Marine Hazardous Substances Data System_Volume 2

A MARINE HAZARDOUS

SUBSTANCES DATA SYSTEM

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Report No.CG-D-9-86

VOL. II OF TASK III FINAL REPORT,MARINE HAZARDOUS CHEMICAL WORKER

R. JOHN PREVOSTPATRICIA K. BOWLES

This document is available to the U.S. public through the NationalTechnical Information Service, Springfield, Virginia 22161

Prepared for:

~., U.S. DepartmentofTransportationUnited States Coast Guard

Office of Research and DevelopmentWashington, D.C. 20593

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-'-, ,

SOUTHWEST RESEARCH INSTITUTEPost Office Drawer 28510, 6220 Culebra Road

San Antonio, Texas 78284

A MARINE HAZARDOUSSUBSTANCES DATA SYSTEM

By

R. John PrevostPatricia K. Bowles

Volume II ofTask III FINAL REPORT

Contract DTCG23;.;82-C-20027SwRI Project'06L7223· .

Prepared for

... U.S. Coast GuardCommandant (G-FCP-22Fl64)

2100 Second Street, S.W.Washington, D.C. 20590

December 1985

Ulric S. Lindholm, Vice PresidentDivision of Engineering and Materials Sciences

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LEGAL NOTICE

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This work was prepared as an account ofgovernment-sponsored work;" Neither the United States,nor the U. S. Coast Guard, nor any person acting on behalf of the U. S. Coast Guard (A) Makes any warranty orrepresentation: expressed or implied, with respect tothe accuracy, completeness, or usefulness of the information contained in this report, or that the use of anyinformation, apparatus,method, or process disclosed inthis report may not infringe privately owned rights: or(B) Assumes any li~bilities with respect t6' the use of orfor damages resulting from the use of any information,apparatus, method:.or process disClosed in this report.As used in the above, "persons acting on behalf of theU. S. Coast Guard" includes any employee or contractorof the U. S. Coast Guard to the extent that suchemployee or contractor prepares, handles or distributes,or provides access to any information pursuant to hisemployment or contractwith the U. S. Coast Guard.

.' ,

The United States Goverr'iment does 'not endorseproducts or manufacturers. Trade or manufacturers'names appear herein solely because they are consideredessential to the object of this report. .

Tecltnical Report Documentation Page

2. GOyern",en, Acce'lion No. 3. Recipien", CO'olog No.

... Ti,l" ond Sub,,,le

A Marine Hazardous Substances Data System

S. Repoll Oo'e

December 19856. P e "O'''''''1l O,goniution Code

06-7223

~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~8. Pe,form,nll O'lloni~Olion Repor, No.7. Au,ho,'.)

R. .1. Prevost and P. K. Bowles9. p.r'o'''''ng Organilo"oft N...... _d Add'.'1

Southwest Research InstituteP. O. Drawer 285106220 Culebra RoadSan Antonio, texas 78284

12. Spon,oring Agency No",e and Add,en

U. S. Coast Guard2100 Second Street, S.W.Washington, D.C. 20590

JO. Worlo Un,' /'4. nRAISl

11. Con,roc, or G,ont No.

DTCG23-82-C-20027

15. Suppl.",en'o,y No,e.

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This document presents a data system for maint ining and processing data onhazardous substances in the marine environment. It is 1\,¥oluille~ H-of,"8' three-volume report which describes a medical monitoring program for marine personnel who may bepotentially exposed to hazardous chemicals during their work.. A rationale for rankingmarine hazardous substances is described and a comprehensive listing of marine hazardous substances, grouped by hazard priority classification is presented. Twenty-twotypes of information or characteristic data for the hazardous substances are maintained

~iR...t.J:le-Ge:t-a:-syste~andoutput can be structured to'present data for specified subsets of- substances and/or subsets of data types. ~<,,"1;ypes of data maintained in "the-Ela.tar1'tis

system include: chemical name, Chemical H8.iards Response Infprmation System_ (CHRIS) Code, time weighted average threshold limit value, short term exposure limit,

immediately dangerous to life or health concenitation, odor threshold, respiratoryhazard index, toxicity priority class code, carcinog~riicity reference per ACGIH, NFPAhealth hazard classification and NAS health haza:i'd,,'rating, Chemical Abstracts Service

?~--""(-C-A-lS}- registry number, DOT emergency respo:n$e,guide number, availability ofNIOSH/OSHA occupational health gUidelines'J~~~i,;.chemical hazards, availability ofbiological monitoring methods, and availabili~Y:~r"~~~l~'~~or tube. fle,,~WG'('dS"~

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Hazardous Substances azard .R"anking;> This~6~4rriient is available to the U.S. publicD~ta .Syst~m " , ~mical..B8ta~ thr()ugh)the National Technical Information-PrlOr!ty",Class~flcatlOn,9I,€alt~~~~ta},.;J Service~cSpringfield,VA 22161

:)ReSplratory Hazard,i~ndex" r: ',,",' " '-1_~" r /' ---veea1l1 '~V\ 1/1 1~;)v\:Ii"r\,;~~TS "

19, Security Clonit. (of this ,e"or') 20. Securi'y Cloni/. (of ,hi, pavel 21. 1'10.0' Pog.. 22. Priu

Unclassified Unclassified 92

Form DOT F 1700.1 (8-721 Reproduction of completed pog. outhori&.d

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ACKNOWLEDGEMENTS

., The authors of this report wish to acknowledge the followingsignificant support in developing the HSDS. Dr. D. E. Johnson and others ofhis staff in the Division of Chemistry and Chemical Engineering at SouthwestResearch Institute establi shed a preliminary version of the HSDS and compiledan initial set of data on marine hazardous substances. In~dditici~,Or.

Johnson was instrumental in helping develop the rationale for classificationof the marine hazardous substances into six priority classes of occupationalhealth hazard. ProfessorJ. W.Hammond and students worki.ng under hissupervision at the University of Texas School of Public Health collected andprovided. the data reported herein on a number of the topics including odor .threshold, IDlH, and CAS, and also provided invaluable assistance in reviewingand ~diting the relatively large set of data contained in th~HSDS:

Acknowledgement is also given to Professor Hammond, a Certified IndustrialHygienist, for specifying the set of non-cargo hazardous substances found inthe marine occupational environment which is discussed and presented in thisreport. Mr. J. C. Buckingham is acknowledged for the compilation of dataregarding the availability of detector tubes and overseeing the input of thatlarge set of data in the HSDS. To these individuals and organizations and toothers not mentioned specifically, who provided help and support in thepreparation of this report, we offer our sincere thanks and appreciation.

iii

TABLE OF CONTENTS

Section

ACKNOWLEDGEMENTS

LIST OF TABLES

Page

iii

v

III. HSDS PROGRAM

111.1 Code Description111.2 HSDS Program Utilization

REFERENCES

APPENDICES

A Listing of Hazardous Substances DataB Program Listings

I.

II.

INTRODUCTION

MARINE HAZARDOUS SUBSTANCES

11.1 Classification of Hazardous Substances11.2 Description ~f~HSDS Data .11.3 Presentation of the Hazardous Substances

1

2

24

11

33

3333

37

A-IB-1

iv

Table No.

1

2

3

4

5

6

7

8

9

A-I

A-2

A-3

LIST OF TABLES

Key to Abbreviations

Justification for Inclusion of Additional Substancesin Priority Class 2

Class 1 Substances - Carcinogen Cargos

Class 2 Substances - High Toxic Hazard Cargos

Class 3 Substances - Toxic Hazard Cargos

Class 4 Substances - Possible Toxic Hazard Cargos

Class 5 Substances - Other Hazardous Cargos

Class 6 Substances - Non Cargo Substances WithToxic Hazard

Identification Numbers for Data Base Records

Data for Class 1 Substances

Data for Class 2 Substances

Master Listing of HSDS Data

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v

Page

5

14

15

16

18

22

24

32

35

A-3

A-5

A-9

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I. INTRODUCTION.~ r

This document presents a hazard9us ~~bstancesda~~ system,(HSDS) for. T" _,' "

maintaining and processing data 'on hazardous su6sfances in the marineenvironment. It is Volume II of a three-volume report which describes thedeslgn cif a medical monitoring program for the marine hazardous chemical

, worker:

Volume I: A Medical Monitoring Program for the Marine HazardousChemical Worker [1)

Volume II: A Marine Hazardous Substances Data SystemVolume III: Biochemical and Medical Information for Marine Hazardous

Substances [2]

The purpose of this volUme is tri provide a ready reference forthreshold limits and other exposure-related information for the hazardouscargo substances regulated under Subchapter 0 and Subchapter 0 (CFR 46, Parts30-40 and 150-154) and for certain non-cargo toxic substances encountered inmaintenance and other routine operations aboard tankers and barges.

The order of presentat;-on of materia'ls in this volume is as follows.Chapter 11 p~e~ents a description' of the rational~ for ranking the ~arine

hazardous· substances, a description of the types of data contained 'in theHSOS, and a co~prehen*i~e listing of the marin~ h~zardous sUbstarices, groupedby hazard priorityclassificatiori.A description of the H~OS pro~ram 1spresented in Chapter III. Detailed listings of HSOS data output and a listingof the'HSOS program statements are presented in Appendices A'andB,respectively.

1

II.l

II. MARINE HAZARDOUS SUBSTANCES

'0; _t,'.

Classification of Hazardous Substances'.. :.' '~':J' '.

i "1;"

The marine hazar'do~s substances for which the HSDS has been designed.include hazardous~a~gos' reg"~'late'd under SUbchapter- D and Subchapter 0 (CFR 46Parts 30-40 and 150-154, respectively) and non-cargo toxic substancesencountered in maintenance and other .routine operations aboard tankers and. , .- " . ..

barges. The~e substances have been separated into six priority classes:

Priority Class

1

2

3

4

5

6

Description of Class

Carcinogen CargosHigh Toxic Hazard Cargos (Noncarcinogens)Toxic Hazard Cargos; .Possjble. Toxic Hazard CargosOther Hazardous Cargos

: ,Non-cargo Substances with Toxic Hazard.~ " .

In general, the priority classes decrease in toxic hazard from PriorityClass,l to Priority Class 5•. Priority Class 6 contains non-cargo substances,some of which are highly toxic~ .. Relevant information on the health hazard ofoccupational exposures for Classes 1-3 substances has been documented bj theAmerican Conference of,GovernmentalIndustr·ialHygienists'(ACGIH) [3) and thisinformation has been used to classify these cargo substances.

The substances designated Classl are bulk .liquid cargos which are.I

known or suspected carcinogens as documented by the ACGIH. The Clas$ 1designation indicates that these substances are considered by the Task IIIpanel [1) to exhibit the greatest potential for occupational health effectsand warrant the greatest precautions for avoidance of exposures.

The substances designated Classes 2 and 3 include the remainder of allbulk liquid cargos regulated under Subchapters 0 and 0 for which a thresholdlimit value (TlV) has been assigned by the ACGIH. The differentiation betweenClasses 2 and 3 is based primarily on the hazard of toxic exposures viarespiration. A respiratory hazard index was developed and used to rank the

2

substances in this regard. This index is defined as the concentration atsaturation (C5) in'parts pei ~illion {pp~) ~ivided b~t~e current ACGIH timeweight~d average (TWA) thr~shold limitv~l~e ~n'ppm'~ndcan be expressed asfollows:'

Respiratory Hazard Index = CS(ppm)jTWA(ppm).

where CS is defined as the concentration of the substance when saturated inair at 20°C and one atmosphere ambient pressure. This concentration isdetermined from the va~ot pressure of the su6stanceat 20°C in mm of mercurydivided by the standard pressure of one atmosphere, 760 mm of mercury, 'andmultiplied by 106 in order to obtain a numerical value in ppm. An upper limitof 106 pp~ was imposed due to the limit of one atmos~hef~ ambient pressure.

The respiratory hazard index was used to evaluate all cargo substanceswith a current ACGIH TLV-TWA~ These substances ~ere ranked with use of theindex with' the bbj~ctive bfdeter~ining which substanc~s should be placed inPriority Class 2, High Toxic Hazard. The desire was to identify approximately100 of the most hazardous-cargo substances and allocate them to Classe~ 1 and2. There was an appa~ent cut~oint at CS/TWA = 10,600; a signific~nt numberof 'substances were grouped above 10,000 units and the remainder were significantly below 10,000 units. This apparently natural cut point was used todistinguish between Priority Classes 2 and 3.

All cargo sUbstances with a respiratory hazard index (CS/TWA) 10,000 orgreater have'been included-in Priofity Class 2, High' Toxic Hazard. Inaddition, substances in Classes 3, 4' and 5 have been evaluated individually todetermine if a rationale based on parameters other'than respiratory hazardshould be used to justify inclusio~ in Class 2. ;Th~se other-paramet~rs are:

(1) Potential contribution to exposure by skinabs'orption(2) Extreme toxicity without regard to vapor pressure

,(3) NAS/NFPAclassiffcation (Described tn'Section II~2)

':J

3

r.,

For Class 4 sUbstanC~~~iinformation on the health hazard of.occupational exposures.1s,;not aval1able Jrom ACGIH;,' re,levant data have. beenobtained from sources other than the ACGIH. Because the ACGIH has beenconsidered by the Task III panel to be the most current and correct source ofsuch information, the health hazard i~formation available for Class 4

, .i I l '

substances is considered to be of importance, but not of the same stature asACGIH data on health h~zards associa,ted with occupational exposures.

}'.

For Class 5 substances, ,no data on health hazards associated withoccupational exposures have been identi~ied for inclusion in, this report.These substances are known to present a safety hazard thus are regulated in. ' ' . ' .. '.. ' ~. .

commerce under Subchapter 0 9rSubchapter D., They~ay or ,may not exhibit anoccupational health hazard.

Class 6.substances are not transported as bulk liquid cargos .but are,encountered in the marine environment in maintenance and other routine

; - . '.

operations. The potential for,exposures to these substances is generally. l, , . " ~

less than for exposure 1 to cargo~u~stances, and thu~ they have been~classed

in the lowest priorityclas~ification. However, all substances designated asClass 6 do exhibit a t,oxic hazard for occupational exposures ,as documented byACGIH [31.

11.2 Description of "SDS Data

Some twenty-two types of d.ata are -maintained. in the HS,oS 'for each,hazardous substance. To facilitate the 1i sti ng of output data, an

- - .' I ' '-

abbreviation has been devised· to label each type of data. Output from the, . . -'. .

HSDS is structured to present data fora given substance on a Jine wJthabbreviated column headings which specify the type of information beinglisted. A key to ,the a,bbreviatio':1s used in the HSDS is ,presented in Table·1. A discussion o( each of these,t,,!en,ty-twQ s4bstance char~cteristics is

. -,,- - ,:,., . . .. -. .

presented as fo llqws. Whereappropri4te, the data, so~rce i ~ re,ferenced. Theabbreviation used to label the information in the HSDS output, as shown inTable 1, is used as the heading for each discussion.

4

Abbreviation

CHEMICAL NAME

CHRIS CODE

CFR

OTHER ROUTE

TLV- TWA PPM-

STEL- PPM

IOLH PPM

ODOR PPM

CS PPM

CS/TWA

TaX CODE

CARC REF

NFPANAS

SEC PROD

CAS

EMRSP GUIDE

BIO MED

NIOSH GUIDE

BID MON

QUAL DT

QUAN OT

TLV DT

TABLE 1. KEY TO ABBREVIATIONS

Description

Chemical name of the hazardous substance

Chemical Hazards Response Information System(Code used by U. S. Coast Guard)

Code of Federal Regulations - primary regulatory citation:o - Subchapter 0, 46CFR Parts 150-154o - Subchapter 0, 46 CFR Parts 30-40

SKIN - Potential contribution to overall exposure by thecutaneous route

Time Weighted Average Threshold Limit Value8-hour TWA in ppm, unless otherwise notedC - Ceiling value, not 8-hour TWA

Short Term Exposure Limit in ppm

Immediately Dangerous to Life or Health Concentration in ppm

Odor Threshold in ppm

Concentration at Saturation (vapor pressure) in ppm

Respiratory Hazard Index

Toxicity Priority Class Code

Carcinogenicity Reference per ACGIH

NFPA Health Hazard ClassificationNAS Health Hazard Rating

Secondary Product

Chemical Abstracts. Service Registry Number

DOT Emergency Response Guide Number

Biochemical and Medical Data Sheet

NIOSH/OSHA Occupational Health Guidelines for ChemicalHazards

Biological Monitoring

Qualitative Detector Tube

Quantitative Detector Tube

Threshold Limit Value Detector Tube

5

CHEMICAL NAME • ",1

;', "," .The chemical name of the hazardous substance is the primary

descriptor for hazardous subsiances:iA {h~ HSDS.. In somec8ses, an a~pro~. ' , ' ...

priate synonym or other explanatory information is also included with theprimary chemical name .. The primary chem ic'a 1 ,names were obtained from a

, " . ':listing [4] of all chemi'cals regulated in the .cFR which was provided by theU. S. Coast Guard Hazardous Materials Branch (G-MTH-1), Washington, D.C •

• • • ' .',' - ,'- I ' ','

CHRIS CODE .....

" ~.,

This is threelettercod~ us~d for the U. S. Coast Guard ChemicalHazards Response InformationSyste~ (CHRIS). The code was obtained from theChemical Data Guide for Bulk Shipment by Water [5].- '. ' .", ,

CFR': , .

The designation 0 for Subch~pter 0 (46 CFR Parts 150-154) o~ D forSubchapter D (46 CFR Parts 30-40) is~rovided as obtained from the listingreferenced CHEMICAL NAME [4].

OTHER ROUTE',-' ,

The designation SKIN is indicated for substances which exhibit apotential contribution to overall exposure by the cutaneous route. ForPriority Class 1-3 sUbStances, this' information was obtained from the ACGIHpubl icationof threshold Umit va,lue.s ,for 1983-84 [3].

TlV-TWA PPM

The time weighted average threshold limit value is presented inppm unless otherwise noted. For certairi substances, the units of milligfamsper cubic meter (MG/M3) are specifiea. For Priority Classes 1, 2, 3, and 6,this information was obtained from the ACGIH pUblication of threshold limitvalues [3]. The presence of a note' in parenthese~ immediately after the"iLvTWA indicates that the v~lue of£he'TLV~is assotiated·witha specific isomer

6

of the substance or witha:secondary product ,given off by the s~bstance. If" • I,,' .

the association is with a secondary product,·the TOX CODE (see next page) isfollowed by an asterisk (*).

For Class 4 sUbstances,TLV data are unavai.lable from the ACGIH.T.He TLV-TWA data for Class 4 substances have been determined from sourcesother than ACGIH and these are specified with TOX CODE designation (seenext page).

As ~iscussed preyiously (Section 11.1), .for substances included inPriority Class 5, no data on occupational health has been identified for

, . " . -'

inclusion in this report. No ACGIH TW,l\-JLV data are available nor have anycomparable data .been.found from other sources.

:STEL PPM

The short term exposure limit is presented in ppm unless otherwise.' specified.' For Priority. Classes 1-3. sUbs.tances, this information was obtainedfrom Reference 3.

IDlH PPM

Jh~·IDLHconcen~ratidh in ppm was ~bt~ined from two sources: TheChemical Dat~ .Guide for .BulkShipment by. Water [4] and the NIOSH/OSHA PocketGuide to Chemical Hazards [6]i.'

ODOR PPM

The odor threshold in ppm was obtained from four separate sources[5,7,8, ..91. DiscrepMcies .a,mong the various sources were resolved by theindustrial hygienist on the,Task ,III .pa~el [1].

CS PPM.

The concentration at saturation is provided in ppm for oneatmosphere of pressure at 20°C. An upper limit of one million ppm was applied

7

because of the specification of normal working conditions of one atmosphere ofpressure. (See Section 11.1 for discussion of CS calculation.)

CS/IWA

The respiratory hazard index, CS/TWA is ~ unitless numbercalculated by dividing the concentration at saturation (CS) by the TWA~TLV~

TOX CODE (Toxicity Code)

This code is the Priority Class designation which decreases intoxic ha~ard from Priority Class 1 to Priority Class 6, as discussed iMSecti~nll.1. In addit10n to the numerical code, other symbols sometimesappear immediately after the numerical code. An asterisk (*) indicates thatthe TLV-TWA data (and thus the TOX CODE classification) is associated with asecondary product. A letter symbol following the numerical code indicates asource of TLV-TWA data other than ACGIH, as discussed previously for Column 5(TLV-TWA PPM). This onl~ occurs for Class 4 substances. The followingreferences have been identified and coded as sources of TLV-TWA data for :Glass4 substances:

Code Reference

C Chemical Data Guide for Bulk. Shipment By Water (5)H Personal CommuniGation with Prof. J. W. Hammond, C.I.H. (10)L Letter from U.S.C.G. Cargo and Hazards Branch [11)N NIOSH Registry of Toxic Effects of Chemical Substances (12)P NIOSH/OSHA Pocket Guide/to Chemical Hazards [6]U Undocumented Source

CARC REF (Carcinogen Reference)

This is the reference to carginogenic potential as determined fromthe 1983-84 publication of threshold limit values [3]. In that reference,substances are classified by ACGIH: as a recognized human carcinogen (AI) oran industrial substance suspected of carcinogenic potential (A2). Theseclassifications, Al or A2, are used as the coding in the HSDS.

8

.NFPA/NAS

The data field for thi~ information is coded in four digits. Thefirst digit is the National Fire Prevention Association (NFPA) health hazardclassification [131 described as follows:

NFPA Health HazardClassification Definition

4 Materials which on very short exposure could cause deathor major residual injury even though prompt medicaltreatment were given.

3 Materials which on short exposure could cause serioustemporary or residual injury even though prompt medicaltreatment were given.

2 Materials which on intense or continued exposure couldcause temporary incapacitation or possible residualinjury unless prompt~edical treatment is given.

1 Materials which on exposure would cause irritation butonly. minor' residual injury. even if no treatment is given.

o Materials which on exposure under fir~ conditions wouldoffer no hazard beyond that of ordinary combustiblematerial.

The second thro~gh fourth digits are the National Academy of Sciences (NAS)vapor irritant" liqUid or solid irritant, and poison health hazard ratings[14], respectivelY"which are described as follows:

NAS Hazard Liquid orRating Vapor Irritant So 1id Irritant

0 No effect No effect

1 Sl ight Effect Causes skinsmarting

2 Moderateirritati~n; First-degree burns,temporary effect short exposure -

3 Irritating; cannot Second-degree burns,be tolerated few mi nutes.'

exposure

4 Severe effect; may Second-degree anddO.permanent injury third-degree burns

Poisons

No effect

Slightly toxic

Intermediatetoxicity

Moderately toxic

Severe1y toxic

Q9

SEC PROD (Secondary Product)

Any toxic secondary product such as H2S or HCL which is emitted bythe primary hazardous substance is indicated in the HSDS.

CAS

The Chemical Abstracts Service registry number was obtained fromthe Registry of Toxic Effects of Chemical Substances [121. This number is auseful identifier for making certain that the exact chemical substance isbeing described in a given reference.

EMRSP GUIDE

The emergency re$ponse gUide number was obtained from the 1984Emergency Response Guidebook pUblished by the U. S. Department ofTfansportation [15]. The emergency response guide number provides animmediate reference which describes potential hazards and recommendedemergency action procedures.

BID MED (Biochemical and Medical)

The inclusion of a Biochemical and Medical Data Sheet for thesubstance in Volume III of the Task III report [21 is indicated in the HSDS.

NIOSH GUIDE

If occupational health gUidelines can be found in the OccupationalHealth Guidelines for Chemical Hazards published by the National Institute forOccupational Safety and Health [161, this fact is indicated in the HSDS databank.

BID MON (Biological Monitoring)

The availability of a biological monitoring method published inVolume I, Appendix Cof the Task III report [1] is indicated in the HSDS by a

10

letter coding which indicates the specific noninvasive sampling medium ormedia: B for breath and/or U for urine.

QUAL Dr (Q~alitatiYe Detector TUbe)*

The availability of a detector tube to qualitatively detect thespecific hazardous substance is indicated in the HSOS by the presence ofletter coding which indicates the manufacturer: 0 for National Draegerand/or G for Gastec (Sensidyne).

QUAM OT (Quantitative Detector Tube)*

The availability of a detector tube to quantitatively measure thespecific hazardous substance is indicated in the HSoS by the same coding asused above for QUAN OT: 0 for National Draeger and/or G for Gastec(Sensidyne).

rlV oT .(TlV·oetector Tube)*

The availability of a detector tube to quantitatively measure thespecific hazardous substance at or below the TLV concentration is indicated inthe HSDS by the same coding used above for QUAL 01 and QUAN OT: 0 forNational Draeger and/or G for Gastec (Sensidyne).

1103 Presentation of the Hazardous Substances

The marine ~azardous substances 1n each of the six priority classesare presented in this section. Data for a total of 699 marine hazardoussubstances are currently maintained in the HSDS. The number of substances ineach priority classification is:

*The indication of'detector tube brand names in QUAL OT, QUAN OT, and TlV DTdoes not reflect any endorsement of specific products but are only used asexamples of detector tubes available.

11

Class Number

1 18( 2 56

3 1634 745 3646 24

Of the total 699 substances, information on the health hazard of occupationalexposures is presented for 335 substances in Classes 1, 2, 3, 4, and 6. Forthe 364 substances in Class 5, no d~ta on health hazards associated withoccupational exposures have been identified for inclusion iri this report.

The rationale for classification discussed in Section 11.1 was used toseparate the substances into these six priority classes. As specified in therationale, Class 1 substances are known or suspected carcinogens. Class 2

substances are high toxic hazard cargos which are not carcinogens. Together,the 74 cargo substances listed in Classes 1 and 2 are considered to be themost worrisome regarding occupational exposures. For medical monitoringpurposes, personnel are classified as high risk [IJ due to high potential forexposure to Class 1 or Class 2 chemical substances. This requi~es twoconditions to be met: 1) High potential for exposure in routine jobassignment, and 2) known or suspected involvement with Class 1 ~r Class 2 ,chemical substances.

As discussed in Section 11.1, the primary rational~ for placement of aI

substance in Class 2 is high respiratory hazard. A respiratory hazard indexwhich accounts for vapor pressure and inherent toxicity was used as anindicator of those substances with high respiratory hazard. However, otherparameters were also considered for justification of inclusion of a substancein Class 2 even when the respiratory hazard index did not justify inclusion.The potential for absorption through skin and extreme toxicity without regardto vapor pressure are two parameters which were considered for the remainderof the list of hazardous substances not designated as Class 1 or Class 2 bythe. primary rationale. Accordingly, a number of substances were transferred

12

from other classes to Class 2 and these are presented in Table 2 with a brief

statement of the specific justification for their inclusion in Class 2.

Certain of the Priority Class 3 substances have been designated bythe Coast Guard Hazardous Materials Branch [17] as more important than the

remaining Class 3 substances for the purposes of health surveillance. Thisdesignation has been indicated in the HSDS by the symbol "#" with the TOX

CODE. A total of 41 substances have thusly been designated as PriorityClass 3#.

The marine hazardous substances in each of the six priority classes are

presented in Tables 3-8 for Priority Classes 1-6, respectively. A limitedamount of data are also presented with the chemical name for each hazardous

substance to help identify the substance and its inherent toxicity. In thesetables, data are presented in alphabetical order of the chemical" name for thefollowing headings:

(1) CHEMICAL NAME(2) CHRIS CODE(3) CFR(4) OTHER ROUTE(5) TLV-TWA(6) SEQ NO

This last heading, SEQ NO, is the sequence number of the line ofin the master listing of data which is presented in Appendix A.

substance, this sequence number provides an easy cross-reference,

presented for that substance in the master listing.

informationFor a given

to the data

11

Complete listings of data for" all twenty-two columns of data for Class1 and for Class 2 substances and a master listing of the complete set of datafor the hazardous substances covered by HSDS are presented in Appendix A. Thedata in the Appendix A master listing are presented in alphabetical order bychemical name. The final column of data in the master list, labeled SEQ NO,is the sequence number of the line of data in the master list. This sequencenumber provides an easy cross-reference to the data for that substancepresented in other parts of this report.

13

TABLE 2. JUSTIFICATION FOR INCLUSION OFADDITIONAL SUBSTANCES IN PRIORITY CLASS 2

Chemical Name

Acetone cyanohydrin

Anil i ne

Chlorosulfonic acid

2,2 1 -Dichloroethyl ether

1,4-Dioxane

Diphenylmethane diisocyanate

Epichlorohydrin

Hydrochloric acid

Hydrofluoric acid

Nitrobenzene

Motor fuel antiknock compounds

Phenol

Phosphorus, white

Styrene

Toluene 2,4-Diisocyanate

Trichloroethylene

*Not recognized by ACGIH.

Justification

Skin absorption, extreme toxicity

Skin absorption

Extreme toxicity, toxic secondary product


Skin absorption

Extreme toxicity, high NAS hazard rating


Skin absorption

High toxicity, high NAS hazard rating

Suspect carcinogen* .

Skin absorption, extreme toxicity.

Suspect carcinogen*

14

20-DEC-8SCHEMICAL NAME

TABLE 3. CLASS 1 SUBSTANCES-CARCINOGEN CARGOS

CHRIS CFR OTHERCODE ROUTE

TlV-TWA SEGlPPM NO.

ACRYLONITRILE ACNBENZENE BNZBENZENE HYDROCARBON MIX () OR = 10% BEN) BHBBENZENE HYDROCARBON MIX (WITH ACETYLENE) BHABENZENE, TOLUENE. XYLENE MIXTURE BTXBUTADIENE (1,3 BUTADIENE) BDIBUTADIENE. BUTYLENE MIX WITH ACETYLENES BBMCARBON TETRACHLORIDE CSTCHLOROFORM CRFETHYLENE DIBROMIDE EDBETHYLENE OXIDE EOXETHYLENE OXIDE. PROPYLENE OXIDE MIXTURE EPMFORMALDEHYDE SOLUTION FHSNITROPROPANE (1-, 2-. AND MIXTURES) NPM2-NITROPROPANE NPPNITROPROPANE (60;'). NITROETHANE (40;') NNMO-TOLUIDINE TLIVINYL CHLORIDE VCM

TOTAL OF 18 ITEM(S) IN TABLE

15

a SKINaoooooo SKINoa SKINQoooooo SKINQ

2 01110 04010 04110 04210 04410 05010 051

5 09310 103

2571 2691 2701 287

10· (2-) 42910 43010 (2-) 431

2 6355 679

TABLE 4. CLASS 2 SUBSTANCES-HIGH TOXIC HAZARD CARGOS

20-DEC-85CHEMICAL NAME CHRIS CFR OTHER

CODE ROUTETLV-TWAPPM

SEGNO.

