001 <0.001 ---- ----µg/L0.001757124-72-4


(6:2 FTS)

<0.001 <0.001 ---- ----µg/L0.00127619-97-2


(8:2 FTS)

<0.001 <0.001 ---- ----µg/L0.00139108-34-4


(10:2 FTS)

<0.001 <0.001 ---- ----µg/L0.001120226-60-0

EP231P: PFAS Sums

<0.0003 <0.0003 <0.0003 ---- ----µg/L0.0003----Sum of PFAS


1



68.7 66.1 68.5 ---- ----%0.0005----13C4-PFOS

84.7 74.7 66.6 ---- ----%0.0005----13C8-PFOA

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13C4-PFOS ---- 60 120

13C8-PFOA ---- 60 120

False

7 7.00False

Environmental




:Address MOBIL

C/O GPO BOX 2907








Site : ----



















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General Comments










Key :







EA005P: pH by PC Titrator (QC Lot: 1569888)

EA005-P: pH Value ---- 0.01 pH Unit 6.21 6.25 0.642 0% - 20%0874_MWRB5_S_180413 ET1801024-015

EA010P: Conductivity by PC Titrator (QC Lot: 1569887)

EA010-P: Electrical Conductivity @ 25°C ---- 1 µS/cm 130 130 0.00 0% - 20%0874_MWRB5_S_180413 ET1801024-015


EA015H: Total Dissolved Solids @180°C ---- 10 mg/L 164 160 2.47 0% - 50%0874_MWRB5_S_180413 ET1801024-015



EA025H: Suspended Solids (SS) ---- 5 mg/L 48 60 22.2 0% - 50%0874_MWRB5_S_180413 ET1801024-015



EA045: Turbidity ---- 0.1 NTU 43.4 42.1 3.04 0% - 20%0874_MWRB5_S_180413 ET1801024-015



ED037-P: Hydroxide Alkalinity as CaCO3 DMO-210-001 1 mg/L <1 <1 0.00 No Limit0874_MWRB5_S_180413 ET1801024-015











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ED037P: Alkalinity by PC Titrator (QC Lot: 1572232) - continued

ED037-P: Bicarbonate Alkalinity as CaCO3 71-52-3 1 mg/L 424 422 0.416 0% - 20%0874_MW253_S_180413 ET1801024-011



ED041G: Sulfate as SO4 - Turbidimetric 14808-79-8 1 mg/L 16 16 0.00 0% - 50%0874_MWRB5_S_180413 ET1801024-015



ED041G: Sulfate as SO4 - Turbidimetric 14808-79-8 1 mg/L 2 2 0.00 No LimitAnonymous ET1801022-011





ED045G: Chloride 16887-00-6 1 mg/L 8 8 0.00 No Limit0874_MWRB5_S_180413 ET1801024-015


ED045G: Chloride 16887-00-6 1 mg/L 6 6 0.00 No LimitAnonymous ET1801022-011





ED093F: Sodium 7440-23-5 1 mg/L 224 224 0.00 0% - 20%




ED093F: Sodium 7440-23-5 1 mg/L 2170 2180 0.480 0% - 20%





ED093F: Sodium 7440-23-5 1 mg/L 1560 1610 3.20 0% - 20%




ED093F: Sodium 7440-23-5 1 mg/L 1970 1980 0.768 0% - 20%


EG020F: Dissolved Metals by ICP-MS (QC Lot: 1574527)

EG020A-F: Manganese 7439-96-5 0.001 mg/L 0.454 0.456 0.427 0% - 20%Anonymous EP1804756-007

EG020A-F: Aluminium 7429-90-5 0.01 mg/L 0.04 0.04 0.00 No Limit

EG020A-F: Iron 7439-89-6 0.05 mg/L 0.07 0.07 0.00 No Limit

EG051G: Ferrous Iron by Discrete Analyser (QC Lot: 1574926)

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EG051G: Ferrous Iron by Discrete Analyser (QC Lot: 1574926) - continued

EG051G: Ferrous Iron ---- 0.05 mg/L <0.05 <0.05 0.00 No Limit0874_MWRB5_S_180413 ET1801024-015

EK040P: Fluoride by PC Titrator (QC Lot: 1569885)

EK040P: Fluoride 16984-48-8 0.1 mg/L <0.1 <0.1 0.00 No Limit0874_MWRB5_S_180413 ET1801024-015

EK057G: Nitrite as N by Discrete Analyser (QC Lot: 1569898)

EK057G: Nitrite as N 14797-65-0 0.01 mg/L <0.01 <0.01 0.00 No Limit0874_MWRB5_S_180413 ET1801024-015

EK061G: Total Kjeldahl Nitrogen By Discrete Analyser (QC Lot: 1580823)

EK061G: Total Kjeldahl Nitrogen as N ---- 0.1 mg/L 18.7 17.7 5.47 0% - 20%Anonymous EB1809432-001


EK067G: Total Phosphorus as P by Discrete Analyser (QC Lot: 1580824)

EK067G: Total Phosphorus as P ---- 0.01 mg/L 0.66 0.68 2.80 0% - 20%Anonymous EB1809432-001


EK071G: Reactive Phosphorus as P by discrete analyser (QC Lot: 1569897)

EK071G: Reactive Phosphorus as P 14265-44-2 0.01 mg/L 2.86 2.85 0.00 0% - 20%0874_MWRB5_S_180413 ET1801024-015

EP005: Total Organic Carbon (TOC) (QC Lot: 1572519)

EP005: Total Organic Carbon ---- 1 mg/L 2 1 0.00 No LimitAnonymous ET1801020-001

EP026SP: Chemical Oxygen Demand (Spectrophotometric) (QC Lot: 1586428)

EP026SP: Chemical Oxygen Demand ---- 10 mg/L 34 32 3.80 No LimitAnonymous EB1809430-001

EP026SP: Chemical Oxygen Demand ---- 10 mg/L <100 <100 0.00 No LimitAnonymous ET1801043-002

EP030: Biochemical Oxygen Demand (BOD) (QC Lot: 1573842)

EP030: Biochemical Oxygen Demand ---- 2 mg/L <2 2 0.00 No LimitAnonymous EB1809322-007

EP030: Biochemical Oxygen Demand ---- 2 mg/L <2 3 0.00 No LimitAnonymous EB1809430-007



(PFOS)



(PFBS)

375-73-5 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFPeS)

2706-91-4 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFHxS)

355-46-4 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFHpS)

375-92-8 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFDS)

335-77-3 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFOS)



(PFBS)

375-73-5 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit

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(PFPeS)



(PFHxS)

355-46-4 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFHpS)

375-92-8 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFDS)

335-77-3 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit



(PFOS)

1763-23-1 0.0003 µg/L 0.0063 0.0061 2.89 0% - 20%0874_MW252_S_180413 ET1801024-012


(PFBS)

375-73-5 0.0005 µg/L 0.0042 0.0043 3.29 No Limit


(PFPeS)

2706-91-4 0.0005 µg/L <0.0005 0.0005 0.00 No Limit


(PFHxS)

355-46-4 0.0005 µg/L 0.0051 0.0052 1.93 0% - 50%


(PFHpS)

375-92-8 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFDS)

335-77-3 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit








EP231X: Perfluorooctane sulfonic acid (PFOS) 1763-23-1 0.01 µg/L 0.07 0.07 0.00 No Limit0874_MWRB5_S_180413 ET1801024-015












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EP231X-ST: Perfluorodecanoic acid (PFDA) 335-76-2 0.0005 µg/L <0.0005 <0.0005 0.00 No LimitAnonymous EB1809230-007





(PFTeDA)

376-06-7 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit












(PFTeDA)

376-06-7 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit



EP231X-ST: Perfluoropentanoic acid (PFPeA) 2706-90-3 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit0874_MW252_S_180413 ET1801024-012










(PFTeDA)

376-06-7 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit










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EP231X: Perfluorododecanoic acid (PFDoDA) 307-55-1 0.02 µg/L <0.02 <0.02 0.00 No LimitAnonymous ET1801011-010




EP231X: Perfluorooctanoic acid (PFOA) 335-67-1 0.01 µg/L <0.01 <0.01 0.00 No Limit0874_MWRB5_S_180413 ET1801024-015













(FOSA)




2355-31-9 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit



2991-50-6 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit



31506-32-8 0.001 µg/L <0.001 <0.001 0.00 No Limit


(EtFOSA)

4151-50-2 0.001 µg/L <0.001 <0.001 0.00 No Limit



24448-09-7 0.001 µg/L <0.001 <0.001 0.00 No Limit



1691-99-2 0.001 µg/L <0.001 <0.001 0.00 No Limit


(FOSA)




2355-31-9 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit



2991-50-6 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit



31506-32-8 0.001 µg/L <0.001 <0.001 0.00 No Limit


(EtFOSA)

4151-50-2 0.001 µg/L <0.001 <0.001 0.00 No Limit

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1691-99-2 0.001 µg/L <0.001 <0.001 0.00 No Limit



(FOSA)




2355-31-9 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit



2991-50-6 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit



31506-32-8 0.001 µg/L <0.001 <0.001 0.00 No Limit


(EtFOSA)

4151-50-2 0.001 µg/L <0.001 <0.001 0.00 No Limit



24448-09-7 0.001 µg/L <0.001 <0.001 0.00 No Limit



1691-99-2 0.001 µg/L <0.001 <0.001 0.00 No Limit





2355-31-9 0.02 µg/L <0.02 <0.02 0.00 No Limit



2991-50-6 0.02 µg/L <0.02 <0.02 0.00 No Limit


(MeFOSA)

31506-32-8 0.05 µg/L <0.05 <0.05 0.00 No Limit


(EtFOSA)

4151-50-2 0.05 µg/L <0.05 <0.05 0.00 No Limit



24448-09-7 0.05 µg/L <0.05 <0.05 0.00 No Limit



1691-99-2 0.05 µg/L <0.05 <0.05 0.00 No Limit

EP231X: Perfluorooctane sulfonamide (FOSA) 754-91-6 0.02 µg/L <0.02 <0.02 0.00 No Limit0874_MWRB5_S_180413 ET1801024-015



2355-31-9 0.02 µg/L <0.02 <0.02 0.00 No Limit



2991-50-6 0.02 µg/L <0.02 <0.02 0.00 No Limit


(MeFOSA)

31506-32-8 0.05 µg/L <0.05 <0.05 0.00 No Limit

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(EtFOSA)

4151-50-2 0.05 µg/L <0.05 <0.05 0.00 No Limit0874_MWRB5_S_180413 ET1801024-015



24448-09-7 0.05 µg/L <0.05 <0.05 0.00 No Limit



1691-99-2 0.05 µg/L <0.05 <0.05 0.00 No Limit



FTS)



FTS)

27619-97-2 0.001 µg/L <0.001 <0.001 0.00 No Limit


FTS)

39108-34-4 0.001 µg/L <0.001 <0.001 0.00 No Limit


(10:2 FTS)

120226-60-0 0.001 µg/L <0.001 <0.001 0.00 No Limit


FTS)



FTS)

27619-97-2 0.001 µg/L <0.001 <0.001 0.00 No Limit


FTS)

39108-34-4 0.001 µg/L <0.001 <0.001 0.00 No Limit


(10:2 FTS)

120226-60-0 0.001 µg/L <0.001 <0.001 0.00 No Limit



FTS)



FTS)

27619-97-2 0.001 µg/L <0.001 <0.001 0.00 No Limit


FTS)

39108-34-4 0.001 µg/L <0.001 <0.001 0.00 No Limit


(10:2 FTS)

120226-60-0 0.001 µg/L <0.001 <0.001 0.00 No Limit



FTS)



FTS)

27619-97-2 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

39108-34-4 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

120226-60-0 0.05 µg/L <0.05 <0.05 0.00 No Limit

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FTS)

757124-72-4 0.05 µg/L <0.05 <0.05 0.00 No Limit0874_MWRB5_S_180413 ET1801024-015


FTS)

27619-97-2 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

39108-34-4 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

120226-60-0 0.05 µg/L <0.05 <0.05 0.00 No Limit





EP231X-ST: Sum of PFAS ---- 0.0003 µg/L 0.0156 0.0161 3.15 0% - 20%0874_MW252_S_180413 ET1801024-012



EP231X: Sum of PFAS ---- 0.01 µg/L 0.16 0.17 6.06 0% - 50%0874_MWRB5_S_180413 ET1801024-015

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Report





EA005-P: pH Value ---- ---- pH Unit ---- 99.54 pH Unit 10298

---- 99.37 pH Unit 10298



<1 98.212890 µS/cm 10791



<10 1022000 mg/L 11288



<5 94.61000 mg/L 12083


EA045: Turbidity ---- 0.1 NTU <0.1 1024 NTU 11387

<0.1 10240 NTU 10595

<0.1 101400 NTU 10397







<1 97.525 mg/L 12080


ED041G: Sulfate as SO4 - Turbidimetric 14808-79-8 1 mg/L <1 103100 mg/L 12080

<1 11425 mg/L 12080



<1 11625 mg/L 12080



<1 97.710 mg/L 12080


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Report






<1 10110 mg/L 12080


ED093F: Calcium 7440-70-2 1 mg/L <1 -------- --------


ED093F: Sodium 7440-23-5 1 mg/L <1 -------- --------



ED093F: Calcium 7440-70-2 1 mg/L <1 -------- --------


ED093F: Sodium 7440-23-5 1 mg/L <1 -------- --------



EG020A-F: Aluminium 7429-90-5 0.01 mg/L <0.01 96.40.5 mg/L 11879

EG020A-F: Manganese 7439-96-5 0.001 mg/L <0.001 98.50.1 mg/L 12089

EG020A-F: Iron 7439-89-6 0.05 mg/L <0.05 99.80.5 mg/L 11482


EG051G: Ferrous Iron ---- 0.05 mg/L <0.05 97.42 mg/L 12085






EK057G: Nitrite as N 14797-65-0 0.01 mg/L <0.01 1020.5 mg/L 12080


EK059G: Nitrite + Nitrate as N ---- 0.01 mg/L <0.01 95.90.5 mg/L 11589









<1 96.7100 mg/L 11379


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Report




EP026SP: Chemical Oxygen Demand (Spectrophotometric) (QCLot: 1586428) - continued

EP026SP: Chemical Oxygen Demand ---- 10 mg/L <10 10050 mg/L 11286

<10 98.8500 mg/L 11286





































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Report










EP231X-ST: Perfluorononanoic acid (PFNA) 375-95-1 0.0005 µg/L <0.0005 1040.01 µg/L 13050





















(MeFOSA)

31506-32-8 0.001 µg/L <0.001 41.40.025 µg/L 13040



(MeFOSE)

24448-09-7 0.001 µg/L <0.001 48.00.025 µg/L 13040


(EtFOSE)

1691-99-2 0.001 µg/L <0.001 58.90.025 µg/L 13040


acid (MeFOSAA)

2355-31-9 0.0005 µg/L <0.0005 53.20.01 µg/L 13040


acid (EtFOSAA)

2991-50-6 0.0005 µg/L <0.0005 51.40.01 µg/L 13040



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Report






(MeFOSA)

31506-32-8 0.001 µg/L <0.001 42.40.025 µg/L 13040



(MeFOSE)

24448-09-7 0.001 µg/L <0.001 50.20.025 µg/L 13040


(EtFOSE)

1691-99-2 0.001 µg/L <0.001 43.80.025 µg/L 13040


acid (MeFOSAA)

2355-31-9 0.0005 µg/L <0.0005 53.80.01 µg/L 13040


acid (EtFOSAA)

2991-50-6 0.0005 µg/L <0.0005 87.60.01 µg/L 13040






(MeFOSE)

24448-09-7 0.05 µg/L <0.05 1021.25 µg/L 15070


(EtFOSE)

1691-99-2 0.05 µg/L <0.05 1031.25 µg/L 15070


(MeFOSAA)

2355-31-9 0.02 µg/L <0.02 1210.5 µg/L 13070


(EtFOSAA)

2991-50-6 0.02 µg/L <0.02 1130.5 µg/L 13070

















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Report




EP231P: PFAS Sums (QCLot: 1582351) - continued










Anonymous ET1801030-001 14808-79-8ED041G: Sulfate as SO4 - Turbidimetric 12920 mg/L 13070


Anonymous ET1801022-002 14808-79-8ED041G: Sulfate as SO4 - Turbidimetric # Not

Determined

20 mg/L 13070



Determined

20 mg/L 13070


Anonymous ET1801030-001 16887-00-6ED045G: Chloride 115400 mg/L 13070


0874_MWRB5_S_180413 ET1801024-015 7429-90-5EG020A-F: Aluminium 98.00.5 mg/L 13070

7439-96-5EG020A-F: Manganese 1010.1 mg/L 13070


Anonymous ET1801030-001 16984-48-8EK040P: Fluoride 1061.92 mg/L 12080


0874_MWRB5_S_180413 ET1801024-015 7664-41-7EK055G: Ammonia as N 77.60.4 mg/L 13070


Anonymous ET1801030-001 14797-65-0EK057G: Nitrite as N 96.40.4 mg/L 13070


0874_MWRB5_S_180413 ET1801024-015 ----EK059G: Nitrite + Nitrate as N # Not

Determined

0.4 mg/L 13070


Anonymous EB1809432-002 ----EK061G: Total Kjeldahl Nitrogen as N 1065 mg/L 13070

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Anonymous EB1809432-002 ----EK067G: Total Phosphorus as P 99.31 mg/L 13070


Anonymous ET1801030-001 14265-44-2EK071G: Reactive Phosphorus as P 1120.4 mg/L 13070


Anonymous ET1801020-002 ----EP005: Total Organic Carbon 95.6100 mg/L 13070


Anonymous EB1809430-003 ----EP026SP: Chemical Oxygen Demand 10247.6 mg/L 13070









0874_MW253_S_180413 ET1801024-011 375-73-5EP231X-ST: Perfluorobutane sulfonic acid (PFBS) 51.20.01 µg/L 13050






















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Anonymous EB1809230-009 307-55-1EP231X-ST: Perfluorododecanoic acid (PFDoDA) 41.40.01 µg/L 13030




0874_MW253_S_180413 ET1801024-011 375-22-4EP231X-ST: Perfluorobutanoic acid (PFBA) 32.30.05 µg/L 13030


























(MeFOSA)

31.50.025 µg/L 13030


(EtFOSA)

41.80.025 µg/L 13030



39.00.025 µg/L 13030



56.60.025 µg/L 13030



45.20.01 µg/L 13030

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Anonymous EB1809230-009 2991-50-6EP231X-ST: N-Ethyl perfluorooctane sulfonamidoacetic

acid (EtFOSAA)

51.20.01 µg/L 13030


0874_MW253_S_180413 ET1801024-011 754-91-6EP231X-ST: Perfluorooctane sulfonamide (FOSA) 43.60.01 µg/L 13030


(MeFOSA)

30.50.025 µg/L 13030


(EtFOSA)

32.50.025 µg/L 13030



32.50.025 µg/L 13030



32.60.025 µg/L 13030



45.80.01 µg/L 13030


acid (EtFOSAA)

75.40.01 µg/L 13030


Anonymous ET1801011-010 754-91-6EP231X: Perfluorooctane sulfonamide (FOSA) 88.40.5 µg/L 13050


(MeFOSA)

1121.25 µg/L 15050



(MeFOSE)

1181.25 µg/L 15050


(EtFOSE)

1111.25 µg/L 15050


acid (MeFOSAA)

1180.5 µg/L 13050


acid (EtFOSAA)

75.20.5 µg/L 13050







0874_MW253_S_180413 ET1801024-011 757124-72-4EP231X-ST: 4:2 Fluorotelomer sulfonic acid (4:2 FTS) 63.20.01 µg/L 13050



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0874_MW253_S_180413 ET1801024-011 120226-60-0EP231X-ST: 10:2 Fluorotelomer sulfonic acid (10:2 FTS) 53.60.01 µg/L 13050






True

Environmental






JACK MCBAIN:Sampler No. of samples received : 23






Summary of Outliers











l Quality Control Sample Frequency Outliers exist - please see following pages for full details.


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Matrix: WATER



ET1801022--002 14808-79-8Sulfate as SO4 -

Turbidimetric




----Not

Determined


ET1801024--010 14808-79-8Sulfate as SO4 -

Turbidimetric




----Not

Determined


ET1801024--015 ----Nitrite + Nitrate as N0874_MWRB5_S_180413 MS recovery not determined,



----Not

Determined



Matrix: WATER



overdue

Days

overdue


Method



13-Apr-2018----0874_MWRB5_S_180413 16-Apr-2018---- ---- 3

EA045: Turbidity


15-Apr-2018----0874_MWRB5_S_180413 16-Apr-2018---- ---- 1



14-Apr-2018----0874_MWRB5_S_180413 18-Apr-2018---- ---- 4



15-Apr-2018----0874_MWRB5_S_180413 16-Apr-2018---- ---- 1



15-Apr-2018----0874_MWRB5_S_180413 16-Apr-2018---- ---- 1



15-Apr-2018----0874_MWRB5_S_180413 17-Apr-2018---- ---- 2


Matrix: WATER


Method ExpectedQC Regular Actual

Rate (%)Quality Control Sample Type Count


NEPM 2013 B3 & ALS QC StandardAmmonia as N by Discrete analyser 0.00 10.000 8

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Matrix: WATER


Method ExpectedQC Regular Actual

Rate (%)Quality Control Sample Type Count

Laboratory Duplicates (DUP) - Continued

NEPM 2013 B3 & ALS QC StandardNitrite and Nitrate as N (NOx) by Discrete Analyser 0.00 10.000 8

Matrix Spikes (MS)

NEPM 2013 B3 & ALS QC StandardChloride by Discrete Analyser 3.70 5.001 27

NEPM 2013 B3 & ALS QC StandardFerrous Iron by Discrete Analyser 0.00 5.000 1














0874_MWRB5_S_180413 13-Apr-2018---- 16-Apr-2018----13-Apr-2018 ---- ûEA006: Sodium Adsorption Ratio (SAR)


0874_MWRB5_S_180413 11-May-2018---- 18-Apr-2018----13-Apr-2018 ---- üEA010P: Conductivity by PC Titrator


0874_MWRB5_S_180413 11-May-2018---- 16-Apr-2018----13-Apr-2018 ---- üEA015: Total Dissolved Solids dried at 180 ± 5 °C


0874_MWRB5_S_180413 20-Apr-2018---- 17-Apr-2018----13-Apr-2018 ---- üEA025: Total Suspended Solids dried at 104 ± 2°C


0874_MWRB5_S_180413 20-Apr-2018---- 17-Apr-2018----13-Apr-2018 ---- üEA045: Turbidity


0874_MWRB5_S_180413 15-Apr-2018---- 16-Apr-2018----13-Apr-2018 ---- ûEA065: Total Hardness as CaCO3


0874_MWRB5_S_180413 11-May-2018---- 18-Apr-2018----13-Apr-2018 ---- ü

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0874_MWRB5_S_180413 27-Apr-2018---- 16-Apr-2018----13-Apr-2018 ---- üClear Plastic Bottle - Natural (ED037-P)

0874_MW228_S_180413, 0874_MW227_S_180413,

0874_MW226_S_180413, 0874_MWRB2_S_180413,

0874_MW262_S_180413, 0874_MW254_S_180413,

0874_MW264_S_180413, 0874_MW204_S_180413,

0874_MW205_S_180413, 0874_MW207_S_180413,

0874_MW253_S_180413, 0874_MW252_S_180413,

0874_MW233_S_180413, 0874_MWRB3_S_180413,

0874_QC1MW_180413_01, 0874_QC1MW_180413_02,

0874_QC1MW_180413_03, 0874_QC3MW_180413

27-Apr-2018---- 17-Apr-2018----13-Apr-2018 ---- ü



0874_MWRB5_S_180413 11-May-2018---- 16-Apr-2018----13-Apr-2018 ---- üClear Plastic Bottle - Natural (ED041G)

0874_MW228_S_180413, 0874_MW227_S_180413,

0874_MW226_S_180413, 0874_MWRB2_S_180413,

0874_MW262_S_180413, 0874_MW254_S_180413,

0874_MW264_S_180413, 0874_MW204_S_180413,

0874_MW205_S_180413, 0874_MW207_S_180413,

0874_MW253_S_180413, 0874_MW252_S_180413,

0874_MW233_S_180413, 0874_MWRB3_S_180413,

0874_QC1MW_180413_01, 0874_QC1MW_180413_02,

0874_QC1MW_180413_03, 0874_QC3MW_180413

11-May-2018---- 17-Apr-2018----13-Apr-2018 ---- ü



0874_MWRB5_S_180413 11-May-2018---- 16-Apr-2018----13-Apr-2018 ---- üClear Plastic Bottle - Natural (ED045G)

0874_MW228_S_180413, 0874_MW227_S_180413,

0874_MW226_S_180413, 0874_MWRB2_S_180413,

0874_MW262_S_180413, 0874_MW254_S_180413,

0874_MW264_S_180413, 0874_MW204_S_180413,

0874_MW205_S_180413, 0874_MW207_S_180413,

0874_MW253_S_180413, 0874_MW252_S_180413,

0874_MW233_S_180413, 0874_MWRB3_S_180413,

0874_QC1MW_180413_01, 0874_QC1MW_180413_02,

0874_QC1MW_180413_03, 0874_QC3MW_180413

11-May-2018---- 17-Apr-2018----13-Apr-2018 ---- ü

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0874_MWRB5_S_180413 11-May-2018---- 18-Apr-2018----13-Apr-2018 ---- üClear Plastic Bottle - Natural (ED093F)

0874_MW228_S_180413, 0874_MW227_S_180413,

0874_MW226_S_180413, 0874_MWRB2_S_180413,

0874_MW262_S_180413, 0874_MW254_S_180413,

0874_MW264_S_180413, 0874_MW204_S_180413,

0874_MW205_S_180413, 0874_MW207_S_180413,

0874_MW253_S_180413, 0874_MW252_S_180413,

0874_MW233_S_180413, 0874_MWRB3_S_180413,

0874_QC1MW_180413_01, 0874_QC1MW_180413_02,

0874_QC1MW_180413_03, 0874_QC3MW_180413

20-Apr-2018---- 18-Apr-2018----13-Apr-2018 ---- ü



0874_MWRB5_S_180413 10-Oct-2018---- 18-Apr-2018----13-Apr-2018 ---- üEG051G: Ferrous Iron by Discrete Analyser


0874_MWRB5_S_180413 14-Apr-2018---- 18-Apr-2018----13-Apr-2018 ---- ûEK040P: Fluoride by PC Titrator


0874_MWRB5_S_180413 11-May-2018---- 16-Apr-2018----13-Apr-2018 ---- üEK055G: Ammonia as N by Discrete Analyser


0874_MWRB5_S_180413 11-May-2018---- 16-Apr-2018----13-Apr-2018 ---- üEK057G: Nitrite as N by Discrete Analyser


0874_MWRB5_S_180413 15-Apr-2018---- 16-Apr-2018----13-Apr-2018 ---- ûEK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser


0874_MWRB5_S_180413 11-May-2018---- 16-Apr-2018----13-Apr-2018 ---- üEK061G: Total Kjeldahl Nitrogen By Discrete Analyser


0874_MWRB5_S_180413 11-May-201811-May-2018 20-Apr-201820-Apr-201813-Apr-2018 ü üEK067G: Total Phosphorus as P by Discrete Analyser


0874_MWRB5_S_180413 11-May-201811-May-2018 20-Apr-201820-Apr-201813-Apr-2018 ü üEK071G: Reactive Phosphorus as P by discrete analyser


0874_MWRB5_S_180413 15-Apr-2018---- 16-Apr-2018----13-Apr-2018 ---- û

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0874_MWRB5_S_180413 11-May-2018---- 17-Apr-2018----13-Apr-2018 ---- üEP026SP: Chemical Oxygen Demand (Spectrophotometric)


0874_MWRB5_S_180413 11-May-2018---- 23-Apr-2018----13-Apr-2018 ---- üEP030: Biochemical Oxygen Demand (BOD)


0874_MWRB5_S_180413 15-Apr-2018---- 17-Apr-2018----13-Apr-2018 ---- ûEP231A: Perfluoroalkyl Sulfonic Acids


0874_MW204_S_180413, 0874_MW205_S_180413,

0874_MW207_S_180413, 0874_MW233_S_180413,

0874_MWRB5_S_180413, 0874_MWRB5_S_180413_F,

0874_QC1MW_180413_01, 0874_QC1MW_180413_02

10-Oct-2018---- 23-Apr-2018----13-Apr-2018 ---- ü


0874_MW228_S_180413, 0874_MW227_S_180413,

0874_MW226_S_180413, 0874_MWRB2_S_180413,

0874_MW262_S_180413, 0874_MW254_S_180413,

0874_MW264_S_180413, 0874_MW253_S_180413,

0874_MW252_S_180413, 0874_MWRB3_S_180413,

0874_QC1MW_180413_03, 0874_QC3MW_180413,

0874_QC4MW_180413, 0874_QC5MW_180413_01,

0874_QC5MW_180413_02




0874_MW204_S_180413, 0874_MW205_S_180413,

0874_MW207_S_180413, 0874_MW233_S_180413,

0874_MWRB5_S_180413, 0874_MWRB5_S_180413_F,

0874_QC1MW_180413_01, 0874_QC1MW_180413_02

10-Oct-2018---- 23-Apr-2018----13-Apr-2018 ---- ü


0874_MW228_S_180413, 0874_MW227_S_180413,

0874_MW226_S_180413, 0874_MWRB2_S_180413,

0874_MW262_S_180413, 0874_MW254_S_180413,

0874_MW264_S_180413, 0874_MW253_S_180413,

0874_MW252_S_180413, 0874_MWRB3_S_180413,

0874_QC1MW_180413_03, 0874_QC3MW_180413,

0874_QC4MW_180413, 0874_QC5MW_180413_01,

0874_QC5MW_180413_02


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0874_MW204_S_180413, 0874_MW205_S_180413,

0874_MW207_S_180413, 0874_MW233_S_180413,

0874_MWRB5_S_180413, 0874_MWRB5_S_180413_F,

0874_QC1MW_180413_01, 0874_QC1MW_180413_02

10-Oct-2018---- 23-Apr-2018----13-Apr-2018 ---- ü


0874_MW228_S_180413, 0874_MW227_S_180413,

0874_MW226_S_180413, 0874_MWRB2_S_180413,

0874_MW262_S_180413, 0874_MW254_S_180413,

0874_MW264_S_180413, 0874_MW253_S_180413,

0874_MW252_S_180413, 0874_MWRB3_S_180413,

0874_QC1MW_180413_03, 0874_QC3MW_180413,

0874_QC4MW_180413, 0874_QC5MW_180413_01,

0874_QC5MW_180413_02




0874_MW204_S_180413, 0874_MW205_S_180413,

0874_MW207_S_180413, 0874_MW233_S_180413,

0874_MWRB5_S_180413, 0874_MWRB5_S_180413_F,

0874_QC1MW_180413_01, 0874_QC1MW_180413_02

10-Oct-2018---- 23-Apr-2018----13-Apr-2018 ---- ü


0874_MW228_S_180413, 0874_MW227_S_180413,

0874_MW226_S_180413, 0874_MWRB2_S_180413,

0874_MW262_S_180413, 0874_MW254_S_180413,

0874_MW264_S_180413, 0874_MW253_S_180413,

0874_MW252_S_180413, 0874_MWRB3_S_180413,

0874_QC1MW_180413_03, 0874_QC3MW_180413,

0874_QC4MW_180413, 0874_QC5MW_180413_01,

0874_QC5MW_180413_02


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EP231P: PFAS Sums


0874_MW204_S_180413, 0874_MW205_S_180413,

0874_MW207_S_180413, 0874_MW233_S_180413,

0874_MWRB5_S_180413, 0874_MWRB5_S_180413_F,

0874_QC1MW_180413_01, 0874_QC1MW_180413_02

10-Oct-2018---- 23-Apr-2018----13-Apr-2018 ---- ü


0874_MW228_S_180413, 0874_MW227_S_180413,

0874_MW226_S_180413, 0874_MWRB2_S_180413,

0874_MW262_S_180413, 0874_MW254_S_180413,

0874_MW264_S_180413, 0874_MW253_S_180413,

0874_MW252_S_180413, 0874_MWRB3_S_180413,

0874_QC1MW_180413_03, 0874_QC3MW_180413,

0874_QC4MW_180413, 0874_QC5MW_180413_01,

0874_QC5MW_180413_02


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NEPM 2013 B3 & ALS QC Standard 0.00 10.000 8 ûAmmonia as N by Discrete analyser EK055G









NEPM 2013 B3 & ALS QC Standard 0.00 10.000 8 ûNitrite and Nitrate as N (NOx) by Discrete Analyser EK059G


























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Method Blanks (MB)






















Matrix Spikes (MS)



NEPM 2013 B3 & ALS QC Standard 3.70 5.001 27 ûChloride by Discrete Analyser ED045G


NEPM 2013 B3 & ALS QC Standard 0.00 5.000 1 ûFerrous Iron by Discrete Analyser EG051G



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Schedule B(3)





Conductivity)

EA016 WATER









Schedule B(3)







Discrete Analyser

ED041G WATER











Schedule B(3)


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Schedule B(3)


Analyser

EK059G WATER





Analyser

EK061G WATER


B(3)


Discrete Analyser

EK062G WATER





Schedule B(3)


Analyser

EK067G WATER






Analyser

EK071G WATER


DA

EN055 - PG WATER




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EP026SP WATER






B(3)











(PFAS) by LCMSMS

EP231X WATER










(PFAS) by LCMSMS

EP231X-ST WATER



Schedule B(3)



Environmental





C/O GPO BOX 2907



QLD AUSTRALIA 4814






V4)


Site : ----




Date

24-Apr-2018




General Comments






l Please be advised that the sample IDs in the container for ALS samples #21, #22, and #23 ends

with '180413' instead of '180416' as per the COC. Jack McBain confirmed that the sample IDs in the

container should be assigned.l Discounted Package Prices apply only when specific ALS Group Codes ('W', 'S', 'NT' suites) are referenced on COCs.





l Breaches in recommended extraction / analysis holding times have occurred for BOD.l All remaining analysis will be conducted by ALS Environmental, Brisbane, NATA accreditation no. 825, Site No. 818.









ET1801024-016 : [ 13-Apr-2018 ] : 0874_MWRB5_S_180413_F

ET1801024-017 : [ 13-Apr-2018 ] : 0874_QC1MW_180413_01

ET1801024-018 : [ 13-Apr-2018 ] : 0874_QC1MW_180413_02

ET1801024-019 : [ 13-Apr-2018 ] : 0874_QC1MW_180413_03

ET1801024-022 : [ 13-Apr-2018 ] : 0874_QC5MW_180413_01

ET1801024-023 : [ 13-Apr-2018 ] : 0874_QC5MW_180413_02











component

WA

TE

R -

EG

02

0F

Dis

solv

ed

Me

tals

by

ICP

/MS

WA

TE

R -

EP

02

6S

P

Ch

em

ica

l Oxy

ge

n D

em

an

d (

CO

D)

WA

TE

R -

EP

03

0

BO

D

WA

TE

R -

EP

23

1X

PF

AS

- F

ull

Su

ite (

28

an

aly

tes)

WA

TE

R -

EP

23

1X

-ST

PF

AS

- S

up

er

Tra

ce W

ate

rs L

ong

Su

ite (

28

WA

TE

R -

NT

-01

& 0

2

Ca

, M

g, N

a, K

, C

l, S

O4

, A

lka

linity

WA

TE

R -

NT

-14

Ext

en

de

d W

ate

r S

uite

B

ET1801024-001 13-Apr-2018 00:00 0874_MW228_S_180413 ü ü

ET1801024-002 13-Apr-2018 00:00 0874_MW227_S_180413 ü ü

ET1801024-003 13-Apr-2018 00:00 0874_MW226_S_180413 ü ü

ET1801024-004 13-Apr-2018 00:00 0874_MWRB2_S_180413 ü ü

ET1801024-005 13-Apr-2018 00:00 0874_MW262_S_180413 ü ü

ET1801024-006 13-Apr-2018 00:00 0874_MW254_S_180413 ü ü

ET1801024-007 13-Apr-2018 00:00 0874_MW264_S_180413 ü ü

ET1801024-008 13-Apr-2018 00:00 0874_MW204_S_180413 ü ü

ET1801024-009 13-Apr-2018 00:00 0874_MW205_S_180413 ü ü

ET1801024-010 13-Apr-2018 00:00 0874_MW207_S_180413 ü ü

ET1801024-011 13-Apr-2018 00:00 0874_MW253_S_180413 ü ü

ET1801024-012 13-Apr-2018 00:00 0874_MW252_S_180413 ü ü

ET1801024-013 13-Apr-2018 00:00 0874_MW233_S_180413 ü ü

ET1801024-014 13-Apr-2018 00:00 0874_MWRB3_S_180413 ü ü

ET1801024-015 13-Apr-2018 00:00 0874_MWRB5_S_180413 ü ü ü ü ü ü

ET1801024-016 13-Apr-2018 00:00 0874_MWRB5_S_180413_F ü

ET1801024-017 13-Apr-2018 00:00 0874_QC1MW_180413_01 ü ü

ET1801024-018 13-Apr-2018 00:00 0874_QC1MW_180413_02 ü ü

ET1801024-019 13-Apr-2018 00:00 0874_QC1MW_180413_03 ü ü

ET1801024-020 13-Apr-2018 00:00 0874_QC3MW_180413 ü ü

ET1801024-021 13-Apr-2018 00:00 0874_QC4MW_180413 ü

ET1801024-022 13-Apr-2018 00:00 0874_QC5MW_180413_01 ü

ET1801024-023 13-Apr-2018 00:00 0874_QC5MW_180413_02 ü

Matrix: WATER


ID

Client sampling

date / time




WA

TE

R -

EA

01

5H

Tota

l Dis

solv

ed

Solid

s -

Sta

nda

rd L

eve

l

WA

TE

R -

EA

02

5H

Susp

en

de

d S

olid

s -

Sta

nd

ard

Le

vel

WA

TE

R -

EA

04

5

Turb

idity

WA

TE

R -

EG

051G

Ferr

ou

s Ir

on

WA

TE

R -

EP

00

5

Tota

l Org

an

ic C

arb

on

(T

OC

)

ET1801024-015 13-Apr-2018 00:00 0874_MWRB5_S_180413 ü ü ü ü ü

Matrix: WATER


ID

Client sampling

date / time


The following table summarises breaches of recommended holding times that have occurred prior to samples/instructions being

received at the laboratory.

Evaluation: û = Holding time breach ; ü = Within holding time. Matrix: WATER

EvaluationClient Sample ID(s)

Due for

extraction

Due for

analysis Evaluation

Samples Received Instructions Received

Date Date

Method

Container

EA005-P: pH by PC Titrator

0874_MWRB5_S_180413 û --------16-Apr-201813-Apr-2018----Clear Plastic Bottle - Natural

EA045: Turbidity



0874_MWRB5_S_180413 û --------16-Apr-201814-Apr-2018----Clear Plastic Bottle - HCl



EK071G: Reactive Phosphorus as P-By Discrete Analyser








ACCOUNTS PAYABLE


AU ACCOUNTS PAYABLE


DAVID HARRIS








DERP LABREPORTS


PHIL SCHULZ









RESULTS RESULTS








Environmental





C/O GPO BOX 2907



QLD AUSTRALIA 4814






V4)


Site : ----




Date

24-Apr-2018




General Comments






l 16.4.18: SRN has been resent to acknowledge adding test location of EP231X and EP231X-ST in

the SRN and COA as it was missed in the previous SRN.l Please be advised that the sample IDs in the container for ALS samples #21, #22, and #23 ends

with '180413' instead of '180416' as per the COC. Jack McBain confirmed that the sample IDs in the

container should be assigned.l Discounted Package Prices apply only when specific ALS Group Codes ('W', 'S', 'NT' suites) are referenced on COCs.






l Breaches in recommended extraction / analysis holding times have occurred for BOD.l All remaining analysis will be conducted by ALS Environmental, Brisbane, NATA accreditation no. 825, Site No. 818.









ET1801024-016 : [ 13-Apr-2018 ] : 0874_MWRB5_S_180413_F

ET1801024-017 : [ 13-Apr-2018 ] : 0874_QC1MW_180413_01

ET1801024-018 : [ 13-Apr-2018 ] : 0874_QC1MW_180413_02

ET1801024-019 : [ 13-Apr-2018 ] : 0874_QC1MW_180413_03

ET1801024-022 : [ 13-Apr-2018 ] : 0874_QC5MW_180413_01

ET1801024-023 : [ 13-Apr-2018 ] : 0874_QC5MW_180413_02











component

WA

TE

R -

EG

02

0F

Dis

solv

ed

Me

tals

by

ICP

/MS

WA

TE

R -

EP

02

6S

P

Ch

em

ica

l Oxy

ge

n D

em

an

d (

CO

D)

WA

TE

R -

EP

03

0

BO

D

WA

TE

R -

EP

23

1X

PF

AS

- F

ull

Su

ite (

28

an

aly

tes)

WA

TE

R -

EP

23

1X

-ST

PF

AS

- S

up

er

Tra

ce W

ate

rs L

ong

Su

ite (

28

WA

TE

R -

NT

-01

& 0

2

Ca

, M

g, N

a, K

, C

l, S

O4

, A

lka

linity

WA

TE

R -

NT

-14

Ext

en

de

d W

ate

r S

uite

B

ET1801024-001 13-Apr-2018 00:00 0874_MW228_S_180413 ü ü

ET1801024-002 13-Apr-2018 00:00 0874_MW227_S_180413 ü ü

ET1801024-003 13-Apr-2018 00:00 0874_MW226_S_180413 ü ü

ET1801024-004 13-Apr-2018 00:00 0874_MWRB2_S_180413 ü ü

ET1801024-005 13-Apr-2018 00:00 0874_MW262_S_180413 ü ü

ET1801024-006 13-Apr-2018 00:00 0874_MW254_S_180413 ü ü

ET1801024-007 13-Apr-2018 00:00 0874_MW264_S_180413 ü ü

ET1801024-008 13-Apr-2018 00:00 0874_MW204_S_180413 ü ü

ET1801024-009 13-Apr-2018 00:00 0874_MW205_S_180413 ü ü

ET1801024-010 13-Apr-2018 00:00 0874_MW207_S_180413 ü ü

ET1801024-011 13-Apr-2018 00:00 0874_MW253_S_180413 ü ü

ET1801024-012 13-Apr-2018 00:00 0874_MW252_S_180413 ü ü

ET1801024-013 13-Apr-2018 00:00 0874_MW233_S_180413 ü ü

ET1801024-014 13-Apr-2018 00:00 0874_MWRB3_S_180413 ü ü

ET1801024-015 13-Apr-2018 00:00 0874_MWRB5_S_180413 ü ü ü ü ü ü

ET1801024-016 13-Apr-2018 00:00 0874_MWRB5_S_180413_F ü

ET1801024-017 13-Apr-2018 00:00 0874_QC1MW_180413_01 ü ü

ET1801024-018 13-Apr-2018 00:00 0874_QC1MW_180413_02 ü ü

ET1801024-019 13-Apr-2018 00:00 0874_QC1MW_180413_03 ü ü

ET1801024-020 13-Apr-2018 00:00 0874_QC3MW_180413 ü ü

ET1801024-021 13-Apr-2018 00:00 0874_QC4MW_180413 ü

ET1801024-022 13-Apr-2018 00:00 0874_QC5MW_180413_01 ü

ET1801024-023 13-Apr-2018 00:00 0874_QC5MW_180413_02 ü

Matrix: WATER


ID

Client sampling

date / time




WA

TE

R -

EA

01

5H

Tota

l Dis

solv

ed

Solid

s -

Sta

nda

rd L

eve

l

WA

TE

R -

EA

02

5H

Susp

en

de

d S

olid

s -

Sta

nd

ard

Le

vel

WA

TE

R -

EA

04

5

Turb

idity

WA

TE

R -

EG

051G

Ferr

ou

s Ir

on

WA

TE

R -

EP

00

5

Tota

l Org

an

ic C

arb

on

(T

OC

)

ET1801024-015 13-Apr-2018 00:00 0874_MWRB5_S_180413 ü ü ü ü ü

Matrix: WATER


ID

Client sampling

date / time






Due for

extraction

Due for

analysis Evaluation


Date Date

Method

Container



EA045: Turbidity



0874_MWRB5_S_180413 û --------16-Apr-201814-Apr-2018----Clear Plastic Bottle - HCl



EK071G: Reactive Phosphorus as P-By Discrete Analyser








ACCOUNTS PAYABLE


AU ACCOUNTS PAYABLE


DAVID HARRIS








DERP LABREPORTS


PHIL SCHULZ









RESULTS RESULTS








0 0.00 True

Environmental





C/O GPO BOX 2907








Site : ----






l General Comments













Matt Frost Senior Organic Chemist Brisbane Organics, Stafford, QLD


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General Comments







purposes.







Key :

EG020-F (Dissolved Metals by ICP-MS): Limit of reporting raised for some samples due to matrix interference.l

EP005: Results for sample '0874_MW250_S_180416' may bias low due to large amounts of sediment. The sample was decanted before analysis.l

EP231X: Poor duplicate precision for some analytes due to sample heterogeneity.l

EK061G (Total Kjeldahl Nitrogen as N) / EK067G (Total Phosphorus as P): Sample ET1801043_018 (0874_MW005_S_180416) was diluted due to matrix interference. LOR adjusted accordingly.l

The presence of high SO4 may bias the EC low.l

EP231X (TOP): Sample#11 results confrimed by re-extraction and re-analysis.l


23313)

l

EP231X (TOP) conducted by ALS Sydney, NATA accreditation no. 825, site no 10911.l

EP231X: Particular samples required dilution prior to extraction due to matrix interferences. LOR values have been adjusted accordingly.l

Particular samples required dilution prior to extraction due to matrix interferences. LOR values have been adjusted accordingly.l


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ET1801043



Analytical Results

0874_MW021_S_1804

16

0874_MW015_S_1804

16

0874_MW016_S_1804

16

0874_MW250_S_1804

16

0874_MW251_S_1804

16


(Matrix: WATER)





6.85 7.64 6.61 ---- ----pH Unit0.01----pH Value


51.2^ 44.7 30.7 ---- -----0.01----Sodium Adsorption Ratio


34400 11100 15900 ---- ----µS/cm1----Electrical Conductivity @ 25°C


24600 6180 11100 ---- ----mg/L10----Total Dissolved Solids @180°C


22400 7220 10300 ---- ----mg/L1----Total Dissolved Solids (Calc.)


944 2870 126 ---- ----mg/L5----Suspended Solids (SS)

EA045: Turbidity

907 2940 106 ---- ----NTU0.1----Turbidity


3190 523 2160 ---- ----mg/L1----Total Hardness as CaCO3









11700Chloride 3620 5090 10200 294mg/L116887-00-6


268Calcium 28 210 325 10mg/L17440-70-2

612Magnesium 110 396 974 9mg/L17439-95-4

6640Sodium 2350 3280 6920 344mg/L17440-23-5

159Potassium 48 52 146 6mg/L17440-09-7


<0.05Aluminium <0.01 <0.01 ---- ----mg/L0.017429-90-5

0.429Manganese 0.008 3.48 ---- ----mg/L0.0017439-96-5

<0.05Iron <0.05 4.41 ---- ----mg/L0.057439-89-6

4 of 26:Page

Work Order :

:Client

ET1801043



Analytical Results

0874_MW021_S_1804

16

0874_MW015_S_1804

16

0874_MW016_S_1804

16

0874_MW250_S_1804

16

0874_MW251_S_1804

16


(Matrix: WATER)





0.09 0.07 14.8 ---- ----mg/L0.05----Ferrous Iron


0.2Fluoride 1.0 0.6 ---- ----mg/L0.116984-48-8


0.04Ammonia as N 0.04 0.99 ---- ----mg/L0.017664-41-7


<0.01Nitrite as N <0.01 <0.01 ---- ----mg/L0.0114797-65-0


2.26Nitrate as N 9.24 0.43 ---- ----mg/L0.0114797-55-8


2.26 9.24 0.43 ---- ----mg/L0.01----Nitrite + Nitrate as N


1.4 2.5 1.6 ---- ----mg/L0.1----Total Kjeldahl Nitrogen as N


3.7^ 11.7 2.0 ---- ----mg/L0.1----Total Nitrogen as N


0.35 0.84 0.14 ---- ----mg/L0.01----Total Phosphorus as P


0.02Reactive Phosphorus as P 0.04 <0.01 ---- ----mg/L0.0114265-44-2


362 117 173 348 15.9meq/L0.01----Total Anions

357 114 187 401 16.4meq/L0.01----Total Cations

0.70 1.23 3.86 7.02 1.34%0.01----Ionic Balance


5 3 28 ---- ----mg/L1----Total Organic Carbon


222 <100 155 ---- ----mg/L10----Chemical Oxygen Demand


<2 <2 2 ---- ----mg/L2----Biochemical Oxygen Demand



(PFBS)

2.52 68.5 206 13.0µg/L0.02375-73-5

5 of 26:Page

Work Order :

:Client

ET1801043



Analytical Results

0874_MW021_S_1804

16

0874_MW015_S_1804

16

0874_MW016_S_1804

16

0874_MW250_S_1804

16

0874_MW251_S_1804

16


(Matrix: WATER)






(PFPeS)

1.88 84.1 252 14.0µg/L0.022706-91-4


(PFHxS)

11.8 909 2580 158µg/L0.02355-46-4


(PFHpS)

0.60 87.9 116 13.4µg/L0.02375-92-8


(PFOS)

14.2 492 960 355µg/L0.011763-23-1


(PFDS)

<0.05 <0.10 <0.10 0.20µg/L0.02335-77-3


<0.5Perfluorobutanoic acid (PFBA) 0.6 20.4 52.2 4.5µg/L0.1375-22-4

0.67Perfluoropentanoic acid (PFPeA) 0.74 31.1 86.1 6.34µg/L0.022706-90-3

3.73Perfluorohexanoic acid (PFHxA) 3.86 166 545 34.4µg/L0.02307-24-4

0.27Perfluoroheptanoic acid (PFHpA) 0.28 21.9 62.3 4.08µg/L0.02375-85-9


<0.10Perfluorononanoic acid (PFNA) <0.05 0.21 0.19 0.10µg/L0.02375-95-1



(PFUnDA)

<0.05 <0.10 <0.10 <0.02µg/L0.022058-94-8


(PFDoDA)

<0.05 <0.10 <0.10 <0.02µg/L0.02307-55-1


(PFTrDA)

<0.05 <0.10 <0.10 <0.02µg/L0.0272629-94-8


(PFTeDA)

<0.12 <0.25 <0.25 <0.05µg/L0.05376-06-7



(FOSA)

<0.05 <0.10 <0.10 0.29µg/L0.02754-91-6



<0.12 <0.25 <0.25 <0.05µg/L0.0531506-32-8



<0.12 <0.25 <0.25 <0.05µg/L0.054151-50-2



<0.12 <0.25 <0.25 <0.05µg/L0.0524448-09-7

6 of 26:Page

Work Order :

:Client

ET1801043



Analytical Results

0874_MW021_S_1804

16

0874_MW015_S_1804

16

0874_MW016_S_1804

16

0874_MW250_S_1804

16

0874_MW251_S_1804

16


(Matrix: WATER)







<0.12 <0.25 <0.25 <0.05µg/L0.051691-99-2



(MeFOSAA)

<0.05 <0.10 <0.10 <0.02µg/L0.022355-31-9



(EtFOSAA)

<0.05 <0.10 <0.10 <0.02µg/L0.022991-50-6



(4:2 FTS)

<0.05 <0.10 <0.10 <0.05µg/L0.05757124-72-4


(6:2 FTS)

0.06 1.38 0.21 0.60µg/L0.0527619-97-2


(8:2 FTS)

<0.05 <0.10 <0.10 0.14µg/L0.0539108-34-4


(10:2 FTS)

<0.05 <0.10 <0.10 <0.05µg/L0.05120226-60-0

EP231P: PFAS Sums

27.6 37.0 1920 4950 612µg/L0.01----Sum of PFAS

17.3Sum of PFHxS and PFOS 26.0 1400 3540 513µg/L0.01355-46-4/1763-23-

1

25.0 34.5 1750 4580 584µg/L0.01----Sum of PFAS (WA DER List)


90.9 101 92.4 95.5 86.7%0.02----13C4-PFOS

96.7 102 97.5 93.7 91.8%0.02----13C8-PFOA

7 of 26:Page

Work Order :

:Client

ET1801043



Analytical Results

0874_MW139_S_1804

16

0874_MW138_S_1804

16

0874_MW054_S_1804

16

0874_MW055_S_1804

16

0874_MW110_S_1804

16


(Matrix: WATER)





---- 7.74 ---- ---- ----pH Unit0.01----pH Value


----^ 59.0 ---- ---- -----0.01----Sodium Adsorption Ratio


---- 12800 ---- ---- ----µS/cm1----Electrical Conductivity @ 25°C


---- 8380 ---- ---- ----mg/L10----Total Dissolved Solids @180°C


---- 8320 ---- ---- ----mg/L1----Total Dissolved Solids (Calc.)


