9
-1- グラフェン・酸化グラフェン・還元型酸化グラフェン グラフェンペーパー 製品名 応用 製品番号 Graphene paper, size 11.5 in. × 23.5 in., thickness 50 μm This is a thin, flexible and lightweight sheet product built on graphene nanoplatelets. It is a more effective solution than aluminum and copper foils for a wide variety of applications to optimize thermal conductivity, thermal spreading, electrical properties, and corrosion resistance. 900449-1EA Graphene paper, size 11.5 in. × 23.5 in., thickness 120 μm 900451-1EA Graphene paper, size 11.5 in. × 23.5 in., thickness 240 μm 900452-1EA グラフェンインク・分散液 製品名 溶媒 粘性 グラフェンサイズ 用途、ほか 製品番号 Graphene dispersion, with ethyl cellulose 1 cyclohexanone and terpineol 8-15 mPa.s (30 °C) ≤3 μm inkjet printable 793663-5ML Graphene dispersion, with ethyl cellulose 1 terpineol 0.75-3 Pa.s (25 °C) (shear viscosity at 100 s -1 , 25 °C) ≤3 μm gravure printable 796115-10ML Graphene dispersion, with ethyl cellulose 1 terpineol 5-50 Pa.s (25 °C) (shear viscosity at 10 s -1 ) ≤3 μm screen printable 798983-10ML Graphene ink ~0.1 wt. % solids in water 1 cP (100 s -1 ) 80-500 nm (exfoliated graphene flakes) Inkjet printable 808288-5ML Graphene ink 7 wt. % solids in water 570 cP (100 s -1 ) 500-1500 nm (exfoliated graphene flakes) flexo/gravure/screen printable 805556-10ML Graphene ink 10 wt. % solids in water 350 cP (100 s -1 ) 500-1500 nm (exfoliated graphene flakes) screen printable 808261-10ML 3D Printing Graphene Ink 2 - 25-45 Pa.s (20 °C) 1-20 μm (length and width) Direct syringe extrusion, Dip-coating, Spin-coating, Casting 808156-5ML Graphene ink photonically annealable 3 - 2-4 mPa.s (20-30 °C) (10-1000 s -1 ) ≤3 μm spin-coating, spray- coating 900960-10ML Graphene ink photonically annealable - 7-14 mPa.s (25 °C) (shear viscosity at 10 s -1 ) ≤3 μm inkjet printing 900695-5ML Graphene dispersion, 0.2 mg/mL in DMF 4 DMF - Sheet size by AFM: 5-10 μm. sheet resistance 2 kΩ/sq 900448-50ML Graphene dispersion, 1 mg/mL in DMF 4 DMF - Sheet size by AFM: 10 μm. sheet resistance 4.8 kΩ/sq 900450-5ML Graphene dispersion, 10 mg/mL, dispersion in NMP NMP - - - 803839-5ML Graphene/PEDOT:PSS hybrid ink dispersion in DMF 5 DMF - Sheet size by AFM: 10 μm 0.2 mg/mL (PEDOT:PSS) 900442-50ML Graphene dispersion, 0.5-1.0 mg/mL in water, with non-ionic surfactant 6 Water - ≤500 nm - 900696-10ML 1. “Inkjet Printing of High Conductivity, Flexible Graphene Patterns”, Ethan B. Secor, Pradyumna L. Prabhumirashi, Kanan Puntambekar, Michael L. Geier, and Mark C. Hersam, The Journal of Physical Chemistry Letters 2013 4 (8), 1347-1351. DOI: 10.1021/jz400644c 2. (a)“Three-Dimensional Printing of High-Content Graphene Scaffolds for Electronic and Biomedical Applications”, Adam E. Jakus, Ethan B. Secor, Alexandra L. Rutz, Sumanas W. Jordan, Mark C. Hersam, and Ramille N. Shah, ACS Nano 2015 9 (4), 4636-4648. DOI: 10.1021/acsnano.5b01179. (b)Webinar: 3D 印刷可能 なハイドロゲルおよび粒子を用いた生体材料インクプラットフォーム 3. “Rapid and Versatile Photonic Annealing of Graphene Inks for Flexible Printed Electronics.” Secor, E. B., Ahn, B. Y., Gao, T. Z., Lewis, J. A. and Hersam, M. C., Adv. Mater. 2015 27: 6683-6688. DOI: 10.1002/adma.201502866 4. “Exfoliation of Graphite into Graphene in Aqueous Solutions of Inorganic Salts”, Khaled Parvez, Zhong-Shuai Wu, Rongjin Li, Xianjie Liu, Robert Graf, Xinliang Feng, and Klaus Müllen, J. Am. Chem. Soc. 2014 136 (16), 6083-6091. DOI: 10.1021/ja5017156 5. “Transparent Conductive Electrodes from Graphene/PEDOT:PSS Hybrid Inks for Ultrathin Organic Photodetectors.”, Liu, Z. , Parvez, K. , Li, R. , Dong, R. , Feng, X. and Müllen, K., Adv. Mater. 2015 27: 669-675. DOI: 10.1002/adma.201403826 6. “High-Concentration Aqueous Dispersions of Graphene Using Nonionic, Biocompatible Block Copolymers”, Jung-Woo T. Seo, Alexander A. Green, Alexander L. Antaris, and Mark C. Hersam, The Journal of Physical Chemistry Letters 2011 2 (9), 1004-1008. DOI: 10.1021/jz2003556 カーボンナノ材料 材料科学関連製品の製品情報は下記 Web サイトまで http://www.aldrich.com/ms-jp (詳細な成分情報などは Web サイトをご確認ください)

カーボンナノ材料 - Sigma-Aldrich · Inkjet printable 808288-5ML Graphene ink 7 wt. % solids in water 570 cP (100 s-1) 500-1500 nm (exfoliated graphene flakes) flexo/gravure/screen

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Page 1: カーボンナノ材料 - Sigma-Aldrich · Inkjet printable 808288-5ML Graphene ink 7 wt. % solids in water 570 cP (100 s-1) 500-1500 nm (exfoliated graphene flakes) flexo/gravure/screen

-1-

グラフェン・酸化グラフェン・還元型酸化グラフェン

グラフェンペーパー

製品名 応用 製品番号

Graphene paper, size 11.5 in. × 23.5 in., thickness 50 μm This is a thin, flexible and lightweight sheet product built on graphene

nanoplatelets. It is a more effective solution than aluminum and copper

foils for a wide variety of applications to optimize thermal conductivity,

thermal spreading, electrical properties, and corrosion resistance.