005019020024031046061002'063064091100109122148151

. -" -156157158191194195196197207212228242243244258300326328329330349350380383386409422423424557560591612615621

0.2521

2521

C5C5C5C510

1 ...12

c' ,·5co. 10

'.1 "1

. 15

10io101025

CO. 022

10101010

CO.2C5

3C5

355

105

50O. 10 MG/M3

2215

O. 1 MG/M32050

21

o SKINo SKINaao SKINoo SKINo SKINo SKINo SKINo SKINoooo SKINoo SKINo SKINo SKINo SKINoooaa SKINoo SKINaoooaaaaooooa SKINoa SKINaoa SKINa SKINaoaaa SKIN

ACETONE CYANOHYDRIN ACYALLYL ALCOHOL ALAALLYL CHLORIDE ALCAMMONIA, ANHYDROUS AMAANILINE ANLBENZYL CHLORIDE BCLBUTYLAMINE (ALL ISOMERS) STYN-BUTYLAMINE BAMSEC-BUTYLAMINE BTLTERT-BUTYLAMINE BUACARBON DISULFIDE CBBCHLORINE CLXCHLOROSULFONIC ACID CSACROTONALDEHYDE CTA2,2'-DICHLOROETHYL ETHER DEEDICHLOROMONJFLUOROMETHANE DFMl,3-DICHLOROPROPENE DPUDICHLOROPROPENE (1,1- 1,2- 1,3- AND MIX) DPSDICHLOROPROPENE,DICHLOROPROPANE MIXTURE) OMXDIISOPROPYLAMINE OIADIMETHYLAMINE DMADIMETHYLAMINE SOLUTION (45% OR LESS) DMGDIMETHYLAMINE SOLUTION ()45% AND <=55%) DMYDIMETHYLAMINE SOLUTION (55% AND <65%) DMC1,4-DIOXANE DOXDIPHENYLMETNANE DIISOCYANATE OPMEPICHLOROHYDRIN EPCETHYLAMINE EAMETHYLAMINE (40% OR LESS) EAOETHYLAMINE (72% OR LESS) EANETHYLENE DICHLORIDE EDCGLUTARALDEHYDE (50% OR LESS) GTAHYDROCHLORIC ACID HCLHYDROFLUORIC ACID HFAHYDROGEN CHLORIDE HOCHYDROGEN FLUORIDE HFXISOPROPYLAMINE IPPISOPROPYLAMINE (90% OR LESS) IPOMETHYLAMINE SOLUTION (42% OR LESS) MSZMETHYL BROMIDE MTSMETHYL CHLORIDE MTCMOTOR FUEL ANTIKNOCK CMPDS (PB ALKYLS) MFANITRIC ACID NACNITRIC ACID (70% OR LESS) NCDNITROBENZENE NTBPHENOL PHNPHOSPHORUS, WHITE PPWPROPYLENE OXIDE POXSTYRENE STYSULFUR DIOXIDE SFD1,1,2,2-TETRACHLOROETHANE TEC

16

TABLE 4. CLASS 2 SUBSTANCES-HIGH TOXIC HAZARD CARGOS (CONT'D)


CODE RQUTETLV-l'WA SEGPPM NO.

TOLUENE 2,4-DIISOCYANATE TDl aTOLUENE DIISOCVANATE, DIPHENVLMET DIISOC TDD 0TRICHLOROETHYLENE TCL 0VINYL ACETATE VAM DVINYLIDENECHLORIDE VCI 0

TOTAL OF 56 ITEM{S) IN TABLE

17

.005

.0055010

5

633634639677681

TABLE 5. CLASS 3 SUBSTANCES-TOXIC HAZARD CARGOS

20-0EC-85CHEMICAL NAME CHRIS CFR OTHER TLV-TWA SEG

CODE ROUTE PPM NO.

ACETALDEHYDE AAD 0 100 001ACETIC ACID AAC 0 10 002ACETIC ANHYDRIDE ACA 0 C5 003ACETONE ACT -0 750 - 004-ACETONITRILE ATN a SKIN 40 006ACRYLAMIDE (50X OR LESS) AAM 0 SKIN 0.3 MG/M3 009ACRYLIC ACID ACR 0 10 010N-AMYL ACETATE AML 0 100 026ASPHALT ASP 0 5 MG/M3 036ASPHALT BLENDING STOCKS: ROOFERS FLUX ARF 0 5 MG/M3 037ASPHALT BLENDING STOCKS: STRAIGHT RUN RE ASR 0 5 MG/M3 038BUTANE BUT a 800 052N-BUTVL ACETATE BCN 0 150 053SEC-BUTYL ACETATE BTA 0 200 054ISO-BUTYL ACRYLATE BAI 0 10 055BUTYL ACRYLATE (INH) ( ISO, N, AND MIXES) BAR 0 10 056N-BUTYL ACRYLATE BTC a 10 057N-BUTYL ALCOHOL BAN 0 SKIN C50 058SEC-BUTYL ALCOHOL BAS D 100 059TERT-BUTYL ALCOHOL BAT 0 100 060BUTYL TOLUENE (P-TERT) 0 10 (P-T) 076CAMPHOR (OIL) CPO 0 2 087CAPRQLACTAM (SOLUTION) CLS 0 5 088CARBON BLACK BASE 0 3. 5 MG/M3 090CAUSTIC POTASH SOLUTION CPS 0 SKIN C2 MG/M3 094CAUSTIC SODA SOLUTION CSS a SKIN C2 MG/M3 095CHLOROBENZENE CRB 0 75 102CHLOROTOLUENE (0, H, p, AND MIXTURES) CHI 0 SKIN <0-) 50 (0-) 110O-CHLOROTOLUENE CTa 0 SKIN 50 112!"i-CRESOL CRL 0 SKIN 5 117O-CRESOL CSL 0 SKIN 5 118P-CRESOL CSO 0 SKIN 5 119CRESOILS CRS 0 SKIN 5 120CUMENE CUM 0 SKIN 50 123CYCLOHEXANE CHX 0 300 124CYCLOHEXANOL CHN 0 50 125CYCLOHEXANONE CCH 0 25 126CYCLQHEXVLAMINE CHA 0 SKIN 10 127CYCLOPENTADIENE POLYMERS 0 75 128DIACETONE ALCOHOL DAA D 50 138DIBUTYL PHTHALATE DPA 0 5 MG/M3 142Q-DICHLOROBENZENE OBO 0 C50 144.P-DICHLOROBENZENE DBP 0 75 145DICHLORODIFLUOROMETHANE DCF a 1000 1461, l-DICHLQROETHANE DCH 0 200 147DICHLOROMETHANE (METHYLENE CHLORIDE) DCM 0 100 1501,2-DICHLOROPROPANE DPP 0 75 1542,2-DXCHLOROPROPIONIC ACID DCN 0 1 159DICHLOROTETRAFLUOROETHANE DTE 0 1000 160DICYCLOPENTADIENE OPT 0 5 161DIETHANOLAMINIE DEA 0 3 162

18

TABLE 5. CLASS 3 SUBSTANCES-TOXIC HAZARD CARGOS (CONT'D)


CODE ROUTEn.V-TWA SEGPPM NO.

DIETHVLAMINEDIETHVLENETRIAMINEOIETHYL PHTHALATEDIISOBUTVL KETONEDIMETHYLACETAMIDEDIMETHVLFORMAMIDEDIMETHYL PHTHALATEDIPHENYLDIPROPYLENE GLVCOL MONOMETHYL ETHERETHANE2-ETHOXYETHANOL2-ETHOXYETHYL ACETATEETHYL ACETATEETHYL ACRYLATEETHYL ALCOHOLETHYL AMYL KETONEETHYLBENZENEETHYL CHLORIDEETHYLENEETHYLENE CHLOROHYDRINETHYLENEDIAMINEETHYLENE GLYCOLETHYLENE GLYCOL MONOBUTYL ETHERETHYLENE GLYCOL MONOETHYL ETHER ACETATEETHYLENE GLYCOL MONOMETHYL ETHERETHYLENE GLYCOL MONOMETHYL ETHER ACETATEETHYL ETHERETHYLIDENE NORBORNENEFORMAMIDEFORMIC ACIDFURFURALFURFURYL ALCOHOLGASOLINE: AUTOMOTIVE (4.23G PB/GAL)GASOLINE: AVIATION (4.86G PB/GAL)GASOLINE BLENDING STOCKS: ALKVLATESGASOLINE BLENDING STaCKS: REFORMATES 'GASOLINE: CASINGHEADGASOLINE: POLYMERGASOLINE: STRAIGHT RUNHEPTANEHEXANEHEXYLENE GLYCOLHYDROCHLORIC ACID, SPENT (15~ OR LESS)INDUSTRIAL WASTES (METHYL MERCAPTAN, ETC)ISOAMYL ACETATEISOBUTYL ACETATEISOBUTYL ALCOHOLI SOPHORONEISOPHORONE DIISOCYANATEISOPROPYL ACETATEISOPROPYL ALCOHOL

DENDETDPHDIKDACDMFDTLOIL

ETHEOE

ETAEACEAL

ETBECLETLECHEDAEGLEGMEGAEME

EETENSFAMFMAFFAFALGATGAVGAKQRFGCSGPLGSRHPTHXAHXGHCSINWIATIBAIALIPHIPDlACIPA

19

aa SKINDDo SKINo SKINDDDoD SKIND SKINDo SKINDDDooo SKINoDD SKIND SKIND SKINDaoDoa SKIND SKINDDoDoDDDDDooDDDDo SKINDD

1015

251010

50.2100

55

4005

100025

1001000

Cl10

C5025

555

400C520

52

10300300300300300300300400

50C25

C5o. 5100150

50C5

CO. 01250400

MG/M3

MG/M3

CM-M)

163174i78185193201202209215230231232239240241245246249252254256259262264266267272280288289290291293294295296297298299310320324327333334335336343345347348

TABLE 5. CLASS 3 SUBSTANCES-TOXIC HAZARD CARGOS (CONT'D)



SEGNO.

ISOPROPYL ETHERMALEIC ANHYDRIDEMESITYL OXIDEMETHACRYLIC ACIDMETHANEMETHYL ACETATEMETHYL ACETYLENE, PROPADIENE MIXTUREMETHYLACRYLATEMETHYL ALCOHOLMETHYL AMYL ALCOHOL(METHYLISOBUTYL CARB.METHYL BUTANOL (ISOAMYL ALCOHOL)METHYL ETHYL KETONE (2-BUTANONE)METHYL FORMATEMETHYL ISOBUTYL CARBINOLMEHTYL ISOBUTYL KETONE (HEXaNE)METHYL METHACRYLATEALPHA-METHYLSTYRENEMONOETHANOLAMINE (ETHANOLAMINE)MORPHOLINENAPHTHALENENAPHTHA: STODDARD SOLVENTl-NITROPROPANEO-NITROTOLUENENITROTOLUENE (0, P, AND MIXTURES)P-NITROTOLUENENONANEOCTANEOIL: CRUDE (SOUR)OLEUMN-PENTANEPERCHLOROETHVLENE(TETRACHLOROETHYLENE)PHOSPHORIC ACIDPHTHALIC ANHYDRIDEPROPANEPROPIONIC ACIDN-PROPYL ACETATEN-PROPYL ALCOHOLPROPYLENEPYRIDINESILICON TETRACHLORIDESODIUM DICHROMATE SOLUTION «=69X)(CRVI)SODIUM HYDROSULFIDE SOLUTION «=45%)SULFURIC ACIDSULFURIC ACID, SPENTTETRAHYDROFURANTOLUENEl,2,4-TRICHLOROBENZENEl,1,2-TRICHLOROETHANE1, 2, 3-TRICHLOROPROPANETRIETHYLAMINETRIMETHYL BENZENE

IPEMLAMSOMADMTHMTTMAPMAMMALMAA

MEKMFMMICMIKMMMMSRMEAMPLNTMNSSNPNNIENITNTTNANOANOILOLMPTAPERPACPANPRPPNAPATPALPPLPROSTCSOLSHRSFASACTHFTOLTCBTCMTCNTEN

20

aaaoaoaaoo0,

ooDDaaoaaDoaoaDDoaDaaoaaDoaaoaaoaoDooaaD

SKINSKINSKIN

SKIN

SKIN

SKINSKIN

SKIN

SKIN

SKIN

2500.25

1520

2001000

10200

251002001002550

10050

32010

10025

222

200300

101

60050

11

10200200

10005

C50.05

1011

200100

C510501025

351366371372

,373375377378379382384

,388391394395396401406408414418428

'432433434435446

(H2S) 454MG/M3 543

553555,

MQ/M3 558562577580583584587596

(HelL) 600MG/M3 605(H2S) 606MGl1t"l3'616MG/it"l3 617

627631

, 637638640649660

, TABLE 5o. CLASS 3 SUBSTANCES- TOX I C HAZARD CARGOS (CONT I D) ,

20-DEC-85CHEMICAL NAME

TRIMETHYL PHOSPHITETURPENTINEUREA, AMMONIUM NITRATE SOLN <> 2X NH3)N-VALERALDEHYDEVI NYLTOLUENEWAX: PARAFFINM-XYLENEa-XYLENEP-XYLENEZINC DIALKYLDITHIQPHOSPHATE

. TOTAL OF 163ITEM(S) IN_TABLE

CHRIS CFR OTHER TLV-TWA SEQCODE ROUTE PPM NO.

TPP 0 2 664TPT D 100 669UAS 0 25 (NH3) 674VAL 0 50 675VNT 0 50 683WPF D 2 MG/M3 686XL" 0 100 693XLO 0 100 694XLP D too 695ZDP 0 10 (H2S) 699

21

TABLE 6. CLASS '4 'SUBSTANCES-POSSIBL£:TOXICHAZARDCARGOS

20-DEC-S5CHEMICAL NAME CHRIS CFR OTHER

COOE ROUTETLV-TWAPPM

SEGNO.

ACETOPHENONEADIPONITRILEALKYLBENZENESULFONIC ACIDSAMMONIUM HYDROXIDE, 28 PERCENtiAG.N-AMYL ALCOHOLN-AMYL METHYL KETONE1,2-BUTYLENE OXIDEBUTYL METHYL KETONECAMPHORCARBOLIC OIL (PHENOL)CHEMICAL WASTES (CHLOR HCARBONS & CAUST)CHLOROHYpRINS (CRUDE>CHLOROPRENE2-CHLOROPROPIONIC ACID2- AND 3-CHLOROPROPIONIC ACIO MIXTUREP-CHLOROTOLUENECRESYLATE SPENT CAUSTICOIETHYLENE GLYCOLDIETHYLENEGLYCOL MONOETHYL ETHERDIETHYLENE GLYCOL MONOETHYL ETHER ACETATDIETHYLENEGLYCOL MONOMETHYL ETHERDIETHYLENE GLYCOL MONOMETHYL ETHER ACETDIETHYLETHANOLAMINE01 (ETHYLHEXYL)PHTHALATEDIOCTYL PHTHALATEDIPHENYL DIPHENYL OXIDEOIPHENYL ETHERETHYL BUTANOLN-ETHYL CYCLOHEXYLAMINEETHYLENE GLYCOL MONOISOPROPYL ETHERFERRIC CHLORIDE SOLUTIONSGLYC'ERINEHEXYL ACETATEISOPRENEJET FUEL: JP-l (KEROSENE)KEROSENEMETHYL AMYL ACETATE2-METHYL-6-ETHYL ANILINEMETHYL HEPTYL KETONE (ETHYL AMYL HEPTANOMINERAL SPIRITSMONOCHLORODIFLUOROMETHANENAPHTHA: AROMATIC (lOX OR LESS BENZENE)NAPHTHA: COAL TARNAPHTHA: CRACKING FRACTIONNAPHTHA: HEAVYNAPHTHA: PARAFFINICNAPHTHA: PETROLEUMNAPHTHA: SOLVENTNAPHTHA: VM & P (75% NAPHTHA)OCTYL PHTHALATEOIL, FUEL: NO. 1 (KEROSENE)

ACP"ADN,ASSAMHAANAMKBTO CJ

CPOCSOCWCCtiO :CRPCLACPMCRNescDEGDGE

DGM

DAE

DOPDDODPEEBTECC

FCSGCR

IPRJPOKRSMACMENMHKMNSMCF

NCT

NSVNVM

OON

D0,

,0'ooDaD

,,0, ,_o ~"

aa SKIN0,a SKINaaoaooooDaoDDoDaDoDDaoDoa SKINDDooaoooooooD

'," :. "." ..

1, ' .,00750" ',Q12

t, MG/M3 016c, 2do, ' '025,.100". , .. ,027,

50 029400 .:068

5 ' o?~2" 0865 089

10 0995 104

25 '1052 1062 (2-) 108

50 1135 121

100 1655 1695 1705 1715 172

10 1755 MO/M3 1775 MO/M3 206

o. 5 2101 211

100 247370 MG/M3 251

25 2651 MO/M3 285

10 MO/M3 30150 323

1000 346100 MO/M3 353100 MO/M3 357

50 381260 387

25 392100 402

1000 403100 410300 411100 412100 413100 415100 416100 417300 419

5 MG/M3 452100 MG/M3 491

22

TABLE 6. CLASS 4 SUBSTANCES-POSSIBLE TOXIC HAZARD CARGOS (CONT'D)


CODE ROUTETLV-TWA SEGPPM NO.

OIL, FUEL: NO. l-DOIL, MISC: ALIPHATICOIL, MISC: AROMATIC (5~ OR LESS BENZENE)OIL,· MISC: AVIATION F2300OIL MISC: COALOIL, MISC: HEARTCUT DISTILLATEOIL, MISC: LUBRICATINGOIL, MISC: MINERALOIL MISC: MOTOROIL, MISC: WHITE (MINERAL)PARALDEHYDEPOLYMETHYLENE POLYPHENYL ISOCYANATEPROP IONALOEHYDEPROPIONITRILEN-PROPYLAMINEPROPYLENE GLYCOL METHYL ETHERPSEUOOCUMENE (1,2,4-TRIMETHVLBENZENE)SODIUM BOROHYORIOE <<:=15X), NAOH/SOLUTTRICRESYL PHOSPHATE «lX a-ISOMER)TRICRESVL PHOSPHATE ()lX ORTHO)TURPENTINE SUBSTITUTE (WHITE SPIRIT)WHITE SPIRITWHITE SPIRIT, LOW AROMATIC


000

aLBOMNOMT

POHPPIPADPCNPRAPME

SBXTCPTCO

Doo

"DDDDDDDoaoOS.KINaoooooooo

100555555555

1. 50.014000

6

10025

2O. 1O. 1350500500

MG/M3 492MG/M3 499MG/M3 501MG/M3 502MG/M3 504MG/M3 509MG/M3 512MG/M3 513MG/M3 515MG/M3 540MG/M3 548

571579582585590595

MG/M3 603MGlM3 641MG/M3 642MG/H3 670

689690

23

,} . " . "

TABLE 7. CLASS 5 SUBSTANCES-OTHER 'HAZARDOUS CARGOS

20-DEC-85CHEM ICAL NAI'1E

.: ~.' ,..~,' .-

.' ," '.. '~, " CHRIS CFR OTHERCODE ROUTE

- , ,."

TLV-TWA SEGPPM NO.

008013014015017018021022023028030

,.039043.04,5048.049

·065.. ' 0¢t6" .• 067

069070'071072073075077078079080082083084085096097098101107111115116129130131132133134135136137139

.-.~ ~ . .' -'

~~' . ;.'

--"'; . .,~

~ . , " ,

.. ,....

• ~ --. ~1'..

~, . .

.: ;'...

AEXAEEAEP

BSCBAL

CEM

BMIBMN

BTE

ooo .'D

..Doooo.oDoooD , ".oDo

," .·D: . '.:0·;oDoo

J, " D ..BAD 0BAE 0BTR 0BLA D

oooooooooaooDDDDoooooa

CHMCLPCTM

DSZ

CCWCMPDALDCCOCEOATDARDANDBZ

CAK

,:,90E'.'. BPH'

·'BTN··.·

/

,"

,C <'t"!

...'....,

ACETYL TRIBUTYL CITRATEALCOHOLS (MIXED)ALKENYL SUCCINIC ACIDALKENYLSUCCINIC ANHYDRIDE'N-ALKYL PHTHALATESALKYL SUCCINNATE FORMALDEHYDE HYDROXY AM2-(2-AMINOETHOXY)ETHANOLAMINOETHYLETHANOLAMINEN-AMINOETHYLPIPERAZINEAMYLENEAMYL TALLATE'BEHENYL ALCOHOLBENZENESULFONYL CHLORIDEBENZYL ALCOHOL"BICYCLIC TERPENEL POLYAMINE AMIDE SALTaISPHENOL A DIGLYCIOYL ETHER'BUTVLBENZYL PHTHALATEBUTYL-ENE'BUT'fL.ENE' GL 'fCOLBUTYLENE ~bLYGLYCOL

N-BUTYL ETHERBUTYL HEPTYL KETONEISO-BUTYL METHACRYLATEN-BUTYL METHACRYLATEBUTYL STEARATEISO-BUTYRALDEHYOEBUTYRALDEHYDE (ISO, N, AND MIXTURES)N-BUTYRALDEHYDEGAMMA-BUTYROLACTONECALCIUM ALKYLPHENATECALCIUM ALKYL SALICYLATECALCIUM AMINO NONYL PHENOLATECALCIUM CARBOXYLATECETYL ALCOHOLCETYL-EICOSYL METHACRYLATECETYL STEARYL ALCOHOLCHLOROACETIC ACID SOLUTION (80X OR LESS)3-CHLOROPROPIONIC ACIDM-CHLOROTOLUENECLEANING SPIRIT (UNLEADED)CREOSOTEP-CYMENEN-DECALOEHYDEDECANEl-DECENEDECYL ACRYLATE (ISO, N, AND MIXTURES)N-DECYL ACRYLATEN-DECYL ALCOHOLN-DECYLBENZENEDETERGENT ALKYLATEDIAMMONIUM SALT OF ZINC EOTA (SOLUTION)

24

TABLE 7. CLASS 5 SUBSTANCES-OTHER HAZARDOUS CARGOS (CONT'D)


CODE ROUTETLV-TWA SEGPPM NO.

DI-N-BUTYLAMINE DBA aDIBUTYL CARBINOL 0M-OICHLOROBENZENE DBM ·0DICHLOROISOPROPYL ETHER OCI a2,4-DICHLOROPHENOL DCP 01.1-DICHLOROPROPANE DPS 01.3-DICHLOROPROPANE OPC 0OIETHVLBENZENE DEB DDIETHYLENE GLYCOL DIETHYL ETHER 0DIETHYLENEGLYCOL MONOBUTYLETHER ACETATE OEM 0DIETHYLENE GLYCOL MONOBUTYL ETHER OME 0DIETH¥LENE GLYCOL MONOPHENYL ETHER 0DI~(2-ETHVLHEXYL)PHOSPHORIC ACID OEP 0DIETHYL SULFATE OSU 0DIHEPTYL PHTHALATE DHP DDlHEXYL PHTHALATE D .01 ISOBUTYLAMINE OBU 0DIISOBUTYLCARBINOL DBC 0DIISOBUTYLENE OBl DDIISOBUTVl PHTHALATE DIT 0DIISODECYl PHTHALATE DID DDIISONONVL PHTHALATE DIN 0DIISOOCTYL PHTHALATE OIa 001 ISOPROPANOLAMINE DIP 0DIISOPROPYL BENZENE 0DIMETHYL AMMONIUM-2,4-0ICHLOROPHENOXYACE ODA 0N,N-DIMETHYLCYCLOHEXYLAMINE OXN 0DIMETHYLETHANOLAMINE ... OMS 02,.2-DIMETHYLPROPANE-l,3-DIOl 0DINONYL PHTHALATE 0DI<OCTYLPHENYL)AMINE DOIPENTENE DPN DDI-N-PROPVLAMINE DNA 0DIPROPYLENE GLYCOL DPG 0DISTILLATES: FLASHED FEED STOCKS OFF 0DISTILLATES: STRAtGHT RUN DSR 0DIUNDECYL PHTHALATE OUP 0DODECANE 0DODECANOL DON "0DODECENE DOD 0l-DODECENE DOC 0DODECVLBENZENE OOB 0DOOECYL OIPHENVL OXIDE OISULFONATE SOLN ODS 0DODECYLMETHACRYLATE OOM QDODECVL PENTADECVL METHACRYLATE DDP 0DODECYL PHENOL 0EPOXYLATED LINEAR ALCOHOLS, Cll-C15 DETHOXYLATED DODECANOl EOD 0ETHOXVLATED PENTADECANOL EOP 0ETHOXVLATED TETRAOECANOL EDT 0ETHOXYLATED TRIDECANOL ETO 0

25

140141143149152153155164166167168173176179180181182183184186187188189190192198199200203204205208213214216217218219220221222223224225226227229233234235236

TABLE 7. CLASS 5 SUBSTANCES-OTHER HAZARDOUS CARGOS (CONTID)

20-DEC-85CHEMICAL NA/"lE

ETHOXYLATED UNDECANOLETHOXY TRIGLYCOLN-ETHYL-N-BUTYLAMINEETHYL CYCLOHEXANEETHYLENE CARBONATEETHYLENE CYANOHYDRINETHYLENE GLYCOL OIACETATEETHYLENE GLYCOL METHYL BUTYL ETHERETHYLENE GLYCOL MONOBUTYL ETHER-ACETATEETHYLENE GLYCOL PHENYL ETHER ""ETHYLENE - PROPYLENE COPOLYMERSETHYLHEXALDEHYDEETHYLHEXANOIC ACID (ETHYL HEXOIC'ACIO)2-ETHYL HEXANOL2-ETHYLHEXYL ACRYLATE2-ETHYL HEXYLAMINEETHYL HEXYL PHTHALATEETHYLHEXYL TALLATEETHYL METHACRYLATE2-ETHYL-3-PROPYLACROLEINETHYL TOLUENEFATTY ACID AMIDESGAS OIL: CRACKEDGLYCERYL TRIACETATEGLYCIDYL ESTER OF TERTIARY CARBOXYLIC'''ACGLYCIOYL ESTER OF VERSATIC ACIDGLYCOLS. RESINS, AND SOLVENTS MIXTUREGLYCOL TRIACETATEGLYOXAL. 40% SOLUTIONGREASEHEPTADECANEHEPTANOIC ACIDHEPTANOL1-HEPTENEHERBICIDE (C15-H22-N02-CL)HEXAETHYLENE GLYCOLHEXAMETHYLENEDIAMINEHEXAMETHVLENEDIAMINE SOLUTIONHEXAMETHYLENE GLYCOLHEXAMETHVLENEIMINEHEXANOLl-HEXENEHOG GREASE2-HYDROXYETHYL ACRYLATEISOBUTYLAMINEISODECALDEHYDEISODECYLACRYLATEISODECYL ALCOHOLISOHEXANEIsoaCTALDEHYDEISOPHORONE DIAMINE


oETG 0EBA 0ECY 0

oETC 0EGY 0

o. 'EMA 0

oD

EHA' 0o

EHX 0EAt 0EHM a

oEHT DETM 0EPA aETE D

DGOC 0

oDDDD'

GaS DDD

HEP 0HTN 0HTE'" 0

oo

HMO aHMC a

oHMI 0HXN D

i HXE 0D

HAl' ;0lAM aIDA DIAI 0rSA DIHA DIOC DIPI 0

26

TLV-TWA SEQPPM NO.

237238249250253255260261263

'268o 271

273274275276277278279281282

- 283; 284

292,302

303.. ,304

305306307308309'311312'313314315316317318319321322325332337

-338339

·340341342344

TABLE 7. CLASS 5 SUBSTANCES-OTHER HAZARDOUS CARGOS (CONT'D)


ISOVALERALDEHYDEJET FUEL: JP-3JET FUEL: Jf1-4JET FUEL: JP-5 <KEROSENE, HEAVY)LACTIC ACIDLARDLATEX, LIQUID SYNTHETICLIGUIFIED NATURAL GAS <OR ~PG)

MAGNESIUM NONYL PHENOL SULFIDEMAGNESIUM SULFONATEMALEIC ANHYDRIDE COPOLYMER2-MERCAPTOEENZOTHIAZOLE <SOLUTIONS)~METHOXYTR I GL YCOLMETHYL ACETOACETATEMETHYL-T-BUTYL ETHER2-METHYL-5-ETHYLPYRIOINEMETHYL FORMAL2~METHYL-2-HYOROXY-3-BUTYNE

METHYL NAPHTHALENE2-METHYL PENTENE2-METHYLPYHIDINEl-METHYLPYRROLIDONEMONOCHLOROTETRAFLUOROETHANEMONOCHLOROTRIFLUOROMETHANEMONOISOPROPANOLAMINENAPHTHENIC ACIDNITROGEN, LIGUIFIED2-NTTROPHENOLNONANOIC ACIDNONANOIC-TRIDECANOIC ACID MIXTURENONENEl-NONENENONYL ALCOHOL

.NONYL PHENOLNONYL PHENOL <ETHOXYLATED)NONYL PHENOL SULFIDE <301. OR LESS)OCTADECENEOCTADECENEAMIDE <OLEAMIDE)OCTENEOCTYL ACETATEISO-OCTYL ALCOHOLN-OCTYL ALCOHOLOCTYL EPOXYTALLATEOIl: CLARIFIEDall: DIESELOIL, EDIBLE: BEECHNUTOIL, EDIBLE: CASTOROIL, EDIBLE: COCOA BUTTEROIL, EDIBLE. COCONUTOIL, EDIBLE: COCONUT OIL, ESTERIFIEDOIL, EDIBLE: COCONUT OIL, FATTY ACID


IVA aJPT 0JPF DJPV. DLTA D

oLLS DLNG a

DDD

MBT 0MTG D

DMBE DMEP aMTF 0MHB 0MNA DMPN DMPR 0MPY DMTE aMCM O.MPA aNTI 0NXX aNTP 0

DD

NON DNNE 0

DNNP D

DDDDDDoD

OET 0OCF 0ODS 0

DOCA D

Dacc D

Do

27

TLV-TWAPPM

SEGNO.