---- 18 ---- ---- ----mg/L5----Suspended Solids (SS)

EA045: Turbidity

---- 9.8 ---- ---- ----NTU0.1----Turbidity


---- 461 ---- ---- ----mg/L1----Total Hardness as CaCO3



<1Carbonate Alkalinity as CaCO3 <1 32 <1 <1mg/L13812-32-6






13000Chloride 3840 1130 42 7690mg/L116887-00-6


220Calcium 23 3 59 84mg/L17440-70-2

836Magnesium 98 14 8 501mg/L17439-95-4

9260Sodium 2910 1250 35 6040mg/L17440-23-5

255Potassium 77 36 32 138mg/L17440-09-7


----Aluminium <0.01 ---- ---- ----mg/L0.017429-90-5

----Manganese 0.015 ---- ---- ----mg/L0.0017439-96-5

----Iron <0.05 ---- ---- ----mg/L0.057439-89-6

8 of 26:Page

Work Order :

:Client

ET1801043



Analytical Results

0874_MW139_S_1804

16

0874_MW138_S_1804

16

0874_MW054_S_1804

16

0874_MW055_S_1804

16

0874_MW110_S_1804

16


(Matrix: WATER)





---- <0.05 ---- ---- ----mg/L0.05----Ferrous Iron


----Fluoride 1.4 ---- ---- ----mg/L0.116984-48-8


----Ammonia as N 0.17 ---- ---- ----mg/L0.017664-41-7


----Nitrite as N <0.01 ---- ---- ----mg/L0.0114797-65-0


----Nitrate as N 0.17 ---- ---- ----mg/L0.0114797-55-8


---- 0.17 ---- ---- ----mg/L0.01----Nitrite + Nitrate as N


---- 0.3 ---- ---- ----mg/L0.1----Total Kjeldahl Nitrogen as N


----^ 0.5 ---- ---- ----mg/L0.1----Total Nitrogen as N


---- 0.04 ---- ---- ----mg/L0.01----Total Phosphorus as P


----Reactive Phosphorus as P 0.04 ---- ---- ----mg/L0.0114265-44-2




8.46 1.47 1.09 0.59 7.40%0.01----Ionic Balance


---- 5 ---- ---- ----mg/L1----Total Organic Carbon


---- 105 ---- ---- ----mg/L10----Chemical Oxygen Demand


---- 3 ---- ---- ----mg/L2----Biochemical Oxygen Demand



(PFBS)

1.21 4.92 8.19 67.1µg/L0.02375-73-5

9 of 26:Page

Work Order :

:Client

ET1801043



Analytical Results

0874_MW139_S_1804

16

0874_MW138_S_1804

16

0874_MW054_S_1804

16

0874_MW055_S_1804

16

0874_MW110_S_1804

16


(Matrix: WATER)






(PFPeS)

1.40 5.15 8.78 87.1µg/L0.022706-91-4

582Perfluorohexane sulfonic acid

(PFHxS)

11.8 32.0 62.1 557µg/L0.02355-46-4


(PFHpS)

0.75 2.05 4.85 58.7µg/L0.02375-92-8

1420Perfluorooctane sulfonic acid

(PFOS)

39.9 93.7 93.7 1660µg/L0.011763-23-1


(PFDS)

<0.02 <0.02 0.14 0.53µg/L0.02335-77-3


17.3Perfluorobutanoic acid (PFBA) 0.4 1.2 6.4 27.4µg/L0.1375-22-4


135Perfluorohexanoic acid (PFHxA) 3.36 8.69 15.7 212µg/L0.02307-24-4



0.36Perfluorononanoic acid (PFNA) 0.03 0.04 0.10 0.38µg/L0.02375-95-1

<0.10Perfluorodecanoic acid (PFDA) <0.02 <0.02 0.05 <0.10µg/L0.02335-76-2


(PFUnDA)

<0.02 <0.02 <0.02 <0.10µg/L0.022058-94-8


(PFDoDA)

<0.02 <0.02 <0.02 <0.10µg/L0.02307-55-1


(PFTrDA)

<0.02 <0.02 <0.02 <0.10µg/L0.0272629-94-8


(PFTeDA)

<0.05 <0.05 <0.05 <0.25µg/L0.05376-06-7



(FOSA)

0.18 0.06 0.09 0.78µg/L0.02754-91-6



<0.05 <0.05 <0.05 <0.25µg/L0.0531506-32-8



<0.05 <0.05 <0.05 <0.25µg/L0.054151-50-2



<0.05 <0.05 <0.05 <0.25µg/L0.0524448-09-7

10 of 26:Page

Work Order :

:Client

ET1801043



Analytical Results

0874_MW139_S_1804

16

0874_MW138_S_1804

16

0874_MW054_S_1804

16

0874_MW055_S_1804

16

0874_MW110_S_1804

16


(Matrix: WATER)







<0.05 <0.05 <0.05 <0.25µg/L0.051691-99-2



(MeFOSAA)

<0.02 <0.02 <0.02 <0.10µg/L0.022355-31-9



(EtFOSAA)

<0.02 <0.02 <0.02 <0.10µg/L0.022991-50-6



(4:2 FTS)

<0.05 <0.05 <0.05 0.16µg/L0.05757124-72-4


(6:2 FTS)

0.05 <0.05 0.27 39.2µg/L0.0527619-97-2


(8:2 FTS)

<0.05 <0.05 0.13 0.76µg/L0.0539108-34-4


(10:2 FTS)

<0.05 <0.05 <0.05 <0.10µg/L0.05120226-60-0

EP231P: PFAS Sums

2480 61.2 152 210 2830µg/L0.01----Sum of PFAS

2000Sum of PFHxS and PFOS 51.7 126 156 2220µg/L0.01355-46-4/1763-23-

1

2320 58.8 144 196 2680µg/L0.01----Sum of PFAS (WA DER List)


104 84.0 90.9 89.0 93.9%0.02----13C4-PFOS

93.6 94.9 94.6 92.8 90.3%0.02----13C8-PFOA

11 of 26:Page

Work Order :

:Client

ET1801043



Analytical Results

0874_MW112_S_1804

16

0874_MW090_S_1804

16

0874_MW046_S_1804

16

0874_MW081_S_1804

16

0874_MW109_S_1804

16


(Matrix: WATER)





---- 7.40 ---- ---- ----pH Unit0.01----pH Value


----^ 31.0 ---- ---- -----0.01----Sodium Adsorption Ratio


---- 10500 ---- ---- ----µS/cm1----Electrical Conductivity @ 25°C


---- 7110 ---- ---- ----mg/L10----Total Dissolved Solids @180°C


---- 6820 ---- ---- ----mg/L1----Total Dissolved Solids (Calc.)


---- 1070 ---- ---- ----mg/L5----Suspended Solids (SS)

EA045: Turbidity

---- 496 ---- ---- ----NTU0.1----Turbidity


---- 888 ---- ---- ----mg/L1----Total Hardness as CaCO3



<1Carbonate Alkalinity as CaCO3 <1 <1 5 <1mg/L13812-32-6






7360Chloride 3280 2600 43 8460mg/L116887-00-6


74Calcium 72 17 2 635mg/L17440-70-2

304Magnesium 172 57 1 914mg/L17439-95-4

5920Sodium 2120 2130 183 5670mg/L17440-23-5

146Potassium 42 40 2 190mg/L17440-09-7


----Aluminium <0.01 ---- ---- ----mg/L0.017429-90-5

----Manganese 0.127 ---- ---- ----mg/L0.0017439-96-5

----Iron <0.05 ---- ---- ----mg/L0.057439-89-6

12 of 26:Page

Work Order :

:Client

ET1801043



Analytical Results

0874_MW112_S_1804

16

0874_MW090_S_1804

16

0874_MW046_S_1804

16

0874_MW081_S_1804

16

0874_MW109_S_1804

16


(Matrix: WATER)





---- <0.05 ---- ---- ----mg/L0.05----Ferrous Iron


----Fluoride 0.7 ---- ---- ----mg/L0.116984-48-8


----Ammonia as N 0.05 ---- ---- ----mg/L0.017664-41-7


----Nitrite as N 0.08 ---- ---- ----mg/L0.0114797-65-0


----Nitrate as N 8.83 ---- ---- ----mg/L0.0114797-55-8


---- 8.91 ---- ---- ----mg/L0.01----Nitrite + Nitrate as N


---- 1.0 ---- ---- ----mg/L0.1----Total Kjeldahl Nitrogen as N


----^ 9.9 ---- ---- ----mg/L0.1----Total Nitrogen as N


---- 0.12 ---- ---- ----mg/L0.01----Total Phosphorus as P


----Reactive Phosphorus as P 0.07 ---- ---- ----mg/L0.0114265-44-2




6.61 1.13 0.58 3.82 7.47%0.01----Ionic Balance


---- 7 ---- ---- ----mg/L1----Total Organic Carbon


---- 122 ---- ---- ----mg/L10----Chemical Oxygen Demand


---- 2 ---- ---- ----mg/L2----Biochemical Oxygen Demand



(PFBS)

127 ---- ---- ----µg/L0.02375-73-5

13 of 26:Page

Work Order :

:Client

ET1801043



Analytical Results

0874_MW112_S_1804

16

0874_MW090_S_1804

16

0874_MW046_S_1804

16

0874_MW081_S_1804

16

0874_MW109_S_1804

16


(Matrix: WATER)




EP231_TOP_A: Perfluoroalkyl Sulfonic Acids - Continued


(PFPeS)

306 ---- ---- ----µg/L0.022706-91-4


(PFHxS)

3430 ---- ---- ----µg/L0.02355-46-4


(PFHpS)

158 ---- ---- ----µg/L0.02375-92-8


(PFOS)

1800 ---- ---- ----µg/L0.011763-23-1


(PFDS)

<0.50 ---- ---- ----µg/L0.02335-77-3


46.4Perfluorobutanoic acid (PFBA) 86.0 ---- ---- ----µg/L0.1375-22-4


220Perfluorohexanoic acid (PFHxA) 976 ---- ---- ----µg/L0.02307-24-4

13.2Perfluoroheptanoic acid (PFHpA) 55.4 ---- ---- ----µg/L0.02375-85-9

33.3Perfluorooctanoic acid (PFOA) 125 ---- ---- ----µg/L0.01335-67-1




(PFUnDA)

<0.50 ---- ---- ----µg/L0.022058-94-8


(PFDoDA)

<0.50 ---- ---- ----µg/L0.02307-55-1


(PFTrDA)

<0.50 ---- ---- ----µg/L0.0272629-94-8


(PFTeDA)

<1.25 ---- ---- ----µg/L0.05376-06-7



(FOSA)

<0.50 ---- ---- ----µg/L0.02754-91-6



<1.25 ---- ---- ----µg/L0.0531506-32-8



<1.25 ---- ---- ----µg/L0.054151-50-2



<1.25 ---- ---- ----µg/L0.0524448-09-7

14 of 26:Page

Work Order :

:Client

ET1801043



Analytical Results

0874_MW112_S_1804

16

0874_MW090_S_1804

16

0874_MW046_S_1804

16

0874_MW081_S_1804

16

0874_MW109_S_1804

16


(Matrix: WATER)




EP231_TOP_C: Perfluoroalkyl Sulfonamides - Continued



<1.25 ---- ---- ----µg/L0.051691-99-2



(MeFOSAA)

<0.50 ---- ---- ----µg/L0.022355-31-9



(EtFOSAA)

<0.50 ---- ---- ----µg/L0.022991-50-6



(4:2 FTS)

<0.50 ---- ---- ----µg/L0.05757124-72-4


(6:2 FTS)

<0.50 ---- ---- ----µg/L0.0527619-97-2


(8:2 FTS)

<0.50 ---- ---- ----µg/L0.0539108-34-4


(10:2 FTS)

<0.50 ---- ---- ----µg/L0.05120226-60-0


1460 7160 ---- ---- ----µg/L0.01----Sum of PFAS

982Sum of PFHxS and PFOS 5230 ---- ---- ----µg/L0.01355-46-4/1763-23-

1

1460 7160 ---- ---- ----µg/L0.01----Sum of TOP C4 - C14 Carboxylates and C4

- C8 Sulfonates

935^ 4520 ---- ---- ----µg/L0.01----Sum of TOP C4 - C14 as Fluorine



(PFBS)

141 5.04 0.08 7.46µg/L0.02375-73-5


(PFPeS)

359 6.96 0.12 6.50µg/L0.022706-91-4


(PFHxS)

3320 88.7 1.61 36.2µg/L0.02355-46-4


(PFHpS)

190 6.64 0.09 0.34µg/L0.02375-92-8


(PFOS)

1800 149 2.42 2.14µg/L0.011763-23-1

15 of 26:Page

Work Order :

:Client

ET1801043



Analytical Results

0874_MW112_S_1804

16

0874_MW090_S_1804

16

0874_MW046_S_1804

16

0874_MW081_S_1804

16

0874_MW109_S_1804

16


(Matrix: WATER)






(PFDS)

0.33 <0.10 <0.02 <0.10µg/L0.02335-77-3


25.5Perfluorobutanoic acid (PFBA) 19.8 1.2 <0.1 1.6µg/L0.1375-22-4


127Perfluorohexanoic acid (PFHxA) 432 23.4 0.25 19.9µg/L0.02307-24-4


39.8Perfluorooctanoic acid (PFOA) 146 3.62 0.06 0.58µg/L0.01335-67-1

0.22Perfluorononanoic acid (PFNA) 0.73 <0.10 <0.02 <0.10µg/L0.02375-95-1

<0.10Perfluorodecanoic acid (PFDA) 0.10 <0.10 <0.02 <0.10µg/L0.02335-76-2


(PFUnDA)

<0.05 <0.10 <0.02 <0.10µg/L0.022058-94-8


(PFDoDA)

<0.05 <0.10 <0.02 <0.10µg/L0.02307-55-1


(PFTrDA)

<0.05 <0.10 <0.02 <0.10µg/L0.0272629-94-8


(PFTeDA)

<0.12 <0.25 <0.05 <0.25µg/L0.05376-06-7



(FOSA)

0.19 <0.10 <0.02 <0.10µg/L0.02754-91-6



<0.12 <0.25 <0.05 <0.25µg/L0.0531506-32-8



<0.12 <0.25 <0.05 <0.25µg/L0.054151-50-2



<0.12 <0.25 <0.05 <0.25µg/L0.0524448-09-7



<0.12 <0.25 <0.05 <0.25µg/L0.051691-99-2



(MeFOSAA)

<0.05 <0.10 <0.02 <0.10µg/L0.022355-31-9



(EtFOSAA)

<0.05 <0.10 <0.02 <0.10µg/L0.022991-50-6

16 of 26:Page

Work Order :

:Client

ET1801043



Analytical Results

0874_MW112_S_1804

16

0874_MW090_S_1804

16

0874_MW046_S_1804

16

0874_MW081_S_1804

16

0874_MW109_S_1804

16


(Matrix: WATER)






(4:2 FTS)

<0.05 <0.10 <0.05 <0.10µg/L0.05757124-72-4


(6:2 FTS)

<0.05 <0.10 <0.05 <0.10µg/L0.0527619-97-2


(8:2 FTS)

<0.05 <0.10 <0.05 <0.10µg/L0.0539108-34-4


(10:2 FTS)

<0.05 <0.10 <0.05 <0.10µg/L0.05120226-60-0

EP231P: PFAS Sums

1360 6510 288 4.69 79.0µg/L0.01----Sum of PFAS

970Sum of PFHxS and PFOS 5120 238 4.03 38.3µg/L0.01355-46-4/1763-23-

1

1260 5960 275 4.48 72.2µg/L0.01----Sum of PFAS (WA DER List)


110 115 ---- ---- ----%0.02----13C4-PFOS

115 115 ---- ---- ----%0.02----13C8-PFOA


94.4 76.3 99.5 96.2 101%0.02----13C4-PFOS

94.0 110 92.7 91.4 92.2%0.02----13C8-PFOA

17 of 26:Page

Work Order :

:Client

ET1801043



Analytical Results

0874_MW250_S_1804

16_F

0874_MW251_S_1804

16_F

0874_MW005_S_1804

16

0874_MW206_S_1804

16

0874_MW057_S_1804

16


(Matrix: WATER)





---- ---- 6.94 ---- ----pH Unit0.01----pH Value


----^ ---- 71.5 ---- -----0.01----Sodium Adsorption Ratio


---- ---- 79300 ---- ----µS/cm1----Electrical Conductivity @ 25°C


---- ---- 71600 ---- ----mg/L10----Total Dissolved Solids @180°C


---- ---- 51500 ---- ----mg/L1----Total Dissolved Solids (Calc.)


---- ---- 282 ---- ----mg/L5----Suspended Solids (SS)

EA045: Turbidity

---- ---- 55.9 ---- ----NTU0.1----Turbidity


---- ---- 13900 ---- ----mg/L1----Total Hardness as CaCO3


<1Hydroxide Alkalinity as CaCO3 <1 <1 ---- ----mg/L1DMO-210-001

<1Carbonate Alkalinity as CaCO3 <1 <1 ---- ----mg/L13812-32-6

250Bicarbonate Alkalinity as CaCO3 <1 320 ---- ----mg/L171-52-3

250 <1 320 ---- ----mg/L1----Total Alkalinity as CaCO3


3680Sulfate as SO4 - Turbidimetric 2390 5090 ---- ----mg/L114808-79-8


13200Chloride 859 32000 ---- ----mg/L116887-00-6


222Calcium 361 882 ---- ----mg/L17440-70-2

849Magnesium 182 2850 ---- ----mg/L17439-95-4

10300Sodium 839 19400 ---- ----mg/L17440-23-5

258Potassium 35 450 ---- ----mg/L17440-09-7


----Aluminium ---- <0.10 ---- ----mg/L0.017429-90-5

----Manganese ---- 7.85 ---- ----mg/L0.0017439-96-5

----Iron ---- <0.10 ---- ----mg/L0.057439-89-6

18 of 26:Page

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:Client

ET1801043



Analytical Results

0874_MW250_S_1804

16_F

0874_MW251_S_1804

16_F

0874_MW005_S_1804

16

0874_MW206_S_1804

16

0874_MW057_S_1804

16


(Matrix: WATER)





---- ---- <0.05 ---- ----mg/L0.05----Ferrous Iron


----Fluoride ---- 0.3 ---- ----mg/L0.116984-48-8


----Ammonia as N ---- 0.22 ---- ----mg/L0.017664-41-7


----Nitrite as N ---- <0.01 ---- ----mg/L0.0114797-65-0


----Nitrate as N ---- 0.02 ---- ----mg/L0.0114797-55-8


---- ---- 0.02 ---- ----mg/L0.01----Nitrite + Nitrate as N


---- ---- <1.0 ---- ----mg/L0.1----Total Kjeldahl Nitrogen as N


----^ ---- <1.0 ---- ----mg/L0.1----Total Nitrogen as N


---- ---- <0.10 ---- ----mg/L0.01----Total Phosphorus as P


----Reactive Phosphorus as P ---- 0.06 ---- ----mg/L0.0114265-44-2


454 74.0 1020 ---- ----meq/L0.01----Total Anions

536 70.4 1130 ---- ----meq/L0.01----Total Cations

8.25 2.50 5.53 ---- ----%0.01----Ionic Balance


---- ---- 6 ---- ----mg/L1----Total Organic Carbon


---- ---- 478 ---- ----mg/L10----Chemical Oxygen Demand


---- ---- <2 ---- ----mg/L2----Biochemical Oxygen Demand



(PFBS)

0.77 16.4 4.17 0.22µg/L0.02375-73-5

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Analytical Results

0874_MW250_S_1804

16_F

0874_MW251_S_1804

16_F

0874_MW005_S_1804

16

0874_MW206_S_1804

16

0874_MW057_S_1804

16


(Matrix: WATER)






(PFPeS)

0.74 20.1 0.23 <0.10µg/L0.022706-91-4


(PFHxS)

4.54 270 <0.10 <0.10µg/L0.02355-46-4


(PFHpS)

0.05 14.9 <0.10 <0.10µg/L0.02375-92-8


(PFOS)

<0.01 135 <0.10 <0.10µg/L0.011763-23-1


(PFDS)

<0.02 <0.10 <0.10 <0.10µg/L0.02335-77-3










(PFUnDA)

<0.02 <0.10 <0.10 <0.10µg/L0.022058-94-8


(PFDoDA)

<0.02 <0.10 <0.10 <0.10µg/L0.02307-55-1


(PFTrDA)

<0.02 <0.10 <0.10 <0.10µg/L0.0272629-94-8


(PFTeDA)

<0.05 <0.25 <0.25 <0.25µg/L0.05376-06-7



(FOSA)

<0.02 <0.10 <0.10 <0.10µg/L0.02754-91-6



<0.05 <0.25 <0.25 <0.25µg/L0.0531506-32-8



<0.05 <0.25 <0.25 <0.25µg/L0.054151-50-2



<0.05 <0.25 <0.25 <0.25µg/L0.0524448-09-7

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Analytical Results

0874_MW250_S_1804

16_F

0874_MW251_S_1804

16_F

0874_MW005_S_1804

16

0874_MW206_S_1804

16

0874_MW057_S_1804

16


(Matrix: WATER)







<0.05 <0.25 <0.25 <0.25µg/L0.051691-99-2



(MeFOSAA)

<0.02 <0.10 <0.10 <0.10µg/L0.022355-31-9



(EtFOSAA)

<0.02 <0.10 <0.10 <0.10µg/L0.022991-50-6



(4:2 FTS)

<0.05 <0.10 <0.10 <0.10µg/L0.05757124-72-4


(6:2 FTS)

<0.05 <0.10 <0.10 <0.10µg/L0.0527619-97-2


(8:2 FTS)

<0.05 <0.10 <0.10 <0.10µg/L0.0539108-34-4


(10:2 FTS)

<0.05 <0.10 <0.10 <0.10µg/L0.05120226-60-0

EP231P: PFAS Sums

43.5 8.18 538 23.6 5.54µg/L0.01----Sum of PFAS

24.3Sum of PFHxS and PFOS 4.54 405 <0.10 <0.10µg/L0.01355-46-4/1763-23-

1

39.2 7.39 503 23.4 5.54µg/L0.01----Sum of PFAS (WA DER List)


96.4 94.7 94.2 105 99.2%0.02----13C4-PFOS

91.6 90.1 93.2 93.6 93.9%0.02----13C8-PFOA

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ET1801043



Analytical Results

0874_QC3MW_S_180

416

0874_MW005_S_1804

16_F

0874_MW081_S_1804

16_F

0874_MW055_S_1804

16_F

0874_MW016_S_1804

16_F


(Matrix: WATER)





----Hydroxide Alkalinity as CaCO3 ---- ---- ---- <1mg/L1DMO-210-001

----Carbonate Alkalinity as CaCO3 ---- ---- ---- <1mg/L13812-32-6

----Bicarbonate Alkalinity as CaCO3 ---- ---- ---- 2mg/L171-52-3

---- ---- ---- ---- 2mg/L1----Total Alkalinity as CaCO3


----Sulfate as SO4 - Turbidimetric ---- ---- ---- 1mg/L114808-79-8


----Chloride ---- ---- ---- <1mg/L116887-00-6


----Calcium ---- ---- ---- <1mg/L17440-70-2

----Magnesium ---- ---- ---- <1mg/L17439-95-4

----Sodium ---- ---- ---- <1mg/L17440-23-5

----Potassium ---- ---- ---- <1mg/L17440-09-7


---- ---- ---- ---- 0.06meq/L0.01----Total Anions

---- ---- ---- ---- <0.01meq/L0.01----Total Cations



(PFBS)

0.95 124 5.06 <0.02µg/L0.02375-73-5


(PFPeS)

0.22 94.4 2.90 <0.02µg/L0.022706-91-4


(PFHxS)

<0.02 243 29.5 <0.02µg/L0.02355-46-4


(PFHpS)

<0.02 <0.10 0.41 <0.02µg/L0.02375-92-8


(PFOS)

<0.01 0.28 0.45 <0.01µg/L0.011763-23-1


(PFDS)

<0.02 <0.10 <0.10 <0.02µg/L0.02335-77-3


20.9Perfluorobutanoic acid (PFBA) 0.8 21.1 4.1 <0.1µg/L0.1375-22-4


160Perfluorohexanoic acid (PFHxA) 6.56 548 37.0 <0.02µg/L0.02307-24-4


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Analytical Results

0874_QC3MW_S_180

416

0874_MW005_S_1804

16_F

0874_MW081_S_1804

16_F

0874_MW055_S_1804

16_F

0874_MW016_S_1804

16_F


(Matrix: WATER)









(PFUnDA)

<0.02 <0.10 <0.10 <0.02µg/L0.022058-94-8


(PFDoDA)

<0.02 <0.10 <0.10 <0.02µg/L0.02307-55-1


(PFTrDA)

<0.02 <0.10 <0.10 <0.02µg/L0.0272629-94-8


(PFTeDA)

<0.05 <0.25 <0.25 <0.05µg/L0.05376-06-7



(FOSA)

<0.02 <0.10 <0.10 <0.02µg/L0.02754-91-6



<0.05 <0.25 <0.25 <0.05µg/L0.0531506-32-8



<0.05 <0.25 <0.25 <0.05µg/L0.054151-50-2



<0.05 <0.25 <0.25 <0.05µg/L0.0524448-09-7



<0.05 <0.25 <0.25 <0.05µg/L0.051691-99-2



(MeFOSAA)

<0.02 <0.10 <0.10 <0.02µg/L0.022355-31-9



(EtFOSAA)

<0.02 <0.10 <0.10 <0.02µg/L0.022991-50-6



(4:2 FTS)

<0.05 <0.10 <0.10 <0.05µg/L0.05757124-72-4


(6:2 FTS)

<0.05 <0.10 <0.10 <0.05µg/L0.0527619-97-2


(8:2 FTS)

<0.05 <0.10 <0.10 <0.05µg/L0.0539108-34-4

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Analytical Results

0874_QC3MW_S_180

416

0874_MW005_S_1804

16_F

0874_MW081_S_1804

16_F

0874_MW055_S_1804

16_F

0874_MW016_S_1804

16_F


(Matrix: WATER)






(10:2 FTS)

<0.05 <0.10 <0.10 <0.05µg/L0.05120226-60-0

EP231P: PFAS Sums

265 11.2 1220 89.7 <0.01µg/L0.01----Sum of PFAS

<0.10Sum of PFHxS and PFOS <0.01 243 30.0 <0.01µg/L0.01355-46-4/1763-23-

1

261 10.9 1130 86.4 <0.01µg/L0.01----Sum of PFAS (WA DER List)


96.7 99.7 99.9 97.4 94.6%0.02----13C4-PFOS

91.8 95.5 95.3 93.0 96.9%0.02----13C8-PFOA

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Analytical Results

----0874_QC5MW_S_180

416_03

0874_QC5MW_S_180

416_02

0874_QC5MW_S_180

416_01

0874_QC4MW_S_180

416


(Matrix: WATER)






(PFBS)

<0.02 <0.02 <0.02 ----µg/L0.02375-73-5


(PFPeS)

<0.02 <0.02 <0.02 ----µg/L0.022706-91-4


(PFHxS)

<0.02 <0.02 <0.02 ----µg/L0.02355-46-4


(PFHpS)

<0.02 <0.02 <0.02 ----µg/L0.02375-92-8


(PFOS)

<0.01 <0.01 <0.01 ----µg/L0.011763-23-1


(PFDS)

<0.02 <0.02 <0.02 ----µg/L0.02335-77-3



<0.02Perfluoropentanoic acid (PFPeA) <0.02 <0.02 <0.02 ----µg/L0.022706-90-3

<0.02Perfluorohexanoic acid (PFHxA) <0.02 <0.02 <0.02 ----µg/L0.02307-24-4

<0.02Perfluoroheptanoic acid (PFHpA) <0.02 <0.02 <0.02 ----µg/L0.02375-85-9

<0.01Perfluorooctanoic acid (PFOA) <0.01 <0.01 <0.01 ----µg/L0.01335-67-1

<0.02Perfluorononanoic acid (PFNA) <0.02 <0.02 <0.02 ----µg/L0.02375-95-1

<0.02Perfluorodecanoic acid (PFDA) <0.02 <0.02 <0.02 ----µg/L0.02335-76-2


(PFUnDA)

<0.02 <0.02 <0.02 ----µg/L0.022058-94-8


(PFDoDA)

<0.02 <0.02 <0.02 ----µg/L0.02307-55-1


(PFTrDA)

<0.02 <0.02 <0.02 ----µg/L0.0272629-94-8


(PFTeDA)

<0.05 <0.05 <0.05 ----µg/L0.05376-06-7



(FOSA)

<0.02 <0.02 <0.02 ----µg/L0.02754-91-6



<0.05 <0.05 <0.05 ----µg/L0.0531506-32-8



<0.05 <0.05 <0.05 ----µg/L0.054151-50-2

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Analytical Results

----0874_QC5MW_S_180

416_03

0874_QC5MW_S_180

416_02

0874_QC5MW_S_180

416_01

0874_QC4MW_S_180

416


(Matrix: WATER)







<0.05 <0.05 <0.05 ----µg/L0.0524448-09-7



<0.05 <0.05 <0.05 ----µg/L0.051691-99-2



(MeFOSAA)

<0.02 <0.02 <0.02 ----µg/L0.022355-31-9



(EtFOSAA)

<0.02 <0.02 <0.02 ----µg/L0.022991-50-6



(4:2 FTS)

<0.05 <0.05 <0.05 ----µg/L0.05757124-72-4


(6:2 FTS)

<0.05 <0.05 <0.05 ----µg/L0.0527619-97-2


(8:2 FTS)

<0.05 <0.05 <0.05 ----µg/L0.0539108-34-4


(10:2 FTS)

<0.05 <0.05 <0.05 ----µg/L0.05120226-60-0

EP231P: PFAS Sums

<0.01 <0.01 <0.01 <0.01 ----µg/L0.01----Sum of PFAS

<0.01Sum of PFHxS and PFOS <0.01 <0.01 <0.01 ----µg/L0.01355-46-4/1763-23-

1

<0.01 <0.01 <0.01 <0.01 ----µg/L0.01----Sum of PFAS (WA DER List)


99.5 100 95.8 99.0 ----%0.02----13C4-PFOS

98.4 97.2 98.7 102 ----%0.02----13C8-PFOA

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13C4-PFOS ---- 60 130

13C8-PFOA ---- 60 130


13C4-PFOS ---- 70 130

13C8-PFOA ---- 70 130

False

7 7.00False

Environmental




:Address MOBIL

C/O GPO BOX 2907








Site : ----



















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General Comments










Key :








EA005-P: pH Value ---- 0.01 pH Unit 6.87 6.89 0.291 0% - 20%Anonymous ET1801042-001



EA010-P: Electrical Conductivity @ 25°C ---- 1 µS/cm 302 306 1.32 0% - 20%Anonymous ET1801042-001










EA045: Turbidity ---- 0.1 NTU 0.7 0.8 0.00 No LimitAnonymous ET1801051-001











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ED093F: Sodium 7440-23-5 1 mg/L 9260 9080 1.95 0% - 20%


ED093F: Calcium 7440-70-2 1 mg/L 7 6 0.00 No LimitAnonymous ET1801040-001

ED093F: Magnesium 7439-95-4 1 mg/L <1 <1 0.00 No Limit

ED093F: Sodium 7440-23-5 1 mg/L 5 5 0.00 No Limit





ED093F: Sodium 7440-23-5 1 mg/L 36 36 0.00 0% - 20%




ED093F: Sodium 7440-23-5 1 mg/L 110 108 1.53 0% - 20%



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EG020F: Dissolved Metals by ICP-MS (QC Lot: 1578079) - continued

EG020A-F: Manganese 7439-96-5 0.001 mg/L 0.044 0.044 0.00 0% - 20%Anonymous ET1801040-001

EG020A-F: Aluminium 7429-90-5 0.01 mg/L <0.01 0.01 0.00 No Limit



EG020A-F: Aluminium 7429-90-5 0.01 mg/L <0.01 <0.01 0.00 No Limit

EG020A-F: Iron 7439-89-6 0.05 mg/L <0.05 <0.05 0.00 No Limit


EG051G: Ferrous Iron ---- 0.05 mg/L <0.05 <0.05 0.00 No LimitAnonymous EB1808198-001

EG051G: Ferrous Iron ---- 0.05 mg/L <0.05 <0.05 0.00 No Limit0874_MW005_S_180416 ET1801043-018


EK040P: Fluoride 16984-48-8 0.1 mg/L 0.2 0.2 0.00 No Limit0874_MW251_S_180416 ET1801043-001

EK040P: Fluoride 16984-48-8 0.1 mg/L 0.4 0.4 0.00 No LimitAnonymous ET1801051-003

EK055G: Ammonia as N by Discrete Analyser (QC Lot: 1573391)

EK055G: Ammonia as N 7664-41-7 0.01 mg/L 0.09 0.04 78.0 No LimitAnonymous ET1801040-001

EK055G: Ammonia as N 7664-41-7 0.01 mg/L 26.9 25.7 4.30 0% - 20%Anonymous ET1801049-001


EK057G: Nitrite as N 14797-65-0 0.01 mg/L 0.61 0.62 1.70 0% - 20%Anonymous ET1801049-002

EK057G: Nitrite as N 14797-65-0 0.01 mg/L <0.01 <0.01 0.00 No LimitAnonymous ET1801042-001

EK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser (QC Lot: 1573392)

EK059G: Nitrite + Nitrate as N ---- 0.01 mg/L 0.05 0.04 0.00 No LimitAnonymous ET1801040-001









EK071G: Reactive Phosphorus as P 14265-44-2 0.01 mg/L 0.02 0.02 0.00 No Limit0874_MW251_S_180416 ET1801043-001


EP005: Total Organic Carbon ---- 1 mg/L 5 6 0.00 No Limit0874_MW251_S_180416 ET1801043-001



EP026SP: Chemical Oxygen Demand ---- 10 mg/L <100 <100 0.00 No Limit0874_MW250_S_180416 ET1801043-002


EP030: Biochemical Oxygen Demand ---- 2 mg/L <2 5 88.9 No Limit0874_MW251_S_180416 ET1801043-001



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EP231_TOP_A: Perfluoroalkyl Sulfonic Acids (QC Lot: 1582393) - continued

EP231X: Perfluorobutane sulfonic acid (PFBS) 375-73-5 0.02 µg/L 0.50 0.58 15.5 0% - 20%Anonymous ET1801059-016










EP231X: Perfluorononanoic acid (PFNA) 375-95-1 0.02 µg/L <0.02 0.02 0.00 No Limit











2355-31-9 0.02 µg/L <0.02 <0.02 0.00 No Limit



2991-50-6 0.02 µg/L <0.02 <0.02 0.00 No Limit


(MeFOSA)

31506-32-8 0.05 µg/L <0.05 <0.05 0.00 No Limit


(EtFOSA)

4151-50-2 0.05 µg/L <0.05 <0.05 0.00 No Limit



24448-09-7 0.05 µg/L <0.05 <0.05 0.00 No Limit



1691-99-2 0.05 µg/L <0.05 <0.05 0.00 No Limit



FTS)



FTS)

27619-97-2 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

39108-34-4 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

120226-60-0 0.05 µg/L <0.05 <0.05 0.00 No Limit

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23-1

0.01 µg/L 14.8 15.8 6.65 0% - 20%


C4 - C8 Sulfonates

---- 0.01 µg/L 19.5 21.0 7.47 0% - 20%








EP231X: Perfluorobutane sulfonic acid (PFBS) 375-73-5 0.02 µg/L 48.9 # 75.2 42.3 0% - 20%0874_MW109_S_180416 ET1801043-011

EP231X: Perfluoroheptane sulfonic acid (PFHpS) 375-92-8 0.02 µg/L 38.0 # 62.9 49.3 0% - 20%



EP231X: Perfluorooctane sulfonic acid (PFOS) 1763-23-1 0.01 µg/L <0.01 <0.01 0.00 No LimitAnonymous EB1809440-005






EP231X: Perfluorooctane sulfonic acid (PFOS) 1763-23-1 0.01 µg/L <0.01 <0.01 0.00 No Limit0874_QC5MW_S_180416_

03

ET1801043-029

















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EP231X: Perfluoroheptane sulfonic acid (PFHpS) 375-92-8 0.02 µg/L <0.02 <0.02 0.00 No LimitAnonymous ET1801024-015



EP231X: Perfluorooctanoic acid (PFOA) 335-67-1 0.01 µg/L 0.35 0.36 2.82 No Limit0874_MW251_S_180416 ET1801043-001











EP231X: Perfluorooctanoic acid (PFOA) 335-67-1 0.01 µg/L 39.8 37.0 7.18 0% - 20%0874_MW109_S_180416 ET1801043-011


EP231X: Perfluoroheptanoic acid (PFHpA) 375-85-9 0.02 µg/L 17.2 # 21.7 23.2 0% - 20%

EP231X: Perfluorononanoic acid (PFNA) 375-95-1 0.02 µg/L 0.22 0.19 14.6 No Limit








EP231X: Perfluorooctanoic acid (PFOA) 335-67-1 0.01 µg/L <0.01 <0.01 0.00 No LimitAnonymous EB1809440-005











EP231X: Perfluorooctanoic acid (PFOA) 335-67-1 0.01 µg/L <0.01 <0.01 0.00 No Limit0874_QC5MW_S_180416_

03

ET1801043-029



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EP231X: Perfluoroheptanoic acid (PFHpA) 375-85-9 0.02 µg/L <0.02 <0.02 0.00 No Limit0874_QC5MW_S_180416_

03

ET1801043-029



































2355-31-9 0.02 µg/L <0.10 <0.10 0.00 No Limit



2991-50-6 0.02 µg/L <0.10 <0.10 0.00 No Limit


(MeFOSA)

31506-32-8 0.05 µg/L <0.25 <0.25 0.00 No Limit

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(EtFOSA)




24448-09-7 0.05 µg/L <0.25 <0.25 0.00 No Limit



1691-99-2 0.05 µg/L <0.25 <0.25 0.00 No Limit

EP231X: Perfluorooctane sulfonamide (FOSA) 754-91-6 0.02 µg/L 0.25 0.24 4.08 No Limit0874_MW109_S_180416 ET1801043-011



2355-31-9 0.02 µg/L <0.10 <0.10 0.00 No Limit



2991-50-6 0.02 µg/L <0.10 <0.10 0.00 No Limit


(MeFOSA)

31506-32-8 0.05 µg/L <0.25 <0.25 0.00 No Limit


(EtFOSA)

4151-50-2 0.05 µg/L <0.25 <0.25 0.00 No Limit



24448-09-7 0.05 µg/L <0.25 <0.25 0.00 No Limit



1691-99-2 0.05 µg/L <0.25 <0.25 0.00 No Limit


EP231X: Perfluorooctane sulfonamide (FOSA) 754-91-6 0.02 µg/L <0.02 <0.02 0.00 No LimitAnonymous EB1809440-005



2355-31-9 0.02 µg/L <0.02 <0.02 0.00 No Limit



2991-50-6 0.02 µg/L <0.02 <0.02 0.00 No Limit


(MeFOSA)

31506-32-8 0.05 µg/L <0.05 <0.05 0.00 No Limit


(EtFOSA)

4151-50-2 0.05 µg/L <0.05 <0.05 0.00 No Limit



24448-09-7 0.05 µg/L <0.05 <0.05 0.00 No Limit



1691-99-2 0.05 µg/L <0.05 <0.05 0.00 No Limit

EP231X: Perfluorooctane sulfonamide (FOSA) 754-91-6 0.02 µg/L <0.02 <0.02 0.00 No Limit0874_QC5MW_S_180416_

03

ET1801043-029



2355-31-9 0.02 µg/L <0.02 <0.02 0.00 No Limit



2991-50-6 0.02 µg/L <0.02 <0.02 0.00 No Limit


(MeFOSA)

31506-32-8 0.05 µg/L <0.05 <0.05 0.00 No Limit

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(EtFOSA)

4151-50-2 0.05 µg/L <0.05 <0.05 0.00 No Limit0874_QC5MW_S_180416_

03

ET1801043-029



24448-09-7 0.05 µg/L <0.05 <0.05 0.00 No Limit



1691-99-2 0.05 µg/L <0.05 <0.05 0.00 No Limit





2355-31-9 0.02 µg/L <0.02 <0.02 0.00 No Limit



2991-50-6 0.02 µg/L <0.02 <0.02 0.00 No Limit


(MeFOSA)

31506-32-8 0.05 µg/L <0.05 <0.05 0.00 No Limit


(EtFOSA)

4151-50-2 0.05 µg/L <0.05 <0.05 0.00 No Limit



24448-09-7 0.05 µg/L <0.05 <0.05 0.00 No Limit



1691-99-2 0.05 µg/L <0.05 <0.05 0.00 No Limit




2355-31-9 0.02 µg/L <0.02 <0.02 0.00 No Limit



2991-50-6 0.02 µg/L <0.02 <0.02 0.00 No Limit


(MeFOSA)

31506-32-8 0.05 µg/L <0.05 <0.05 0.00 No Limit


(EtFOSA)

4151-50-2 0.05 µg/L <0.05 <0.05 0.00 No Limit



24448-09-7 0.05 µg/L <0.05 <0.05 0.00 No Limit



1691-99-2 0.05 µg/L <0.05 <0.05 0.00 No Limit



FTS)



FTS)

27619-97-2 0.05 µg/L <0.10 <0.10 0.00 No Limit


FTS)

39108-34-4 0.05 µg/L <0.10 <0.10 0.00 No Limit

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FTS)



FTS)



FTS)

27619-97-2 0.05 µg/L 6.23 6.66 6.67 0% - 20%


FTS)

39108-34-4 0.05 µg/L <0.10 <0.10 0.00 No Limit


FTS)

120226-60-0 0.05 µg/L <0.10 <0.10 0.00 No Limit



FTS)



FTS)

27619-97-2 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

39108-34-4 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

120226-60-0 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

757124-72-4 0.05 µg/L <0.05 <0.05 0.00 No Limit0874_QC5MW_S_180416_

03

ET1801043-029


FTS)

27619-97-2 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

39108-34-4 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

120226-60-0 0.05 µg/L <0.05 <0.05 0.00 No Limit



FTS)



FTS)

27619-97-2 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

39108-34-4 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

120226-60-0 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)



FTS)

27619-97-2 0.05 µg/L <0.05 <0.05 0.00 No Limit

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FTS)



FTS)

120226-60-0 0.05 µg/L <0.05 <0.05 0.00 No Limit




23-1

0.01 µg/L 17.3 17.7 1.89 0% - 20%

EP231X: Sum of PFAS (WA DER List) ---- 0.01 µg/L 25.0 25.4 1.35 0% - 20%


EP231X: Sum of PFAS ---- 0.01 µg/L <0.01 <0.01 0.00 No LimitAnonymous EB1809440-005


23-1

0.01 µg/L <0.01 <0.01 0.00 No Limit

EP231X: Sum of PFAS (WA DER List) ---- 0.01 µg/L <0.01 <0.01 0.00 No Limit

EP231X: Sum of PFAS ---- 0.01 µg/L <0.01 <0.01 0.00 No Limit0874_QC5MW_S_180416_

03

ET1801043-029


23-1

0.01 µg/L <0.01 <0.01 0.00 No Limit





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Report






---- 99.37 pH Unit 10298


EA010-P: Electrical Conductivity @ 25°C ---- 1 µS/cm <1 94.8147 µS/cm 10791

<1 10112890 µS/cm 10791



<10 1022000 mg/L 11288



<5 94.61000 mg/L 12083



<0.1 99.240 NTU 10595

<0.1 101400 NTU 10397







<1 10725 mg/L 12080



<1 11425 mg/L 12080



<1 10410 mg/L 12080



<1 97.710 mg/L 12080


ED093F: Calcium 7440-70-2 1 mg/L <1 -------- --------

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ED093F: Dissolved Major Cations (QCLot: 1578080) - continued


ED093F: Sodium 7440-23-5 1 mg/L <1 -------- --------



ED093F: Calcium 7440-70-2 1 mg/L <1 -------- --------


ED093F: Sodium 7440-23-5 1 mg/L <1 -------- --------





EG020A-F: Iron 7439-89-6 0.05 mg/L <0.05 1040.5 mg/L 11482



















<1 95.5100 mg/L 11379



<10 98.8500 mg/L 11286




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EP231_TOP_A: Perfluoroalkyl Sulfonic Acids (QCLot: 1582393) - continued





EP231X: Perfluorooctane sulfonic acid (PFOS) 1763-23-1 0.01 µg/L <0.01 1041 µg/L 15050







EP231X: Perfluorooctanoic acid (PFOA) 335-67-1 0.01 µg/L <0.01 1081 µg/L 15050












(MeFOSE)

24448-09-7 0.05 µg/L <0.05 -------- --------


(EtFOSE)

1691-99-2 0.05 µg/L <0.05 -------- --------


(MeFOSAA)

2355-31-9 0.02 µg/L <0.02 -------- --------


(EtFOSAA)

2991-50-6 0.02 µg/L <0.02 -------- --------









63-23-1

0.01 µg/L <0.01 -------- --------

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EP231_TOP_P: PFAS Sums (QCLot: 1582393) - continued


Sulfonates

---- 0.01 µg/L <0.01 -------- --------
























EP231X: Perfluoropentanoic acid (PFPeA) 2706-90-3 0.02 µg/L <0.02 97.20.5 µg/L 13070



EP231X: Perfluorooctanoic acid (PFOA) 335-67-1 0.01 µg/L <0.01 98.40.5 µg/L 13070


EP231X: Perfluorodecanoic acid (PFDA) 335-76-2 0.02 µg/L <0.02 80.20.5 µg/L 13070








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EP231X: N-Methyl perfluorooctane sulfonamide (MeFOSA) 31506-32-8 0.05 µg/L <0.05 93.01.25 µg/L 13070



(MeFOSE)

24448-09-7 0.05 µg/L <0.05 1081.25 µg/L 13070


(EtFOSE)

1691-99-2 0.05 µg/L <0.05 99.71.25 µg/L 13070


(MeFOSAA)

2355-31-9 0.02 µg/L <0.02 1020.5 µg/L 13070


(EtFOSAA)

2991-50-6 0.02 µg/L <0.02 1000.5 µg/L 13070






(MeFOSE)

24448-09-7 0.05 µg/L <0.05 96.91.25 µg/L 13070

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(EtFOSE)

1691-99-2 0.05 µg/L <0.05 1041.25 µg/L 13070


(MeFOSAA)

2355-31-9 0.02 µg/L <0.02 1050.5 µg/L 13070


(EtFOSAA)

2991-50-6 0.02 µg/L <0.02 98.20.5 µg/L 13070






(MeFOSE)

24448-09-7 0.05 µg/L <0.05 1021.25 µg/L 15070


(EtFOSE)

1691-99-2 0.05 µg/L <0.05 1031.25 µg/L 15070


(MeFOSAA)

2355-31-9 0.02 µg/L <0.02 1210.5 µg/L 13070


(EtFOSAA)

2991-50-6 0.02 µg/L <0.02 1130.5 µg/L 13070



















63-23-1

0.01 µg/L <0.01 -------- --------

EP231X: Sum of PFAS (WA DER List) ---- 0.01 µg/L <0.01 -------- --------

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63-23-1

0.01 µg/L <0.01 -------- --------











Determined

20 mg/L 13070









Anonymous EB1808198-002 ----EG051G: Ferrous Iron 1002 mg/L 13070


0874_MW250_S_180416 ET1801043-002 16984-48-8EK040P: Fluoride 1041.92 mg/L 12080


Anonymous ET1801040-002 7664-41-7EK055G: Ammonia as N 78.30.4 mg/L 13070


Anonymous ET1801042-002 14797-65-0EK057G: Nitrite as N 1010.4 mg/L 13070


Anonymous ET1801040-002 ----EK059G: Nitrite + Nitrate as N 79.20.4 mg/L 13070


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EK061G: Total Kjeldahl Nitrogen By Discrete Analyser (QCLot: 1580823) - continued





0874_MW250_S_180416 ET1801043-002 14265-44-2EK071G: Reactive Phosphorus as P 1090.4 mg/L 13070


0874_MW250_S_180416 ET1801043-002 ----EP005: Total Organic Carbon 94.7100 mg/L 13070




0874_MW250_S_180416 ET1801043-002 375-73-5EP231X: Perfluorobutane sulfonic acid (PFBS) 90.62.5 µg/L 13070


355-46-4EP231X: Perfluorohexane sulfonic acid (PFHxS) # Not

Determined

2.5 µg/L 13070



Determined

2.5 µg/L 13070



Anonymous EB1809440-006 375-73-5EP231X: Perfluorobutane sulfonic acid (PFBS) 93.20.5 µg/L 13070














0874_MW250_S_180416 ET1801043-002 375-22-4EP231X: Perfluorobutanoic acid (PFBA) 96.712.5 µg/L 13070



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0874_MW250_S_180416 ET1801043-002 375-85-9EP231X: Perfluoroheptanoic acid (PFHpA) 95.02.5 µg/L 13070

335-67-1EP231X: Perfluorooctanoic acid (PFOA) 94.62.5 µg/L 13070








Anonymous EB1809440-006 375-22-4EP231X: Perfluorobutanoic acid (PFBA) 97.72.5 µg/L 13070
























0874_MW250_S_180416 ET1801043-002 754-91-6EP231X: Perfluorooctane sulfonamide (FOSA) 1222.5 µg/L 13070


(MeFOSA)

84.86.25 µg/L 13070


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0874_MW250_S_180416 ET1801043-002 24448-09-7EP231X: N-Methyl perfluorooctane sulfonamidoethanol

(MeFOSE)

1026.25 µg/L 13070


(EtFOSE)

1066.25 µg/L 13070


acid (MeFOSAA)

1072.5 µg/L 13070


acid (EtFOSAA)

99.22.5 µg/L 13070


Anonymous EB1809440-006 754-91-6EP231X: Perfluorooctane sulfonamide (FOSA) 1290.5 µg/L 13070


(MeFOSA)

93.51.25 µg/L 13070



(MeFOSE)

97.81.25 µg/L 13070


(EtFOSE)

98.31.25 µg/L 13070


acid (MeFOSAA)

1050.5 µg/L 13070


acid (EtFOSAA)

98.80.5 µg/L 13070


Anonymous ET1801011-010 754-91-6EP231X: Perfluorooctane sulfonamide (FOSA) 88.40.5 µg/L 13050


(MeFOSA)

1121.25 µg/L 15050



(MeFOSE)

1181.25 µg/L 15050


(EtFOSE)

1111.25 µg/L 15050


acid (MeFOSAA)

1180.5 µg/L 13050


acid (EtFOSAA)

75.20.5 µg/L 13050


0874_MW250_S_180416 ET1801043-002 757124-72-4EP231X: 4:2 Fluorotelomer sulfonic acid (4:2 FTS) 1002.5 µg/L 13070




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Anonymous EB1809440-006 757124-72-4EP231X: 4:2 Fluorotelomer sulfonic acid (4:2 FTS) 1030.5 µg/L 13070









True

Environmental












Summary of Outliers





l Duplicate outliers exist - please see following pages for full details.