900449-1EA

Graphene paper, size 11.5 in. × 23.5 in., thickness 120 µm 900451-1EA

Graphene paper, size 11.5 in. × 23.5 in., thickness 240 μm 900452-1EA

グラフェンインク・分散液

製品名 溶媒 粘性 グラフェンサイズ 用途、ほか 製品番号

Graphene dispersion, with ethyl cellulose 1 cyclohexanone and

terpineol 8-15 mPa.s (30 °C) ≤3 μm inkjet printable 793663-5ML

Graphene dispersion, with ethyl cellulose 1 terpineol

0.75-3 Pa.s (25 °C)

(shear viscosity at

100 s-1, 25 °C)

≤3 μm gravure printable 796115-10ML

Graphene dispersion, with ethyl cellulose 1 terpineol

5-50 Pa.s (25 °C)

(shear viscosity at 10

s-1)

≤3 μm screen printable 798983-10ML

Graphene ink ~0.1 wt. % solids in

water 1 cP (100 s-1)

80-500 nm

(exfoliated

graphene flakes)

Inkjet printable 808288-5ML

Graphene ink 7 wt. % solids in

water 570 cP (100 s-1)

500-1500 nm

(exfoliated

graphene flakes)

flexo/gravure/screen

printable 805556-10ML

Graphene ink 10 wt. % solids in

water 350 cP (100 s-1)

500-1500 nm

(exfoliated

graphene flakes)

screen printable 808261-10ML

3D Printing Graphene Ink 2 - 25-45 Pa.s (20 °C) 1-20 μm (length

and width)

Direct syringe extrusion,

Dip-coating, Spin-coating,

Casting

808156-5ML

Graphene ink photonically annealable 3 - 2-4 mPa.s (20-30 °C)

(10-1000 s-1) ≤3 μm

spin-coating, spray-

coating 900960-10ML

Graphene ink photonically annealable -

7-14 mPa.s (25 °C)

(shear viscosity at 10

s-1)

≤3 μm inkjet printing 900695-5ML

Graphene dispersion, 0.2 mg/mL in DMF 4 DMF - Sheet size by

AFM: 5-10 μm. sheet resistance 2 kΩ/sq 900448-50ML

Graphene dispersion, 1 mg/mL in DMF 4 DMF - Sheet size by

AFM: 10 μm.

sheet resistance 4.8

kΩ/sq 900450-5ML

Graphene dispersion, 10 mg/mL, dispersion

in NMP NMP - - - 803839-5ML

Graphene/PEDOT:PSS hybrid ink dispersion

in DMF 5 DMF -

Sheet size by

AFM: 10 μm 0.2 mg/mL (PEDOT:PSS) 900442-50ML

Graphene dispersion, 0.5-1.0 mg/mL in

water, with non-ionic surfactant 6 Water - ≤500 nm - 900696-10ML

1. “Inkjet Printing of High Conductivity, Flexible Graphene Patterns”, Ethan B. Secor, Pradyumna L. Prabhumirashi, Kanan Puntambekar, Michael L. Geier, and Mark

C. Hersam, The Journal of Physical Chemistry Letters 2013 4 (8), 1347-1351. DOI: 10.1021/jz400644c

2. (a)“Three-Dimensional Printing of High-Content Graphene Scaffolds for Electronic and Biomedical Applications”, Adam E. Jakus, Ethan B. Secor, Alexandra L.

Rutz, Sumanas W. Jordan, Mark C. Hersam, and Ramille N. Shah, ACS Nano 2015 9 (4), 4636-4648. DOI: 10.1021/acsnano.5b01179. (b)Webinar: 3D 印刷可能

なハイドロゲルおよび粒子を用いた生体材料インクプラットフォーム

3. “Rapid and Versatile Photonic Annealing of Graphene Inks for Flexible Printed Electronics.” Secor, E. B., Ahn, B. Y., Gao, T. Z., Lewis, J. A. and Hersam, M. C.,

Adv. Mater. 2015 27: 6683-6688. DOI: 10.1002/adma.201502866

4. “Exfoliation of Graphite into Graphene in Aqueous Solutions of Inorganic Salts”, Khaled Parvez, Zhong-Shuai Wu, Rongjin Li, Xianjie Liu, Robert Graf, Xinliang

Feng, and Klaus Müllen, J. Am. Chem. Soc. 2014 136 (16), 6083-6091. DOI: 10.1021/ja5017156

5. “Transparent Conductive Electrodes from Graphene/PEDOT:PSS Hybrid Inks for Ultrathin Organic Photodetectors.”, Liu, Z. , Parvez, K. , Li, R. , Dong, R. ,

Feng, X. and Müllen, K., Adv. Mater. 2015 27: 669-675. DOI: 10.1002/adma.201403826

6. “High-Concentration Aqueous Dispersions of Graphene Using Nonionic, Biocompatible Block Copolymers”, Jung-Woo T. Seo, Alexander A. Green, Alexander L.