352354355356358359360363364365367369374376385389390393397398399400404405407420425427436437438439440441442443444445447448449450451453455456457458459460461

TABLE 7. CLASS 5 SUBSTANCES~OTHER HAZARDOUS CARGOS (CONT'D)


OIL, EDIBLE: COCONUT OIL, METHYL.ESTEROIL, EDIBLE: COD LIVEROIL, EDIBLE: CORNOIL, EDIBLE: COTTONSEEDOIL, EDIBLE COTTON SEED FATTY ACIDOIL, EDIBLE: FISHOIL, EDIBLE. GRAPESEEDOIL, EDIBLE: GROUNDNUTOIL, EDIBLE: HAZELNUTOIL, EDIBLE. LARDOIL, EDIBLE. MAIZEOIL, EDIBLE MUSTARD SEEDOIL, EDIBLE: NUTMEG BUTTEROIL, EDIBLE: OLIVEOIL, EDIBLE: PALMOIL, EDIBLE PEANUTOIL, EDIBLE: POPPYOIL, EDIBLE: RAISIN SEEDOIL, EDIBLE: RAPESEEDOIL, EDIBLE: RICE BRANOIL, EDIBLE: SAFFLOWEROIL, EDIBLE: SALADOIL, EDIBLE: SESAMEOIL, EDIBLE: SOYA BEANOIL, EDIBLE: SOYBEAN (EPOXIOIZED)OIL, EDIBLE: SUNFLOWER SEEDOIL, EDIBLE: TUCUMOIL, EDIBLE: VEGETABLEOIL, EDIBLE: WALNUTOIL. FUEL: NO. 2OIL, FUEL: NO. 2-DOIL, FUEL: NO. 4OIL, FUEL: NO. 5OIL. FUEL: NO. 6OIL, MISC: ABSORPTIONOIL, MISC: ANIMALOIL, MISC: CASHEW NUT SHELLOIL, MISC: COAL TAROIL, MISC: CROTONOIL, MISC: GAS, LOW POUROIL, MISC: GAS, LOW SULFUROIL, MISC: LANOLINOIL, MISC: LINSEEDOIL, MISC: MINERAL SEALOIL, MISC: NEATSFOOTOIL, MISC: OITICIAOIL, MISC: PENETRATINGOIL, MISC: PERILLAOIL, MISC: PILCHARDOIL, MISC: PINEOIL, MIse: RANGE


DDD

OCSD'0

OFS 0DoD

OLD DDoD

OOL 0OPM DOPN D

DDDo

OSF DDo

OSB 0'D .

DOTC DOVG 0

DOTW DOTD DOFR DOFV DOSX DOAS 0

oOCN 0OCT DOCR D

Doo

OLS 0OMS 0ONF 0

oOPT D

ooo

ORGD'

28

TLV-TWAPPM

SEGNO.

462463464465466467

-468469470471472473474475476477478479480481482483484485486487488489490493494495496497498500503505506507508510511514516517518519520521522

TABLE 7. CLASS 5 SUBSTANCES-OTHER HAZARDOUS' CARGOS (CONT'D)



SEGNO.

OIL, MISC: RESIDUALOIL MISC: RESINOIL, MISC: RESINOUS PETROLEUMOIL, MISC: ROADOIL, MISC: ROSINOIL, MISC: SEALOIL, MISC: SOAPSTOCKOIL, MISC: SPERMOIL, MISC: SPINDLEOIL MISC: SPRAYOIL, MISC: TALLOIL, MISC: TALL, FATTY ACIDDIL, MISC: TANNER'SOIL, MISC: TRANSFORMEROIL. MI SC: TUNGOIL, MISC: TURBINEOIL, MISC: I-JHALEOIL, MISC: 1,.1000

'OLEIC ACIDOLEYL ALCOHOL (OCTADECANOL)ORGAN I C AM I ~JE 70PENTACHLOROETHANEPENTADECANOL1, 3-PENTADIENEPENTAETHYLENE GLYCOLt-PENTENEPETROLATUMPHOSPHORIZED BICYCLIC TERPENEPHTHALATE PLASTICIZERSPINENEPOLYALKENVL SUCCINIC ANHYDRIDE AMINEPOLYAMINE, AMIDE MIXTUREPOLYBUTENEPOLYETHYLENE GLYCOLPOLYETHYLENE POLYAMINESPOLY I SOBUT''r'LENEPOLYMERIZED ESTERPOLYPROPYLENEPOLYPROPYLENE GLYCOLPOLYPROPYLENE GLYCOL METHYL ETHERPOLYSTYRENE DIAL~YL MALEATEPOLYVINYLBENZYLTRIMETHYL AMMONLUM CHLORIN-PROPANOLAMINEPROPIONIC ANHYDRIDEPROPYL BENZENEPROPYLENE BUTYLENE POLYMER

, PROPYLENE GLYCOLPROPYLENE POLYMERPROPYLENE TETRAMERPROPYLENE TRIMERRUM

DRS

. OROORN

OSPOSOOSYOTL

OTNOTF

OTB

OLA

peEPOCPDI

PTEPTL

PLB

PEB

PLPPGC

. PGM

PVBPL~

PAH

PBPPPG

PTT

o0,oooooDDoooDoooDoooDoDooDDooooDDoooD

·0'0oDoooooooooo

523524525526527528529530531532533534535536537538539541542544545549550551552554556559561563564565566567568569570572573574575576578581586588589592593594597

29

TABLE 7. CLASS 5 SUBSTANCES-OTHEg HAZARDOUS CARGOS (CONT1D)


SODIUM ACETATE, GLYCOL. WATER SOLUTIONSSODIUM BOROHYDRIDE <13%)SODIUM CHLORATE <50% OR LESS)SODIUM HYPOCHLORITE SOLUTION «=15%)SODIUM 2-MERCAPTOBENZOTHIAZOLSOLUTIONSODIUM SULFONATESTEARIC ACIDSTEARYL ALCOHOL <OCTADECANOL)SULFOLANESULFURTALLOWTALLOW FATTY ALCOHOLTALLOW NITRILETETRADECANOLl-TETRADECENETETRADECYLB£NZENETETRAETHYLENE GLYCOLTETRAETHYLENEPENTAMINETETRAHYDRONAPHTHALENETETRAPROPYL BENZENETOLUENEDIAMINETRIARYLPHOSPHATETRIDECANETRIDECANOIC ACIDTRIOECANOLl-TRIDECENETRIDECYL BENZENETRIETHANOLAMINETRIETHYLBENZENETRIETHYLENE GLYCOLTRIETHYLENE GLYCOL DIETHY[ BUTYRATETRIETHYLENE GLYCOL MONOMETHYL ETHERTRIETHYLENETETRAMINETRIETHYL PHOSPHATETRIISOOCTYL TRIMELLITATETRIISOPROPANOLAMINE2,2.4-TRIMETHYL PENTANEOIOL-l,3-0IISOBUTTRIMETHYLACETIC ACIDTRIMETHYL HEXAMETHYLENE OIAMINE<224.244)TRIMETHYL HEXAMETHYLENE OIISOCYANATE2.2.4-TRIMETHYL-3-PENTANOL-I-ISOBUTYRATETRIPROPYLENETRIPROPYLENE GLYCOLTRIPROPYLENE GLYCOL MONOMETHYL'ETHERTRIXYLONYL PHOSPHATEUNDECANOLl-UNDECENEN-UNDECYLBENZENEVINYL ACETATE, FUMARATE COPOLYMERVINYL ETHYL ETHERVINYL NEOOECANATE


oSBI 0SOD 0SHP" '05MB 0

DSRA 0

oSFL 0SXX 0TLO 0TFA 0

D'TTN DTTD DTOB 0TTG DTTP 0THN 0

DTOA 0

ooo

TON DTDC 0

DTEA 0TEB . DTEG 0

Do

TET 0DD

TIP 0o

TAA 0THA 0THI 0

oD

TGC DDD

UNO DUDC D'UDB D

oVEE 0VND 0

30

TLV-TWAPPM

SEGNO.

601602604607608609610611613614618619620622623624625626628629632636643644645646647648650651652653654655656657658659661662663665666667668671672673678680682

TA~LE,7. CLASS 5 SUBSTANCES-OTHER HAZARDOUS CARGOS (CONT'D)

20-DEC-85CHEMICAL N/,j"IE

WAX: CANDELILLAWAX:, CARNAUBAWAX: PETROL.EUMWINEWOOL GREASEXYLENE PARASOLXYLENOL



DWCA D

,DDDD

XYL 0

31

TLV-TWA SEGPPM NO.

684685687691692696697

TABLE 8. CLASS 6 SUBS"rANCE'S-NONCARGO SUBSTANCES WITH Toxi C HAZARD

20-DEC-85CHEM ICAL NAME :>: '.; ,

ASBESTOS--AMOSITEASBESTOS--CHRYSOTILEASBESTOS--CROCIDOLITEASBESTOS--OTHERBERYLLIUMCADMIUMCARBON MONOXIDECHROMIUM (VI>FLUORIDESHYDROGEN SULFIDELEAD DUSTLEAD FUMESMANGANESE (FUME)MERCURYNICKELNITROGEN OXIDESOZONEPAINT PIGMENTS (DRY)SANDSILICATITANIUMVANADIUMWELDING FUMESZINC


CHRIS CFR OTHER TLV-TWA SEGCODE ROUTE PPM NO.

0, 5 F/CC 0322 F/CC 033

O. 2 F/CC 0342 F/CC 035

,002 MG//'13 0470.05 MG//'13 081

50 0920.05 MG/M3 114

2. 5 MG/M3 28610.0 3310.15 MG/M3 3610.15 MG/M3 362

1.0 MG//'13 3680.05 MG/M3 370

1.0 MG/M3 421:3 426

0.1 5461.0 MG/M3 5470.3 MG/M:3 598O. 3 MG//'13 5995. 0 MGIM3 630

0, 05 MGIM3 6765. 0 MG/M3 6885. 0 MGIM3 698

32

III. HSDS PROGRAM

A computerized data base of the hazardous substances data was createdto more effectively and mor~ easily manage thii large volume of information.A system was needed which wou'ld allow a user to extract, change, delete or adddata in a logical manner. As a result, a set of small computer codes has beenwritten to develop and utilize the hazardous substance data system (HSDS).

III.l Code Description

All computer programs written and used t~ initially create the database and currently manage it are in th~ FORTRAN 77 language. The programs arepresently run on a Digital Equipment Corporation (DEC) PDPllj70 centralprocessor unit with the RSX-11M operating system. However, the two codesnecessary to manage the data base should be easily adaptable to other machi~es

with FORTRAN 77 compilers and 64K word memory. The data files which containthe data base itself require 2.4 megabyte disk storage space.

As mentioned earlier, the, HSDS program consists of a set of relativelysmall computer codes. All but two of the codes were used on~y in theinitialization of the data base and are no longer necessary to accessor manage the data. The two remaining codes, CGEDIT and CGTAff, will bedescribed in-detail in this section;· Theit~basic functions are to change d

data base entry in some way and to create a tabular listing of entries whichhave been sorted by some common characteristic.

111.2 HSDS Program Utilization

The databas~ itseff resides in 26 separ~te direct access files denotedCG$$.DAT, where $$ ranges from ~l to 26. The information contained in thefiles corresponds to 26 columns of data which can be accessed by the HSDSprograms. The columns correspond to the 22 substance characteristicsdescribed in Section II with an additional column for storing a sequence oridentification number for each substance in the data base and three additionalcolumns of information used internally during the development of the data base

33

but not discussed in this repo.rL·, ,Acee·ss to,the information in the data base~ ." - :,'." ~ I

is acquired using the two computer codes, CGEDIT and CGTAB.

; ~ .

Program CGEDIT is the ma,;,n, ,editor, of the. data ,base. It i,s used ,to

change stored tr'1formation about a su~stance. Three opti.o~sar.e,available:

1) del ete an .ent i r,e data.base r~cord,

2) change one or more single entries (columns) in a data base record,

or 3) add one or more new records to the data base.

(As discussed here, a record refers toa~omplete s,etof inform~tion about one

hazardous substance. E.ach record contains 26 entr.ies, or columns as described

in Table g.) , Each option require~ input of .the sequenc~ oridentificatiQn

number of the record to"de 1et~, change, or a~d a .record behi nd it.. A1-1., ..

changes are made permant:!~t to the, data base, s.o the old files should be saved,

in o~her files as a backup system before begiryning a se~sio~ with the ~ditor .

program. . .' ,- ~

In order to view chal1ges mad~wi~h 'C,GED~T or,create,any-: kind of.

sorted list of items in the ~ata base, program CG!AB must, be utiljzed.This program allows the user to .obtain a tabular .listingof the entire data

. ..' - - . '. - .. .

base or a listing of a certain portion of the data.~ase whicr.,hasc0lJ1!l10n ,

characteri st ics. The program cre~tes a table by; sort i l1g:,thrp.u~h all dat,a

base records to match a user-requested. characteristic value. ' Thel,lse,r then• '-' - • • I ., ( , " ,.~' • • •

inputs which entries (columns) are des,ired, to be ,included, in a table •. The.• ,'. I". '.' _ ., t ' . ••

number of printed column entries cannot exceed 132 characters in length.

If the user requests a tab le pri ntout which exceeds. t~,i s. ,1el1gth~:,an, ~rror< ".

is transmitted. The program creates the table by extracting from each data

base file the informati9n corre~ponding to those records which were.

identified in the sort, and storing, the data in.a file na,med ~TAB,.DAT.

. ,. ~,

34

TABLE 9. "IDENTIFICATION NUMBERS FOR DATA BASE RECORDS

IdentificationNumber

1

2

3

4

5

6

7

8

9

10

11.

12

13

14

15

16

17

18

19

20

21

2223

2425

26

Data Base Record Abbreviation*

CHEMICAL NAMECHRIS CODECFROTHER ROUTE

. TLV- TWA PPMSTEL PPMIDLH PPMODOR PPMCS PPMCS/TWATaX CODE·CARC REFSEQ NONFPA NASAIR DATA (not used in this report)QUAN CODE (not used in this report)SEC PRODCASEMRSP. GUIDEMSDS (not used in this report)BIO MEDNIOSH GUIDEBIO MaNQUAL DTQUAN DTTlV DT

*Described in Table 1 and discussed in Section 11.2.

35

Sorting on a.column is; accompHs~edJ~y_;cqmpar.ing ,each record entry in thecolumn to a check value using one of the following logical operators:

Operator .., . Jqu,valefit~Symbol _ Description

.EQ. . "',=,~ :' (" Equal

. LT. <. Less than ,

.GT. > Greater than• LE. < Less than or equal

.GE. >: Greater than or equal

.NE. t- Not equal

Multiple sorts are possible by inputting successive check values andoperators. The final entries in the table written to file CTAB.DAT are1) a designation of the number of records in the table and 2) an optionalprinting of several footnotes about the overall data base. ' The latterentry is usually printed when a table of the entire data base is requested.

A brief overview of the two programs necessary to manage the HSDS hasbeen preserited in'this Section; It is intended to describe the contents ofthe data base and the options~vailable for accessing these contents, but isnot p~esented as a complete user'~g~ideto the HSDS. Listings of computercodes CGEDIT and CGTAB are, however, intluded in Appendix A to demonstrateprogram flow.

.' ",

36

REFERENCES

1. Prevost, R. J. and Johnson, Q. E., A Medical Monitoring Program for theMarine-Hazardous Chemical Worker, Volume I, Task III Final Report; SwRI

- Project 06-7223, USDOT Contract DTCG23-82-C-20027, July 1985.

2. Prevost, R. J. and Hammond, J. W., Biochemical and Medical Informationfor Marine Hazardous Substances, Volume III,Task III Final Report, SwRIProject 06-7223, USDOT Contract DTCG23-82-C':'20027, July 1985.

3. TLVs, Threshold Limit Values for Chemical Substances and Physical Agentsin the Work Environment with Intended Changes for 1983-84, The AmericanConference of Governmental Industrial Hygienists, Cincinnati, Ohio, 1984.

4. Listing of All Chemicals' Regulated in the CFR, U. S. Coast Guard, Cargoand Hazards Branch, 19 May 1983.

5. Chemical Data Guide for Bulk Shipment by Water, United States Coast GuardDocument CIM 16616.6, 1982.

6. NIOSH/OSHA Pocket Guide to Chemical Hazards, U.S. Department of Health. and Human Services,·Natio~al Institute for Occupatio~al Safety and Health

Publicati6n No. 78-210, 1978.

7. Hellman, T. M. and Small, F. H., Characterization of the Odor Propertiesof 101 Petrochemicals Using Sensory Methods, J. Air Pollution ControlAssociation, 24:979-982, 1963.

8. Amoore, J. E. and Hautala, E., Odor as an Aid to Chemical Safety: OdorThresholds Compared with Thresholds limit Values and Volatiles for 214Ind. Chemicals in Air and Water Dilutions~ J. Applied. Tox., Vol. 3,No.6, pp. 272~290, 1983.

9. Vershreven, K. A., Handbook of Environmental Data on Organic Chemicals,Van Nostrand Reinhold, New York, New York, 2nd Edition, 1983.

37

10. Personal Communication with>P,rofess.or J. W. Hammond, C.I.H., University

of Texas School of Public Health, Houston, Texas, 1984.

."", .,

11. ' Letter, from Commande,~, !J. F. i.McGowan,:: ,Ch,ief ,Cargo andH4,zards Branch,

U. S. Coast Gu~rd, ',to Mr. ~J. 'Chr,istopher Bucki'ngham, S,outhwest ',Research

Institute, dated August 17, 1984.

.' ,

12. Reg is try ,of Toxi c Effects of,,~hem;cal Substances" U·. S. Department of

Health and Human Servi!ces, National Institute for,OccupationaLSafety andL '" , " , '.,..'.' , ',- , "

Hea lth, 1980.

, '" .~'!. '::

1~.fjre ,Protection Guide on Hazard,ous, Mater,i,als, Code 704M, 4th edition,

Nati.onal Fire Protection.. AS,sociiition", Boston, Mass., 1972,. _:'

14. Eva]uation o,f thee Hazard of Bulk Water Transp.ortation of -Industrial

Chemicals, A Tentative Guide, National Academy of,-$ciences', Committee on

Hazardous Materials, Washington~ D.C., 1972.

15. 1984 Emergency Response Guidebook, U. S. Department ,of ,Transportation,

Document No. DOT P 5800.3, 1984.

~-, .. ~ I ,

16." Occupational Health,Guiqelines for Chemical: HQzards, U. S •.,Department of

Health and Human Services, National Institute'fl?r,OcclJpatior:JCilSafety and

Health. Publication No. 81-213. 1981.

'~ , . !" '

17. Communi ca t.ion ,with, LCDR R.,- J. Rrosser-, USCG Hazardou~~ateri a1s, Br(l.nch, ' '. I'. ' '

(G-MTH-l), Washington, D.C., November ~985.,'·;' ,

'\ -' -l ":, 1".

"

o , •

:' -

" /. •• • ~ " •• I'. .... "0',

. -"',', ..

-. ..'.~

....,.• • I r. ;, '. ~ ~. ,.; _. : '. ~ :

",,' " ~ -

38

':", • ,l ~ •

APPENDIX A

listing of Hazardous Substances Data

A-I

LISTING OF HAZARDOUS SUBSTANCES DATA

This appendix presents the data currently being maintained in theHSDS. Three tables of data are provided. Tables A-I and A-2 present acomplete set of data for Class 1 and Class 2 substances, respectively. Amaster listing of the complete set of data for all classes of substances ispresented in Table A-3.

In each of the tables, the data are presented alphabetically, bychemical name, with data for the first ten substance characteristics (aslisted in Table I and discussed in Section II of the text) on one pagefollowed by data for the remaining substance characteristics on the secondpage. The chemical name is presented on both pages for convenience. Thus,for any specific chemical substance, the location in the table is determinedby searching the listing alphabetically, with the data for that substancebeing found on two adjacent pages.

A sequence nUr1)ber (SEQ ;Np.:) is ·indicated with each 1i ne of data. In themaster listing, Table A-3, the sequence numbers begin with 001 and proceedconsecutively to 699. This same sequence number is presented with the datafor a given substance in Tables 3-8 in the main body of this report, and inTables A-I and A-2 of this appendix.

The data presented in Tables A-I and A-2 for a given substance areidentical to the data for that substance presented in Table A-3. The purposeof this duplication is to provide the dat~ for Class I (Table A-I) and Class 2(Table A-2) separately because of the importance placed on these two classesof substances.

20-DEC-B5CHEMICAL NAI'IE CHR IS CFR OTHER

CODE ROUTE

:>I

<.oJ

ACRYLONITRILE ACNBENZENE BNZBENZENE HYDROCARBON MIX (> OR • lOX BEN) BHBBENZENE HYDROCARBON "IX (WITH ACETYLENE) BHABENZENE. TOLUENE. XYLENE "I XTURE BTlBUTADIENE (1.3 BUTADIENE) BDIBUTADIENE. BUTYLENE "IX WITH ACETYLENES BB"CARBON TETRACHLORIDE CBTCHLOROFOR" CRFETHYLENE DIBROMIDE ED8ETHYLENE OXIDE EOXETHYLENE OXIDE. PROPYLENE OXIDE "IXTURE EP"FORtW..DEHYDE SOLUTION FftSNITRDPROPANE (1-. 2-. AND "I'XTURES' NP"2-NITROPAOPANE NPPNITROPROPANE (60X). NITRDETHANE (40%) NNMo-TDLUIDINE TLIVINYL CHLORIDE VC"

TOTAL OF 18 lTE"(S) IN TABLE

o SKINooooooo SKINoo SKINooooooo SKINo

20-DEC-85CHEMICAL NAME TOX CARC NFPA SEC CAS EMRSP BID NIOSH BIO QUAL QUAN TLV SEQ

CODE REF NAS PROD QUIDE MED QUIDE MON DT DT DT NO.

ACRYLONITRILE 1 Al 4313 107-13-1 X U DC DQ 011BENZENE 1 A2 2113 71-43-2 27 X U DQ DC 040BENZENE HYDROCARBON MIX () DR = lOX BEN) 1 A2 ---- D D 041BENZENE HYDROCARBON MIX (WITH ACETYLENE) I A2 ---- D 042BENZENE. TOLUENE. XYLENE MIXTURE 1 A2 -113 27 D 044BUTADIENE (1.3 BUTADIENE) 1 A2 2111 106-99-0 17 X X DC 050BUTADIENE. BUTVLENE MIX WITH ACETVLENES I A2 ---- D 051CARBON TETRACHLORIDE 1 A2 3214 56-23-5 55 X X DC DC 093CHLOROFORM 1 A2 2212 67-66-3 55 X X DC DQ 103ETHYLENE DIBROMIDE 1 A2 3113 106-93-4 55 X X DC 257ETHYLENE OXIDE 1 A2 2332 75-21-8 69 X DC G 269ETHYLENE OXIDE. PROPYLENE OXIDE MIXTURE 1 A2 ---- 26 D 270FORMALDEHYDE SOLUTION 1 A2 2323 50-00-0 29 )( DC DG 287NITROPROPANE (1-. 2-, AND MIXTURES) 1 A2 ---- 26 4292-NITROPROPANE 1 A2 1111 79-46-9 26 X 430NITROPROPANE (bOX). NITROETHANE (4070) 1 A2 ---- 26 431O-TOLUIDINE 1 A2 3--- 95-53-4 55 X Q 635VINVL CHLORIDE 1 Al 2212 75-01-4 17 X DG DQ 679

",TOTAL OF 18 ITEM(S) IN TABLE

-I::t>c:cr\'TI

::t>I

.1--'

"

.. 0::t>

'.-1:::t>

;-' ..~.~

"cAl

,n,ro '::t>

J~, .1--'

, '- .. j ~

• ~ I ' .~ .,t"· ...

c-'"

.... ,...

(nc:

.-c:c· .V1· -l· ::t>:zn

· \'TI, V1

n.0:z-l

b

'-' ,

~--

",;,.:

.'......~, ~.;

.~.:: ~

:_.~

"

. ,',

',"'".

.;,t

.::,.' ~~i

-~~

, ".~.

., .... '

'" '"; f-,,': :~

. ,'..~

',';,

", ;>

''',

.". Of,',;

. ,

\~'-'" :,"::

,~~, I. '_ 1';'

.;::; I ., _~ .. -

- .~ " ::; ,

.. ~: ;--~

..... Z':.

-' ~

:- ~ ..'..'"

::t>I~

-i'" t .. ~' . t!" ,'."j ."!,"

:;-.-

• '. 1. ~-.

- ~~ .. ~'" .

,'-j .'.;

~ ~ .;

'"to

t. .':~ .' ..

"::" .: ~ ;.';T'

r", " "

,,_7. .' ~'~

20-DEC-85CHEMICAL NAME CHRIS CFR OTHER TLV-TWA STEL IDLH ODOR CS CS/TWA SEG

CODE ROUTE PPM PPM PPM PPM PPM NO.

ACETONE CYANOHYDRIN ACY 0 SKIN O. 25 1. lE3 4.2E300SALLYL ALCOHOL ALA 0 SKIN 2 4 150 O. 78 2. 2E4 1. lE4 019ALLYL CHLORIDE ALC 0 1 2 300 0.213.9ES 3. 9ES 020AMMONIA, ANHYDROUS AMA 0 25 35 500 4.21.0E6 4.0E4024ANILINE ANL 0 SKIN 2 5 100 1. 0 7.9E2 4. OE2 031BENZYL CHLORIDE BCL 0 1 10 0.4 1. 2E4 1.2E4 046BUTYLAMINE (ALL ISOMERS) BTY 0 SKIN C5 2000 0.24 2.9E5 5. 7E4 061N-BUTYLAMINE BAM 0 SKIN C5 I.B LIES 2.2E4062SEC-BUTYLAMINE BTL 0 SKIN C5 1.8E5 3. 7E4 063TERT-BUTYLAMINE BUA 0 SKIN C5 4. 5E5 B.9E40b4 --l

):>CARBON DISULFIDE CBB 0 SKIN 10 500 0.13.9E5 3.9E4091 c:JCHLORINE CLX 0 1 3 25 0.351.0E6 1.0E6 100 r-CHLOROSULFONIC ACID CSA 0 1 109 m

CROTONALDEHYDE CTA 0 2 6 400 0.23.9E4 2.0E4122 ):>

2.2'-DICHLOROETHYL ETHER DEE 0 SKIN 5 10 250 15.0 5.3E2 1. lE2 148I

NDICHLOR0P10NOFLUOROMETHANE DFI'I 0 10 150.0 1.0E6 1. OE5 1511,3-DICHLOROPROPENE DPU 0 SKIN 1 10 1. 5 1. 4E5 1. 4E5 156DICHLOROPROPENE (1,1- 1,2- 1,3- AND I'IIX) DPS 0 SKIN 1 10 1.5 157 0DICHLOROPROPENE,DICHLOROPROPANE I'IIXTURE) DI'IX 0 SKIN 1 10 1.5 158

):>--4

DIISOPROPYLAMINE DIA 0 SKIN 5 1000 0.49.2E4 1. BE4 191 ):>

DIMETHYLAl'liNE DMA 0 10 2000 0.051.0E6 1.0ES 194 "T'\DII'IETHYLAI'IINE SOLUTION (45% OR LESS) DI'IQ 0 10 2000 195 0DIMETHYLAI'IINE SOLUTION ()45X AND <-55%) DMY 0 10 2000 4.2E5 19b ::0DIMETHYLAI'IINE SOLUTION (55% AND <69%) DI'IC 0 10 2000 197 ("')

1,4-:DIOXANE DOX 0 SKIN 25 100 200 I.B 3.6E4 1.4E3207 r-):>

DIPHENYLl'lETHANE DIISOCYANATE DPI'I 0 CO. 02 20 6.6El 212 VI):> EP i CHLOROHYDR IN EPC 0 SKIN 2 5 100 0.93 1. 6E4 8.0E3228 VI

I ETHYLAl'lINE EAI'I 0 10 4000 0.83 1. OE6 I.OE5 242 NU1 ETHYLAP1INE (40% DR LESS) EAO 0 10 4000 0.83 243 VIETHYLAP1INE (72X OR LESS) EAN 0 10 4000 0.83 244 c:::

ETHYLENE DICHLORIDE EDC 0 10 15 1000 40.0 1.3E5 1.3E4258 c:JVI

QLUTAAALDE~DE (SOX OR LESS) OTA 0 CO.2 0.042.2E4 1. IE5 300 --4HYDROCHLORIC ACID HCL 0 C5 100 1.02.8E5 326 ):>

:zHYDROFLUORIC ACID HFA 0 3 6 100 0.04 328 ("')

HYDROGEN CHLOR I DE . HOC 0 CS 100 1.01.0E6 2.0£5 329 I'TIVIHYDROOEN FLUORIDE HFX 0 3 6 20 0.04 I.OE6 3.3E5330

ISOPROPYLAI'IINE IPP 0 5 10 4000 O. 7 6. IE5 1. 2E5 349ISOPROPYLAP1INE (90% OR LESS) IPO 0 5 10 4000 O. 7 350METHYLAMINE SOLUTION (42% OR LESS) I'ISZ 0 10 100 0.02 1. OE6 I.OE5 380METHYL BRO!'lIDE !'ITB 0 SKIN 5 IS 2000 0.23 1. OEb 2.0E5383METHYL CHLOR IDE I'ITC 0 50 100 1000 1.0Eb 2.0E4386MOTOR FUEL ANTIKNOCK CI'IPDS (PB ALKYLS) I'IFA 0 SKIN O. 10 I'IQ/1'I3 40 0.26.6E3 409NITRIC ACID NAC 0 2 4 100 4.3E4 2.2E4422NITRIC ACID (70% OR LESS) NCD 0 2 4 100 4. 3E4 2.2E4423NITROBENZENE NTB 0 SKIN I 2 200 0.02.bE2 2.6E2424PHENOL PHN 0 SKIN 5 10 100 0.2 4.7E2 9.4E1557PHOSPHORUS, WHITE PPW 0 O. I I'IG/1'I3 0.3 MG/M3 560PROPYLENE OXIDE POX 0 20 2000 65.05.9E5 2.9E4591STYRENE STY 0 50 100 5000 O. IS 6.6E3 1. 3E2 612SULFUR DIOXIDE SFD 0 2 S 100 1. 0 1. OE6 5.0E561S1,1.2,2-TETRACHLOROETHANE TEC 0 SKIN 1 5 150 2.6 1. 7E4 1.7E4 621

20-DEC-85CHEMICAL NAME TOX CARC NFPA SEC CAS EMRSP BID NIOSH BID QUAL QUAN TLV SEQ

CODE REF NAS PROD GUIDE MED GUIDE MON DT DT DT NO.- :,

ACETONE CYANoHVDRIN 2 4124 75-86-5 55 G 005,ALLVL ALCOHOL ,2 3323 107-18-6 28 X X D 019ALLVLCHLbR IDE 2 3323 107-05-1 ' 28 X X 020AMMONIA. ANHYDROUS ,2 ,3422 7664-41-7 15 X X DG DG'024

'ANILINE, ,2 ,3113 62-53-3 57 X X U DG DG 031BE,NZ'YL: C.-,LoR I DE :d 2442 100-44-7 59 X DG G :046

,BUT,VLA,MINE (ALL ISOMERS) ,)2 -344 "109-73-9 68 X I) 061 -i, , N-BUTVLAMINE " ' 2 " .2444 :t09'-7~9 68 X DG G 062 :t::o~EC-BUTVLAMINE .~ 3344 .109-73-9 '68 0 063 C:J

-" r-,'TER"f-BUTvLAMiNE 2 ----- ;109-73-9 68 0 064 I"Tl

, CARBON DISULFIDE 2 2223 ' 75-15-0 28 X X DG DG 091' .

