HBr Relevant to the HBr-FvsV state paper:

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HBr Relevant to the HBr-FvsV state paper: https://notendur.hi.is/agust/rannsoknir/rempi/hbr/Jan12/PPT-130212ak.ppt https://notendur.hi.is/agust/rannsoknir/rempi/hbr/Jan12/XLS-130212ak.xls https://notendur.hi.is/jil3/work/Paper/HBr_FvsV/BWs%20for%20HBr_FvsV.xlsx. Model:. 1/ t 0 E1. E1. - PowerPoint PPT Presentation

Text of HBr Relevant to the HBr-FvsV state paper:

  • HBr

    Relevant to the HBr-FvsV state paper:

    https://notendur.hi.is/agust/rannsoknir/rempi/hbr/Jan12/PPT-130212ak.ppt https://notendur.hi.is/agust/rannsoknir/rempi/hbr/Jan12/XLS-130212ak.xlshttps://notendur.hi.is/jil3/work/Paper/HBr_FvsV/BWs%20for%20HBr_FvsV.xlsx

  • Model:E1H0V7F11/t0E11/tother1/t0H01/tE11/tH01/tF11/t0F1Assume:

  • Linewidthshttps://notendur.hi.is/jil3/work/Paper/HBr_FvsV/BWs%20for%20HBr_FvsV.xlsx

  • https://notendur.hi.is/agust/rannsoknir/rempi/hbr/Jan12/XLS-130212ak.xls

    Bw vs lifetime comparisons79

    J=6J=6J=3states:Bw/cm-1t(ps)=1/t (ps-1)rate const. SumsfractionBw/cm-10t(ps)=1/t (ps-1)rate const. SumsfractionV77.80613ca.0.6789541.4728551.472855V714.269271.241430.8055230.8055231?E14.73001>1.1205050.8924550.6059353.872561.3686040.7306720.907078?F11.4125>>3.7522120.2665090.1809481.007495.2605980.1900920.235986?H01.23787>>4.2815480.233561.392525E1+F1+H00.1585771.41253.7522120.2665091.1872740.330853?diff/others:12.448620.080330.080330.05454-0.381750?J=5(?)J=4V78guess!0.66251.5094341.50943417.61490.6960041.4367741.4367741E14.874031.0873960.9196280.6092544.684421.131410.8838530.615165F11.444473.6691660.2725420.1805591.186074.4685390.2237870.155756H01.126314.7056320.2125111.4046810.1407891.164614.550880.2197381.3273770.152938diff/others:9.5462810.1047530.1047530.0693999.1410830.1093960.1093960.07614

  • https://notendur.hi.is/agust/rannsoknir/rempi/hbr/Jan12/XLS-130212ak.xls

    Bw vs lifetime comparisons81

    J=6J=6J=3states:Bw/cm-1t(ps)=1/t (ps-1)rate const. SumsfractionBw/cm-10t(ps)=1/t (ps-1)rate const. SumsfractionV77.80613ca.0.6789541.4728551.472855V71?4.269271.241430.8055230.8055231?E13.30123>1.6054620.6228740.422902?3.761811.4088960.7097750.881137?F11.58492>>3.3440170.2990420.203035?1.319214.0175560.2489080.309001?H01.35547>>3.9100830.2557491.177664E1+F1+H00.173642?1.392113.807170.2626621.2213450.326077?diff/others:3.3876420.2951910.2951910.200421?-0.415820?J=5(?)J=4V78.525guess!0.6217011.6084911.60849117.61490.6960041.4367741.4367741E14.977771.0647340.9392020.5839033.940641.3449590.7435170.517491F12.321782.2827310.4380720.272351.700663.1164370.3208790.223333H01.224254.3291810.2309911.6082640.1436071.257744.2139070.2373091.3017060.165168diff/others:4416.6670.0002260.0002260.0001417.4036820.1350680.1350680.094008

  • In summary: according to J=4 and 6: i = 79 & 81 : rates ca.E1H0V7F11/t0H01/tV7 = 1.47 ps-11/t0F11/t0E11/tH0=0.23 ps-11/tE1 = 0.83 ps-1 1/tF1 =0.27 1/tother=0.11 ps-1

  • In summary: according to J=4 and 6: i = 79& 81 : fractional rates ca.:E1H0V7F11/t0H0Rel. 1/tV7 = 11/t0F11/t0E1Rel. 1/tE1 = 0.58Rel. 1/tH0 =0.16 Rel. 1/tF1 =0.19 1/tother=0.07