Antaris, and Mark C. Hersam, The Journal of Physical Chemistry Letters 2011 2 (9), 1004-1008. DOI: 10.1021/jz2003556

カーボンナノ材料

材料科学関連製品の製品情報は下記 Webサイトまで

http://www.aldrich.com/ms-jp

(詳細な成分情報などはWeb サイトをご確認ください)

Page 2: カーボンナノ材料 - Sigma-Aldrich · Inkjet printable 808288-5ML Graphene ink 7 wt. % solids in water 570 cP (100 s-1) 500-1500 nm (exfoliated graphene flakes) flexo/gravure/screen

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グラフェン ナノプレートレット

製品名 組成、他 製品番号

Graphene nanoplatelets, 5 μm particle size, surface area 50-80 m2/g Residual acid content: <0.5 wt%

Composition oxygen content, <1%

Thickness 15 nm , average

900409-250G

Graphene nanoplatelets, 15 μm particle size, surface area 50-80 m2/g 900410-250G

Graphene nanoplatelets, 25 μm particle size, surface area 50-80 m2/g 900411-250G

Graphene nanoplatelets, 5 μm particle size, surface area 120-150 m2/g Residual acid content: < 0.5 wt%

Composition oxygen content, <1%

Thickness 6-8 nm , average

900412-250G

Graphene nanoplatelets, 15 μm particle size, surface area 120-150 m2/g 900420-250G

Graphene nanoplatelets, 25 μm particle size, surface area 120-150 m2/g 900413-100G

Graphene nanoplatelets, surface area 300 m2/g Thickness a few nm

Particle size <2 μm

900394-250G

Graphene nanoplatelets, surface area 500 m2/g 900439-250G

Graphene nanoplatelets, surface area 750 m2/g 900407-250G

Graphene nanoplatelets, 1 mg/mL, dispersion in H2O Highly conductive few layer graphene platelets.

Sheet Resistantce: 10 (+/-5) ohm/sq for a 25 μm film

799092-50ML

Graphene nanoplatelets, powder 799084-500MG

Graphene nanoplatelets, powder, hydrocarbon functionalized,

hydrophobic

Carbon >85 wt. %

Oxygen >3 wt. %

Dispersibility: dichloromethane, N-methyl-2-

pyrrolidone, and other non-polar solvents

Lipophilic hydrocarbon functionalization on graphene

nanoplatelets.

806633-25G

Graphene nanoplatelets, powder, hydrophobic

Carbon >95 wt. %

Oxygen <2 wt. %

Gaphene nanoplatelets with large lateral dimension (>

25 micron) Highly hydrophobic. It has been used with

success as electrical conductive additive in powder

coating formulation among other properties.

806668-25G

Graphene nanoplatelets, powder, oxidized

Carbon >95 wt. %

Oxygen >1 wt. %

It is slightly oxidized (content of oxygen around 2%)

yielding to a superior dispersion behavior in different

solvent/matrix. It has been used with success as anti-

corrosion additive in powder coating formulation among

other properties.

806641-25G

Graphene nanoplatelets, powder, polycarboxylate functionalized, hydrophilic

Carbon >70 wt. %

Oxygen >10 wt. %

Polycarboxylate chemically modified graphite

nanoplatelets. High stability in aqueous medium.

806625-25G

グラフェンナノリボン

製品名 サイズ、他 製品番号

Graphene nanoribbons Produced by unzipping multi-walled carbon nanotubes by potassium

intercalation. L × W: 2-15 μm × 40-250 nm

797774-500MG

Graphene nanoribbons, alkyl functionalized 797766-500MG

詳細はこちら→ 【レビュー】グラフェンナノリボン:その合成と応用

酸化グラフェン

製品名 用途、他 製品番号

Graphene oxide, 2 mg/mL, dispersion in H2O

• Chloride free (purified by dialysis)

• Monolayer sheet

• Mean sheet diameter: 22 μm, 90% below 50 μm by laser

diffraction

763705-25ML

763705-100ML

Graphene oxide, 4 mg/mL, dispersion in H2O monolayer content (measured in 0.5mg/mL): >95% 777676-50ML

777676-200ML

Graphene oxide, paste, non-exfoliated

Graphene oxide paste can make storage and transportation of large

quantities in a safe manner. Graphene oxide solutions of desired

concentration or graphene oxide paper or sheet can be made from

graphene oxide paste.

900704-25G

900704-100G

Graphene oxide, film (4cm (diameter) x 12-15mm

(thickness), non-conductive) Novel graphene oxide membranes for ionic and molecular sieving. 798991-1EA

Graphene oxide nanocolloids, 2 mg/mL, dispersion in H2O Single-layer graphene oxide sheets down to a few nanometers in

lateral width

795534-50ML

795534-200ML

Graphene oxide, 15-20 sheets, 4-10% edge-oxidized, 1

mg/mL, dispersion in H2O Oxygen (Dry Basis): < 11 %

794341-50ML

794341-200ML

Graphene oxide, 15-20 sheets, 4-10% edge-oxidized,

powder 796034-1G

Graphene oxide, alkylamine functionalized, 2.0 mg/mL,

dispersion (in toluene)

The excellent solubility /dispersibility of alkylamine-functionalized

graphene oxides (FGOs) in low-polar solvents. 809055-50ML

Graphene oxide, ammonia functionalized, 1 mg/mL,

dispersion in H2O Nitrogen: 3 - 6 %

791520-25ML

791520-100ML

Graphene oxide, pH stabilized, dispersion in 0.05 M HEPES

buffer, pH 7.5 -

901940-25ML NEW!

901940-100ML NEW!

Page 3: カーボンナノ材料 - Sigma-Aldrich · Inkjet printable 808288-5ML Graphene ink 7 wt. % solids in water 570 cP (100 s-1) 500-1500 nm (exfoliated graphene flakes) flexo/gravure/screen

-3-

ドープグラフェン他

製品名 アプリケーション例 製品番号

Graphene, alkylamine functionalized

• Polymer filler to improve thermal, electrical and mechanical

properties.

• Rubber filler to improve mechanical and gas barrier properties.

• Hydrophobic surface.

• Lubrication.

900551-250MG

Graphene, silane modified

• Polymer filler to improve thermal, electrical and mechanical

properties.

• Rubber filler to improve mechanical and gas barrier properties.

• Super hydrophobic surface.

900552-250MG

Nitrogen-doped graphene (high electrochemical activity)

High electrochemical activity towards oxygen reduction in alkali

medium providing an affordable industrial alternative to currently

used noble metal-based catalysts (i.e. Pt, Pd).

900416-500MG

Nitrogen-doped graphene (Nitrogen, 2.0-4.0%, >500 m2/g (BET))

• Electro catalyst.

• Field-effect transistors.

• Sensors.

• Lithium ion batteries.

• Supercapacitors. 900527-250MG

Nitrogen/Phosphorus co-doped graphene

• Electro catalyst.

• Field-effect transistors.

• Sensors.

• Lithium ion batteries.

• Supercapacitors.