:t::oCHLoR I~E' ", , , ," _,2 3424 7782-50-5 20 X .x DG DG 100 I

CHLOROSUlFONICACIO .,2 3444 HCL 7,790-94-5 39 D 109 N

<:ROTONlli...DEHYDE ,2 3333 123-73-9 28 X X D 1222;2 '';'''DICHLOROETHVL ETHER .;2 -323 111-44-4 57 X X:, 148 0

< IJICHLOROMONOFLUOROMETHANE ,;;2 ---- 75-43-4 12 X X 151 :t::o• 1. 3':'0 I CHLOROPROPENE 2 -223 542-75-6 29 X 156 '-i

'DrCHlOROPROPENE (1.1- J.2- 1.3- AND MIX) 2 542-75-6 " ::t::o---- 29 157 . -, ,~~r. ~(

D·ICH.LljROPROPENE~DICHLOR'oPROPANE MIXTURE)' ,2,'"., , ".'"---- 8003-19-8 29 158''mr ;.'(. ·.. ·0

OIISOPROPVLAMINE ",2., 3324 "108-18-9 68 )( X G 191 i ';0

. DIMETHVLAMINE' ','; 2 3222 ',124-40-3 19 X X DG' G 194.. '

OtMETHYl~MINE SOLUTION <45% OR LESS) 2 ·124-40-3 26 0'" ~:~."

;;\ ,.::-,~: ',M---- r-

/DiMETHvtAMINE SOLUTION (~45% AND (=55%) 2 124-40-3 26- ~ --, :t::o'----- ..

DIMETHYLAMiNE~SOLUTION (55% ANO (6~7.) 2,:. ---- 124-40-3 26 197--; -:. !: V'l

1'; '4.:.b i'OXANE'"' ." , 207~-:; " ' V'l

2 2113 123-91-1 ·26 X X DG .::' :'DIPHENYLMETHANE DIISOCVANATE. .2 -324 '101-68-8 X 212 'N

EPICHLP~OHVbR~'N .j, ·2 3334 X:, -" <.~ -\

:t::o ' ,. 106-89-8 30 X DG G'228 -:V'l

I ETHVLAMtNE .. ' ,2 3323 75-04-7 68 X'· DG G,242 ','c:.,' C:J

0'\ ETHVLAMINEH(40% OR :LESS)' ·2:, ---- .75-04-7 29 X ,'243 V'l

EiHVL.AMINE '(72% OR LESS) 2 ',75-04-7 29 X 0 2447' " _ -i

.' . :t::o,ETHVLENE QIc'H(ORIDE . 2 2223 107-06-2 26 X DG 258 Z

GLUTA.RALDi::HVD~ (507. OR.LES~) 2 ---- 111-30-8 X 0 300C'"')I"Tl

HYDROCHLORIC ACID :2 3332 7647-01-0 15 DG D 326 V'l

HVDRO':-LUOR'IC 'AbD " 2 4444 7664-39-3 15 .. G •. 328.HYDROGEN CHLORIDE' ". .2 3433 7647-01-0 1-5 X X ' 'DG DG, 329 C'"')

HVDROGEN'FLUORIDE 2 4444 7664-39-3 15 X X DG DG 330 0

ISOPROPYLAI'lINEz

2 3324 75-31-0 68 X X DG G 349 -iISOPROPyl-AMINE (907. OR LESS) 2 ---- 75-31-0 68 X 'iD ' ' 3'50 -

0METHVLAMINE SOLUTION (42% OR LESS) 2' ---- 74-89-5 68 X G G '380 '-'

METHyL BROMIDE 2 ---- ·74-83-9 55 X X DG o 383METHVL CHLORIDE 2 ., 2002 .74-87-3 18 X X 0 386MOTOR FUEL ANTIKNOCK CMPDS (PB ALKVLS) 2 78-00-2 56 4()9NITinCACID :2 2343 7697-37-2 44 X X DG OG 422NITRIC ACID '(707. OR LESS) 2 ---- 7697-37-2 44 X X 0 ,423NITROBENZENE 2 3324 98-95-3 55, X X U 424PHENOL 2, 3233 108-95-2 55 X U DG DG 557PHOSPHORUS, WHITE 2. 3-44 7723-14-0 560PROPVLENE OXIDE 2 2322 75-56-9 26 X X DG 591STVRENE 2 2222 100-42-5 27 X X UB G G 612SULFUR DIOXIDE 2 34i4 7446-09-5 16 X X DG DG 6151.1.2.2-TETRACHLOROETHANE 2 ---- 79-34-5 55 X X G 621

TOLUENE 2.4-DIISOCYANATE TDI 0TOLUENE DIISDCYANATE. DIPHENYLI'lET DIISOC TDD 0TRICHLOROETHYLENE TCL 0VINYL ACETATE VAM 0VINYLIDENECHLORIDE VCI 0


CODE ROUTETLV-TWA STEL IDLH ODOR CS CS/TWA SEQPPM PPM PPM PPM PPM NO.

.005 .02 10 0.21 1. 3El 2. 6E2 633

.005 .02 10 O. 21 1.3E1 63450 150 1000 21. 4 7.6E4 1.5E3 63910 20 5000 0.4 1. 2E5 1. 2E4 677

5 20 5000 500.0 5.3E5 1. 6E5 681

)::0I

""-J

TOTAL OF 56 ITEM(S) IN TABLEi

--I)::0C:JrI"T1

)::0 .I

N

c)::0--I)::0

"T'lo:;;0

("")rl>U"U"

NU"...

c::C:JU"--I)::0:z("")I"T1U"

("")

o:z--I

C

20-DEC-85CHEMICAL NAME TOX CARC NFPA SEC

CODE REF NAS PRODCAS EMRSP BIO NIOSH BIO QUAL QUAN TLV SEQ

GUIDE MED GUIDE MON DT DT DT NO.

:l:>I

(Xl

TOLUENE 2.4-DIISOCYANATE 2 3334 584-84-9 57 X D 633TOLUENE DIISOCYANATE. DIPHENYLMET DIISOC 2 ---- 634TRICHLOROETHYLENE 2 -112 79-01-6 74 X UB DG G 639VINYL ACETATE 2 2112 108-05-4 26 X DG G 677VINYL I DENECHLOR IDE 2 2223 75-35-4 26 X DG G 681

TOTAL OF 56 ITEM(S I IN TABLE -i:l:>OJrfTI

:l:>I

N

o.:P-i

" :P

"TJo::0

('")r:l:>VIVI

N

"VICOJ

. VI

"~:z('")fTIVI

('")o

. :z-i

o-

20-DEC-85CHEMICAL NAME CHRIS CFR OTHER TLV-TWA STEL 10LH ODOR CS CS/TWA SEG


ACETALDEHYDE AAD 0 100 150 10000 o 21 9 9E5 9. 9E3 001ACETIC ACID AAC 0 10 15 1000 0.211.5E4 1.5E3 OO?ACETIC ··ANHYDRIoE ACA 0 C5 1000 0.36 5.3E3 1. lE3 003ACETONE 'ACT 0 750 1000 20000 132. 5 2.4E5 3.2E2004ACETONE CYANOHYDRIN ACY 0 SIo\IN 0 .. 25 1. lE3 4.2E3005ACETONITRILE ATN 0 SKIN 40 60 4000 39. 8 9. 6E4 2 4E3 006ACETOPHENONE' ACP 0 1 0.6 1. 3E3 1.3E3 007ACETYL TRIBUTYL CITRATE 0 008ACRVLAMIoE (507. OR LESS) AAM 0 SKIN O. 3 MG/M3 O. 6 MG/M3 009ACRYLIC AC 10 ACR ·0 10 1.0 4 lE3 4. lE2 010 ~ACRYlONITR ILE' ACN 0 SKIN 2 4000 21. 0 1. lE5 5.5E4 011 )::>

Ao-IPONITRILE ADN 0 50 012 D:lr-

ALCOHOLS (MIXED> 0 O. 78 013 ITl

ALKENYL SUCCINIC ACID 0 014 )::>ALKENYlSUCCINIC ANHYDRIDE D 015 I

ALKYlBENZENESULFONIC ACIDS ABS 0 1 MG/M3 016 wN-ALKYL PHTHALATES D 017ALKYL SUCCINNATE FORMALDEHYDE HYDROXY AM D 018 3:ALLYL ALCOHOL ALA 0 SKIN 2 4 150 O. 78 2. 2E4 1. lE4 019 )::>

ALLYl CHLOR IDE ALC 0 1 2 300 O. 21 3. 9E5 3. 9E5 020 l/)

~2-(2-AMINOETHOXY)ETHANOL AEX 0 021 ITlAMINOETHYLETHANOLAMINE AEE 0 022 :::0

N-AMINOETHYLPIPERAZINE AEP 0 023 r-AMMONIA. ANHYDROUS AMA 0 25 35 500 4.2 1. OE6 4.0E4024

,.;...l/)

AMMONIUM HYDROXIDE. 28 PERCENT AG. P\MH 0 200 500 47.0 025 .....N-AMYL ACETATE Ai'lL D 100 150 4000 0.155.3E3 5. 3El 026 .....

z)::> N-AHYL ALCOHOL AAN D 100 O. 12 3.7E3 3. 7El 027 Ci)I AMYLENE D 5. 3E5 028 0\0 N-AHYL HETHYL KETONE AHIo\ 0 50 100 3. 4E3 6. 8El 029 "'T1

AMYL TALLATE D 030 :::I:ANILINE ANL 0 SIo\IN 2 5 100 1.0 7.9E2 4. OE2 031 l/)

ASBESTOS--AMOSITE 0.5 F/CC 032 Cl/)ASBESTOS--CHRYSOTIlE 2 F/CC 033

ASBESTOS--CROCloOLITE 0.2 F/CC 034 C)::>ASBESTOS--OTHER 2 F/CC 035 -"l

ASPHALT ASP D 5 HG/M3 10 HG/M3 036 )::>

ASPHALT BLENDINQ·STOCIo\S: ROOFERS FLUX ARF 0 5 MG/H3 10 MG/M3 037ASPHALT BLENDING STOCKS: STRAIGHT RUN RE ASR D 5 MG/1"I3 10 MG/M3 038BEHENYL ALCOHOL D 039BENZENE BNZ 0 10 25 2000 2.09.9E4 9, 9E3 040BENZENE HYDROCARBON MIX () OR = 107. BEN) BHB 0 10 25 041BENZENE HYDROCARBON MIX (WITH ACETYLENE) BHA 0 10 25 042BENZENESULFONYL CHLORIDE BSC 0 5. 3El 043BENZENE. TOLUENE. XYLENE MIXTURE BTX 0 10 25 2000 0.019.9E4 2. OE4 044BENZYL ALCOHOL BAl D 045BENZYL CHLORIDE BCl 0 1 10 0.4 1. 2E4 1.2E4 046BERYLLIUH .002 MG/M3 047BICYCLIC TERPENEL POlYAHINE AMIDE SALT 0 048BISPHENOl A DIGLYCIDYL ETHER BDE D 049BUTADIENE (1.3 BUTADIENE) BDI 0 10 15 20000 0.4 1.0E6 1.0E3 050BUTADIENE. BUTYLENE MIX WITH ACETYLENES DBM 0 10 15 20000 051

20-DEC-85CHEMICAL NAME TOX CARC NFPA SEC CAS EMRSP BID NIOSH BIO QUAL QUAN TLV SEQ

CODE REF NAS PROD GUIDE MED GUIDE MON DT DT DT NO.

ACETALDEHYDE 3 2312 75-07-0 26 X X DG DG 001ACETIC ACID 3. 2232 64-19-7 29 X X~ DG DG 002ACETIC ANHYDRIDE 3et 2333 108-24-7 39 X X DG G 003ACETONE 3 1100 67-64-1 26 X U DG o 004ACETONE CYANOHYDRIN 2 4124 75-86-5 55 G 005ACETONITRILE 3 2113 75-05-8 28 X X U 006ACETOPHENONE 4U 1--- 98-86-2 D 007ACETYL TRIBUTYL CITRATE 5 ---- 008 -I

:;x::.ACRYLAMIDE (50Y. OR LESS) 3. -013 79-06-1 X X 009 CO

ACRYLIC AC 10 3 3332 79-10-7 X 010 r-rl1

AC RYLDN ITR I LE 1 Al 4313 107-13-1 X U DG DG 011ADIPONITRILE 4C 4113 lil-69-3 012 :;x::.

IALCOHOLS (MIXED) 5 ---- D 013 <.oJAL~ENYL SUCCINIC ACID 5 ---- 014ALKENYLSUCCINIC,ANHYDRIDE 5 ---- 015ALKYLBENZENESULFONIC ACIDS 4L ---- 016 3:

:;x::.N-ALKYL PHTHALATES 5 ~---- 017 V'lALKYL SUCCINNATE, FORMALDEHYDE HYDROXY AM 5 ---- 018 -I

ALLYL ALCOHOL 2 3323 107-18-6 28 019rl1

X X D ~ALLYL CHLOR IDE 2 3323 107-05-1 28 X X 020 r-2~(2-AMINOETHOXY)ETHANOL 5 ---- 929-06-6 60· D 021 ......AMINOETHYlETHANOLAMINE 5 -131 111-41-1 022 V'l

N-AMINOETHYLP IPERAZ INE 5 ---- 140-31-8 60 D 023 -I......AMMONIA, ANHYDROUS 2 3422 7664-41-7 15 X X DG DG 024 :2:

AMMONIUM HYDROXIDE, 28 PERCENT AG, 4C -222 1336-21-6 60 D 025G)

N-AMYL ACETATE 3 1101 628-63-7 26 X X DG G 026 0N-AMYL ,ALCOHOL. 4C 1102 ·71-41-0 26 D 027 "T1

:;x::. AMYLENE 5 ---- 513-35-9 26 D 028 ::J:I

N.,.AMyL" METHYL KETONE 4U 26 V'lI-' ---- 029 00 AMYL TALLATE 5 ---- 030 V'l

ANILINE 2 3113 62-53-3 57 X X U DG DG 031 0ASDESTOS--AMOSITE 6 Al 12172-73-5 31 X 032 :;x::.ASBESTOS--CHRYSOTILE 6 At 12001-29-5 31 X 033 -I

:;x::.ASDESTOS--CROCIDOLITE 6 Al 12001-28-4 31 X 034ASBESTOS-:-OTHER 6 Al 1332-21-4 31 035 nASPHALT 3 0121 8052-42-4 27 X 036 0ASPHALT BLENDING STOCKS: ROOFERS FLUX 3 0121 27 037 :2:

-IASPHAL~ BLENDING STOCKS: STRAIGHT RUN RE 3 0121 27 038 -BEHENYL ALCOHOL 5 ---- 039 0

BENZENE 1~ A2 2113 71-43-2 27 X U DG DG- 040BENZENE HYDROCARBON MIx () OR .. lOX BEN) 1 A2 ---- D D 041BENZENE HYDROCARBON MIX (WITH ACETYLENE) 1 A2 ---- D 042BENZENESULFONYL CHLORIDE 5 ---- 98-09-9' 55 043BENZENE, TOLUENE, XYLENE MIXTURE 1 A2 -113 27 D 044BENZYL ALCOHOL 5 2--- 100-51-6 045BENZYL, CHL'OR I DE 2 2442 100-44-7 59 x DG G 046BERYt.LIUM 6 A2 7440-41-7 32 047BICYCLIC TERPENEL POLYAMINE AMIDE SALT 5 ---- 048BISPHENOL A DIGLYCIDYL ETHER 5- -011 167-55-43 049BUTADIENE (1.3 BUTADIENE) 1 A2 2111 106-99-0 17 X X DG 050BUTADIENE. BUTYLENE MIX WITH ACETYLENES 1 A2 ---- D 051

20-DEC-85CHEMICAL NAME CHRIS CFR OTHER TLV-TWA STEL IDLH ODOR CS CS/TWA SEQ


BUTANE BUT 0 800 5000.01.0E6 1.3E3 052N-SUTVL ACETATE BCN D 150 200 10000 O. 4 1. lE4 7. 3El 053SEC-BUTYL ACETATE BTA D 200 250 10000 200. 0 2. 7E4 1. 4E2 054ISO-BUTVL ACRVLATE BAI 0 10 0.04 1. 4E4 1.4E3 055BUTVL ACRVLATE (INH) ( ISO. N. AND MIXES) BAR 0 10 0.06 056N-BUTVL'ACRVLATE . BTC 0 10 0.044.2E3 057N-BUTVL ALCOHOL BAN D SKIN C50 BOOO 1.0 1. 2E4 3. 2E2 058SEC-BUTYL ALCOHOL BAS D 100 150 10000 0.4 4. lE4 4. lE2 059 ~

TERT~BUTVL ALCOHOL BAT D 100 150 BOOO 0.734.0E4 4. OE2 060)::>to

BUTVLAMINE (ALL ISOMERS) . BTV 0 SKIN C5 2000 0.24 2.9E5 5. 7E4 061 r-N-BUTVLAMINE BAM 0 SKIN C5 1. 8 1. 1E5 2.2E4062 IT1

SEC-BUTVLAMINE BTL 0 SKIN C5 1.8E5 3. 7E4 063 )::>

TERT-BUTVLAMINE BUA 0 SKIN C5 45E5 B. 9E4 064 Iw

BUTVLBENZVL PHTHALATE .BPH D 2.1E2 065.BUTVLENE BTN 0 1.0E6 066BUTVLENE GLVCOL D 7. BEl 067 3:1.2-BUTVLENE OXIDE BTO 0 400 O. 7 2. 7E5 6 BE2 068

)::>Vl

BUTVLENE POLYGLVCOL D 069 ~

N-BUTVL ETHER BTE 0 O. 47 070 IT1::tl

BUTVL HEPTYL KETONE D 071ISO-BUTYL METHACRYLATE BMI 0 072 r-......N-BUTVL METHACRYLATE BMN 0 50. 4 4. 6E3 073 Vl.

BUTVL METHYL KETONE D 5 074 ~......BUTYL STEARATE D 075 :zBUTVL TOLUENE (P-TERT) D 10 (P-Tl 20 (P-Tl 1000 5.0 076 enISO-BUTVRALDEHYDE BAD 0 1.5E5 077 0BUTYRALpEHYDE (ISO. N. AND MIXTURES) BAE 0 078 ""Tl

)::> N-BUTYRALDEHYDE BTR 0 0.005 1. 2E5 079 ::J:I

GAMMA-BUTYROLACTO~E BLA D 080 Vl..... C..... CADMIUM 0.05 MG/M3 0.2 MG/M3 081 VlCALCIUM ALKYLPHENATE D 082 cCALCIUM ALKYL SALICYLATE CAK D OB3 )::>

CALCIUM AMINO NONYL PHENOLATE D 084 .......CALCIUM CARBOXYLATE D OB5

)::>

CAMPHOR CPO 0 2 3 0.027 086 nCAMPHOR (OIL) CPO 0 2 3 32 16. 0 2. 4E2 1.2E2 OB7 0CAPROLACTAM (SOLUTION) CLS D 5 10 1.3E4 2.6E20BB :zCARBOLIC OIL (PHENOL) CBO 0 5 10 100 0.056.6E2 1.3E2 OB9 ~-CARBON BLACK BASE D 3. 5 MG/M3 7. 0 MG/M3 090 cCARBON DISULFIDE CBB 0 SKIN 10 500 0.13.9E5 3. 9E4 091CARBON MONOXIDE 50 400 1500 092CARBON TETRACHLORIDE CBT 0 SKIN 5 20 300 21. 0 1. 2E5 2. 4E4 093CAUSTIC POTASH SOLUTION CPS 0 SKIN C2 MG/M3 094CAUSTIC SODA SOLUTION CSS 0 SKIN C2 MG/M3 2. 2E3 095CETYL ALCOHOL D 096CETYL-EICOSVL METHACRVLATE CEM 0 097CETVL STEARVL ALCOHOL D 098CHEMICAL WASTES (CHLOR HCARBONS & CAUST) ewe 0 SKIN 10 099CHLORINE CLX 0 1 3 25 0.35 1. OE6 1. OE6 100CHLOROACETIC ACID SOLUTION (80% OR LESS) CHM 0 101CHLOROBENZENE CRB 0 75 2400 O. 21 1. 2E4 1. 6E2 102

20-DEC-85CHEMICAL NAME TOX CARC NFPA SEC CAS EMRSP BIO NIOSH BIO QUAL QUAN TLV SEQ


BUTANE 3 1000 106-97-8 22 X DG 052N-BUTYL ACETATE 3 1112 123-86-4 26 X X DG G 053SEC-BUTYL ACETATE 3 1112 105-46-4 26 X X D 054ISO-BUTYL ACRYLATE 3. -111 141-32-2 26 X 0 055B~TYL ACRYLATE (INH) ( ISO. N. AND MIXES) 3. ---- 141-32-2 26 0 056N-BUTYL ACRYLATE 3 2111 141-32-2 26 D 057N-BUTYL ALCOHOL 31 1112 71-36-3 26 X X DG G 058

-iSEC-BUTYL ALCOHOL 3 -101 78-92-2 26 X X DG G 059 ):>

TERT-BUTYL ALCOHOL 3 1101 75-'-65-0 26 X X G G 060 cer-BUTYLAMINE (ALL ISOMERS) 2' -344 109-73-9 68 X 0 061 IT1

N-BUTVLAMINE . 2 2444 1-09-73-9 68 X DG G .062 ):>SEC-:BUTYU~MINE. 2 3344' 109-73-9 68 D 063 . I

TERT-BUTYLAMINE 2 ---- 109-73-9 68 D 064 w.' ~- '. . -'

BUTYLBENZYL PHTHALATE 5. 1000 117-83-9 065BUTYLENE 5 ---- 22 0 066BUTYLENE'QLVCOL 5 -000 107-88-0 067 ::3:

. ):>

1.2-'-BUTYLENE OXIDE 4C 2--- 106-88-7 26 068 Vl

BUTYLENE POLYGLYCOL 5 ---- 069 -im

N-BUTYL ETHER ·5 2--- 142-96-1 26 D 070 .::cBUTYL HEPTVL KETONE 5 ---- 071 r-I~O-BUTYL METHACRYLATE 5 ---- 97-86-9 30 D 072 .-'

N-'-BUTYL METHACRYLATE 5 2--- 97-88-'1 30 073 Vl.-i

BUTYL.HETHYLKETONE 4U ---- 591-78-6 D 074 .......BUTYL STEARATE 5 ---- 075 ::z

Ci')BUTYL TOLUENE (P-TERTl 3 ---- 98-51-1 27 X D 076ISO-BUTYRALDEHYDE 5 " 2212 78-84-2 26 D 077 <=>

:T1BUTY~ALDEHYDE iISO. N. AND MIXTURES) 5 ---- 123-72-8' 26 D 078

:t:> N"-BUTYRALDEHYDE 5 2212 123-72-8 26 D 079 :i:VlI GAMMA-BUTYROLACTONE 5 ---- 96-48-0 080 0....

N CADMIUM 6 7440-43-9 53 X U 081 Vl

CALCIUM ALKYLPHENATE 5 ---- 082 0CA~CIUM ALKVL SALICYLATE 5 ---- 083 :t:>CALCIUM AMINO NONVL PHENOLATE 5

-l---- 084 ):>

CALCIUM CARBOXYLATE 5 ---- 085 -CAMPHOR 4P ---- 76-22-2 32 X X Oe6 hCAMPHOR <OILl 3 -011 76-22-2 27 > 087 0

::zCAPROLACTAM (SOLUTION) 3 -004 105-60-2 X 088 -iCARBOLIC OIL (PHENOL) 4C 3233 108-95-2 0 089 ',' -CARBON BLACK BASE" 3 ---- 1333-86-4 X 090 C-CARB"oN DISULFIDE 2 2223, 75-15-0 28 X X DG DG 091CARBON MONOXIDE 6 630-08-0 18 X B .092CARBON TET~ACHLORIDE 1 A2 3214' 56'-23-5 55 X X DG DG 093 .,'CA~STIC POTASH SOLUTION 3 ',3041 1310-58-3 60 094CAUSTIC SODA SOqJTION 3 ~ . 3041 1310-73-2 60 X 095CETYL ALCOHOL 5 ---- " 36653-82-4 096CETVL-EICOSYLMETHACRVLATE 5- ---- 097CETVL STEARVL ALCOHOL ,5 '. ---- 098CHEMICAL WASTE~ (CHLOR HCARBONS & CAUST) 4U ---- D 099CHLORINE 2 3424 7782--50-5 20 X X DG DG 100CH~OROACETIC ACID SOLUTION (BOX OR LESS) 5 3444 79~11-8 60 0 101CHLOROBENZENE 3. .OZ012 108-90-7 27 X X DG DG 102

; r.



CHLOROFORM CRF 0 10 50 1000 200.0 2. lE5 2. lE4 103CHLOROHYDRINS (CRUDE) CHD 0 5 25 5.0 6.7E3 1. 3E3 104CHLOROPRENE CRP 0 SKIN I 25 400 O. 11 2.4E5 2 4E4 1052-CHLOROPROPIONIC ACID CLA a 2 1063-CHLOROPROPIONIC ACID CLP 0 1072- AND 3-CHLOROPROPIONIC ACID MIXTURE CPM a 2 <2-) 108CHLOROSULFONIC ACID CSA 0 1 109

--tCHLOROTOLUENE (0. M. P, AND MIXTURES) CHI 0 SKIN (0-) 50 <0-) 75 (0-) O. 32 110 )::>M-CHLOROTOLUENE CTM 0 111 c:JO-CHLOROTOLUENE CTO a SKIN 50 75 112 r-

rT'lP-CHLOROTOLUENE CRN 0 50 113

)::>CHROMIUM (VI) O. 05 MG/M3 114 ICLEANING SPIRIT (UNLEADED) D 115 wCREOSOTE CCW a 116M-CRESOL CRL 0 SKIN 5 250 0.22.0E2 4.0El 117

3:O-CRESOL CSL a SKIN 5 250 O. 2 3 3E2 6.6El 118 )::>P-CRESOL CSO 0 SKIN 5 250 0.001 1.4E2 2. 8El 119 <.nCRESOLS CRS 0 SKIN 5 250 O. 20 6. 8E2 1.4E2 120 --t

rT'lCRESYLATE SPENT CAUSTIC CSC 0 5 250 121 AICROTONALDEHYDE CTA 0 2 6 400 O. 2 3. 9E4 2.0E4 122 r-CUMENE CUM D SKIN 50 75 8000 0.052.0E4 4.0E2123 ......CVCLOHEXANE CHX D 300 375 10000 0.4 1. 3E5 4.2E2124 <.n

--tCYCLOHEXANOL CHN D 50 3500 0.05 1.3E3 . 2.6El 125 ......CYCLOHEXANONE CCH a 25 100 5000 0.122.6E3 1.0E2 126 z

enCYCLOHEXYLAMINE CHA a SKIN 10 127CYCLOPENTADIENE POLYMERS D 75 150 2000 128 a

"'T'\P"'"CYMENE CMP D 129)::> N-DECALDEHYDE DAL D 2.9E2 130 ::I:I <.n.-. DECANE DCC D 131 0w I-DECENE DCE D 132 <.n

DECYL ACRYLATE (ISO. N. AND MIXTURES) DAT 0 1.3El 133 0N-DECYL ACRYLATE DAR 0 134 )::>

--tN-DECYL ALCOHOL DAN D 135 )::>N-DECYLBENZENE DBZ D 136DETERGENT ALKYLATE D 1.3El 137 nDIACETONE ALCOHOL DAA D 50 75 2100 1. 1 1.3E3 2. 6El 138 aDIAMMONIUM SALT OF ZINC EDTA (SOLUTION) DSZ a 139 z

--tDI-N-BUTVLAMINE DBA 0 0.48 2.6E3 140 -DIBUTYL CARBINOL D O. 16 3. 9E2 141 0

DIBUTYL PHTHALATE DPA D 5 MG/M3 10 MG/M3 142M-DICHLOROBENZENE DBM 0 1500 143a-DICHLOROBENZENE DBO a C50 1700 0.4 1. 3E3 2.6El 144P-DICHLOROBENZENE DBP 0 75 110 1000 O. 18 145DICHLORODIFLUOROMETHANE DCF 0 1000 1250 50000 1.0E6 1. OE3 1461. I-DICHLOROETHANE DCH 0 200 250 4000 2. 4E5 1.2E3 1472. 2 '-DICHLOROETHYL ETHER DEE 0 SKIN 5 10 250 15.05.3E2 1. lE2 148DICHLOROISOPROPYL ETHER DCI 0 149DICHLOROMETHANE (METHYLENE CHLORIDE) DCM 0 100 500 2000 210.0 4.6E5 4.6E3150DICHLOROMoNOFLUORoMETHANE DFM 0 10 150.0 1. OE6 1. OE5 1512. 4-D I CHLOROPHENOL DCP 0 1521.1-DICHLORoPRoPANE DPB 0 153



CHLOROFORM 1 A2 2212 67-66-3 55 X X DG DG 103CHLOROHYDRINS (CRUDE) 4C 3334 96-24-2 104CHLOROPRENE 4C 2323 126-99-8 30 X X 0 o 1052-CHLOROPROPIONIC ACID 4N ---- 598-78-7 60 1063-CHLOROPROPIONIC ACID 5 ---- 107-94-8 60 1072- AND 3-CHLOROPROPIONIC ACID MIXTURE 4N ---- 60 108CHLOROSULFONIC ACID 2 3444 HCL 7790-94-5 39 D 109CHLOROTOLUENE (0. M. P. AND MIXTURES) 3 ---- 95-49-8 27 X 110 --l