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Matrix: WATER


Duplicate (DUP) RPDs



0874_MW109_S_180416 RPD exceeds LOR based limits0% - 20%42.3 %EP231A: Perfluoroalkyl Sulfonic Acids


sulfonic acid

(PFHpS)

0874_MW109_S_180416 RPD exceeds LOR based limits0% - 20%49.3 %EP231A: Perfluoroalkyl Sulfonic Acids


acid (PFHpA)

0874_MW109_S_180416 RPD exceeds LOR based limits0% - 20%23.2 %EP231B: Perfluoroalkyl Carboxylic Acids


ET1801043--005 14808-79-8Sulfate as SO4 -

Turbidimetric




----Not

Determined



sulfonic acid

(PFHxS)




----Not

Determined







----Not

Determined



Matrix: WATER



overdue

Days

overdue


Method



16-Apr-2018----0874_MW251_S_180416, 0874_MW250_S_180416,

0874_MW016_S_180416, 0874_MW055_S_180416,

0874_MW081_S_180416, 0874_MW005_S_180416

17-Apr-2018---- ---- 1



17-Apr-2018----0874_MW251_S_180416, 0874_MW250_S_180416,

0874_MW016_S_180416, 0874_MW055_S_180416,

0874_MW081_S_180416, 0874_MW005_S_180416

18-Apr-2018---- ---- 1

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0874_MW251_S_180416, 0874_MW250_S_180416,

0874_MW016_S_180416, 0874_MW055_S_180416,

0874_MW081_S_180416, 0874_MW005_S_180416

16-Apr-2018---- 17-Apr-2018----16-Apr-2018 ---- û



0874_MW251_S_180416, 0874_MW250_S_180416,

0874_MW016_S_180416, 0874_MW055_S_180416,

0874_MW081_S_180416, 0874_MW005_S_180416

14-May-2018---- 19-Apr-2018----16-Apr-2018 ---- ü



0874_MW251_S_180416, 0874_MW250_S_180416,

0874_MW016_S_180416, 0874_MW055_S_180416,

0874_MW081_S_180416, 0874_MW005_S_180416

14-May-2018---- 17-Apr-2018----16-Apr-2018 ---- ü



0874_MW251_S_180416, 0874_MW250_S_180416,

0874_MW016_S_180416, 0874_MW055_S_180416,

0874_MW081_S_180416, 0874_MW005_S_180416

23-Apr-2018---- 17-Apr-2018----16-Apr-2018 ---- ü



0874_MW251_S_180416, 0874_MW250_S_180416,

0874_MW016_S_180416, 0874_MW055_S_180416,

0874_MW081_S_180416, 0874_MW005_S_180416

23-Apr-2018---- 17-Apr-2018----16-Apr-2018 ---- ü

EA045: Turbidity


0874_MW251_S_180416, 0874_MW250_S_180416,

0874_MW016_S_180416, 0874_MW055_S_180416,

0874_MW081_S_180416, 0874_MW005_S_180416

18-Apr-2018---- 17-Apr-2018----16-Apr-2018 ---- ü

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0874_MW251_S_180416, 0874_MW250_S_180416,

0874_MW016_S_180416, 0874_MW055_S_180416,

0874_MW081_S_180416, 0874_MW005_S_180416

14-May-2018---- 19-Apr-2018----16-Apr-2018 ---- ü



0874_MW251_S_180416, 0874_MW250_S_180416,

0874_MW016_S_180416, 0874_MW015_S_180416,

0874_MW021_S_180416, 0874_MW110_S_180416,

0874_MW055_S_180416, 0874_MW054_S_180416,

0874_MW138_S_180416, 0874_MW139_S_180416,

0874_MW109_S_180416, 0874_MW081_S_180416,

0874_MW046_S_180416, 0874_MW090_S_180416,

0874_MW112_S_180416, 0874_MW057_S_180416,

0874_MW206_S_180416, 0874_MW005_S_180416,

0874_QC3MW_S_180416

30-Apr-2018---- 17-Apr-2018----16-Apr-2018 ---- ü



0874_MW251_S_180416, 0874_MW250_S_180416,

0874_MW016_S_180416, 0874_MW015_S_180416,

0874_MW021_S_180416, 0874_MW110_S_180416,

0874_MW055_S_180416, 0874_MW054_S_180416,

0874_MW138_S_180416, 0874_MW139_S_180416,

0874_MW109_S_180416, 0874_MW081_S_180416,

0874_MW046_S_180416, 0874_MW090_S_180416,

0874_MW112_S_180416, 0874_MW057_S_180416,

0874_MW206_S_180416, 0874_MW005_S_180416,

0874_QC3MW_S_180416

14-May-2018---- 17-Apr-2018----16-Apr-2018 ---- ü



0874_MW251_S_180416, 0874_MW250_S_180416,

0874_MW016_S_180416, 0874_MW015_S_180416,

0874_MW021_S_180416, 0874_MW110_S_180416,

0874_MW055_S_180416, 0874_MW054_S_180416,

0874_MW138_S_180416, 0874_MW139_S_180416,

0874_MW109_S_180416, 0874_MW081_S_180416,

0874_MW046_S_180416, 0874_MW090_S_180416,

0874_MW112_S_180416, 0874_MW057_S_180416,

0874_MW206_S_180416, 0874_MW005_S_180416,

0874_QC3MW_S_180416

14-May-2018---- 17-Apr-2018----16-Apr-2018 ---- ü

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0874_MW251_S_180416, 0874_MW250_S_180416,

0874_MW016_S_180416, 0874_MW055_S_180416,

0874_MW081_S_180416, 0874_MW005_S_180416

14-May-2018---- 19-Apr-2018----16-Apr-2018 ---- ü


0874_MW015_S_180416, 0874_MW021_S_180416,

0874_MW110_S_180416, 0874_MW054_S_180416,

0874_MW138_S_180416, 0874_MW139_S_180416,

0874_MW109_S_180416, 0874_MW046_S_180416,

0874_MW090_S_180416, 0874_MW112_S_180416,

0874_MW057_S_180416, 0874_MW206_S_180416,

0874_QC3MW_S_180416

23-Apr-2018---- 19-Apr-2018----16-Apr-2018 ---- ü



0874_MW251_S_180416, 0874_MW250_S_180416,

0874_MW016_S_180416, 0874_MW055_S_180416,

0874_MW081_S_180416, 0874_MW005_S_180416

13-Oct-2018---- 19-Apr-2018----16-Apr-2018 ---- ü



0874_MW251_S_180416, 0874_MW250_S_180416,

0874_MW016_S_180416, 0874_MW055_S_180416,

0874_MW081_S_180416, 0874_MW005_S_180416

17-Apr-2018---- 18-Apr-2018----16-Apr-2018 ---- û



0874_MW251_S_180416, 0874_MW250_S_180416,

0874_MW016_S_180416, 0874_MW055_S_180416,

0874_MW081_S_180416, 0874_MW005_S_180416

14-May-2018---- 17-Apr-2018----16-Apr-2018 ---- ü



0874_MW251_S_180416, 0874_MW250_S_180416,

0874_MW016_S_180416, 0874_MW055_S_180416,

0874_MW081_S_180416, 0874_MW005_S_180416

14-May-2018---- 17-Apr-2018----16-Apr-2018 ---- ü



0874_MW251_S_180416, 0874_MW250_S_180416,

0874_MW016_S_180416, 0874_MW055_S_180416,

0874_MW081_S_180416, 0874_MW005_S_180416

18-Apr-2018---- 17-Apr-2018----16-Apr-2018 ---- ü

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0874_MW251_S_180416, 0874_MW250_S_180416,

0874_MW016_S_180416, 0874_MW055_S_180416,

0874_MW081_S_180416, 0874_MW005_S_180416

14-May-2018---- 17-Apr-2018----16-Apr-2018 ---- ü



0874_MW251_S_180416, 0874_MW250_S_180416,

0874_MW016_S_180416, 0874_MW055_S_180416,

0874_MW081_S_180416, 0874_MW005_S_180416

14-May-201814-May-2018 20-Apr-201820-Apr-201816-Apr-2018 ü ü



0874_MW251_S_180416, 0874_MW250_S_180416,

0874_MW016_S_180416, 0874_MW055_S_180416,

0874_MW081_S_180416, 0874_MW005_S_180416




0874_MW251_S_180416, 0874_MW250_S_180416,

0874_MW016_S_180416, 0874_MW055_S_180416,

0874_MW081_S_180416, 0874_MW005_S_180416

18-Apr-2018---- 17-Apr-2018----16-Apr-2018 ---- ü



0874_MW251_S_180416, 0874_MW250_S_180416,

0874_MW016_S_180416, 0874_MW055_S_180416,

0874_MW081_S_180416, 0874_MW005_S_180416

14-May-2018---- 18-Apr-2018----16-Apr-2018 ---- ü



0874_MW251_S_180416, 0874_MW250_S_180416,

0874_MW016_S_180416, 0874_MW055_S_180416,

0874_MW081_S_180416, 0874_MW005_S_180416

14-May-2018---- 23-Apr-2018----16-Apr-2018 ---- ü



0874_MW251_S_180416, 0874_MW250_S_180416,

0874_MW016_S_180416, 0874_MW055_S_180416,

0874_MW081_S_180416, 0874_MW005_S_180416

18-Apr-2018---- 18-Apr-2018----16-Apr-2018 ---- ü



0874_MW109_S_180416, 0874_MW081_S_180416 13-Oct-201813-Oct-2018 22-Apr-201822-Apr-201816-Apr-2018 ü üEP231_TOP_B: Perfluoroalkyl Carboxylic Acids


0874_MW109_S_180416, 0874_MW081_S_180416 13-Oct-201813-Oct-2018 22-Apr-201822-Apr-201816-Apr-2018 ü ü

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0874_MW109_S_180416, 0874_MW081_S_180416 13-Oct-201813-Oct-2018 22-Apr-201822-Apr-201816-Apr-2018 ü üEP231_TOP_D: (n:2) Fluorotelomer Sulfonic Acids


0874_MW109_S_180416, 0874_MW081_S_180416 13-Oct-201813-Oct-2018 22-Apr-201822-Apr-201816-Apr-2018 ü üEP231_TOP_P: PFAS Sums


0874_MW109_S_180416, 0874_MW081_S_180416 13-Oct-201813-Oct-2018 22-Apr-201822-Apr-201816-Apr-2018 ü üEP231A: Perfluoroalkyl Sulfonic Acids


0874_MW251_S_180416, 0874_MW250_S_180416,

0874_MW016_S_180416, 0874_MW015_S_180416,

0874_MW021_S_180416, 0874_MW110_S_180416,

0874_MW055_S_180416, 0874_MW054_S_180416,

0874_MW138_S_180416, 0874_MW139_S_180416,

0874_MW109_S_180416, 0874_MW046_S_180416,

0874_MW090_S_180416, 0874_MW112_S_180416,

0874_MW057_S_180416, 0874_MW206_S_180416,

0874_MW005_S_180416, 0874_MW251_S_180416_F,

0874_MW250_S_180416_F, 0874_MW016_S_180416_F,

0874_MW055_S_180416_F, 0874_MW081_S_180416_F,

0874_MW005_S_180416_F, 0874_QC3MW_S_180416,

0874_QC4MW_S_180416, 0874_QC5MW_S_180416_01,

0874_QC5MW_S_180416_02, 0874_QC5MW_S_180416_03

13-Oct-2018---- 19-Apr-2018----16-Apr-2018 ---- ü


0874_MW081_S_180416 13-Oct-2018---- 23-Apr-2018----16-Apr-2018 ---- ü

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0874_MW251_S_180416, 0874_MW250_S_180416,

0874_MW016_S_180416, 0874_MW015_S_180416,

0874_MW021_S_180416, 0874_MW110_S_180416,

0874_MW055_S_180416, 0874_MW054_S_180416,

0874_MW138_S_180416, 0874_MW139_S_180416,

0874_MW109_S_180416, 0874_MW046_S_180416,

0874_MW090_S_180416, 0874_MW112_S_180416,

0874_MW057_S_180416, 0874_MW206_S_180416,

0874_MW005_S_180416, 0874_MW251_S_180416_F,

0874_MW250_S_180416_F, 0874_MW016_S_180416_F,

0874_MW055_S_180416_F, 0874_MW081_S_180416_F,

0874_MW005_S_180416_F, 0874_QC3MW_S_180416,

0874_QC4MW_S_180416, 0874_QC5MW_S_180416_01,

0874_QC5MW_S_180416_02, 0874_QC5MW_S_180416_03

13-Oct-2018---- 19-Apr-2018----16-Apr-2018 ---- ü


0874_MW081_S_180416 13-Oct-2018---- 23-Apr-2018----16-Apr-2018 ---- üEP231C: Perfluoroalkyl Sulfonamides


0874_MW251_S_180416, 0874_MW250_S_180416,

0874_MW016_S_180416, 0874_MW015_S_180416,

0874_MW021_S_180416, 0874_MW110_S_180416,

0874_MW055_S_180416, 0874_MW054_S_180416,

0874_MW138_S_180416, 0874_MW139_S_180416,

0874_MW109_S_180416, 0874_MW046_S_180416,

0874_MW090_S_180416, 0874_MW112_S_180416,

0874_MW057_S_180416, 0874_MW206_S_180416,

0874_MW005_S_180416, 0874_MW251_S_180416_F,

0874_MW250_S_180416_F, 0874_MW016_S_180416_F,

0874_MW055_S_180416_F, 0874_MW081_S_180416_F,

0874_MW005_S_180416_F, 0874_QC3MW_S_180416,

0874_QC4MW_S_180416, 0874_QC5MW_S_180416_01,

0874_QC5MW_S_180416_02, 0874_QC5MW_S_180416_03

13-Oct-2018---- 19-Apr-2018----16-Apr-2018 ---- ü


0874_MW081_S_180416 13-Oct-2018---- 23-Apr-2018----16-Apr-2018 ---- ü

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0874_MW251_S_180416, 0874_MW250_S_180416,

0874_MW016_S_180416, 0874_MW015_S_180416,

0874_MW021_S_180416, 0874_MW110_S_180416,

0874_MW055_S_180416, 0874_MW054_S_180416,

0874_MW138_S_180416, 0874_MW139_S_180416,

0874_MW109_S_180416, 0874_MW046_S_180416,

0874_MW090_S_180416, 0874_MW112_S_180416,

0874_MW057_S_180416, 0874_MW206_S_180416,

0874_MW005_S_180416, 0874_MW251_S_180416_F,

0874_MW250_S_180416_F, 0874_MW016_S_180416_F,

0874_MW055_S_180416_F, 0874_MW081_S_180416_F,

0874_MW005_S_180416_F, 0874_QC3MW_S_180416,

0874_QC4MW_S_180416, 0874_QC5MW_S_180416_01,

0874_QC5MW_S_180416_02, 0874_QC5MW_S_180416_03

13-Oct-2018---- 19-Apr-2018----16-Apr-2018 ---- ü


0874_MW081_S_180416 13-Oct-2018---- 23-Apr-2018----16-Apr-2018 ---- üEP231P: PFAS Sums


0874_MW251_S_180416, 0874_MW250_S_180416,

0874_MW016_S_180416, 0874_MW015_S_180416,

0874_MW021_S_180416, 0874_MW110_S_180416,

0874_MW055_S_180416, 0874_MW054_S_180416,

0874_MW138_S_180416, 0874_MW139_S_180416,

0874_MW109_S_180416, 0874_MW046_S_180416,

0874_MW090_S_180416, 0874_MW112_S_180416,

0874_MW057_S_180416, 0874_MW206_S_180416,

0874_MW005_S_180416, 0874_MW251_S_180416_F,

0874_MW250_S_180416_F, 0874_MW016_S_180416_F,

0874_MW055_S_180416_F, 0874_MW081_S_180416_F,

0874_MW005_S_180416_F, 0874_QC3MW_S_180416,

0874_QC4MW_S_180416, 0874_QC5MW_S_180416_01,

0874_QC5MW_S_180416_02, 0874_QC5MW_S_180416_03

13-Oct-2018---- 19-Apr-2018----16-Apr-2018 ---- ü


0874_MW081_S_180416 13-Oct-2018---- 23-Apr-2018----16-Apr-2018 ---- ü

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Method Blanks (MB)






















Matrix Spikes (MS)








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Schedule B(3)





Conductivity)

EA016 WATER









Schedule B(3)







Discrete Analyser

ED041G WATER











Schedule B(3)


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Schedule B(3)


Analyser

EK059G WATER





Analyser

EK061G WATER


B(3)


Discrete Analyser

EK062G WATER





Schedule B(3)


Analyser

EK067G WATER






Analyser

EK071G WATER


DA

EN055 - PG WATER




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EP026SP WATER






B(3)











(PFAS) by LCMSMS

EP231X WATER












Schedule B(3)




pp. 9342¿9349:


EP231.


PFAS

* ORG70-W WATER

Environmental





C/O GPO BOX 2907



QLD AUSTRALIA 4814






V4)


Site : ----




Date

26-Apr-2018


No. of coolers/boxes : :3 Temperature 14.7, 12.1, 13.5°C - Ice

present


General Comments






l It has been noted that a bottle submitted for metals analysis for ALS sample #18 was not marked

in the appropriate box as ‘field filtered’ or ‘unfiltered’, as such your container has been logged as

‘unspecified’ and no analysis assigned. An aliquot has been split and filtered into another Red

Green bottle for dissolved metals analysis. Please note for future submissions the importance of

marking the appropriate box on the sample bottle label.l Please be advised that the container for ALS sample #10 is labelled as '0874_MW139_S_180416'

instead of '0874_MW129_S_180416' as per the COC. The sample ID in the container has been

assigned as confirmed by Jack McBain via phone call 17.4.18.l Discounted Package Prices apply only when specific ALS Group Codes ('W', 'S', 'NT' suites) are referenced on COCs.



l EP231X (TOP) conducted by ALS Sydney, NATA accreditation no. 825, site no 10911.l Please direct any turn around / technical queries to the laboratory contact designated above.


l Samples submitted for dissolved metals analysis should be field filtered. Additional charges of $5.00 will apply to each sample

requiring laboratory filtration.










ET1801043-019 : [ 16-Apr-2018 ] : 0874_MW251_S_180416_F

ET1801043-020 : [ 16-Apr-2018 ] : 0874_MW250_S_180416_F

ET1801043-021 : [ 16-Apr-2018 ] : 0874_MW016_S_180416_F

ET1801043-022 : [ 16-Apr-2018 ] : 0874_MW055_S_180416_F

ET1801043-023 : [ 16-Apr-2018 ] : 0874_MW081_S_180416_F

ET1801043-024 : [ 16-Apr-2018 ] : 0874_MW005_S_180416_F

ET1801043-027 : [ 16-Apr-2018 ] : 0874_QC5MW_S_180416_01

ET1801043-028 : [ 16-Apr-2018 ] : 0874_QC5MW_S_180416_02

ET1801043-029 : [ 16-Apr-2018 ] : 0874_QC5MW_S_180416_03











component

WA

TE

R -

EG

02

0F

Dis

solv

ed

Me

tals

by

ICP

/MS

WA

TE

R -

EG

05

1G

Fe

rro

us

Iro

n

WA

TE

R -

EP

02

6S

P

Ch

em

ica

l Oxy

ge

n D

em

an

d (

CO

D)

WA

TE

R -

EP

03

0

BO

D

WA

TE

R -

EP

23

1X

PF

AS

- F

ull

Su

ite (

28

an

aly

tes)

WA

TE

R -

NT

-01

& 0

2

Ca

, M

g, N

a, K

, C

l, S

O4

, A

lka

linity

WA

TE

R -

NT

-14

Ext

en

de

d W

ate

r S

uite

B

ET1801043-001 16-Apr-2018 00:00 0874_MW251_S_180416 ü ü ü ü ü ü ü



ET1801043-004 16-Apr-2018 00:00 0874_MW015_S_180416 ü ü

ET1801043-005 16-Apr-2018 00:00 0874_MW021_S_180416 ü ü

ET1801043-006 16-Apr-2018 00:00 0874_MW110_S_180416 ü ü


ET1801043-008 16-Apr-2018 00:00 0874_MW054_S_180416 ü ü

ET1801043-009 16-Apr-2018 00:00 0874_MW138_S_180416 ü ü

ET1801043-010 16-Apr-2018 00:00 0874_MW139_S_180416 ü ü

ET1801043-011 16-Apr-2018 00:00 0874_MW109_S_180416 ü ü


ET1801043-013 16-Apr-2018 00:00 0874_MW046_S_180416 ü ü

ET1801043-014 16-Apr-2018 00:00 0874_MW090_S_180416 ü ü

ET1801043-015 16-Apr-2018 00:00 0874_MW112_S_180416 ü ü

ET1801043-016 16-Apr-2018 00:00 0874_MW057_S_180416 ü ü

ET1801043-017 16-Apr-2018 00:00 0874_MW206_S_180416 ü ü


ET1801043-019 16-Apr-2018 00:00 0874_MW251_S_180416_F ü

ET1801043-020 16-Apr-2018 00:00 0874_MW250_S_180416_F ü

ET1801043-021 16-Apr-2018 00:00 0874_MW016_S_180416_F ü

ET1801043-022 16-Apr-2018 00:00 0874_MW055_S_180416_F ü

ET1801043-023 16-Apr-2018 00:00 0874_MW081_S_180416_F ü

ET1801043-024 16-Apr-2018 00:00 0874_MW005_S_180416_F ü

ET1801043-025 16-Apr-2018 00:00 0874_QC3MW_S_180416 ü ü

ET1801043-026 16-Apr-2018 00:00 0874_QC4MW_S_180416 ü

Matrix: WATER


ID

Client sampling

date / time




WA

TE

R -

EG

020F

Dis

solv

ed

Me

tals

by

ICP

/MS

WA

TE

R -

EG

051G

Ferr

ou

s Ir

on

WA

TE

R -

EP

02

6S

P

Che

mic

al O

xyg

en D

em

an

d (

CO

D)

WA

TE

R -

EP

03

0

BO

D

WA

TE

R -

EP

23

1X

PF

AS

- F

ull

Suite

(28 a

naly

tes)

WA

TE

R -

NT

-01 &

02

Ca,

Mg,

Na,

K, C

l, S

O4,

Alk

alin

ity

WA

TE

R -

NT

-14

Ext

ende

d W

ate

r S

uite

B

ET1801043-027 16-Apr-2018 00:00 0874_QC5MW_S_180416_ ü

ET1801043-028 16-Apr-2018 00:00 0874_QC5MW_S_180416_ ü

ET1801043-029 16-Apr-2018 00:00 0874_QC5MW_S_180416_ ü

WA

TE

R -

EA

01

5H

To

tal D

isso

lve

d S

olid

s -

Sta

nd

ard

Le

vel

WA

TE

R -

EA

02

5H

Su

spe

nd

ed

So

lids

- S

tan

da

rd L

eve

l

WA

TE

R -

EA

04

5

Tu

rbid

ity

WA

TE

R -

EP

00

5

To

tal O

rga

nic

Ca

rbo

n (

TO

C)

WA

TE

R -

EP

23

1X

(T

OP

)

PF

AS

- T

ota

l Oxi

dis

ab

le P

recu

rso

r (T

OP

) A

ssay

ET1801043-001 16-Apr-2018 00:00 0874_MW251_S_180416 ü ü ü ü

ET1801043-002 16-Apr-2018 00:00 0874_MW250_S_180416 ü ü ü ü

ET1801043-003 16-Apr-2018 00:00 0874_MW016_S_180416 ü ü ü ü

ET1801043-007 16-Apr-2018 00:00 0874_MW055_S_180416 ü ü ü ü

ET1801043-011 16-Apr-2018 00:00 0874_MW109_S_180416 ü

ET1801043-012 16-Apr-2018 00:00 0874_MW081_S_180416 ü ü ü ü ü

ET1801043-018 16-Apr-2018 00:00 0874_MW005_S_180416 ü ü ü ü

Matrix: WATER


ID

Client sampling

date / time







AU ACCOUNTS PAYABLE


DAVID HARRIS








DERP LABREPORTS


PHIL SCHULZ









RESULTS RESULTS








0 0.00 True

Environmental





C/O GPO BOX 2907








Site : ----






l General Comments












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General Comments







purposes.







Key :

EP005: Results for sample '0874_SW102_180416' may bias low due to large amounts of sediment. The sample was decanted before analysis.l


23313)

l


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Analytical Results

------------0874_SW102_180416

_F

0874_SW102_180416Client sample IDSub-Matrix: WATER

(Matrix: WATER)





6.92 ---- ---- ---- ----pH Unit0.01----pH Value


7.31^ ---- ---- ---- -----0.01----Sodium Adsorption Ratio


1700 ---- ---- ---- ----µS/cm1----Electrical Conductivity @ 25°C


1040 ---- ---- ---- ----mg/L10----Total Dissolved Solids @180°C


1100 ---- ---- ---- ----mg/L1----Total Dissolved Solids (Calc.)


150 ---- ---- ---- ----mg/L5----Suspended Solids (SS)

EA045: Turbidity

31.8 ---- ---- ---- ----NTU0.1----Turbidity


251 ---- ---- ---- ----mg/L1----Total Hardness as CaCO3


<1Hydroxide Alkalinity as CaCO3 ---- ---- ---- ----mg/L1DMO-210-001

<1Carbonate Alkalinity as CaCO3 ---- ---- ---- ----mg/L13812-32-6

127Bicarbonate Alkalinity as CaCO3 ---- ---- ---- ----mg/L171-52-3

127 ---- ---- ---- ----mg/L1----Total Alkalinity as CaCO3


19Sulfate as SO4 - Turbidimetric ---- ---- ---- ----mg/L114808-79-8


470Chloride ---- ---- ---- ----mg/L116887-00-6


46Calcium ---- ---- ---- ----mg/L17440-70-2

33Magnesium ---- ---- ---- ----mg/L17439-95-4

266Sodium ---- ---- ---- ----mg/L17440-23-5

11Potassium ---- ---- ---- ----mg/L17440-09-7


0.02Aluminium ---- ---- ---- ----mg/L0.017429-90-5

0.559Manganese ---- ---- ---- ----mg/L0.0017439-96-5

0.59Iron ---- ---- ---- ----mg/L0.057439-89-6

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Analytical Results

------------0874_SW102_180416

_F


(Matrix: WATER)





0.62 ---- ---- ---- ----mg/L0.05----Ferrous Iron


<0.1Fluoride ---- ---- ---- ----mg/L0.116984-48-8


0.08Ammonia as N ---- ---- ---- ----mg/L0.017664-41-7


<0.01Nitrite as N ---- ---- ---- ----mg/L0.0114797-65-0


0.03Nitrate as N ---- ---- ---- ----mg/L0.0114797-55-8


0.03 ---- ---- ---- ----mg/L0.01----Nitrite + Nitrate as N


2.4 ---- ---- ---- ----mg/L0.1----Total Kjeldahl Nitrogen as N


2.4^ ---- ---- ---- ----mg/L0.1----Total Nitrogen as N


0.29 ---- ---- ---- ----mg/L0.01----Total Phosphorus as P


0.15Reactive Phosphorus as P ---- ---- ---- ----mg/L0.0114265-44-2


16.2 ---- ---- ---- ----meq/L0.01----Total Anions

16.9 ---- ---- ---- ----meq/L0.01----Total Cations

2.03 ---- ---- ---- ----%0.01----Ionic Balance


22 ---- ---- ---- ----mg/L1----Total Organic Carbon


86 ---- ---- ---- ----mg/L10----Chemical Oxygen Demand


11 ---- ---- ---- ----mg/L2----Biochemical Oxygen Demand



(PFBS)

<0.02 ---- ---- ----µg/L0.02375-73-5

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Analytical Results

------------0874_SW102_180416

_F


(Matrix: WATER)






(PFPeS)

<0.02 ---- ---- ----µg/L0.022706-91-4


(PFHxS)

<0.02 ---- ---- ----µg/L0.02355-46-4


(PFHpS)

<0.02 ---- ---- ----µg/L0.02375-92-8


(PFOS)

<0.01 ---- ---- ----µg/L0.011763-23-1


(PFDS)

<0.02 ---- ---- ----µg/L0.02335-77-3










(PFUnDA)

<0.02 ---- ---- ----µg/L0.022058-94-8


(PFDoDA)

<0.02 ---- ---- ----µg/L0.02307-55-1


(PFTrDA)

<0.02 ---- ---- ----µg/L0.0272629-94-8


(PFTeDA)

<0.05 ---- ---- ----µg/L0.05376-06-7



(FOSA)

<0.02 ---- ---- ----µg/L0.02754-91-6



<0.05 ---- ---- ----µg/L0.0531506-32-8



<0.05 ---- ---- ----µg/L0.054151-50-2



<0.05 ---- ---- ----µg/L0.0524448-09-7

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Analytical Results

------------0874_SW102_180416

_F


(Matrix: WATER)







<0.05 ---- ---- ----µg/L0.051691-99-2



(MeFOSAA)

<0.02 ---- ---- ----µg/L0.022355-31-9



(EtFOSAA)

<0.02 ---- ---- ----µg/L0.022991-50-6



(4:2 FTS)

<0.05 ---- ---- ----µg/L0.05757124-72-4


(6:2 FTS)

<0.05 ---- ---- ----µg/L0.0527619-97-2


(8:2 FTS)

<0.05 ---- ---- ----µg/L0.0539108-34-4


(10:2 FTS)

<0.05 ---- ---- ----µg/L0.05120226-60-0

EP231P: PFAS Sums

1.82 0.19 ---- ---- ----µg/L0.01----Sum of PFAS

1.38Sum of PFHxS and PFOS <0.01 ---- ---- ----µg/L0.01355-46-4/1763-23-

1



95.5 100 ---- ---- ----%0.02----13C4-PFOS

94.5 94.7 ---- ---- ----%0.02----13C8-PFOA

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13C4-PFOS ---- 70 130

13C8-PFOA ---- 70 130

False

4 4.00True

Environmental




:Address MOBIL

C/O GPO BOX 2907








Site : ----
















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General Comments










Key :





















EA045: Turbidity ---- 0.1 NTU 0.7 0.8 0.00 No LimitAnonymous ET1801051-001











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ED041G: Sulfate (Turbidimetric) as SO4 2- by DA (QC Lot: 1572903) - continued









ED093F: Sodium 7440-23-5 1 mg/L 38 40 7.69 0% - 20%




ED093F: Sodium 7440-23-5 1 mg/L 102 100 2.12 0% - 20%






EG020A-F: Manganese 7439-96-5 0.001 mg/L <0.001 <0.001 0.00 No LimitAnonymous ET1801041-001




EG051G: Ferrous Iron ---- 0.05 mg/L <0.05 <0.05 0.00 No LimitAnonymous EB1808198-001

EG051G: Ferrous Iron ---- 0.05 mg/L <0.05 <0.05 0.00 No LimitAnonymous ET1801043-018








EK057G: Nitrite as N 14797-65-0 0.01 mg/L 0.61 0.62 1.70 0% - 20%Anonymous ET1801049-002







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EK061G: Total Kjeldahl Nitrogen By Discrete Analyser (QC Lot: 1580823) - continued






EK071G: Reactive Phosphorus as P 14265-44-2 0.01 mg/L 0.02 0.02 0.00 No LimitAnonymous ET1801043-001







EP030: Biochemical Oxygen Demand ---- 2 mg/L <2 5 88.9 No LimitAnonymous ET1801043-001


EP231X: Perfluorooctane sulfonic acid (PFOS) 1763-23-1 0.01 µg/L <0.01 <0.01 0.00 No LimitAnonymous EB1809440-005






EP231X: Perfluorooctane sulfonic acid (PFOS) 1763-23-1 0.01 µg/L <0.01 <0.01 0.00 No LimitAnonymous ET1801043-029







EP231X: Perfluorooctanoic acid (PFOA) 335-67-1 0.01 µg/L <0.01 <0.01 0.00 No LimitAnonymous EB1809440-005












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EP231X: Perfluoropentanoic acid (PFPeA) 2706-90-3 0.02 µg/L <0.02 <0.02 0.00 No LimitAnonymous ET1801043-029














2355-31-9 0.02 µg/L <0.02 <0.02 0.00 No Limit



2991-50-6 0.02 µg/L <0.02 <0.02 0.00 No Limit


(MeFOSA)

31506-32-8 0.05 µg/L <0.05 <0.05 0.00 No Limit


(EtFOSA)

4151-50-2 0.05 µg/L <0.05 <0.05 0.00 No Limit



24448-09-7 0.05 µg/L <0.05 <0.05 0.00 No Limit



1691-99-2 0.05 µg/L <0.05 <0.05 0.00 No Limit




2355-31-9 0.02 µg/L <0.02 <0.02 0.00 No Limit



2991-50-6 0.02 µg/L <0.02 <0.02 0.00 No Limit


(MeFOSA)

31506-32-8 0.05 µg/L <0.05 <0.05 0.00 No Limit


(EtFOSA)

4151-50-2 0.05 µg/L <0.05 <0.05 0.00 No Limit



24448-09-7 0.05 µg/L <0.05 <0.05 0.00 No Limit



1691-99-2 0.05 µg/L <0.05 <0.05 0.00 No Limit



FTS)


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FTS)



FTS)

39108-34-4 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

120226-60-0 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)



FTS)

27619-97-2 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

39108-34-4 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

120226-60-0 0.05 µg/L <0.05 <0.05 0.00 No Limit


EP231X: Sum of PFAS ---- 0.01 µg/L <0.01 <0.01 0.00 No LimitAnonymous EB1809440-005


23-1

0.01 µg/L <0.01 <0.01 0.00 No Limit


EP231X: Sum of PFAS ---- 0.01 µg/L <0.01 <0.01 0.00 No LimitAnonymous ET1801043-029


23-1

0.01 µg/L <0.01 <0.01 0.00 No Limit


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Report






---- 99.37 pH Unit 10298



<1 10112890 µS/cm 10791



<10 1022000 mg/L 11288



<5 94.61000 mg/L 12083



<0.1 99.240 NTU 10595

<0.1 101400 NTU 10397





<1 10725 mg/L 12080



<1 10410 mg/L 12080


ED093F: Calcium 7440-70-2 1 mg/L <1 -------- --------


ED093F: Sodium 7440-23-5 1 mg/L <1 -------- --------





EG020A-F: Iron 7439-89-6 0.05 mg/L <0.05 1020.5 mg/L 11482


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Report




EG051G: Ferrous Iron by Discrete Analyser (QCLot: 1576469) - continued


















<1 95.5100 mg/L 11379



<10 98.8500 mg/L 11286

















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Report















(MeFOSE)

24448-09-7 0.05 µg/L <0.05 96.91.25 µg/L 13070


(EtFOSE)

1691-99-2 0.05 µg/L <0.05 1041.25 µg/L 13070


(MeFOSAA)

2355-31-9 0.02 µg/L <0.02 1050.5 µg/L 13070


(EtFOSAA)

2991-50-6 0.02 µg/L <0.02 98.20.5 µg/L 13070









63-23-1

0.01 µg/L <0.01 -------- --------










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7439-96-5EG020A-F: Manganese # Not

Determined

0.1 mg/L 13070


Anonymous EB1808198-002 ----EG051G: Ferrous Iron 1002 mg/L 13070






Anonymous ET1801042-002 14797-65-0EK057G: Nitrite as N 1010.4 mg/L 13070








Anonymous ET1801043-002 14265-44-2EK071G: Reactive Phosphorus as P 1090.4 mg/L 13070






Anonymous EB1809440-006 375-73-5EP231X: Perfluorobutane sulfonic acid (PFBS) 93.20.5 µg/L 13070








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Anonymous EB1809440-006 2706-90-3EP231X: Perfluoropentanoic acid (PFPeA) 95.00.5 µg/L 13070











Anonymous EB1809440-006 754-91-6EP231X: Perfluorooctane sulfonamide (FOSA) 1290.5 µg/L 13070


(MeFOSA)

93.51.25 µg/L 13070



(MeFOSE)

97.81.25 µg/L 13070


(EtFOSE)

98.31.25 µg/L 13070


acid (MeFOSAA)

1050.5 µg/L 13070


acid (EtFOSAA)

98.80.5 µg/L 13070






True

Environmental












Summary of Outliers













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Matrix: WATER



ET1801044--001 7439-96-5Manganese0874_SW102_180416 MS recovery not determined,



----Not

Determined



Matrix: WATER



overdue

Days

overdue


Method



16-Apr-2018----0874_SW102_180416 17-Apr-2018---- ---- 1














0874_SW102_180416 16-Apr-2018---- 17-Apr-2018----16-Apr-2018 ---- ûEA006: Sodium Adsorption Ratio (SAR)


0874_SW102_180416 14-May-2018---- 20-Apr-2018----16-Apr-2018 ---- üEA010P: Conductivity by PC Titrator


0874_SW102_180416 14-May-2018---- 17-Apr-2018----16-Apr-2018 ---- üEA015: Total Dissolved Solids dried at 180 ± 5 °C


0874_SW102_180416 23-Apr-2018---- 17-Apr-2018----16-Apr-2018 ---- üEA025: Total Suspended Solids dried at 104 ± 2°C


0874_SW102_180416 23-Apr-2018---- 17-Apr-2018----16-Apr-2018 ---- ü

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EA045: Turbidity


0874_SW102_180416 18-Apr-2018---- 17-Apr-2018----16-Apr-2018 ---- üEA065: Total Hardness as CaCO3


0874_SW102_180416 14-May-2018---- 20-Apr-2018----16-Apr-2018 ---- üED037P: Alkalinity by PC Titrator


0874_SW102_180416 30-Apr-2018---- 17-Apr-2018----16-Apr-2018 ---- üED041G: Sulfate (Turbidimetric) as SO4 2- by DA


0874_SW102_180416 14-May-2018---- 17-Apr-2018----16-Apr-2018 ---- üED045G: Chloride by Discrete Analyser


0874_SW102_180416 14-May-2018---- 17-Apr-2018----16-Apr-2018 ---- üED093F: Dissolved Major Cations


0874_SW102_180416 14-May-2018---- 20-Apr-2018----16-Apr-2018 ---- üEG020F: Dissolved Metals by ICP-MS


0874_SW102_180416 13-Oct-2018---- 20-Apr-2018----16-Apr-2018 ---- üEG051G: Ferrous Iron by Discrete Analyser

Clear Plastic Bottle - HCl - Filtered (EG051G)

0874_SW102_180416 23-Apr-2018---- 18-Apr-2018----16-Apr-2018 ---- üEK040P: Fluoride by PC Titrator


0874_SW102_180416 14-May-2018---- 17-Apr-2018----16-Apr-2018 ---- üEK055G: Ammonia as N by Discrete Analyser


0874_SW102_180416 14-May-2018---- 17-Apr-2018----16-Apr-2018 ---- üEK057G: Nitrite as N by Discrete Analyser


0874_SW102_180416 18-Apr-2018---- 17-Apr-2018----16-Apr-2018 ---- üEK059G: Nitrite plus Nitrate as N (NOx) by Discrete Analyser


0874_SW102_180416 14-May-2018---- 17-Apr-2018----16-Apr-2018 ---- üEK061G: Total Kjeldahl Nitrogen By Discrete Analyser


0874_SW102_180416 14-May-201814-May-2018 20-Apr-201820-Apr-201816-Apr-2018 ü ü

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0874_SW102_180416 14-May-201814-May-2018 20-Apr-201820-Apr-201816-Apr-2018 ü üEK071G: Reactive Phosphorus as P by discrete analyser


0874_SW102_180416 18-Apr-2018---- 17-Apr-2018----16-Apr-2018 ---- üEP005: Total Organic Carbon (TOC)


0874_SW102_180416 14-May-2018---- 18-Apr-2018----16-Apr-2018 ---- üEP026SP: Chemical Oxygen Demand (Spectrophotometric)


0874_SW102_180416 14-May-2018---- 23-Apr-2018----16-Apr-2018 ---- üEP030: Biochemical Oxygen Demand (BOD)


0874_SW102_180416 18-Apr-2018---- 18-Apr-2018----16-Apr-2018 ---- üEP231A: Perfluoroalkyl Sulfonic Acids


0874_SW102_180416, 0874_SW102_180416_F 13-Oct-2018---- 19-Apr-2018----16-Apr-2018 ---- üEP231B: Perfluoroalkyl Carboxylic Acids


0874_SW102_180416, 0874_SW102_180416_F 13-Oct-2018---- 19-Apr-2018----16-Apr-2018 ---- üEP231C: Perfluoroalkyl Sulfonamides


0874_SW102_180416, 0874_SW102_180416_F 13-Oct-2018---- 19-Apr-2018----16-Apr-2018 ---- üEP231D: (n:2) Fluorotelomer Sulfonic Acids


0874_SW102_180416, 0874_SW102_180416_F 13-Oct-2018---- 19-Apr-2018----16-Apr-2018 ---- üEP231P: PFAS Sums


0874_SW102_180416, 0874_SW102_180416_F 13-Oct-2018---- 19-Apr-2018----16-Apr-2018 ---- ü

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Method Blanks (MB)





















Matrix Spikes (MS)











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Schedule B(3)





Conductivity)

EA016 WATER









Schedule B(3)







Discrete Analyser

ED041G WATER











Schedule B(3)


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Schedule B(3)


Analyser

EK059G WATER





Analyser

EK061G WATER


B(3)


Discrete Analyser

EK062G WATER





Schedule B(3)


Analyser

EK067G WATER






Analyser

EK071G WATER


DA

EN055 - PG WATER




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EP026SP WATER






B(3)











(PFAS) by LCMSMS

EP231X WATER



Schedule B(3)


Environmental





C/O GPO BOX 2907



QLD AUSTRALIA 4814






V4)


Site : ----




Date

26-Apr-2018



: : 3 / 2MEDIUM ESKYReceipt Detail No. of samples received / analysed

General Comments





























component

(On

Hold

) S

OIL

No a

na

lysi

s re

que

sted

ET1801044-003 16-Apr-2018 00:00 0874_SD102_180416 ü

Matrix: SOIL


ID

Client sampling

date / time

WA

TE

R -

EG

02

0F

Dis

solv

ed

Me

tals

by

ICP

/MS

WA

TE

R -

EG

05

1G

Ferr

ous

Iro

n

WA

TE

R -

EP

02

6S

P

Chem

ical O

xyg

en

De

ma

nd

(C

OD

)

WA

TE

R -

EP

03

0

BO

D

WA

TE

R -

EP

23

1X

PF

AS

- F

ull

Su

ite (

28

an

aly

tes)

WA

TE

R -

NT

-01

& 0

2

Ca, M

g, N

a, K

, C

l, S

O4

, A

lka

linity

WA

TE

R -

NT

-14

Ext

ended

Wa

ter

Su

ite B

ET1801044-001 16-Apr-2018 00:00 0874_SW102_180416 ü ü ü ü ü ü ü

ET1801044-002 16-Apr-2018 00:00 0874_SW102_180416_F ü

Matrix: WATER


ID

Client sampling

date / time

WA

TE

R -

EA

015H

Tota

l Dis

solv

ed S

olid

s -

Sta

ndard

Leve

l

WA

TE

R -

EA

025H

Susp

ended S

olid

s -

Sta

ndard

Leve

l

WA

TE

R -

EA

045

Turb

idity

WA

TE

R -

EP

005

Tota

l Org

anic

Carb

on (

TO

C)

ET1801044-001 16-Apr-2018 00:00 0874_SW102_180416 ü ü ü ü

Matrix: WATER


ID

Client sampling

date / time







ACCOUNTS PAYABLE


AU ACCOUNTS PAYABLE


DAVID HARRIS








DERP LABREPORTS


PHIL SCHULZ









RESULTS RESULTS








0 0.00 True

Environmental





C/O GPO BOX 2907








Site : ----






l General Comments












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General Comments







purposes.







Key :

EP005: Results for sample '0874_SW132_180417' may bias low due to large amounts of sediment. The sample was decanted before analysis.l

EP231: Matrix spike recovery bias low due to matrix interference. Confirmed by re-extraction and re-analysisl


23313)

l

EP231X-ST conducted by ALS Sydney, NATA accreditation no. 825, site no 10911.l


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Analytical Results


(Matrix: WATER)





6.89 ---- 7.00 7.16 9.69pH Unit0.01----pH Value


4.54^ ---- 6.01 9.08 15.8-0.01----Sodium Adsorption Ratio


653 ---- 904 2120 3220µS/cm1----Electrical Conductivity @ 25°C


370 ---- 506 1170 1850mg/L10----Total Dissolved Solids @180°C


424 ---- 588 1380 2090mg/L1----Total Dissolved Solids (Calc.)


22 ---- 14 182 30mg/L5----Suspended Solids (SS)

EA045: Turbidity

3.0 ---- 8.7 3.9 59.0NTU0.1----Turbidity


81 ---- 104 240 246mg/L1----Total Hardness as CaCO3



<1Carbonate Alkalinity as CaCO3 <1 <1 <1 51mg/L13812-32-6






158Chloride 194 229 590 902mg/L116887-00-6


16Calcium 14 17 30 44mg/L17440-70-2

10Magnesium 13 15 40 33mg/L17439-95-4

94Sodium 114 141 323 570mg/L17440-23-5

2Potassium 2 2 6 1mg/L17440-09-7


<0.01Aluminium ---- <0.01 <0.01 <0.01mg/L0.017429-90-5

0.248Manganese ---- 0.449 0.488 0.003mg/L0.0017439-96-5

0.20Iron ---- 0.06 0.09 <0.05mg/L0.057439-89-6

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Analytical Results


(Matrix: WATER)





0.20 ---- 0.07 0.11 <0.05mg/L0.05----Ferrous Iron


<0.1Fluoride ---- <0.1 <0.1 0.5mg/L0.116984-48-8


0.06Ammonia as N ---- 0.03 0.04 0.06mg/L0.017664-41-7


<0.01Nitrite as N ---- <0.01 <0.01 <0.01mg/L0.0114797-65-0


<0.01Nitrate as N ---- <0.01 <0.01 0.02mg/L0.0114797-55-8


<0.01 ---- <0.01 <0.01 0.02mg/L0.01----Nitrite + Nitrate as N


0.9 ---- 5.9 1.3 7.0mg/L0.1----Total Kjeldahl Nitrogen as N


0.9^ ---- 5.9 1.3 7.0mg/L0.1----Total Nitrogen as N


0.06 ---- 0.65 0.14 0.58mg/L0.01----Total Phosphorus as P


0.01Reactive Phosphorus as P ---- <0.01 0.03 <0.01mg/L0.0114265-44-2




0.31 0.47 1.34 0.12 1.70%0.01----Ionic Balance


11 ---- 15 10 10mg/L1----Total Organic Carbon


32 ---- 162 45 324mg/L10----Chemical Oxygen Demand


2 ---- 9 5 12mg/L2----Biochemical Oxygen Demand



(PFBS)

0.272 ---- ---- 3.23µg/L0.0005375-73-5

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Analytical Results


(Matrix: WATER)






(PFBS)

---- 0.39 0.37 ----µg/L0.02375-73-5


(PFPeS)

0.306 ---- ---- 3.37µg/L0.00052706-91-4


(PFPeS)

---- 0.43 0.39 ----µg/L0.022706-91-4


(PFHxS)

2.93 ---- ---- 19.4µg/L0.0005355-46-4


(PFHxS)

---- 3.54 3.62 ----µg/L0.02355-46-4


(PFHpS)

0.122 ---- ---- 0.928µg/L0.0005375-92-8


(PFHpS)

---- 0.25 0.19 ----µg/L0.02375-92-8


(PFOS)

3.66 ---- ---- 25.0µg/L0.00031763-23-1


(PFDS)

0.0099 ---- ---- 0.114µg/L0.0005335-77-3


(PFOS)

---- 5.96 3.07 ----µg/L0.011763-23-1


(PFDS)

---- <0.02 <0.02 ----µg/L0.02335-77-3


<0.002Perfluorobutanoic acid (PFBA) 0.024 ---- ---- 0.202µg/L0.002375-22-4

----Perfluorobutanoic acid (PFBA) ---- 0.2 0.1 ----µg/L0.1375-22-4

0.0119Perfluoropentanoic acid (PFPeA) 0.181 ---- ---- 1.60µg/L0.00052706-90-3

----Perfluoropentanoic acid (PFPeA) ---- 0.19 0.19 ----µg/L0.022706-90-3

0.0241Perfluorohexanoic acid (PFHxA) 0.910 ---- ---- 8.61µg/L0.0005307-24-4

----Perfluorohexanoic acid (PFHxA) ---- 0.98 1.09 ----µg/L0.02307-24-4

0.0120Perfluoroheptanoic acid (PFHpA) 0.0960 ---- ---- 1.51µg/L0.0005375-85-9

----Perfluoroheptanoic acid (PFHpA) ---- 0.11 0.11 ----µg/L0.02375-85-9

0.0062Perfluorooctanoic acid (PFOA) 0.176 ---- ---- 2.56µg/L0.0005335-67-1

----Perfluorooctanoic acid (PFOA) ---- 0.19 0.17 ----µg/L0.01335-67-1

0.0005Perfluorononanoic acid (PFNA) 0.0039 ---- ---- 0.124µg/L0.0005375-95-1

----Perfluorononanoic acid (PFNA) ---- <0.02 <0.02 ----µg/L0.02375-95-1

0.0006Perfluorodecanoic acid (PFDA) 0.0011 ---- ---- 0.0026µg/L0.0005335-76-2

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Analytical Results


(Matrix: WATER)





----Perfluorodecanoic acid (PFDA) ---- <0.02 <0.02 ----µg/L0.02335-76-2


(PFUnDA)

<0.0005 ---- ---- <0.0005µg/L0.00052058-94-8


(PFUnDA)

---- <0.02 <0.02 ----µg/L0.022058-94-8


(PFDoDA)

<0.0005 ---- ---- <0.0005µg/L0.0005307-55-1


(PFDoDA)

---- <0.02 <0.02 ----µg/L0.02307-55-1


(PFTrDA)

<0.0005 ---- ---- <0.0005µg/L0.000572629-94-8


(PFTrDA)

---- <0.02 <0.02 ----µg/L0.0272629-94-8


(PFTeDA)

<0.0005 ---- ---- <0.0005µg/L0.0005376-06-7


(PFTeDA)

---- <0.05 <0.05 ----µg/L0.05376-06-7



(FOSA)

0.0018 ---- ---- 0.0178µg/L0.0005754-91-6


(FOSA)

---- <0.02 <0.02 ----µg/L0.02754-91-6



<0.001 ---- ---- <0.001µg/L0.00131506-32-8



---- <0.05 <0.05 ----µg/L0.0531506-32-8



<0.001 ---- ---- <0.001µg/L0.0014151-50-2



---- <0.05 <0.05 ----µg/L0.054151-50-2



<0.001 ---- ---- <0.001µg/L0.00124448-09-7



---- <0.05 <0.05 ----µg/L0.0524448-09-7



<0.001 ---- ---- <0.001µg/L0.0011691-99-2

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Analytical Results


(Matrix: WATER)







---- <0.05 <0.05 ----µg/L0.051691-99-2



(MeFOSAA)

<0.0005 ---- ---- <0.0005µg/L0.00052355-31-9



(MeFOSAA)

---- <0.02 <0.02 ----µg/L0.022355-31-9



(EtFOSAA)

<0.0005 ---- ---- <0.0005µg/L0.00052991-50-6



(EtFOSAA)

---- <0.02 <0.02 ----µg/L0.022991-50-6



(4:2 FTS)

<0.001 ---- ---- <0.001µg/L0.001757124-72-4


(4:2 FTS)

---- <0.05 <0.05 ----µg/L0.05757124-72-4


(6:2 FTS)

0.011 ---- ---- 0.068µg/L0.00127619-97-2


(6:2 FTS)

---- <0.05 <0.05 ----µg/L0.0527619-97-2


(8:2 FTS)

<0.001 ---- ---- 0.002µg/L0.00139108-34-4


(8:2 FTS)

---- <0.05 <0.05 ----µg/L0.0539108-34-4


(10:2 FTS)

<0.001 ---- ---- <0.001µg/L0.001120226-60-0


(10:2 FTS)

---- <0.05 <0.05 ----µg/L0.05120226-60-0

EP231P: PFAS Sums

0.254 8.70 ---- ---- 66.7µg/L0.0003----Sum of PFAS

---- ---- 12.2 9.30 ----µg/L0.01----Sum of PFAS

0.165Sum of PFHxS and PFOS 6.59 ---- ---- 44.4µg/L0.0003355-46-4/1763-23-

1

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Analytical Results


(Matrix: WATER)





----Sum of PFHxS and PFOS ---- 9.50 6.69 ----µg/L0.01355-46-4/1763-23-

1

0.241 8.26 ---- ---- 62.2µg/L0.0003----Sum of PFAS (WA DER List)

---- ---- 11.6 8.72 ----µg/L0.01----Sum of PFAS (WA DER List)


84.6 97.1 ---- ---- 68.9%0.0005----13C4-PFOS

---- ---- 94.2 90.0 ----%0.02----13C4-PFOS

85.7 106 ---- ---- 94.8%0.0005----13C8-PFOA

---- ---- 97.6 99.9 ----%0.02----13C8-PFOA

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Analytical Results

0874_SW125_180417

_F

0874_SW013_180417

_F

0874_SW016_180417

_F

0874_SW126_1804170874_SW010S_18041

7


(Matrix: WATER)





8.36 8.04 ---- ---- ----pH Unit0.01----pH Value


10.2^ 3.73 ---- ---- -----0.01----Sodium Adsorption Ratio


1810 749 ---- ---- ----µS/cm1----Electrical Conductivity @ 25°C


998 418 ---- ---- ----mg/L10----Total Dissolved Solids @180°C


1180 487 ---- ---- ----mg/L1----Total Dissolved Solids (Calc.)