900531-250MG

Nitrogen/Sulfur co-doped graphene 900530-250MG

Phosphorus-doped graphene 900529-250MG

Sulfur-doped graphene 900528-250MG

Boron-doped graphene 900526-250MG

Boron/Nitrogen co-doped graphene 900535-250MG

Graphene, powder, electrical conductivity >103 S/m • Anti-corrosion coatings.

• Anti-static packaging-cement.

• Composites electronics 900561-500MG

ナノコンポジット, 10 mg/mL, dispersion in acetone

製品名 Loading Density by TEM

Particle size アプリケーション例 製品番号

Pd/graphene 10%-50% (Pd nanocrystal)

5-50 nm (Pd nanocrystal)

• Perfect for transmission electron microscopy imaging standard.

• A catalytic material to be used in fuel cells, CH4 gas sensor.

803707-5ML

Pd/reduced graphene oxide 803790-5ML

Pt/graphene 5%-30% (Pt nanocrystal)

2-5 nm (Pt nanocrystal)

• Supercapacitor electrode materials.

• Filling materials for heating conduction.

• Photocatalysis.

803693-5ML

Pt/reduced graphene oxide 803782-5ML

PtCo/graphene 10%-50% (PtCo nanocrystal)

2-5 nm (PtCo nanocrystal) Efficient electrocatalyst material for fuel cells including

methanol oxidation, proton exchange membrane.

803766-5ML

PtCo/reduced graphene oxide 803901-5ML

PtPd/graphene 10%-50% (PtPd nanocrystal)

5-50 nm (PtPd nanocrystal)

803758-5ML

PtPd/reduced graphene oxide 803820-5ML

Fe3O4/graphene 30%-70% (Fe3O4 nanocrystal)

5-25 nm (Fe3O4 nanocrystal)

• Electromagnetic wave absorption materials.

• Electro-magnetic device.

• Anode material for lithium-ion batteries.

803715-5ML

Fe3O4/reduced graphene oxide 803804-5ML

Mn3O4/graphene 30%-70% (Mn3O4 nanocrystal)

5-25 nm (Mn3O4 nanocrystal)

High capacity anode material for supercapacitors and lithium

ion batteries.

803723-5ML

Mn3O4/reduced graphene oxide 803812-5ML

TiO2/graphene 30%-70% (TiO2 nanocrystal)

10-40 nm (TiO2 nanocrystal)

• Photocatalyst

• Dye sensitized solar cells

805351-5ML

TiO2/reduced graphene oxide 805343-5ML

単層グラフェン膜 by CVD

製品名 Substrate 製品番号

Monolayer graphene film, 1 cm x 1 cm on copper foil Cu Foil thickness: 25 μm 773697-4EA

Monolayer graphene film, 1 in x 1 in on copper foil Cu Foil thickness: 18 μm

799009-1EA

Monolayer graphene film, 4 in diameter on copper foil 900415-1EA

Monolayer graphene film 1 in x 1 in on copper foil, with PMMA coating Cu Foil thickness: 18 μm

PMMA Coating: <100 nm

900445-1EA

Monolayer graphene film 1 cm x 1 cm on copper foil, with PMMA coating 900443-4EA

Monolayer graphene film, 1 cm x 1 cm on quartz Quartz substrate thickness: 525 μm 773719-4EA

Monolayer graphene film, 1 cm x 1 cm on SiO2/Si substrate SiO2/Si substrate thickness: 525 μm 773700-4EA

Monolayer graphene film, 1 in. x 1 in. on PET film PET film thickness: 0.188 mm

745863-1EA

745863-5EA

Monolayer graphene film, 2 in. x 2 in. on PET film 745871-1EA

Suspended monolayer graphene on TEM grid substrate (Quantifoil gold)

Type: QUANTIFOIL R 2/4

Hole Size: 2 micrometers

Space between holes: 4

micrometers

Diameter: 3 mm

Coating: Au coated 798177-1PK

還元型酸化グラフェン

製品名 組成 表面積、他 製品番号

Reduced graphene oxide Carbon: >75%

Nitrogen: <5%

BET surf. Area: 103 m2/g

Conductivity: 7111 S/m (pressed pallet)

805424-500MG

805424-1G

Reduced graphene oxide Carbon: 95 wt. %

Nitrogen: >5 wt. %

BET surf. Area: 450 m2/g

Conductivity: 600 S/m (20 nm film thickness)

777684-250MG

777684-500MG

Page 4: カーボンナノ材料 - Sigma-Aldrich · Inkjet printable 808288-5ML Graphene ink 7 wt. % solids in water 570 cP (100 s-1) 500-1500 nm (exfoliated graphene flakes) flexo/gravure/screen

-4-

Reduced graphene oxide, amine functionalized Carbon: >65 wt. %

Nitrogen: >5 wt. % 805432-500MG

Reduced graphene oxide, octadecylamine functionalized Carbon: >78 wt. %

Nitrogen: >3 wt. % Surface group: -NH(CH2)17CH3 805084-500MG

Reduced graphene oxide, piperazine functionalized Carbon: >65 wt. %

Nitrogen: >5 wt. % Surface group: piperazine 805440-500MG

Reduced graphene oxide, tetraethylene pentamine

functionalized

Carbon: >65 wt. %

Nitrogen: >8 wt. % Surface group: -N(CH2CH2NHCH2CH2NH2)2 806579-500MG

Reduced graphene oxide, stabilized with poly(sodium 4-

styrenesulfonate), 10 mg/mL, dispersion in H2O -

Non-covalent functionalization with PSS

molecules prevents rGO from aggregation. 900197-100ML

単層カーボンナノチューブ ※供給元資料よりの参考情報。製品規格は Web サイトにてご確認ください。

Carbon nanotube, single-walled(Signis ®

CG-100)

Carbon nanotube, single-walled(Signis ®

CG-200)

Carbon nanotube, single-walled(Signis

® CG 300)

704113-250MG, 1G 724777-250MG, 1G 775533-250MG, 1G

Economical Single-Wall CNT

Carbon Purity: ≥ 90 wt% (TGA)

CNT Purity: ≥ 89 wt% (TGA)

Average Diameter: 0.82 nm (NIRF)