M-CHLOROTOLUENE 5 ---- 27 111 ~OJ

O-CHLOROTOLUENE 3 ---- 95-49-8 27 112 r

P-CHLOROTOLUENE 4U ---- 106-43-4 27 113 I"T1

CHROMIUM (VI) 6 Al 7440-47-3 X U 114 ~

CLEANING SPIRIT (UNLEADED) 5 ---- 115 ItAl

CREOSOTE 5 2232 8001-58-9 27 0 o 116M-CRESOL 3 3--- 1319-77-3 55 X DG DG 117O-CRESOL 3 3--- 1319-77-3 55 X DG DG 118 3:

P-CRESOL 3 3--- 1319-77-3 55 X DG DG 119 ~VI

CRESOLS 3 3232 1319-77-3 55 X DG DG 120 --l

CRESYLATE SPENT CAUSTIC 4U ---- 121 I"T1:;0

CROTONALDEHYDE 2 3333 123-73-9 28 X X D 122CUMENE 3* 0111 98-82-8 28 X X U DG G 123 r.....CYCLOHEXANE 3 1112 110-82-7 26 X X UB DG DG 124 VI

CYCLOHEXANOL 3 1121 108-93-0 X X 125 --l.....CYCLOHEXANONE 3* -321 108-94-1 26 X G G 126 :zCYCLOHEXYLAMINE 3 2342 108-91-8 68 X DG G 127 G)

CYCLOPENTADIENE POLYMERS 3 ---- 542-92-7 X 128 0P-CYMENE 5 2011 99-87-6 27 129

,.,~ N-DECALDEHYDE 5 ---- 130 :z:I DECANE 5 124-18-5 27 VI...... ---- 131 Cl

+:> 1-DECENE ~ ---- 132 VI

DECYL ACRYLATE (ISO. N. AND MIXTURES) 5 -111 133 ClN-DECYL ACRYLATE 5 ---- 134 ~

N-DECYL ALCOHOL 5 -000 2156-96-9 135 --l~

N-DECYLBENZENE 5 2--- 112-30-1 136DETERGENT ALKYLATE 5 -000 137DIACETONE ALCOHOL 3 1--- 123-42-2 26 X D 138

n0

DIAMMONIUM SALT OF ZINC EDTA (SOLUTION) 5 ---- 139 :zDI-N-BUTYLAMINE 5 3242 68 140

--l-DIBUTYL CARBINOL 5 -111 112-73-2 141 Cl

DIBUTYL PHTHALATE 3 -000 84-74-2 X 142M-DICHLOROBENZENE 5 3--- 0 143O-DICHLOROBENZENE 3.. 2211 95-50-1 58 X X DG G 144P-DICHLOROBENZENE 3 ---- 106-46-7 58 X X D 145DICHLORODIFLUOROMETHANE 3 0001 75-71-8 12 X X 1461. I-DICHLOROETHANE 3 2--- 75-34-3 27 X X G 1472. 2 '-DICHLOROETHYL ETHER :2 -323 111-44-4 57 X X 148DICHLOROISOPROPYL ETHER 5 ---- 108-60-1 59 149DICHLOROMETHANE (METHYLENE CHLORIDE) 3 2212 7~-09-2 74 X B D 150DICHLOROMONOFLUOROMETHANE 2 ---- 75-43-4 12 X X 1512. 4-D I CHLOROPHENOL 5 ---- 120-83-2 0 1521.1-DICHLOROPROPANE 5 2113 78-99-9 27 0 153


CODE ROUTE PPM PPM PPM PPM PPM NO

1.2-DICHLOROPROPANE DPP 0 75 110 5. 3E4 7. lE2 1541.3-DICHLOROPROPANE DPC 0 1551.3-DICHLOROPROPENE DPU 0 SKIN 1 10 1. 5 1. 4E5 1.4E5 156DICHLOROPROPENE (1.1- 1.2- 1.3- AND MIX) DPS 0 SKIN 1 10 1.5 157DICHLOROPROPENE.DICHLOROPROPANE MIXTURE) DMX 0 SKIN 1 10 1.5 1582.2-DICHLOROPROPIONIC ACID DCN 0 1 159DICHLOROTETRAFLUOROETHANE DTE 0 1000 1250 50000 1.0E6 1. OE3 160DICVCLOPENTADIENE OPT 0 5 50 0.02 2.0E3 4. OE2 161 --I

)::-DIETHANOLAMINE DEA 0 3 0.27 1. OE2 3. 3El 162 CODIETHVLAMINE DEN 0 10 25 2000 O. 16 2. 6E5 2. 7E3 163 r

I"TlDIETHVLBENZENE DEB 0 1.3E3 164

)::-DIETHYLENE GLYCOL DEG 0 100 1. OEO 165 IDIETHYLENE GLYCOL DIETHYL ETHER 0 166 (.oJ

DIETHYLENEGLVCOL MONOBUTYL ETHER ACETATE DEM 0 O. 2 167DIETHVLENE GLVCOL MONOBUTYL ETHER DME D 0.48 168DIETHYLENEGLYCOL MONOETHYL ETHER DGE 0 5 1.3 169 3:

)::-DIETHYLENE GLYCOL MONOETHYL ETHER ACETAT 0 5 0.64 170 VIDIETHYLENEGLYCOL MONOMETHYL ETHER DGM D 5 2. 6E2 171 --I

I"TlDIETHYLENE GLYCOL MONOMETHYL ETHER ACET D 5 O. 64 172 :::0DIETHYLENE GLYCOL MONOPHENYL ETHER D 0.40 173 rDIETHYLENETRJAMINE DET 0 SKIN 1 10. 0 174 .......DIETHYLETHANOLAMINE DAE 0 10 0.27 I. 3E3 1. 3E2 175 VI

--IDI-(2-ETHYLHEXYL)PHOSPHORIC ACID DEP 0 176 .......DI(ETHYLHEXYL)PHTHALATE D 5 MG/M3 177 z

enDIETHVL PHTHALATE DPH D 5 MG/M3 10 MG/M3 178DIETHYL SULFATE DSU 0 179 0....,DIHEPTYL PHTHALATE DHP 0 180

)::- DIHEXYL PHTHALATE 0 181 :::I:I 01 ISOBUTYLAMINE DBU 0 VI

...... 182 0(J1 01 ISOBUTYLCARBINOL DBC 0 3. 9E2 183 VI

DIISOBUTYLENE DBL D 8. 8E4 184 0DIISOBUTYL KETONE DIll. 0 25 2000 O. 31 1.3E3 5.2El 185 )::-

--IDIISOBUTYL PHTHALATE DIl 0 186 )::-DIISODECYL PHTHALATE DID D 187DIISONONYL PHTHALATE DIN 0 188 ("")

DIISOOCTYL PHTHALATE DID D 189 001 ISOPROPANOLAMINE DIP 0 190

z--I

DIISOPROPYLAMINE DIA 0 SKIN 5 1000 0.49.2E4 1.8E4 191 -DIISOPROPYL BENZENE D 192 0

DIMETHYLACETAMIDE DAC 0 SKIN 10 15 46.0 1. 9E3 1.9E2 193DIMETHYLAMINE DMA 0 10 2000 0.051.0E6 1. OE5 194DIMETHYLAMINE SOLUTION (45% OR LESS) DMG 0 10 2000 195DIMETHYLAMINE SOLUTION (>45% AND <~55%) DMY 0 10 2000 4.2E5 196DIMETHYLAMINE SOLUTION (55% AND <65%) DMC 0 10 2000 197DIMETHYL AMMONIUM-2.4-DICHLOROPHENOXVACE DDA 0 198N.N-DIMETHVLCYCLOHEXYLAMINE DXN 0 3.6E3 199DIMETHYLETHANOLAMINE DMB 0 5. 5E3 200DIMETHYLFORMAMIDE DMF 0 SKIN 10 20 3500 2.23.6E3 3. 6E2 201DIMETHYL PHTHALATE DTL D 5 MG/M3 10 MG/M3 9300 MG/M3 1.3E3 2022.2-DIMETHYLPROPANE-1.3-DIOL D 203

'DINONYL PHTHALATE 0 204

20-0EC-85CHEMICAL NAME TOX CARC NFPA SEC CAS EMRSP BID NIOSH BID QUAL QUAN TLV SEQ


1.2-DICHLOROPROPANE 3 2113 78-87-5 27 X DG G 1541.3-DICHLOROPROPANE 5 2113 142-28-9 27 1551.3-DICHLOROPROPENE 2 -223 542-75-6 29 X 156DICHLOROPROPENE (1.1- 1.2- 1.3- AND MIX) 2 ---- 542-75-6 29 157DICHLOROPROPENE.DICHLOROPROPANE MIXTURE) 2 ---- 8003-19-8 29 1582.2-DICHLOROPROPIONIC ACID 3 ---- 75-99-0 bO X 159OICHLOROTETRAFLUOROETHANE 3 ---- 76-14-2 12 X X 160DICYCLOPENTADIENE 3. -112 77-73-b 26 X 0 161 -I

:t:>DIETHANOLAMINE 3 -222 111-42-2 X X D 162 OJDIETHYLAMINE 3 -312 109-89-7 b8 X DG G 163 r

rnOIETHYLBENZENE 5 -111 25340-17-4 29 DO 164DIETHYLENE GLYCOL 4C 1001 111-46-6 165 :t:>

IDIETHYLENE GLYCOL DIETHYL ETHER 5 ---- 112-36-7 166 wOIETHYLENEGLYCOL MONOBUTYL ETHER ACETATE 5 -000 124-17-4 167DIETHYLENE GLYCOL MONOBUTYL ETHER 5 1101 112-34-5 168DIETHYLENEGLYCOL MONOETHYL ETHER 4H -000 169 3:

:t:>DIETHYLENE GLYCOL MONOETHYL ETHER ACETAT 4H ---- 112-15-2 170 VIDIETHYLENEGLYCOL MONOMETHYL ETHER 4H -000 111-77-3 171 -I

rnDIETHYLENE GLYCOL MONOMETHYL ETHER ACET 4H ---- 629-38-9 D 172 :;0

DIETHYLENE GLYCOL MONOPHENYL ETHER 5 ---- 104-68-7 173DIETHYLENETRIAMINE 3 3222 111-40-0 29 X DG 174

r......DIETHYLETHANOLAMINE 4U 3--- 100-37-8 175 VI

DI-(2-ETHYLHEXYL)PHOSPHORIC ACID 5 -023 298-07-7 60 176-I......

01 (ETHYLHEXYL)PHTHALATE 4N ---- 117-81-7 177 :2:

DIETHYL PHTHALATE 3 0--- 84-66-2 X 178G)

DIETHYL SULFATE 5 ---- 64-67-5 55 179 aDIHEPTYL PHTHALATE 5 ---- 180 "'TI

:t:> DIHEXYL PHTHALATE 5 ---- 181 :cI DIISOBUTYLAMINE 5 ---- 110-9b-3 b8 182 VI

...... CJ0' DIISOBUTYLCARBINOL 5 -111 108-82-7 183 VI

01 ISOBUTYLENE 5 -010 12002-23-2 26 184 CJDIISOBUTYL KETONE 3. 1211 108-83-8 26 X 185 :t:>OIISOBUTYL PHTHALATE 5 ---- 84-69-5 18b -I

:;::.DIISODECYL PHTHALATE 5 ---- 187DIISONONYL PHTHALATE 5 ---- 188

...........n

DIISOOCTYL PHTHALATE 5 ---- 189 aDIISOPROPANOLAMINE 5 3222 110-97-4 190 :2:

-IDIISOPROPYLAMINE 2 3324 108-18-9 b8 .X X DG G 191 -DIISOPROPYL BENZENE 5 ---- 577-55-9 192 CJ

DIMETHYLACETAMIDE 3 ---- 127-19-5 X X DG DG 193DIMETHYLAMINE 2 3222 124-40-3 19 X X DG G 194DIMETHYLAMINE SOLUTION (45% OR LESS) 2 ---- 124-40-3 26 0 195DIMETHYLAMINE SOLUTION (>45% AND <=557.) 2 ---- 124-40-3 2b 196DIMETHYLAMINE SOLUTION (557. AND <65%) 2 ---- 124-40-3 26 197DIMETHYL AMMONIUM-2.4-DICHLOROPHENOXYACE 5 ---- 2008-39-1 198N.N-DIMETHYLCYCLOHEXYLAMINE 5 ---- 98-94-2 60 199DIMETHYLETHANOLAMINE 5 ---- 108-01-0 29 D 200DIMETHYLFORMAMIDE 3 -223 b8-12-2 2b X UB DG G 201DIMETHYL PHTHALATE 3 ---- 131-11-3 X X 2022. 2-DIMETHYLPROPANE-l.3-DIOL 5 ---- 12b-30-7 D 203DINONYL PHTHALATE 5 ---- 84-76-4 204

20-0EC-85CHEMICAL NAME CHRIS CFR OTHER TLV-TWA STEL IDLH ODOR CS CS/TWA SEG


DI(OCTYLPHENYL)AMINE 0 205DIOCTYL PHTHALATE DOP D 5 MG/M3 1.3E1 2061.4-DIOXANE DOX 0 SKIN 25 100 200 1. 8 3.6E4 1.4E3 207DIPENTENE OPN D 208OIPHENYL OIL 0 o 2 O. 6 50 1,0 6.6E1209DIPHENYL DIPHENYL OXIDE 000 D O. 5 210DIPHENYL ETHER DPE 0 1 2. 6El 211DIPHENYLMETHANE OIISOCYANATE DPM 0 CO. 02 20 6. 6El 212 -l

)::>DI-N-PROPYLAMINE DNA 0 3. 9E4 213 tcDIPROPYLENE GLYCOL OPG D 214 I

IT1DIPROPYLENE GLYCOL HONOHETHYL ETHER D 100 150 3.9E2 1. 7E2 215DISTILLATES: FLASHED FEED STOCKS DFF D 216 )::>

JDISTILLATES: STRAIGHT RUN DSR 0 217 wOIUNDECYL PHTHALATE DUP 0 218DODECANE 0 3. 9E2 219DOOECANOL DDN D 1.3E3 220 3:

)::>DODECENE DOD D 221 V'lI-DoDECENE DOC D 222 -l

IT1DoDECYLBENZENE DDB 0 1.3E1 223 ;;0OoDECYL OIPHENYL OXIOE DISULFoNATE SOLN DOS 0 224 rDoDECYLMETHACRYLATE DDM 0 225 ........DODECYL PENTADECYL METHACRYLATE DDP 0 226 V'l

-lDODECYL PHENOL D 227 ........EPICHLOROHYDRIN EPC 0 SKIN 2 5 100 0.93 1. 6E4 8. OE3 228 :zEPOXYLATED LINEAR ALCOHOLS. C11-C15 D 229 G'l

ETHANE ETH 0 1500 230 a2-ETHOXYETHANOL EGE D SKIN 5 6000 O. 6 5. OE3 1. lE3 231 ...."

)::> 2-ETHOXYETHYL ACETATE 0 SKIN 5 2500 0.145.0E3 3. 2E2 232 :cJETHOXYLATEO DODECANOL EOO 0 233 V'lI-' c::r

" ETHOXYLATED PENTAOECANOL EOP 0 234 V'lETHOXYLATED TETRAOECANOL EOT 0 235 c::rETHOXYLATED TRIDECANOL ETO 0 236 )::>

ETHOXYLATED UNOECANOL D 237 -l)::>ETHOXY TRIGLYCOL ETG 0 1.3El 238

ETHYL ACETATE ETA 0 400 10000 13.2 1. 3E5 3. 3E2 239 nETHYL ACRYLATE EAC 0 SKIN 5 25 2000 O. 0001 3 9E4 7.8E3240 aETHYL ALCOHOL EAL D 1000 4.675.8E4 5. 8El 241 :z

-lETHYLAMINE EAM 0 10 4000 0.83 1.0E6 1.0E5242 -ETHYLAMINE (40X OR LESS) EAO 0 10 4000 O. 83 243 c::rETHYLAMINE (72X OR LESS) EAN 0 10 4000 O. 83 244ETHYL AMYL KETONE 0 25 3000 5.02.6E3 1.0E2245ETHYLBENZENE ETB 0 100 125 2000 140.02.0E4 2.0E2246ETHYL BUTANOL EaT 0 100 1500 0.8 1. 2E3 247N-ETHYL-N-BUTYLAMINE EBA 0 248ETHYL CHLORIDE ECL 0 1000 1250 20000 1.0E6 1.0E3 249ETHYL CYCLOHEXANE ECY D 250N-ETHYL CYCLoHEXYLAMINE ECC 0 370 MG/M3 251ETHYLENE ETL 0 252ETHYLENE CARBONATE 0 400 253ETHYLENE CHLOROHYDRIN ECH 0 SKIN C1 10 0.938.9E3 8.9E3254ETHYLENE CYANOHYDRIN ETC 0 255



DI(OCTVLPHENYL)AMINE 5 ---- 205DIOCTVL PHTHALATE 4N ---- I 117-84-0 206L 4-DIOXANE 2 2113 123-91-1 26 X X DG 207DIPENTENE 5 0110 138-86-3 27 0 208DIPHENYL 3 ---- 92-52-4 X X 209DIPHENYL DIPHENYL OXIDE 4N ---- 8004-13-5 210DIPHENYL ETHER 4N 1--- 101-84-8 211DIPHENYLMETHANE DIISOCYANATE 2 -324 101-68-8 X 212 -i

::t:>DI-N-PROPYLAMINE 5 3--- 142-84-7 68 213 c:cDIPROPYLENE GLYCOL 5 -001 110-98-5 0 214 r-

IT1DIPROPYLENE GLYCOL MONOMETHYL ETHER 3 ---- 34590-94-8 X X D 215DISTILLATES: FLASHED FEED STOCKS 5 -112 216 ::t:>

I

DISTILLATES: STRAIGHT RUN 5 -112 217 wDIUNDECYL PHTHALATE 5 ---- 218DODECANE 5 ---- 112-40-3 219DODECANOL 5 ---- 112-53-8 220 3:

::t:>DODECENE 5 0111 6842-15-5 221 V'l

I-DODECENE 5 ---- 6842-15-5 222 -iIT1

DODECYLBENZENE 5 -000 25265-78-5 223 ;::0

DODECYL DIPHENYL OXIDE DISULFONATE SOLN 5 ---- 224 r-DODECYLMETHACRYLATE 5 ---- 142-90-5 225 -.DODECYL PENTADECYL METHACRYLATE 5 ---- 226 V'l

--IDODECYL PHENOL 5 ---- 27193-86-8 0 227 -.EPICHLOROHYDRIN 2 3334 106-89-8 30 X X DG G 228 :2

G"lEPOXYLATED LINEAR ALCOHOLS. CI1-CI5 5 ---- 229ETHANE 3 ---- 74-84-0 22 X D 230 0

2-ETHOXYETHANOL 3. -112 110-80-5 26 X X 0 G 231 "::t:> 2-ETHOXYETHYL ACETATE 3_ -112 111-15-9 26 X X D 232 :::r:I ETHOXYLATED DODECANOL 5 233

V'l...... ---- 0CO ETHOXYLATED PENTADECANOL 5 ---- 234 V'l

ETHOXVLATED TETRADECANOL 5 ---- 235 0ETHOXYLATED TRIDECANOL 5 ---- 236 ::t:>

ETHOXYLATED UNDECANOL 5 ---- 237 -l::t:>

ETHOXY TRIGLYCOL 5 -000 112-50-5 238ETHYL ACETATE 3 1112 141-78-6 26 X X DG DG 239 ("")

ETHYL ACRYLATE 3. 2323 140-88-5 27 X X DG 240 0

ETHYL ALCOHOL 3 0101 64-17-5 26 X DG DG 241 :2--I

ETHYLAMINE 2 3323 75-04-7 68 X DG G 242 -ETHYLAMINE (407. OR LESS) 2 ---- 75-04-7 29 X 243 0

ETHYLAMINE (72% OR LESS) 2 ---- 75-04-7 29 X 0 244ETHYL AMYL KETONE 3 ---- 541-85-5 26 X 245ETHYLBENZENE 3 2222 100-41-4 26 X U DG DG 246ETHYL BUTANOL 4C 1--- 97-95-0 26 D 247N-ETHYL-N-BUTYLAMINE 5 ---- 617-79-8 248ETHYL CHLOR IDE 3 2111 75-00-3 27 X G G 249ETHYL CYCLOHEXANE 5 ---- 1678-91-7 250N-ETHYL CYCLOHEXYLAMINE 4L ---- 54.59-93-8 251ETHYLENE 3 1001 74-85-1 22 X DG 252ETHYLENE CARBONATE 5 ---- 96-49-1 253ETHYLENE CHLOROHYDRIN 3. 3--- 107-07-3 55 X X 254ETHYLENE CYANOHYDRIN 5 2002 109-78-4 255

20-oEC-85CHEMICAL NAME CHRIS CFR OTHER TLV-TWA STEL IDLH ODOR CS CS/TWA SEQ


ETHYLENEDIAMINE EDA 0 10 2000 3.4 1. 4E4 1.4E3 256ETHYLENE DIBROMIDE EDB 0 SKIN 400 26.0 1. 2E4 257ETHYLENE DICHLORIDE EDC 0 10 15 1000 40.01,3E5 1,3E4 258ETHYLENE GLYCOL EGL 0 C50 25. 0 6. 6El 1. 3EO 259ETHYLENE GLYCOL DIACETATE EGY D 260ETHYLENE GLYCOL METHYL BUTYL ETHER D 261ETHYLENE GLYCOL MONOBUTYL ETHER EGM D SKIN 25 700 0.48 1.0E3 262ETHYLENE GLYCOL MONOBUTYL ETHER ACETATE EMA D 0.25 263 -I

):>ETHYLENE GLYCOL MONOETHYL ETHER ACETATE EGA D SKIN 5 2500 0.20 1.6E3 264 OJETHYLENE GLYCOL MONOISOPROPYL ETHER D 25 265 r-

IT1ETHYLENE GLYCOL MONOMETHYL ETHER' EME D SKIN 5 O. 4 8. 2E3 266ETHYLENE GLYCOL MONOMETHYL ETHER ACETATE 0 5 35 2500 O. 66 9. 2E3 3, 7E2 267 ):>

IETHYLENE GLYCOL PHENYL ETHER 0 268 wETHYLENE OX IDE EOX 0 1 800 50001.0E6 1.0E5 269ETHYLENE OXIDE. PROPYLENE OXIDE MIXTURE EPM 0 1 1400 500. 0 270ETHYLENE - PROPYLENE COPOLYMERS D 271 3:

):>ETHYL ETHER EET 0 400 500 19000 0.335.8E5 1. 5E3 272 c.nETHYLHEXALDEHYDE EHA D 273 -IETHYLHEXANOIC ACID (ETHYL HEXOIC ACID) 0 274

IT1::0

2-ETHYL HEXANOL EHX 0 O. 14 4,7E2 275 r-2-ETHYLHEXYL ACRYL~TE EAI 0 O. 18 1. 3E2 276 ......2-ETHYL HEXYLAMINE EHM 0 277 c.nETHYL HEXYL PHTHALATE 0 278 -I......ETHYLHEXYL TALLATE EHT D 279 :zETHYLIoENE NORBORNENE END 0 C5 0.076.0E3 1.2E3 280 G'>

ETHYL METHACRYLATE ETM 0 2. OE4 281 a2-ETHYL-3-PROPYLACROLEIN EPA 0 6.6E2 282 "):> ETHYL TOLUENE ETE 0 283 :I:

IFATTY ACID AMI DES 0 c.n...... 284 0

1.0 FERRIC CHLORIDE SOLUTIONS FCS 0 1 MG/M3 1. 7E3 285 c.nFLUORIDES 2. 5 MG/M3 500 MG/M3 286 0FORMALDEHYDE SOLUTION FMS 0 1 2 100 0.8 1.7E3 287 ):>

FORMAMIDE FAM 0 20 30 1.3E2 6. 5EO 288 -I):>

FORMIC ACID FHA 0 5 100 21.07.9E2 289FURFURAL FFA 0 SKIN 2 10 250 0.252.0E3 I,OE3 290 ("")FURFURYL ALCOHOL FAL 0 SKIN 10 15 250 8.0 1. 3E3 1. 3E2 291 aGAS OIL: CRACKED GOC D 292 :z

-IGASOLINE: AUTOMOTIVE (4.230 PB/GALI GAT 0 300 500 10000 O. 25 2. 5E5 8.3E2293 -GASOLINE: AVIATION (4.86Q PB/GAL) GAV D 300 500 10000 0.25 294 0

GASOLINE BLENDING STOCKS: ALKYLATES GAK D 300 500 10000 0.3 295GASOLINE BLENDING STOCKS: REFORMATES GRF D 300 500 10000 0.4 296GASOLINE: CASINGHEAD GCS 0 300 500 10000 297GASOLINE: POLYMER GPL D 300 500 10000 298GASOLINE: STRAIGHT RUN GSR D 300 500 10000 O. 25 299GLUTARALDEHYDE (SOX OR LESS) GTA 0 CO.2 0.042.2E4 1. lE5 300GLYCERINE GCR D 10 MG/M3 301GLYCERYL TRIACETATE D 302GLYCIDYL ESTER OF TERTIARY CARBOXYLIC AC D 303GLYCIDYL ESTER OF VERSATIC ACID D 304GLYCOLS. RESINS. AND SOLVENTS MIXTURE D 305GLYCOL TRIACETATE D 306



ETHYLENEDIAMINE 3 3333 107-15-3 29 X DG G 256ETHYLENE DIBROMIDE 1 A2 3113 106-93-4 55 X X DO 257ETHYLENE DICHLORIDE 2 2223 107-06-2 26 X DG 258ETHYLENE GLYCOL 3 1001 107-21-1 X G 259ETHYLENE GLYCOL DIACETATE 5 1000 111-55-7 260ETHYLENE GLYCOL METHYL BUTYL ETHER 5 ---- 261ETHYLENE GLYCOL MONOBUTYL ETHER 3 2112 111-76-2 26 DG 262ETHYLENE GLYCOL MONOBUTYL ETHER ACETATE 5 ---- 112-07-2 D 263 -i

::t:>ETHYLENE GLYCOL MONOETHYL ETHER ACETATE 3 -111 111-15-9 26 0 264 0::1

ETHYLENE GLYCOL MONOISOPROPYL ETHER 4N ---- 109-59-1 265 r-/T1

ETHYLENE GLYCOL MONOMETHYL ETHER 3 -112 109-86-4 26 DG 266ETHYLENE GLYCOL MONOMETHYL ETHER ACETATE 3 ---- 110-49-6 26 DG 267 ::t:>

IETHYLENE GLYCOL PHENYL ETHER 5 ---- 112-99-6 268 wETHYLENE OXIOE 1 A2 2332 75-21-8 69 X DG G 269ETHYLENE OXIDE. PROPYLENE OXIDE MIXTURE 1 A2 ---- 26 0 270ETHYLENE - PROPYLENE COPOLYMERS 5 ---- 271 ~

::t:>ETHYL ETHER 3 2102 60-29-7 26 X DG G 272 VlETHYLHEXALDEHYDE 5 2121 123-05-7 26 273 -i

/T1ETHYLHEXANOIC ACID (ETHYL HEXOIC ACID) 5 ---- 149-57-5 274 :;J;J

2-ETHYL HEXANOL 5 2111 104-76-7 275 r-2-ETHYLHEXYL ACRYLATE 5 2011 103-11-7 276 ......2-ETHYL HEXYLAMINE 5 ---- 104-75-6 29 277 Vl

-iETHYL HEXYL PHTHALATE 5 ---- 117-81-7 278 ......ETHYLHEXYL TALLATE 5 ---- 279 :zETHYLIDENE NORBORNENE 3* -314 16219-75-3 280

C")

ETHYL METHACRYLATE 9 2"':-- 97-63-2 30 281 a2-ETHYL-3-PROPYLACROLEIN 9 -323 645-62-5 282

-.,

::t:> ETHYL TOLUENE 5, ---- 611-14-3 283 :::I:

I FATTY ACID AMIDES ~- 5 622-96-8 284 VlN ---- .= Cla FERRIC CHLORIDE SOLUTIONS 4N ---- 7705-08-0 31 285 Vl

FLUORIDES 6 X U 286 ClFORMALDEHYDE SOLUTION 1 A2 2323 50-00-0 29 X DG DG 287 ::t:>FORMAM IDE 3 ---- 75-12-7 X 288 -i

::t:>FORMIC AC ID 3 3333 64-18-6 60 X X DG ,G 289FURFURAL 3* 2223 98-01-1 29 X X U G G 290 nFURFURYL ALCOHOL 3 1212 98-00-0 55 X 291 aGAS OIL: CRACKED 5 1112 27 292 :z

-iGASOLINE: AUTOMOTIVE (4.230 PB/GAL) 3* 1112 8006-61-9 27 X DG G 293 -GASOLINE: AVIATION (4.86G PB/GAL) 3* 1112 27 294 Cl

GASOLINE BLENDING STOCKS: ALKYLATES 3* 1112 27 295GASOLINE BLENDING STOCKS: REFORMATES 3* 1112 27 296GASOLINE: CASINGHEAD 3* 1101 27 D 297GASOLINE: POLYMER 3et 1112 27· 298GASOLINE: STRAIGHT RUN 3et 1112 27 D 299GLUTARALDEHYDE (907. OR LESS) 2 ---- 111-30-8 X D 300GLYCERINE 4N 1000 56-81-5 X 301GLYCERYL TRIACETATE 5 ---- 102-76-1 302GLYCIDYL ESTER OF TERTIARY CARBOXYLIC AC 5 ---- 303~LYCIDYL ESTER OF VERSATIC ACID 5 ---- 304GLYCOLS. RESINS. AND SOLVENTS MIXTURE 5 ---- D 305GLYCOL TRIACETATE 5 ---- 306



""-GLYOXAL. 40% SOLUTION GOS 0 307GREASE D 308HEPTADECANE 0 309HEPTANE HPT' 0 400 500 4250 223.0 1.5E4 3.8E1310HEPTANOIC AC 10 HEP 0 311HEPTANOL HTN 0 312I-HEPTENE HTE 0 313