20 <5 ---- ---- ----mg/L5----Suspended Solids (SS)

EA045: Turbidity

23.5 3.0 ---- ---- ----NTU0.1----Turbidity


185 133 ---- ---- ----mg/L1----Total Hardness as CaCO3



9Carbonate Alkalinity as CaCO3 <1 ---- ---- ----mg/L13812-32-6






410Chloride 136 ---- ---- ----mg/L116887-00-6


46Calcium 27 ---- ---- ----mg/L17440-70-2

17Magnesium 16 ---- ---- ----mg/L17439-95-4

319Sodium 99 ---- ---- ----mg/L17440-23-5

2Potassium 6 ---- ---- ----mg/L17440-09-7


<0.01Aluminium <0.01 ---- ---- ----mg/L0.017429-90-5

0.250Manganese 0.051 ---- ---- ----mg/L0.0017439-96-5

<0.05Iron <0.05 ---- ---- ----mg/L0.057439-89-6

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Analytical Results

0874_SW125_180417

_F

0874_SW013_180417

_F

0874_SW016_180417

_F

0874_SW126_1804170874_SW010S_18041

7


(Matrix: WATER)





<0.05 0.06 ---- ---- ----mg/L0.05----Ferrous Iron


0.6Fluoride 0.2 ---- ---- ----mg/L0.116984-48-8


0.04Ammonia as N 0.05 ---- ---- ----mg/L0.017664-41-7


<0.01Nitrite as N <0.01 ---- ---- ----mg/L0.0114797-65-0


0.06Nitrate as N <0.01 ---- ---- ----mg/L0.0114797-55-8


0.06 <0.01 ---- ---- ----mg/L0.01----Nitrite + Nitrate as N


1.0 1.6 ---- ---- ----mg/L0.1----Total Kjeldahl Nitrogen as N


1.1^ 1.6 ---- ---- ----mg/L0.1----Total Nitrogen as N


0.16 0.11 ---- ---- ----mg/L0.01----Total Phosphorus as P


0.06Reactive Phosphorus as P 0.03 ---- ---- ----mg/L0.0114265-44-2




0.86 0.88 ---- ---- ----%0.01----Ionic Balance


12 11 ---- ---- ----mg/L1----Total Organic Carbon


40 40 ---- ---- ----mg/L10----Chemical Oxygen Demand


3 2 ---- ---- ----mg/L2----Biochemical Oxygen Demand



(PFBS)

---- 0.0022 ---- ----µg/L0.0005375-73-5

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Analytical Results

0874_SW125_180417

_F

0874_SW013_180417

_F

0874_SW016_180417

_F

0874_SW126_1804170874_SW010S_18041

7


(Matrix: WATER)






(PFBS)

0.31 ---- 0.06 0.06µg/L0.02375-73-5


(PFPeS)

---- <0.0005 ---- ----µg/L0.00052706-91-4


(PFPeS)

0.25 ---- <0.02 <0.02µg/L0.022706-91-4


(PFHxS)

---- <0.0005 ---- ----µg/L0.0005355-46-4


(PFHxS)

1.92 ---- <0.02 <0.02µg/L0.02355-46-4


(PFHpS)

---- <0.0005 ---- ----µg/L0.0005375-92-8


(PFHpS)

0.13 ---- <0.02 <0.02µg/L0.02375-92-8


(PFOS)

---- <0.0003 ---- ----µg/L0.00031763-23-1


(PFDS)

---- <0.0005 ---- ----µg/L0.0005335-77-3


(PFOS)

3.77 ---- <0.01 <0.01µg/L0.011763-23-1


(PFDS)

<0.02 ---- <0.02 <0.02µg/L0.02335-77-3


----Perfluorobutanoic acid (PFBA) ---- <0.002 ---- ----µg/L0.002375-22-4

0.1Perfluorobutanoic acid (PFBA) 0.2 ---- 0.2 0.1µg/L0.1375-22-4

----Perfluoropentanoic acid (PFPeA) ---- 0.0105 ---- ----µg/L0.00052706-90-3

0.31Perfluoropentanoic acid (PFPeA) 0.16 ---- 0.19 0.18µg/L0.022706-90-3

----Perfluorohexanoic acid (PFHxA) ---- 0.0241 ---- ----µg/L0.0005307-24-4

0.36Perfluorohexanoic acid (PFHxA) 0.66 ---- 0.87 0.96µg/L0.02307-24-4

----Perfluoroheptanoic acid (PFHpA) ---- 0.0036 ---- ----µg/L0.0005375-85-9

0.26Perfluoroheptanoic acid (PFHpA) 0.07 ---- 0.07 0.07µg/L0.02375-85-9

----Perfluorooctanoic acid (PFOA) ---- 0.0023 ---- ----µg/L0.0005335-67-1

0.27Perfluorooctanoic acid (PFOA) 0.13 ---- 0.04 0.03µg/L0.01335-67-1

----Perfluorononanoic acid (PFNA) ---- <0.0005 ---- ----µg/L0.0005375-95-1

0.02Perfluorononanoic acid (PFNA) <0.02 ---- <0.02 <0.02µg/L0.02375-95-1

12 of 21:Page

Work Order :

:Client

ET1801057



Analytical Results

0874_SW125_180417

_F

0874_SW013_180417

_F

0874_SW016_180417

_F

0874_SW126_1804170874_SW010S_18041

7


(Matrix: WATER)





----Perfluorodecanoic acid (PFDA) ---- <0.0005 ---- ----µg/L0.0005335-76-2

<0.02Perfluorodecanoic acid (PFDA) <0.02 ---- <0.02 <0.02µg/L0.02335-76-2


(PFUnDA)

---- <0.0005 ---- ----µg/L0.00052058-94-8


(PFUnDA)

<0.02 ---- <0.02 <0.02µg/L0.022058-94-8


(PFDoDA)

---- <0.0005 ---- ----µg/L0.0005307-55-1


(PFDoDA)

<0.02 ---- <0.02 <0.02µg/L0.02307-55-1


(PFTrDA)

---- <0.0005 ---- ----µg/L0.000572629-94-8


(PFTrDA)

<0.02 ---- <0.02 <0.02µg/L0.0272629-94-8


(PFTeDA)

---- <0.0005 ---- ----µg/L0.0005376-06-7


(PFTeDA)

<0.05 ---- <0.05 <0.05µg/L0.05376-06-7



(FOSA)

---- <0.0005 ---- ----µg/L0.0005754-91-6


(FOSA)

<0.02 ---- <0.02 <0.02µg/L0.02754-91-6



---- <0.001 ---- ----µg/L0.00131506-32-8



<0.05 ---- <0.05 <0.05µg/L0.0531506-32-8



---- <0.001 ---- ----µg/L0.0014151-50-2



<0.05 ---- <0.05 <0.05µg/L0.054151-50-2



---- <0.001 ---- ----µg/L0.00124448-09-7



<0.05 ---- <0.05 <0.05µg/L0.0524448-09-7

13 of 21:Page

Work Order :

:Client

ET1801057



Analytical Results

0874_SW125_180417

_F

0874_SW013_180417

_F

0874_SW016_180417

_F

0874_SW126_1804170874_SW010S_18041

7


(Matrix: WATER)







---- <0.001 ---- ----µg/L0.0011691-99-2



<0.05 ---- <0.05 <0.05µg/L0.051691-99-2



(MeFOSAA)

---- <0.0005 ---- ----µg/L0.00052355-31-9



(MeFOSAA)

<0.02 ---- <0.02 <0.02µg/L0.022355-31-9



(EtFOSAA)

---- <0.0005 ---- ----µg/L0.00052991-50-6



(EtFOSAA)

<0.02 ---- <0.02 <0.02µg/L0.022991-50-6



(4:2 FTS)

---- <0.001 ---- ----µg/L0.001757124-72-4


(4:2 FTS)

<0.05 ---- <0.05 <0.05µg/L0.05757124-72-4


(6:2 FTS)

---- <0.001 ---- ----µg/L0.00127619-97-2


(6:2 FTS)

<0.05 ---- <0.05 <0.05µg/L0.0527619-97-2


(8:2 FTS)

---- <0.001 ---- ----µg/L0.00139108-34-4


(8:2 FTS)

<0.05 ---- <0.05 <0.05µg/L0.0539108-34-4


(10:2 FTS)

---- <0.001 ---- ----µg/L0.001120226-60-0


(10:2 FTS)

<0.05 ---- <0.05 <0.05µg/L0.05120226-60-0

EP231P: PFAS Sums

---- ---- 0.0427 ---- ----µg/L0.0003----Sum of PFAS

3.66 7.60 ---- 1.43 1.40µg/L0.01----Sum of PFAS

14 of 21:Page

Work Order :

:Client

ET1801057



Analytical Results

0874_SW125_180417

_F

0874_SW013_180417

_F

0874_SW016_180417

_F

0874_SW126_1804170874_SW010S_18041

7


(Matrix: WATER)





----Sum of PFHxS and PFOS ---- <0.0003 ---- ----µg/L0.0003355-46-4/1763-23-

1

1.93Sum of PFHxS and PFOS 5.69 ---- <0.01 <0.01µg/L0.01355-46-4/1763-23-

1

---- ---- 0.0427 ---- ----µg/L0.0003----Sum of PFAS (WA DER List)

3.52 7.22 ---- 1.43 1.40µg/L0.01----Sum of PFAS (WA DER List)


---- ---- 77.6 ---- ----%0.0005----13C4-PFOS

103 85.4 ---- 108 93.6%0.02----13C4-PFOS

---- ---- 106 ---- ----%0.0005----13C8-PFOA

101 99.6 ---- 98.3 96.7%0.02----13C8-PFOA

15 of 21:Page

Work Order :

:Client

ET1801057



Analytical Results

0874_QC3SW_1804170874_QC1SW_1804170874_SW126_180417

_F

0874_SW010S_18041

7_F

0874_SW132_180417

_F


(Matrix: WATER)





----Hydroxide Alkalinity as CaCO3 ---- ---- <1 <1mg/L1DMO-210-001

----Carbonate Alkalinity as CaCO3 ---- ---- <1 <1mg/L13812-32-6

----Bicarbonate Alkalinity as CaCO3 ---- ---- 57 3mg/L171-52-3

---- ---- ---- 57 3mg/L1----Total Alkalinity as CaCO3


----Sulfate as SO4 - Turbidimetric ---- ---- 4 <1mg/L114808-79-8


----Chloride ---- ---- 190 <1mg/L116887-00-6


----Calcium ---- ---- 14 <1mg/L17440-70-2

----Magnesium ---- ---- 13 <1mg/L17439-95-4

----Sodium ---- ---- 114 <1mg/L17440-23-5

----Potassium ---- ---- 2 <1mg/L17440-09-7


---- ---- ---- 6.58 0.06meq/L0.01----Total Anions

---- ---- ---- 6.78 <0.01meq/L0.01----Total Cations

---- ---- ---- 1.47 ----%0.01----Ionic Balance



(PFBS)

0.0969 ---- 0.252 <0.0005µg/L0.0005375-73-5


(PFBS)

---- 0.23 ---- ----µg/L0.02375-73-5


(PFPeS)

0.0482 ---- 0.280 <0.0005µg/L0.00052706-91-4


(PFPeS)

---- 0.05 ---- ----µg/L0.022706-91-4


(PFHxS)

0.152 ---- 2.67 <0.0005µg/L0.0005355-46-4


(PFHxS)

---- <0.02 ---- ----µg/L0.02355-46-4


(PFHpS)

0.0020 ---- 0.118 <0.0005µg/L0.0005375-92-8


(PFHpS)

---- <0.02 ---- ----µg/L0.02375-92-8

16 of 21:Page

Work Order :

:Client

ET1801057



Analytical Results

0874_QC3SW_1804170874_QC1SW_1804170874_SW126_180417

_F

0874_SW010S_18041

7_F

0874_SW132_180417

_F


(Matrix: WATER)






(PFOS)

0.0012 ---- 3.44 <0.0003µg/L0.00031763-23-1


(PFDS)

<0.0005 ---- 0.0077 <0.0005µg/L0.0005335-77-3


(PFOS)

---- <0.01 ---- ----µg/L0.011763-23-1


(PFDS)

---- <0.02 ---- ----µg/L0.02335-77-3


----Perfluorobutanoic acid (PFBA) <0.002 ---- 0.019 <0.002µg/L0.002375-22-4

1.4Perfluorobutanoic acid (PFBA) ---- 0.2 ---- ----µg/L0.1375-22-4

----Perfluoropentanoic acid (PFPeA) 0.308 ---- 0.177 <0.0005µg/L0.00052706-90-3

1.71Perfluoropentanoic acid (PFPeA) ---- 0.16 ---- ----µg/L0.022706-90-3

----Perfluorohexanoic acid (PFHxA) 0.509 ---- 0.788 <0.0005µg/L0.0005307-24-4

8.24Perfluorohexanoic acid (PFHxA) ---- 0.64 ---- ----µg/L0.02307-24-4

----Perfluoroheptanoic acid (PFHpA) 0.260 ---- 0.116 <0.0005µg/L0.0005375-85-9

1.16Perfluoroheptanoic acid (PFHpA) ---- 0.06 ---- ----µg/L0.02375-85-9

----Perfluorooctanoic acid (PFOA) 0.168 ---- 0.154 <0.0005µg/L0.0005335-67-1

0.87Perfluorooctanoic acid (PFOA) ---- 0.08 ---- ----µg/L0.01335-67-1

----Perfluorononanoic acid (PFNA) 0.0074 ---- 0.0044 <0.0005µg/L0.0005375-95-1

<0.02Perfluorononanoic acid (PFNA) ---- <0.02 ---- ----µg/L0.02375-95-1

----Perfluorodecanoic acid (PFDA) 0.0005 ---- 0.0010 <0.0005µg/L0.0005335-76-2

<0.02Perfluorodecanoic acid (PFDA) ---- <0.02 ---- ----µg/L0.02335-76-2


(PFUnDA)

<0.0005 ---- <0.0005 <0.0005µg/L0.00052058-94-8


(PFUnDA)

---- <0.02 ---- ----µg/L0.022058-94-8


(PFDoDA)

<0.0005 ---- <0.0005 <0.0005µg/L0.0005307-55-1


(PFDoDA)

---- <0.02 ---- ----µg/L0.02307-55-1


(PFTrDA)

<0.0005 ---- <0.0005 <0.0005µg/L0.000572629-94-8


(PFTrDA)

---- <0.02 ---- ----µg/L0.0272629-94-8

17 of 21:Page

Work Order :

:Client

ET1801057



Analytical Results

0874_QC3SW_1804170874_QC1SW_1804170874_SW126_180417

_F

0874_SW010S_18041

7_F

0874_SW132_180417

_F


(Matrix: WATER)






(PFTeDA)

<0.0005 ---- <0.0005 <0.0005µg/L0.0005376-06-7


(PFTeDA)

---- <0.05 ---- ----µg/L0.05376-06-7



(FOSA)

<0.0005 ---- 0.0015 <0.0005µg/L0.0005754-91-6


(FOSA)

---- <0.02 ---- ----µg/L0.02754-91-6



<0.001 ---- <0.001 <0.001µg/L0.00131506-32-8



---- <0.05 ---- ----µg/L0.0531506-32-8



<0.001 ---- <0.001 <0.001µg/L0.0014151-50-2



---- <0.05 ---- ----µg/L0.054151-50-2



<0.001 ---- <0.001 <0.001µg/L0.00124448-09-7



---- <0.05 ---- ----µg/L0.0524448-09-7



<0.001 ---- <0.001 <0.001µg/L0.0011691-99-2



---- <0.05 ---- ----µg/L0.051691-99-2



(MeFOSAA)

<0.0005 ---- <0.0005 <0.0005µg/L0.00052355-31-9



(MeFOSAA)

---- <0.02 ---- ----µg/L0.022355-31-9



(EtFOSAA)

<0.0005 ---- <0.0005 <0.0005µg/L0.00052991-50-6

18 of 21:Page

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:Client

ET1801057



Analytical Results

0874_QC3SW_1804170874_QC1SW_1804170874_SW126_180417

_F

0874_SW010S_18041

7_F

0874_SW132_180417

_F


(Matrix: WATER)







(EtFOSAA)

---- <0.02 ---- ----µg/L0.022991-50-6



(4:2 FTS)

<0.001 ---- <0.001 <0.001µg/L0.001757124-72-4


(4:2 FTS)

---- <0.05 ---- ----µg/L0.05757124-72-4


(6:2 FTS)

0.119 ---- 0.011 <0.001µg/L0.00127619-97-2


(6:2 FTS)

---- <0.05 ---- ----µg/L0.0527619-97-2


(8:2 FTS)

0.003 ---- <0.001 <0.001µg/L0.00139108-34-4


(8:2 FTS)

---- <0.05 ---- ----µg/L0.0539108-34-4


(10:2 FTS)

<0.001 ---- <0.001 <0.001µg/L0.001120226-60-0


(10:2 FTS)

---- <0.05 ---- ----µg/L0.05120226-60-0

EP231P: PFAS Sums

---- 1.68 ---- 8.04 <0.0003µg/L0.0003----Sum of PFAS

14.8 ---- 1.42 ---- ----µg/L0.01----Sum of PFAS

----Sum of PFHxS and PFOS 0.153 ---- 6.11 <0.0003µg/L0.0003355-46-4/1763-23-

1

<0.01Sum of PFHxS and PFOS ---- <0.01 ---- ----µg/L0.01355-46-4/1763-23-

1

---- 1.62 ---- 7.63 <0.0003µg/L0.0003----Sum of PFAS (WA DER List)

14.7 ---- 1.37 ---- ----µg/L0.01----Sum of PFAS (WA DER List)


---- 82.7 ---- 92.2 70.3%0.0005----13C4-PFOS

97.3 ---- 89.8 ---- ----%0.02----13C4-PFOS

---- 102 ---- 99.7 102%0.0005----13C8-PFOA

97.6 ---- 94.4 ---- ----%0.02----13C8-PFOA

19 of 21:Page

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:Client

ET1801057



Analytical Results

------------0874_QC5SW_1804170874_QC4SW_180417Client sample IDSub-Matrix: WATER

(Matrix: WATER)






(PFBS)

<0.0005 ---- ---- ----µg/L0.0005375-73-5


(PFPeS)

<0.0005 ---- ---- ----µg/L0.00052706-91-4


(PFHxS)

<0.0005 ---- ---- ----µg/L0.0005355-46-4


(PFHpS)

<0.0005 ---- ---- ----µg/L0.0005375-92-8


(PFOS)

<0.0003 ---- ---- ----µg/L0.00031763-23-1


(PFDS)

<0.0005 ---- ---- ----µg/L0.0005335-77-3




<0.0005Perfluorohexanoic acid (PFHxA) <0.0005 ---- ---- ----µg/L0.0005307-24-4


<0.0005Perfluorooctanoic acid (PFOA) <0.0005 ---- ---- ----µg/L0.0005335-67-1




(PFUnDA)

<0.0005 ---- ---- ----µg/L0.00052058-94-8


(PFDoDA)

<0.0005 ---- ---- ----µg/L0.0005307-55-1


(PFTrDA)

<0.0005 ---- ---- ----µg/L0.000572629-94-8


(PFTeDA)

<0.0005 ---- ---- ----µg/L0.0005376-06-7



(FOSA)

<0.0005 ---- ---- ----µg/L0.0005754-91-6



<0.001 ---- ---- ----µg/L0.00131506-32-8



<0.001 ---- ---- ----µg/L0.0014151-50-2

20 of 21:Page

Work Order :

:Client

ET1801057



Analytical Results

------------0874_QC5SW_1804170874_QC4SW_180417Client sample IDSub-Matrix: WATER

(Matrix: WATER)







<0.001 ---- ---- ----µg/L0.00124448-09-7



<0.001 ---- ---- ----µg/L0.0011691-99-2



(MeFOSAA)

<0.0005 ---- ---- ----µg/L0.00052355-31-9



(EtFOSAA)

<0.0005 ---- ---- ----µg/L0.00052991-50-6



(4:2 FTS)

<0.001 ---- ---- ----µg/L0.001757124-72-4


(6:2 FTS)

<0.001 ---- ---- ----µg/L0.00127619-97-2


(8:2 FTS)

<0.001 ---- ---- ----µg/L0.00139108-34-4


(10:2 FTS)

<0.001 ---- ---- ----µg/L0.001120226-60-0

EP231P: PFAS Sums

<0.0003 <0.0003 ---- ---- ----µg/L0.0003----Sum of PFAS

<0.0003Sum of PFHxS and PFOS <0.0003 ---- ---- ----µg/L0.0003355-46-4/1763-23-

1

<0.0003 <0.0003 ---- ---- ----µg/L0.0003----Sum of PFAS (WA DER List)


79.0 61.8 ---- ---- ----%0.0005----13C4-PFOS

99.2 92.0 ---- ---- ----%0.0005----13C8-PFOA

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ET1801057







13C4-PFOS ---- 60 120

13C8-PFOA ---- 60 120

False

4 4.00True

Environmental




:Address MOBIL

C/O GPO BOX 2907








Site : ----
















2 of 16:Page

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ET1801057



General Comments










Key :









EA005-P: pH Value ---- 0.01 pH Unit 8.36 8.36 0.00 0% - 20%0874_SW010S_180417 ET1801057-006



EA010-P: Electrical Conductivity @ 25°C ---- 1 µS/cm 1810 1810 0.0552 0% - 20%0874_SW010S_180417 ET1801057-006





EA025H: Suspended Solids (SS) ---- 5 mg/L 22 20 9.52 No Limit0874_SW016_180417 ET1801057-001




EA045: Turbidity ---- 0.1 NTU 23.5 23.4 0.426 0% - 20%0874_SW010S_180417 ET1801057-006






ED037-P: Hydroxide Alkalinity as CaCO3 DMO-210-001 1 mg/L <1 <1 0.00 No Limit0874_SW010S_180417 ET1801057-006

ED037-P: Carbonate Alkalinity as CaCO3 3812-32-6 1 mg/L 9 9 0.00 No Limit




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ED041G: Sulfate as SO4 - Turbidimetric 14808-79-8 1 mg/L 2 2 0.00 No Limit0874_SW016_180417 ET1801057-001






ED093F: Sodium 7440-23-5 1 mg/L 94 93 1.38 0% - 20%


ED093F: Calcium 7440-70-2 1 mg/L 7 7 0.00 No LimitAnonymous ET1801059-009

ED093F: Magnesium 7439-95-4 1 mg/L 8 8 0.00 No Limit

ED093F: Sodium 7440-23-5 1 mg/L 424 424 0.00 0% - 20%



EG020A-F: Manganese 7439-96-5 0.001 mg/L 0.248 0.244 1.62 0% - 20%0874_SW016_180417 ET1801057-001



EG020A-F: Manganese 7439-96-5 0.001 mg/L 0.002 0.002 0.00 No LimitAnonymous ET1801059-009




EG051G: Ferrous Iron ---- 0.05 mg/L 0.20 0.21 0.00 No Limit0874_SW016_180417 ET1801057-001




EK040P: Fluoride 16984-48-8 0.1 mg/L 0.6 0.7 0.00 No Limit0874_SW010S_180417 ET1801057-006


EK055G: Ammonia as N 7664-41-7 0.01 mg/L 0.06 <0.01 143 No Limit0874_SW016_180417 ET1801057-001



EK057G: Nitrite as N 14797-65-0 0.01 mg/L <0.01 <0.01 0.00 No Limit0874_SW016_180417 ET1801057-001

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ET1801057






EK059G: Nitrite + Nitrate as N ---- 0.01 mg/L <0.01 <0.01 0.00 No Limit0874_SW016_180417 ET1801057-001

EK059G: Nitrite + Nitrate as N ---- 0.01 mg/L 0.16 0.16 0.00 0% - 50%Anonymous ET1801058-005


EK061G: Total Kjeldahl Nitrogen as N ---- 0.1 mg/L 436 454 4.04 0% - 20%Anonymous EB1809760-011

EK061G: Total Kjeldahl Nitrogen as N ---- 0.1 mg/L 0.9 0.9 0.00 No Limit0874_SW016_180417 ET1801057-001


EK067G: Total Phosphorus as P ---- 0.01 mg/L <0.01 <0.01 0.00 No LimitAnonymous EB1808834-002



EK067G: Total Phosphorus as P ---- 0.01 mg/L 0.65 0.68 5.79 0% - 50%0874_SW013_180417 ET1801057-003


EK071G: Reactive Phosphorus as P 14265-44-2 0.01 mg/L 0.01 0.01 0.00 No Limit0874_SW016_180417 ET1801057-001


EP005: Total Organic Carbon ---- 1 mg/L 11 11 0.00 0% - 50%0874_SW016_180417 ET1801057-001



EP026SP: Chemical Oxygen Demand ---- 10 mg/L 32 32 0.00 No Limit0874_SW016_180417 ET1801057-001



EP030: Biochemical Oxygen Demand ---- 2 mg/L <2 <2 0.00 No LimitAnonymous EB1809565-001

EP030: Biochemical Oxygen Demand ---- 2 mg/L 30 28 7.13 0% - 50%Anonymous EB1809565-011













EP231X: Perfluorodecane sulfonic acid (PFDS) 335-77-3 0.02 µg/L 1.06 1.03 2.49 0% - 20%



(PFOS)

1763-23-1 0.0003 µg/L 0.0885 0.0865 2.19 0% - 20%0874_SW016_180417 ET1801057-001

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(PFBS)

375-73-5 0.0005 µg/L 0.0211 0.0221 4.45 0% - 20%0874_SW016_180417 ET1801057-001


(PFPeS)

2706-91-4 0.0005 µg/L 0.0092 0.0100 7.93 0% - 50%


(PFHxS)

355-46-4 0.0005 µg/L 0.0769 0.0822 6.71 0% - 20%


(PFHpS)

375-92-8 0.0005 µg/L 0.0030 0.0031 4.56 No Limit


(PFDS)

335-77-3 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


















EP231X: Perfluorodecanoic acid (PFDA) 335-76-2 0.02 µg/L 0.09 0.10 0.00 No Limit

EP231X: Perfluoroundecanoic acid (PFUnDA) 2058-94-8 0.02 µg/L 0.02 0.02 0.00 No Limit






EP231X-ST: Perfluoropentanoic acid (PFPeA) 2706-90-3 0.0005 µg/L 0.0119 0.0111 7.32 0% - 20%0874_SW016_180417 ET1801057-001





EP231X-ST: Perfluorodecanoic acid (PFDA) 335-76-2 0.0005 µg/L 0.0006 <0.0005 0.00 No Limit

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EP231X-ST: Perfluoroundecanoic acid (PFUnDA) 2058-94-8 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit0874_SW016_180417 ET1801057-001




(PFTeDA)

376-06-7 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit






2355-31-9 0.02 µg/L <0.02 <0.02 0.00 No Limit



2991-50-6 0.02 µg/L <0.02 <0.02 0.00 No Limit


(MeFOSA)

31506-32-8 0.05 µg/L <0.05 <0.05 0.00 No Limit


(EtFOSA)

4151-50-2 0.05 µg/L <0.05 <0.05 0.00 No Limit



24448-09-7 0.05 µg/L <0.05 <0.05 0.00 No Limit



1691-99-2 0.05 µg/L <0.05 <0.05 0.00 No Limit

EP231X: Perfluorooctane sulfonamide (FOSA) 754-91-6 0.02 µg/L 0.38 0.40 5.40 0% - 50%Anonymous ET1801059-003



2355-31-9 0.02 µg/L <0.02 <0.02 0.00 No Limit



2991-50-6 0.02 µg/L <0.02 <0.02 0.00 No Limit


(MeFOSA)

31506-32-8 0.05 µg/L <0.05 <0.05 0.00 No Limit


(EtFOSA)

4151-50-2 0.05 µg/L <0.05 <0.05 0.00 No Limit



24448-09-7 0.05 µg/L <0.05 <0.05 0.00 No Limit



1691-99-2 0.05 µg/L <0.05 <0.05 0.00 No Limit



(FOSA)

754-91-6 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit0874_SW016_180417 ET1801057-001



2355-31-9 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit



2991-50-6 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit

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31506-32-8 0.001 µg/L <0.001 <0.001 0.00 No Limit0874_SW016_180417 ET1801057-001


(EtFOSA)

4151-50-2 0.001 µg/L <0.001 <0.001 0.00 No Limit



24448-09-7 0.001 µg/L <0.001 <0.001 0.00 No Limit



1691-99-2 0.001 µg/L <0.001 <0.001 0.00 No Limit



FTS)

757124-72-4 0.05 µg/L <0.05 <0.05 0.00 No Limit0874_SW013_180417 ET1801057-003


FTS)

27619-97-2 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

39108-34-4 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

120226-60-0 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)



FTS)

27619-97-2 0.05 µg/L 1.11 1.08 3.10 0% - 20%


FTS)

39108-34-4 0.05 µg/L 0.87 0.86 1.15 0% - 50%


FTS)

120226-60-0 0.05 µg/L <0.05 <0.05 0.00 No Limit



FTS)

757124-72-4 0.001 µg/L <0.001 <0.001 0.00 No Limit0874_SW016_180417 ET1801057-001


FTS)

27619-97-2 0.001 µg/L <0.001 <0.001 0.00 No Limit


FTS)

39108-34-4 0.001 µg/L <0.001 <0.001 0.00 No Limit


(10:2 FTS)

120226-60-0 0.001 µg/L <0.001 <0.001 0.00 No Limit




23-1

0.01 µg/L 9.50 9.52 0.210 0% - 20%



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23-1

0.01 µg/L 52.0 53.6 2.99 0% - 20%Anonymous ET1801059-003




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Report






---- 99.17 pH Unit 10298



<1 98.812890 µS/cm 10791



<10 1032000 mg/L 11288


EA025H: Suspended Solids (SS) ---- 5 mg/L <5 101150 mg/L 12083

<5 92.81000 mg/L 12083



<0.1 10340 NTU 10595

<0.1 101400 NTU 10397







<1 11525 mg/L 12080



<1 10010 mg/L 12080


ED093F: Calcium 7440-70-2 1 mg/L <1 -------- --------


ED093F: Sodium 7440-23-5 1 mg/L <1 -------- --------





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Report




EG020F: Dissolved Metals by ICP-MS (QCLot: 1581877) - continued

EG020A-F: Iron 7439-89-6 0.05 mg/L <0.05 95.90.5 mg/L 11482





















<1 97.0100 mg/L 11379



<10 96.8500 mg/L 11286











EP231X-ST: Perfluorobutane sulfonic acid (PFBS) 375-73-5 0.0005 µg/L <0.0005 1030.01 µg/L 13050


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Report





EP231X-ST: Perfluorohexane sulfonic acid (PFHxS) 355-46-4 0.0005 µg/L <0.0005 1040.01 µg/L 13050



















EP231X-ST: Perfluorohexanoic acid (PFHxA) 307-24-4 0.0005 µg/L <0.0005 1070.01 µg/L 13050














(MeFOSE)

24448-09-7 0.05 µg/L <0.05 1101.25 µg/L 13070


(EtFOSE)

1691-99-2 0.05 µg/L <0.05 1051.25 µg/L 13070


(MeFOSAA)

2355-31-9 0.02 µg/L <0.02 1110.5 µg/L 13070

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Report






(EtFOSAA)

2991-50-6 0.02 µg/L <0.02 98.00.5 µg/L 13070




(MeFOSA)

31506-32-8 0.001 µg/L <0.001 58.00.025 µg/L 13040



(MeFOSE)

24448-09-7 0.001 µg/L <0.001 59.00.025 µg/L 13040


(EtFOSE)

1691-99-2 0.001 µg/L <0.001 40.10.025 µg/L 13040


acid (MeFOSAA)

2355-31-9 0.0005 µg/L <0.0005 56.40.01 µg/L 13040


acid (EtFOSAA)

2991-50-6 0.0005 µg/L <0.0005 42.20.01 µg/L 13040














63-23-1

0.01 µg/L <0.01 -------- --------








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ET1801057







0874_SW012_180417 ET1801057-002 14808-79-8ED041G: Sulfate as SO4 - Turbidimetric 11820 mg/L 13070






Determined

0.1 mg/L 13070


0874_SW013_180417 ET1801057-003 ----EG051G: Ferrous Iron 1002 mg/L 13070




0874_SW013_180417 ET1801057-003 7664-41-7EK055G: Ammonia as N 76.70.4 mg/L 13070


0874_SW013_180417 ET1801057-003 14797-65-0EK057G: Nitrite as N 1010.4 mg/L 13070


0874_SW013_180417 ET1801057-003 ----EK059G: Nitrite + Nitrate as N 76.40.4 mg/L 13070


Anonymous EB1809760-012 ----EK061G: Total Kjeldahl Nitrogen as N 95.75 mg/L 13070




0874_SW125_180417 ET1801057-004 ----EK067G: Total Phosphorus as P 91.21 mg/L 13070


0874_SW013_180417 ET1801057-003 14265-44-2EK071G: Reactive Phosphorus as P 1020.4 mg/L 13070


0874_SW013_180417 ET1801057-003 ----EP005: Total Organic Carbon 98.9100 mg/L 13070


0874_SW013_180417 ET1801057-003 ----EP026SP: Chemical Oxygen Demand 95.5291 mg/L 13070


0874_SW125_180417 ET1801057-004 375-73-5EP231X: Perfluorobutane sulfonic acid (PFBS) 90.80.5 µg/L 13070



Determined

0.5 µg/L 13070

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ET1801057







0874_SW125_180417 ET1801057-004 375-92-8EP231X: Perfluoroheptane sulfonic acid (PFHpS) 1100.5 µg/L 13070


Determined

0.5 µg/L 13070




Determined

0.01 µg/L 13050


Determined

0.01 µg/L 13050


Determined

0.01 µg/L 13050


Determined

0.01 µg/L 13050


Determined

0.01 µg/L 13050



0874_SW125_180417 ET1801057-004 375-22-4EP231X: Perfluorobutanoic acid (PFBA) 1022.5 µg/L 13070













Determined

0.05 µg/L 13030


Determined

0.01 µg/L 13050


Determined

0.01 µg/L 13050


Determined

0.01 µg/L 13050


Determined

0.01 µg/L 13050

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ET1801057







0874_SW012_180417 ET1801057-002 375-95-1EP231X-ST: Perfluorononanoic acid (PFNA) 66.00.01 µg/L 13050




72629-94-8EP231X-ST: Perfluorotridecanoic acid (PFTrDA) # 28.60.01 µg/L 13030

376-06-7EP231X-ST: Perfluorotetradecanoic acid (PFTeDA) # 26.20.025 µg/L 13030


0874_SW125_180417 ET1801057-004 754-91-6EP231X: Perfluorooctane sulfonamide (FOSA) 1200.5 µg/L 13070


(MeFOSA)

95.11.25 µg/L 13070



(MeFOSE)

1081.25 µg/L 13070


(EtFOSE)

95.31.25 µg/L 13070


acid (MeFOSAA)

1090.5 µg/L 13070


acid (EtFOSAA)

1060.5 µg/L 13070




(MeFOSA)

41.80.025 µg/L 13030


(EtFOSA)

43.70.025 µg/L 13030



37.00.025 µg/L 13030



# 28.60.025 µg/L 13030



30.40.01 µg/L 13030


acid (EtFOSAA)

# 27.00.01 µg/L 13030


0874_SW125_180417 ET1801057-004 757124-72-4EP231X: 4:2 Fluorotelomer sulfonic acid (4:2 FTS) 1050.5 µg/L 13070




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0874_SW012_180417 ET1801057-002 757124-72-4EP231X-ST: 4:2 Fluorotelomer sulfonic acid (4:2 FTS) 1270.01 µg/L 13050




True

Environmental












Summary of Outliers













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ET1801057





Matrix: WATER



ET1801057--003 7439-96-5Manganese0874_SW013_180417 MS recovery not determined,



----Not

Determined



sulfonic acid

(PFHxS)




----Not

Determined







----Not

Determined







----Not

Determined



sulfonic acid

(PFPeS)




----Not

Determined



sulfonic acid

(PFHxS)




----Not

Determined



sulfonic acid

(PFHpS)




----Not

Determined







----Not

Determined



acid (PFPeA)




----Not

Determined



(PFHxA)




----Not

Determined



acid (PFHpA)




----Not

Determined



(PFOA)




----Not

Determined


ET1801057--002 72629-94-8Perfluorotridecanoic

acid (PFTrDA)


objective

30-130%28.6 %EP231B: Perfluoroalkyl Carboxylic Acids

ET1801057--002 376-06-7Perfluorotetradecanoic

acid (PFTeDA)


objective

30-130%26.2 %EP231B: Perfluoroalkyl Carboxylic Acids

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ET1801057



Matrix: WATER



ET1801057--002 1691-99-2N-Ethyl perfluorooctane

sulfonamidoethanol

(EtFOSE)


objective


ET1801057--002 2991-50-6N-Ethyl perfluorooctane

sulfonamidoacetic

acid (EtFOSAA)


objective



Matrix: WATER



overdue

Days

overdue


Method



17-Apr-2018----0874_SW016_180417, 0874_SW013_180417,

0874_SW125_180417, 0874_SW132_180417,

0874_SW010S_180417, 0874_SW126_180417

18-Apr-2018---- ---- 1














0874_SW016_180417, 0874_SW013_180417,

0874_SW125_180417, 0874_SW132_180417,

0874_SW010S_180417, 0874_SW126_180417

17-Apr-2018---- 18-Apr-2018----17-Apr-2018 ---- û



0874_SW016_180417, 0874_SW013_180417,

0874_SW125_180417, 0874_SW132_180417,

0874_SW010S_180417, 0874_SW126_180417

15-May-2018---- 24-Apr-2018----17-Apr-2018 ---- ü

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ET1801057








0874_SW016_180417, 0874_SW013_180417,

0874_SW125_180417, 0874_SW132_180417,

0874_SW010S_180417, 0874_SW126_180417

15-May-2018---- 18-Apr-2018----17-Apr-2018 ---- ü



0874_SW016_180417, 0874_SW013_180417,

0874_SW125_180417, 0874_SW132_180417,

0874_SW010S_180417, 0874_SW126_180417

24-Apr-2018---- 18-Apr-2018----17-Apr-2018 ---- ü



0874_SW016_180417, 0874_SW013_180417,

0874_SW125_180417, 0874_SW132_180417,

0874_SW010S_180417, 0874_SW126_180417

24-Apr-2018---- 18-Apr-2018----17-Apr-2018 ---- ü

EA045: Turbidity


0874_SW016_180417, 0874_SW013_180417,

0874_SW125_180417, 0874_SW132_180417,

0874_SW010S_180417, 0874_SW126_180417

19-Apr-2018---- 18-Apr-2018----17-Apr-2018 ---- ü



0874_SW016_180417, 0874_SW013_180417,

0874_SW125_180417, 0874_SW132_180417,

0874_SW010S_180417, 0874_SW126_180417

15-May-2018---- 24-Apr-2018----17-Apr-2018 ---- ü



0874_SW016_180417, 0874_SW013_180417,

0874_SW125_180417, 0874_SW132_180417,

0874_SW010S_180417, 0874_SW126_180417

01-May-2018---- 18-Apr-2018----17-Apr-2018 ---- ü


0874_SW012_180417, 0874_QC1SW_180417,

0874_QC3SW_180417

01-May-2018---- 19-Apr-2018----17-Apr-2018 ---- ü



0874_SW016_180417, 0874_SW012_180417,

0874_SW013_180417, 0874_SW125_180417,

0874_SW132_180417, 0874_SW010S_180417,

0874_SW126_180417, 0874_QC1SW_180417,

0874_QC3SW_180417

15-May-2018---- 18-Apr-2018----17-Apr-2018 ---- ü

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0874_SW016_180417, 0874_SW012_180417,

0874_SW013_180417, 0874_SW125_180417,

0874_SW132_180417, 0874_SW010S_180417,

0874_SW126_180417, 0874_QC1SW_180417,

0874_QC3SW_180417

15-May-2018---- 18-Apr-2018----17-Apr-2018 ---- ü



0874_SW016_180417, 0874_SW013_180417,

0874_SW125_180417, 0874_SW132_180417,

0874_SW010S_180417, 0874_SW126_180417

15-May-2018---- 24-Apr-2018----17-Apr-2018 ---- ü


0874_SW012_180417, 0874_QC1SW_180417,

0874_QC3SW_180417

24-Apr-2018---- 24-Apr-2018----17-Apr-2018 ---- ü



0874_SW016_180417, 0874_SW013_180417,

0874_SW125_180417, 0874_SW132_180417,

0874_SW010S_180417, 0874_SW126_180417

14-Oct-2018---- 24-Apr-2018----17-Apr-2018 ---- ü



0874_SW016_180417, 0874_SW013_180417,

0874_SW125_180417, 0874_SW132_180417,

0874_SW010S_180417, 0874_SW126_180417

24-Apr-2018---- 23-Apr-2018----17-Apr-2018 ---- ü



0874_SW016_180417, 0874_SW013_180417,

0874_SW125_180417, 0874_SW132_180417,

0874_SW010S_180417, 0874_SW126_180417

15-May-2018---- 18-Apr-2018----17-Apr-2018 ---- ü



0874_SW016_180417, 0874_SW013_180417,

0874_SW125_180417, 0874_SW132_180417,

0874_SW010S_180417, 0874_SW126_180417

15-May-2018---- 19-Apr-2018----17-Apr-2018 ---- ü



0874_SW016_180417, 0874_SW013_180417,

0874_SW125_180417, 0874_SW132_180417,

0874_SW010S_180417, 0874_SW126_180417

19-Apr-2018---- 18-Apr-2018----17-Apr-2018 ---- ü

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0874_SW016_180417, 0874_SW013_180417,

0874_SW125_180417, 0874_SW132_180417,

0874_SW010S_180417, 0874_SW126_180417

15-May-2018---- 19-Apr-2018----17-Apr-2018 ---- ü



0874_SW016_180417, 0874_SW013_180417,

0874_SW125_180417, 0874_SW132_180417,

0874_SW010S_180417, 0874_SW126_180417




0874_SW016_180417, 0874_SW013_180417,

0874_SW125_180417, 0874_SW132_180417,

0874_SW010S_180417, 0874_SW126_180417




0874_SW016_180417, 0874_SW013_180417,

0874_SW125_180417, 0874_SW132_180417,

0874_SW010S_180417, 0874_SW126_180417

19-Apr-2018---- 18-Apr-2018----17-Apr-2018 ---- ü



0874_SW016_180417, 0874_SW013_180417,

0874_SW125_180417, 0874_SW132_180417,

0874_SW010S_180417, 0874_SW126_180417

15-May-2018---- 19-Apr-2018----17-Apr-2018 ---- ü



0874_SW016_180417, 0874_SW013_180417,

0874_SW125_180417, 0874_SW132_180417,

0874_SW010S_180417, 0874_SW126_180417

15-May-2018---- 26-Apr-2018----17-Apr-2018 ---- ü



0874_SW016_180417, 0874_SW013_180417,

0874_SW125_180417, 0874_SW132_180417,

0874_SW010S_180417, 0874_SW126_180417

19-Apr-2018---- 19-Apr-2018----17-Apr-2018 ---- ü

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0874_SW013_180417, 0874_SW125_180417,

0874_SW010S_180417, 0874_SW126_180417,

0874_SW013_180417_F, 0874_SW125_180417_F,

0874_SW132_180417_F, 0874_SW126_180417_F

14-Oct-2018---- 23-Apr-2018----17-Apr-2018 ---- ü


0874_SW016_180417, 0874_SW012_180417,

0874_SW132_180417, 0874_SW016_180417_F,

0874_SW010S_180417_F, 0874_QC1SW_180417,

0874_QC3SW_180417, 0874_QC4SW_180417,

0874_QC5SW_180417




0874_SW013_180417, 0874_SW125_180417,

0874_SW010S_180417, 0874_SW126_180417,

0874_SW013_180417_F, 0874_SW125_180417_F,

0874_SW132_180417_F, 0874_SW126_180417_F

14-Oct-2018---- 23-Apr-2018----17-Apr-2018 ---- ü


0874_SW016_180417, 0874_SW012_180417,

0874_SW132_180417, 0874_SW016_180417_F,

0874_SW010S_180417_F, 0874_QC1SW_180417,

0874_QC3SW_180417, 0874_QC4SW_180417,

0874_QC5SW_180417




0874_SW013_180417, 0874_SW125_180417,

0874_SW010S_180417, 0874_SW126_180417,

0874_SW013_180417_F, 0874_SW125_180417_F,

0874_SW132_180417_F, 0874_SW126_180417_F

14-Oct-2018---- 23-Apr-2018----17-Apr-2018 ---- ü


0874_SW016_180417, 0874_SW012_180417,

0874_SW132_180417, 0874_SW016_180417_F,

0874_SW010S_180417_F, 0874_QC1SW_180417,

0874_QC3SW_180417, 0874_QC4SW_180417,

0874_QC5SW_180417


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0874_SW013_180417, 0874_SW125_180417,

0874_SW010S_180417, 0874_SW126_180417,

0874_SW013_180417_F, 0874_SW125_180417_F,

0874_SW132_180417_F, 0874_SW126_180417_F

14-Oct-2018---- 23-Apr-2018----17-Apr-2018 ---- ü


0874_SW016_180417, 0874_SW012_180417,

0874_SW132_180417, 0874_SW016_180417_F,

0874_SW010S_180417_F, 0874_QC1SW_180417,

0874_QC3SW_180417, 0874_QC4SW_180417,

0874_QC5SW_180417


EP231P: PFAS Sums


0874_SW013_180417, 0874_SW125_180417,

0874_SW010S_180417, 0874_SW126_180417,

0874_SW013_180417_F, 0874_SW125_180417_F,

0874_SW132_180417_F, 0874_SW126_180417_F

14-Oct-2018---- 23-Apr-2018----17-Apr-2018 ---- ü


0874_SW016_180417, 0874_SW012_180417,

0874_SW132_180417, 0874_SW016_180417_F,

0874_SW010S_180417_F, 0874_QC1SW_180417,

0874_QC3SW_180417, 0874_QC4SW_180417,

0874_QC5SW_180417


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Method Blanks (MB)






















Matrix Spikes (MS)








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Schedule B(3)





Conductivity)

EA016 WATER









Schedule B(3)







Discrete Analyser

ED041G WATER











Schedule B(3)


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Schedule B(3)


Analyser

EK059G WATER





Analyser

EK061G WATER


B(3)


Discrete Analyser

EK062G WATER





Schedule B(3)


Analyser

EK067G WATER






Analyser

EK071G WATER


DA

EN055 - PG WATER




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EP026SP WATER






B(3)











(PFAS) by LCMSMS

EP231X WATER










(PFAS) by LCMSMS

EP231X-ST WATER



Schedule B(3)



Environmental





C/O GPO BOX 2907



QLD AUSTRALIA 4814






V4)


Site : ----




Date

27-Apr-2018



: : 17 / 17MEDIUM AND SMALL ESKIESReceipt Detail No. of samples received / analysed

General Comments






l Please be advised that the VOC vials containers for ALS sample #3 is labelled as

'0874_SD013_180417' instead of '0874_SW013_180417' as per the COC.l Discounted Package Prices apply only when specific ALS Group Codes ('W', 'S', 'NT' suites) are referenced on COCs.



l EP231X-ST conducted by ALS Sydney, NATA accreditation no. 825, site no 10911.












ET1801057-012 : [ 17-Apr-2018 ] : 0874_SW010S_180417_F











componentW

AT

ER

- E

G0

20F

Dis

solv

ed

Meta

ls b

y IC

P/M

S

WA

TE

R -

EG

051G

Fe

rro

us

Iron

WA

TE

R -

EP

026S

P

Ch

em

ica

l Oxy

ge

n D

em

and

(C

OD

)

WA

TE

R -

EP

030

BO

D

WA

TE

R -

EP

231X

-ST

PF

AS

- S

up

er

Tra

ce W

ate

rs L

ong

Su

ite (

28

WA

TE

R -

NT

-01 &

02

Ca

, M

g, N

a, K

, C

l, S

O4

, A

lka

linity

WA

TE

R -

NT

-14

Ext

en

de

d W

ate

r S

uite

B

ET1801057-001 17-Apr-2018 00:00 0874_SW016_180417 ü ü ü ü ü ü ü

ET1801057-002 17-Apr-2018 00:00 0874_SW012_180417 ü ü

ET1801057-003 17-Apr-2018 00:00 0874_SW013_180417 ü ü ü ü ü ü

ET1801057-004 17-Apr-2018 00:00 0874_SW125_180417 ü ü ü ü ü ü

ET1801057-005 17-Apr-2018 00:00 0874_SW132_180417 ü ü ü ü ü ü ü

ET1801057-006 17-Apr-2018 00:00 0874_SW010S_180417 ü ü ü ü ü ü

ET1801057-007 17-Apr-2018 00:00 0874_SW126_180417 ü ü ü ü ü ü

ET1801057-008 17-Apr-2018 00:00 0874_SW016_180417_F ü

ET1801057-012 17-Apr-2018 00:00 0874_SW010S_180417_F ü

ET1801057-014 17-Apr-2018 00:00 0874_QC1SW_180417 ü ü

ET1801057-015 17-Apr-2018 00:00 0874_QC3SW_180417 ü ü

ET1801057-016 17-Apr-2018 00:00 0874_QC4SW_180417 ü

ET1801057-017 17-Apr-2018 00:00 0874_QC5SW_180417 ü

Matrix: WATER


ID

Client sampling

date / time

WA

TE

R -

EA

015H

Tota

l Dis

solv

ed S

olid

s -

Sta

ndard

Leve

l

WA

TE

R -

EA

025H

Susp

ended S

olid

s -

Sta

ndard

Leve

l

WA

TE

R -

EA

045

Turb

idity

WA

TE

R -

EP

005

Tota

l Org

anic

Carb

on (

TO

C)

WA

TE

R -

EP

231X

PF

AS

- F

ull

Suite

(28 a

naly

tes)

ET1801057-001 17-Apr-2018 00:00 0874_SW016_180417 ü ü ü ü

ET1801057-003 17-Apr-2018 00:00 0874_SW013_180417 ü ü ü ü ü

ET1801057-004 17-Apr-2018 00:00 0874_SW125_180417 ü ü ü ü ü

ET1801057-005 17-Apr-2018 00:00 0874_SW132_180417 ü ü ü ü

ET1801057-006 17-Apr-2018 00:00 0874_SW010S_180417 ü ü ü ü ü

ET1801057-007 17-Apr-2018 00:00 0874_SW126_180417 ü ü ü ü ü

ET1801057-009 17-Apr-2018 00:00 0874_SW013_180417_F ü

ET1801057-010 17-Apr-2018 00:00 0874_SW125_180417_F ü

ET1801057-011 17-Apr-2018 00:00 0874_SW132_180417_F ü

Matrix: WATER


ID

Client sampling

date / time




WA

TE

R -

EA

01

5H

Tota

l Dis

solv

ed

Solid

s -

Sta

nda

rd L

eve

l

WA

TE

R -

EA

02

5H

Susp

en

de

d S

olid

s -

Sta

nd

ard

Le

vel

WA

TE

R -

EA

04

5

Turb

idity

WA

TE

R -

EP

00

5

Tota

l Org

an

ic C

arb

on

(T

OC

)

WA

TE

R -

EP

23

1X

PF

AS

- F

ull

Suite

(28 a

naly

tes)

ET1801057-013 17-Apr-2018 00:00 0874_SW126_180417_F ü






Due for

extraction

Due for

analysis Evaluation


Date Date

Method

Container


0874_SW010S_180417 û --------18-Apr-201817-Apr-2018----Clear Plastic Bottle - Natural

0874_SW013_180417 û --------18-Apr-201817-Apr-2018----Clear Plastic Bottle - Natural






ACCOUNTS PAYABLE


AU ACCOUNTS PAYABLE


DAVID HARRIS








DERP LABREPORTS


PHIL SCHULZ









RESULTS RESULTS








0 0.00 True

Environmental





C/O GPO BOX 2907








Site : ----






l General Comments














2 of 35:Page

Work Order :

:Client

ET1801059



General Comments







purposes.







Key :

EG020-F (Dissolved Metals by ICP-MS): Limit of reporting raised due to matrix interference.l

EK061G (Total Kjeldahl Nitrogen as N): Sample ET1801059_015 (0874_MW246_S_180417) was diluted due to matrix interference. LOR adjusted accordingly.l



It has been noted that EK071G (Reactive Phosphorus as P) is greater than EK067G (Total Phosphorus as P) for sample ET1801059_017 (0874_MW026_S_180417), however this difference is within the limits of

experimental variation.

l


23313)

l

Ionic Balance out of acceptable limits for some samples due to analytes not quantified in this report.l

EP231X: Particular samples required dilution due to the presence of high level contaminants and/or matrix interference. LOR values have been adjusted accordingly.l


3 of 35:Page

Work Order :

:Client

ET1801059



Analytical Results

0874_MW118_S_1804

17

0874_MW013_S_1804

17

0874_MW129_S_1804

17

0874_MW126_S_1804

17

0874_MW116_S_1804

17


(Matrix: WATER)





6.95 7.04 ---- ---- ----pH Unit0.01----pH Value


17.8^ 14.9 ---- ---- -----0.01----Sodium Adsorption Ratio


7980 382 ---- ---- ----µS/cm1----Electrical Conductivity @ 25°C


5040 447 ---- ---- ----mg/L10----Total Dissolved Solids @180°C


5190 248 ---- ---- ----mg/L1----Total Dissolved Solids (Calc.)


