Madame Curie - Radium and Polonium

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    26/11/2012

    Research work of Madame Marie SklodowskaCurie for The Nobel Prize in Chemistry,1911

    Presented by : ashish

    1Topic

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    26/11/2012 2Content

    Madame CurieAn Introduction.

    Double Nobel Laureate.

    Radioactivity.

    The Discoveries.

    Polonium.

    Radium.

    Isolation of Radium .

    Uses.

    Harmful Radioactivity.

    Bibliography.

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    26/11/2012 3Madame CurieAn Introduction

    Birth: November 7, 1867 - Warsaw, Poland.

    Family: Pierre Curie, Irene Joliot-Curie, Eve Curie.

    Native Country: Poland.

    Adopted Country: France.

    Scientific fields: Physics, Chemistry.

    Contributions: Radioactivity, Radium, Polonium.

    Death: July 4, 1934Passy, Haute-Novae, France.

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    26/11/2012 4Double Nobel Laureate

    The Nobel Prize in Physics 1903 was divided, one half awarded to Antoine Henri

    Becquerel "in recognition of the extraordinary services he has rendered by hisdiscovery of spontaneous radioactivity", the other half jointly to Pierre Curie and MarieCurie, ne Sklodowska "in recognition of the extraordinary services they haverendered by their joint researches on the radiation phenomena discovered by ProfessorHenri Becquerel".

    The Nobel Prize in Chemistry 1911 was awarded to Marie Curie "in recognition ofher services to the advancement of chemistry by the discovery of the elementsradium and polonium, by the isolation of radium and the study of the nature andcompounds of this remarkable element".

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    26/11/2012 5Radioactivity

    Henri Becquerels Uranic Rays

    Henri Becquerel had observed that uranium compounds gave off certain invisiblerays which could penetrate opaque objects and affect photographic plates. He

    named them uranic rays.

    The term Radio-activity

    While working on uranic rays for her Doctoral thesis, Madame Curie coined theterm radio-active rays and hence, called the phenomenon of emitting these

    invisible rays as radio-activity.

    Thorium

    While studying various compounds for radioactivity, Madame Curie found

    Thorium to be radioactive too.

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    26/11/2012 6The Discoveries

    Pitchblende Ore

    While studying the pitchblende ore, Madame Curie found to it to be more

    radioactive than uranium and hypothesized that it contained at least 3 previously

    unknown elements, which were much much more radioactive than Uranium and

    Thorium. Polonium

    On 18th July, 1898, Polonium was discovered by the Curies and named in the

    honour of Poland, Madame Curies native country.

    RadiumOn 26th December, 1898, Radium was discovered and named after the latin word

    for ray.

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    26/11/2012 7Polonium

    Name Polonium

    Symbol Po

    Atomic number 84

    Group number 16

    Group Metal

    Block p

    Half Life of208Po 2.898 years

    Half Life of209Po 103 years

    Half Life of210

    Po 138.37 daysMelting Point 527 K

    Boiling Point 1235 K

    Electronic Configuration [Xe] 4f14 5d10 6s2 6p4

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    26/11/2012 8Radium

    Name RadiumSymbol Ra

    Atomic number 88

    Group number 2

    Group Alkaline earth metal

    Block s

    Half life of 226Ra 1602 years

    Half life of 228Ra 6.7 years

    Boiling Point 973 K

    Melting Point 2010 K

    Electronic Configuration [Rn] 7s2

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    26/11/2012 9Isolation of Radium

    Extraction of radiferous Barium Sulphate.

    Conversion of sulphate to chloride.

    Separation of radium chloride from barium chloride.

    Activity measurements.

    Spectroscopic confirmation.

    Electrolysis of Radium chloride.

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    26/11/2012 10Uses of Radium

    Used in medical radioisotopes. Used as a gamma ray source. Used to produce neutrons.

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    26/11/2012 11Uses of Polonium

    Polonium is also used in anti-static brushes to eliminate dust on

    photographic film.

    It is sealed in brushes to control the radioactive emissions.

    Can be used as a lightweight heat source for thermoelectric power in space

    satellites.

    Can be mixed or alloyed with Beryllium to provide a source of neutrons.

    Polonium is used to eliminate static electricity produced duringprocesses such as rolling paper, wire and sheet metal.

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    26/11/2012 12Harmful radioactivity

    Deaths of five "Radium Girl" employees who had used radium-basedluminous paints on the dials of watches.

    Madame Curie, herself died of aplastic anemia, due to long termexposure to radioactivity.

    Irene Joliot-Curie, died of leukemia, 10 years after a capsule ofpolonium exploded on her bench.

    Poloniums harmful radioactivity has also been used to a murder

    weapon.

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    26/11/2012 13A few Curies Quotes

    Nothing in life is to be feared, it is only to be understood. Now is the time to

    understand more, so that we may fear less.

    Be less curious about people and more curious about ideas.

    We must have perseverance and above all confidence in ourselves. We must

    believe that we are gifted for something.

    Nothing in life is to be feared. It is to be understood.

    We must not forget that when radium was discovered no one knew that it would

    prove useful in hospitals. The work was one of pure science. And this is a proof that

    scientific work must not be considered from the point of view of the directusefulness of it. It must be done for itself, for the beauty ofscience.

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    26/11/2012 14Bibliography

    http://www.nobelprize.org/nobel_prizes/chemistry/laureates/1911/marie-curie-

    lecture.html

    http://www.aip.org/history/curie/discover.htm

    http://www.britannica.com/nobelprize/article-9435287#TOP

    http://www.aip.org/history/curie/article.htm

    http://www.iupac.org/publications/ci/2011/3301/5_adloff.html

    Radiochemistry and the Discovery of Isotopes(New York: Dover, 1970), A. Dover

    http://www.nobelprize.org/nobel_prizes/chemistry/laureates/1911/marie-curie-lecture.htmlhttp://www.nobelprize.org/nobel_prizes/chemistry/laureates/1911/marie-curie-lecture.htmlhttp://www.aip.org/history/curie/discover.htmhttp://www.britannica.com/nobelprize/article-9435287http://www.aip.org/history/curie/article.htmhttp://www.iupac.org/publications/ci/2011/3301/5_adloff.htmlhttp://www.iupac.org/publications/ci/2011/3301/5_adloff.htmlhttp://www.aip.org/history/curie/article.htmhttp://www.britannica.com/nobelprize/article-9435287http://www.britannica.com/nobelprize/article-9435287http://www.britannica.com/nobelprize/article-9435287http://www.aip.org/history/curie/discover.htmhttp://www.nobelprize.org/nobel_prizes/chemistry/laureates/1911/marie-curie-lecture.htmlhttp://www.nobelprize.org/nobel_prizes/chemistry/laureates/1911/marie-curie-lecture.htmlhttp://www.nobelprize.org/nobel_prizes/chemistry/laureates/1911/marie-curie-lecture.htmlhttp://www.nobelprize.org/nobel_prizes/chemistry/laureates/1911/marie-curie-lecture.htmlhttp://www.nobelprize.org/nobel_prizes/chemistry/laureates/1911/marie-curie-lecture.html
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    26/11/2012 15End of Presentation