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Ultrasound as a green reactor
GREEN CHEMISTRY
Seminar
Presented by:
Supervisor: Assoc. Prof. Dr Nam Thanh
Son Phan
Contents Introduction
Sound wave and ultrasound Applications of ultrasound in industry
and chemistry, and ultrasound apparatus Power of ultrasound: Acoustic cavitation Effects of ultrasound on reactions
4/12 Green principles are adapted Researches on ultrasound-assisted
reactions Conclusion
SOUND WAVE AND ULTRASOUND1
Industrial applications of ultrasound2
Ultrasound apparatus
ultrasonic cleaning bath
2
ultrasonic horn
Ultrasound apparatus2
THE POWER OF ULTRASOUND3
THE POWER OF ULTRASOUND3
ACOUSTIC CAVITATION
“Cavitation is an extraordinary method of concentrating the diffuse energy of sound into a chemically usable form”.
Kenneth Suslick
3
ACOUSTIC CAVITATION
Cavitation• The formation, growth, and implosive
collapse of bubbles in a liquid• Cavity growth depends on many factors (f,
T, t,. etc).Types of cavitation
Stable Cavitation • The bubbles oscillate
around their equilibrium position over several refraction/compression cycles
Transient Cavitation • The bubbles grow
over one (sometimes two or three) acoustic cycles to double their initial size and finally collapse violently
• Rectified diffusion
Rectified diffusion
• During oscillations of cavities, the amount of gas or vapor that diffuses in or out of the cavity depends on the surface area, which is slightly larger during expansion than during compression.
3
Radical effectsMechanical effects Electrochemical
Temperature
Intensity
Frequency
Solvent
Gas type and contentExternal applied pressure
US
FACTORs AFFECT AFFECTs FACTORs ???
Effects of Ultrasound
Physical Effects • The hot-spot
theory• Shear forces, jets
and shock wavesChemical Effects • Radical effects• Mechanical effects • Effect on
electrochemical processes
4
HOMOGENEOUS LIQUID-PHASE REACTIONS4
CAVITATION NEAR A SURFACE4
HETEROGENEOUS POWDER-LIQUID REACTIONS4
HETEROGENEOUS LIQUID-LIQUID REACTIONS (EMULSION)4
1 • Prevent waste
2• Use safer
solvents and reaction conditions
3 • Increase energy efficiency
4 • Minimize the potential for accidents
4/12 green principles
may be adapted by using
ultrasound
5
RESEARCHES ON ULTRASOUND-ASSISTED REACTIONS
6
“Ultrasound-promoted synthesis of quinolines using basic ionic liquids in aqueous media as a green procedure”
Elaheh Kowsari, M. Mallakmohammadi. 2011
Effect of the ultrasonic irradiation time and the ultrasonic frequency on the substituted quinoline yield
The ultrasonic irradiation time had significant effect on the condensation, when the amount of BIL1 (0.5 mmol) and the ultrasonic frequency (50 kHz) were kept constant. At 1, 1.5, and 2 h, quinoline (3a) was obtained with 40%, 65%, and 95% GC yields, respectively.
“Ultrasound-promoted a green protocol for the synthesis of 2,4-diarylthiazoles under ambient temperature in [bmim]BF4”
Jalil Noei, Ahmad Reza Khosropour. 2009
A simplified green chemistry approaches to synthesis of 2-substituted 1,2,3-triazoles and 4-amino-5-cyanopyrazole derivatives conventional heating versus microwave and ultrasound as ecofriendly energy sources
Khadijah M. Al-Zaydi. 2009
Conclusion
As increasing environmental consciousness in chemical research
and industry, the challenge for a sustainable environment calls for
clean procedures. Ultrasonic-assisted organic synthesis (UAOS) as
a green synthetic approach is a powerful technique that is being
used more and more to accelerate organic reactions
Notable features of the ultrasound approach are enhanced reaction
rates, formation of purer products in high yields, easier
manipulation and considered a processing aid in terms of energy
conservation and waste minimization which compared with
traditional methods
[1]. Timothy J. Mason, John P. Lorimer, Applied sonochemistry: Uses of power ultrasound in chemistry and processing, Wiley-VCH Verlag GmbH, Weinheim, 2002.
[2]. Mukesh Doble, Anil K. Kruthiventi, Green chemistry and processes, Elsevier, Oxford, 2007.
[3]. Elaheh Kowsari, M. Mallakmohammadi, Ultrasound promoted synthesis of quinolines using basic ionic liquids in aqueous media as a green procedure, Ultrasonics Sonochemistry, Volume 18, Issue 1, January 2011, Pages 447-454
[4]. Khadijah M. Al-Zaydi , A simplified green chemistry approaches to synthesis of 2-substituted 1,2,3-triazoles and 4-amino-5-cyanopyrazole derivatives conventional heating versus microwave and ultrasound as ecofriendly energy sources, Ultrasonics Sonochemistry, Volume 16, Issue 6, August 2009, Pages 805-809
[5]. Jalil Noei, Ahmad Reza Khosropour, Ultrasound-promoted a green protocol for the synthesis of 2,4-diarylthiazoles under ambient temperature in [bmim]BF4, Ultrasonics Sonochemistry, Volume 16, Issue 6, August 2009, Pages 711-717
References
Appendix 1: Effect of temperature
Appendix 2: Effect of Intensity (or PA)
Appendix 3: Effect of frequency and time
Appendix 4: Effect of solvent
1. VISCOSITY
2. VAPOUR PRESSURE
Appendix 5: Effect of gas type and content