Median Length: 1 micron (AFM)

Specific Surface Area: ≥ 700 m2/g (BET)

Moisture Content: ≤ 5 wt% (TGA)

G/D Ratio: ≥ 15 (Raman, 633 nm)

Large Diameter Single-Wall CNT

Carbon Purity: ≥ 90 wt% (TGA)

CNT Purity: ≥ 89 wt% (TGA)

Average Diameter: 1.3 nm (NIRF)

Median Length: 1 micron (AFM)

Specific Surface Area: ≥ 700 m2/g (BET)

Moisture Content: ≤ 5 wt% (TGA)

G/D Ratio: ≥ 15 (Raman, 633 nm)

Conductive Single-Wall CNT

Carbon Purity: ≥ 95 wt% (TGA)

CNT Purity: ≥ 94 wt% (TGA)

Average Diameter: 0.84 nm (NIRF)

Median Length: 1 micron (AFM)

Specific Surface Area: ≥ 700 m2/g (BET)

Moisture Content: ≤ 5 wt% (TGA)

G/D Ratio: ≥ 15 (Raman, 633 nm)

Sheet Resistance: ≤600 Ω/□ @ 85% VLT

(TCF)

Carbon nanotube, single-walled,(6,5)

chirality(Signis ® SG-65i)

Carbon nanotube, single-walled,(6,5)

chirality(Signis® SG-65)

Carbon nanotube, single-walled,(7,6)

chirality(Signis ® SG-76)

773735-250MG, 1G 704148-250MG, 1G 704121-250MG, 1G

Semiconducting Single-Wall CNT Enriched in

Chirality (6,5)

Carbon Purity: ≥ 95 wt% (TGA)

CNT Purity: ≥ 94 wt% (TGA)

Semiconducting CNT Content: 95% (Opt. Abs.)

(6,5) CNT Content: ≥ 40% (NIRF)

Average Diameter: 0.78 nm (NIRF)

Median Length: 1 micron (AFM)

Specific Surface Area: ≥ 700 m2/g (BET)

Moisture Content: ≤ 5 wt% (TGA)

G/D Ratio: ≥ 20 (Raman, 633 nm)

組成: >90%(carbon)、≥77%(carbon as

SWCNT, T1%)

長さ: ≥700 nm

直径: 0.7 - 0.9 nm(光吸収スペクトルお

よび AFM にて確認)

Single-Wall CNT Enriched in Chirality (7,6)

Carbon Purity: ≥ 90 wt% (TGA)

CNT Purity: ≥ 89 wt% (TGA)

Average Diameter: 0.83 nm (NIRF)

Median Length: 1 micron (AFM)

Specific Surface Area: ≥ 700 m2/g (BET)

Moisture Content: ≤ 5 wt% (TGA)

Carbon nanotube, single-walled

(NANOCYL™ NC1100)

Carbon nanotube, single-walled

(Tuball)

Carbon nanotube, single-walled Low

metal content (Tuball) NEW!

755710-250MG, 1G 805033-25G 901634-25G

製法 CVD 法

炭素純度 >70% (TGA)

不純物 金属酸化物・カーボンシェル:

<30% (TGA), アモルファルカー

ボン: NA (HRTEM)

平均直径×長さ 2 nm (HRTEM, Raman) × several

μm (TEM)

表面積 >1000 m2/g (BET)

組成: ≥85 % (carbon), >70%

(carbon as SWNT)

平均直径×長さ 1.8 nm (1.3-2.3 nm) ×>5 μm

(AFM)

表面積 ~520 m2/g (BET)

Used as additives

組成 ≥93% (carbon as SWNT by TEM,

TGA)

>99% (carbon content, EDX, TGA)

長さ >5 μm , By AFM

直径 1.2-2.0 nm , By Optical absorption

不純物 <1% Metal impurities (TGA, By EDX)

Low-iron, purified SWCNT powder especially for use

in energy applications

Carbon nanotube, single-walled

(ZEONANO)

900711-5G

製法 Super-growth (SG) method

組成: ≥98 % carbon basis

Ash: < 1%

平均直径×長さ 3-5 nm ×>300-500 μm (in

forest)

表面積 800-1000 m2/g (BET)

Application

• Electrode in power storage devices.

• Additives in structural materials.

• Flexible electronic materials.

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Signis is a registered trademark of Chasm Advanced Materials, Inc. CoMoCAT is a trademark of Chasm Advanced Materials, Inc. NANOCYL is a trademarks of Nanocyl, Inc.

Nanointegris社製単層カーボンナノチューブ (詳しくは Web サイト(www.aldrich.com/nano-jp)をご覧ください)

IsoNanotubes-M™ (750530-

1MG)

IsoNanotubes-S™ (750522-

1MG)

PureTubes™ (750492-100MG)

SuperPureTubes™ (750514-25MG)

ナノチューブタイプ Arc discharge or Plasma Torch

チューブ直径 1.2 - 1.7 nm

チューブ平均直径 1.4 nm

チューブ長さ 0.3 – 5 µm

チューブ平均長さ 1 micron

炭素系不純物 < 5% by mass

残留触媒 ~1% by mass ~1% by mass < 3.5% by mass (750492)

< 1% by mass (750514)

半導体性 CNT 含有量 2 % 98% 70 %

金属性 CNT 含有量 98% 2 % 30 %

価格 ¥107,000 ¥70,200 ¥49,700 (750492)

¥46,000 (750514)

IsoNanotubes, PureTubes and SuperPureTubes are trademarks of NanoIntegris, Inc.