987 1450 ---- ---- ----mg/L5----Suspended Solids (SS)

EA045: Turbidity

632 1580 ---- ---- ----NTU0.1----Turbidity


1120 5 ---- ---- ----mg/L1----Total Hardness as CaCO3









2460Chloride 25 17 3480 87mg/L116887-00-6


226Calcium 2 1 224 3mg/L17440-70-2

135Magnesium <1 <1 188 2mg/L17439-95-4

1370Sodium 91 56 2050 105mg/L17440-23-5

2Potassium <1 <1 2 1mg/L17440-09-7


<0.01Aluminium <0.01 ---- ---- ----mg/L0.017429-90-5

0.094Manganese <0.001 ---- ---- ----mg/L0.0017439-96-5

<0.05Iron <0.05 ---- ---- ----mg/L0.057439-89-6

4 of 35:Page

Work Order :

:Client

ET1801059



Analytical Results

0874_MW118_S_1804

17

0874_MW013_S_1804

17

0874_MW129_S_1804

17

0874_MW126_S_1804

17

0874_MW116_S_1804

17


(Matrix: WATER)





<0.05 <0.05 ---- ---- ----mg/L0.05----Ferrous Iron


0.2Fluoride 0.3 ---- ---- ----mg/L0.116984-48-8


0.03Ammonia as N 0.04 ---- ---- ----mg/L0.017664-41-7


<0.01Nitrite as N <0.01 ---- ---- ----mg/L0.0114797-65-0


<0.01Nitrate as N 0.26 ---- ---- ----mg/L0.0114797-55-8


<0.01 0.26 ---- ---- ----mg/L0.01----Nitrite + Nitrate as N


0.3 0.5 ---- ---- ----mg/L0.1----Total Kjeldahl Nitrogen as N


0.3^ 0.8 ---- ---- ----mg/L0.1----Total Nitrogen as N


0.15 0.27 ---- ---- ----mg/L0.01----Total Phosphorus as P


0.04Reactive Phosphorus as P 0.07 ---- ---- ----mg/L0.0114265-44-2


79.3 4.00 2.56 113 4.72meq/L0.01----Total Anions

82.0 4.06 2.48 116 4.91meq/L0.01----Total Cations

1.66 0.75 ---- 1.04 1.98%0.01----Ionic Balance


3 2 ---- ---- ----mg/L1----Total Organic Carbon


<50 12 ---- ---- ----mg/L10----Chemical Oxygen Demand


4 <2 ---- ---- ----mg/L2----Biochemical Oxygen Demand



(PFBS)

100 ---- ---- ----µg/L0.02375-73-5

5 of 35:Page

Work Order :

:Client

ET1801059



Analytical Results

0874_MW118_S_1804

17

0874_MW013_S_1804

17

0874_MW129_S_1804

17

0874_MW126_S_1804

17

0874_MW116_S_1804

17


(Matrix: WATER)






(PFPeS)

89.8 ---- ---- ----µg/L0.022706-91-4


(PFHxS)

439 ---- ---- ----µg/L0.02355-46-4


(PFHpS)

33.9 ---- ---- ----µg/L0.02375-92-8


(PFOS)

1860 ---- ---- ----µg/L0.011763-23-1


(PFDS)

3.35 ---- ---- ----µg/L0.02335-77-3


----Perfluorobutanoic acid (PFBA) 108 ---- ---- ----µg/L0.1375-22-4

----Perfluoropentanoic acid (PFPeA) 120 ---- ---- ----µg/L0.022706-90-3

----Perfluorohexanoic acid (PFHxA) 875 ---- ---- ----µg/L0.02307-24-4

----Perfluoroheptanoic acid (PFHpA) 51.8 ---- ---- ----µg/L0.02375-85-9

----Perfluorooctanoic acid (PFOA) 127 ---- ---- ----µg/L0.01335-67-1

----Perfluorononanoic acid (PFNA) 3.75 ---- ---- ----µg/L0.02375-95-1

----Perfluorodecanoic acid (PFDA) 0.55 ---- ---- ----µg/L0.02335-76-2


(PFUnDA)

<0.50 ---- ---- ----µg/L0.022058-94-8


(PFDoDA)

<0.50 ---- ---- ----µg/L0.02307-55-1


(PFTrDA)

<0.50 ---- ---- ----µg/L0.0272629-94-8


(PFTeDA)

<1.25 ---- ---- ----µg/L0.05376-06-7



(FOSA)

<0.50 ---- ---- ----µg/L0.02754-91-6



<1.25 ---- ---- ----µg/L0.0531506-32-8



<1.25 ---- ---- ----µg/L0.054151-50-2



<1.25 ---- ---- ----µg/L0.0524448-09-7

6 of 35:Page

Work Order :

:Client

ET1801059



Analytical Results

0874_MW118_S_1804

17

0874_MW013_S_1804

17

0874_MW129_S_1804

17

0874_MW126_S_1804

17

0874_MW116_S_1804

17


(Matrix: WATER)







<1.25 ---- ---- ----µg/L0.051691-99-2



(MeFOSAA)

<0.50 ---- ---- ----µg/L0.022355-31-9



(EtFOSAA)

<0.50 ---- ---- ----µg/L0.022991-50-6



(4:2 FTS)

<0.50 ---- ---- ----µg/L0.05757124-72-4


(6:2 FTS)

<0.50 ---- ---- ----µg/L0.0527619-97-2


(8:2 FTS)

<0.50 ---- ---- ----µg/L0.0539108-34-4


(10:2 FTS)

<0.50 ---- ---- ----µg/L0.05120226-60-0


---- 3810 ---- ---- ----µg/L0.01----Sum of PFAS

----Sum of PFHxS and PFOS 2300 ---- ---- ----µg/L0.01355-46-4/1763-23-

1

---- 3810 ---- ---- ----µg/L0.01----Sum of TOP C4 - C14 Carboxylates and C4

- C8 Sulfonates

----^ 2460 ---- ---- ----µg/L0.01----Sum of TOP C4 - C14 as Fluorine



(PFBS)

20.2 1.20 17.9 0.12µg/L0.02375-73-5


(PFPeS)

15.6 0.93 20.0 0.07µg/L0.022706-91-4


(PFHxS)

81.8 6.22 71.7 0.31µg/L0.02355-46-4


(PFHpS)

7.92 0.60 12.1 <0.02µg/L0.02375-92-8


(PFOS)

342 45.8 268 1.29µg/L0.011763-23-1

7 of 35:Page

Work Order :

:Client

ET1801059



Analytical Results

0874_MW118_S_1804

17

0874_MW013_S_1804

17

0874_MW129_S_1804

17

0874_MW126_S_1804

17

0874_MW116_S_1804

17


(Matrix: WATER)





0.12Perfluorodecane sulfonic acid

(PFDS)

0.48 1.06 <0.02 <0.02µg/L0.02335-77-3







0.02Perfluorononanoic acid (PFNA) 0.47 0.16 0.08 <0.02µg/L0.02375-95-1

<0.02Perfluorodecanoic acid (PFDA) 0.05 0.09 <0.02 <0.02µg/L0.02335-76-2


(PFUnDA)

<0.02 0.02 <0.02 <0.02µg/L0.022058-94-8


(PFDoDA)

<0.02 <0.02 <0.02 <0.02µg/L0.02307-55-1


(PFTrDA)

<0.02 <0.02 <0.02 <0.02µg/L0.0272629-94-8


(PFTeDA)

<0.05 <0.05 <0.05 <0.05µg/L0.05376-06-7



(FOSA)

0.29 0.38 <0.02 <0.02µg/L0.02754-91-6



<0.05 <0.05 <0.05 <0.05µg/L0.0531506-32-8



<0.05 <0.05 <0.05 <0.05µg/L0.054151-50-2



<0.05 <0.05 <0.05 <0.05µg/L0.0524448-09-7



<0.05 <0.05 <0.05 <0.05µg/L0.051691-99-2



(MeFOSAA)

<0.02 <0.02 <0.02 <0.02µg/L0.022355-31-9



(EtFOSAA)

<0.02 <0.02 <0.02 <0.02µg/L0.022991-50-6

8 of 35:Page

Work Order :

:Client

ET1801059



Analytical Results

0874_MW118_S_1804

17

0874_MW013_S_1804

17

0874_MW129_S_1804

17

0874_MW126_S_1804

17

0874_MW116_S_1804

17


(Matrix: WATER)






(4:2 FTS)

<0.05 <0.05 <0.05 <0.05µg/L0.05757124-72-4


(6:2 FTS)

0.50 1.11 4.00 0.09µg/L0.0527619-97-2


(8:2 FTS)

0.12 0.87 <0.05 <0.05µg/L0.0539108-34-4


(10:2 FTS)

<0.05 <0.05 <0.05 <0.05µg/L0.05120226-60-0

EP231P: PFAS Sums

147 565 68.8 485 2.41µg/L0.01----Sum of PFAS

83.2Sum of PFHxS and PFOS 424 52.0 340 1.60µg/L0.01355-46-4/1763-23-

1

135 540 65.6 453 2.34µg/L0.01----Sum of PFAS (WA DER List)


---- 110 ---- ---- ----%0.02----13C4-PFOS

---- 125 ---- ---- ----%0.02----13C8-PFOA


93.3 86.1 88.6 95.1 91.9%0.02----13C4-PFOS

96.7 99.7 99.2 99.9 102%0.02----13C8-PFOA

9 of 35:Page

Work Order :

:Client

ET1801059



Analytical Results

0874_MW063_S_1804

17

0874_MW061_S_1804

17

0874_MW120_S_1804

17

0874_MW033_S_1804

17

0874_MW034_S_1804

17


(Matrix: WATER)





---- ---- 7.08 7.78 7.41pH Unit0.01----pH Value


----^ ---- 26.2 24.0 33.1-0.01----Sodium Adsorption Ratio


---- ---- 11200 2120 7020µS/cm1----Electrical Conductivity @ 25°C


---- ---- 6850 1250 3940mg/L10----Total Dissolved Solids @180°C


---- ---- 7280 1380 4560mg/L1----Total Dissolved Solids (Calc.)


---- ---- 740 102 168mg/L5----Suspended Solids (SS)

EA045: Turbidity

---- ---- 241 47.5 48.8NTU0.1----Turbidity


---- ---- 1280 50 343mg/L1----Total Hardness as CaCO3









3630Chloride 28 3280 324 1780mg/L116887-00-6


319Calcium 27 203 7 55mg/L17440-70-2

210Magnesium 5 188 8 50mg/L17439-95-4

1940Sodium 75 2160 424 1410mg/L17440-23-5

2Potassium 1 8 <1 2mg/L17440-09-7


----Aluminium ---- <0.01 <0.01 <0.01mg/L0.017429-90-5

----Manganese ---- 0.069 0.002 0.003mg/L0.0017439-96-5

----Iron ---- <0.05 <0.05 <0.05mg/L0.057439-89-6

10 of 35:Page

Work Order :

:Client

ET1801059



Analytical Results

0874_MW063_S_1804

17

0874_MW061_S_1804

17

0874_MW120_S_1804

17

0874_MW033_S_1804

17

0874_MW034_S_1804

17


(Matrix: WATER)





---- ---- <0.05 <0.05 <0.05mg/L0.05----Ferrous Iron


----Fluoride ---- 0.5 2.0 0.3mg/L0.116984-48-8


----Ammonia as N ---- 0.02 0.01 0.03mg/L0.017664-41-7


----Nitrite as N ---- <0.01 <0.01 <0.01mg/L0.0114797-65-0


----Nitrate as N ---- 0.12 0.08 0.95mg/L0.0114797-55-8


---- ---- 0.12 0.08 0.95mg/L0.01----Nitrite + Nitrate as N


---- ---- 0.2 <0.1 <0.1mg/L0.1----Total Kjeldahl Nitrogen as N


----^ ---- 0.3 <0.1 1.0mg/L0.1----Total Nitrogen as N


---- ---- 0.14 0.03 0.02mg/L0.01----Total Phosphorus as P


----Reactive Phosphorus as P ---- 0.14 <0.01 0.01mg/L0.0114265-44-2


117 4.80 115 22.6 64.1meq/L0.01----Total Anions

118 5.05 120 19.4 68.2meq/L0.01----Total Cations

0.11 2.53 1.83 7.43 3.09%0.01----Ionic Balance


---- ---- 7 4 7mg/L1----Total Organic Carbon


---- ---- <50 11 <50mg/L10----Chemical Oxygen Demand


---- ---- <2 3 <2mg/L2----Biochemical Oxygen Demand



(PFBS)

0.79 4.17 0.67 1.74µg/L0.02375-73-5

11 of 35:Page

Work Order :

:Client

ET1801059



Analytical Results

0874_MW063_S_1804

17

0874_MW061_S_1804

17

0874_MW120_S_1804

17

0874_MW033_S_1804

17

0874_MW034_S_1804

17


(Matrix: WATER)






(PFPeS)

0.92 4.72 0.97 2.40µg/L0.022706-91-4


(PFHxS)

7.99 29.4 8.75 15.3µg/L0.02355-46-4


(PFHpS)

0.77 1.52 0.64 1.22µg/L0.02375-92-8


(PFOS)

30.7 23.3 20.6 28.3µg/L0.011763-23-1


(PFDS)

0.54 <0.02 <0.02 <0.02µg/L0.02335-77-3







<0.02Perfluorononanoic acid (PFNA) 0.13 0.02 <0.02 <0.02µg/L0.02375-95-1

<0.02Perfluorodecanoic acid (PFDA) 0.04 <0.02 <0.02 <0.02µg/L0.02335-76-2


(PFUnDA)

<0.02 <0.02 <0.02 <0.02µg/L0.022058-94-8


(PFDoDA)

<0.02 <0.02 <0.02 <0.02µg/L0.02307-55-1


(PFTrDA)

<0.02 <0.02 <0.02 <0.02µg/L0.0272629-94-8


(PFTeDA)

<0.05 <0.05 <0.05 <0.05µg/L0.05376-06-7



(FOSA)

0.60 <0.02 0.04 <0.02µg/L0.02754-91-6



<0.05 <0.05 <0.05 <0.05µg/L0.0531506-32-8



<0.05 <0.05 <0.05 <0.05µg/L0.054151-50-2



<0.05 <0.05 <0.05 <0.05µg/L0.0524448-09-7

12 of 35:Page

Work Order :

:Client

ET1801059



Analytical Results

0874_MW063_S_1804

17

0874_MW061_S_1804

17

0874_MW120_S_1804

17

0874_MW033_S_1804

17

0874_MW034_S_1804

17


(Matrix: WATER)







<0.05 <0.05 <0.05 <0.05µg/L0.051691-99-2



(MeFOSAA)

<0.02 <0.02 <0.02 <0.02µg/L0.022355-31-9



(EtFOSAA)

<0.02 <0.02 <0.02 <0.02µg/L0.022991-50-6



(4:2 FTS)

<0.05 <0.05 <0.05 <0.05µg/L0.05757124-72-4


(6:2 FTS)

0.12 <0.05 <0.05 0.27µg/L0.0527619-97-2


(8:2 FTS)

0.15 <0.05 <0.05 <0.05µg/L0.0539108-34-4


(10:2 FTS)

<0.05 <0.05 <0.05 <0.05µg/L0.05120226-60-0

EP231P: PFAS Sums

35.4 50.0 78.0 35.6 58.5µg/L0.01----Sum of PFAS


1



94.8 84.7 103 90.9 103%0.02----13C4-PFOS

99.8 102 95.3 95.6 98.5%0.02----13C8-PFOA

13 of 35:Page

Work Order :

:Client

ET1801059



Analytical Results

0874_MW246_S_1804

17

0874_MW245_S_1804

17

0874_MW122_S_1804

17

0874_MW135_S_1804

17

0874_MW056_S_1804

17


(Matrix: WATER)





---- ---- ---- 6.47 6.93pH Unit0.01----pH Value


----^ ---- ---- 21.6 35.4-0.01----Sodium Adsorption Ratio


---- ---- ---- 4810 31200µS/cm1----Electrical Conductivity @ 25°C


---- ---- ---- 2660 20800mg/L10----Total Dissolved Solids @180°C


---- ---- ---- 3130 20300mg/L1----Total Dissolved Solids (Calc.)


---- ---- ---- 443 960mg/L5----Suspended Solids (SS)

EA045: Turbidity

---- ---- ---- 599 472NTU0.1----Turbidity


---- ---- ---- 602 2810mg/L1----Total Hardness as CaCO3









6450Chloride 8240 5140 1140 9810mg/L116887-00-6


456Calcium 600 250 76 267mg/L17440-70-2

286Magnesium 1120 471 100 521mg/L17439-95-4

3610Sodium 6400 3710 1200 4350mg/L17440-23-5

90Potassium 158 160 47 107mg/L17440-09-7


----Aluminium ---- ---- <0.01 <0.01mg/L0.017429-90-5

----Manganese ---- ---- 4.28 0.561mg/L0.0017439-96-5

----Iron ---- ---- 29.0 0.06mg/L0.057439-89-6

14 of 35:Page

Work Order :

:Client

ET1801059



Analytical Results

0874_MW246_S_1804

17

0874_MW245_S_1804

17

0874_MW122_S_1804

17

0874_MW135_S_1804

17

0874_MW056_S_1804

17


(Matrix: WATER)





---- ---- ---- 36.5 <0.05mg/L0.05----Ferrous Iron


----Fluoride ---- ---- 0.7 0.6mg/L0.116984-48-8


----Ammonia as N ---- ---- 0.89 0.05mg/L0.017664-41-7


----Nitrite as N ---- ---- 0.09 <0.01mg/L0.0114797-65-0


----Nitrate as N ---- ---- 0.10 0.45mg/L0.0114797-55-8


---- ---- ---- 0.19 0.45mg/L0.01----Nitrite + Nitrate as N


---- ---- ---- 2.7 <0.5mg/L0.1----Total Kjeldahl Nitrogen as N


----^ ---- ---- 2.9 <0.5mg/L0.1----Total Nitrogen as N


---- ---- ---- 0.17 0.13mg/L0.01----Total Phosphorus as P


----Reactive Phosphorus as P ---- ---- <0.01 0.02mg/L0.0114265-44-2


200 400 218 42.4 302meq/L0.01----Total Anions

206 404 217 65.4 248meq/L0.01----Total Cations

1.40 0.52 0.24 21.4 9.84%0.01----Ionic Balance


---- ---- ---- 10 8mg/L1----Total Organic Carbon


---- ---- ---- 51 220mg/L10----Chemical Oxygen Demand


---- ---- ---- 7 ----mg/L2----Biochemical Oxygen Demand



(PFBS)

---- ---- 19.6 ----µg/L0.02375-73-5

15 of 35:Page

Work Order :

:Client

ET1801059



Analytical Results

0874_MW246_S_1804

17

0874_MW245_S_1804

17

0874_MW122_S_1804

17

0874_MW135_S_1804

17

0874_MW056_S_1804

17


(Matrix: WATER)






(PFPeS)

---- ---- 37.0 ----µg/L0.022706-91-4


(PFHxS)

---- ---- 263 ----µg/L0.02355-46-4


(PFHpS)

---- ---- 9.32 ----µg/L0.02375-92-8


(PFOS)

---- ---- 59.6 ----µg/L0.011763-23-1


(PFDS)

---- ---- <0.10 ----µg/L0.02335-77-3


----Perfluorobutanoic acid (PFBA) ---- ---- 41.3 ----µg/L0.1375-22-4








(PFUnDA)

---- ---- <0.10 ----µg/L0.022058-94-8


(PFDoDA)

---- ---- <0.10 ----µg/L0.02307-55-1


(PFTrDA)

---- ---- <0.10 ----µg/L0.0272629-94-8


(PFTeDA)

---- ---- <0.25 ----µg/L0.05376-06-7



(FOSA)

---- ---- <0.10 ----µg/L0.02754-91-6



---- ---- <0.25 ----µg/L0.0531506-32-8



---- ---- <0.25 ----µg/L0.054151-50-2



---- ---- <0.25 ----µg/L0.0524448-09-7

16 of 35:Page

Work Order :

:Client

ET1801059



Analytical Results

0874_MW246_S_1804

17

0874_MW245_S_1804

17

0874_MW122_S_1804

17

0874_MW135_S_1804

17

0874_MW056_S_1804

17


(Matrix: WATER)







---- ---- <0.25 ----µg/L0.051691-99-2



(MeFOSAA)

---- ---- <0.10 ----µg/L0.022355-31-9



(EtFOSAA)

---- ---- <0.10 ----µg/L0.022991-50-6



(4:2 FTS)

---- ---- <0.10 ----µg/L0.05757124-72-4


(6:2 FTS)

---- ---- <0.10 ----µg/L0.0527619-97-2


(8:2 FTS)

---- ---- <0.10 ----µg/L0.0539108-34-4


(10:2 FTS)

---- ---- <0.10 ----µg/L0.05120226-60-0


---- ---- ---- 579 ----µg/L0.01----Sum of PFAS

----Sum of PFHxS and PFOS ---- ---- 323 ----µg/L0.01355-46-4/1763-23-

1

---- ---- ---- 579 ----µg/L0.01----Sum of TOP C4 - C14 Carboxylates and C4

- C8 Sulfonates

----^ ---- ---- 365 ----µg/L0.01----Sum of TOP C4 - C14 as Fluorine



(PFBS)

0.67 <0.05 18.5 3.93µg/L0.02375-73-5


(PFPeS)

0.71 <0.05 30.4 5.43µg/L0.022706-91-4


(PFHxS)

7.89 0.10 259 53.8µg/L0.02355-46-4


(PFHpS)

0.16 <0.05 10.8 5.18µg/L0.02375-92-8


(PFOS)

0.87 <0.05 60.2 198µg/L0.011763-23-1

17 of 35:Page

Work Order :

:Client

ET1801059



Analytical Results

0874_MW246_S_1804

17

0874_MW245_S_1804

17

0874_MW122_S_1804

17

0874_MW135_S_1804

17

0874_MW056_S_1804

17


(Matrix: WATER)






(PFDS)

<0.10 <0.05 <0.02 0.49µg/L0.02335-77-3


0.6Perfluorobutanoic acid (PFBA) <0.5 <0.2 8.3 1.3µg/L0.1375-22-4

0.34Perfluoropentanoic acid (PFPeA) 0.21 <0.05 8.59 2.82µg/L0.022706-90-3

0.85Perfluorohexanoic acid (PFHxA) 1.15 <0.05 54.4 20.3µg/L0.02307-24-4

<0.10Perfluoroheptanoic acid (PFHpA) <0.10 <0.05 13.6 1.50µg/L0.02375-85-9

<0.10Perfluorooctanoic acid (PFOA) <0.10 <0.05 21.0 3.50µg/L0.01335-67-1

<0.10Perfluorononanoic acid (PFNA) <0.10 <0.05 0.11 <0.10µg/L0.02375-95-1



(PFUnDA)

<0.10 <0.05 <0.02 <0.10µg/L0.022058-94-8


(PFDoDA)

<0.10 <0.05 <0.02 <0.10µg/L0.02307-55-1


(PFTrDA)

<0.10 <0.05 <0.02 <0.10µg/L0.0272629-94-8


(PFTeDA)

<0.25 <0.12 <0.05 <0.25µg/L0.05376-06-7



(FOSA)

<0.10 <0.05 0.05 0.75µg/L0.02754-91-6



<0.25 <0.12 <0.05 <0.25µg/L0.0531506-32-8



<0.25 <0.12 <0.05 <0.25µg/L0.054151-50-2



<0.25 <0.12 <0.05 <0.25µg/L0.0524448-09-7



<0.25 <0.12 <0.05 <0.25µg/L0.051691-99-2



(MeFOSAA)

<0.10 <0.05 <0.02 <0.10µg/L0.022355-31-9



(EtFOSAA)

<0.10 <0.05 <0.02 <0.10µg/L0.022991-50-6

18 of 35:Page

Work Order :

:Client

ET1801059



Analytical Results

0874_MW246_S_1804

17

0874_MW245_S_1804

17

0874_MW122_S_1804

17

0874_MW135_S_1804

17

0874_MW056_S_1804

17


(Matrix: WATER)






(4:2 FTS)

<0.10 <0.05 <0.05 <0.10µg/L0.05757124-72-4


(6:2 FTS)

0.10 <0.05 1.10 <0.10µg/L0.0527619-97-2


(8:2 FTS)

<0.10 <0.05 0.15 <0.10µg/L0.0539108-34-4


(10:2 FTS)

<0.10 <0.05 <0.05 <0.10µg/L0.05120226-60-0

EP231P: PFAS Sums

7.13 11.8 0.10 486 297µg/L0.01----Sum of PFAS

3.46Sum of PFHxS and PFOS 8.76 0.10 319 252µg/L0.01355-46-4/1763-23-

1

6.58 10.9 0.10 445 285µg/L0.01----Sum of PFAS (WA DER List)


---- ---- ---- 105 ----%0.02----13C4-PFOS

---- ---- ---- 110 ----%0.02----13C8-PFOA


93.0 98.0 99.1 92.2 89.0%0.02----13C4-PFOS

97.2 97.9 92.3 91.2 91.0%0.02----13C8-PFOA

19 of 35:Page

Work Order :

:Client

ET1801059



Analytical Results

0874_MW265_S_1804

17

0874_MW136_S_1804

17

0874_MW243_S_1804

17

0874_MW026_S_1804

17

0874_MW232_S_1804

17


(Matrix: WATER)





8.11 7.40 6.62 ---- ----pH Unit0.01----pH Value


30.8^ 28.2 61.3 ---- -----0.01----Sodium Adsorption Ratio


2570 3830 45500 ---- ----µS/cm1----Electrical Conductivity @ 25°C


1530 2120 40200 ---- ----mg/L10----Total Dissolved Solids @180°C


1670 2490 29600 ---- ----mg/L1----Total Dissolved Solids (Calc.)


289 295 2240 ---- ----mg/L5----Suspended Solids (SS)

EA045: Turbidity

174 139 1730 ---- ----NTU0.1----Turbidity


87 143 6880 ---- ----mg/L1----Total Hardness as CaCO3









334Chloride 794 18000 125 12500mg/L116887-00-6


10Calcium 26 465 12 536mg/L17440-70-2

15Magnesium 19 1390 8 1330mg/L17439-95-4

659Sodium 775 11700 284 8360mg/L17440-23-5

<1Potassium <1 315 10 148mg/L17440-09-7


<0.01Aluminium <0.01 <0.05 ---- ----mg/L0.017429-90-5

0.002Manganese 0.081 1.80 ---- ----mg/L0.0017439-96-5

<0.05Iron <0.05 <0.05 ---- ----mg/L0.057439-89-6

20 of 35:Page

Work Order :

:Client

ET1801059



Analytical Results

0874_MW265_S_1804

17

0874_MW136_S_1804

17

0874_MW243_S_1804

17

0874_MW026_S_1804

17

0874_MW232_S_1804

17


(Matrix: WATER)





<0.05 <0.05 <0.05 ---- ----mg/L0.05----Ferrous Iron


1.4Fluoride 0.5 0.2 ---- ----mg/L0.116984-48-8


<0.01Ammonia as N <0.01 0.14 ---- ----mg/L0.017664-41-7


<0.01Nitrite as N <0.01 <0.01 ---- ----mg/L0.0114797-65-0


12.1Nitrate as N 0.13 1.10 ---- ----mg/L0.0114797-55-8


12.1 0.13 1.10 ---- ----mg/L0.01----Nitrite + Nitrate as N


1.2 <0.1 1.2 ---- ----mg/L0.1----Total Kjeldahl Nitrogen as N


13.3^ 0.1 2.3 ---- ----mg/L0.1----Total Nitrogen as N


0.09 0.10 0.44 ---- ----mg/L0.01----Total Phosphorus as P


0.05Reactive Phosphorus as P 0.11 0.02 ---- ----mg/L0.0114265-44-2


25.2 36.4 597 12.5 460meq/L0.01----Total Anions

30.4 36.6 654 13.9 504meq/L0.01----Total Cations

9.44 0.18 4.63 5.16 4.58%0.01----Ionic Balance


8 2 5 ---- ----mg/L1----Total Organic Carbon


19 15 340 ---- ----mg/L10----Chemical Oxygen Demand


<2 <2 <2 ---- ----mg/L2----Biochemical Oxygen Demand



(PFBS)

---- ---- ---- 0.31µg/L0.02375-73-5

21 of 35:Page

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:Client

ET1801059



Analytical Results

0874_MW265_S_1804

17

0874_MW136_S_1804

17

0874_MW243_S_1804

17

0874_MW026_S_1804

17

0874_MW232_S_1804

17


(Matrix: WATER)






(PFPeS)

---- ---- ---- 0.13µg/L0.022706-91-4


(PFHxS)

---- ---- ---- 0.36µg/L0.02355-46-4


(PFHpS)

---- ---- ---- <0.02µg/L0.02375-92-8


(PFOS)

---- ---- ---- 0.10µg/L0.011763-23-1


(PFDS)

---- ---- ---- <0.02µg/L0.02335-77-3


0.4Perfluorobutanoic acid (PFBA) ---- ---- ---- <0.1µg/L0.1375-22-4

0.34Perfluoropentanoic acid (PFPeA) ---- ---- ---- 0.04µg/L0.022706-90-3


0.17Perfluoroheptanoic acid (PFHpA) ---- ---- ---- 0.02µg/L0.02375-85-9


<0.02Perfluorononanoic acid (PFNA) ---- ---- ---- <0.02µg/L0.02375-95-1

<0.02Perfluorodecanoic acid (PFDA) ---- ---- ---- <0.02µg/L0.02335-76-2


(PFUnDA)

---- ---- ---- <0.02µg/L0.022058-94-8


(PFDoDA)

---- ---- ---- <0.02µg/L0.02307-55-1


(PFTrDA)

---- ---- ---- <0.02µg/L0.0272629-94-8


(PFTeDA)

---- ---- ---- <0.05µg/L0.05376-06-7



(FOSA)

---- ---- ---- <0.02µg/L0.02754-91-6



---- ---- ---- <0.05µg/L0.0531506-32-8



---- ---- ---- <0.05µg/L0.054151-50-2



---- ---- ---- <0.05µg/L0.0524448-09-7

22 of 35:Page

Work Order :

:Client

ET1801059



Analytical Results

0874_MW265_S_1804

17

0874_MW136_S_1804

17

0874_MW243_S_1804

17

0874_MW026_S_1804

17

0874_MW232_S_1804

17


(Matrix: WATER)







---- ---- ---- <0.05µg/L0.051691-99-2



(MeFOSAA)

---- ---- ---- <0.02µg/L0.022355-31-9



(EtFOSAA)

---- ---- ---- <0.02µg/L0.022991-50-6



(4:2 FTS)

---- ---- ---- <0.05µg/L0.05757124-72-4


(6:2 FTS)

---- ---- ---- <0.05µg/L0.0527619-97-2


(8:2 FTS)

---- ---- ---- 0.06µg/L0.0539108-34-4


(10:2 FTS)

---- ---- ---- <0.05µg/L0.05120226-60-0


19.5 ---- ---- ---- 1.20µg/L0.01----Sum of PFAS


1

19.5 ---- ---- ---- 1.14µg/L0.01----Sum of TOP C4 - C14 Carboxylates and C4

- C8 Sulfonates

12.4^ ---- ---- ---- 0.70µg/L0.01----Sum of TOP C4 - C14 as Fluorine



(PFBS)

0.28 162 0.10 1.81µg/L0.02375-73-5


(PFPeS)

0.34 164 0.07 0.78µg/L0.022706-91-4


(PFHxS)

3.06 1010 0.58 2.22µg/L0.02355-46-4


(PFHpS)

0.29 76.9 0.04 <0.10µg/L0.02375-92-8


(PFOS)

12.5 366 1.15 0.24µg/L0.011763-23-1

23 of 35:Page

Work Order :

:Client

ET1801059



Analytical Results

0874_MW265_S_1804

17

0874_MW136_S_1804

17

0874_MW243_S_1804

17

0874_MW026_S_1804

17

0874_MW232_S_1804

17


(Matrix: WATER)






(PFDS)

<0.02 <0.10 <0.02 <0.10µg/L0.02335-77-3


0.2Perfluorobutanoic acid (PFBA) 0.1 29.3 <0.1 <0.5µg/L0.1375-22-4


0.61Perfluorohexanoic acid (PFHxA) 0.81 302 0.22 0.47µg/L0.02307-24-4






(PFUnDA)

<0.02 <0.10 <0.02 <0.10µg/L0.022058-94-8


(PFDoDA)

<0.02 <0.10 <0.02 <0.10µg/L0.02307-55-1


(PFTrDA)

<0.02 <0.10 <0.02 <0.10µg/L0.0272629-94-8


(PFTeDA)

<0.05 <0.25 <0.05 <0.25µg/L0.05376-06-7



(FOSA)

0.05 <0.10 <0.02 <0.10µg/L0.02754-91-6



<0.05 <0.25 <0.05 <0.25µg/L0.0531506-32-8



<0.05 <0.25 <0.05 <0.25µg/L0.054151-50-2



<0.05 <0.25 <0.05 <0.25µg/L0.0524448-09-7



<0.05 <0.25 <0.05 <0.25µg/L0.051691-99-2



(MeFOSAA)

<0.02 <0.10 <0.02 <0.10µg/L0.022355-31-9



(EtFOSAA)

<0.02 <0.10 <0.02 <0.10µg/L0.022991-50-6

24 of 35:Page

Work Order :

:Client

ET1801059



Analytical Results

0874_MW265_S_1804

17

0874_MW136_S_1804

17

0874_MW243_S_1804

17

0874_MW026_S_1804

17

0874_MW232_S_1804

17


(Matrix: WATER)






(4:2 FTS)

<0.05 <0.10 <0.05 <0.10µg/L0.05757124-72-4


(6:2 FTS)

<0.05 3.15 <0.05 <0.10µg/L0.0527619-97-2


(8:2 FTS)

<0.05 <0.10 <0.05 <0.10µg/L0.0539108-34-4


(10:2 FTS)

<0.05 <0.10 <0.05 <0.10µg/L0.05120226-60-0

EP231P: PFAS Sums

16.6 18.1 2250 2.33 5.65µg/L0.01----Sum of PFAS

13.8Sum of PFHxS and PFOS 15.6 1380 1.73 2.46µg/L0.01355-46-4/1763-23-

1

15.7 17.4 2010 2.22 4.87µg/L0.01----Sum of PFAS (WA DER List)


89.5 ---- ---- ---- 81.0%0.02----13C4-PFOS

116 ---- ---- ---- 112%0.02----13C8-PFOA


100 95.5 91.9 96.6 94.8%0.02----13C4-PFOS

90.7 93.6 93.7 92.2 95.2%0.02----13C8-PFOA

25 of 35:Page

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:Client

ET1801059



Analytical Results

0874_MW061_S_1804

17_F

0874_MW120_S_1804

17_F

0874_MW126_S_1804

17_F

0874_MW116_S_1804

17_F

0874_MW004_S_1804

17


(Matrix: WATER)





<1Hydroxide Alkalinity as CaCO3 ---- ---- ---- ----mg/L1DMO-210-001

<1Carbonate Alkalinity as CaCO3 ---- ---- ---- ----mg/L13812-32-6

54Bicarbonate Alkalinity as CaCO3 ---- ---- ---- ----mg/L171-52-3

54 ---- ---- ---- ----mg/L1----Total Alkalinity as CaCO3


34Sulfate as SO4 - Turbidimetric ---- ---- ---- ----mg/L114808-79-8


56Chloride ---- ---- ---- ----mg/L116887-00-6


4Calcium ---- ---- ---- ----mg/L17440-70-2

3Magnesium ---- ---- ---- ----mg/L17439-95-4

72Sodium ---- ---- ---- ----mg/L17440-23-5

3Potassium ---- ---- ---- ----mg/L17440-09-7


3.37 ---- ---- ---- ----meq/L0.01----Total Anions

3.66 ---- ---- ---- ----meq/L0.01----Total Cations

4.11 ---- ---- ---- ----%0.01----Ionic Balance



(PFBS)

3.40 4.80 2.08 0.36µg/L0.02375-73-5


(PFPeS)

0.74 0.39 1.10 0.32µg/L0.022706-91-4


(PFHxS)

0.20 <0.02 2.74 0.71µg/L0.02355-46-4


(PFHpS)

<0.02 <0.02 <0.05 <0.02µg/L0.02375-92-8


(PFOS)

<0.02 <0.01 <0.05 <0.01µg/L0.011763-23-1


(PFDS)

<0.02 <0.02 <0.05 <0.02µg/L0.02335-77-3


<0.1Perfluorobutanoic acid (PFBA) 3.2 8.5 1.4 0.4µg/L0.1375-22-4

<0.02Perfluoropentanoic acid (PFPeA) 3.33 9.44 1.75 0.44µg/L0.022706-90-3

<0.02Perfluorohexanoic acid (PFHxA) 15.3 37.6 8.53 1.94µg/L0.02307-24-4

26 of 35:Page

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:Client

ET1801059



Analytical Results

0874_MW061_S_1804

17_F

0874_MW120_S_1804

17_F

0874_MW126_S_1804

17_F

0874_MW116_S_1804

17_F

0874_MW004_S_1804

17


(Matrix: WATER)





<0.02Perfluoroheptanoic acid (PFHpA) 1.83 5.26 0.68 0.20µg/L0.02375-85-9

<0.01Perfluorooctanoic acid (PFOA) 1.07 4.84 0.59 0.37µg/L0.01335-67-1




(PFUnDA)

<0.02 <0.02 <0.05 <0.02µg/L0.022058-94-8


(PFDoDA)

<0.02 <0.02 <0.05 <0.02µg/L0.02307-55-1


(PFTrDA)

<0.02 <0.02 <0.05 <0.02µg/L0.0272629-94-8


(PFTeDA)

<0.05 <0.05 <0.12 <0.05µg/L0.05376-06-7



(FOSA)

<0.02 <0.02 <0.05 <0.02µg/L0.02754-91-6



<0.05 <0.05 <0.12 <0.05µg/L0.0531506-32-8



<0.05 <0.05 <0.12 <0.05µg/L0.054151-50-2



<0.05 <0.05 <0.12 <0.05µg/L0.0524448-09-7



<0.05 <0.05 <0.12 <0.05µg/L0.051691-99-2



(MeFOSAA)

<0.02 <0.02 <0.05 <0.02µg/L0.022355-31-9



(EtFOSAA)

<0.02 <0.02 <0.05 <0.02µg/L0.022991-50-6



(4:2 FTS)

<0.05 <0.05 <0.05 <0.05µg/L0.05757124-72-4


(6:2 FTS)

<0.05 0.29 <0.05 <0.05µg/L0.0527619-97-2


(8:2 FTS)

<0.05 <0.05 <0.05 <0.05µg/L0.0539108-34-4

27 of 35:Page

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:Client

ET1801059



Analytical Results

0874_MW061_S_1804

17_F

0874_MW120_S_1804

17_F

0874_MW126_S_1804

17_F

0874_MW116_S_1804

17_F

0874_MW004_S_1804

17


(Matrix: WATER)






(10:2 FTS)

<0.05 <0.05 <0.05 <0.05µg/L0.05120226-60-0

EP231P: PFAS Sums

0.16 29.1 71.1 18.9 4.74µg/L0.01----Sum of PFAS

0.14Sum of PFHxS and PFOS 0.20 <0.01 2.74 0.71µg/L0.01355-46-4/1763-23-

1



97.0 94.8 98.8 97.5 97.3%0.02----13C4-PFOS

95.3 92.4 96.1 91.1 91.9%0.02----13C8-PFOA

28 of 35:Page

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:Client

ET1801059



Analytical Results

0874_MW026_S_1804

17_F

0874_MW232_S_1804

17_F

0874_MW246_S_1804

17_F

0874_MW245_S_1804

17_F

0874_MW063_S_1804

17_F


(Matrix: WATER)






(PFBS)

3.98 2.20 0.18 0.22µg/L0.02375-73-5


(PFPeS)

1.68 0.20 <0.02 <0.02µg/L0.022706-91-4


(PFHxS)

8.61 <0.10 <0.02 <0.02µg/L0.02355-46-4


(PFHpS)

<0.02 <0.10 <0.02 <0.02µg/L0.02375-92-8


(PFOS)

<0.01 <0.10 <0.01 <0.01µg/L0.011763-23-1


(PFDS)

<0.02 <0.10 <0.02 <0.02µg/L0.02335-77-3










(PFUnDA)

<0.02 <0.10 <0.02 <0.02µg/L0.022058-94-8


(PFDoDA)

<0.02 <0.10 <0.02 <0.02µg/L0.02307-55-1


(PFTrDA)

<0.02 <0.10 <0.02 <0.02µg/L0.0272629-94-8


(PFTeDA)

<0.05 <0.25 <0.05 <0.05µg/L0.05376-06-7



(FOSA)

<0.02 <0.10 <0.02 <0.02µg/L0.02754-91-6



<0.05 <0.25 <0.05 <0.05µg/L0.0531506-32-8



<0.05 <0.25 <0.05 <0.05µg/L0.054151-50-2

29 of 35:Page

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:Client

ET1801059



Analytical Results

0874_MW026_S_1804

17_F

0874_MW232_S_1804

17_F

0874_MW246_S_1804

17_F

0874_MW245_S_1804

17_F

0874_MW063_S_1804

17_F


(Matrix: WATER)







<0.05 <0.25 <0.05 <0.05µg/L0.0524448-09-7



<0.05 <0.25 <0.05 <0.05µg/L0.051691-99-2



(MeFOSAA)

<0.02 <0.10 <0.02 <0.02µg/L0.022355-31-9



(EtFOSAA)

<0.02 <0.10 <0.02 <0.02µg/L0.022991-50-6



(4:2 FTS)

<0.05 <0.10 <0.05 <0.05µg/L0.05757124-72-4


(6:2 FTS)

0.34 <0.10 <0.05 0.05µg/L0.0527619-97-2


(8:2 FTS)

<0.05 <0.10 <0.05 <0.05µg/L0.0539108-34-4


(10:2 FTS)

<0.05 <0.10 <0.05 <0.05µg/L0.05120226-60-0

EP231P: PFAS Sums

9.88 85.0 40.7 1.62 3.75µg/L0.01----Sum of PFAS

0.42Sum of PFHxS and PFOS 8.61 <0.10 <0.01 <0.01µg/L0.01355-46-4/1763-23-

1



97.9 98.1 99.2 86.9 95.6%0.02----13C4-PFOS

86.8 89.3 92.1 91.9 91.8%0.02----13C8-PFOA

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ET1801059



Analytical Results

0874_QC3MW_18041

7

0874_QC1MW_18041

7_03

0874_QC1MW_18041

7_02

0874_QC1MW_18041

7_01

0874_MW243_S_1804

17_F


(Matrix: WATER)










----Sulfate as SO4 - Turbidimetric 7500 4820 9 <1mg/L114808-79-8


----Chloride 7480 12200 22 <1mg/L116887-00-6


----Calcium 600 526 <1 <1mg/L17440-70-2

----Magnesium 1010 1300 1 <1mg/L17439-95-4

----Sodium 5940 8240 66 <1mg/L17440-23-5

----Potassium 144 146 <1 <1mg/L17440-09-7


---- 377 449 2.80 0.06meq/L0.01----Total Anions

---- 375 495 2.95 <0.01meq/L0.01----Total Cations

---- 0.26 4.89 ---- ----%0.01----Ionic Balance



(PFBS)

0.64 2.14 1.30 <0.02µg/L0.02375-73-5


(PFPeS)

0.71 0.80 0.83 <0.02µg/L0.022706-91-4


(PFHxS)

7.30 2.68 6.10 <0.02µg/L0.02355-46-4


(PFHpS)

0.12 <0.10 0.59 <0.02µg/L0.02375-92-8


(PFOS)

0.94 0.41 56.8 <0.01µg/L0.011763-23-1


(PFDS)

<0.10 <0.10 0.98 <0.02µg/L0.02335-77-3


20.4Perfluorobutanoic acid (PFBA) <0.5 <0.5 2.1 <0.1µg/L0.1375-22-4


194Perfluorohexanoic acid (PFHxA) 1.06 0.54 3.00 <0.02µg/L0.02307-24-4

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Analytical Results

0874_QC3MW_18041

7

0874_QC1MW_18041

7_03

0874_QC1MW_18041

7_02

0874_QC1MW_18041

7_01

0874_MW243_S_1804

17_F


(Matrix: WATER)





13.6Perfluoroheptanoic acid (PFHpA) <0.10 <0.10 0.79 <0.02µg/L0.02375-85-9

3.89Perfluorooctanoic acid (PFOA) <0.10 <0.10 2.01 <0.01µg/L0.01335-67-1

<0.10Perfluorononanoic acid (PFNA) <0.10 <0.10 0.17 <0.02µg/L0.02375-95-1

<0.10Perfluorodecanoic acid (PFDA) <0.10 <0.10 0.10 <0.02µg/L0.02335-76-2


(PFUnDA)

<0.10 <0.10 0.02 <0.02µg/L0.022058-94-8


(PFDoDA)

<0.10 <0.10 <0.02 <0.02µg/L0.02307-55-1


(PFTrDA)

<0.10 <0.10 <0.02 <0.02µg/L0.0272629-94-8


(PFTeDA)

<0.25 <0.25 <0.05 <0.05µg/L0.05376-06-7



(FOSA)

<0.10 <0.10 0.35 <0.02µg/L0.02754-91-6



<0.25 <0.25 <0.05 <0.05µg/L0.0531506-32-8



<0.25 <0.25 <0.05 <0.05µg/L0.054151-50-2



<0.25 <0.25 <0.05 <0.05µg/L0.0524448-09-7



<0.25 <0.25 <0.05 <0.05µg/L0.051691-99-2



(MeFOSAA)

<0.10 <0.10 <0.02 <0.02µg/L0.022355-31-9



(EtFOSAA)

<0.10 <0.10 <0.02 <0.02µg/L0.022991-50-6



(4:2 FTS)

<0.10 <0.10 <0.05 <0.05µg/L0.05757124-72-4


(6:2 FTS)

<0.10 <0.10 1.21 <0.05µg/L0.0527619-97-2


(8:2 FTS)

<0.10 <0.10 0.80 <0.05µg/L0.0539108-34-4

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Analytical Results

0874_QC3MW_18041

7

0874_QC1MW_18041

7_03

0874_QC1MW_18041

7_02

0874_QC1MW_18041

7_01

0874_MW243_S_1804

17_F


(Matrix: WATER)






(10:2 FTS)

<0.10 <0.10 <0.05 <0.05µg/L0.05120226-60-0

EP231P: PFAS Sums

331 11.0 6.72 80.1 <0.01µg/L0.01----Sum of PFAS

<0.10Sum of PFHxS and PFOS 8.24 3.09 62.9 <0.01µg/L0.01355-46-4/1763-23-

1

326 10.2 5.92 77.1 <0.01µg/L0.01----Sum of PFAS (WA DER List)


98.2 94.5 81.8 90.8 90.1%0.02----13C4-PFOS

92.9 95.6 95.8 95.4 96.6%0.02----13C8-PFOA

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Analytical Results

0874_QC5MW_18041

7_04

0874_QC5MW_18041

7_03

0874_QC5MW_18041

7_02

0874_QC5MW_18041

7_01

0874_QC4MW_18041

7


(Matrix: WATER)






(PFBS)

<0.02 <0.02 <0.02 <0.02µg/L0.02375-73-5


(PFPeS)

<0.02 <0.02 <0.02 <0.02µg/L0.022706-91-4


(PFHxS)

<0.02 <0.02 <0.02 <0.02µg/L0.02355-46-4


(PFHpS)

<0.02 <0.02 <0.02 <0.02µg/L0.02375-92-8


(PFOS)

<0.01 <0.01 <0.01 <0.01µg/L0.011763-23-1


(PFDS)

<0.02 <0.02 <0.02 <0.02µg/L0.02335-77-3


<0.1Perfluorobutanoic acid (PFBA) <0.1 <0.1 <0.1 <0.1µg/L0.1375-22-4

<0.02Perfluoropentanoic acid (PFPeA) <0.02 <0.02 <0.02 <0.02µg/L0.022706-90-3

<0.02Perfluorohexanoic acid (PFHxA) <0.02 <0.02 <0.02 <0.02µg/L0.02307-24-4

<0.02Perfluoroheptanoic acid (PFHpA) <0.02 <0.02 <0.02 <0.02µg/L0.02375-85-9

<0.01Perfluorooctanoic acid (PFOA) <0.01 <0.01 <0.01 <0.01µg/L0.01335-67-1




(PFUnDA)

<0.02 <0.02 <0.02 <0.02µg/L0.022058-94-8


(PFDoDA)

<0.02 <0.02 <0.02 <0.02µg/L0.02307-55-1


(PFTrDA)

<0.02 <0.02 <0.02 <0.02µg/L0.0272629-94-8


(PFTeDA)

<0.05 <0.05 <0.05 <0.05µg/L0.05376-06-7



(FOSA)

<0.02 <0.02 <0.02 <0.02µg/L0.02754-91-6



<0.05 <0.05 <0.05 <0.05µg/L0.0531506-32-8



<0.05 <0.05 <0.05 <0.05µg/L0.054151-50-2

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Analytical Results

0874_QC5MW_18041

7_04

0874_QC5MW_18041

7_03

0874_QC5MW_18041

7_02

0874_QC5MW_18041

7_01

0874_QC4MW_18041

7


(Matrix: WATER)







<0.05 <0.05 <0.05 <0.05µg/L0.0524448-09-7



<0.05 <0.05 <0.05 <0.05µg/L0.051691-99-2



(MeFOSAA)

<0.02 <0.02 <0.02 <0.02µg/L0.022355-31-9



(EtFOSAA)

<0.02 <0.02 <0.02 <0.02µg/L0.022991-50-6



(4:2 FTS)

<0.05 <0.05 <0.05 <0.05µg/L0.05757124-72-4


(6:2 FTS)

<0.05 <0.05 <0.05 <0.05µg/L0.0527619-97-2


(8:2 FTS)

<0.05 <0.05 <0.05 <0.05µg/L0.0539108-34-4


(10:2 FTS)

<0.05 <0.05 <0.05 <0.05µg/L0.05120226-60-0

EP231P: PFAS Sums

<0.01 <0.01 <0.01 <0.01 <0.01µg/L0.01----Sum of PFAS

<0.01Sum of PFHxS and PFOS <0.01 <0.01 <0.01 <0.01µg/L0.01355-46-4/1763-23-

1

<0.01 <0.01 <0.01 <0.01 <0.01µg/L0.01----Sum of PFAS (WA DER List)


89.1 94.2 90.5 90.8 93.3%0.02----13C4-PFOS

100 93.6 99.5 97.8 97.4%0.02----13C8-PFOA

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13C4-PFOS ---- 60 130

13C8-PFOA ---- 60 130


13C4-PFOS ---- 70 130

13C8-PFOA ---- 70 130

False

6 6.00False

Environmental




:Address MOBIL

C/O GPO BOX 2907








Site : ----


















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General Comments










Key :








EA005-P: pH Value ---- 0.01 pH Unit 6.95 6.96 0.144 0% - 20%0874_MW116_S_180417 ET1801059-001



EA010-P: Electrical Conductivity @ 25°C ---- 1 µS/cm 7980 8090 1.37 0% - 20%0874_MW116_S_180417 ET1801059-001



EA015H: Total Dissolved Solids @180°C ---- 10 mg/L 5040 4850 3.74 0% - 20%0874_MW116_S_180417 ET1801059-001



EA025H: Suspended Solids (SS) ---- 5 mg/L 987 1110 12.1 0% - 20%0874_MW116_S_180417 ET1801059-001

EA025H: Suspended Solids (SS) ---- 5 mg/L <5 10 66.7 No LimitAnonymous ET1801065-001


EA045: Turbidity ---- 0.1 NTU 632 632 0.00 0% - 20%0874_MW116_S_180417 ET1801059-001












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ED037-P: Hydroxide Alkalinity as CaCO3 DMO-210-001 1 mg/L <1 <1 0.00 No Limit0874_QC1MW_180417_03 ET1801059-034








ED041G: Sulfate as SO4 - Turbidimetric 14808-79-8 1 mg/L 9 9 0.00 No Limit0874_MW129_S_180417 ET1801059-003











ED093F: Sodium 7440-23-5 1 mg/L 94 93 1.38 0% - 20%


ED093F: Calcium 7440-70-2 1 mg/L 7 7 0.00 No Limit0874_MW061_S_180417 ET1801059-009


ED093F: Sodium 7440-23-5 1 mg/L 424 424 0.00 0% - 20%



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ED093F: Dissolved Major Cations (QC Lot: 1581878) - continued



ED093F: Sodium 7440-23-5 1 mg/L 6400 6400 0.100 0% - 20%


ED093F: Calcium 7440-70-2 1 mg/L 4 4 0.00 No Limit0874_MW004_S_180417 ET1801059-021


ED093F: Sodium 7440-23-5 1 mg/L 72 68 5.94 0% - 20%






EG020A-F: Manganese 7439-96-5 0.001 mg/L 0.002 0.002 0.00 No Limit0874_MW061_S_180417 ET1801059-009




EG051G: Ferrous Iron ---- 0.05 mg/L 0.20 0.21 0.00 No LimitAnonymous ET1801057-001

EG051G: Ferrous Iron ---- 0.05 mg/L <0.05 <0.05 0.00 No Limit0874_MW063_S_180417 ET1801059-010


EK040P: Fluoride 16984-48-8 0.1 mg/L 0.2 0.2 0.00 No Limit0874_MW116_S_180417 ET1801059-001

EK040P: Fluoride 16984-48-8 0.1 mg/L 1.5 1.6 0.00 0% - 50%Anonymous ET1801068-001


EK055G: Ammonia as N 7664-41-7 0.01 mg/L 0.03 <0.01 109 No Limit0874_MW116_S_180417 ET1801059-001




EK057G: Nitrite as N 14797-65-0 0.01 mg/L <0.01 <0.01 0.00 No Limit0874_MW116_S_180417 ET1801059-001


EK059G: Nitrite + Nitrate as N ---- 0.01 mg/L <0.01 <0.01 0.00 No Limit0874_MW116_S_180417 ET1801059-001



EK061G: Total Kjeldahl Nitrogen as N ---- 0.1 mg/L 0.3 0.3 0.00 No Limit0874_MW116_S_180417 ET1801059-001

EK061G: Total Kjeldahl Nitrogen as N ---- 0.1 mg/L 0.2 0.2 0.00 No Limit0874_MW120_S_180417 ET1801059-008


EK067G: Total Phosphorus as P ---- 0.01 mg/L 0.13 0.12 9.06 No Limit0874_MW246_S_180417 ET1801059-015

EK067G: Total Phosphorus as P ---- 0.01 mg/L 0.14 0.14 0.00 0% - 50%0874_MW120_S_180417 ET1801059-008


EK071G: Reactive Phosphorus as P 14265-44-2 0.01 mg/L 0.04 0.04 0.00 No Limit0874_MW116_S_180417 ET1801059-001

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EP005: Total Organic Carbon ---- 1 mg/L 11 11 0.00 0% - 50%Anonymous ET1801057-001

EP005: Total Organic Carbon ---- 1 mg/L 4 5 24.6 No Limit0874_MW061_S_180417 ET1801059-009


EP026SP: Chemical Oxygen Demand ---- 10 mg/L 32 32 0.00 No LimitAnonymous ET1801057-001

EP026SP: Chemical Oxygen Demand ---- 10 mg/L <50 <50 0.00 No Limit0874_MW063_S_180417 ET1801059-010


EP030: Biochemical Oxygen Demand ---- 2 mg/L 4 <2 75.0 No LimitAnonymous ET1801058-003

EP030: Biochemical Oxygen Demand ---- 2 mg/L 3 <2 0.00 No LimitAnonymous ET1801058-013


EP030: Biochemical Oxygen Demand ---- 2 mg/L <2 <2 0.00 No Limit0874_MW243_S_180417 ET1801059-018













EP231X: Perfluorononanoic acid (PFNA) 375-95-1 0.02 µg/L <0.02 0.02 0.00 No Limit











2355-31-9 0.02 µg/L <0.02 <0.02 0.00 No Limit



2991-50-6 0.02 µg/L <0.02 <0.02 0.00 No Limit


(MeFOSA)

31506-32-8 0.05 µg/L <0.05 <0.05 0.00 No Limit


(EtFOSA)

4151-50-2 0.05 µg/L <0.05 <0.05 0.00 No Limit

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EP231_TOP_C: Perfluoroalkyl Sulfonamides (QC Lot: 1582393) - continued






1691-99-2 0.05 µg/L <0.05 <0.05 0.00 No Limit



FTS)



FTS)

27619-97-2 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

39108-34-4 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

120226-60-0 0.05 µg/L <0.05 <0.05 0.00 No Limit




23-1

0.01 µg/L 14.8 15.8 6.65 0% - 20%


C4 - C8 Sulfonates

---- 0.01 µg/L 19.5 21.0 7.47 0% - 20%













EP231X: Perfluorodecane sulfonic acid (PFDS) 335-77-3 0.02 µg/L 1.06 1.03 2.49 0% - 20%


EP231X: Perfluorooctane sulfonic acid (PFOS) 1763-23-1 0.01 µg/L <0.05 <0.05 0.00 No Limit0874_MW122_S_180417 ET1801059-013






EP231X: Perfluorooctane sulfonic acid (PFOS) 1763-23-1 0.01 µg/L <0.01 <0.01 0.00 No Limit0874_MW126_S_180417_F ET1801059-023

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EP231X: Perfluorobutane sulfonic acid (PFBS) 375-73-5 0.02 µg/L 4.80 4.73 1.51 0% - 20%0874_MW126_S_180417_F ET1801059-023






EP231X: Perfluorooctane sulfonic acid (PFOS) 1763-23-1 0.01 µg/L 0.41 0.46 11.5 No Limit0874_QC1MW_180417_02 ET1801059-033























EP231X: Perfluorodecanoic acid (PFDA) 335-76-2 0.02 µg/L 0.09 0.10 0.00 No Limit

EP231X: Perfluoroundecanoic acid (PFUnDA) 2058-94-8 0.02 µg/L 0.02 0.02 0.00 No Limit










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EP231X: Perfluorononanoic acid (PFNA) 375-95-1 0.02 µg/L <0.05 <0.05 0.00 No Limit0874_MW122_S_180417 ET1801059-013