-IHERBICIDE (C15-H22-N02-CL) D 314 ::t:>HEXAETHYLENE GLYCOL 0 315 CO

HEXAMETHYLENEDIAMINE HMD 0 316 r-I"T1

HEXAMETHYLENEOIAMINE SOLUTION HMC 0 317::t:>HEXAMETHYLENE GLYCOL 0 318 I

HEXAMETHYLENEIMINE Hi'll 0 6. 6E3 319 wHEXANE HXA D 50 5000 30.0 1. 2E5 2.4E3320HEXANOL HXN 0 1.3E3 321I-HEXENE HXE 0 322 :::

::t:>HEXYL ACETATE 0 50 300 4000 5. 3E3 323 <.nHEXYLENE GLYCOL HXG 0 C25 C125 6. 6El 2.6EO 324 -I

I"T1HOG GREASE 0 325 :;;0

HYDROCHLORIC ACID HCL 0 C5 100 1.0 2. BE5 326 r-HYOROCHLORIC ACID. SPENT (157. OR LESS) HCS 0 C5 100 327 .......HYOROFLUORIC ACIO HFA 0 3 6 100 0.04 328 <.n

-IHYDROGEN CHLORIDE HOC 0 C5 100 1.0 1.0E6 2. OE5 329 .......HYDROGEN FLUORIDE HFX 0 3 6 20 0.04 1. OE6 3. 3E5 330 z

G)HYOROGEN SULFIDE 10.0 15 300 O. 7 3312-HYOROXYETHYL ACRYLATE HAl 0 332 0

"'T'IINDUSTRIAL WASTES (METHYL MERCAPTAN. ETC) INW 0 0.5 (1'1-1'1) 333::t:> ISOAMYL ACETATE IAT D 100 125 3000 0.03 5.3E3 5. 3El 334 :::I:

<.nI ISOBUTYL ACETATE IBA 0 150 187 7500 6.0 1.7E4 1. lE2 335 I::)NISOBUTYL ALCOHOL IAL D 50 75 8000 1. B 1. 2E4 2. 4E2 336 <.n......ISOBUTYLAMINE lAM 0 1.3E5 337 I::)

ISODECALDEHYDE lOA 0 2. 9E2 338 ::t:>-IISODECYL ACRYLATE IAI 0 1.3El 339 ::t:>

ISODECYL ALCOHOL ISA 0 340ISOHEXANE IHA D 1.3E5 341 ("'")

ISOOCTALDEHYDE IOC D 342 0:zISOPHORONE IPH 0 C5 BOO 0.5439E2 7. BEl 343 -I

ISOPHORONE DIAMINE IP I 0 344 -ISOPHORONE DIISOCYANATE IPD 0 SKIN CO.Ol 345

I::)

ISOPRENE IPR 0 1000 5. 3E5 346ISOPROPYL ACETATE lAC 0 250 310 16000 0.97 5.7E4 2.3E2 347ISOPROPYL ALCOHOL IPA D 400 500 20000 22. 5 4. 3E4 1. lE2 348ISOPROPYLAMINE IPP 0 5 10 4000 0.7 6.1E5 1.2E5 349ISOPROPYLAMINE (90% OR LESS) IPO 0 5 10 4000 O. 7 350ISOPROPYL ETHER IPE 0 250 310 10000 0.53 1. 7E5 6.8E2351ISOVALERALDEHYDE IVA 0 352JET FUEL: JP-l (KEROSENE) JPO D 100 MG/1'13 1.0 353JET FUEL: JP-3 JPT D 354JET FUEL: JP-4 JPF D 0.25 355JET FUEL: JP-5 (KEROSENE. HEAVY) JPV D 1.0 356KEROSENE KRS D 100 MG/M3 1. a 2.7E3 357

20-DEC-85CHEMICAL NAME TOX CARC NFPA SEC CAS EMRSP BID NIOSH BID GUAL GUAN TLV SEQ


GLYOXAL. 40% SOLUTION 5 -111 107-22-2 307GREASE 5 ---- 308HEPTADECANE 5 ---- I 309HEPTANE 3 -011 142-82-5 27 X X DG G 310HEPTANOIC AC ID 5 ---- 111-14-8 311HEPTANOL 5 ---- 111-70-6 D 312I-HEPTENE 5 -110 27 313HERBICIDE (CI5-H22-N02-CL) 5 ---- 314 --l

:t=oHEXAETHYLENE GLYCOL 5 ---- 2615-15-8 315 OJ

HEXAMETHYLENEDIAMINE 5 -123 124-09-4 60 316 r("Tl

HEXAMETHYLENEDIAMINE SOLUTION 5 ---- 60 317HEXAMETHYLENE GLYCOL 5 ---- 629-11-8 318 ::t:>

IHEXAMETHYLENEIMINE 5 ---- 111-49-9 29 319 wHEXANE 3. 1001 110-54-3 27 X X UB DG G 3;;WHEXANOL 5 ---- 111-27-3 26 0 321I":HEXENE 5 ---- 27 322 ~

::t:>HEXYL ACETATE 4N 1211 142-92-7 X X 0 323 <.nHEXYLENE GLYCOL 3 3344 107-41-5 X 324 --l

("Tl

HOG GREASE 5 ---- 325 ;;0

HYDROCHLORIC ACID 2 3332 7647-01-0 15 DG o 326 rHYDROCHLORIC ACID. SPENT (15% OR LESS) 3 ---- 60 DG 327 ......HYDROFLUORIC ACID 2 4444 7664-39-3 15 G 328 <.n

--lHYDROGEN CHLORIDE 2 3433 7647-01-0 15 X X DG DC 329 ......HYDROGEN FLUORIDE 2 4444 7664-39-3 15 X X DG DG 330 ::z

'"HYDROGEN SULFIDE 6 7783-06-4 13 X 3312-HYDROXYETHYL ACRYLATE 5 -444 818-61-1 332 0

"T1INDUSTRIAL WASTES (METHYL MERCAPTAN. ETC) 3 ---- 333

::t:> ISOAMYL ACETATE 3 1--- 123-92-2 X X D 334 ::cI <.n

N ISOBUTYL ACETATE 3 1112 110-19-0 26 X X DC G 335 0N ISOBUTYL ALCOHOL 3 1101 78-83-1 26 X X DG 336 <.n

ISOBUTYLAMINE 5 2344 78-81-9 68 D 337 0ISODECALDEHYDE 5 -111 3085-26-5 338 ::t:>

--lISODECYL ACRYLATE 5 -111 1330-61-6 339 ::t:>ISODECYL ALCOHOL 5 -020 25339-17-7 340ISOHEXANE 5 -001 107-83-5 D 341 ("")

ISOOCTALDEHYDE 5 -101 342 aISOPHORONE 3* 2222 78-59-1 X 343

::z--l

ISOPHORONE DIAMINE 5 ---- 60 344 -ISOPHORONE DIISOCYANATE 3. ---- 4098-71-9 55 X 345 0

ISOPRENE 4L 2111 78-79-5 27 346ISOPROPYL ACETATE 3 1112 108-21-4 26 X X DG 347ISOPROPYL ALCOHOL 3 1102 67-63-0 26 X X DC DG 348ISOPROPYLAMINE 2 3324 75-31-0 68 X X DG G 349ISOPROPYLAMINE (90% OR LESS) 2 ---- 75-31-0 68 X 0 350ISOPROPYL ETHER 3 2111 108-20-3 26 X X 0 351ISOVALERALDEHYDE 5 ---- 590-86-3 352JET FUEL: JP-l (KEROSENE) 4N 0111 8008-20-6 27 D 353JET FUEL: JP-3 5 0111 27 354JET FUEL: JP-4 5 0111 27 D 355JET FUEL: JP-5 (KEROSENE. HEAVY) 5 0111 27 0 356KEROSENE 4N 0111 8008-20-6 27 DG 357

20-0EC-85CHEMICAL NAME CHRIS CFR OTHER TLV-TWA STEL IDLH ODOR CS CS/TWA SEG


LACTIC ACID LTA D 358LARD D 359LATEX. LIGUID SYNTHETIC LLS D 360LEAD DUST 0.15 MG/M3 361LEAD FUMES O. 15 MG/M3 362LIQUIFIED NATURAL GAS (OR LPG) LNG 0 363MAGNESIUM NONYL PHENOL SULFIDE 0 364MAGNESIUM SULFONATE 0 365 -i

:J::>MALEIC ANHYDRIDE MLA 0 O. 25 O. 4 0 lEO O. 3EO 366 COMALEIC ANHYDRIDE COPOLYMER D 367 r

('TlMANGANESE (FUME) 1. 0 MG/M3 3 MG/M3 3682-MERCAPTOBENZOTHIAZOLE (SOLUTIONS) MBT D 369 :J::>

IMERCURY 0.05 MG/M3 28 MG/M3 370 wMESITYL OXIDE MSO 0 15 25 5000 O. 05 1. lE4 7. 3E2 371METHACRYLIC ACID MAD 0 20 5.0 1. 3E3 6. 5El 372METHANE MTH 0 373 ::::

:J::>METHOXYTRIGLYCOL MTG 0 374 U'lMETHVL ACETATE I MTT 0 200 250 10000 4. 6 2. 2E5 1. lE3 375 -i

('TlMETHVL ACETOACETATE 0 376 :::0METHYL ACETYLENE. PROPAOIENE MIXTURE MAP 0 1000 1250 20000 100,0 1. OE6 1.0E3 377 rMETHYLACRYLATE MAM 0 SKIN 10 1000 00059.0E4 9. OE3 378 ........METHYL ALCOHOL MAL D SKIN 200 250 25000 53.3 1.3E5 6. 5E2 379 U'l

-iMETHYLAMINE SOLUTION (42% OR LESS) MSZ 0 10 100 0.02 1. OE6 1,OE5 380 ........METHYL AMYL ACETATE MAC D 50 0.04 4.7E3 381 :zMETHYL AMYL ALCOHOL(METHYLISOBUTYL CARB. MAA 0 SKIN 25 40 2000 6. 6E3 2.6E2382

G")

METHYL BROMIDE MTB 0 SKIN 5 15 2000 0.23 1.0E6 2.0E5383 0"'TlMETHYL BUTANOL (ISOAMYL ALCOHOL) D 100 125 8000 1.0 384

:J::> METHYL-T-BUTYL ETHER MBE 0 385 ::J:I U'lN METHYL CHLORIDE MTC 0 50 100 1000 1.0E6 2.0E4386 aw 2-METHYL-6-ETHYL ANILINE MEN 0 SKIN 260 387 U'l

METHYL ETHYL KETONE (2~BUTANONE) MEK 0 200 300 3000 4.681.3E5 6. 5E2 388 a2-METHYL-5-ETHYLPYRIOINE MEP 0 1.2E3 389 :J::>

-iMETHYL FORMAL MTF 0 390 :J::>METHYL FORMATE MFM 0 100 150 5000 2000.0 5,.3E5 5.3E3391METHYL HEPTYL KETONE (ETHYL AMYL HEPTANO MHK 0 25 3000 5.0 392 n2-METHYL-2-HYDROXY-3-BUTYNE MHO 0 393 0METHYL ISOBUTYL CARBINOL MIC D SKIN 25 40 2000 0.035.0E3 2.0E2394 :z

-iMEHTYL ISOBUTYL KETONE (HEXONE) MIK D 50 75 3000 0.5 1. 3E4 2.6E2395 -METHYL METHACRYLATE MMM 0 100 125 4000 0,24.6E4 4.6E2396 aMETHYL NAPHTHALENE MNA 0 3972-METHYL PENTENE MPN 0 3982-METHYLPYRIOINE MPR 0 399I-METHYLPYRROLIOONE MPY 0 400ALPHA-METHYLSTYRENE MSR 0 50 100 5, 4E3 1. lE2 401MINERAL SPIRITS MNS 0 100 5000 3. 4E4 402MONOCHLOROD I FLUOROMETHANE MCF 0 1000 1250 20000 403MONOCHLOROTETRAFLUOROETHANE MTE 0 404MONOCHLOROTRI FLUOROMETHANE MCM 0 405MONOETHANOLAMINE (ETHANOLAMINE) MEA 0 3 6 1000 4.05.3E2 406MONO ISOPRoPANoLAMINE MPA 0 407MORPHoLINE MPL 0 SKIN 20 30 8000 0.07 9.2E3 4.6E2408

20-DEC-85CHEMICAL NAME TOX CARC NFPA SEC CAS EMRSP BIO NIOSH BIO QUAL QUAN TLV SEQ

CODE REF NAS PROD GUIDE MED GUIDE MON DT DT DT NO·

LACTIC AC 10 5 ---- 50-21-5 358LARD 5 ---- 359LATEX. LIQUID SYNTHETIC 5 ---- 9016-00-6 360LEAD DUST 6 7439-92-1 U 361LEAD FUMES 6 .7439-92-1 U 362LIGUIFIED NATURAL GAS (OR LPG) 5 -000 22 0 363MAGNESIUM NONYL PHENOL SULFIDE 5 ---- 364MAGNESIUM SULFONATE 5 ---- 365 -;

:PMALEIC ANHYDRIDE 3 3221 108-31-6 60 X X 366 OJ

MALEIC ANHYDRIDE COPOLYMER 5 ---- 367 r-I"T'1

MANGANESE (FUME) 6 7439-96-5 X 3682-MERCAPTOBENZOTHIAZOLE (SOLUTIONS) 5 ---- 2492-26-4 369 ::l:>

IMERCURY 6 7439-97-6 60 X U 370 wMESITYL OXIDE 3 3222 141-79-7 26 II 371METHACRYLIC ACID 3 ---- 79-41-4 60 II 0 372METHANE 3 -000 74-82-8 22 II D 373 ::::

:PMETHOXYTRIGLYCOL 5 ---- 374 VlMETHYL ACETATE 3 1201 79-20-9 X X 0 375 -l

METHYL ACETOACETATE 5 105-45-3 376 I"T'1---- :::0METHYL ACETYLENE. PROPADIENE MIXTURE 3 ---- 17 II X 377METHYLACRYLATE 3. 2323 96-33-3 27 X X DG 378 r-......METHYL ALCOHOL 3. 1112 67-56-1 28 X II U DG G 379 (/)

METHYLAMINE SOLUTION (42X OR LESS) 2 --- 74-89-5 68 I( G G 380 --!.......METHYL AMYL ACETATE 4N 1211 108-84-9 26 381 :z:METHYL AMYL ALCOHOL(METHYLISOBUTYL CARB. 3 2212 108-11-2 26 382 C'>

METHYL BROMIDE 2 ---- 74-83-9 55 X X DC D 383 0METHYL BUTANOL (ISOAMYL ALCOHOL) 3 ---- 123-51-3 I( 384

....,::l:> METHYL-T-BUTYL ETHER 5 ---- 26 385 ~,

METHYL CHLORIDE 2 2002 74-87-3 18 X X 0 386 (/)

N 0

""'" 2-METHYL-6-ETHYL ANILINE 4L ---- 24549-06-2 387 Vl

METHYL ETHYL KETONE (2-BUTANONE) 3. 1112 78-93-3 26 I( U DG G 388 02-METHYL-5-ETHYLPYRIDINE 5 2222 104-90-5 60 389 :PMETHYL FORMAL 5 2111 390 -;

::l:>METI:iYL FORMATE 3 2311 107-31-3 26 X X 391METHYL HEPTYL KETONE (ETHYL AMYL HEPTANO 4H ---- 821-55-6 392 n2-METHYL-2-HY~ROXY-3-BUTYNE 5 2--- 393 0METHYL ISOBUTYL CARBINOL 3. 2212 108-11-2 26 X II 394 :z:

--!MEHTYL ISOBUTYL KETONE (HEXONE) 3. 2111 108-10-1 26 X DG 395 -METHYL METHACRYLATE 3 2323 80-62-6 27 X II DG D 396 0

METHYL NAPHTHALENE 5 ---- 1321-94-4 3972-METHYL PENTENE 5 ---- 763-29-1 3982-METHYLPYRIDINE 5 2221 109-06-8 399I-METHYLPYRROLIDONE 5 2--- 872-50-4 400ALPHA-METHYLSTYRENE 3 1--- 98-83-9 X 401MINERAL SPIRITS 4H 0--- 8030-30-6 DG 402MONOCHLORODIFLUOROMETHANE 4N -001 75-45-6 12 0 403MONOCHLOROTETRAFLUOROETHANE 5 ---- 63938-10-3 404MONOCHLOROTRIFLUOROHETHANE 5 ---- 75-72-9 405MONOETHANOLAMINE (ETHANOLAMINE) 3 2222 141-43-5 60 D 406MONOISOPROPANOLAMINE 5 -121 78-96-6 407MORPHOLINE 3 2111 110-91-8 29 II X DC G 408



MOTOR FUEL ANTIKNOCK CMPOS CPB ALKYLS) MFA 0 SKIN O. 10 MG/M3 40 0.26.6E3 409NAPHTHA: AROMATIC (10% OR LESS BENZENE) 0 100 5.0 410NAPHTHA: COAL TAR NCT 0 300 10000 5.03.9E3 411NAPHTHA: CRACKING FRACTION 0 100 412NAPHTHA: HEAVY 0 100 413NAPHTHALENE NTH 0 10 15 500 0.03 1. 3E3 1. 3E2 414NAPHTHA: PARAFFINIC 0 100 415NAPHTHA: PETROLEUM 0 100 10000 416 --l

)::-NAPHTHA: SOLVENT NSV 0 100 5000 417 toNAPHTHA: STODDARD SOLVENT NSS 0 100 200 5000 3. 9E3 418 r-

['T1NAPHTHA: VM Il.< P (75% NAPHTHA) NVM 0 300 400 5000 100.03.9E3 419NAPHTHENIC AC 10 NTI 0 420 )::-

INICKEL 1.0 MG/M3 421 wNITR IC ACID NAC 0 2 4 100 4, 3E4 2. 2E4 422NITRIC ACID (70% OR LESS) NCO 0 2 4 100 4. 3E4 2. 2E4 423NITROBENZENE NTB 0 SKIN 1 2 200 O. 0 2. 6E2 2.6E2424 3:

)::-NITROGEN, LIQUIFIEO NXX 0 425 InNITROGEN OX I DES 3 5 25 5. 0 426 --l

['T12-NITROPHENOL NTP 0 427 :;c1-NITROPROPANE NPN 0 25 35 2300 300.0 9.9E3 3.9E2428 r-NITROPROPANE (1-. 2-, AND MIXTURES) NPM 0 10 (2-) 20 (2-) 2300 75.0 429 .......2-NITROPROPANE NPP 0 10 20 2300 300.0 1.7E4 6.8E2430 In

--lNITROPROPANE (60X). NITROETHANE (40X) NNM 0 10 1.2-) 20 (2-) 2300 83.0 431 .......O-NITROTOLUENE NIE 0 SKIN 2 200 3.0 1. 3E3 432 :zNlTROTOLUENE CO. P. AND MIXTURES) NIT 0 SKIN 2 200 3. 0 433 Ci>

P-NITROTOLUENE NTT 0 2 200 1.3E2 434 aNONANE NAN 0 200 250 5000 0.43 1.3E4 6. 5El 435

.,.,:;p NONANOIC ACID D 1.3E3 436 ~

I NONANOIC-TRIOECANOIC ACID MIXTURE 0 437 InN 0(J"1 NONENE NON D 438 In

1-NONENE NNE 0 439 0NONYL ALCOHOL 0 3.9E2 440 )::-

NONYL PHENOL NNP 0 441 --l)::-

NONYL PHENOL (ETHOXYLATEOl 0 442NONYL PHENOL SULFIDE (30% OR lESS) D 443

........("")

OCTAOECENE 0 444 aOCTADECENEAMIOE (OLEAMIOEl 0 445 :z

--lOCTANE DAN 0 300 375 3700 150.01.4E4 1, 1E2 446 -OCTENE 0 447 0

OCTYl ACETATE 0 5. 3E2 448ISO-OCTYL ALCOHOL 0 4.0E3 449N-OCTYL ALCOHOL 0 450OCTYL EPOXYTALlATE OET 0 451OCTYl PHTHALATE 0 5 MG/M3 452OIL: CLARIFIED OCF 0 453OIL: CRUDE CSOUR) OIL 0 10 CH2S) 454OIL: DIESEL ODS 0 455OIL. EDIBLE: BEECHNUT 0 456OIL. EDIBLE: CASTOR DCA D 457OIL. EDIBLE: COCOA BUTTER 0 458OIL. EDIBLE: COCONUT OCC 0 459


CODE REF NAS PROD GUIDE MED GUIDE MON DT DT DT No_

MOTOR FUEL ANTIKNOCK CMPDS (PB ALKYLS) 2 ---- 78-00-2 56 409NAPHTHA: AROMATIC (107. OR LESS BENZENE) 4N ---- 8030-30-6 27 D 410NAPHTHA: COAL TAR 4N ---- 8030-30-6 27 411NAPHTHA: CRAC~ING FRACTION 4N ---- 8030-30-6 27 412NAPHTHA: HEAVY 4N ---- 8030-30-6 27 413NAPHTHALENE 3' 2212 91-20-3 32 X X 414NAPHTHA: PARAFFINIC 4N ---- 8030-30-6 27 415NAPHTHA: PETROLEUM 4N ---- 8030-30-6 27 X 0 416 -I

::t:>NAPHTHA: SOLVENT 4N ---- 8030-30-6 27 D 417 toNAPHTHA: STODDARD SOLVENT 3 0--- 8052-41-3 27 X 0 G G 418 r-

l'T1NAPHTHA: VM ~ P (757. NAPHTHA) 4H ---- 8030-30-6 27 D 419NAPHTHENIC ACID 5 -113 1338-24-5 420 ::t:>

INICKEL 6 7440-02-0 X U D o 421 wNITR IC AC ID 2 2343 7697-37-2 44 X X DG OG 422NITRIC ACIO (707. OR LESS) 2 ---- 7697-37-2 44 X X 0 423NITROBENZENE 2 3324 98-95-3 55 X X U 424 3:

::t:>NITROGEN. LIGUIFIED 5 ---- 7727-37-9 21 425 VlNITROGEN OXIDES 6 10102-44-0 X 426 -I

l'T12-NITROPHENOL 5 ---- 88-75-5 55 427 :::0I-NITROPROPANE 3 ---- 108-03-2 26 X X 428 r-NITROPROPANE ( 1-. 2-:-. AND MIXTURES) 1 A2 ---- 26 429 ......2-NITROPROPANE 1 A2 1111 79-46-9 26 X 430 Vl

-INITROPROPANE (b07.). NITROETHANE (407.) 1 A2 ---- 26 431 ......O-NITROTOLUENE 31 2--- 99-08-1 55 X 432 zNITROTOLUENE (0. P. AND MIXTURES) 3 ---- 99-08-1 55 X 433

G)

P-N ITROTOLUENE 3 3--- 99-08-1 55 X X 434 0

NONANE 3 0000 111-84-2 27 X 435 ",- .«

::t:> NONANOIC ACID 5 ---- 112-05-0 436 :cI NONANOIC-TRIDECANOIC ACID MIXTURE 5 ---- 437 Vl

N t:l0'\ NONENE 5 -110 27215-95-8 438 Vl

I-NONENE 5 -110 27215-95-8 439 t:lNONYL ALCOHOL 5 -000 143-08-8 440 ::t:>NONYL PHENOL 5 1121 25154-52-3 441 -I

::t:>NONYL PHENOL (ETHOXYLATED) 5 ---- -442NONYL PHENOL SULFIDE (307. OR LESS) 5 ---- 443 nOCTADECENE 5 ---- 444 0OCTADECENEAMIDE (OLEAMIDEI 5 ---- 445 z

-IOCTANE 3 0--- 111-65-9 27 X X DG G 44b -OCTENE 5 ---- 25377-83-7 447 t:l

OCTYL ACETATE 5 ---- 112-14-1 448ISO-OCTYL ALCOHOL 5 -001 449N-OCTYL ALCOHOL 5 ---- 111-87-5 450

.OCTYL EPOXYTALLATE 5 ---- 451OCTYL PHTHALATE 4N ---- 117-84-0 452OIL: CLARIFIED 5 ---- D 453OIL: CRUDE (SOUR) 31 1011 H2S D 454OIL: DIESEL 9 0--- D 455

'<' -OIL. EDIBLE: BEECHNUT 5 ---- 456OIL. EDIBLE: CASTOR 5 ---- 457OIL. EDIBLE: COCOA BUTTER 5 ---- 458OIL. EDIBLE: COCONUT 5 0--- 459



OIL. EDIBLE: COCONUT OIL, ESTERIFIED D 460OIL. EDIBLE: COCONUT OIL FATTY ACID D 461OIL EDIBLE: COCONUT OIL. METHYL ESTER D 462OIL. EDIBLE: COD LIVER D 463OIL. EDIBLE: CORN D 464OIL. EDIBLE: COTTONSEED OCS 0 465OIL EDIBLE: COTTON SEED FATTY ACIO D 466OIL. EDIBLE: FISH OFS 0 467 --i

)::>OIL. EDIBLE: GRAPESEED D 468 O:JOIL. EDIBLE: GROUNDNUT D 469 r-

,."OIL. EDIBLE: HAZELNUT D 470OIL, EDIBLE: LARD OLD D 471 )::>

IOIL. EDIBLE: MAIZE D 472 wOIL. EDIBLE: MUSTARD SEED D 473OIL. EDIBLE: NUTMEG BUTTER D 474OIL. EDIBLE: OLIVE DOL D 2. 7E3 475 3:

)::>OIL, EDIBLE: PALM OPM D 476 VlOIL. EDIBLE: PEANUT OPN D 2. 7E3 477 --i

,."OIL. EDIBLE: POppy D 478 ;;J;JOIL EDIBLE: RAISIN SEED D 479 r-OIL. EDIBLE: RAPESEED D 480 ......OIL. EDIBLE: RICE BRAN D 481 Vl

--iOIL. EDIBLE: SAFFLOWER OSF D 482 ......OIL. EDIBLE: SALAD D 483 :::zOIL. EDIBLE: SESAME D 484 enOIL EDIBLE: SOYA BEAN OSB D 2. 7E3 485 0OIL EDIBLE: SOYBEAN (EPOXIDIZED) D 486

..,.,)::> OIL EDIBLE: SUNFLOWER SEED D 487 :I:I

VlN OIL EDIBLE: TUCUM OTC 0 488 0..... OIL, EDIBLE: VEGETABLE OVG D 489 VlOIL. EDIBLE: WALNUT D 490 COIL FUEL: NO 1 (KEROSENE) DON D 100 MG/M3 1.0 491 )::>

OIL FUEL: NO. I-D ODD D 100 MG/M3 1.0 492 --i)::>

OIL FUEL: NO. 2 OTW D 493OIL. FUEL: NO. 2-D OTD D 494 ("")OIL. FUEL: NO. 4 OFR D 495 0OIL. FUEL: NO. S OFV D 496 :::z

--iOIL. FUEL: NO. 6 OSX D 497 -OIL. MISC: ABSORPTION OAS D 498 0

OIL. MISC: ALIPHATIC D 5 MG/M3 499OIL. MISC: ANIMAL D 500OIL. MISC: AROMATI~ (5% OR LESS BENZENE) D 5 MG/M3 901OIL. MISC: AVIATION F2300 D 5 MG/M3 902OIL. MISC: CASHEW NUT SHELL OCN 0 503OIL. MISC: COAL D' 5 MG/M3 504OIL. MISC: COAL TAR OCT D 505OIL. MISC: CROTON OCR D 506OIL. MISC: GAS, LOW POUR D 507OIL. MISC: GAS, LOW SULFUR D 508OIL. MISC: HEARTCUT DISTILLATE D 5 MG/M3 509OIL. MISC: LANOLIN D 510



OIL. EDIBLE: COCONUT OIL ESTERIFIED 5 ---- 460OIL EDIBLE: COCONUT OIL FATTY ACID 5 ---- 461OIL. EDIBLE: COCONUT OIL. METHYL ESTER 5 ---- 462OIL. EDIBLE: COD LIVER 5 ---- 463OIL EDIBLE: CORN 5 ---- 464OIL. EDIBLE: COTTONSEED 5 0--- 465OIL. EDIBLE: COTTON SEED FATTY ACID 5 ---- 466OIL. EDIBLE: FISH 5 ---- 467 --i

:x::oOIL. EDIBLE: GRAPESEED 5 ---- 468 o;l

OIL. EDIBLE: GROUNDNUT 5 ---- 469 r-I'T1OIL EDIBLE: HAZELNUT 5 ---- 470

OIL. EDIBLE: LARD 5 0--- 471 ~IOIL. EDIBLE: MAIZE 5 ---- 472 <..oJ

OIL EDIBLE: MUSTARD SEED 5 ---- 473OIL. EDIBLE: NUTMEG BUTTER 5 ---- 474OIL. EDIBLE: OLIVE 5 ---- 475 3:

:t:>OIL. EDIBLE: PALM 5 0--- 476 VlOIL. EDIBLE: PEANUT 5 0--- 477 --i

I'T1OIL. EDIBLE: POppy 5 ---- 478 ;0OIL. EDIBLE: RAISIN SEED 5 ---- 479 r-OIL EDIBLE: RAPESEED 5 ---- 480 ......OIL EDIBLE: RICE BRAN 5 ---- 481 Vl

OIL. EDIBLE: SAFFLOWER 5 ---- 482 --i......OIL. EDIBLE: SALAD 5 ---- 483 :zOIL EDIBLE: SESAME 5 ---- 484 G')

OIL. EDIBLE: SOYA BEAN 5 0--- 485 0OIL. EDIBLE: SOYBEAN (EPOXIDIZED> 5 ---- 486

.,.,:t:> OIL EDIBLE: SUNFLOWER SEED 5 ---- 487 :::I:I

VlN OIL EDIBLE: TUCUM 5 0--- 488 0CO OIL. EDIBLE: VEGET"BLE 5 0--- 489 VlOIL. EDIBLE: WALNUT 5 ---- 490 0OIL. FUEL: NO 1 (KEROSENE) 4N 0111 8008-20-6 27 D 491 :t:>OIL. FUEL: NO I-D 4H 0--- 0 492 --i

:t:>OIL. FUEL: NO. 2 5 0--- 0 493OIL. FUEL: NO, 2-D 5 0--- 0 494 nOIL FUEL: NO. 4 5 0--- D 495 0OIL. FUEL: NO. 5 5 0--- 0 496 :z

--iOIL FUEL: NO. b 5 0--- 0 497 -OIL. MISC: ABSORPTION 5 ---- 498 CJ

OIL MISC: ALIPHATIC 4H ---- 0 499OIL. MISC: ANIMAL 5 ---- 500OIL. MISC: AROMATIC (5% OR LESS BENZENE) 4H ---- 0 501OIL MISC: AVIATION F2300 4H ---- 502OIL. MISC: CASHEW NUT SHELL 5 ---- 503OIL MISC: COAL 4H ---- D 504OIL. MISC: COAL TAR 5 -112 505OIL MISC: CROTON 5 ---- 506OIL. MISC: GAS. LOW POUR 5 ---- 0 507OIL. MISC: GAS. LOW SULFUR 5 ---- 0 508OIL. MISC: HEARTCUT DISTILLATE 4H ---- 509OIL. MIse: LANOLIN 5 ---- 510

20-DEC-85CHEMICAL NAME CHRIS CFR OTHER TLV-TWA STEL IDLH DOOR CS CS/TWA SEQ


OIL, MISC: LINSEEO OLS 0 511OIL. MISC: LUBRICATING OLB 0 5 MG/M3 512OIL, MISC: MINERAL OMN 0 5 MG/M3 513OIL, MISC: MINERAL SEAL OMS 0 514OIL. MISC: MOTOR OMT 0 5 MG/M3 515OIL. MISC: NEATSFOOT ONF 0 516OIL. MISC: OITICIA 0 517

-lOIL. MISC: PENETRATING OPT 0 518 ~OIL. MISC: PERILLA 0 519 toOIL. MISC: PILCHARO 0 520 r-

I'TlOIL. MISC: PINE 0 521~OIL. MISC: RANGE ORG 0 522 IOIL. MISC: RESIDUAL 0 523 Lv

OIL. MISC: RESIN DRS 0 524OIL. MISC: RESINOUS PETROLEUM D 525

:::;:OIL. MISC: ROAO ORO 0 526 ~OIL. MISC: ROSIN ORN 0 527 (/)

OIL. MISC: SEAL D 528 -lI'TlOIL. MISC: SOAPSTOCK 0 529 :;0

OIL. MISC: SPERM OSP 0 2. 6E3 530 r-OIL. MISC: SPINOLE OSO 0 531 ......OIL. MISC: SPRAY OSY 0 532 (/)

-lOIL. MISC: TALL OTL 0 2.0E3 533 ......OIL. MISC: . TALL. FATTY ACID 0 534 :z

Ci>OIL. MISC: TANNER'S OTN 0 535OIL. MISC: TRANSFORMER OTF 0 536 a

"OIL. MISC: TUNG D 537~. OIL. MISC: TURBINE OTB 0 538 :::I:I (/)

N OIL. MISC: WHALE 0 539 0\D OIL. MISC: WH ITE (1'1 I NERALl 0 5 I'IG/M3 540 (/)

OIL, MISC: WOOD 0 541 0OLEIC AC 10 OLA D 1.3E3 542 ~

-lOLEUM OLM 0 1 MG/1'I3 543 ~OLEYL ALCOHOL (OCTADECANOL) D 544ORGANIC AI'IINE 70 0 545 nOZONE O. 1 10 O. 05 546 a

:zPAINT PIGMENTS (DRY) 1.0 MG/M3 547 -lPARALDEHYDE PDH 0 1. 5 MG/M3 15 MG/M3 0.8 3.3E4 548 -PENTACHLOROETHANE PCE 0 4. 5E3 549 0

PENTAOECANOL POC 0 5501. 3-PENTADIENE POI 0 551PENTAETHYLENE GLYCOL 0 552N-PENTANE PTA 0 600 750 5000 990.0 5.7E5 9. 5E2 553I-PENTENE PTE 0 5. 3E5 554PERCHLOROETHYLENE(TETRACHLOROETHYLENE) PER 0 50 200 500 4.7 2. lE4 4.2E2555PETROLATUI'I PTL 0 556PHENOL PHN 0 SKIN 5 10 100 O. 2 4. 7E2 9.'4El 557PHOSPHORIC ACID PAC 0 1 MG/M3 3 MG/M3 3.9El 558PHOSPHORIZED BICYCLIC TERPENE 0 559PHOSPHORUS. WHITE PPW 0 O. 1 MG/M3 0.3 I'IG1 1'13 560PHTHALATE PLASTICIZERS 0 561

20-DEC-8~

CHEMICAL NAME TOX CARC NFPA SEC CAS EMRSP BID NIOSH BID QUAL QUAN TLV SEQCODE REF NAS PROD GUIDE MED GUIDE MON DT DT DT NO.