透明導電性 CNT インク CoMoCAT®カーボンナノチューブを含む導電性インクには、コーティングの種類ごとに 3 つのタイプがあります。耐久性と環境安定性の必要な用途で、優れた透明

導電性を示すコーティングが可能です。

製品名 用途 製品番号

SWCNT, conductive aqueous ink, 0.2 mg/mL (Signis® AC100) Spray Coating 791490-25ML

791490-100ML

SWCNT conductive aqueous ink, 1.00 mg/mL (Signis® AC200) Meyer-Rod/Slot-Die Coating 791504-25ML

791504-100ML

SWCNT solvent-based conductive ink, 1 mg/mL (Signis® VC101 ink) Screen Printing 792462-25ML

792462-100ML

※詳細な物性やコーティング条件は、供給元 Chasm Advanced Materials 社の Web サイト(www.chasmtek.com)をご覧ください。

カーボンナノホーン Web サイト(www.aldrich.com/nano-jp)にて、レビュー「カーボンナノホーン:大量製造技術、材料特性、応用展開」を公開中です。

製品名 物性 製品番号・価格

Carbon nanohorns, as-grown

(CNH, CNHs)

assay:90% (TGA) impurities:0% metallic, 10% graphite, amorphous

diameter:2-5 nm (TEM)

surface area:spec. surface area 400 m2/g (BET)

804118-250MG

Carbon nanohorns, oxidized

(CNHox, Holey Carbon

Nanohorns)

assay:90% (TGA) impurities:0% Metallic compound, 10% graphite;

amorphous

diameter:2-5 nm (TEM)

surface area:spec. surface area 1300-1400 m2/g (BET method)

804126-250MG

ポリジアセチレンナノチューブ(PDNT) ポリジアセチレンナノチューブ(PDNT:Polydiacetylene Nanotube)は、共役 2 重、3 重結合の架橋構造から構成される自己組織化ジアセチレンナノチューブで

す。PDNT は、均一な構造をもち、固体もしくは溶液内において応答性の高いクロミック特性を示すことで知られています。Web サイト(www.aldrich.com/nano-

jp)にて、レビューを公開中です。

性質

• 内径と外径が非常に均一な高純度ナノチューブ

• ポリマー内のπ電子による電気伝導性

• 熱およびメカノクロミズム

期待される応用例

• バイオセンサ

• 色の変化を利用した圧力センサ

• 酵素担体

• ナノエレクトロニクス、Lab-on-a-chip デバイス

• Langmuir-Blodgett 膜

• MEMS、メンブレンフィルタ、ガス分離

Poly(N-[2-(ethylamino)ethyl]-10,12-pentacosadiyneamide hydrogen bromide) nanotube

O.D. × I.D. × L 100 nm × 30 nm × 1,000 nm 773484-250MG

Poly(N-[2-(propylamino)ethyl]-10,12-pentacosadiyneamide hydrogen bromide) nanotube

O.D. × I.D. × L 110 nm × 40 nm × 1,000 nm 773492-250MG

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修飾済み単層カーボンナノチューブ

Single-walled carbon nanotubes, octadecylamine

functionalized 1)

Single-walled carbon nanotubes, polyaminobenzene sulfonic

acid functionalized 2)

652482-100MG 639230-100MG

炭素含有量 80 – 90 % (carbon basis)

ODA 含有量 30 – 40 wt.%

金属含有量 2 - 6 %

直径(Bundle) 2 – 10 nm

長さ 0.5 – 2 µm, bundles

溶解性

THF, 1,2-Dichlorobenzene, CS2 : ≧1 mg/ml

ベンゼン、トルエン、クロロホルム、ジクロロメタンにも溶解

炭素含有量 75 – 85 % (carbon basis)

金属含有量 4 %

ポリマー含有量 65 % (PABS, typical)

ポリマー平均分子量 Mw 400 – 600 g/mol (PABS)

直径(Bundle) 4 – 5 nm

長さ 500 – 1000 nm

溶解性 c) H2O: 5.0 mg/ml, DMF: 0.1 mg/ml,

Ethanol: 0.05 mg/ml

Single-walled carbon nanotubes, poly(ethylene glycol)

functionalized 2) Carbon nanotube, single-walled, amide functionalized

652474-100MG 685380-100MG

炭素含有量 > 80 % (carbon basis)

金属含有量 4 - 5 %

ポリマー含有量 80 wt.%

ポリマー平均分子量

Mw ~600 g/mol (PEG)

直径(Bundle) 4 – 5 nm

長さ 500 – 600 nm, bundles

溶解性 H2O: 5.0 mg/ml

炭素含有量 > 90 % (carbon basis)

アミド含有量 per 4 atom% (amide groups)

金属含有量 5 - 8 %

直径(Bundle) 4 – 6 nm

長さ 0.7 – 1.0 µm, bundles

溶解性

DMF, acetone, alcohols:

0.5 - 1.0 mg/mL (with sonication)

Single-walled carbon nanotubes, carboxylic acid functionalized

652490-250MG, 1G

As-produced nanotubes are purified with nitric acid and left

in a highly functionalized form. This material contains

carboxylic acid functionality along the length of the

nanotube which can be derivatized with a variety of

functional groups.(2) The carboxylic acid groups are located

at the edge and defect sites on the side walls. The SWNTs

material is produced by electric arc discharge technique.(4),(5)

The type of Carboxylic group is ”-COOH”.

炭素含有量 > 90 % (carbon basis)

カルボン酸含有量 1.0 - 3.0 atom% carboxylic acid

金属含有量 5 - 8 %

直径(Bundle) 4 – 5 nm

長さ 0.5 – 1.5 µm, bundles

溶解性 DMF = 1.0 mg/ml, H2O = 0.1 mg/ml

各 SWCNT の平均直径は 1.4 nm ± 0.1 nm。炭素含有量は「Nano. Lett., 2003, 3(3), 309」の方法で測定。アーク放電法で作製された SWCNT を使用。

1) Niyogi, S. et al. Accts. Chem. Res. 2002, 35, 1105. 2) Zhao, B. et al. Adv. Funct. Mater. 2004, 14(1), 71., Zhao, B. et al. J. Am. Chem. Soc. 2005, 127, 8197.

3) Solubilities determined by NIR absorbance. 4) Journet, C. et al., Nature 1997, 388, 756. 5) Itkis, M.E. et al. J. Phys. Chem. B 2004, 108, 12770.