EP231X: Perfluorooctanoic acid (PFOA) 335-67-1 0.01 µg/L 4.84 4.63 4.40 0% - 20%0874_MW126_S_180417_F ET1801059-023












EP231X: Perfluorooctanoic acid (PFOA) 335-67-1 0.01 µg/L <0.10 <0.10 0.00 No Limit0874_QC1MW_180417_02 ET1801059-033















2355-31-9 0.02 µg/L <0.02 <0.02 0.00 No Limit



2991-50-6 0.02 µg/L <0.02 <0.02 0.00 No Limit


(MeFOSA)

31506-32-8 0.05 µg/L <0.05 <0.05 0.00 No Limit


(EtFOSA)

4151-50-2 0.05 µg/L <0.05 <0.05 0.00 No Limit

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1691-99-2 0.05 µg/L <0.05 <0.05 0.00 No Limit

EP231X: Perfluorooctane sulfonamide (FOSA) 754-91-6 0.02 µg/L 0.38 0.40 5.40 0% - 50%0874_MW129_S_180417 ET1801059-003



2355-31-9 0.02 µg/L <0.02 <0.02 0.00 No Limit



2991-50-6 0.02 µg/L <0.02 <0.02 0.00 No Limit


(MeFOSA)

31506-32-8 0.05 µg/L <0.05 <0.05 0.00 No Limit


(EtFOSA)

4151-50-2 0.05 µg/L <0.05 <0.05 0.00 No Limit



24448-09-7 0.05 µg/L <0.05 <0.05 0.00 No Limit



1691-99-2 0.05 µg/L <0.05 <0.05 0.00 No Limit





2355-31-9 0.02 µg/L <0.05 <0.05 0.00 No Limit



2991-50-6 0.02 µg/L <0.05 <0.05 0.00 No Limit


(MeFOSA)

31506-32-8 0.05 µg/L <0.12 <0.12 0.00 No Limit


(EtFOSA)

4151-50-2 0.05 µg/L <0.12 <0.12 0.00 No Limit



24448-09-7 0.05 µg/L <0.12 <0.12 0.00 No Limit



1691-99-2 0.05 µg/L <0.12 <0.12 0.00 No Limit

EP231X: Perfluorooctane sulfonamide (FOSA) 754-91-6 0.02 µg/L <0.02 <0.02 0.00 No Limit0874_MW126_S_180417_F ET1801059-023



2355-31-9 0.02 µg/L <0.02 <0.02 0.00 No Limit



2991-50-6 0.02 µg/L <0.02 <0.02 0.00 No Limit


(MeFOSA)

31506-32-8 0.05 µg/L <0.05 <0.05 0.00 No Limit


(EtFOSA)

4151-50-2 0.05 µg/L <0.05 <0.05 0.00 No Limit

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24448-09-7 0.05 µg/L <0.05 <0.05 0.00 No Limit0874_MW126_S_180417_F ET1801059-023



1691-99-2 0.05 µg/L <0.05 <0.05 0.00 No Limit


EP231X: Perfluorooctane sulfonamide (FOSA) 754-91-6 0.02 µg/L <0.10 <0.10 0.00 No Limit0874_QC1MW_180417_02 ET1801059-033



2355-31-9 0.02 µg/L <0.10 <0.10 0.00 No Limit



2991-50-6 0.02 µg/L <0.10 <0.10 0.00 No Limit


(MeFOSA)

31506-32-8 0.05 µg/L <0.25 <0.25 0.00 No Limit


(EtFOSA)

4151-50-2 0.05 µg/L <0.25 <0.25 0.00 No Limit



24448-09-7 0.05 µg/L <0.25 <0.25 0.00 No Limit



1691-99-2 0.05 µg/L <0.25 <0.25 0.00 No Limit



FTS)



FTS)

27619-97-2 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

39108-34-4 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

120226-60-0 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)



FTS)

27619-97-2 0.05 µg/L 1.11 1.08 3.10 0% - 20%


FTS)

39108-34-4 0.05 µg/L 0.87 0.86 1.15 0% - 50%


FTS)

120226-60-0 0.05 µg/L <0.05 <0.05 0.00 No Limit



FTS)



FTS)

27619-97-2 0.05 µg/L <0.05 <0.05 0.00 No Limit

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FTS)



FTS)

120226-60-0 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

757124-72-4 0.05 µg/L <0.05 <0.05 0.00 No Limit0874_MW126_S_180417_F ET1801059-023


FTS)

27619-97-2 0.05 µg/L 0.29 0.29 0.00 No Limit


FTS)

39108-34-4 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

120226-60-0 0.05 µg/L <0.05 <0.05 0.00 No Limit



FTS)



FTS)

27619-97-2 0.05 µg/L <0.10 <0.10 0.00 No Limit


FTS)

39108-34-4 0.05 µg/L <0.10 <0.10 0.00 No Limit


FTS)

120226-60-0 0.05 µg/L <0.10 <0.10 0.00 No Limit




23-1

0.01 µg/L 9.50 9.52 0.210 0% - 20%




23-1

0.01 µg/L 52.0 53.6 2.99 0% - 20%



EP231X: Sum of PFAS ---- 0.01 µg/L 0.10 0.10 0.00 No Limit0874_MW122_S_180417 ET1801059-013


23-1

0.01 µg/L 0.10 0.10 0.00 No Limit

EP231X: Sum of PFAS (WA DER List) ---- 0.01 µg/L 0.10 0.10 0.00 No Limit

EP231X: Sum of PFAS ---- 0.01 µg/L 71.1 71.2 0.140 0% - 20%0874_MW126_S_180417_F ET1801059-023


23-1

0.01 µg/L <0.01 <0.01 0.00 No Limit



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EP231X: Sum of PFAS ---- 0.01 µg/L 6.72 6.33 5.98 0% - 20%0874_QC1MW_180417_02 ET1801059-033


23-1

0.01 µg/L 3.09 2.79 10.2 0% - 20%


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Report






---- 99.37 pH Unit 10298



<1 99.712890 µS/cm 10791



<10 98.82000 mg/L 11288


EA025H: Suspended Solids (SS) ---- 5 mg/L <5 112150 mg/L 12083

<5 1201000 mg/L 12083



<0.1 10340 NTU 10595

<0.1 99.8400 NTU 10397









<1 11725 mg/L 12080



<1 11525 mg/L 12080



<1 99.310 mg/L 12080



<1 10410 mg/L 12080

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Report





ED093F: Calcium 7440-70-2 1 mg/L <1 -------- --------


ED093F: Sodium 7440-23-5 1 mg/L <1 -------- --------



ED093F: Calcium 7440-70-2 1 mg/L <1 -------- --------


ED093F: Sodium 7440-23-5 1 mg/L <1 -------- --------





EG020A-F: Iron 7439-89-6 0.05 mg/L <0.05 95.90.5 mg/L 11482










EK059G: Nitrite + Nitrate as N ---- 0.01 mg/L <0.01 99.00.5 mg/L 11589









<1 97.0100 mg/L 11379



<10 96.8500 mg/L 11286



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Report











EP231X: Perfluorooctane sulfonic acid (PFOS) 1763-23-1 0.01 µg/L <0.01 1041 µg/L 15050







EP231X: Perfluorooctanoic acid (PFOA) 335-67-1 0.01 µg/L <0.01 1081 µg/L 15050












(MeFOSE)

24448-09-7 0.05 µg/L <0.05 -------- --------


(EtFOSE)

1691-99-2 0.05 µg/L <0.05 -------- --------


(MeFOSAA)

2355-31-9 0.02 µg/L <0.02 -------- --------


(EtFOSAA)

2991-50-6 0.02 µg/L <0.02 -------- --------







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Report







63-23-1

0.01 µg/L <0.01 -------- --------


Sulfonates

---- 0.01 µg/L <0.01 -------- --------





















EP231X: Perfluorodecane sulfonic acid (PFDS) 335-77-3 0.02 µg/L <0.02 83.40.5 µg/L 13070













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Report

































(MeFOSE)

24448-09-7 0.05 µg/L <0.05 1101.25 µg/L 13070


(EtFOSE)

1691-99-2 0.05 µg/L <0.05 1051.25 µg/L 13070


(MeFOSAA)

2355-31-9 0.02 µg/L <0.02 1110.5 µg/L 13070


(EtFOSAA)

2991-50-6 0.02 µg/L <0.02 98.00.5 µg/L 13070





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ET1801059




Report






(MeFOSE)

24448-09-7 0.05 µg/L <0.05 90.71.25 µg/L 13070


(EtFOSE)

1691-99-2 0.05 µg/L <0.05 98.11.25 µg/L 13070


(MeFOSAA)

2355-31-9 0.02 µg/L <0.02 99.60.5 µg/L 13070


(EtFOSAA)

2991-50-6 0.02 µg/L <0.02 91.00.5 µg/L 13070






(MeFOSE)

24448-09-7 0.05 µg/L <0.05 1031.25 µg/L 13070


(EtFOSE)

1691-99-2 0.05 µg/L <0.05 88.51.25 µg/L 13070


(MeFOSAA)

2355-31-9 0.02 µg/L <0.02 1050.5 µg/L 13070


(EtFOSAA)

2991-50-6 0.02 µg/L <0.02 93.20.5 µg/L 13070



















63-23-1

0.01 µg/L <0.01 -------- --------

19 of 23:Page

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ET1801059




Report




EP231P: PFAS Sums (QCLot: 1582175) - continued





63-23-1

0.01 µg/L <0.01 -------- --------





63-23-1

0.01 µg/L <0.01 -------- --------








0874_MW126_S_180417 ET1801059-002 14808-79-8ED041G: Sulfate as SO4 - Turbidimetric 10720 mg/L 13070



Determined

20 mg/L 13070




0874_MW013_S_180417 ET1801059-004 16887-00-6ED045G: Chloride # Not

Determined

400 mg/L 13070




Determined

0.1 mg/L 13070


Anonymous ET1801057-003 ----EG051G: Ferrous Iron 1002 mg/L 13070


20 of 23:Page

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:Client

ET1801059






EK040P: Fluoride by PC Titrator (QCLot: 1577207) - continued

0874_MW126_S_180417 ET1801059-002 16984-48-8EK040P: Fluoride 1031.92 mg/L 12080


0874_MW126_S_180417 ET1801059-002 7664-41-7EK055G: Ammonia as N 78.60.4 mg/L 13070


0874_MW126_S_180417 ET1801059-002 14797-65-0EK057G: Nitrite as N 1050.4 mg/L 13070


0874_MW126_S_180417 ET1801059-002 ----EK059G: Nitrite + Nitrate as N 97.20.4 mg/L 13070


0874_MW126_S_180417 ET1801059-002 ----EK061G: Total Kjeldahl Nitrogen as N 93.15 mg/L 13070


Anonymous EB1809943-001 ----EK067G: Total Phosphorus as P 1021 mg/L 13070


0874_MW126_S_180417 ET1801059-002 14265-44-2EK071G: Reactive Phosphorus as P 1030.4 mg/L 13070




Anonymous ET1801057-003 ----EP026SP: Chemical Oxygen Demand 95.5291 mg/L 13070





Determined

0.5 µg/L 13070



Determined

0.5 µg/L 13070



0874_MW245_S_180417 ET1801059-014 375-73-5EP231X: Perfluorobutane sulfonic acid (PFBS) # Not

Determined

0.5 µg/L 13070

2706-91-4EP231X: Perfluoropentane sulfonic acid (PFPeS) # Not

Determined

0.5 µg/L 13070


Determined

0.5 µg/L 13070

375-92-8EP231X: Perfluoroheptane sulfonic acid (PFHpS) # Not

Determined

0.5 µg/L 13070

21 of 23:Page

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:Client

ET1801059







0874_MW245_S_180417 ET1801059-014 1763-23-1EP231X: Perfluorooctane sulfonic acid (PFOS) # Not

Determined

0.5 µg/L 13070



0874_QC1MW_180417_03 ET1801059-034 375-73-5EP231X: Perfluorobutane sulfonic acid (PFBS) 1120.5 µg/L 13070



Determined

0.5 µg/L 13070



Determined

0.5 µg/L 13070















0874_MW245_S_180417 ET1801059-014 375-22-4EP231X: Perfluorobutanoic acid (PFBA) 98.32.5 µg/L 13070

2706-90-3EP231X: Perfluoropentanoic acid (PFPeA) # Not

Determined

0.5 µg/L 13070

307-24-4EP231X: Perfluorohexanoic acid (PFHxA) # Not

Determined

0.5 µg/L 13070

375-85-9EP231X: Perfluoroheptanoic acid (PFHpA) # Not

Determined

0.5 µg/L 13070

335-67-1EP231X: Perfluorooctanoic acid (PFOA) # Not

Determined

0.5 µg/L 13070






22 of 23:Page

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:Client

ET1801059







0874_MW245_S_180417 ET1801059-014 376-06-7EP231X: Perfluorotetradecanoic acid (PFTeDA) 1001.25 µg/L 13070


0874_QC1MW_180417_03 ET1801059-034 375-22-4EP231X: Perfluorobutanoic acid (PFBA) 1082.5 µg/L 13070

2706-90-3EP231X: Perfluoropentanoic acid (PFPeA) # Not

Determined

0.5 µg/L 13070

307-24-4EP231X: Perfluorohexanoic acid (PFHxA) # Not

Determined

0.5 µg/L 13070


335-67-1EP231X: Perfluorooctanoic acid (PFOA) # Not

Determined

0.5 µg/L 13070








Anonymous ET1801057-004 754-91-6EP231X: Perfluorooctane sulfonamide (FOSA) 1200.5 µg/L 13070


(MeFOSA)

95.11.25 µg/L 13070



(MeFOSE)

1081.25 µg/L 13070


(EtFOSE)

95.31.25 µg/L 13070


acid (MeFOSAA)

1090.5 µg/L 13070


acid (EtFOSAA)

1060.5 µg/L 13070




(MeFOSA)

92.51.25 µg/L 13070



(MeFOSE)

1131.25 µg/L 13070


(EtFOSE)

98.11.25 µg/L 13070

23 of 23:Page

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:Client

ET1801059







0874_MW245_S_180417 ET1801059-014 2355-31-9EP231X: N-Methyl perfluorooctane sulfonamidoacetic

acid (MeFOSAA)

1010.5 µg/L 13070


acid (EtFOSAA)

97.40.5 µg/L 13070


0874_QC1MW_180417_03 ET1801059-034 754-91-6EP231X: Perfluorooctane sulfonamide (FOSA) 1180.5 µg/L 13070


(MeFOSA)

1021.25 µg/L 13070



(MeFOSE)

1021.25 µg/L 13070


(EtFOSE)

1011.25 µg/L 13070


acid (MeFOSAA)

1040.5 µg/L 13070


acid (EtFOSAA)

1110.5 µg/L 13070


Anonymous ET1801057-004 757124-72-4EP231X: 4:2 Fluorotelomer sulfonic acid (4:2 FTS) 1050.5 µg/L 13070





0874_MW245_S_180417 ET1801059-014 757124-72-4EP231X: 4:2 Fluorotelomer sulfonic acid (4:2 FTS) 1060.5 µg/L 13070





0874_QC1MW_180417_03 ET1801059-034 757124-72-4EP231X: 4:2 Fluorotelomer sulfonic acid (4:2 FTS) 1150.5 µg/L 13070




True

Environmental












Summary of Outliers













2 of 19:Page

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:Client

ET1801059





Matrix: WATER



ET1801059--004 14808-79-8Sulfate as SO4 -

Turbidimetric




----Not

Determined


ET1801059--004 16887-00-6Chloride0874_MW013_S_180417 MS recovery not determined,



----Not

Determined


ET1801057--003 7439-96-5ManganeseAnonymous MS recovery not determined,



----Not

Determined







----Not

Determined



sulfonic acid

(PFPeS)




----Not

Determined



sulfonic acid

(PFHxS)




----Not

Determined



sulfonic acid

(PFHxS)




----Not

Determined



sulfonic acid

(PFHxS)

0874_QC1MW_180417_03 MS recovery not determined,



----Not

Determined



sulfonic acid

(PFHpS)




----Not

Determined







----Not

Determined







----Not

Determined







----Not

Determined



acid (PFPeA)




----Not

Determined


3 of 19:Page

Work Order :

:Client

ET1801059



Matrix: WATER




acid (PFPeA)




----Not

Determined



(PFHxA)




----Not

Determined



(PFHxA)




----Not

Determined



acid (PFHpA)




----Not

Determined



(PFOA)




----Not

Determined



(PFOA)




----Not

Determined



Matrix: WATER



overdue

Days

overdue


Method



17-Apr-2018----0874_MW116_S_180417, 0874_MW126_S_180417,

0874_MW120_S_180417, 0874_MW061_S_180417,

0874_MW063_S_180417, 0874_MW245_S_180417,

0874_MW246_S_180417, 0874_MW232_S_180417,

0874_MW026_S_180417, 0874_MW243_S_180417

18-Apr-2018---- ---- 1










4 of 19:Page

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:Client

ET1801059








0874_MW116_S_180417, 0874_MW126_S_180417,

0874_MW120_S_180417, 0874_MW061_S_180417,

0874_MW063_S_180417, 0874_MW245_S_180417,

0874_MW246_S_180417, 0874_MW232_S_180417,

0874_MW026_S_180417, 0874_MW243_S_180417

17-Apr-2018---- 18-Apr-2018----17-Apr-2018 ---- û



0874_MW116_S_180417, 0874_MW126_S_180417,

0874_MW120_S_180417, 0874_MW061_S_180417,

0874_MW063_S_180417, 0874_MW245_S_180417,

0874_MW246_S_180417, 0874_MW232_S_180417,

0874_MW026_S_180417, 0874_MW243_S_180417

15-May-2018---- 24-Apr-2018----17-Apr-2018 ---- ü



0874_MW116_S_180417, 0874_MW126_S_180417,

0874_MW120_S_180417, 0874_MW061_S_180417,

0874_MW063_S_180417, 0874_MW245_S_180417,

0874_MW246_S_180417, 0874_MW232_S_180417,

0874_MW026_S_180417, 0874_MW243_S_180417

15-May-2018---- 18-Apr-2018----17-Apr-2018 ---- ü



0874_MW116_S_180417, 0874_MW126_S_180417,

0874_MW120_S_180417, 0874_MW061_S_180417,

0874_MW063_S_180417, 0874_MW245_S_180417,

0874_MW246_S_180417, 0874_MW232_S_180417,

0874_MW026_S_180417, 0874_MW243_S_180417

24-Apr-2018---- 19-Apr-2018----17-Apr-2018 ---- ü



0874_MW116_S_180417, 0874_MW126_S_180417,

0874_MW120_S_180417, 0874_MW061_S_180417,

0874_MW063_S_180417, 0874_MW245_S_180417,

0874_MW246_S_180417, 0874_MW232_S_180417,

0874_MW026_S_180417, 0874_MW243_S_180417

24-Apr-2018---- 19-Apr-2018----17-Apr-2018 ---- ü

EA045: Turbidity


0874_MW116_S_180417, 0874_MW126_S_180417,

0874_MW120_S_180417, 0874_MW061_S_180417,

0874_MW063_S_180417, 0874_MW245_S_180417,

0874_MW246_S_180417, 0874_MW232_S_180417,

0874_MW026_S_180417, 0874_MW243_S_180417

19-Apr-2018---- 18-Apr-2018----17-Apr-2018 ---- ü

5 of 19:Page

Work Order :

:Client

ET1801059








0874_MW116_S_180417, 0874_MW126_S_180417,

0874_MW120_S_180417, 0874_MW061_S_180417,

0874_MW063_S_180417, 0874_MW245_S_180417,

0874_MW246_S_180417, 0874_MW232_S_180417,

0874_MW026_S_180417, 0874_MW243_S_180417

15-May-2018---- 24-Apr-2018----17-Apr-2018 ---- ü



0874_MW116_S_180417, 0874_MW126_S_180417,

0874_MW120_S_180417, 0874_MW061_S_180417,

0874_MW063_S_180417, 0874_MW245_S_180417,

0874_MW246_S_180417, 0874_MW232_S_180417,

0874_MW026_S_180417, 0874_MW243_S_180417

01-May-2018---- 18-Apr-2018----17-Apr-2018 ---- ü


0874_MW129_S_180417, 0874_MW013_S_180417,

0874_MW118_S_180417, 0874_MW034_S_180417,

0874_MW033_S_180417, 0874_MW056_S_180417,

0874_MW135_S_180417, 0874_MW122_S_180417,

0874_MW136_S_180417, 0874_MW265_S_180417,

0874_MW004_S_180417, 0874_QC1MW_180417_01,

0874_QC1MW_180417_02, 0874_QC1MW_180417_03,

0874_QC3MW_180417

01-May-2018---- 19-Apr-2018----17-Apr-2018 ---- ü



0874_MW116_S_180417, 0874_MW126_S_180417,

0874_MW120_S_180417, 0874_MW061_S_180417,

0874_MW063_S_180417, 0874_MW245_S_180417,

0874_MW246_S_180417, 0874_MW232_S_180417,

0874_MW026_S_180417, 0874_MW243_S_180417

15-May-2018---- 18-Apr-2018----17-Apr-2018 ---- ü


0874_MW129_S_180417, 0874_MW013_S_180417,

0874_MW118_S_180417, 0874_MW034_S_180417,

0874_MW033_S_180417, 0874_MW056_S_180417,

0874_MW135_S_180417, 0874_MW122_S_180417,

0874_MW136_S_180417, 0874_MW265_S_180417,

0874_MW004_S_180417, 0874_QC1MW_180417_01,

0874_QC1MW_180417_02, 0874_QC1MW_180417_03,

0874_QC3MW_180417

15-May-2018---- 19-Apr-2018----17-Apr-2018 ---- ü

6 of 19:Page

Work Order :

:Client

ET1801059








0874_MW116_S_180417, 0874_MW126_S_180417,

0874_MW120_S_180417, 0874_MW061_S_180417,

0874_MW063_S_180417, 0874_MW245_S_180417,

0874_MW246_S_180417, 0874_MW232_S_180417,

0874_MW026_S_180417, 0874_MW243_S_180417

15-May-2018---- 18-Apr-2018----17-Apr-2018 ---- ü


0874_MW129_S_180417, 0874_MW013_S_180417,

0874_MW118_S_180417, 0874_MW034_S_180417,

0874_MW033_S_180417, 0874_MW056_S_180417,

0874_MW135_S_180417, 0874_MW122_S_180417,

0874_MW136_S_180417, 0874_MW265_S_180417,

0874_MW004_S_180417, 0874_QC1MW_180417_01,

0874_QC1MW_180417_02, 0874_QC1MW_180417_03,

0874_QC3MW_180417

15-May-2018---- 19-Apr-2018----17-Apr-2018 ---- ü



0874_MW116_S_180417, 0874_MW126_S_180417,

0874_MW120_S_180417, 0874_MW061_S_180417,

0874_MW063_S_180417, 0874_MW245_S_180417,

0874_MW246_S_180417, 0874_MW232_S_180417,

0874_MW026_S_180417, 0874_MW243_S_180417

15-May-2018---- 24-Apr-2018----17-Apr-2018 ---- ü


0874_MW129_S_180417, 0874_MW013_S_180417,

0874_MW118_S_180417, 0874_MW034_S_180417,

0874_MW033_S_180417, 0874_MW056_S_180417,

0874_MW135_S_180417, 0874_MW122_S_180417,

0874_MW136_S_180417, 0874_MW265_S_180417,

0874_MW004_S_180417, 0874_QC1MW_180417_01,

0874_QC1MW_180417_02, 0874_QC1MW_180417_03,

0874_QC3MW_180417

24-Apr-2018---- 24-Apr-2018----17-Apr-2018 ---- ü



0874_MW116_S_180417, 0874_MW126_S_180417,

0874_MW120_S_180417, 0874_MW061_S_180417,

0874_MW063_S_180417, 0874_MW245_S_180417,

0874_MW246_S_180417, 0874_MW232_S_180417,

0874_MW026_S_180417, 0874_MW243_S_180417

14-Oct-2018---- 24-Apr-2018----17-Apr-2018 ---- ü

7 of 19:Page

Work Order :

:Client

ET1801059








0874_MW116_S_180417, 0874_MW126_S_180417,

0874_MW120_S_180417, 0874_MW061_S_180417,

0874_MW063_S_180417, 0874_MW245_S_180417,

0874_MW246_S_180417, 0874_MW232_S_180417,

0874_MW026_S_180417, 0874_MW243_S_180417

24-Apr-2018---- 23-Apr-2018----17-Apr-2018 ---- ü



0874_MW116_S_180417, 0874_MW126_S_180417,

0874_MW120_S_180417, 0874_MW061_S_180417,

0874_MW063_S_180417, 0874_MW245_S_180417,

0874_MW246_S_180417, 0874_MW232_S_180417,

0874_MW026_S_180417, 0874_MW243_S_180417

15-May-2018---- 18-Apr-2018----17-Apr-2018 ---- ü



0874_MW116_S_180417, 0874_MW126_S_180417,

0874_MW120_S_180417, 0874_MW061_S_180417,

0874_MW063_S_180417, 0874_MW245_S_180417,

0874_MW246_S_180417, 0874_MW232_S_180417,

0874_MW026_S_180417, 0874_MW243_S_180417

15-May-2018---- 19-Apr-2018----17-Apr-2018 ---- ü



0874_MW116_S_180417, 0874_MW126_S_180417,

0874_MW120_S_180417, 0874_MW061_S_180417,

0874_MW063_S_180417, 0874_MW245_S_180417,

0874_MW246_S_180417, 0874_MW232_S_180417,

0874_MW026_S_180417, 0874_MW243_S_180417

19-Apr-2018---- 18-Apr-2018----17-Apr-2018 ---- ü



0874_MW116_S_180417, 0874_MW126_S_180417,

0874_MW120_S_180417, 0874_MW061_S_180417,

0874_MW063_S_180417, 0874_MW245_S_180417,

0874_MW246_S_180417, 0874_MW232_S_180417,

0874_MW026_S_180417, 0874_MW243_S_180417

15-May-2018---- 19-Apr-2018----17-Apr-2018 ---- ü



0874_MW116_S_180417, 0874_MW126_S_180417,

0874_MW120_S_180417, 0874_MW061_S_180417,

0874_MW063_S_180417, 0874_MW245_S_180417,

0874_MW246_S_180417, 0874_MW232_S_180417,

0874_MW026_S_180417, 0874_MW243_S_180417


8 of 19:Page

Work Order :

:Client

ET1801059








0874_MW116_S_180417, 0874_MW126_S_180417,

0874_MW120_S_180417, 0874_MW061_S_180417,

0874_MW063_S_180417, 0874_MW245_S_180417,

0874_MW246_S_180417, 0874_MW232_S_180417,

0874_MW026_S_180417, 0874_MW243_S_180417




0874_MW116_S_180417, 0874_MW126_S_180417,

0874_MW120_S_180417, 0874_MW061_S_180417,

0874_MW063_S_180417, 0874_MW245_S_180417,

0874_MW246_S_180417, 0874_MW232_S_180417,

0874_MW026_S_180417, 0874_MW243_S_180417

19-Apr-2018---- 18-Apr-2018----17-Apr-2018 ---- ü



0874_MW116_S_180417, 0874_MW126_S_180417,

0874_MW120_S_180417, 0874_MW061_S_180417,

0874_MW063_S_180417, 0874_MW245_S_180417,

0874_MW246_S_180417, 0874_MW232_S_180417,

0874_MW026_S_180417, 0874_MW243_S_180417

15-May-2018---- 19-Apr-2018----17-Apr-2018 ---- ü



0874_MW116_S_180417, 0874_MW126_S_180417,

0874_MW120_S_180417, 0874_MW061_S_180417,

0874_MW063_S_180417, 0874_MW245_S_180417,

0874_MW246_S_180417, 0874_MW232_S_180417,

0874_MW026_S_180417, 0874_MW243_S_180417

15-May-2018---- 26-Apr-2018----17-Apr-2018 ---- ü



0874_MW116_S_180417, 0874_MW126_S_180417,

0874_MW120_S_180417, 0874_MW061_S_180417,

0874_MW063_S_180417, 0874_MW245_S_180417,

0874_MW232_S_180417, 0874_MW026_S_180417,

0874_MW243_S_180417

19-Apr-2018---- 19-Apr-2018----17-Apr-2018 ---- ü



0874_MW126_S_180417, 0874_MW245_S_180417,

0874_MW232_S_180417, 0874_MW265_S_180417


9 of 19:Page

Work Order :

:Client

ET1801059








0874_MW126_S_180417, 0874_MW245_S_180417,

0874_MW232_S_180417, 0874_MW265_S_180417




0874_MW126_S_180417, 0874_MW245_S_180417,

0874_MW232_S_180417, 0874_MW265_S_180417




0874_MW126_S_180417, 0874_MW245_S_180417,

0874_MW232_S_180417, 0874_MW265_S_180417




0874_MW126_S_180417, 0874_MW245_S_180417,

0874_MW232_S_180417, 0874_MW265_S_180417




0874_MW116_S_180417, 0874_MW126_S_180417,

0874_MW129_S_180417, 0874_MW013_S_180417,

0874_MW118_S_180417, 0874_MW034_S_180417,

0874_MW033_S_180417, 0874_MW120_S_180417,

0874_MW061_S_180417, 0874_MW063_S_180417,

0874_MW056_S_180417, 0874_MW135_S_180417,

0874_MW122_S_180417, 0874_MW245_S_180417,

0874_MW246_S_180417, 0874_MW232_S_180417,

0874_MW026_S_180417, 0874_MW243_S_180417,

0874_MW136_S_180417, 0874_MW265_S_180417,

0874_MW004_S_180417, 0874_MW116_S_180417_F,

0874_MW126_S_180417_F, 0874_MW120_S_180417_F,

0874_MW061_S_180417_F, 0874_MW063_S_180417_F,

0874_MW245_S_180417_F, 0874_MW246_S_180417_F,

0874_MW232_S_180417_F, 0874_MW026_S_180417_F,

0874_MW243_S_180417_F, 0874_QC1MW_180417_01

14-Oct-2018---- 23-Apr-2018----17-Apr-2018 ---- ü


0874_QC1MW_180417_02, 0874_QC1MW_180417_03,

0874_QC3MW_180417, 0874_QC4MW_180417,

0874_QC5MW_180417_01, 0874_QC5MW_180417_02,

0874_QC5MW_180417_03, 0874_QC5MW_180417_04

14-Oct-2018---- 26-Apr-2018----17-Apr-2018 ---- ü

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0874_MW116_S_180417, 0874_MW126_S_180417,

0874_MW129_S_180417, 0874_MW013_S_180417,

0874_MW118_S_180417, 0874_MW034_S_180417,

0874_MW033_S_180417, 0874_MW120_S_180417,

0874_MW061_S_180417, 0874_MW063_S_180417,

0874_MW056_S_180417, 0874_MW135_S_180417,

0874_MW122_S_180417, 0874_MW245_S_180417,

0874_MW246_S_180417, 0874_MW232_S_180417,

0874_MW026_S_180417, 0874_MW243_S_180417,

0874_MW136_S_180417, 0874_MW265_S_180417,

0874_MW004_S_180417, 0874_MW116_S_180417_F,

0874_MW126_S_180417_F, 0874_MW120_S_180417_F,

0874_MW061_S_180417_F, 0874_MW063_S_180417_F,

0874_MW245_S_180417_F, 0874_MW246_S_180417_F,

0874_MW232_S_180417_F, 0874_MW026_S_180417_F,

0874_MW243_S_180417_F, 0874_QC1MW_180417_01

14-Oct-2018---- 23-Apr-2018----17-Apr-2018 ---- ü


0874_QC1MW_180417_02, 0874_QC1MW_180417_03,

0874_QC3MW_180417, 0874_QC4MW_180417,

0874_QC5MW_180417_01, 0874_QC5MW_180417_02,

0874_QC5MW_180417_03, 0874_QC5MW_180417_04

14-Oct-2018---- 26-Apr-2018----17-Apr-2018 ---- ü

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0874_MW116_S_180417, 0874_MW126_S_180417,

0874_MW129_S_180417, 0874_MW013_S_180417,

0874_MW118_S_180417, 0874_MW034_S_180417,

0874_MW033_S_180417, 0874_MW120_S_180417,

0874_MW061_S_180417, 0874_MW063_S_180417,

0874_MW056_S_180417, 0874_MW135_S_180417,

0874_MW122_S_180417, 0874_MW245_S_180417,

0874_MW246_S_180417, 0874_MW232_S_180417,

0874_MW026_S_180417, 0874_MW243_S_180417,

0874_MW136_S_180417, 0874_MW265_S_180417,

0874_MW004_S_180417, 0874_MW116_S_180417_F,

0874_MW126_S_180417_F, 0874_MW120_S_180417_F,

0874_MW061_S_180417_F, 0874_MW063_S_180417_F,

0874_MW245_S_180417_F, 0874_MW246_S_180417_F,

0874_MW232_S_180417_F, 0874_MW026_S_180417_F,

0874_MW243_S_180417_F, 0874_QC1MW_180417_01

14-Oct-2018---- 23-Apr-2018----17-Apr-2018 ---- ü


0874_QC1MW_180417_02, 0874_QC1MW_180417_03,

0874_QC3MW_180417, 0874_QC4MW_180417,

0874_QC5MW_180417_01, 0874_QC5MW_180417_02,

0874_QC5MW_180417_03, 0874_QC5MW_180417_04

14-Oct-2018---- 26-Apr-2018----17-Apr-2018 ---- ü

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0874_MW116_S_180417, 0874_MW126_S_180417,

0874_MW129_S_180417, 0874_MW013_S_180417,

0874_MW118_S_180417, 0874_MW034_S_180417,

0874_MW033_S_180417, 0874_MW120_S_180417,

0874_MW061_S_180417, 0874_MW063_S_180417,

0874_MW056_S_180417, 0874_MW135_S_180417,

0874_MW122_S_180417, 0874_MW245_S_180417,

0874_MW246_S_180417, 0874_MW232_S_180417,

0874_MW026_S_180417, 0874_MW243_S_180417,

0874_MW136_S_180417, 0874_MW265_S_180417,

0874_MW004_S_180417, 0874_MW116_S_180417_F,

0874_MW126_S_180417_F, 0874_MW120_S_180417_F,

0874_MW061_S_180417_F, 0874_MW063_S_180417_F,

0874_MW245_S_180417_F, 0874_MW246_S_180417_F,

0874_MW232_S_180417_F, 0874_MW026_S_180417_F,

0874_MW243_S_180417_F, 0874_QC1MW_180417_01

14-Oct-2018---- 23-Apr-2018----17-Apr-2018 ---- ü


0874_QC1MW_180417_02, 0874_QC1MW_180417_03,

0874_QC3MW_180417, 0874_QC4MW_180417,

0874_QC5MW_180417_01, 0874_QC5MW_180417_02,

0874_QC5MW_180417_03, 0874_QC5MW_180417_04

14-Oct-2018---- 26-Apr-2018----17-Apr-2018 ---- ü

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EP231P: PFAS Sums


0874_MW116_S_180417, 0874_MW126_S_180417,

0874_MW129_S_180417, 0874_MW013_S_180417,

0874_MW118_S_180417, 0874_MW034_S_180417,

0874_MW033_S_180417, 0874_MW120_S_180417,

0874_MW061_S_180417, 0874_MW063_S_180417,

0874_MW056_S_180417, 0874_MW135_S_180417,

0874_MW122_S_180417, 0874_MW245_S_180417,

0874_MW246_S_180417, 0874_MW232_S_180417,

0874_MW026_S_180417, 0874_MW243_S_180417,

0874_MW136_S_180417, 0874_MW265_S_180417,

0874_MW004_S_180417, 0874_MW116_S_180417_F,

0874_MW126_S_180417_F, 0874_MW120_S_180417_F,

0874_MW061_S_180417_F, 0874_MW063_S_180417_F,

0874_MW245_S_180417_F, 0874_MW246_S_180417_F,

0874_MW232_S_180417_F, 0874_MW026_S_180417_F,

0874_MW243_S_180417_F, 0874_QC1MW_180417_01

14-Oct-2018---- 23-Apr-2018----17-Apr-2018 ---- ü


0874_QC1MW_180417_02, 0874_QC1MW_180417_03,

0874_QC3MW_180417, 0874_QC4MW_180417,

0874_QC5MW_180417_01, 0874_QC5MW_180417_02,

0874_QC5MW_180417_03, 0874_QC5MW_180417_04

14-Oct-2018---- 26-Apr-2018----17-Apr-2018 ---- ü

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Method Blanks (MB)






















Matrix Spikes (MS)








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Schedule B(3)





Conductivity)

EA016 WATER









Schedule B(3)







Discrete Analyser

ED041G WATER











Schedule B(3)


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Schedule B(3)


Analyser

EK059G WATER





Analyser

EK061G WATER


B(3)


Discrete Analyser

EK062G WATER





Schedule B(3)


Analyser

EK067G WATER






Analyser

EK071G WATER


DA

EN055 - PG WATER




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EP026SP WATER






B(3)











(PFAS) by LCMSMS

EP231X WATER












Schedule B(3)




pp. 9342¿9349:


EP231.


PFAS

* ORG70-W WATER

Environmental





C/O GPO BOX 2907



QLD AUSTRALIA 4814






V4)


Site : ----




Date

27-Apr-2018


No. of coolers/boxes : :5 Temperature 4.3, 0.5, 13.2, 5.5, 2.2°C -

Ice present


General Comments






l Please be advised that for sample #27 an aliquot has been split and filtered into another PFAS

bottle and analysis will assigned in the filtered bottle. This has been confirmed with Jack McBain

via phone call 18.4.18.l Please be advised that no BOD analysis will be assigned for ALS sample #15 as confirmed by

Jack McBain via phone call 18.4.18.l Please be advised that the container for ALS sample #33 is labelled as '0874_QC1MW_180417_02'

instead of '0874_QC1MW_180417_01' as per the COC. The sample ID in the container has been

assigned as confirmed by Jack McBain via email 18.4.18.l Please be advised that the container for ALS sample #34 is labelled as '0874_QC1MW_180417_03'

instead of '0874_QC1MW_180417_01' as per the COC. The sample ID in the container has been

assigned as confirmed by Jack McBain via email 18.4.18.l Please be advised that the container for ALS sample #7 is labelled as '0874_MW033_S_180417'

instead of '0874_MW003_S_180417' as per the COC. The sample ID in the container will be used as

confirmed by Jack McBain via phone call 18.4.18.l Discounted Package Prices apply only when specific ALS Group Codes ('W', 'S', 'NT' suites) are referenced on COCs.














ET1801059-022 : [ 17-Apr-2018 ] : 0874_MW116_S_180417_F

ET1801059-023 : [ 17-Apr-2018 ] : 0874_MW126_S_180417_F

ET1801059-024 : [ 17-Apr-2018 ] : 0874_MW120_S_180417_F

ET1801059-025 : [ 17-Apr-2018 ] : 0874_MW061_S_180417_F

ET1801059-026 : [ 17-Apr-2018 ] : 0874_MW063_S_180417_F

ET1801059-027 : [ 17-Apr-2018 ] : 0874_MW245_S_180417_F

ET1801059-028 : [ 17-Apr-2018 ] : 0874_MW246_S_180417_F

ET1801059-029 : [ 17-Apr-2018 ] : 0874_MW232_S_180417_F

ET1801059-030 : [ 17-Apr-2018 ] : 0874_MW026_S_180417_F

ET1801059-031 : [ 17-Apr-2018 ] : 0874_MW243_S_180417_F

ET1801059-032 : [ 17-Apr-2018 ] : 0874_QC1MW_180417_01

ET1801059-033 : [ 17-Apr-2018 ] : 0874_QC1MW_180417_02

ET1801059-034 : [ 17-Apr-2018 ] : 0874_QC1MW_180417_03

ET1801059-037 : [ 17-Apr-2018 ] : 0874_QC5MW_180417_01

ET1801059-038 : [ 17-Apr-2018 ] : 0874_QC5MW_180417_02

ET1801059-039 : [ 17-Apr-2018 ] : 0874_QC5MW_180417_03

ET1801059-040 : [ 17-Apr-2018 ] : 0874_QC5MW_180417_04











component

WA

TE

R -

EG

02

0F

Dis

solv

ed

Me

tals

by

ICP

/MS

WA

TE

R -

EG

05

1G

Ferr

ous

Iro

n

WA

TE

R -

EP

02

6S

P

Chem

ical O

xyg

en

De

ma

nd

(C

OD

)

WA

TE

R -

EP

03

0

BO

D

WA

TE

R -

EP

23

1X

PF

AS

- F

ull

Su

ite (

28

an

aly

tes)

WA

TE

R -

NT

-01

& 0

2

Ca, M

g, N

a, K

, C

l, S

O4

, A

lka

linity

WA

TE

R -

NT

-14

Ext

ended

Wa

ter

Su

ite B



ET1801059-003 17-Apr-2018 00:00 0874_MW129_S_180417 ü ü

ET1801059-004 17-Apr-2018 00:00 0874_MW013_S_180417 ü ü

ET1801059-005 17-Apr-2018 00:00 0874_MW118_S_180417 ü ü

ET1801059-006 17-Apr-2018 00:00 0874_MW034_S_180417 ü ü

ET1801059-007 17-Apr-2018 00:00 0874_MW033_S_180417 ü ü




ET1801059-011 17-Apr-2018 00:00 0874_MW056_S_180417 ü ü

ET1801059-012 17-Apr-2018 00:00 0874_MW135_S_180417 ü ü

ET1801059-013 17-Apr-2018 00:00 0874_MW122_S_180417 ü ü


ET1801059-015 17-Apr-2018 00:00 0874_MW246_S_180417 ü ü ü ü ü ü




ET1801059-019 17-Apr-2018 00:00 0874_MW136_S_180417 ü ü

ET1801059-020 17-Apr-2018 00:00 0874_MW265_S_180417 ü ü

Matrix: WATER


ID

Client sampling

date / time




WA

TE

R -

EG

020F

Dis

solv

ed

Me

tals

by

ICP

/MS

WA

TE

R -

EG

051G

Ferr

ou

s Ir

on

WA

TE

R -

EP

02

6S

P

Che

mic

al O

xyg

en D

em

an

d (

CO

D)

WA

TE

R -

EP

03

0

BO

D

WA

TE

R -

EP

23

1X

PF

AS

- F

ull

Suite

(28 a

naly

tes)

WA

TE

R -

NT

-01 &

02

Ca,

Mg,

Na,

K, C

l, S

O4,

Alk

alin

ity

WA

TE

R -

NT

-14

Ext

ende

d W

ate

r S

uite

B

ET1801059-021 17-Apr-2018 00:00 0874_MW004_S_180417 ü ü

ET1801059-022 17-Apr-2018 00:00 0874_MW116_S_180417_F ü

ET1801059-023 17-Apr-2018 00:00 0874_MW126_S_180417_F ü

ET1801059-024 17-Apr-2018 00:00 0874_MW120_S_180417_F ü

ET1801059-025 17-Apr-2018 00:00 0874_MW061_S_180417_F ü

ET1801059-026 17-Apr-2018 00:00 0874_MW063_S_180417_F ü

ET1801059-027 17-Apr-2018 00:00 0874_MW245_S_180417_F ü

ET1801059-028 17-Apr-2018 00:00 0874_MW246_S_180417_F ü

ET1801059-029 17-Apr-2018 00:00 0874_MW232_S_180417_F ü

ET1801059-030 17-Apr-2018 00:00 0874_MW026_S_180417_F ü

ET1801059-031 17-Apr-2018 00:00 0874_MW243_S_180417_F ü

ET1801059-032 17-Apr-2018 00:00 0874_QC1MW_180417_01 ü ü

ET1801059-033 17-Apr-2018 00:00 0874_QC1MW_180417_02 ü ü

ET1801059-034 17-Apr-2018 00:00 0874_QC1MW_180417_03 ü ü

ET1801059-035 17-Apr-2018 00:00 0874_QC3MW_180417 ü ü

ET1801059-036 17-Apr-2018 00:00 0874_QC4MW_180417 ü

ET1801059-037 17-Apr-2018 00:00 0874_QC5MW_180417_01 ü

ET1801059-038 17-Apr-2018 00:00 0874_QC5MW_180417_02 ü

ET1801059-039 17-Apr-2018 00:00 0874_QC5MW_180417_03 ü

ET1801059-040 17-Apr-2018 00:00 0874_QC5MW_180417_04 ü

WA

TE

R -

EA

015H

Tota

l Dis

solv

ed S

olid

s -

Sta

ndard

Leve

l

WA

TE

R -

EA

025H

Susp

ended S

olid

s -

Sta

ndard

Leve

l

WA

TE

R -

EA

045

Turb

idity

WA

TE

R -

EP

005

Tota

l Org

anic

Carb

on (

TO

C)

WA

TE

R -

EP

231X

(T

OP

)

PF

AS

- T

ota

l Oxi

dis

able

Pre

curs

or

(TO

P)

Ass

ay

ET1801059-001 17-Apr-2018 00:00 0874_MW116_S_180417 ü ü ü ü

ET1801059-002 17-Apr-2018 00:00 0874_MW126_S_180417 ü ü ü ü ü

ET1801059-008 17-Apr-2018 00:00 0874_MW120_S_180417 ü ü ü ü

ET1801059-009 17-Apr-2018 00:00 0874_MW061_S_180417 ü ü ü ü

ET1801059-010 17-Apr-2018 00:00 0874_MW063_S_180417 ü ü ü ü

ET1801059-014 17-Apr-2018 00:00 0874_MW245_S_180417 ü ü ü ü ü

ET1801059-015 17-Apr-2018 00:00 0874_MW246_S_180417 ü ü ü ü

ET1801059-016 17-Apr-2018 00:00 0874_MW232_S_180417 ü ü ü ü ü

ET1801059-017 17-Apr-2018 00:00 0874_MW026_S_180417 ü ü ü ü

ET1801059-018 17-Apr-2018 00:00 0874_MW243_S_180417 ü ü ü ü

Matrix: WATER


ID

Client sampling

date / time




WA

TE

R -

EA

01

5H

Tota

l Dis

solv

ed

Solid

s -

Sta

nda

rd L

eve

l

WA

TE

R -

EA

02

5H

Susp

en

de

d S

olid

s -

Sta

nd

ard

Le

vel

WA

TE

R -

EA

04

5

Turb

idity

WA

TE

R -

EP

00

5

Tota

l Org

an

ic C

arb

on

(T

OC

)

WA

TE

R -

EP

23

1X

(T

OP

)

PF

AS

- T

ota

l Oxi

dis

able

Pre

curs

or

(TO

P)

Ass

ay

ET1801059-020 17-Apr-2018 00:00 0874_MW265_S_180417 ü






Due for

extraction

Due for

analysis Evaluation


Date Date

Method

Container


0874_MW026_S_180417 û --------18-Apr-201817-Apr-2018----Clear Plastic Bottle - Natural














ACCOUNTS PAYABLE


AU ACCOUNTS PAYABLE


DAVID HARRIS








DERP LABREPORTS


PHIL SCHULZ








RESULTS RESULTS








0 0.00 True

Environmental





C/O GPO BOX 2907








Site : ----






l General Comments










Greg Vogel Laboratory Manager Brisbane Inorganics, Stafford, QLD




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General Comments







purposes.







Key :

EP231: Matrix spike recovery bias low due to matrix interference.l


23313)

l

EP231X(TOP) and EP231X-ST conducted by ALS Sydney, NATA accreditation no. 825, site no 10911.l

EP231: Particular samples required dilution due to the presence of high level contaminants. LOR values have been adjusted accordingly.l



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Analytical Results

0874_SW203_1804180874_SW207_1804180874_SW206_1804180874_SW205_1804180874_QC1SW_180418

_01


(Matrix: WATER)












199Chloride 4460 12300 10200 16400mg/L116887-00-6


26Calcium 110 307 256 397mg/L17440-70-2

12Magnesium 298 1020 844 1370mg/L17439-95-4

123Sodium 2530 7520 6140 10100mg/L17440-23-5

2Potassium 97 401 331 501mg/L17440-09-7


7.39 141 389 323 516meq/L0.01----Total Anions

7.69 142 437 358 585meq/L0.01----Total Cations

1.94 0.61 5.80 5.12 6.22%0.01----Ionic Balance



(PFBS)

---- ---- ---- 0.0220µg/L0.0005375-73-5


(PFBS)

0.10 <0.10 0.10 ----µg/L0.02375-73-5


(PFPeS)

---- ---- ---- 0.0032µg/L0.00052706-91-4


(PFPeS)

<0.05 <0.10 <0.10 ----µg/L0.022706-91-4


(PFHxS)

---- ---- ---- 0.0261µg/L0.0005355-46-4


(PFHxS)

0.48 0.16 0.18 ----µg/L0.02355-46-4


(PFHpS)

---- ---- ---- 0.0011µg/L0.0005375-92-8


(PFHpS)

<0.05 <0.10 <0.10 ----µg/L0.02375-92-8

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Analytical Results

0874_SW203_1804180874_SW207_1804180874_SW206_1804180874_SW205_1804180874_QC1SW_180418

_01


(Matrix: WATER)






(PFOS)

---- ---- ---- 0.0191µg/L0.00031763-23-1


(PFDS)

---- ---- ---- <0.0005µg/L0.0005335-77-3


(PFOS)

0.39 <0.10 0.21 ----µg/L0.011763-23-1


(PFDS)

<0.05 <0.10 <0.10 ----µg/L0.02335-77-3


<0.002Perfluorobutanoic acid (PFBA) ---- ---- ---- <0.002µg/L0.002375-22-4

----Perfluorobutanoic acid (PFBA) <0.2 <0.5 <0.5 ----µg/L0.1375-22-4

0.0218Perfluoropentanoic acid (PFPeA) ---- ---- ---- 0.0031µg/L0.00052706-90-3

----Perfluoropentanoic acid (PFPeA) 0.06 <0.10 <0.10 ----µg/L0.022706-90-3


----Perfluorohexanoic acid (PFHxA) 0.18 <0.10 0.13 ----µg/L0.02307-24-4

0.0124Perfluoroheptanoic acid (PFHpA) ---- ---- ---- 0.0015µg/L0.0005375-85-9

----Perfluoroheptanoic acid (PFHpA) <0.05 <0.10 <0.10 ----µg/L0.02375-85-9


----Perfluorooctanoic acid (PFOA) <0.05 <0.10 <0.10 ----µg/L0.01335-67-1

0.0008Perfluorononanoic acid (PFNA) ---- ---- ---- <0.0005µg/L0.0005375-95-1

----Perfluorononanoic acid (PFNA) <0.05 <0.10 <0.10 ----µg/L0.02375-95-1

0.0005Perfluorodecanoic acid (PFDA) ---- ---- ---- <0.0005µg/L0.0005335-76-2

----Perfluorodecanoic acid (PFDA) <0.05 <0.10 <0.10 ----µg/L0.02335-76-2


(PFUnDA)

---- ---- ---- <0.0005µg/L0.00052058-94-8


(PFUnDA)

<0.05 <0.10 <0.10 ----µg/L0.022058-94-8


(PFDoDA)

---- ---- ---- <0.0005µg/L0.0005307-55-1


(PFDoDA)

<0.05 <0.10 <0.10 ----µg/L0.02307-55-1


(PFTrDA)

---- ---- ---- <0.0005µg/L0.000572629-94-8


(PFTrDA)

<0.05 <0.10 <0.10 ----µg/L0.0272629-94-8

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Analytical Results

0874_SW203_1804180874_SW207_1804180874_SW206_1804180874_SW205_1804180874_QC1SW_180418

_01


(Matrix: WATER)






(PFTeDA)

---- ---- ---- <0.0005µg/L0.0005376-06-7


(PFTeDA)

<0.12 <0.25 <0.25 ----µg/L0.05376-06-7



(FOSA)

---- ---- ---- <0.0005µg/L0.0005754-91-6


(FOSA)

<0.05 <0.10 <0.10 ----µg/L0.02754-91-6



---- ---- ---- <0.001µg/L0.00131506-32-8



<0.12 <0.25 <0.25 ----µg/L0.0531506-32-8



---- ---- ---- <0.001µg/L0.0014151-50-2



<0.12 <0.25 <0.25 ----µg/L0.054151-50-2



---- ---- ---- <0.001µg/L0.00124448-09-7



<0.12 <0.25 <0.25 ----µg/L0.0524448-09-7



---- ---- ---- <0.001µg/L0.0011691-99-2



<0.12 <0.25 <0.25 ----µg/L0.051691-99-2



(MeFOSAA)

---- ---- ---- <0.0005µg/L0.00052355-31-9



(MeFOSAA)

<0.05 <0.10 <0.10 ----µg/L0.022355-31-9



(EtFOSAA)

---- ---- ---- <0.0005µg/L0.00052991-50-6

6 of 25:Page

Work Order :

:Client

ET1801082



Analytical Results

0874_SW203_1804180874_SW207_1804180874_SW206_1804180874_SW205_1804180874_QC1SW_180418

_01


(Matrix: WATER)







(EtFOSAA)

<0.05 <0.10 <0.10 ----µg/L0.022991-50-6



(4:2 FTS)

---- ---- ---- <0.001µg/L0.001757124-72-4


(4:2 FTS)

<0.05 <0.10 <0.10 ----µg/L0.05757124-72-4


(6:2 FTS)

---- ---- ---- <0.001µg/L0.00127619-97-2


(6:2 FTS)

<0.05 <0.10 <0.10 ----µg/L0.0527619-97-2


(8:2 FTS)

---- ---- ---- <0.001µg/L0.00139108-34-4


(8:2 FTS)

<0.05 <0.10 <0.10 ----µg/L0.0539108-34-4


(10:2 FTS)

---- ---- ---- <0.001µg/L0.001120226-60-0


(10:2 FTS)

<0.05 <0.10 <0.10 ----µg/L0.05120226-60-0

EP231P: PFAS Sums

0.773 ---- ---- ---- 0.0870µg/L0.0003----Sum of PFAS

---- 1.21 0.16 0.62 ----µg/L0.01----Sum of PFAS


1

----Sum of PFHxS and PFOS 0.87 0.16 0.39 ----µg/L0.01355-46-4/1763-23-

1

0.714 ---- ---- ---- 0.0827µg/L0.0003----Sum of PFAS (WA DER List)

---- 1.21 0.16 0.62 ----µg/L0.01----Sum of PFAS (WA DER List)


82.6 ---- ---- ---- 95.8%0.0005----13C4-PFOS

---- 94.2 102 106 ----%0.02----13C4-PFOS

84.6 ---- ---- ---- 107%0.0005----13C8-PFOA

---- 95.7 94.0 96.8 ----%0.02----13C8-PFOA

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:Client

ET1801082



Analytical Results


(Matrix: WATER)





---- ---- ---- 7.71 ----pH Unit0.01----pH Value


----^ ---- ---- 6.79 -----0.01----Sodium Adsorption Ratio


---- ---- ---- 1020 ----µS/cm1----Electrical Conductivity @ 25°C


---- ---- ---- 578 ----mg/L10----Total Dissolved Solids @180°C


---- ---- ---- 663 ----mg/L1----Total Dissolved Solids (Calc.)