OIL. MISC: LINSEED 5 0--- 511OIL. MISC: LUBRICATING 4H 0--- 0 512OIL. MISC: MINERAL 4H 0--- X X D 513OIL. MISC: MINERAL SEAL 5 ---- 514OIL. MISC: MOTOR 4H ---- D" 515OIL, MISC: NEATSFOOT 5 ---- 516OIL. MISC: OITICIA 5 ---- 517OIL. MISC: PENETRATING 5 ---- 518 --i

~OIL. MISC: PERILLA 5 ---- ~19 OJOIL. MISC: PILCHARD 5 ---- 520 r-

('Tl

OIL. MISC: PINE 5 ---- 521OIL. MISC: RANGE 5 0111 522 ~

IOIL. MISC: RESIDUAL 5 ---- D 523 wOIL. MISC: RESIN 5 -222 524OIL. MISC: RESINOUS PETROLEUM 5 ---- 525OIL. MISC: ROAD 5 0121 526 3:OIL. MISC: ROSIN 5 -222 527

~Vl

OIL. MISC: SEAL 5 ---- 528 --i('Tl

OIL. MISC: SOAPSTOCK 5 ---- 529 :;;0

OIL. MISC: SPERM 5 -010 530 r-OIL. MISC: SPINDLE 5 ---- 531 ......OIL. MISC: SPRAY 5 0111 532 Vl

OIL. MISC: TALL 5 ---- 533 --i......OIL. MISC: TALL. FATTY ACID 5 ---- 534 :zOIL. MISC: TANNER'S 5 ---- 535

G)

OIL. MISC: TRANSFORMER 5 0--- D ·536 aOIL. MISC: TUNG 5 ---- 537

,.,~ OIL. MISC: TURBINE 5 0--- 538 :::I:Iw OIL. MISC: WHALE 5 ---- 539 Vl

0a OIL. MISC: WHITE (MINERAL> 4H ---- 540 Vl

OIL. MISC: WOOD 5 ---- 541 0OLEIC ACID 5 0--- 112-80-1 542 ~

OLEUM 3 3443 8014-95-7 39 D 543 --i~

OLEYL ALCOHOL (OCTADECANOL) 5 ---- 544ORGANIC AMINE 70 5 ---- 545 nOZONE 6 10028-15-6 X 546 aPAINT PIGMENTS (DRY) 6 547 :z

--iPARALDEHYDE 4H 2--- 123-63-7 26 548 -PENTACHLOROETHANE 5 ---- 76-01-7 55 549 0

PENTADECANOL 5 ---- 5501. 3-PENTADIENE 5 ---- 2004-70-8 551PENTAETHYLENE GLYCOL 5 ---- 552N-PENTANE 3 1001 109-66-0 27 X X DG DG 553l-PENTENE 5 ---- 554PERCHLOROETHYLENE(TETRACHLOROETHYLENE) 3. -112 127-18-4 74 X DG DG 555PETROLATUM 5 ---- 8012-95-1 556PHENOL 2 3233 108-95-2 55 X U DG DG 557PHOSPHORIC ACID 3 2031 7664-38-2 60 X x 558PHOSPHORIZED BICYCLIC TERPENE 5 ---- 559PHOSPHORUS. WHITE 2 3-44 7723-14-0 560PHTHALATE PLASTICIZERS 5 ---- 561

20-DEC-B5CHEMICAL NAME CHRIS CFR OTHER TLV-TWA STEL IDLH ODOR CS CS/TWA SEQ


PHTHALIC ANHYDRIDE PAN 0 1 4 5 0.056.6El 6.6E1562PINENE D 563POLYALKENYL SUCCINIC ANHYDRIDE AMINE D 564POLYAMINE. AMIDE MIXTURE D 565POLYBUTENE PLB D 566POLYETHYLENE GLYCOL 0 567POLYETHYLENE POLYAMINES PEB 0 568

-IPOLYISOBUTYLENE D 569 ;x:.POLYMERIZED ESTER D 570 to

IPOLYMETHYLENE POLYPHENYL ISOCYANATE PPI 0 0.01 5 O. 4 571 rr1POLYPROPYLENE PLP D 572 ;x:.POLYPROPYLENE GLYCOL PGC D 573 IPOLYPROPYLENE GLYCOL METHYL ETHER PGM D 574 wPOLYSTYRENE DIALKYL MALEATE 0 575POLYVINYLBENZYLTRIMETHYL AMMONIUM CHLORI PVB 0 576

3:PROPANE PRP 0 20000 1.0E6 577 ;x:.N-PROPANOLAMINE PLA 0 2. 8E3 578 l/)

PROPIONALDEHYDE PAD 0 4000 3 4E5 579 -Irr1PROP ION I C AC ID PNA 0 10 15 O. 1 3.2E3 3.2E2580 :::c

PROPIONIC ANHYDRIDE PAH 0 1.3E3 5Bl IPROPIONITRILE PCN 0 SKIN 6 5. lE4 5B2 .......N-PROPYL ACETATE PAT 0 200 250 BOOO 20.0 3.3E4 1.7E2583 l/)

-IN-PROPYL ALCOHOL PAL 0 SKIN 200 250 4000 40.01.9E4 2.6E2584 .......N-PROPYLAMINE PRA 0 1. 0 3.2E5 585 :z

'"PROPYL BENZENE D 3. 3E3 586PROPYLENE PPL 0 1000 1250 10000 B5.0 1. OE6 5B7 0....,PROPYLENE BUTYLENE POLYMER PBP 0 5BB;x:. PROPYLENE GLYCOL PPG D 2.6E2 589 ::c

I l/)w PROPYLENE GLYCOL METHYL ETHER PME D 100 590 0I-' PROPYLENE OXIDE POX 0 20 2000 65.05.9E5 2.9E4591 l/)

PROPYLENE POLYMER 0 592 0PROPYLENE TETRAMER PTT D 593 ;x:.

-IPROPYLENE TRIMER D 594 ;x:.PSEUDOCUMENE (1.2.4-TRIMETHYLBENZENEl 0 25 8000 O. 05 595PYRIDINE PRO 0 5 10 3600 0.17 2.4E4 4. 7E3 596 nRUM 0 597 0

:zSAND O. 3 MG/M3 59B --lSILICA 0.3 MG/M3 599 -

0SILICON TETRACHLORIDE STC 0 C5 (HCLl 100 600SODIUM ACETATE. GLYCOL. WATER SOLUTIONS 0 601SODIUM BOROHYDRIDE (137.l SBI 0 602SODIUM BOROHYDRIDE «~157.l. NAOH/SOLUT SBX 0 :2 MG/M3 603SODIUM CHLORATE (507. OR LESSl SDD 0 604SODIUM DICHROMATE SOLUTION «=697.l(CRVIl SDL 0 0.05 MG/M3 605SODIUM HYDROSULFIDE SOLUTION «~45X) SHR 0 10 (H2Sl 606SODIUM HYPOCHLORITE SOLUTION «=157.) SHP 0 607SODIUM 2-MERCAPTOBENZOTHIAZOL SOLUTION 5MB 0 608SODIUM SULFONATE D 609STEAR I C AC ID SRA D 610STEARYL ALCOHOL (OCTADECANOLl D 611STYRENE STY 0 50 100 5000 0.156.6E3 1. 3E2 612

20-DEC-85CHEMICAL NAME TOX CARC NFPA SEC CAS EMRSP DID NIOSH BID QUAL QUAN TLV SEQ

CODE REF NAS PROD GUIDE MED GUIDE MON DT DT DT NO_

PHTHALIC ANHYDRIDE 3 2231 85-44-9 60 X X 562PINENE 5 ---- 80-56-8 26 563POLYALKENYL SUCCINIC ANHYDRIDE AMINE 5 ---- I 564POLYAMINE, AMIDE I'll XTURE 5 ---- 565POLYBUTENE 5 0--- 566POLYETHYLENE GLYCOL 5 ---- 25322-68-3 567POLYETHYLENE POLYAMINES 5 ---- 568POLYISOBUTYLENE 5 ---- 569 --l

:;r::.POLYMERIZED ESTER 5 ---- 570 OJ

POLYMETHYLENE POLYPHENYL ISOCYANATE 4C -324 571 rI'T1

POLYPROPYLENE 5 ---- 572POLYPROPYLENE GLYCOL 5 ---- 25322-69-4 573 :;r::.

IPOLYPROPYLENE GLYCOL METHYL ETHER 5 ---- 574 wPOLYSTYRENE DIALKYL MALEATE 5 ---- 575POLYVINYLBENZYLTRIMETHYL AMMONIUM CHLORI 5 ---- 576PROPANE 3 1000 74-98-6 22 X X DG 577 3:

:;r::.N-PROPANOLAMINE 5 ---- 578 VlPROP IONALDEHYDE -4L 2212 123-62-6 26 D 579 --l

I'T1PROPIONIC ACID 3* 2232 79-09-4 29 X D 580 ::0PROPIONIC ANHYDRIDE 5 2321 123-62-6 29 581 rPROPIONITRILE 4L ---- 107-12-0 28 G 582 .......N-PROPYL ACETATE 3 -112 109-60-4 26 X X G G 583 Vl

--lN-PROPYL ALCOHOL 3 -102 71-23-8 26 X X DG DG 584 .......N-PROPYLAMINE 4C 3--- 107-10-8 68 585 z

enPROPYL BENZENE 5 ---- 103-65-1 26 586PROPYLENE 3 1001 115-07-1 22 DG G- 587 0

PROPYLENE BUTYLENE POLYMER 5 588"'Tl----

:;r::. PROPYLENE GLYCOL 5 -000 57-55-6 589 :J:I Vlw PROPYLENE GLYCOL METHYL ETHER 4N ---- 107-98-2 X 590 0

N PROPYLENE OXIDE 2 2322 75-56-9 26 X X DG 591 Vl

PROPYLENE POLYMER 5 ---- 592 0PROPYLENE TETRAMER 5 0111 27 593 :;r::.

--lPROPYLENE TRIMER 5 -110 594 :;r::.PSEUDOCUMENE <1.2,4-TRIMET~YLBENZENE) 4N ---- 95-63-6 - 595PYRIDINE 3 2221 110-86-1 26 X X DG DG 596 ("')

RUM 5 ---- D 597 0SAND 6 14808-60-7 X 598 z

--lSILICA 6 14808-60-7 X X 599 -SILICON TETRACHLORIDE 3* -444 HCL 10026-04-7 39 600 0

SODIUM ACETATE. GLYCOL, WATER SOLUTIONS 5 ---- 127-09-3 601SODIUM BOROHYDRIDE <131.) 5 ---- 16940-66-2 32 602SODIUM BOROHYDRIDE «z151.). NAOH/SOLUT 4L ---- 16940-66-2 32 603SODIUM CHLORATE <501. OR LESS) 5 ---- 7775-09-9 31 604SODIUM DICHROMATE SOLUTION «:69X)(CRVI) 3 ---- 10588-01-9 35 605SODIUM HYDROSULFIDE SOLUTION «=45X) 3* ---- H2S 16721-80-5 59 606SqDIUM HYPOCHLORITE SOLUTION «=151.) 5 ---- 60 607SODIUM 2-MERCAPTOBENZOTHIAZOL SOLUTION 5 ---- 2492-26-4 608SODIUM SULFONATE 5 ---- 609STEARIC ACID 5 1--- 57-11-4 610STEARYL ALCOHOL (OCTADECANOL) 5 . ---- 112-92-5 611STYRENE 2 2222 100-42-5 _27 X X UB G Q 612

20-0EC-85CHEMICAL NAME CHRIS CFR OTHER TLV-TWA STEL IOLH ODOR CS CS/TWA SEQ


SULFOLANE SFL D 6.bE3 613SULFUR SXX 0 614SULFUR DIOXIDE SFD 0 2 5 100 1. 0 1. OE6 5.0E5 615SULFUR I C AC ID SFA 0 1 MG/M3 1.3EO bIbSULFURIC ACID, SPENT SAC 0 1 MGIM3 b17TALLOW TLO D 2.bE3 b18TALLOW FATTY ALCOHOL TFA D 619TALLOW NITRILE D 620 -l

:x:-1.1,2,2-TETRACHLOROETHANE TEC 0 SKIN 1 5 150 2.6 1. 7E4 I. 7E4 621 OJTETRADECANOL TTN D 622 r

rn1-TETRAOECENE TTO 0 623TETRADECYLBENZENE TDB D 624 :x:-

ITETRAETHYLENE GLYCOL TTG D 1.3EO 625 wTETRAETHYLENEPENTAMINE TTP 0 626TETRAHYDROFURAN THF 0 200 250 20000 2 0 1. 9E5 9. 5E2 627TETRAHYDRONAPHTHALENE THN D b28 3:TETRAPROPYL BENZENE D 629 :x:-

(,/')TITANIUM 5. 0 MG/M3 b30 -lTOLUENE TOL 0 SKIN 100 150 2000 2. 14 2. 9E4 2. 9E2 631 rn

::0TOLUENEDIAMINE TDA 0 632TOLUENE 2,4-DIISOCYANATE TOI 0 .005 .02 10 0.21 1.3E1 2.bE2 b33

,-......

TOLUENE DIISOCYANATE, DIPHENYLMET OIISOC TDD 0 .005 .02 10 O. 21 1. 3E1 634 (,/')

O-TOLUIDINE TLI 0 SKIN 2 100 1. 0 1.3E2 6. 5E1 b35 -l......TRIARYLPHOSPHATE D 636 Z1.2,4-TRICHLOROBENZENE TCB 0 C5 3.0 1. 3E3 2.6E2637 G")

1.1,2-TRICHLOROETHANE TCM 0 SKIN 10 20 500 2. 5E4 638 0TRICHLOROETHYLENE TCL 0 50 150 1000 21. 4 7.6E4 I. 5E3 639 ."

:t>oI 1,2,3-TRICHLOROPROPANE TCN 0 50 75 1000 2. 6E3 640 ::I:w TRICRESYL PHOSPHATE «1% O-ISOMER) TCP 0 O. 1 MG/M3 641 (,/')w 0TRICRESYL PHOSPHATE (~17. ORTHO) TCO 0 O. 1 MG/M3 642 (,/')

TRIDECANE D 643 0TRIDECANOIC ACID D 644 :x:-TRIDECANOL TDN D 645 -l

:x:-I-TRIOECENE TDC 0 646TRIDECYL BENZENE D 647 nTRIETHANOLAMINE TEA 0 1. 3El 648 0TRIETHYLAMINE TEN 0 10 15 1000 0.48 7.0E4 7. OE3 649 z

-lTRIETHYLBENZENE TEB D 650 -TRIETHYLENE GLYCOL TEG 0 1.3EO b51 0TRIETHYLENE GLYCOL DIETHYL BUTYRATE D 652TRIETHYLENE GLYCOL MONOMETHYL ETHER 0 b53TRIETHYLENETETRAMINE TET 0 654TRIETHYL PHOSPHATE D b55TRIISOOCTYL TRIMELLITATE D b56TRIISOPROPANOLAMINE TIP 0 6572,2.4-TRIMETHYL PENTANEDIOL-l.3-DIISOBUT D b58TRIMETHYLACETIC ACID TAA 0 659TRIMETHYL BENZENE D 25 35 100 O. 05 6bOTRIMETHYL HEXAMETHYLENE OIAMINE(224,244) THA 0 b61TRIMETHYL HEXAMETHYLENE DIISOCYANATE THI 0 6622,2,4-TRIMETHYL-3-PENTANOL-I-ISOBUTYRATE D 663

20-DEC-85CHEMICAL NAME TOX CARC NFPA SEC CAS EHRSP BIO NIOSH BIO QUAL QUAN TLV SEQ


SULFOLANE 5 -001 126-33-0 0 613SULFUR 5 1111 7704-34-9 32 614SULFUR DIOXIDE 2 3414 7446-09-5 16 X X DG DG 615SULFURIC ACID 3 3242 7664-93-9 39 X X 0 o 616SULFUR Ie AC ID, SPENT 3 3--- 7664-93-9 39 X X 617TALLOW 5 0--- 618TALLOW FATTY ALCOHOL 5 ---- 619TALLOW NITR I LE 5 ---- 620 ---l

:x:-1.1,2.2-TETRACHLOROETHANE 2 ---- 79-34-5 55 X X G 621 c:eTETRADECANOL 5 ---- 112-72-1 622 r-

m1-TETRADECENE 9 ---- 623TETRADECYLBENZENE 5 ---- 624 :x:-

ITETRAETHYLENE GLYCOL 5 1000 112-60-7 625 wTETRAETHYLENEPENTAMINE 5 2122 112-57-2 60 626TETRAHYDROFURAN 3 2112 109-99-9 26 X X DG G 627TETRAHYDRONAPHTHALENE 5 1112 119-64-2 628 :::s::

:x:-TETRAPROPYL BENZENE 5 ---- 629 tilTITANIUM 6 37 630 ---l

mTOLUENE 3. 2112 108-88-3 27 X X UB DG DG 631 ;0

TOLUENEDIAHINE 5 ---- 95-80-7 632 r-TOLUENE 2.4-DIISOCYANATE 2 3334 584-84-9 57 X D 633 .....TOLUENE DIISOCYANATE, DIPHENVLHET DIISOC 2 ---- 634 til

--iO-TOLUIDINE 1 A2 3--- 95-53-4 55 X G 635 .....TRIARYLPHOSPHATE 5 ---- 636 :z1. 2. 4-TRICHLOROBENZENE 3. ---- 120-82-1 54 X D 637

G)

1.1.2-TRICHLOROETHANE 3. ---- 79-00-5 74 X X G 638 0

TRICHLOROETHYLENE 2 -112 79-01-6 74 X UB DG G 639 "T1

:x:-I 1. 2. 3-TRICHLOROPROPANE 3 ---- 96-18-4 X X 640 :I:

w TRICRESYL PHOSPHATE «17. O-ISOMER) 4N ---- 78-30-8 55 X 641 til0.;:.

TRICRESYL PHOSPHATE ()17. ORTHO) 4N ---- 78-30-8 55 X 642 til

TRlDECANE 5 ---- 629-50-5 643 0TRIDECANOIC ACID 5 ---- 638-53-9 644 :x:-TRIDECANOL 5 -000 112-70-9 645 ---l

:x:-l-TR IDECENE 5 ---- 646TRIDECYL BENZENE 5 ---- 647 nTRIETHANOLAMINE 5 1011 102-71-6 68 0 648 0TR I.ETHYLAM I NE 3 -222 121-44-8 X DG DG 649 :z

---lTRIETHYLBENZENE 5 -111 25340-18-5 650 -TRIETHYLENE GLYCOL 5 -000 112-27-6 651 0

TRIETHYLENE GLYCOL DIETHYL BUTYRATE 5 ---- 95-08-9 652TRIETHYLENE GLYCOL HONOMETHYL ETHER ·5 ---- 112-35-6 653TRIETHYLENETETRAMINE 5 -221 112-24-3 60 654TRIETHYL PHOSPHATE 5 ---- 78-40-0 655TRIISOOCTYL TRIMELLITATE 5 ---- 656TRIISOPROPANOLAHINE 9 ---- 122-20-3 6572.2.4-TRIHETHYL PENTANEDIOL-l,3-DIISOBUT 5 ---- 6846-50-0 658TRIMETHYLACETIC ACID 5 ---- 75-98-9 659TRIMETHYL BENZENE 3 ---- 29551-13-7 26 X 660TRIMETHYL HEXAMETHYLENE DIAHINE(224.244) 5 ---- 60 661TRIMETHYL HEXAMETHYLENE DIISOCYANATE 5 ---- 55 6622. 2. 4-TRIMETHYL-3-PENTANOL-I-ISOBUTYRATE 5 ---- 663

20-0EC-85CHEMICAL NAME CHRIS CFR OTHER TLV-TWA STEL IOLH ODOR CS CS/TWA SEG


TRIMETHYL PHOSPHITE TPP 0 2 5 664TRIPROPYLENE D 665TRIPROPYLENE GLYCOL TGC D 1. 3E 1 666TRIPROPYLENE GLYCOL MONOMETHYL ETHER 0 667TRIXYLONYL PHOSPHATE 0 668TURPENTINE TPT 0 100 150 1900 6.6E3 6.6E1669TURPENTINE SUBSTITUTE CWHITE SPIRIT) 0 350 MG/M3 670UNDECANOL UNO 0 671 ----l

::t:>1-UNOECENE UOC 0 672 OJ

N-UNDECYLBENZENE UOB D 673 r-,."

UREA. AMMONIUM NITRATE SOLN () 2X NH3) UAS 0 25 CNH3l 35 CNH3l 674::t:>N-VALERALDEHYDE VAL 0 50 0.03 3.4E4 6. 8E2 675 I

VANADIUM 0.05 MG/M3 676 wVINYL ACETATE VAM 0 10 20 5000 0.4 1. 2E5 1.2E4 677VINYL ACETATE. FUMARATE COPOLYMER D 678VINYL CHLORIDE VCM 0 5 500 260.0 1.0E6 2. OES 679 3':

::t:>VINYL ETHYL ETHER VEE 0 5. 6E5 680 t.nVINYLI DENECHLOR IDE VCI 0 5 20 5000 500.05.3E5 1.6E5 681 ----l

,."VINYL NEOOECANATE VND 0 682 :;:0

VINYLTOLUENE VNT 0 50 100 500 10.06.4E3 1.3E2 683 r-WAX' CANOELILLA D 684 ......WAX: CARNAUBA WCA 0 685 t.n

----lWAX: PARAFFIN WPF D 2 MG/M3 6 MG/M3 686 ......WAX: PETROLEUM D 687 z

Cj)WELDING FUMES 5.0 MG/M3 688WHITE SPIRIT D 500 10000 O. 3 689 0

"'T'I);:> WHITE SPIRIT. LOW AROMATIC D 500 10000 O. 3 690I WINE D 691 :::I:

t.nw WOOL GREASE 0 692 0<..T1M-XYLENE XLM D 100 150 10000 3.7 1.3E4 1.3E2693 t.n

O-XYLENE XLO D 100 150 10000 3.7 1. 3E4 1.3E2 694 0P-XYLENE XLP D 100 150 10000 3.7 1.3E4 1. 3E2 695 ):>

----lXYLENE PARASOL 0 696 ::t:>XYLENOL XYL 0 697lINC 5.0 MG/M3 698 ("')

Z[NCDIAL~YLDITHIOPHOSPHATE ZOP D 10 CH25) O. 7 699 0.2----l-

TOTAL OF 699 ITEMCS) IN TABLE 0

* CHLORDDIFLUORDMETHANE -- SEE MDNOCHLOROOIFLUOROMETHANE* ETHYL HEXOIC ACID -- SEE ETHYLHEXANOIC ACID* ETHYLENE GLYCOL MONOETHVL ETHER -- SEE 2-ETHOXYETHANOL* GLYCOL OIACITATE -- SEE ETHYLENE GLYCOL OIACITATE* METHYL AMYL KETONE -- SEE N-AMVL METHYL KETONE

20-DEC-85CHEMICAL NAME TOX CARC NFPA SEC CAS EMRSP BIO NIOSH BID QUAL QUAN TLV SEQ


TRIMETHYL PHOSPHITE 3 ---- 121-45-9 26 X 664TRIPROPYLENE 5 ---- 27 665TRIPROPYLENE GLYCOL 9 -000 24800-44-0 666TRIPROPYLENE GLYCOL MONOMETHYL ETHER 5 ---- 667TRIXYLONYL PHOSPHATE 5 ---- 668TURPENTINE 3 1111 8006-64-2 27 X X 669TURPENTINE SUBSTITUTE (WHITE SPIRIT) 4N ---- 8030-30-6 27 670UNDECANOL 5 ---- 112-42-5 27 671 --i

1-UNDECENE 5 672)::>---- CO

N-UNDECYLBENZENE 5 ---- 673 rUREA. AMMONIUM NITRATE SOLN (> 2% NH3) 3* 674 /'TI----N-VALERALDEHYDE 3 -112 110-62-3 26 X 675 )::>

VANADIUM 6 7440-62-2 X 676 Iw

VINYL ACETATE 2 2112 108-05-4 26 X DG G 677VINYL ACETATE. FUMARATE COPOLYMER 5 ---- 678VINYL CHLOR IDE 1 Al 2212 75-01-4 17 X DG DG 679 3:VINYL ETHYL ETHER 5 2--- 109-92-2 26 680

)::>Vl

VINYLIDENECHLORIDE 2 2223 75-35-4 26 X DG G 681 --iVINYL NEODECANATE 5 ---- 682 /'TI

;;0VI NYLTOLUENE 3 2211 25013-15-4 27 X X 0 683WAX: CANDELILLA 5 ---- 684 r......WAX: CARNAUBA 5 ---- 685 Vl

WAX: PARAFFIN 3 ---- 8002-74-2 27 686 --i......WAX: PETROLEUM 5 ---_. 687 Z

WELDING FUMES 6 688 G)

WHITE SPIRIT 4H ---- 8030-30-6 27 689 0WHITE SPIRIT. LOW AROMATIC 4H ---- 8030-30-6 27 690

,.,)::> WINE 5 ---- 0 691 :J:I

WOOL GREASE 5 Vlw ---- 692 0m M-XYLENE 3 2112 1330-20-7 27 X X U G G 693 VlO-XYLENE 3 2112 1330-20-7 27 X X U G G 694. 0P-XYLENE 3 2112 1330-20-7 27 X X U G G 695 )::>

XYLENE PARASOL 5 ---- 696 --i)::>

XYLENOL 5 2--- 1300-71-6 55 0 697ZINC 6 7440-66-6 698 nZINC DIALKYLDITHIOPHOSPHATE 3* ---- H2S 699 0

z--i-

TOTAL OF 699 ITEM(S) IN TABLE 0

* CHLORODIFLUOROMETHANE -- SEE MONOCHLORODIFLUOROMETHANE* ET~YL HEXOIC ACID -- SEE ETHYLHEXANOIC ACID* ETHYLENE GLYCOL MONOETHYL ETHER -- SEE 2-ETHOXYETHANOL* GLYCOL DIACITATE -- SEE ETHYLENE GLYCOL DIACITATE* METHYL AMYL KETONE -- SEE N-AMYL METHYL KETONE

APPENDIX 8

Program Listings

B-1

Program

CGEDIT

B-2

REMOVE RECORDCHANGE COLUMN ENTRY IN EXISTING RECORDADD NEW RECORD(S)

THIS PROGRAM CONS1'ITUTES THE EDITOR FOR THE CHEMICAL SUriSTANCEDATA BASE.CURRENT OPTIONS:

CCCCCCcCCCCCC

PROGRAI"I CGEDIT

T.K. BOWLES

MODIFIED BY TKB

5/18/84

12/6/84 TO ADD NEW COLUMNS TO DATA BASE

DIMENSION NCH(26)BYTE REC(40),CN(2),COL(IO),NREC(40,26),TREC(40),TMP(4)DATA COL/'C', 'G', '0'.0. '.', '0', 'A', 'T',O,OIDATA NCH/40, 6, 4,10,11,11,13,7,6,7,5/5.4,5; 5,5,5.11. 6,5 .. 4,6'-

$ 4.5,5.4/5 TYPE*, 'ENTER OPTION: '

TYPE*, '0 EDIT SESSION IS FINISHED'TVPE*, '1 -- REMOVE RECORD FROM DATA BASE'TYPE*. "2 ::.: CHANGE 1 OR MORE COLUMN ENTRIES IN EXISTING COLUMN'TYPE*, '3 ;:: ADD NEW RECORD(S) TO DATA BASE'ACCEPT*, IOPTNCOL==26IF(IOPT EQ. O)GOrO 500GOTO(100.200, 300) IOPTTYPE*. "~JARNING*** ILLEGAL OPTION *** TRY AGAIN'GOTD 5

ioa TYPE*. 'ErHER LINE NUMBER OF RECORD TO BE DELETED'ACCEPT*.LINLIN1;::LIN+lDO 50 10:.:1, NCOLENCODE<2,IOOO,CN)1IF(!. LT. lOlCN(l)='O'COL( 3) =CN ( 1 )COL< 4) =CN (2)

OPEN(UNIT=l,NAME=COL. TYPE='OLD',ACCESS='DIRECT')C----~DETERMINE NUMBER OF LINES CURRENTLY IN DATA BASEC

READ(l'l)RECDECODE(3,1200.REC)NLINIF(LINl.GT. NLINl THEN

TYPE·!t-, 'LINE NUMBER DOES NOT EXIST-'-TRV AGAIN'GOTO 5

ENDIFNLIN1=NLIN-lDO 30 J=LIN1.NLINlJPl=J+lREAD(l'JPl)(REC(K),K=I,NCH(I»IF (I. EG. 13) THENJMl=J-lENCODE (3,1200,REC)JMlIF (JMl. LT. 100)REC(1)='0'IF (JMl, LT. lO)REC(2)='0'REC(4);::' I

ENDIFWRITE(l'J)(REC(~),K=l.NCH(I»

30 CONTINUEc---->CHANGE NUMBER OF RECORDS FOR LATER REFERENCEC

ENCODE(3.1200.REC)NLINl B-3

8-4

WRITE(l Jl)RECCLOSE(!)