Nanocyl社製 2層カーボンナノチューブ

NANOCYLTM NC2150, Short Double-Wall

製品番号、価格 755141-1G

製法 CVD 法

炭素純度 >90% (TGA)

不純物 金属酸化物:<10% (TGA)

カーボンシェル・アモルファルカーボン: TBD (HRTEM)

平均直径×長さ 3.5 nm (HRTEM) × several μm (TEM/SEM)

※供給元資料よりの参考情報

多層カーボンナノチューブ

Carbon nanotube, few-walled

(Signis® FW100) Carbon nanotube, multi-walled

Carbon nanotube, multi-walled,

thin(NANOCYLTM NC-3100)

900788-250MG, 1G 698849-1G 755133-5G

組成: > ≥94% (carbon as CNT by TGA)

Median number of walles: 2 to 3 (TEM)

G/D ratio: ≥10 (Raman)

直径×長さ: 2.5-3 nm × 2-6 μm

BET 表面積: >700 m2/g (BET)

製法: CoMoCAT™ synthesis process

組成: >98% carbon content (trace metal basis)

外径×長さ:

6 - 13 nm × 2.5 - 20 μm (約7 ~ 13層)

BET 表面積 約 220 m2/g (SSA)

製法: CVD 法 (塩酸処理済み)

組成: >95% carbon content (TGA)

直径×長さ: 9.5 nm × 1.5 μm (TEM)

金属酸化物: < 5% (TGA)

製法: CVD 法

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Carbon nanotube, multi-walled,

short, thin(NANOCYLTM NC-3150)

Carbon nanotube, multi-walled,

thin, carboxylic acid functionalized Carbon nanotube, multi-walled

755117-1G 755125-1G 659258-2G, 10G

組成: >95% carbon content (TGA)

直径×長さ: 9.5 nm × 1 μm (TEM)

金属酸化物: < 5% (TGA)

製法: CVD 法

組成: >8% carboxylic acid functionalized

直径×長さ:

9.5 nm × 1.5 μm (TEM)

製法: CVD 法

Product of Nanocyl, Inc

組成: >90% carbon content、≤0.1 % (Fe)

直径×長さ:

110 – 170 nm × 5 – 9 μm

製法: CVD 法

Carbon nanotube, multi-walled,

flake of bundled CNTs

Carbon nanotube, multi-walled,

vertically aligned on Si substrate

Carbon nanotube, multi-walled,

vertically aligned on Si substrate

901002-1G 901052-1EA 901051-1EA

組成: >95% carbon content

直径(O.D.)×長さ:

10-40 nm × 0.5-1.5 mm

製法: CVD 法

基板: 20 mm x 20 mm Si substrate

Areal density: 1-5 x 109 cm-2

直径×長さ: 10 - 40 nm × 1.0 mm ± 0.1 mm

組成: ≥98% (carbon as CNT)

製法: CVD 法

基板: 20 mm x 20 mm Si substrate

Areal density: 1-5 x 109 cm-2

直径×長さ: 10 - 40 nm × 0.5 mm ± 0.1 mm

組成: ≥98% (carbon as CNT)

製法: CVD 法

Carbon nanotube, multi-walled,

drawable, vertically aligned on Si

substrate

Carbon nanotube, multi-walled,

sheet

Carbon nanotube, multi-walled,

sheet

901046-1EA 901082-1EA 901056-1EA

基板: 10 mm x 20 mm Si substrate

Areal density: 1-5 x 109 cm-2

直径×長さ: 10 - 40 nm × 1.0 mm ± 0.1 mm

組成: ≥98% (carbon as CNT)

製法: CVD 法

組成: >95% carbon content

直径: 10-40 nm (carbon nanotubes)

シート大きさ: 100 mm × 100 mm × 1-5 μm

製法: CVD 法

組成: >95% carbon content

直径: 10-40 nm (carbon nanotubes)

シート大きさ: 50 mm × 50 mm × 1-5 μm

製法: CVD 法

Carbon nanotube, multi-walled

901019-25G

組成: >95% carbon content

直径: 50-90 nm

アスペクト比: >100 , by FE-SEM

製法: CVD 法

Carbon nanochips

別名 Heat treated platelet graphite nanofibers, carbon

nanochip fibers

外観 flakes

サイズ aspect Ratio: 25, average length: 2.5μm, average

width : 100 nm

表面積 40 m2/g

799017-500MG

Application

• Negative electrode for lithium ion secondary batteries.

• Catalyst for ethylene oxidative dehydrogenation.

General description

Carbon nanochips consist of wrapped graphite sheets oriented perpendicular

to the fiber axis. Carbon nanochips are formed when platelet graphene or

graphite nanofibers are heated in argon to about 3000°C, resulting in a

sealing action of some of the edge sites and also removes all traces of

inclusions such as the catalyst that is used to grow the precursor graphite

nanofibers.

フラーレン誘導体

[60]PCBM Bis[60]PCBM, 99.5%(mixture of isomers)

[70]PCBM, 99% PCBB, [60]PCB-C4 , > 97%

(99%: scale-up grade)

684430-1G

(99.5%: research grade)

684449-100MG, 500G

(99.9%: for exploratory work)

684457-100MG

704326-100MG 684465-100MG, 500G 685321-100MG, 1G

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PCBO, [60]PCB-C8 , 99% [60]ThCBM, 99% d5-PCBM, 99% C60 Pyrrolidine tris-acid ethyl ester, 97%

684481-100MG 688215-100MG 684503-100MG 709093-250MG

C60 Pyrrolidine tris-acid, 97% (1,2-Methanofullerene C60)-61-carboxylic acid

N-Methylfulleropyrrolidine, 99%

ICBA

709085-100MG 658847-25MG 668184-100MG (99%) 753955-250MG

(99.9%) 745839-250MG

water, pH >9: soluble

ICMA, 97% Small gap fullerenes1 Small gap fullerene-ethyl nipecotate, ≥95%

Polyhydroxy small gap fullerenes, hydrated

753947-250MG 707503-1G 707473-250MG 707481-100MG

water, pH >9: soluble

C60-SAM, >99% Polyhydroxylated fullerenes, Water soluble (C60(OH)n · mH2O (n>40, m>8))

802832-100MG 793248-100MG

極性溶媒に対して溶解性をもたないフラーレンを水溶性にするため、フラーレン分子表面に多数の水酸基を付与

することにより、優れた水溶解性を実現しています。また、共役結合に由来する抗酸化に加え、水酸基由来の抗酸

化作用を発揮するため、優れた抗酸化作用を示します。これらの特徴を生かし、研磨剤としての利用やライフサイ

エンス分野など幅広い応用が期待されます 2-7。

【特徴】

● 40 個以上の水酸基を持つフラーレン誘導体

● 高い水溶解性(50 mg/mL)