---- ---- ---- 14 ----mg/L5----Suspended Solids (SS)

EA045: Turbidity

---- ---- ---- 5.3 ----NTU0.1----Turbidity


---- ---- ---- 112 ----mg/L1----Total Hardness as CaCO3









9930Chloride 17500 6670 264 206mg/L116887-00-6


251Calcium 393 205 25 26mg/L17440-70-2

810Magnesium 1370 494 12 12mg/L17439-95-4

5820Sodium 10100 3970 165 121mg/L17440-23-5

313Potassium 498 145 2 2mg/L17440-09-7


----Aluminium ---- ---- <0.01 ----mg/L0.017429-90-5

----Manganese ---- ---- 0.030 ----mg/L0.0017439-96-5

----Iron ---- ---- 0.06 ----mg/L0.057439-89-6

8 of 25:Page

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:Client

ET1801082



Analytical Results


(Matrix: WATER)





---- ---- ---- 0.05 ----mg/L0.05----Ferrous Iron


----Fluoride ---- ---- 0.1 ----mg/L0.116984-48-8


----Ammonia as N ---- ---- <0.01 ----mg/L0.017664-41-7


----Nitrite as N ---- ---- <0.01 ----mg/L0.0114797-65-0


----Nitrate as N ---- ---- 0.08 ----mg/L0.0114797-55-8


---- ---- ---- 0.08 ----mg/L0.01----Nitrite + Nitrate as N


---- ---- ---- 0.7 ----mg/L0.1----Total Kjeldahl Nitrogen as N


----^ ---- ---- 0.8 ----mg/L0.1----Total Nitrogen as N


---- ---- ---- 0.04 ----mg/L0.01----Total Phosphorus as P


----Reactive Phosphorus as P ---- ---- <0.01 ----mg/L0.0114265-44-2


315 550 212 9.78 7.67meq/L0.01----Total Anions

340 584 227 9.46 7.60meq/L0.01----Total Cations

3.86 3.01 3.57 1.66 0.47%0.01----Ionic Balance


---- ---- ---- 8 ----mg/L1----Total Organic Carbon


---- ---- ---- 25 ----mg/L10----Chemical Oxygen Demand


---- ---- ---- 2 ----mg/L2----Biochemical Oxygen Demand



(PFBS)

---- ---- 2.53 ----µg/L0.02375-73-5

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:Client

ET1801082



Analytical Results


(Matrix: WATER)






(PFPeS)

---- ---- 2.66 ----µg/L0.022706-91-4


(PFHxS)

---- ---- 16.9 ----µg/L0.02355-46-4


(PFHpS)

---- ---- 1.09 ----µg/L0.02375-92-8


(PFOS)

---- ---- 18.7 ----µg/L0.011763-23-1


(PFDS)

---- ---- <0.10 ----µg/L0.02335-77-3










(PFUnDA)

---- ---- <0.10 ----µg/L0.022058-94-8


(PFDoDA)

---- ---- <0.10 ----µg/L0.02307-55-1


(PFTrDA)

---- ---- <0.10 ----µg/L0.0272629-94-8


(PFTeDA)

---- ---- <0.25 ----µg/L0.05376-06-7



(FOSA)

---- ---- <0.10 ----µg/L0.02754-91-6



---- ---- <0.25 ----µg/L0.0531506-32-8



---- ---- <0.25 ----µg/L0.054151-50-2



---- ---- <0.25 ----µg/L0.0524448-09-7

10 of 25:Page

Work Order :

:Client

ET1801082



Analytical Results


(Matrix: WATER)







---- ---- <0.25 ----µg/L0.051691-99-2



(MeFOSAA)

---- ---- <0.10 ----µg/L0.022355-31-9



(EtFOSAA)

---- ---- <0.10 ----µg/L0.022991-50-6



(4:2 FTS)

---- ---- <0.10 ----µg/L0.05757124-72-4


(6:2 FTS)

---- ---- <0.10 ----µg/L0.0527619-97-2


(8:2 FTS)

---- ---- <0.10 ----µg/L0.0539108-34-4


(10:2 FTS)

---- ---- <0.10 ----µg/L0.05120226-60-0


---- ---- ---- 65.1 ----µg/L0.01----Sum of PFAS


1

---- ---- ---- 65.1 ----µg/L0.01----Sum of TOP C4 - C14 Carboxylates and C4

- C8 Sulfonates

----^ ---- ---- 41.6 ----µg/L0.01----Sum of TOP C4 - C14 as Fluorine



(PFBS)

0.0023 0.0805 ---- 0.0866µg/L0.0005375-73-5


(PFBS)

---- ---- 2.96 ----µg/L0.02375-73-5


(PFPeS)

0.0021 0.0015 ---- 0.0623µg/L0.00052706-91-4


(PFPeS)

---- ---- 2.67 ----µg/L0.022706-91-4


(PFHxS)

0.0150 0.0103 ---- 0.500µg/L0.0005355-46-4

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:Client

ET1801082



Analytical Results


(Matrix: WATER)






(PFHxS)

---- ---- 16.6 ----µg/L0.02355-46-4


(PFHpS)

0.0006 <0.0005 ---- 0.0186µg/L0.0005375-92-8


(PFHpS)

---- ---- 1.60 ----µg/L0.02375-92-8


(PFOS)

0.0082 0.0053 ---- 0.356µg/L0.00031763-23-1


(PFDS)

<0.0005 <0.0005 ---- <0.0005µg/L0.0005335-77-3


(PFOS)

---- ---- 25.9 ----µg/L0.011763-23-1


(PFDS)

---- ---- <0.02 ----µg/L0.02335-77-3


<0.002Perfluorobutanoic acid (PFBA) <0.002 0.006 ---- 0.010µg/L0.002375-22-4


0.0121Perfluoropentanoic acid (PFPeA) 0.0014 0.0022 ---- 0.0283µg/L0.00052706-90-3


0.0504Perfluorohexanoic acid (PFHxA) 0.0049 0.0019 ---- 0.151µg/L0.0005307-24-4


0.0067Perfluoroheptanoic acid (PFHpA) 0.0009 0.0012 ---- 0.0166µg/L0.0005375-85-9


0.0111Perfluorooctanoic acid (PFOA) 0.0007 0.0009 ---- 0.0295µg/L0.0005335-67-1


<0.0005Perfluorononanoic acid (PFNA) <0.0005 <0.0005 ---- 0.0011µg/L0.0005375-95-1


<0.0005Perfluorodecanoic acid (PFDA) <0.0005 <0.0005 ---- 0.0007µg/L0.0005335-76-2



(PFUnDA)

<0.0005 <0.0005 ---- <0.0005µg/L0.00052058-94-8


(PFUnDA)

---- ---- <0.02 ----µg/L0.022058-94-8


(PFDoDA)

<0.0005 <0.0005 ---- <0.0005µg/L0.0005307-55-1

12 of 25:Page

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:Client

ET1801082



Analytical Results


(Matrix: WATER)






(PFDoDA)

---- ---- <0.02 ----µg/L0.02307-55-1


(PFTrDA)

<0.0005 <0.0005 ---- <0.0005µg/L0.000572629-94-8


(PFTrDA)

---- ---- <0.02 ----µg/L0.0272629-94-8


(PFTeDA)

<0.0005 <0.0005 ---- <0.0005µg/L0.0005376-06-7


(PFTeDA)

---- ---- <0.05 ----µg/L0.05376-06-7



(FOSA)

<0.0005 <0.0005 ---- 0.0009µg/L0.0005754-91-6


(FOSA)

---- ---- 0.04 ----µg/L0.02754-91-6



<0.001 <0.001 ---- <0.001µg/L0.00131506-32-8



---- ---- <0.05 ----µg/L0.0531506-32-8



<0.001 <0.001 ---- <0.001µg/L0.0014151-50-2



---- ---- <0.05 ----µg/L0.054151-50-2



<0.001 <0.001 ---- <0.001µg/L0.00124448-09-7



---- ---- <0.05 ----µg/L0.0524448-09-7



<0.001 <0.001 ---- <0.001µg/L0.0011691-99-2



---- ---- <0.05 ----µg/L0.051691-99-2



(MeFOSAA)

<0.0005 <0.0005 ---- <0.0005µg/L0.00052355-31-9

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:Client

ET1801082



Analytical Results


(Matrix: WATER)







(MeFOSAA)

---- ---- <0.02 ----µg/L0.022355-31-9



(EtFOSAA)

<0.0005 <0.0005 ---- <0.0005µg/L0.00052991-50-6



(EtFOSAA)

---- ---- <0.02 ----µg/L0.022991-50-6



(4:2 FTS)

<0.001 <0.001 ---- <0.001µg/L0.001757124-72-4


(4:2 FTS)

---- ---- <0.05 ----µg/L0.05757124-72-4


(6:2 FTS)

<0.001 <0.001 ---- 0.005µg/L0.00127619-97-2


(6:2 FTS)

---- ---- <0.05 ----µg/L0.0527619-97-2


(8:2 FTS)

<0.001 <0.001 ---- <0.001µg/L0.00139108-34-4


(8:2 FTS)

---- ---- <0.05 ----µg/L0.0539108-34-4


(10:2 FTS)

<0.001 <0.001 ---- <0.001µg/L0.001120226-60-0


(10:2 FTS)

---- ---- <0.05 ----µg/L0.05120226-60-0

EP231P: PFAS Sums

0.412 0.0361 0.110 ---- 1.27µg/L0.0003----Sum of PFAS

---- ---- ---- 57.4 ----µg/L0.01----Sum of PFAS

0.278Sum of PFHxS and PFOS 0.0232 0.0156 ---- 0.856µg/L0.0003355-46-4/1763-23-

1


1

0.387 0.0334 0.108 ---- 1.18µg/L0.0003----Sum of PFAS (WA DER List)



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ET1801082



Analytical Results


(Matrix: WATER)




EP231_TOP_S: PFAS Surrogate - Continued

---- ---- ---- 100 ----%0.02----13C4-PFOS

---- ---- ---- 99.0 ----%0.02----13C8-PFOA


107 73.4 109 ---- 96.6%0.0005----13C4-PFOS

---- ---- ---- 91.8 ----%0.02----13C4-PFOS

104 98.1 106 ---- 104%0.0005----13C8-PFOA

---- ---- ---- 100 ----%0.02----13C8-PFOA

15 of 25:Page

Work Order :

:Client

ET1801082



Analytical Results

0874_QC3SW_1804180874_QC1SW_180418

_02

0874_SW123_180418

_F

0874_SW213_1804180874_SW211_180418Client sample IDSub-Matrix: WATER

(Matrix: WATER)





<1Hydroxide Alkalinity as CaCO3 <1 ---- <1 <1mg/L1DMO-210-001

<1Carbonate Alkalinity as CaCO3 <1 ---- <1 <1mg/L13812-32-6

16Bicarbonate Alkalinity as CaCO3 105 ---- 134 3mg/L171-52-3

16 105 ---- 134 3mg/L1----Total Alkalinity as CaCO3


<1Sulfate as SO4 - Turbidimetric 2180 ---- 1580 1mg/L114808-79-8


12Chloride 14300 ---- 10300 <1mg/L116887-00-6


2Calcium 352 ---- 258 <1mg/L17440-70-2

2Magnesium 1190 ---- 839 <1mg/L17439-95-4

10Sodium 8780 ---- 6100 <1mg/L17440-23-5

<1Potassium 471 ---- 320 <1mg/L17440-09-7


0.66 451 ---- 326 0.08meq/L0.01----Total Anions

0.70 509 ---- 355 <0.01meq/L0.01----Total Cations

---- 6.10 ---- 4.30 ----%0.01----Ionic Balance



(PFBS)

<0.0005 ---- ---- <0.0005µg/L0.0005375-73-5


(PFBS)

---- 0.88 <0.10 ----µg/L0.02375-73-5


(PFPeS)

<0.0005 ---- ---- <0.0005µg/L0.00052706-91-4


(PFPeS)

---- 0.06 <0.10 ----µg/L0.022706-91-4


(PFHxS)

0.0012 ---- ---- <0.0005µg/L0.0005355-46-4


(PFHxS)

---- <0.02 0.30 ----µg/L0.02355-46-4


(PFHpS)

<0.0005 ---- ---- <0.0005µg/L0.0005375-92-8


(PFHpS)

---- <0.02 <0.10 ----µg/L0.02375-92-8

16 of 25:Page

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:Client

ET1801082



Analytical Results

0874_QC3SW_1804180874_QC1SW_180418

_02

0874_SW123_180418

_F


(Matrix: WATER)






(PFOS)

0.0013 ---- ---- <0.0003µg/L0.00031763-23-1


(PFDS)

<0.0005 ---- ---- <0.0005µg/L0.0005335-77-3


(PFOS)

---- <0.01 0.20 ----µg/L0.011763-23-1


(PFDS)

---- <0.02 <0.10 ----µg/L0.02335-77-3


<0.002Perfluorobutanoic acid (PFBA) <0.002 ---- ---- <0.002µg/L0.002375-22-4

----Perfluorobutanoic acid (PFBA) ---- 0.8 <0.5 ----µg/L0.1375-22-4

<0.0005Perfluoropentanoic acid (PFPeA) <0.0005 ---- ---- <0.0005µg/L0.00052706-90-3

----Perfluoropentanoic acid (PFPeA) ---- 0.99 <0.10 ----µg/L0.022706-90-3

<0.0005Perfluorohexanoic acid (PFHxA) <0.0005 ---- ---- <0.0005µg/L0.0005307-24-4

----Perfluorohexanoic acid (PFHxA) ---- 3.93 0.10 ----µg/L0.02307-24-4

<0.0005Perfluoroheptanoic acid (PFHpA) 0.0008 ---- ---- <0.0005µg/L0.0005375-85-9

----Perfluoroheptanoic acid (PFHpA) ---- 0.34 <0.10 ----µg/L0.02375-85-9

<0.0005Perfluorooctanoic acid (PFOA) <0.0005 ---- ---- <0.0005µg/L0.0005335-67-1

----Perfluorooctanoic acid (PFOA) ---- 0.32 <0.10 ----µg/L0.01335-67-1

<0.0005Perfluorononanoic acid (PFNA) <0.0005 ---- ---- <0.0005µg/L0.0005375-95-1

----Perfluorononanoic acid (PFNA) ---- <0.02 <0.10 ----µg/L0.02375-95-1

<0.0005Perfluorodecanoic acid (PFDA) <0.0005 ---- ---- <0.0005µg/L0.0005335-76-2

----Perfluorodecanoic acid (PFDA) ---- <0.02 <0.10 ----µg/L0.02335-76-2


(PFUnDA)

<0.0005 ---- ---- <0.0005µg/L0.00052058-94-8


(PFUnDA)

---- <0.02 <0.10 ----µg/L0.022058-94-8


(PFDoDA)

<0.0005 ---- ---- <0.0005µg/L0.0005307-55-1


(PFDoDA)

---- <0.02 <0.10 ----µg/L0.02307-55-1


(PFTrDA)

<0.0005 ---- ---- <0.0005µg/L0.000572629-94-8


(PFTrDA)

---- <0.02 <0.10 ----µg/L0.0272629-94-8

17 of 25:Page

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:Client

ET1801082



Analytical Results

0874_QC3SW_1804180874_QC1SW_180418

_02

0874_SW123_180418

_F


(Matrix: WATER)






(PFTeDA)

<0.0005 ---- ---- <0.0005µg/L0.0005376-06-7


(PFTeDA)

---- <0.05 <0.25 ----µg/L0.05376-06-7



(FOSA)

<0.0005 ---- ---- <0.0005µg/L0.0005754-91-6


(FOSA)

---- <0.02 <0.10 ----µg/L0.02754-91-6



<0.001 ---- ---- <0.001µg/L0.00131506-32-8



---- <0.05 <0.25 ----µg/L0.0531506-32-8



<0.001 ---- ---- <0.001µg/L0.0014151-50-2



---- <0.05 <0.25 ----µg/L0.054151-50-2



<0.001 ---- ---- <0.001µg/L0.00124448-09-7



---- <0.05 <0.25 ----µg/L0.0524448-09-7



<0.001 ---- ---- <0.001µg/L0.0011691-99-2



---- <0.05 <0.25 ----µg/L0.051691-99-2



(MeFOSAA)

<0.0005 ---- ---- <0.0005µg/L0.00052355-31-9



(MeFOSAA)

---- <0.02 <0.10 ----µg/L0.022355-31-9



(EtFOSAA)

<0.0005 ---- ---- <0.0005µg/L0.00052991-50-6

18 of 25:Page

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:Client

ET1801082



Analytical Results

0874_QC3SW_1804180874_QC1SW_180418

_02

0874_SW123_180418

_F


(Matrix: WATER)







(EtFOSAA)

---- <0.02 <0.10 ----µg/L0.022991-50-6



(4:2 FTS)

<0.001 ---- ---- <0.001µg/L0.001757124-72-4


(4:2 FTS)

---- <0.05 <0.10 ----µg/L0.05757124-72-4


(6:2 FTS)

<0.001 ---- ---- <0.001µg/L0.00127619-97-2


(6:2 FTS)

---- <0.05 <0.10 ----µg/L0.0527619-97-2


(8:2 FTS)

<0.001 ---- ---- <0.001µg/L0.00139108-34-4


(8:2 FTS)

---- <0.05 <0.10 ----µg/L0.0539108-34-4


(10:2 FTS)

<0.001 ---- ---- <0.001µg/L0.001120226-60-0


(10:2 FTS)

---- <0.05 <0.10 ----µg/L0.05120226-60-0

EP231P: PFAS Sums

0.0005 0.0033 ---- ---- <0.0003µg/L0.0003----Sum of PFAS

---- ---- 7.32 0.60 ----µg/L0.01----Sum of PFAS

0.0005Sum of PFHxS and PFOS 0.0025 ---- ---- <0.0003µg/L0.0003355-46-4/1763-23-

1

----Sum of PFHxS and PFOS ---- <0.01 0.50 ----µg/L0.01355-46-4/1763-23-

1

0.0005 0.0033 ---- ---- <0.0003µg/L0.0003----Sum of PFAS (WA DER List)

---- ---- 7.26 0.60 ----µg/L0.01----Sum of PFAS (WA DER List)


81.8 90.6 ---- ---- 80.8%0.0005----13C4-PFOS

---- ---- 94.1 104 ----%0.02----13C4-PFOS

93.0 103 ---- ---- 104%0.0005----13C8-PFOA

---- ---- 91.9 98.3 ----%0.02----13C8-PFOA

19 of 25:Page

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:Client

ET1801082



Analytical Results

0874_SW112_1804190874_SW014_1804190874_SW131_1804190874_QC5SW_1804180874_QC4SW_180418Client sample IDSub-Matrix: WATER

(Matrix: WATER)





---- ---- 6.54 7.39 7.64pH Unit0.01----pH Value


----^ ---- 4.88 8.14 7.22-0.01----Sodium Adsorption Ratio


---- ---- 703 1960 1300µS/cm1----Electrical Conductivity @ 25°C


---- ---- 417 1140 732mg/L10----Total Dissolved Solids @180°C


---- ---- 457 1270 845mg/L1----Total Dissolved Solids (Calc.)


---- ---- <5 <5 <5mg/L5----Suspended Solids (SS)

EA045: Turbidity

---- ---- 1.8 2.0 2.4NTU0.1----Turbidity


---- ---- 91 267 154mg/L1----Total Hardness as CaCO3


----Hydroxide Alkalinity as CaCO3 ---- <1 <1 <1mg/L1DMO-210-001

----Carbonate Alkalinity as CaCO3 ---- <1 <1 <1mg/L13812-32-6

----Bicarbonate Alkalinity as CaCO3 ---- 57 181 123mg/L171-52-3

---- ---- 57 181 123mg/L1----Total Alkalinity as CaCO3


----Sulfate as SO4 - Turbidimetric ---- 3 22 60mg/L114808-79-8


----Chloride ---- 186 526 308mg/L116887-00-6


----Calcium ---- 15 56 32mg/L17440-70-2

----Magnesium ---- 13 31 18mg/L17439-95-4

----Sodium ---- 107 306 206mg/L17440-23-5

----Potassium ---- 2 2 17mg/L17440-09-7


----Aluminium ---- <0.01 <0.01 0.02mg/L0.017429-90-5

----Manganese ---- 0.240 0.124 0.064mg/L0.0017439-96-5

----Iron ---- 0.69 <0.05 <0.05mg/L0.057439-89-6

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:Client

ET1801082



Analytical Results


(Matrix: WATER)





---- ---- 0.69 <0.05 <0.05mg/L0.05----Ferrous Iron


----Fluoride ---- <0.1 0.2 0.6mg/L0.116984-48-8


----Ammonia as N ---- 0.01 0.01 0.08mg/L0.017664-41-7


----Nitrite as N ---- <0.01 <0.01 0.02mg/L0.0114797-65-0


----Nitrate as N ---- <0.01 <0.01 2.29mg/L0.0114797-55-8


---- ---- <0.01 <0.01 2.31mg/L0.01----Nitrite + Nitrate as N


---- ---- 0.7 0.4 1.1mg/L0.1----Total Kjeldahl Nitrogen as N


----^ ---- 0.7 0.4 3.4mg/L0.1----Total Nitrogen as N


---- ---- 0.02 0.08 0.15mg/L0.01----Total Phosphorus as P


----Reactive Phosphorus as P ---- <0.01 0.06 0.10mg/L0.0114265-44-2


---- ---- 6.45 18.9 12.4meq/L0.01----Total Anions

---- ---- 6.52 18.7 12.5meq/L0.01----Total Cations

---- ---- 0.58 0.54 0.32%0.01----Ionic Balance


---- ---- 11 6 6mg/L1----Total Organic Carbon


---- ---- 30 20 18mg/L10----Chemical Oxygen Demand


---- ---- 7 <2 <2mg/L2----Biochemical Oxygen Demand



(PFBS)

<0.0005 0.219 0.0230 0.0311µg/L0.0005375-73-5

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:Client

ET1801082



Analytical Results


(Matrix: WATER)






(PFPeS)

<0.0005 0.234 0.0041 0.0146µg/L0.00052706-91-4


(PFHxS)

<0.0005 2.28 0.0340 0.136µg/L0.0005355-46-4


(PFHpS)

<0.0005 0.149 0.0019 0.0063µg/L0.0005375-92-8


(PFOS)

<0.0003 2.71 0.0310 0.166µg/L0.00031763-23-1


(PFDS)

<0.0005 0.0068 <0.0005 <0.0005µg/L0.0005335-77-3


<0.002Perfluorobutanoic acid (PFBA) 0.003 0.017 0.006 <0.002µg/L0.002375-22-4





<0.0005Perfluorononanoic acid (PFNA) <0.0005 0.0028 0.0006 0.0014µg/L0.0005375-95-1

<0.0005Perfluorodecanoic acid (PFDA) <0.0005 0.0010 0.0007 0.0034µg/L0.0005335-76-2


(PFUnDA)

<0.0005 <0.0005 <0.0005 <0.0005µg/L0.00052058-94-8


(PFDoDA)

<0.0005 <0.0005 <0.0005 <0.0005µg/L0.0005307-55-1


(PFTrDA)

<0.0005 <0.0005 <0.0005 <0.0005µg/L0.000572629-94-8


(PFTeDA)

<0.0005 <0.0005 <0.0005 <0.0005µg/L0.0005376-06-7



(FOSA)

<0.0005 0.0022 <0.0005 0.0005µg/L0.0005754-91-6



<0.001 <0.001 <0.001 <0.001µg/L0.00131506-32-8



<0.001 <0.001 <0.001 <0.001µg/L0.0014151-50-2



<0.001 <0.001 <0.001 <0.001µg/L0.00124448-09-7

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Analytical Results


(Matrix: WATER)







<0.001 <0.001 <0.001 <0.001µg/L0.0011691-99-2



(MeFOSAA)

<0.0005 <0.0005 <0.0005 <0.0005µg/L0.00052355-31-9



(EtFOSAA)

<0.0005 <0.0005 <0.0005 <0.0005µg/L0.00052991-50-6



(4:2 FTS)

<0.001 <0.001 <0.001 <0.001µg/L0.001757124-72-4


(6:2 FTS)

<0.001 0.014 <0.001 0.004µg/L0.00127619-97-2


(8:2 FTS)

<0.001 <0.001 <0.001 <0.001µg/L0.00139108-34-4


(10:2 FTS)

<0.001 <0.001 <0.001 <0.001µg/L0.001120226-60-0

EP231P: PFAS Sums

<0.0003 0.0030 6.70 0.131 0.504µg/L0.0003----Sum of PFAS


1

<0.0003 0.0030 6.30 0.124 0.478µg/L0.0003----Sum of PFAS (WA DER List)


79.2 81.8 85.5 88.1 97.5%0.0005----13C4-PFOS

98.7 101 91.7 91.7 94.7%0.0005----13C8-PFOA

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Analytical Results

--------0874_SW112_180419

_F

0874_SW014_180419

_F

0874_SW131_180419

_F


(Matrix: WATER)






(PFBS)

0.0021 0.0053 ---- ----µg/L0.0005375-73-5


(PFPeS)

<0.0005 <0.0005 ---- ----µg/L0.00052706-91-4


(PFHxS)

<0.0005 <0.0005 ---- ----µg/L0.0005355-46-4


(PFHpS)

<0.0005 <0.0005 ---- ----µg/L0.0005375-92-8


(PFOS)

<0.0003 <0.0003 ---- ----µg/L0.00031763-23-1


(PFDS)

<0.0005 <0.0005 ---- ----µg/L0.0005335-77-3


0.023Perfluorobutanoic acid (PFBA) <0.002 <0.002 ---- ----µg/L0.002375-22-4

0.128Perfluoropentanoic acid (PFPeA) 0.0085 0.0360 ---- ----µg/L0.00052706-90-3

0.752Perfluorohexanoic acid (PFHxA) 0.0097 0.0505 ---- ----µg/L0.0005307-24-4

0.0611Perfluoroheptanoic acid (PFHpA) 0.0020 0.0061 ---- ----µg/L0.0005375-85-9

0.0770Perfluorooctanoic acid (PFOA) 0.0018 0.0087 ---- ----µg/L0.0005335-67-1




(PFUnDA)

<0.0005 <0.0005 ---- ----µg/L0.00052058-94-8


(PFDoDA)

<0.0005 <0.0005 ---- ----µg/L0.0005307-55-1


(PFTrDA)

<0.0005 <0.0005 ---- ----µg/L0.000572629-94-8


(PFTeDA)

<0.0005 <0.0005 ---- ----µg/L0.0005376-06-7



(FOSA)

<0.0005 <0.0005 ---- ----µg/L0.0005754-91-6



<0.001 <0.001 ---- ----µg/L0.00131506-32-8



<0.001 <0.001 ---- ----µg/L0.0014151-50-2

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Analytical Results

--------0874_SW112_180419

_F

0874_SW014_180419

_F

0874_SW131_180419

_F


(Matrix: WATER)







<0.001 <0.001 ---- ----µg/L0.00124448-09-7



<0.001 <0.001 ---- ----µg/L0.0011691-99-2



(MeFOSAA)

<0.0005 <0.0005 ---- ----µg/L0.00052355-31-9



(EtFOSAA)

<0.0005 <0.0005 ---- ----µg/L0.00052991-50-6



(4:2 FTS)

<0.001 <0.001 ---- ----µg/L0.001757124-72-4


(6:2 FTS)

<0.001 <0.001 ---- ----µg/L0.00127619-97-2


(8:2 FTS)

<0.001 <0.001 ---- ----µg/L0.00139108-34-4


(10:2 FTS)

<0.001 <0.001 ---- ----µg/L0.001120226-60-0

EP231P: PFAS Sums

1.16 0.0241 0.107 ---- ----µg/L0.0003----Sum of PFAS

0.0010Sum of PFHxS and PFOS <0.0003 <0.0003 ---- ----µg/L0.0003355-46-4/1763-23-

1

1.16 0.0241 0.107 ---- ----µg/L0.0003----Sum of PFAS (WA DER List)


93.6 96.1 64.5 ---- ----%0.0005----13C4-PFOS

96.2 94.5 96.4 ---- ----%0.0005----13C8-PFOA

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13C4-PFOS ---- 60 130

13C8-PFOA ---- 60 130


13C4-PFOS ---- 60 120

13C8-PFOA ---- 60 120

False

6 6.00False

Environmental




:Address MOBIL

C/O GPO BOX 2907








Site : ----


















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General Comments










Key :









EA005-P: pH Value ---- 0.01 pH Unit 7.71 7.84 1.67 0% - 20%0874_SW123_180418 ET1801082-009



EA010-P: Electrical Conductivity @ 25°C ---- 1 µS/cm 1020 1020 0.196 0% - 20%0874_SW123_180418 ET1801082-009





EA025H: Suspended Solids (SS) ---- 5 mg/L 14 15 8.70 No Limit0874_SW123_180418 ET1801082-009



EA045: Turbidity ---- 0.1 NTU 5.3 5.3 0.00 0% - 20%0874_SW123_180418 ET1801082-009

EA045: Turbidity ---- 0.1 NTU 226 230 1.75 0% - 20%Anonymous ET1801086-022











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ED037-P: Bicarbonate Alkalinity as CaCO3 71-52-3 1 mg/L <1 <1 0.00 No Limit

ED037-P: Total Alkalinity as CaCO3 ---- 1 mg/L <1 <1 0.00 No Limit


















ED041G: Sulfate as SO4 - Turbidimetric 14808-79-8 1 mg/L 2 2 0.00 No Limit0874_QC1SW_180418_01 ET1801082-001






ED045G: Chloride 16887-00-6 1 mg/L 199 199 0.00 0% - 20%0874_QC1SW_180418_01 ET1801082-001



ED093F: Calcium 7440-70-2 1 mg/L 26 26 0.00 0% - 20%0874_QC1SW_180418_01 ET1801082-001


ED093F: Sodium 7440-23-5 1 mg/L 123 122 0.00 0% - 20%




ED093F: Sodium 7440-23-5 1 mg/L 121 122 1.24 0% - 20%



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EG020F: Dissolved Metals by ICP-MS (QC Lot: 1585941) - continued


EG020A-F: Aluminium 7429-90-5 0.01 mg/L 0.03 <0.01 108 No Limit






EG051G: Ferrous Iron ---- 0.05 mg/L 0.20 0.21 0.00 No LimitAnonymous ET1801057-001




EK040P: Fluoride 16984-48-8 0.1 mg/L 0.1 <0.1 0.00 No Limit0874_SW123_180418 ET1801082-009


EK055G: Ammonia as N 7664-41-7 0.01 mg/L 0.05 <0.01 132 No LimitAnonymous ET1801078-011

EK055G: Ammonia as N 7664-41-7 0.01 mg/L 0.02 <0.01 0.00 No LimitAnonymous ET1801085-001



EK057G: Nitrite as N 14797-65-0 0.01 mg/L <0.01 <0.01 0.00 No Limit0874_SW123_180418 ET1801082-009





EK061G: Total Kjeldahl Nitrogen as N ---- 0.1 mg/L 0.7 0.7 0.00 No Limit0874_SW123_180418 ET1801082-009

EK061G: Total Kjeldahl Nitrogen as N ---- 0.1 mg/L 2.0 1.7 15.7 No LimitAnonymous ET1801086-025


EK067G: Total Phosphorus as P ---- 0.01 mg/L 0.04 0.04 0.00 No Limit0874_SW123_180418 ET1801082-009

EK067G: Total Phosphorus as P ---- 0.01 mg/L 0.43 0.48 11.2 No LimitAnonymous ET1801086-025


EK071G: Reactive Phosphorus as P 14265-44-2 0.01 mg/L 0.12 0.12 0.00 0% - 50%Anonymous ET1801086-023

EK071G: Reactive Phosphorus as P 14265-44-2 0.01 mg/L <0.01 <0.01 0.00 No Limit0874_SW123_180418 ET1801082-009









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EP030: Biochemical Oxygen Demand (BOD) (QC Lot: 1585278) - continued


EP030: Biochemical Oxygen Demand ---- 2 mg/L 12 10 23.2 No LimitAnonymous EB1809814-001


EP030: Biochemical Oxygen Demand ---- 2 mg/L <2 3 0.00 No Limit0874_SW112_180419 ET1801082-020
























2355-31-9 0.02 µg/L <0.02 <0.02 0.00 No Limit



2991-50-6 0.02 µg/L <0.02 <0.02 0.00 No Limit


(MeFOSA)

31506-32-8 0.05 µg/L <0.05 <0.05 0.00 No Limit


(EtFOSA)

4151-50-2 0.05 µg/L <0.05 <0.05 0.00 No Limit



24448-09-7 0.05 µg/L <0.05 <0.05 0.00 No Limit



1691-99-2 0.05 µg/L <0.05 <0.05 0.00 No Limit



FTS)


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EP231_TOP_D: (n:2) Fluorotelomer Sulfonic Acids (QC Lot: 1586695) - continued


FTS)



FTS)

39108-34-4 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

120226-60-0 0.05 µg/L <0.05 <0.05 0.00 No Limit




23-1

0.01 µg/L <0.01 <0.01 0.00 No Limit


C4 - C8 Sulfonates

---- 0.01 µg/L <0.01 <0.01 0.00 No Limit



(PFOS)

1763-23-1 0.0003 µg/L 0.202 0.247 20.0 0% - 20%0874_QC1SW_180418_01 ET1801082-001


(PFBS)

375-73-5 0.0005 µg/L 0.0615 0.0691 11.7 0% - 20%


(PFPeS)

2706-91-4 0.0005 µg/L 0.0436 0.0516 16.8 0% - 20%


(PFHxS)

355-46-4 0.0005 µg/L 0.279 0.320 13.4 0% - 20%


(PFHpS)

375-92-8 0.0005 µg/L 0.0136 0.0146 6.80 0% - 20%


(PFDS)

335-77-3 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFOS)

1763-23-1 0.0003 µg/L <0.0003 <0.0003 0.00 No Limit0874_QC5SW_180418 ET1801082-017


(PFBS)

375-73-5 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFPeS)

2706-91-4 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFHxS)

355-46-4 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFHpS)

375-92-8 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


(PFDS)

335-77-3 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


EP231X: Perfluorooctane sulfonic acid (PFOS) 1763-23-1 0.01 µg/L 3.15 2.88 9.12 0% - 20%Anonymous EB1809957-013



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EP231X: Perfluorohexane sulfonic acid (PFHxS) 355-46-4 0.02 µg/L 3.13 3.04 2.95 0% - 20%Anonymous EB1809957-013










EP231X-ST: Perfluoropentanoic acid (PFPeA) 2706-90-3 0.0005 µg/L 0.0218 0.0225 3.16 0% - 20%0874_QC1SW_180418_01 ET1801082-001





EP231X-ST: Perfluorodecanoic acid (PFDA) 335-76-2 0.0005 µg/L 0.0005 0.0005 0.00 No Limit





(PFTeDA)

376-06-7 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit


EP231X-ST: Perfluoropentanoic acid (PFPeA) 2706-90-3 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit0874_QC5SW_180418 ET1801082-017










(PFTeDA)

376-06-7 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit

EP231X-ST: Perfluorobutanoic acid (PFBA) 375-22-4 0.002 µg/L 0.003 0.002 0.00 No Limit


EP231X: Perfluorooctanoic acid (PFOA) 335-67-1 0.01 µg/L 0.18 0.16 7.10 0% - 50%Anonymous EB1809957-013





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EP231X: Perfluorodecanoic acid (PFDA) 335-76-2 0.02 µg/L <0.02 <0.02 0.00 No LimitAnonymous EB1809957-013



















(FOSA)

754-91-6 0.0005 µg/L 0.0006 0.0006 0.00 No Limit0874_QC1SW_180418_01 ET1801082-001



2355-31-9 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit



2991-50-6 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit



31506-32-8 0.001 µg/L <0.001 <0.001 0.00 No Limit


(EtFOSA)

4151-50-2 0.001 µg/L <0.001 <0.001 0.00 No Limit



24448-09-7 0.001 µg/L <0.001 <0.001 0.00 No Limit



1691-99-2 0.001 µg/L <0.001 <0.001 0.00 No Limit


(FOSA)




2355-31-9 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit



2991-50-6 0.0005 µg/L <0.0005 <0.0005 0.00 No Limit



31506-32-8 0.001 µg/L <0.001 <0.001 0.00 No Limit

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(EtFOSA)




24448-09-7 0.001 µg/L <0.001 <0.001 0.00 No Limit



1691-99-2 0.001 µg/L <0.001 <0.001 0.00 No Limit





2355-31-9 0.02 µg/L <0.02 <0.02 0.00 No Limit



2991-50-6 0.02 µg/L <0.02 <0.02 0.00 No Limit


(MeFOSA)

31506-32-8 0.05 µg/L <0.05 <0.05 0.00 No Limit


(EtFOSA)

4151-50-2 0.05 µg/L <0.05 <0.05 0.00 No Limit



24448-09-7 0.05 µg/L <0.05 <0.05 0.00 No Limit



1691-99-2 0.05 µg/L <0.05 <0.05 0.00 No Limit

EP231X: Perfluorooctane sulfonamide (FOSA) 754-91-6 0.02 µg/L 0.04 0.04 0.00 No Limit0874_SW123_180418 ET1801082-009



2355-31-9 0.02 µg/L <0.02 <0.02 0.00 No Limit



2991-50-6 0.02 µg/L <0.02 <0.02 0.00 No Limit


(MeFOSA)

31506-32-8 0.05 µg/L <0.05 <0.05 0.00 No Limit


(EtFOSA)

4151-50-2 0.05 µg/L <0.05 <0.05 0.00 No Limit



24448-09-7 0.05 µg/L <0.05 <0.05 0.00 No Limit



1691-99-2 0.05 µg/L <0.05 <0.05 0.00 No Limit



FTS)

757124-72-4 0.001 µg/L <0.001 <0.001 0.00 No Limit0874_QC1SW_180418_01 ET1801082-001


FTS)

27619-97-2 0.001 µg/L 0.002 0.002 0.00 No Limit


FTS)

39108-34-4 0.001 µg/L <0.001 <0.001 0.00 No Limit

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(10:2 FTS)

120226-60-0 0.001 µg/L <0.001 <0.001 0.00 No Limit0874_QC1SW_180418_01 ET1801082-001


FTS)



FTS)

27619-97-2 0.001 µg/L <0.001 <0.001 0.00 No Limit


FTS)

39108-34-4 0.001 µg/L <0.001 <0.001 0.00 No Limit


(10:2 FTS)

120226-60-0 0.001 µg/L <0.001 <0.001 0.00 No Limit



FTS)



FTS)

27619-97-2 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

39108-34-4 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

120226-60-0 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

757124-72-4 0.05 µg/L <0.05 <0.05 0.00 No Limit0874_SW123_180418 ET1801082-009


FTS)

27619-97-2 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

39108-34-4 0.05 µg/L <0.05 <0.05 0.00 No Limit


FTS)

120226-60-0 0.05 µg/L <0.05 <0.05 0.00 No Limit


EP231X-ST: Sum of PFAS ---- 0.0003 µg/L 0.773 0.884 13.3 0% - 20%0874_QC1SW_180418_01 ET1801082-001

EP231X-ST: Sum of PFAS ---- 0.0003 µg/L 0.0030 0.0020 40.0 0% - 50%0874_QC5SW_180418 ET1801082-017


EP231X: Sum of PFAS ---- 0.01 µg/L 8.85 8.29 6.53 0% - 20%Anonymous EB1809957-013


23-1

0.01 µg/L 6.28 5.92 5.90 0% - 20%




23-1

0.01 µg/L 42.5 41.9 1.42 0% - 20%


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Report






---- 99.37 pH Unit 10298



<1 99.112890 µS/cm 10791



<10 99.82000 mg/L 11288



<5 97.01000 mg/L 12083



<0.1 10240 NTU 10595

<0.1 101400 NTU 10397









<1 11625 mg/L 12080



<1 10325 mg/L 12080



<1 10010 mg/L 12080



<1 10710 mg/L 12080

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Report





ED093F: Calcium 7440-70-2 1 mg/L <1 -------- --------


ED093F: Sodium 7440-23-5 1 mg/L <1 -------- --------





EG020A-F: Iron 7439-89-6 0.05 mg/L <0.05 1020.5 mg/L 11482




EK040P: Fluoride 16984-48-8 0.1 mg/L <0.1 1015 mg/L 12080















<1 96.2100 mg/L 11379


EP026SP: Chemical Oxygen Demand ---- 10 mg/L <10 96.550 mg/L 11286

<10 95.2500 mg/L 11286


EP030: Biochemical Oxygen Demand ---- 2 mg/L <2 106198 mg/L 11577





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Report




























(MeFOSE)

24448-09-7 0.05 µg/L <0.05 -------- --------


(EtFOSE)

1691-99-2 0.05 µg/L <0.05 -------- --------


(MeFOSAA)

2355-31-9 0.02 µg/L <0.02 -------- --------


(EtFOSAA)

2991-50-6 0.02 µg/L <0.02 -------- --------









63-23-1

0.01 µg/L <0.01 -------- --------

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Report






Sulfonates

---- 0.01 µg/L <0.01 -------- --------














EP231X: Perfluorodecane sulfonic acid (PFDS) 335-77-3 0.02 µg/L <0.02 90.20.5 µg/L 13070























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Report










(MeFOSA)

31506-32-8 0.001 µg/L <0.001 50.40.025 µg/L 13040



(MeFOSE)

24448-09-7 0.001 µg/L <0.001 52.70.025 µg/L 13040


(EtFOSE)

1691-99-2 0.001 µg/L <0.001 50.30.025 µg/L 13040


acid (MeFOSAA)

2355-31-9 0.0005 µg/L <0.0005 43.80.01 µg/L 13040


acid (EtFOSAA)

2991-50-6 0.0005 µg/L <0.0005 46.60.01 µg/L 13040






(MeFOSE)

24448-09-7 0.05 µg/L <0.05 82.51.25 µg/L 13070


(EtFOSE)

1691-99-2 0.05 µg/L <0.05 84.61.25 µg/L 13070


(MeFOSAA)

2355-31-9 0.02 µg/L <0.02 96.40.5 µg/L 13070


(EtFOSAA)

2991-50-6 0.02 µg/L <0.02 84.00.5 µg/L 13070













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Report







63-23-1

0.01 µg/L <0.01 -------- --------








0874_SW131_180419 ET1801082-018 14808-79-8ED041G: Sulfate as SO4 - Turbidimetric 12620 mg/L 13070


0874_SW205_180418 ET1801082-002 14808-79-8ED041G: Sulfate as SO4 - Turbidimetric # Not

Determined

20 mg/L 13070




0874_SW205_180418 ET1801082-002 16887-00-6ED045G: Chloride # Not

Determined

400 mg/L 13070





Anonymous ET1801057-003 ----EG051G: Ferrous Iron 1002 mg/L 13070


0874_SW131_180419 ET1801082-018 16984-48-8EK040P: Fluoride 1061.92 mg/L 12080




0874_SW131_180419 ET1801082-018 14797-65-0EK057G: Nitrite as N 1010.4 mg/L 13070



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0874_SW131_180419 ET1801082-018 ----EK061G: Total Kjeldahl Nitrogen as N 1025 mg/L 13070


0874_SW131_180419 ET1801082-018 ----EK067G: Total Phosphorus as P 95.11 mg/L 13070


0874_SW131_180419 ET1801082-018 14265-44-2EK071G: Reactive Phosphorus as P 1010.4 mg/L 13070


0874_SW123_180418 ET1801082-009 ----EP005: Total Organic Carbon 94.4100 mg/L 13070





Determined

0.01 µg/L 13050







Anonymous EB1809957-014 375-73-5EP231X: Perfluorobutane sulfonic acid (PFBS) 1090.5 µg/L 13070



Determined

0.5 µg/L 13070



Determined

0.5 µg/L 13070



0874_SW203_180418 ET1801082-005 375-22-4EP231X-ST: Perfluorobutanoic acid (PFBA) 38.20.05 µg/L 13030










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0874_SW203_180418 ET1801082-005 376-06-7EP231X-ST: Perfluorotetradecanoic acid (PFTeDA) 66.70.025 µg/L 13030
















(MeFOSA)

47.70.025 µg/L 13030


(EtFOSA)

39.20.025 µg/L 13030



47.50.025 µg/L 13030



48.50.025 µg/L 13030



55.20.01 µg/L 13030


acid (EtFOSAA)

62.20.01 µg/L 13030


Anonymous EB1809957-014 754-91-6EP231X: Perfluorooctane sulfonamide (FOSA) 84.20.5 µg/L 13070


(MeFOSA)

86.61.25 µg/L 13070



(MeFOSE)

99.01.25 µg/L 13070


(EtFOSE)

88.41.25 µg/L 13070


acid (MeFOSAA)

1060.5 µg/L 13070

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Anonymous EB1809957-014 2991-50-6EP231X: N-Ethyl perfluorooctane sulfonamidoacetic

acid (EtFOSAA)

93.80.5 µg/L 13070


0874_SW203_180418 ET1801082-005 757124-72-4EP231X-ST: 4:2 Fluorotelomer sulfonic acid (4:2 FTS) 1090.01 µg/L 13050









True

Environmental












Summary of Outliers













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Matrix: WATER



ET1801082--002 14808-79-8Sulfate as SO4 -

Turbidimetric




----Not

Determined


ET1801082--002 16887-00-6Chloride0874_SW205_180418 MS recovery not determined,



----Not

Determined


EB1809957--014 355-46-4Perfluorohexane

sulfonic acid

(PFHxS)




----Not

Determined


EB1809957--014 1763-23-1Perfluorooctane





----Not

Determined



Matrix: WATER



overdue

Days

overdue


Method



18-Apr-2018----0874_SW123_180418 19-Apr-2018---- ---- 1














0874_SW123_180418 18-Apr-2018---- 19-Apr-2018----18-Apr-2018 ---- ûClear Plastic Bottle - Natural (EA005-P)

0874_SW131_180419, 0874_SW014_180419,

0874_SW112_180419

19-Apr-2018---- 19-Apr-2018----19-Apr-2018 ---- ü

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0874_SW123_180418 16-May-2018---- 24-Apr-2018----18-Apr-2018 ---- üClear Plastic Bottle - Filtered; Lab-acidified (ED093F)

0874_SW131_180419, 0874_SW014_180419,

0874_SW112_180419

17-May-2018---- 24-Apr-2018----19-Apr-2018 ---- ü



0874_SW123_180418 16-May-2018---- 19-Apr-2018----18-Apr-2018 ---- üClear Plastic Bottle - Natural (EA010-P)

0874_SW131_180419, 0874_SW014_180419,

0874_SW112_180419

17-May-2018---- 19-Apr-2018----19-Apr-2018 ---- ü



0874_SW123_180418 25-Apr-2018---- 20-Apr-2018----18-Apr-2018 ---- üClear Plastic Bottle - Natural (EA015H)

0874_SW131_180419, 0874_SW014_180419,

0874_SW112_180419

26-Apr-2018---- 20-Apr-2018----19-Apr-2018 ---- ü



0874_SW123_180418 25-Apr-2018---- 20-Apr-2018----18-Apr-2018 ---- üClear Plastic Bottle - Natural (EA025H)

0874_SW131_180419, 0874_SW014_180419,

0874_SW112_180419

26-Apr-2018---- 20-Apr-2018----19-Apr-2018 ---- ü

EA045: Turbidity


0874_SW123_180418 20-Apr-2018---- 19-Apr-2018----18-Apr-2018 ---- üClear Plastic Bottle - Natural (EA045)

0874_SW131_180419, 0874_SW014_180419,

0874_SW112_180419

21-Apr-2018---- 19-Apr-2018----19-Apr-2018 ---- ü




0874_SW131_180419, 0874_SW014_180419,

0874_SW112_180419

17-May-2018---- 24-Apr-2018----19-Apr-2018 ---- ü

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0874_QC1SW_180418_01, 0874_SW205_180418,

0874_SW206_180418, 0874_SW207_180418,

0874_SW203_180418, 0874_SW202_180418,

0874_SW204_180418, 0874_SW212_180418,

0874_SW123_180418, 0874_SW015_180418,

0874_SW211_180418, 0874_SW213_180418,

0874_QC1SW_180418_02, 0874_QC3SW_180418

02-May-2018---- 19-Apr-2018----18-Apr-2018 ---- ü


0874_SW131_180419, 0874_SW014_180419,

0874_SW112_180419

03-May-2018---- 19-Apr-2018----19-Apr-2018 ---- ü



0874_SW123_180418 16-May-2018---- 19-Apr-2018----18-Apr-2018 ---- üClear Plastic Bottle - Natural (ED041G)

0874_QC1SW_180418_01, 0874_SW205_180418,

0874_SW206_180418, 0874_SW207_180418,

0874_SW203_180418, 0874_SW202_180418,

0874_SW204_180418, 0874_SW212_180418,

0874_SW015_180418, 0874_SW211_180418,

0874_SW213_180418, 0874_QC1SW_180418_02,

0874_QC3SW_180418

16-May-2018---- 20-Apr-2018----18-Apr-2018 ---- ü


0874_SW131_180419, 0874_SW014_180419,

0874_SW112_180419

17-May-2018---- 19-Apr-2018----19-Apr-2018 ---- ü



0874_SW123_180418 16-May-2018---- 19-Apr-2018----18-Apr-2018 ---- üClear Plastic Bottle - Natural (ED045G)

0874_QC1SW_180418_01, 0874_SW205_180418,

0874_SW206_180418, 0874_SW207_180418,

0874_SW203_180418, 0874_SW202_180418,

0874_SW204_180418, 0874_SW212_180418,

0874_SW015_180418, 0874_SW211_180418,

0874_SW213_180418, 0874_QC1SW_180418_02,

0874_QC3SW_180418

16-May-2018---- 20-Apr-2018----18-Apr-2018 ---- ü


0874_SW131_180419, 0874_SW014_180419,

0874_SW112_180419

17-May-2018---- 19-Apr-2018----19-Apr-2018 ---- ü

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0874_SW131_180419, 0874_SW014_180419,

0874_SW112_180419

17-May-2018---- 24-Apr-2018----19-Apr-2018 ---- ü


0874_QC1SW_180418_01, 0874_SW205_180418,

0874_SW206_180418, 0874_SW207_180418,

0874_SW203_180418, 0874_SW202_180418,

0874_SW204_180418, 0874_SW212_180418,

0874_SW015_180418, 0874_SW211_180418,

0874_SW213_180418, 0874_QC1SW_180418_02,

0874_QC3SW_180418

25-Apr-2018---- 24-Apr-2018----18-Apr-2018 ---- ü



0874_SW123_180418 15-Oct-2018---- 24-Apr-2018----18-Apr-2018 ---- üClear Plastic Bottle - Filtered; Lab-acidified (EG020A-F)

0874_SW131_180419, 0874_SW014_180419,

0874_SW112_180419

16-Oct-2018---- 24-Apr-2018----19-Apr-2018 ---- ü



0874_SW123_180418 25-Apr-2018---- 23-Apr-2018----18-Apr-2018 ---- üClear Plastic Bottle - HCl - Filtered (EG051G)

0874_SW131_180419, 0874_SW014_180419,

0874_SW112_180419

26-Apr-2018---- 23-Apr-2018----19-Apr-2018 ---- ü



0874_SW123_180418 16-May-2018---- 19-Apr-2018----18-Apr-2018 ---- üClear Plastic Bottle - Natural (EK040P)

0874_SW131_180419, 0874_SW014_180419,

0874_SW112_180419

17-May-2018---- 19-Apr-2018----19-Apr-2018 ---- ü



0874_SW123_180418 16-May-2018---- 20-Apr-2018----18-Apr-2018 ---- üClear Plastic Bottle - Sulfuric Acid (EK055G)

0874_SW131_180419, 0874_SW014_180419,

0874_SW112_180419

17-May-2018---- 20-Apr-2018----19-Apr-2018 ---- ü

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0874_SW123_180418 20-Apr-2018---- 19-Apr-2018----18-Apr-2018 ---- üClear Plastic Bottle - Natural (EK057G)

0874_SW131_180419, 0874_SW014_180419,

0874_SW112_180419

21-Apr-2018---- 19-Apr-2018----19-Apr-2018 ---- ü



0874_SW123_180418 16-May-2018---- 20-Apr-2018----18-Apr-2018 ---- üClear Plastic Bottle - Sulfuric Acid (EK059G)

0874_SW131_180419, 0874_SW014_180419,

0874_SW112_180419

17-May-2018---- 20-Apr-2018----19-Apr-2018 ---- ü



0874_SW123_180418 16-May-201816-May-2018 27-Apr-201827-Apr-201818-Apr-2018 ü üClear Plastic Bottle - Sulfuric Acid (EK061G)

0874_SW131_180419, 0874_SW014_180419,

0874_SW112_180419




0874_SW123_180418 16-May-201816-May-2018 27-Apr-201827-Apr-201818-Apr-2018 ü üClear Plastic Bottle - Sulfuric Acid (EK067G)

0874_SW131_180419, 0874_SW014_180419,

0874_SW112_180419




0874_SW123_180418 20-Apr-2018---- 19-Apr-2018----18-Apr-2018 ---- üClear Plastic Bottle - Natural (EK071G)

0874_SW131_180419, 0874_SW014_180419,

0874_SW112_180419

21-Apr-2018---- 19-Apr-2018----19-Apr-2018 ---- ü



0874_SW123_180418 16-May-2018---- 23-Apr-2018----18-Apr-2018 ---- üAmber TOC Vial - Sulfuric Acid (EP005)

0874_SW131_180419, 0874_SW014_180419,

0874_SW112_180419

17-May-2018---- 23-Apr-2018----19-Apr-2018 ---- ü



0874_SW123_180418 16-May-2018---- 27-Apr-2018----18-Apr-2018 ---- üClear Plastic Bottle - Sulfuric Acid (EP026SP)

0874_SW131_180419, 0874_SW014_180419,

0874_SW112_180419

17-May-2018---- 27-Apr-2018----19-Apr-2018 ---- ü

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0874_SW123_180418 20-Apr-2018---- 20-Apr-2018----18-Apr-2018 ---- üClear Plastic Bottle - Natural (EP030)

0874_SW131_180419, 0874_SW014_180419,

0874_SW112_180419

21-Apr-2018---- 21-Apr-2018----19-Apr-2018 ---- ü



0874_SW123_180418 15-Oct-201815-Oct-2018 26-Apr-201823-Apr-201818-Apr-2018 ü üEP231_TOP_B: Perfluoroalkyl Carboxylic Acids


0874_SW123_180418 15-Oct-201815-Oct-2018 26-Apr-201823-Apr-201818-Apr-2018 ü üEP231_TOP_C: Perfluoroalkyl Sulfonamides


0874_SW123_180418 15-Oct-201815-Oct-2018 26-Apr-201823-Apr-201818-Apr-2018 ü üEP231_TOP_D: (n:2) Fluorotelomer Sulfonic Acids


0874_SW123_180418 15-Oct-201815-Oct-2018 26-Apr-201823-Apr-201818-Apr-2018 ü üEP231_TOP_P: PFAS Sums


0874_SW123_180418 15-Oct-201815-Oct-2018 26-Apr-201823-Apr-201818-Apr-2018 ü üEP231A: Perfluoroalkyl Sulfonic Acids


0874_SW205_180418, 0874_SW206_180418,

0874_SW207_180418, 0874_SW123_180418,

0874_SW123_180418_F, 0874_QC1SW_180418_02

15-Oct-2018---- 27-Apr-2018----18-Apr-2018 ---- ü


0874_QC1SW_180418_01, 0874_SW203_180418,

0874_SW202_180418, 0874_SW204_180418,

0874_SW212_180418, 0874_SW015_180418,

0874_SW211_180418, 0874_SW213_180418,

0874_QC3SW_180418, 0874_QC4SW_180418,

0874_QC5SW_180418



0874_SW131_180419, 0874_SW014_180419,

0874_SW112_180419, 0874_SW131_180419_F,

0874_SW014_180419_F, 0874_SW112_180419_F


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0874_SW205_180418, 0874_SW206_180418,

0874_SW207_180418, 0874_SW123_180418,

0874_SW123_180418_F, 0874_QC1SW_180418_02

15-Oct-2018---- 27-Apr-2018----18-Apr-2018 ---- ü


0874_QC1SW_180418_01, 0874_SW203_180418,

0874_SW202_180418, 0874_SW204_180418,

0874_SW212_180418, 0874_SW015_180418,

0874_SW211_180418, 0874_SW213_180418,

0874_QC3SW_180418, 0874_QC4SW_180418,

0874_QC5SW_180418



0874_SW131_180419, 0874_SW014_180419,

0874_SW112_180419, 0874_SW131_180419_F,

0874_SW014_180419_F, 0874_SW112_180419_F




0874_SW205_180418, 0874_SW206_180418,

0874_SW207_180418, 0874_SW123_180418,

0874_SW123_180418_F, 0874_QC1SW_180418_02

15-Oct-2018---- 27-Apr-2018----18-Apr-2018 ---- ü


0874_QC1SW_180418_01, 0874_SW203_180418,

0874_SW202_180418, 0874_SW204_180418,

0874_SW212_180418, 0874_SW015_180418,

0874_SW211_180418, 0874_SW213_180418,

0874_QC3SW_180418, 0874_QC4SW_180418,

0874_QC5SW_180418



0874_SW131_180419, 0874_SW014_180419,

0874_SW112_180419, 0874_SW131_180419_F,

0874_SW014_180419_F, 0874_SW112_180419_F


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0874_SW205_180418, 0874_SW206_180418,

0874_SW207_180418, 0874_SW123_180418,

0874_SW123_180418_F, 0874_QC1SW_180418_02

15-Oct-2018---- 27-Apr-2018----18-Apr-2018 ---- ü


0874_QC1SW_180418_01, 0874_SW203_180418,

0874_SW202_180418, 0874_SW204_180418,

0874_SW212_180418, 0874_SW015_180418,

0874_SW211_180418, 0874_SW213_180418,

0874_QC3SW_180418, 0874_QC4SW_180418,

0874_QC5SW_180418



0874_SW131_180419, 0874_SW014_180419,

0874_SW112_180419, 0874_SW131_180419_F,

0874_SW014_180419_F, 0874_SW112_180419_F


EP231P: PFAS Sums


0874_SW205_180418, 0874_SW206_180418,

0874_SW207_180418, 0874_SW123_180418,

0874_SW123_180418_F, 0874_QC1SW_180418_02

15-Oct-2018---- 27-Apr-2018----18-Apr-2018 ---- ü


0874_QC1SW_180418_01, 0874_SW203_180418,

0874_SW202_180418, 0874_SW204_180418,

0874_SW212_180418, 0874_SW015_180418,

0874_SW211_180418, 0874_SW213_180418,

0874_QC3SW_180418, 0874_QC4SW_180418,

0874_QC5SW_180418



0874_SW131_180419, 0874_SW014_180419,

0874_SW112_180419, 0874_SW131_180419_F,

0874_SW014_180419_F, 0874_SW112_180419_F


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Method Blanks (MB)























Matrix Spikes (MS)





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Schedule B(3)





Conductivity)

EA016 WATER









Schedule B(3)







Discrete Analyser

ED041G WATER











Schedule B(3)


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Schedule B(3)


Analyser

EK059G WATER





Analyser

EK061G WATER


B(3)


Discrete Analyser

EK062G WATER





Schedule B(3)


Analyser

EK067G WATER






Analyser

EK071G WATER


DA

EN055 - PG WATER




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EP026SP WATER






B(3)











(PFAS) by LCMSMS

EP231X WATER



















(PFAS) by LCMSMS

EP231X-ST WATER



Schedule B(3)



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pp. 9342¿9349:


EP231.