50 CONTINUEGOTO 5

C----)CHANGE A COLUMN ENTRYC

200 TYPE*, JENTER lINE NUMBER OF RECORD TO CHANGE J

ACCEPT*,lINlIN1=lIN+lDO 250 I=l,NCOLTYPE*, J ENTER COLUMN NUMBER TO ED I T J

TYPE*, '***ENTER 0 IF FINISHED***'ACCEPT*, ICOlIF(ICOL. EG. O)GOTO 5ENCODE(2,1000,CN)IeOlIF(ICOl. LT. 10)CN(1l='OJCOL(3)=CN( 1)COL(4)=CN(2)OPEN(UNIT=l, NAME=COl, TYPE='OlDJ, ACCESS=JDIRECT')TYPE*, JOLD DATA FOR COLUMN', ICOlREAD(1'LIN1)(REC(J),J=1,NCH(ICOl»WR I TE (5, 1400) (REC (J), J= 1. NCH ( I COL) )TYPE*, JENTER CORRECTED DATAl FOR COLUMN', ICOLREAD(5, 1100) (REC(J),-.)=1. NCH'( ICOL»WRITE( i'LIN1) (REC(·), -.)=1, NCH( ICOl»CLOSE(l)

250 CONTINUEGOTO 5

C----)ADD NEW RECORDC

300 TYPE*, 'ADD NEW RECORD (S) AFTER lINEACCEPT*, ~.KK

C----)ADD ONE TO ACCOUNT FOR DISPLACEMENT OF LINE NUMBER DISPLAYEDC IN TABLE AND ACTUAL PHYSICAL RECORD NUMBER OF THE CHEMICALC (FIRST RECORD IN EACH FILE IS THE NU~BER OF ITEMS IN THAT FILE)C

303 KKK=KKK+lKKK1=KKK+lKKK2=KKK+2TYPE*, 'ENTER A $ FOR CHEMICAL NAME WHEN DONE;

C----)DATA INPUT IS SETUP WITH 'CURSOR CONTROL' FOR ADM3C TERMINAL--SLIC~ER METHOD COULD BE USED IF WE JUSTC WANT TO USE VT100 TERMINALS.C

WRITE(5,305)305 FORMAT(lX, 'CHEMICAL NAME=',$)

READ( 5,306) (NREC (1,1),1=1. NCH( 1»306 FORMAT(40Al)

IF(NREC (L 1). EG. '$' )GOTO 5WRITE(5,310)

310 FORMAT (1H+, 54X, 'CHRIS CODE=', $)

READ ( 5, 306) (NREC ( L 2), 1= L NCH (2) )WRITE(5,315)

315 FORMATU/IX, 'CFR=', $)

READ (5, 306) (NREC ( L 3), 1= L NCH (3) )WRITE(5,320)

320 FORMAT ( 1H+, 15X, 'OTHER ROUTE= I, $)

READ(S, 306) (NREC( 1,4),1=1. NCH(4»WRITE(5,325)

32S FORMAT (lH+, 33X, 'TLV-TWA= I, $)

READ ( 5 I 306) (NR EC ( I. 5), 1=1. NC H ( 5) )WRITE(S,330)

330 FORMAT ( IH+, 54X, 'STEL= J , $)

READ(S, 306) (NREC( 1. 6),1=1. NCH(6»WRITE(S,335)

33S FORMATU/1X, 'IDLH=I,$iREAD (5.306) (NREC (1,7>, 1=1. NCH( 7) )WRITECS,340)

340 FORMAT ( IH+, 15X, I ODOR= I, $)

READ( 5,306) (NREC (1. 8), 1=1. NCIj(S»WRITE(S,345)

345 FORMAT (lH+, 33X, ICB= I, $)READ C5, 306) (NREC ( r.. 9), 1= 1. NCH ( 9) )WRITE(S,350)

350 FORMAT( lH+, 54X. ICS/TWA= I, $)

READ(S,306)(NRECCI, 10), 1=1.NCH(10»WRITE(S,35S)

3~S'5 FORMAT(I/1X, ITOX CODE=',$)READ(S, 306)(NREC( 1. 11), 1=1. NCH(l1) iWRITE(S, 360i

360 FORMAT( lH+, 15X, 'CARC REF='. $)

READe;, 306) (NREC (1, 12),1=1, NCH( 12»WRITE(S,365)

365 FORMAT(1H+,33X, INFPA NAS=',$)READC'5,306)(NREC(I, 14), I=LNCH(i4»WRITE(5,370)

370 FORMAT<lH+, 54X, 'AIR DATA?=I, $)

READ ( 5, 306) (NREC ( 1. 15), 1=1, NCH ( 15) )WRITE(S,375)

37S FORMATU/lX. IQUAN CODE=', $)READ(S,306)(NREC(I, 16), I=1.NCH(16»WRITE(5,376)

376 FoRMAT(lH+. lSX, 'SEC PROD=I, $)

READ( 5,306) (NREC (1. 17),1=1, NCH( 17»WRITE( 5,377>

31'7 FORMAT ( IH+, 33X, 'CAS:::: I, $)

READ ( S, 306)( NREC ( r. 18), 1= 1, NCH ( 18) )WRITEC5,37B)

378 FORMAT(lH+,54X, 'EMRSP GUIDE=I,$)READ( 5,306) (NREC (1. 19),1=1. NCHC 19»WRITE(S,379)

379 FORMAT<I/1X, IMSDS=', $)READ( 5,306) (NREC (1, 20),1=1, NCH(20»WRITE(5,380)

380 FORMAT <1H+. 15X, 11310 MED=I, $)

READ(S, 306) (NREC( 1,21).1=1. NCH(21»WR 1TE ( 5, 381 )

3e1 FORMAT< 1H+, 33)(, 'NI05H GUIDE= I, $)

READ<5, 306) (NREC( 10 22),1=1. NCH(22»WRITE(5,382)

:382 FORMAT(lH+, 54X, IBID MON=I, $)

READ ( S, 306) (NREC ( L 23), 1=1, NCH ( 23) )WRITECS, 383)

383 FORMAT<I/IX, 'QUAL DT=',$)READC 5,306) (NREC (1. 22),1=1. NCH(22»WRITE(S,384)

:384 FORMAT<lH+, 15X, 'QUAN DT='. $)

READ(S, 306) (NREC(I. 2S), 1=1, NCH(2S»WRITE(5 .. 38S)

385 FORMAT(lH+,33X, ITLV DT=',$)READ( 5,306) (NREC (L 26).1=1. NCH(26»ENCODE(3,1200,TMP)KKKIF(KKK.LT.I00) TMP(l)='OIIF(KKK.LT.l0) TMP(2)='O'TMP (4) =' !

DO 388 1=1,NCH(13) 8-5

NREC ( I, 13) =TMP ( I )388 CONTINUE

C----)CHANGE SEQUENCE OF DATA EASE RECORDS TO ACCOUNT FOR ADDITIONCS)C

DO 400 JJ=l,NCOLENCODE(2,1000,CN)JJIFCJJ. LT. 10) CN(l)='O'COL(3)=CN( 1)

COL(4)=CN(2}OPEN(UNIT=l,NAME=COL,TYPE='OLD',ACCESS='DIRECT')READ(l'l)RECDECODE(3,1200,REC)NLINNLIN=NLIN+lENCODEC3,1200,REC)NLINWRITE(l'l}RECDO 390 JJJ=NLIN,KKK2,-1'JJJM1=JJJ-lREAD ( 1 'JJJM 1 ) <TREC ( I), 1=1. NCH (JJ) )

C---->IF FILE IS THE ONE WITH SEGUENCE NUMBERS FOR LISTINGS, ACTUALLYC CHANGE THOSE NUMEERS TO ACCOUNT FOR ADDITION(S). DON'T JUST MOVE'C RECORDS.C

IF (JJ. EG. 13) THENENCODE (3,1200,TREC)JJJMlIF (JJJM1.LT. 100)TREC(1)='O'IF (JJJM1. LT. 10)TREC(2)='O'TREC (4) =' ,

ENDIFWRITE( 1 'JJJ) <TREC( I j, 1=1, NCH(JJ»

390 CONTINUEWR I TE ( 1 ! KIo<.K 1) (NREC ( L JJ), 1=1. NCH (JJ) )CLOSEt!)

400 CONTINUEGOTD 303

500 CALL EXIT1000 FORMAT(I2)1100 FORMAT(60Al)1200 FORMAT(I3)1300 FORMAT <14)1400 FORMAT(lX,60Al)

END

B-6

Program

CGTAB

B-7

PROGRAM CGTAB

MODIFIED BY TKB 12/6/84 TO INCLUDE NEW COLUMNS IN DATA BASE

KEY VAR IABLES:

THIS PROGRAM CREATES THE TABULAR LISTING OF THE CHEMICAL SUBSTANCEDATA BASE. LISTINGS CAN BE MADE BY SORTING TECHNIGUES ON COLUMNS

REC----BYTE DUMMY ARRAY FOR READING IN DATA FROM DATA BASE FILESCSAV---BYTE ARRAY FOR TEMPORARY STORAGE OF ONE LINE OF DATA FOR

PRINTING IN TABLE .IADRS--ARRAY FOR STORING ADDRESSES OF ITEMS FOR THE TABLE LISTING

--DETERMINED BY SORT ON PARTICULAR COLUMN OF DATA BASENCH----ARRAY CONTAINING MAX NUMBER OF CHARACTERS FOR EACH

DATA BASE COLUMNNHH----ARRAY CONTAINING NUMBER OF CHARACTERS FOR RIGHT JUSTIFICATION

FOR EACH DATA BASE COLUMNCOL----BYTE ARRAY FOR FILE NAME TO BE OPENEDCN-----BVTE ARRAY FOR COLUMN NUMBER (TO IDENTIFY PROPER FILE)LOP----IDENTIFIES LOGICAL OPERATOR FOR SORT:

EG,LT,GT,LE.GE,NECHK----ByTE ARRAY CHECK VALUE FOR COLUMN SORTNIK----NUMBER OF RECORDS FOR EACH COLUMN AFTER SORTNCP----NUMBER OF·COLUMNS TO PRINT IN TABLEICP----ARRAy OF COLUMN NUMBERS TO PRINT IN TABLE

5/16/84T. K. BOWLESCCCCCCCCCCCCCCCCCCCCCCCCCCCC

DIMENSION IADRS(800).NCHC26).NHH(26), ICP(26)BYTE COL(10).CN(2).RECC40),CSAV(40,26),NUM(3),GARB,CHK(10)DATA COL I 'c r. rG f, .. 0 ' , 0, '. r, rDr, rA .. , "T .. , o. 0 IDATA NCH/40, 6. 4,10,11.11,13,7,6,7,5,5,4,5,5,5,5,11,6,5,4,6,

$ 4.5,5,4/DATA NHH/40. 5,3, 5, 5, 5. 7.7,6,7,4,4,4,5,3,3,5,11,4,3,3,4,

$ 4,4,4,4/NCOL=26TYPE*, 'ENTER NUI,mER OF LINES PER PAGE IN TABLE«=55)'ACCEPT*,LTABNSORT=OLSORT=OTYPE*, 'IF YOU WANT TO SINGULARLY SELECT CERTAIN ITEMS'TYPE*, r INSTEAD OF DOING SORT OF ENTIRE DATA BASE, I

TYPE*. 'ENTER l'TYPE*, '-OTHERWISE, ENTER 0'ACCEPT*, ISEL

C----)CREATE'SCRATCH FILE FOR STORING SELECTED RECORDSC

1 OPEN(UNIT=2,NAME='CSCRTCH. DAT',TYPE='SCRATCH',ACCESS='DIRECT')IF(ISEL.EQ. l)GOTO 103

C---->DETERMINE BY WHICH COLUMN TO SORTC

TYPE*, 'ENTER COLUt1N NUMBER BY WHICH TO SORT'ACCEPT*, ICNDENCoDE(2,1100,CN)ICNDIFCICND.LT.l0ICN(11='0"COL(3)===CN(1)COL( 4) ::;:CN (2)oPENCUNIT=l,NAME=COL,TYPE='OLD',ACCESS='DIRECT')

C---->SELECT LOGICAL OPERATOR FOR SORT: EQ,LT,GT!LE,GE,NEC

TYPE*, 'SELECT LOGICAL OPERATOR FOR SORT: r

TYPE*, 'ENTER 1 FOR . EG. r

8-8

TYPE*, 'ENTER 2 FOR . LT. 'TYPE*, 'ENTER 3 FOR . GT. 'TYPE*, 'ENTER 4 FOR . LE. 'TYPE*, 'ENTER 5 FOR . GE. 'TYPE*, 'ENTER 6 FOR . NE. 'ACCEPT*, LOPTYPE*, 'IS DECODING NECESSARY FOR SORT?'TYPE*, 'ENTER 1 IF YES, 0 IF NO I

ACCEPT*, IDCODTYPE*, 'ENTER CHECK VALUE I

READ(5, 1800).JN, (CHK<I), 1=1t.JN)C---->DETERMINE NUMBER OF RECORDS IN DATA BASEC

READ( l' 1 )RECDECODE(3,1400,REC)NLINIK=lDO 100 IC=2,NLINREAD(l'IC)(REC(J),J=l,NCH(ICND»

C----)DETERMINE NUMBER OF ACTUAL CHARACTERS IN RECC FOR USE IN DECODING, IF NECESSARYC

JNR=ODO 2 J=l,NHH(ICND)IF(REC(J). EG.' ')GOTO 3

2 JNR=JNR+l3 GARB=O

C---->CERTAIN COLUMNS NEED TO HAVE RECORD DECODED TO SORTC OTHERS CAN BE CHECKED DIRECTLY AGAINST ASCII CODEC

IF(IDCOD.NE.1) THENIF(LOP,NE. 1. AND, LOP.NE. 6)THEN

TYPE*, 'INVALID LOGICAL OPERATOR FOR ALPHA DATA--'TYPE*, 'MUST USE . EG. OR ,NE.'CALL EXIT

ELSEIF(LOP, EG. 1) THENDO 5 J=1. IN

5 IFCREC(J), NE. CHK(J» GOTO 100ELSE

JNCNT=ODO 7 J=l,JN

7 IFCRECCJ). EG. CHK(J» .JNCNT=JNCNT+lIFCJNCNT.EG. IN) GOTO 100

ENDIFIADRS(IK)=ICIK=IK+1GOTO 100

ELSEIFC ICND. EG. 11) JNR=lIDEC=OIF CICND. EG. 5, AND. REC (1). EG. 'c I) THEN

DO 8 J=1. CJNR-l )8 REC(J)=REC(J+1)

JNR=JNR-lENDIFIF ( ( ICND. EG. 5. OR. ICND. EG. 6'. OR. ICND. EG. 7). AND. JNR. NE. 0) THEN

DO 9 J=1. JNRIF(RECeJ). EG. '. ') IDEC=l

9 GARB=OIF(IDEC.EQ.O) THEN

JNR=JNR+lREC eJNR )= '. '

ENDIFELSEIF«ICND.EQ. 5.0R. ICND. EG.6. OR. ICND. EG. 7). AND. JNR.EG. 0) THEN

B-9•

I.·~.' [i 'I -~~! ,i. 0 \,JE}lljl;'

[jE:(~,fJl'!r:: i, ,);\l; ~ \.; ~.,'"~', {~-;~-!~"'"1 ECH~.

L+~r IV!:::, .JNi~, l'~!,"~' ~;:i,:.C I CREeF..ND 1 F'

:.- ,··'lm'::,t,id·i T:.~i ,;F-::f!i~;F:RU:,T[ 'LOGICAL OPER,/Hi~IP r.uR SORT

GOT!J' 1'.' ,~Cj. ~:>:~''-i-(j, ,:i':i, t/),UJPT, I:T:l>. "', ;,:u,;l. f [0; ., CiG I .>6,', C!F·[RATOH--·Pt~:G·,:;RAt'I TFRM l'NATED I

;';.M.L. l:-- ,! T

I ("~ IF (EF,:L< L:\~i F,~,r'~!··,_ C:J ff:; r3(:Gi]T\:! :,:'

:0 If-! i:-Rf:~ 1,;' r:,~--i., F.;·~U",'jF:: ~~[ (:) CCJ TU i.:it:'GIJH1 ;',,:,'j

,:'~(~,I Ir: (r.:qF~;~ -~J I E.:~~,>~.: Gi~}TU IJO

(iCiT D i ',::,

'0 IF',E~[: '.,l:'" f<";:":'f'IL' ,.!i-~I:: I'~E 0) f~[l"ro .:3',){~IJT I] 1 ,'j

""J U'- (' EJ([,.: \':.i': 1::.'", ,,'

GC!TU t :,<'::'.U r.F(Eh~E:~- ~'~E: Ei:=Hi-', ;;',")iCJ r::,()

',;~JT'D i I." ;)

'; : (I I ~~ DRS ( ~.,,~ ;~:. i. i~

H:,~'Ih+ ",() GAHBd',

Nl!'\,:=II--\·· LCLiJ~l:: ( i, '

:, (·'3 11'·',; 1Dl1 l(i!J 1:"" 1. 8<',;::TVPE~. Ud"ER l.:. ~ +~ i';i.if"1G[~~ TO SELECT'['IF' t>·, . r 1:- r;:-1 :'1 I ";HED, etHER '7999 I

(':'CC[PT-=, i"'::,L. I,iIF(r'JSL'~i',), ,::I} ,":,._~" :-(;I:;IU 11)5

r':"DRSI :V ',·o::I\iSl. [~'~"' 1.104 1\-",:=11'\+1.jeiS NIK=li-"-··j

(-----)NOW SAV~ ~PPR:J~~IAr~ RECORDS (ADDRESSES SAVED IN IADRSJ FROM~ EACH COLUMN TQ BE PRINTEDC

: ("1:3 TYPE''>', U'fH::Fi i',,:' UF- CiJl._'.ii"lNS TO BE F)i, HHEO'ACCEPn·I\JI.'pTYPE'll, ~.fHER _'I.UI1!·IS Tei Ff"UNT'AC CE F' T""., i [C P , i; I::. i , r-"c F' )J. C!:,UM=CDO 110 i ~ 1" '--i( r'

1 i) U':; 8ut1"" I;: SUM+ I'~\>" r c I:' ( II !

IF(ICSU~ GT l~~; THF~

T'tF'E'·'. rIJT;~l" 'lTd; iAiIDTH OF f(EGU~>~TEf.i CUL.UMNS EXCEEDS 132--'T YF' E''''.. . rRV ":, ~, ."- Ir-j ,(;;0 T Ci \ ,:'8

EM) Ii=-Ii, Y:,':=: 1DO 2(iO r.:-: 1. , NC r'ENe O[IE ; ~2, 11 DC, ;= \-i) Ie P ( I )IF ( Ie P ( 1 i L T :~,::: OJ i 1 ) ;:-, I () i

IF(NSC:;~;jT, EG. tJ) -.,'OL.;,2 1 ::::-'G-'

COL(;)) "CN( 1)CIJL i 4 ) :::(:i'~ (,;~,

;JPEN ( UI'~j T== 1. 1'-li:;i';C-:=C I]l_, T YPI'::= ' OLD' • A!~C css",' Ii I REC T ' )Ir(LSORT EQ O~ THEN

i'--- ,_,OPEN r:' [LE !'~O?':'!~I'; II6.L DATA BASE IN CASE YOU WANT'- MUi_ TI PLE SIJf"~F:: B-10

cCOL(2)='P'OPEN(UNIT=4,NAME=COL,TYPE='NEW',ACCESS='DIRECT')NIK1=NIK+lENCODE(3, 1400,REC) NI~l

WRITE(4'1) RECENDIFDO 150 IREC=1,NIKKI=IADRS(IREC)READ ( 1 ' KI ) (REC (J), J= L NCH ( I CP ( I ) ) )IF(LSORT. EQ.O) THEN

C---->WRITE RECORD TO PARTIAL DATA BASE FILE IN .CASE YOUC WANT MULTIPLE SORTSC

WRITE(4'IREC+1)(REC(J),J=1,NCH(ICP(I»)ENDIF

C--'--:>R I GHT JUST I FY RECORD I N COLUMNC (UNLESS IT IS THE CHEMICAL NAME COLUMN)C SPECIAL TREATMENT FOR PRESENr COLUMN 11 (TOX CODE)C

IF(ICP(I).EQ.l) GOTD 145IF(ICP,I). EG.11) THEN

REC(4)=REC(2)REC(3)=REC(1)REC(5)=' ,REC(!)=' ,REC(2)=' ,GOTO 145

ENDIFICNT=O

. C----)CHECK FOR FIRST BLANK SPACEC

DO 120 J=l,NHH(lCP(I»IF(REC(J). EG. ' ') GOTD 121ICNT=ICNT+l

120 CONTINUEC----)CHECK TO SEE IF RIGHT-JUSTIFICATION IS TO OCCUR OVER ENTIREC FIELD SPECIFICATION OR JUST PART OF ITC

121 IF(NCH(ICP(I». NE. NHH(ICP(I») THENC----:>RIGHT JUSTIFY SECOND PORTION OF RECORD FIRSTC

ICNT2=ICNT+2NCNT=ICNT+lDO 122 NN=ICNT2.NCH(ICP(I»IF(REC(NN). EG.' ') GOTO 123NCNT=NCNT+l

122 CONTINUE123 NDIF=NCH(ICP(I»-NCNT

C----)THIS PORTION OF RECORD COMPLETELY FILLS ALLOTMENT IF THEC FOLLOWING IS TRUE:C

IF(NDIF. EG. O. OR. NCNT. EG. (ICNT+l» GOTD 128C----)OTHERWISE, RIGHT JUSTIFYC

DO 124 K=NCH( ICP (I», (NDIF+ICNT2),-1REC(K)=REC(NCNT)NCNT=NCNT-l

124 CONTINUEC---->FILL LEADING SPACES IN FIELDC

DO 125 K=1.NOIFr'l:'rn<+Tr.NT+l):' I 6-11

125 CONTINUEENDIF

C----)RIGHT JUSTIFY ENTIRE RECORDC

128 IDIF=NHH(ICP(I»-ICNTIF(IDIF, EG. O. OR. ICNT. EG. 0) GoTO 145DO 130 K=NHH<ICP(I».(IDIF+1).-lREC (K) =REC ( ICNT>ICNT=ICNT-1

130 CONTINUEC----)FILL LEADING SPACES INFIELDC

DO 140 K=1, IDIFREC (K) =' ,

140 CONTINUEC----)SAVE RIGHT JUSTIFIED RECORD IN SCRATCH FILEC

145 WRITE(2'KK)(REC(J),J=1,NCH(ICP(I»),KK=KK+l

150 CONTINUECLOSE(1)CLOSE(4)

200 CONTINUEC---->SET UP TABLEC

oPEN(UNIT=3,NAME='CTAB.DAT'.TYPE='NEW')C----)PRINT INITIAL HEADINGSC

CALL HDWRIT(NCP. ICP.NCH)KLIN=1DO 300 I=1,NIK

C---->CHECK TO SEE IF NEW PAGEC

IF(KLIN.GT, LTAB)THENCALL HDWRIT(NCP, ICP.NCH)KLIN=1

ENDIFDO 250 J=L NCPIJ=(J-1)*NIK+IREAD(2'IJ) (CSAV(K.J).K=l.NCH(ICP(J»)

250 CONTINUEC----)PRINT ONE LINE IN TABLEC

WRITE(3.1200) «CSAV(K. J). K=L NCH( ICP(J» ).J=t, NCP)KLIN=KLIN+l

300 CONTINUEC----)WRITE NUMBER OF TABLE ENTRIES FOR THIS SORT'C

WRITE(3.1500)NIKC----)TABLE FOOTNOTESC

TYPE*. 'DO YOU WANT TO PRINT FOOTNOTES FOR TABLE?'TYPE*. •ENTER Y OR N'READ(S.1000)GARBXF(GARB. EG. 'Y') THENWRITE(3,1300)

ENDJrFC---->BLANK WRITE TO PROHIBIT 'SQUEEZING' OF LAST LINEC

WRITE(3.1000)C----)CHECK TO SEE IF MORE SORTS AREREGUIREDC

TYPE*. 'MORE SORTS?' B-12 .

140015001.8001900

1C'0011001 ;;:1001300

,$

$

$

$

$

$

C

TVPE'l"i-, ClfrE:R Y ':JR i\j'

READi 5:1.0(0)GAF:8IF(GARD EG. 'Y') THEN

TYPE;"l", . IF YOu WANT TO DO 1'10RE THAN DI\lE: SORT ON THE~.

TYPE~,:3AI'1E MASTl.~R SELECTED LIST, ENTER l'TYPE·!:>, 'CHHERWI SE, ENTER 0'ACCEF'r*, LSORTNSORT~-:l

ISEL:::::OCLm:;E(J)CLOSI::<,2\GOTD 1.

ENDIFFORt1AT (;2A 1 )FORMAT ( [2'F IJRMAT ( 1 X, 1:32A 1 )FORMAT( ////5:<, '-lJ i. ';;X.

'CHLORODIFLUOROMETHANE --_. SEE MDNOCHLORODIFLUOROMETHANE'/'5:i, '*', :::::X, 't:THYL HEXOIC ACID-'-' SEE ETHVLHEXANOICACID'/'5 X., i -);- ',;;- X J 'ETHYL.ENE GLveOL f'lONOETH'/L ETHER -- "'~::;EE ,2-ETHDX'r'ETHANOL'/5X, ,,,', ;;2 X, "GL.YCDL DIACITATE'seE ETHYLE:NE GLYCOL Dlt~CI"TA';E'/5X, '*',2X,. tiETH'{L AI1YL. "'CTONE -- SEE I,J·-AMYL t'IETHYL KETONE')

FORl'lAT i. J:3)FORMA T ( / / 5x.! 'TDT AI- Of:': L'+.' I TEl'1\. O' Hi. TAl3 Lt: ' !FOR NAT (Gi, (,A'D·A 1 )FORMATt.E12 4)CAL.L EXITEND

.SUBROUT I NE Hm..JR ( T (f-·.!CP., I CP, NCH)

C THIS SuBROUTINE WfnTfS COL:UMN HEAD[:f~S ON EACH NEW PAGEc

.LCO

100011001 ;;;00

DIMENSI.ON ICF(;;6/.l\\CH(2b)BYTE HD(40,26/,CN(2 i ,COL(10I, XDAT(9)DATA COL:" H .' , 0 , G.' ," 1) , , "A", .. T ' , 0, 0, 0,.'CALL DATE (XDAT:IWRITE(3,1200)XDAT00 200 Io".j.\=:: 1. 2DO 100 1=1.. NCPENCODE(2, 1000, Ci'~i rcp.: I)IF(ICPIII LT 10JCN(1;='O"COL(2)==CN(1)COL(3)=CN(2)OPEN(UNIT~l,NAME=(OL.TYPE='OLD',ACCESS='DIRECT')

READ ( 1 '1/,1-4..) ( HD ( .J .. I ! ' ,j:.-: 1, NCH ( I CP ( I ) ) )CLOSE( 1)CONTINUE

WRITEC3" 11(0) '. (H[}l.,)· I), J==l, NCH( Iep (I)) 1,1=1, NCP)CONTINUEWRITE(3,1100)WRITE(3,11.00)FORMAT (12/FORMA1 <" lX, l32Ai J

FORMAT (lHl, 132Al)RETURNEND

R-B

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Marine Hazardous Substances Data System_Volume 2