● 水溶液中で単分散

● 優れた抗酸化作用・抗炎症作用

● 抗菌作用など生物学的応用にも期待

1. Diener, M.D. et. al Carbon 49, 37-46, (2011) 2. Kokubo K, et al. Nano Res 4(2), 204-215, (2011) 3. Ken Kokubo et. al ACS Nano, 2(2), 327-333 (2008) 4. Yasukazu Saitoh et. al Journal

of Photochemistry and Photobiology B: Biology, 102(1), 69-76 (2011) 5. Eropkin YM, et al. Pharmaceut. Chem. J. 47(2), 87-91, (2013) 6. Hisae Aoshima et. al Biocontrol Science, 14(2),

69-72 (2009) 7. Yasukazu Saitoh et. al Molecular and Cellular Biochemistry, 366(1-2), 191-200 (2012)

炭素系量子ドット Carbon quantum dots, 0.2+% in H2O (λem 450-550 nm) 900414-10ML

Graphene quantum dots, blue luminescent, 1 mg/mL in H2O 900708-50ML

Graphene quantum dots, blue luminescent, powder 900726-50MG

Graphene quantum dots, cyan luminescent, 1 mg/mL in H2O 900707-50ML

Graphene quantum dots, aqua green luminescent, 1 mg/mL in H2O 900712-50ML

Graphene quantum dots, aqua green luminescent, powder 900713-50MG

Graphene quantum dots, >0.005% in H2O 900560-10ML

900708(Graphene quantum dots, blue luminescent)の外観および TEM 像

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蛍光ナノダイヤモンド

蛍光ナノダイヤモンドは、ダイヤモンド中の窒素と格子欠陥が形成する N-V(nitrogen-vacancy) cenrter による高い蛍光特性を有するナノダイヤモンドです。また、

ナノダイヤモンドは高い生体適合性を持ち、低い細胞毒性および遺伝毒性を示すことから、生物医学用イメージングや診断、治療薬としての利用が期待されてい

ます。Web サイト(www.aldrich.com/nano-jp)にて、レビュー「色中心を有する蛍光ナノダイヤモンド粒子:その特性と応用」を公開中です。

製品名 製品番号

Fluorescent nanodiamond, Nitrogen vacancy >300 NV/particle, 70 nm, 1 mg/mL in deionized water 798169-5ML

Fluorescent nanodiamond, Nitrogen vacancy >500 NV/particle, 90 nm, 1 mg/mL in deionized water 798150-5ML

Fluorescent nanodiamond, Nitrogen vacancy >400 NV/particle, 100 nm, 1 mg/mL in deionized water 798142-5ML

Fluorescent nanodiamond, Nitrogen vacancy >800 NV/particle, 100 nm, 1 mg/mL in deionized water 798134-5ML

Fluorescent nanodiamond, Nitrogen vacancy >1200 NV/particle, 120 nm, 1 mg/mL in deionized water 798088-5ML

Fluorescent nanodiamond, Nitrogen vacancy <=4 NV/particle, 35 nm, 1 mg/mL in deionized water, carboxylated 900172-5ML

Fluorescent nanodiamond, Nitrogen vacancy >60 NVN/particle, 70 nm, 1 mg/mL in deionized water 900173-5ML

Fluorescent nanodiamond, Nitrogen vacancy >900 NV/particle, 100 nm, 1 mg/mL in deionized water, hydroxylated 900174-5ML

Fluorescent nanodiamond, nitrogen vacancy ~3 ppm, 140 nm avg. part. size, amine functionalized, powder 901799-5MG NEW!

Fluorescent nanodiamond, nitrogen vacancy ~3 ppm, 140 nm avg. part. size, amine functionalized, PEG 3000 coated, 1

mg/mL in deionized water 901802-5ML NEW!

Fluorescent nanodiamond, nitrogen vacancy ~3 ppm, 140 nm avg. part. size, biotin functionalized, PEG 3000 coated, 1

mg/mL in deionized water 901798-2ML NEW!

Fluorescent nanodiamond, nitrogen vacancy ~3 ppm, 140 nm avg. part. size, carboxylic acid functionalized, PEG 3000

coated, 1 mg/mL in deionized water 901800-5ML NEW!

Fluorescent nanodiamond, nitrogen vacancy ~3 ppm, 140 nm avg. part. size, hydroxyl functionalized, PEG 3000 coated, 1

mg/mL in deionized water 901803-5ML NEW!

Nanodiamonds, 65 nm octadecane functionalized, powder 901770-1G NEW!

Nanodiamonds, 65 nm, dodecane functionalized, powder 901967-1G NEW!

Monodispersed nanodiamond particles, 5 nm, 10 mg/mL in NMP, carboxylated 900177-100ML

Monodispersed nanodiamond particles, 5 nm, 10 mg/mL in polyalphaolefin synthetic base oil, carboxylated 900178-5ML

900178-100ML

Monodispersed nanodiamond particles, 5 nm, 10 mg/mL in DMSO, hydroxylated 900179-5ML

900179-100ML

Monodispersed nanodiamond particles, 5 nm, 10 mg/mL in H2O, carboxylated 900180-5ML

900180-100ML

Monodispersed nanodiamond particles, 5 nm, 10 mg/mL in ethylene glycol, carboxylated 900184-5ML

900184-100ML

Monodispersed nanodiamond particles, 5 nm, 10 mg/mL in DMSO 900185-5ML

900185-100ML

掲載の製品及び情報は 2019年 3月 1日現在の内容であり、収載の品目、製品情報、価格等は予告なく変更される場合がございます。/ 最新の情報は、弊社Webサ

イト(sigmaaldrich.com/japan)をご覧ください。/ 掲載価格は希望販売価格(税別)です。詳細はシグマ アルドリッチ製品販売代理店様へご確認ください。/ 弊社の試薬

は試験研究用のみを目的として販売しております。医薬品原料並びに工業用原料等としてご購入の際は、こちらの Webサイト(sigma.com/safc-jp)をご覧ください。