PFAS

* ORG70-W WATER

Environmental





C/O GPO BOX 2907



QLD AUSTRALIA 4814






V4)


Site : ----




Date

30-Apr-2018


No. of coolers/boxes : :5 Temperature 14, 16, 11.6, 4.7, 18.7°C -

Ice present


General Comments









l EP231X(TOP) and EP231X-ST conducted by ALS Sydney, NATA accreditation no. 825, site no 10911.












ET1801082-001 : [ 18-Apr-2018 ] : 0874_QC1SW_180418_01

ET1801082-014 : [ 18-Apr-2018 ] : 0874_QC1SW_180418_02











componentW

AT

ER

- E

G0

20F

Dis

solv

ed

Meta

ls b

y IC

P/M

S

WA

TE

R -

EP

026S

P

Ch

em

ica

l O

xyg

en D

em

and

(C

OD

)

WA

TE

R -

EP

030

BO

D

WA

TE

R -

EP

231X

PF

AS

- F

ull

Su

ite (

28 a

na

lyte

s)

WA

TE

R -

EP

231X

-ST

PF

AS

- S

up

er

Tra

ce W

ate

rs L

ong

Su

ite (

28

WA

TE

R -

NT

-01 &

02

Ca

, M

g, N

a, K

, C

l, S

O4

, A

lka

linity

WA

TE

R -

NT

-14

Ext

en

de

d W

ate

r S

uite

B

ET1801082-001 18-Apr-2018 00:00 0874_QC1SW_180418_01 ü ü

ET1801082-002 18-Apr-2018 00:00 0874_SW205_180418 ü ü

ET1801082-003 18-Apr-2018 00:00 0874_SW206_180418 ü ü

ET1801082-004 18-Apr-2018 00:00 0874_SW207_180418 ü ü

ET1801082-005 18-Apr-2018 00:00 0874_SW203_180418 ü ü

ET1801082-006 18-Apr-2018 00:00 0874_SW202_180418 ü ü

ET1801082-007 18-Apr-2018 00:00 0874_SW204_180418 ü ü

ET1801082-008 18-Apr-2018 00:00 0874_SW212_180418 ü ü

ET1801082-009 18-Apr-2018 00:00 0874_SW123_180418 ü ü ü ü ü ü

ET1801082-010 18-Apr-2018 00:00 0874_SW015_180418 ü ü

ET1801082-011 18-Apr-2018 00:00 0874_SW211_180418 ü ü

ET1801082-012 18-Apr-2018 00:00 0874_SW213_180418 ü ü

ET1801082-013 18-Apr-2018 00:00 0874_SW123_180418_F ü

ET1801082-014 18-Apr-2018 00:00 0874_QC1SW_180418_02 ü ü

ET1801082-015 18-Apr-2018 00:00 0874_QC3SW_180418 ü ü

ET1801082-016 18-Apr-2018 00:00 0874_QC4SW_180418 ü

ET1801082-017 18-Apr-2018 00:00 0874_QC5SW_180418 ü

ET1801082-018 19-Apr-2018 00:00 0874_SW131_180419 ü ü ü ü ü ü

ET1801082-019 19-Apr-2018 00:00 0874_SW014_180419 ü ü ü ü ü ü

ET1801082-020 19-Apr-2018 00:00 0874_SW112_180419 ü ü ü ü ü ü

ET1801082-021 19-Apr-2018 00:00 0874_SW131_180419_F ü

ET1801082-022 19-Apr-2018 00:00 0874_SW014_180419_F ü

ET1801082-023 19-Apr-2018 00:00 0874_SW112_180419_F ü

Matrix: WATER


ID

Client sampling

date / time




WA

TE

R -

EA

01

5H

Tota

l Dis

solv

ed

Solid

s -

Sta

nda

rd L

eve

l

WA

TE

R -

EA

02

5H

Susp

en

de

d S

olid

s -

Sta

nd

ard

Le

vel

WA

TE

R -

EA

04

5

Turb

idity

WA

TE

R -

EG

051G

Ferr

ou

s Ir

on

WA

TE

R -

EP

00

5

Tota

l Org

an

ic C

arb

on

(T

OC

)

WA

TE

R -

EP

23

1X

(T

OP

)

PF

AS

- T

ota

l Oxi

dis

able

Pre

curs

or

(TO

P)

Ass

ay

ET1801082-009 18-Apr-2018 00:00 0874_SW123_180418 ü ü ü ü ü ü

ET1801082-018 19-Apr-2018 00:00 0874_SW131_180419 ü ü ü ü ü

ET1801082-019 19-Apr-2018 00:00 0874_SW014_180419 ü ü ü ü ü

ET1801082-020 19-Apr-2018 00:00 0874_SW112_180419 ü ü ü ü ü

Matrix: WATER


ID

Client sampling

date / time






Due for

extraction

Due for

analysis Evaluation


Date Date

Method

Container




ACCOUNTS PAYABLE


AU ACCOUNTS PAYABLE


DAVID HARRIS








DERP LABREPORTS


PHIL SCHULZ









RESULTS RESULTS








0 0.00 True

Environmental





C/O GPO BOX 2907








Site : ----






l General Comments














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General Comments







purposes.







Key :

EG020-F (Dissolved Metals by ICP-MS): Limit of reporting raised due to matrix interference.l




23313)

l

EP231X(TOP) and EP231X-ST conducted by ALS Sydney, NATA accreditation no. 825, site no 10911.l



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Analytical Results

0874_MW224_S_1804

18

0874_MW009_S_1804

18

0874_MW125_D_1804

18

0874_MW002_S_1804

18

0874_MW246_S_1804

18


(Matrix: WATER)





---- ---- 7.18 ---- ----pH Unit0.01----pH Value


----^ ---- 43.5 ---- -----0.01----Sodium Adsorption Ratio


---- ---- 11700 ---- ----µS/cm1----Electrical Conductivity @ 25°C


---- ---- 7680 ---- ----mg/L10----Total Dissolved Solids @180°C


---- ---- 7600 ---- ----mg/L1----Total Dissolved Solids (Calc.)


---- ---- 65 ---- ----mg/L5----Suspended Solids (SS)

EA045: Turbidity

---- ---- 44.5 ---- ----NTU0.1----Turbidity


---- ---- 680 ---- ----mg/L1----Total Hardness as CaCO3







----Sulfate as SO4 - Turbidimetric 1890 645 568 75mg/L114808-79-8


----Chloride 5060 3570 5690 4800mg/L116887-00-6


----Calcium 308 53 263 301mg/L17440-70-2

----Magnesium 491 133 389 248mg/L17439-95-4

----Sodium 3040 2610 3180 2650mg/L17440-23-5

----Potassium 73 50 50 6mg/L17440-09-7


----Aluminium ---- <0.01 ---- ----mg/L0.017429-90-5

----Manganese ---- 0.002 ---- ----mg/L0.0017439-96-5

----Iron ---- <0.05 ---- ----mg/L0.057439-89-6

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Analytical Results

0874_MW224_S_1804

18

0874_MW009_S_1804

18

0874_MW125_D_1804

18

0874_MW002_S_1804

18

0874_MW246_S_1804

18


(Matrix: WATER)





---- ---- <0.05 ---- ----mg/L0.05----Ferrous Iron


----Fluoride ---- 0.3 ---- ----mg/L0.116984-48-8


----Ammonia as N ---- <0.01 ---- ----mg/L0.017664-41-7


----Nitrite as N ---- <0.01 ---- ----mg/L0.0114797-65-0


----Nitrate as N ---- 0.16 ---- ----mg/L0.0114797-55-8


---- ---- 0.16 ---- ----mg/L0.01----Nitrite + Nitrate as N


---- ---- 1.2 ---- ----mg/L0.1----Total Kjeldahl Nitrogen as N


----^ ---- 1.4 ---- ----mg/L0.1----Total Nitrogen as N


---- ---- 0.14 ---- ----mg/L0.01----Total Phosphorus as P


----Reactive Phosphorus as P ---- 0.11 ---- ----mg/L0.0114265-44-2


---- 186 127 178 144meq/L0.01----Total Anions

---- 190 128 185 151meq/L0.01----Total Cations

---- 1.10 0.66 1.90 2.25%0.01----Ionic Balance


---- ---- 22 ---- ----mg/L1----Total Organic Carbon


---- ---- <100 ---- ----mg/L10----Chemical Oxygen Demand


<2 ---- <2 ---- ----mg/L2----Biochemical Oxygen Demand



(PFBS)

0.68 32.0 0.70 0.18µg/L0.02375-73-5

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ET1801086



Analytical Results

0874_MW224_S_1804

18

0874_MW009_S_1804

18

0874_MW125_D_1804

18

0874_MW002_S_1804

18

0874_MW246_S_1804

18


(Matrix: WATER)






(PFPeS)

0.51 39.6 0.63 0.06µg/L0.022706-91-4


(PFHxS)

4.01 569 5.43 0.83µg/L0.02355-46-4


(PFHpS)

0.14 22.8 0.37 <0.05µg/L0.02375-92-8


(PFOS)

2.66 731 10.0 1.20µg/L0.011763-23-1


(PFDS)

<0.05 <0.02 <0.05 <0.05µg/L0.02335-77-3


----Perfluorobutanoic acid (PFBA) <0.2 6.7 <0.2 <0.2µg/L0.1375-22-4

----Perfluoropentanoic acid (PFPeA) 0.22 16.7 0.24 0.08µg/L0.022706-90-3

----Perfluorohexanoic acid (PFHxA) 1.12 134 1.36 0.12µg/L0.02307-24-4

----Perfluoroheptanoic acid (PFHpA) 0.10 8.88 0.18 <0.05µg/L0.02375-85-9

----Perfluorooctanoic acid (PFOA) 0.16 10.6 0.52 <0.05µg/L0.01335-67-1

----Perfluorononanoic acid (PFNA) <0.05 0.15 <0.05 0.10µg/L0.02375-95-1



(PFUnDA)

<0.05 <0.02 <0.05 <0.05µg/L0.022058-94-8


(PFDoDA)

<0.05 <0.02 <0.05 <0.05µg/L0.02307-55-1


(PFTrDA)

<0.05 <0.02 <0.05 <0.05µg/L0.0272629-94-8


(PFTeDA)

<0.12 <0.05 <0.12 <0.12µg/L0.05376-06-7



(FOSA)

<0.05 <0.02 0.14 <0.05µg/L0.02754-91-6



<0.12 <0.05 <0.12 <0.12µg/L0.0531506-32-8



<0.12 <0.05 <0.12 <0.12µg/L0.054151-50-2



<0.12 <0.05 <0.12 <0.12µg/L0.0524448-09-7

6 of 38:Page

Work Order :

:Client

ET1801086



Analytical Results

0874_MW224_S_1804

18

0874_MW009_S_1804

18

0874_MW125_D_1804

18

0874_MW002_S_1804

18

0874_MW246_S_1804

18


(Matrix: WATER)







<0.12 <0.05 <0.12 <0.12µg/L0.051691-99-2



(MeFOSAA)

<0.05 <0.02 <0.05 <0.05µg/L0.022355-31-9



(EtFOSAA)

<0.05 <0.02 <0.05 <0.05µg/L0.022991-50-6



(4:2 FTS)

<0.05 <0.05 <0.05 <0.05µg/L0.05757124-72-4


(6:2 FTS)

<0.05 <0.05 <0.05 0.13µg/L0.0527619-97-2


(8:2 FTS)

<0.05 <0.05 <0.05 <0.05µg/L0.0539108-34-4


(10:2 FTS)

<0.05 <0.05 <0.05 <0.05µg/L0.05120226-60-0

EP231P: PFAS Sums

---- 9.60 1570 19.6 2.70µg/L0.01----Sum of PFAS

----Sum of PFHxS and PFOS 6.67 1300 15.4 2.03µg/L0.01355-46-4/1763-23-

1

---- 8.95 1510 18.4 2.54µg/L0.01----Sum of PFAS (WA DER List)


---- 97.6 89.4 104 97.6%0.02----13C4-PFOS

---- 97.1 94.0 95.4 98.1%0.02----13C8-PFOA

7 of 38:Page

Work Order :

:Client

ET1801086



Analytical Results

0874_MW036_S_1804

18

0874_MW051_S_1804

18

0874_MW049_S_1804

18

0874_MW222_S_1804

18

0874_MW223_S_1804

18


(Matrix: WATER)












561Chloride 3760 396 212 23mg/L116887-00-6


38Calcium 202 20 8 3mg/L17440-70-2

22Magnesium 185 9 7 3mg/L17439-95-4

525Sodium 2300 398 338 188mg/L17440-23-5

<1Potassium 5 2 1 <1mg/L17440-09-7


24.0 120 17.6 14.6 7.82meq/L0.01----Total Anions

26.5 125 19.1 15.7 8.57meq/L0.01----Total Cations

5.00 2.24 3.98 3.63 4.60%0.01----Ionic Balance



(PFBS)

1.27 0.12 0.08 0.18µg/L0.02375-73-5


(PFPeS)

0.91 0.08 0.06 0.24µg/L0.022706-91-4


(PFHxS)

5.25 0.74 0.60 4.09µg/L0.02355-46-4


(PFHpS)

0.23 0.03 0.04 0.08µg/L0.02375-92-8


(PFOS)

2.26 1.56 0.79 1.44µg/L0.011763-23-1


(PFDS)

<0.02 <0.02 <0.02 <0.02µg/L0.02335-77-3


0.2Perfluorobutanoic acid (PFBA) 0.1 0.1 <0.1 0.2µg/L0.1375-22-4

0.27Perfluoropentanoic acid (PFPeA) 0.12 0.33 <0.02 0.31µg/L0.022706-90-3


8 of 38:Page

Work Order :

:Client

ET1801086



Analytical Results

0874_MW036_S_1804

18

0874_MW051_S_1804

18

0874_MW049_S_1804

18

0874_MW222_S_1804

18

0874_MW223_S_1804

18


(Matrix: WATER)





0.18Perfluoroheptanoic acid (PFHpA) 0.09 0.41 <0.02 0.21µg/L0.02375-85-9


<0.02Perfluorononanoic acid (PFNA) <0.02 0.38 <0.02 0.06µg/L0.02375-95-1

<0.02Perfluorodecanoic acid (PFDA) <0.02 0.62 <0.02 0.05µg/L0.02335-76-2


(PFUnDA)

<0.02 0.07 <0.02 <0.02µg/L0.022058-94-8


(PFDoDA)

<0.02 0.08 <0.02 <0.02µg/L0.02307-55-1


(PFTrDA)

<0.02 <0.02 <0.02 <0.02µg/L0.0272629-94-8


(PFTeDA)

<0.05 <0.05 <0.05 <0.05µg/L0.05376-06-7



(FOSA)

<0.02 <0.02 <0.02 <0.02µg/L0.02754-91-6



<0.05 <0.05 <0.05 <0.05µg/L0.0531506-32-8



<0.05 <0.05 <0.05 <0.05µg/L0.054151-50-2



<0.05 <0.05 <0.05 <0.05µg/L0.0524448-09-7



<0.05 <0.05 <0.05 <0.05µg/L0.051691-99-2



(MeFOSAA)

<0.02 <0.02 <0.02 <0.02µg/L0.022355-31-9



(EtFOSAA)

<0.02 <0.02 <0.02 <0.02µg/L0.022991-50-6



(4:2 FTS)

<0.05 <0.05 <0.05 <0.05µg/L0.05757124-72-4


(6:2 FTS)

<0.05 <0.05 <0.05 <0.05µg/L0.0527619-97-2


(8:2 FTS)

<0.05 <0.05 <0.05 <0.05µg/L0.0539108-34-4

9 of 38:Page

Work Order :

:Client

ET1801086



Analytical Results

0874_MW036_S_1804

18

0874_MW051_S_1804

18

0874_MW049_S_1804

18

0874_MW222_S_1804

18

0874_MW223_S_1804

18


(Matrix: WATER)






(10:2 FTS)

<0.05 <0.05 <0.05 <0.05µg/L0.05120226-60-0

EP231P: PFAS Sums

18.3 11.0 5.66 1.62 7.63µg/L0.01----Sum of PFAS


1



97.2 108 98.4 115 99.7%0.02----13C4-PFOS

98.7 92.8 100 98.0 93.5%0.02----13C8-PFOA

10 of 38:Page

Work Order :

:Client

ET1801086



Analytical Results

0874_QC1MW_18041

8_02

0874_QC1MW_18041

8_01

0874_MW125_D_1804

18_F

0874_MW231_S_1804

18

0874_MW229_S_1804

18


(Matrix: WATER)





<1Hydroxide Alkalinity as CaCO3 <1 ---- <1 ----mg/L1DMO-210-001

<1Carbonate Alkalinity as CaCO3 <1 ---- <1 ----mg/L13812-32-6

165Bicarbonate Alkalinity as CaCO3 236 ---- 186 ----mg/L171-52-3

165 236 ---- 186 ----mg/L1----Total Alkalinity as CaCO3


1050Sulfate as SO4 - Turbidimetric 1060 ---- 1820 ----mg/L114808-79-8


9680Chloride 7360 ---- 5090 ----mg/L116887-00-6


670Calcium 246 ---- 314 ----mg/L17440-70-2

779Magnesium 505 ---- 494 ----mg/L17439-95-4

5100Sodium 4340 ---- 3090 ----mg/L17440-23-5

57Potassium 174 ---- 76 ----mg/L17440-09-7


298 234 ---- 185 ----meq/L0.01----Total Anions

321 247 ---- 193 ----meq/L0.01----Total Cations

3.65 2.63 ---- 1.98 ----%0.01----Ionic Balance



(PFBS)

0.0023 ---- ---- ----µg/L0.0005375-73-5


(PFBS)

---- 15.3 0.73 0.90µg/L0.02375-73-5


(PFPeS)

0.0006 ---- ---- ----µg/L0.00052706-91-4


(PFPeS)

---- 3.76 0.58 0.94µg/L0.022706-91-4


(PFHxS)

0.0069 ---- ---- ----µg/L0.0005355-46-4


(PFHxS)

---- 0.65 4.02 7.70µg/L0.02355-46-4


(PFHpS)

<0.0005 ---- ---- ----µg/L0.0005375-92-8


(PFHpS)

---- <0.05 0.12 0.56µg/L0.02375-92-8

11 of 38:Page

Work Order :

:Client

ET1801086



Analytical Results

0874_QC1MW_18041

8_02

0874_QC1MW_18041

8_01

0874_MW125_D_1804

18_F

0874_MW231_S_1804

18

0874_MW229_S_1804

18


(Matrix: WATER)






(PFOS)

0.0244 ---- ---- ----µg/L0.00031763-23-1


(PFDS)

<0.0005 ---- ---- ----µg/L0.0005335-77-3


(PFOS)

---- <0.05 2.54 13.1µg/L0.011763-23-1


(PFDS)

---- <0.05 <0.05 <0.05µg/L0.02335-77-3



----Perfluorobutanoic acid (PFBA) ---- 7.0 <0.2 <0.2µg/L0.1375-22-4


----Perfluoropentanoic acid (PFPeA) ---- 17.0 0.22 0.35µg/L0.022706-90-3


----Perfluorohexanoic acid (PFHxA) ---- 132 1.10 1.92µg/L0.02307-24-4


----Perfluoroheptanoic acid (PFHpA) ---- 5.86 0.10 0.26µg/L0.02375-85-9


----Perfluorooctanoic acid (PFOA) ---- 4.39 0.14 0.73µg/L0.01335-67-1

0.0014Perfluorononanoic acid (PFNA) <0.0005 ---- ---- ----µg/L0.0005375-95-1




0.0005Perfluoroundecanoic acid

(PFUnDA)

<0.0005 ---- ---- ----µg/L0.00052058-94-8


(PFUnDA)

---- <0.05 <0.05 <0.05µg/L0.022058-94-8


(PFDoDA)

<0.0005 ---- ---- ----µg/L0.0005307-55-1


(PFDoDA)

---- <0.05 <0.05 <0.05µg/L0.02307-55-1


(PFTrDA)

<0.0005 ---- ---- ----µg/L0.000572629-94-8


(PFTrDA)

---- <0.05 <0.05 <0.05µg/L0.0272629-94-8

12 of 38:Page

Work Order :

:Client

ET1801086



Analytical Results

0874_QC1MW_18041

8_02

0874_QC1MW_18041

8_01

0874_MW125_D_1804

18_F

0874_MW231_S_1804

18

0874_MW229_S_1804

18


(Matrix: WATER)






(PFTeDA)

<0.0005 ---- ---- ----µg/L0.0005376-06-7


(PFTeDA)

---- <0.12 <0.12 <0.12µg/L0.05376-06-7



(FOSA)

<0.0005 ---- ---- ----µg/L0.0005754-91-6


(FOSA)

---- <0.05 <0.05 0.18µg/L0.02754-91-6



<0.001 ---- ---- ----µg/L0.00131506-32-8



---- <0.12 <0.12 <0.12µg/L0.0531506-32-8



<0.001 ---- ---- ----µg/L0.0014151-50-2



---- <0.12 <0.12 <0.12µg/L0.054151-50-2



<0.001 ---- ---- ----µg/L0.00124448-09-7



---- <0.12 <0.12 <0.12µg/L0.0524448-09-7



<0.001 ---- ---- ----µg/L0.0011691-99-2



---- <0.12 <0.12 <0.12µg/L0.051691-99-2



(MeFOSAA)

<0.0005 ---- ---- ----µg/L0.00052355-31-9



(MeFOSAA)

---- <0.05 <0.05 <0.05µg/L0.022355-31-9



(EtFOSAA)

<0.0005 ---- ---- ----µg/L0.00052991-50-6

13 of 38:Page

Work Order :

:Client

ET1801086



Analytical Results

0874_QC1MW_18041

8_02

0874_QC1MW_18041

8_01

0874_MW125_D_1804

18_F

0874_MW231_S_1804

18

0874_MW229_S_1804

18


(Matrix: WATER)







(EtFOSAA)

---- <0.05 <0.05 <0.05µg/L0.022991-50-6



(4:2 FTS)

<0.001 ---- ---- ----µg/L0.001757124-72-4


(4:2 FTS)

---- <0.05 <0.05 <0.05µg/L0.05757124-72-4


(6:2 FTS)

<0.001 ---- ---- ----µg/L0.00127619-97-2


(6:2 FTS)

---- <0.05 <0.05 <0.05µg/L0.0527619-97-2


(8:2 FTS)

<0.001 ---- ---- ----µg/L0.00139108-34-4


(8:2 FTS)

---- <0.05 <0.05 <0.05µg/L0.0539108-34-4


(10:2 FTS)

<0.001 ---- ---- ----µg/L0.001120226-60-0


(10:2 FTS)

---- <0.05 <0.05 <0.05µg/L0.05120226-60-0

EP231P: PFAS Sums

0.355 0.0347 ---- ---- ----µg/L0.0003----Sum of PFAS

---- ---- 186 9.55 26.6µg/L0.01----Sum of PFAS


1

----Sum of PFHxS and PFOS ---- 0.65 6.56 20.8µg/L0.01355-46-4/1763-23-

1


---- ---- 182 8.85 25.0µg/L0.01----Sum of PFAS (WA DER List)


86.8 90.3 ---- ---- ----%0.0005----13C4-PFOS

---- ---- 103 95.4 102%0.02----13C4-PFOS

94.1 97.2 ---- ---- ----%0.0005----13C8-PFOA

---- ---- 96.8 93.0 91.7%0.02----13C8-PFOA

14 of 38:Page

Work Order :

:Client

ET1801086



Analytical Results

0874_MW244_S_1804

19

0874_QC5MW_18041

8_02

0874_QC5MW_18041

8_01

0874_QC4MW_18041

8

0874_QC3MW_18041

8


(Matrix: WATER)





---- ---- ---- ---- 7.11pH Unit0.01----pH Value


----^ ---- ---- ---- 62.6-0.01----Sodium Adsorption Ratio


---- ---- ---- ---- 55100µS/cm1----Electrical Conductivity @ 25°C


---- ---- ---- ---- 44500mg/L10----Total Dissolved Solids @180°C


---- ---- ---- ---- 35800mg/L1----Total Dissolved Solids (Calc.)


---- ---- ---- ---- 4250mg/L5----Suspended Solids (SS)

EA045: Turbidity

---- ---- ---- ---- 3600NTU0.1----Turbidity


---- ---- ---- ---- 6500mg/L1----Total Hardness as CaCO3


<1Hydroxide Alkalinity as CaCO3 ---- ---- ---- <1mg/L1DMO-210-001

<1Carbonate Alkalinity as CaCO3 ---- ---- ---- <1mg/L13812-32-6

3Bicarbonate Alkalinity as CaCO3 ---- ---- ---- 201mg/L171-52-3

3 ---- ---- ---- 201mg/L1----Total Alkalinity as CaCO3


<1Sulfate as SO4 - Turbidimetric ---- ---- ---- 3720mg/L114808-79-8


<1Chloride ---- ---- ---- 20700mg/L116887-00-6


<1Calcium ---- ---- ---- 474mg/L17440-70-2

<1Magnesium ---- ---- ---- 1290mg/L17439-95-4

3Sodium ---- ---- ---- 11600mg/L17440-23-5

<1Potassium ---- ---- ---- 296mg/L17440-09-7


----Aluminium ---- ---- ---- <0.05mg/L0.017429-90-5

----Manganese ---- ---- ---- 2.02mg/L0.0017439-96-5

----Iron ---- ---- ---- <0.05mg/L0.057439-89-6

15 of 38:Page

Work Order :

:Client

ET1801086



Analytical Results

0874_MW244_S_1804

19

0874_QC5MW_18041

8_02

0874_QC5MW_18041

8_01

0874_QC4MW_18041

8

0874_QC3MW_18041

8


(Matrix: WATER)





---- ---- ---- ---- <0.05mg/L0.05----Ferrous Iron


----Fluoride ---- ---- ---- 0.5mg/L0.116984-48-8


----Ammonia as N ---- ---- ---- 0.06mg/L0.017664-41-7


----Nitrite as N ---- ---- ---- <0.01mg/L0.0114797-65-0


----Nitrate as N ---- ---- ---- 0.06mg/L0.0114797-55-8


---- ---- ---- ---- 0.06mg/L0.01----Nitrite + Nitrate as N


---- ---- ---- ---- 1.1mg/L0.1----Total Kjeldahl Nitrogen as N


----^ ---- ---- ---- 1.2mg/L0.1----Total Nitrogen as N


---- ---- ---- ---- 0.33mg/L0.01----Total Phosphorus as P


----Reactive Phosphorus as P ---- ---- ---- 0.01mg/L0.0114265-44-2


0.06 ---- ---- ---- 665meq/L0.01----Total Anions

0.13 ---- ---- ---- 642meq/L0.01----Total Cations

---- ---- ---- ---- 1.79%0.01----Ionic Balance


---- ---- ---- ---- 2mg/L1----Total Organic Carbon


---- ---- ---- ---- 340mg/L10----Chemical Oxygen Demand


---- ---- ---- ---- <2mg/L2----Biochemical Oxygen Demand



(PFBS)

---- ---- ---- 3.48µg/L0.02375-73-5

16 of 38:Page

Work Order :

:Client

ET1801086



Analytical Results

0874_MW244_S_1804

19

0874_QC5MW_18041

8_02

0874_QC5MW_18041

8_01

0874_QC4MW_18041

8

0874_QC3MW_18041

8


(Matrix: WATER)






(PFPeS)

---- ---- ---- 4.04µg/L0.022706-91-4


(PFHxS)

---- ---- ---- 20.9µg/L0.02355-46-4


(PFHpS)

---- ---- ---- 0.51µg/L0.02375-92-8


(PFOS)

---- ---- ---- 9.26µg/L0.011763-23-1


(PFDS)

---- ---- ---- <0.10µg/L0.02335-77-3


----Perfluorobutanoic acid (PFBA) ---- ---- ---- 0.4µg/L0.1375-22-4








(PFUnDA)

---- ---- ---- <0.10µg/L0.022058-94-8


(PFDoDA)

---- ---- ---- <0.10µg/L0.02307-55-1


(PFTrDA)

---- ---- ---- <0.10µg/L0.0272629-94-8


(PFTeDA)

---- ---- ---- <0.25µg/L0.05376-06-7



(FOSA)

---- ---- ---- <0.10µg/L0.02754-91-6



---- ---- ---- <0.25µg/L0.0531506-32-8



---- ---- ---- <0.25µg/L0.054151-50-2



---- ---- ---- <0.25µg/L0.0524448-09-7

17 of 38:Page

Work Order :

:Client

ET1801086



Analytical Results

0874_MW244_S_1804

19

0874_QC5MW_18041

8_02

0874_QC5MW_18041

8_01

0874_QC4MW_18041

8

0874_QC3MW_18041

8


(Matrix: WATER)







---- ---- ---- <0.25µg/L0.051691-99-2



(MeFOSAA)

---- ---- ---- <0.10µg/L0.022355-31-9



(EtFOSAA)

---- ---- ---- <0.10µg/L0.022991-50-6



(4:2 FTS)

---- ---- ---- <0.10µg/L0.05757124-72-4


(6:2 FTS)

---- ---- ---- <0.10µg/L0.0527619-97-2


(8:2 FTS)

---- ---- ---- <0.10µg/L0.0539108-34-4


(10:2 FTS)

---- ---- ---- <0.10µg/L0.05120226-60-0


---- ---- ---- ---- 50.9µg/L0.01----Sum of PFAS


1

---- ---- ---- ---- 50.9µg/L0.01----Sum of TOP C4 - C14 Carboxylates and C4

- C8 Sulfonates

----^ ---- ---- ---- 32.0µg/L0.01----Sum of TOP C4 - C14 as Fluorine



(PFBS)

<0.0005 <0.0005 <0.0005 ----µg/L0.0005375-73-5


(PFBS)

---- ---- ---- 4.73µg/L0.02375-73-5


(PFPeS)

<0.0005 <0.0005 <0.0005 ----µg/L0.00052706-91-4


(PFPeS)

---- ---- ---- 4.61µg/L0.022706-91-4


(PFHxS)

<0.0005 <0.0005 <0.0005 ----µg/L0.0005355-46-4

18 of 38:Page

Work Order :

:Client

ET1801086



Analytical Results

0874_MW244_S_1804

19

0874_QC5MW_18041

8_02

0874_QC5MW_18041

8_01

0874_QC4MW_18041

8

0874_QC3MW_18041

8


(Matrix: WATER)






(PFHxS)

---- ---- ---- 25.9µg/L0.02355-46-4


(PFHpS)

<0.0005 <0.0005 <0.0005 ----µg/L0.0005375-92-8


(PFHpS)

---- ---- ---- 0.80µg/L0.02375-92-8


(PFOS)

<0.0003 <0.0003 <0.0003 ----µg/L0.00031763-23-1


(PFDS)

<0.0005 <0.0005 <0.0005 ----µg/L0.0005335-77-3


(PFOS)

---- ---- ---- 16.2µg/L0.011763-23-1


(PFDS)

---- ---- ---- <0.10µg/L0.02335-77-3



----Perfluorobutanoic acid (PFBA) ---- ---- ---- <0.5µg/L0.1375-22-4

<0.0005Perfluoropentanoic acid (PFPeA) <0.0005 <0.0005 <0.0005 ----µg/L0.00052706-90-3


<0.0005Perfluorohexanoic acid (PFHxA) <0.0005 <0.0005 <0.0005 ----µg/L0.0005307-24-4


<0.0005Perfluoroheptanoic acid (PFHpA) <0.0005 <0.0005 <0.0005 ----µg/L0.0005375-85-9


<0.0005Perfluorooctanoic acid (PFOA) <0.0005 <0.0005 <0.0005 ----µg/L0.0005335-67-1


<0.0005Perfluorononanoic acid (PFNA) <0.0005 <0.0005 <0.0005 ----µg/L0.0005375-95-1


<0.0005Perfluorodecanoic acid (PFDA) <0.0005 <0.0005 <0.0005 ----µg/L0.0005335-76-2



(PFUnDA)

<0.0005 <0.0005 <0.0005 ----µg/L0.00052058-94-8


(PFUnDA)

---- ---- ---- <0.10µg/L0.022058-94-8


(PFDoDA)

<0.0005 <0.0005 <0.0005 ----µg/L0.0005307-55-1

19 of 38:Page

Work Order :

:Client

ET1801086



Analytical Results

0874_MW244_S_1804

19

0874_QC5MW_18041

8_02

0874_QC5MW_18041

8_01

0874_QC4MW_18041

8

0874_QC3MW_18041

8


(Matrix: WATER)






(PFDoDA)

---- ---- ---- <0.10µg/L0.02307-55-1


(PFTrDA)

<0.0005 <0.0005 <0.0005 ----µg/L0.000572629-94-8


(PFTrDA)

---- ---- ---- <0.10µg/L0.0272629-94-8


(PFTeDA)

<0.0005 <0.0005 <0.0005 ----µg/L0.0005376-06-7


(PFTeDA)

---- ---- ---- <0.25µg/L0.05376-06-7



(FOSA)

<0.0005 <0.0005 <0.0005 ----µg/L0.0005754-91-6


(FOSA)

---- ---- ---- <0.10µg/L0.02754-91-6



<0.001 <0.001 <0.001 ----µg/L0.00131506-32-8



---- ---- ---- <0.25µg/L0.0531506-32-8



<0.001 <0.001 <0.001 ----µg/L0.0014151-50-2



---- ---- ---- <0.25µg/L0.054151-50-2



<0.001 <0.001 <0.001 ----µg/L0.00124448-09-7



---- ---- ---- <0.25µg/L0.0524448-09-7



<0.001 <0.001 <0.001 ----µg/L0.0011691-99-2



---- ---- ---- <0.25µg/L0.051691-99-2



(MeFOSAA)

<0.0005 <0.0005 <0.0005 ----µg/L0.00052355-31-9

20 of 38:Page

Work Order :

:Client

ET1801086



Analytical Results

0874_MW244_S_1804

19

0874_QC5MW_18041

8_02

0874_QC5MW_18041

8_01

0874_QC4MW_18041

8

0874_QC3MW_18041

8


(Matrix: WATER)







(MeFOSAA)

---- ---- ---- <0.10µg/L0.022355-31-9



(EtFOSAA)

<0.0005 <0.0005 <0.0005 ----µg/L0.00052991-50-6



(EtFOSAA)

---- ---- ---- <0.10µg/L0.022991-50-6



(4:2 FTS)

<0.001 <0.001 <0.001 ----µg/L0.001757124-72-4


(4:2 FTS)

---- ---- ---- <0.10µg/L0.05757124-72-4


(6:2 FTS)

<0.001 <0.001 <0.001 ----µg/L0.00127619-97-2


(6:2 FTS)

---- ---- ---- <0.10µg/L0.0527619-97-2


(8:2 FTS)

<0.001 <0.001 <0.001 ----µg/L0.00139108-34-4


(8:2 FTS)

---- ---- ---- <0.10µg/L0.0539108-34-4


(10:2 FTS)

<0.001 <0.001 <0.001 ----µg/L0.001120226-60-0


(10:2 FTS)

---- ---- ---- <0.10µg/L0.05120226-60-0

EP231P: PFAS Sums

<0.0003 <0.0003 <0.0003 <0.0003 ----µg/L0.0003----Sum of PFAS

---- ---- ---- ---- 61.2µg/L0.01----Sum of PFAS

<0.0003Sum of PFHxS and PFOS <0.0003 <0.0003 <0.0003 ----µg/L0.0003355-46-4/1763-23-

1


1

<0.0003 <0.0003 <0.0003 <0.0003 ----µg/L0.0003----Sum of PFAS (WA DER List)

---- ---- ---- ---- 55.8µg/L0.01----Sum of PFAS (WA DER List)

21 of 38:Page

Work Order :

:Client

ET1801086



Analytical Results

0874_MW244_S_1804

19

0874_QC5MW_18041

8_02

0874_QC5MW_18041

8_01

0874_QC4MW_18041

8

0874_QC3MW_18041

8


(Matrix: WATER)





---- ---- ---- ---- 97.0%0.02----13C4-PFOS

---- ---- ---- ---- 102%0.02----13C8-PFOA


76.7 75.3 82.3 93.3 ----%0.0005----13C4-PFOS

---- ---- ---- ---- 101%0.02----13C4-PFOS

103 102 102 102 ----%0.0005----13C8-PFOA

---- ---- ---- ---- 95.3%0.02----13C8-PFOA

22 of 38:Page

Work Order :

:Client

ET1801086



Analytical Results

0874_MW248_S_1804

19

0874_MW247_S_1804

19

0874_MW239_S_1804

19

0874_MW242_S_1804

19

0874_MW121_S_1804

19


(Matrix: WATER)





5.51 7.68 7.26 6.55 7.64pH Unit0.01----pH Value


28.4^ 15.4 18.2 7.09 49.8-0.01----Sodium Adsorption Ratio


21000 5730 4230 541 14500µS/cm1----Electrical Conductivity @ 25°C


16500 3700 2650 830 10300mg/L10----Total Dissolved Solids @180°C


13600 3720 2750 352 9420mg/L1----Total Dissolved Solids (Calc.)


202 1140 10500 2040 5490mg/L5----Suspended Solids (SS)

EA045: Turbidity

167 226 6600 1730 3900NTU0.1----Turbidity


3780 790 322 47 811mg/L1----Total Hardness as CaCO3









6350Chloride 1560 1040 48 3910mg/L116887-00-6


492Calcium 122 63 9 74mg/L17440-70-2

620Magnesium 118 40 6 152mg/L17439-95-4

4020Sodium 996 750 112 3260mg/L17440-23-5

160Potassium 34 6 5 24mg/L17440-09-7


0.55Aluminium <0.01 <0.01 <0.01 <0.01mg/L0.017429-90-5

12.3Manganese 1.39 0.528 0.001 0.071mg/L0.0017439-96-5

0.73Iron <0.05 <0.05 <0.05 <0.05mg/L0.057439-89-6

23 of 38:Page

Work Order :

:Client

ET1801086



Analytical Results

0874_MW248_S_1804

19

0874_MW247_S_1804

19

0874_MW239_S_1804

19

0874_MW242_S_1804

19

0874_MW121_S_1804

19


(Matrix: WATER)





0.70 <0.05 <0.05 <0.05 <0.05mg/L0.05----Ferrous Iron


0.6Fluoride 0.4 0.2 0.2 0.4mg/L0.116984-48-8


0.10Ammonia as N 0.18 <0.01 0.01 0.04mg/L0.017664-41-7


<0.01Nitrite as N <0.01 <0.01 <0.01 <0.01mg/L0.0114797-65-0


0.26Nitrate as N 0.10 4.36 0.04 0.55mg/L0.0114797-55-8


0.26 0.10 4.36 0.04 0.55mg/L0.01----Nitrite + Nitrate as N


0.9 0.4 0.8 0.6 2.0mg/L0.1----Total Kjeldahl Nitrogen as N


1.2^ 0.5 5.2 0.6 2.6mg/L0.1----Total Nitrogen as N


0.05 0.09 0.32 0.57 0.43mg/L0.01----Total Phosphorus as P


<0.01Reactive Phosphorus as P 0.04 0.12 0.42 0.03mg/L0.0114265-44-2


244 55.4 39.9 5.40 160meq/L0.01----Total Anions

254 60.0 39.2 5.94 159meq/L0.01----Total Cations

2.17 3.93 0.91 4.79 0.36%0.01----Ionic Balance


7 2 7 4 28mg/L1----Total Organic Carbon


<100 <50 <50 <10 <100mg/L10----Chemical Oxygen Demand


<2 3 <2 <2 <2mg/L2----Biochemical Oxygen Demand



(PFBS)

---- ---- ---- 47.7µg/L0.02375-73-5

24 of 38:Page

Work Order :

:Client

ET1801086



Analytical Results

0874_MW248_S_1804

19

0874_MW247_S_1804

19

0874_MW239_S_1804

19

0874_MW242_S_1804

19

0874_MW121_S_1804

19


(Matrix: WATER)






(PFPeS)

---- ---- ---- 63.7µg/L0.022706-91-4


(PFHxS)

---- ---- ---- 625µg/L0.02355-46-4


(PFHpS)

---- ---- ---- 50.4µg/L0.02375-92-8


(PFOS)

---- ---- ---- 860µg/L0.011763-23-1


(PFDS)

---- ---- ---- <1.00µg/L0.02335-77-3


----Perfluorobutanoic acid (PFBA) ---- ---- ---- 43.2µg/L0.1375-22-4


----Perfluorohexanoic acid (PFHxA) ---- ---- ---- 446µg/L0.02307-24-4






(PFUnDA)

---- ---- ---- <1.00µg/L0.022058-94-8


(PFDoDA)

---- ---- ---- <1.00µg/L0.02307-55-1


(PFTrDA)

---- ---- ---- <1.00µg/L0.0272629-94-8


(PFTeDA)

---- ---- ---- <2.50µg/L0.05376-06-7



(FOSA)

---- ---- ---- <1.00µg/L0.02754-91-6



---- ---- ---- <2.50µg/L0.0531506-32-8



---- ---- ---- <2.50µg/L0.054151-50-2



---- ---- ---- <2.50µg/L0.0524448-09-7

25 of 38:Page

Work Order :

:Client

ET1801086



Analytical Results

0874_MW248_S_1804

19

0874_MW247_S_1804

19

0874_MW239_S_1804

19

0874_MW242_S_1804

19

0874_MW121_S_1804

19


(Matrix: WATER)







---- ---- ---- <2.50µg/L0.051691-99-2



(MeFOSAA)

---- ---- ---- <1.00µg/L0.022355-31-9



(EtFOSAA)

---- ---- ---- <1.00µg/L0.022991-50-6



(4:2 FTS)

---- ---- ---- <1.00µg/L0.05757124-72-4


(6:2 FTS)

---- ---- ---- <1.00µg/L0.0527619-97-2


(8:2 FTS)

---- ---- ---- <1.00µg/L0.0539108-34-4


(10:2 FTS)

---- ---- ---- <1.00µg/L0.05120226-60-0


---- ---- ---- ---- 2270µg/L0.01----Sum of PFAS

----Sum of PFHxS and PFOS ---- ---- ---- 1480µg/L0.01355-46-4/1763-23-

1

---- ---- ---- ---- 2270µg/L0.01----Sum of TOP C4 - C14 Carboxylates and C4

- C8 Sulfonates

----^ ---- ---- ---- 1450µg/L0.01----Sum of TOP C4 - C14 as Fluorine



(PFBS)

---- 0.0346 ---- ----µg/L0.0005375-73-5


(PFBS)

0.05 ---- 1.60 70.0µg/L0.02375-73-5


(PFPeS)

---- 0.0139 ---- ----µg/L0.00052706-91-4


(PFPeS)

<0.02 ---- 2.27 73.0µg/L0.022706-91-4


(PFHxS)

---- 0.137 ---- ----µg/L0.0005355-46-4

26 of 38:Page

Work Order :

:Client

ET1801086



Analytical Results

0874_MW248_S_1804

19

0874_MW247_S_1804

19

0874_MW239_S_1804

19

0874_MW242_S_1804

19

0874_MW121_S_1804

19


(Matrix: WATER)






(PFHxS)

0.21 ---- 21.8 727µg/L0.02355-46-4


(PFHpS)

---- 0.0026 ---- ----µg/L0.0005375-92-8


(PFHpS)

<0.02 ---- 1.88 83.0µg/L0.02375-92-8


(PFOS)

---- 0.285 ---- ----µg/L0.00031763-23-1


(PFDS)

---- <0.0005 ---- ----µg/L0.0005335-77-3


(PFOS)

0.22 ---- 107 1510µg/L0.011763-23-1


(PFDS)

<0.02 ---- <0.02 <0.05µg/L0.02335-77-3


----Perfluorobutanoic acid (PFBA) ---- <0.002 ---- ----µg/L0.002375-22-4

<0.5Perfluorobutanoic acid (PFBA) <0.1 ---- 0.4 9.3µg/L0.1375-22-4

----Perfluoropentanoic acid (PFPeA) ---- 0.0033 ---- ----µg/L0.00052706-90-3

<0.10Perfluoropentanoic acid (PFPeA) <0.02 ---- 0.64 19.2µg/L0.022706-90-3

----Perfluorohexanoic acid (PFHxA) ---- 0.0394 ---- ----µg/L0.0005307-24-4

0.22Perfluorohexanoic acid (PFHxA) 0.04 ---- 4.05 150µg/L0.02307-24-4

----Perfluoroheptanoic acid (PFHpA) ---- 0.0084 ---- ----µg/L0.0005375-85-9

<0.10Perfluoroheptanoic acid (PFHpA) <0.02 ---- 0.41 15.2µg/L0.02375-85-9

----Perfluorooctanoic acid (PFOA) ---- 0.0183 ---- ----µg/L0.0005335-67-1

<0.10Perfluorooctanoic acid (PFOA) <0.02 ---- 1.38 61.0µg/L0.01335-67-1

----Perfluorononanoic acid (PFNA) ---- 0.0029 ---- ----µg/L0.0005375-95-1

<0.10Perfluorononanoic acid (PFNA) <0.02 ---- 0.04 0.52µg/L0.02375-95-1

----Perfluorodecanoic acid (PFDA) ---- 0.0022 ---- ----µg/L0.0005335-76-2

<0.10Perfluorodecanoic acid (PFDA) <0.02 ---- <0.02 <0.05µg/L0.02335-76-2


(PFUnDA)

---- <0.0005 ---- ----µg/L0.00052058-94-8


(PFUnDA)

<0.02 ---- <0.02 <0.05µg/L0.022058-94-8


(PFDoDA)

---- <0.0005 ---- ----µg/L0.0005307-55-1

27 of 38:Page

Work Order :

:Client

ET1801086



Analytical Results

0874_MW248_S_1804

19

0874_MW247_S_1804

19

0874_MW239_S_1804

19

0874_MW242_S_1804

19

0874_MW121_S_1804

19


(Matrix: WATER)






(PFDoDA)

<0.02 ---- <0.02 <0.05µg/L0.02307-55-1


(PFTrDA)

---- <0.0005 ---- ----µg/L0.000572629-94-8


(PFTrDA)

<0.02 ---- <0.02 <0.05µg/L0.0272629-94-8


(PFTeDA)

---- <0.0005 ---- ----µg/L0.0005376-06-7


(PFTeDA)

<0.05 ---- <0.05 <0.12µg/L0.05376-06-7



(FOSA)

---- 0.0064 ---- ----µg/L0.0005754-91-6


(FOSA)

<0.02 ---- 0.73 0.21µg/L0.02754-91-6



---- <0.001 ---- ----µg/L0.00131506-32-8



<0.05 ---- <0.05 <0.12µg/L0.0531506-32-8



---- <0.001 ---- ----µg/L0.0014151-50-2



<0.05 ---- <0.05 <0.12µg/L0.054151-50-2



---- <0.001 ---- ----µg/L0.00124448-09-7



<0.05 ---- <0.05 <0.12µg/L0.0524448-09-7



---- <0.001 ---- ----µg/L0.0011691-99-2



<0.05 ---- <0.05 <0.12µg/L0.051691-99-2



(MeFOSAA)

---- <0.0005 ---- ----µg/L0.00052355-31-9

Documents

Method Blank (MB) and Laboratory Control Spike (LCS) Report