8
RESEARCH ARTICLE Drag reduction using superhydrophobic sanded Teflon surfaces Dong Song Robert J. Daniello Jonathan P. Rothstein Received: 8 January 2014 / Revised: 13 June 2014 / Accepted: 2 July 2014 Ó Springer-Verlag Berlin Heidelberg 2014 Abstract In this paper, a series of experiments are pre- sented which demonstrate drag reduction for the laminar flow of water through microchannels using superhydro- phobic surfaces with random surface microstructure. These superhydrophobic surfaces were fabricated with a simple, inexpensive technique of sanding polytetrafluoroethylene (PTFE) with sandpaper having grit sizes between 120- and 600-grit. A microfluidic device was used to measure the pressure drop as a function of the flow rate to determine the drag reduction and slip length of each surface. A maximum pressure drop reduction of 27 % and a maximum apparent slip length of b = 20 lm were obtained for the superhy- drophobic surfaces created by sanding PTFE with a 240-grit sandpaper. The pressure drop reduction and slip length were found to increase with increasing mean particle size of the sandpaper up to 240-grit. Beyond that grit size, increasing the pitch of the surface roughness was found to cause the interface to transition from the Cassie–Baxter state to the Wenzel state. This transition was observed both as an increase in the contact angle hysteresis and simulta- neously as a reduction in the pressure drop reduction. For these randomly rough surfaces, a correlation between the slip length and the contact angle hysteresis was found. The surfaces with the smallest contact angle hysteresis were found to also have the largest slip length. Finally, a number of sanding protocols were tested by sanding preferentially along the flow direction, across the flow direction and with a random circular pattern. In all cases, sanding in the flow direction was found to produce the largest pressure drop reduction. 1 Introduction Superhydrophobic surfaces can be found in nature in a number of plants and insects around the world (Barthlott and Neinhuis 1997; Hebets and Chapman 2000; Hu et al. 2003; Nørgaard and Dacke 2010; Shirtcliffe et al. 2006a, b; Zheng et al. 2007). Superhydrophobic surfaces have large advancing contact angles, h A [ 150°, and little difference between their advancing and receding contact angles, h A & h R . The extreme water repellency of naturally occurring superhydrophobic surfaces gives the lotus leaves and other plants their self-cleaning properties (Barthlott and Neinhuis 1997), allows water striders to walk on water (Hu et al. 2003) and makes it possible for insects and spiders to breath under water (Hebets and Chapman 2000; Shirtcliffe et al. 2006a). There are two important factors needed to produce superhydrophobic surfaces: low surface energy and micro/nanoroughness. The combination of surface roughness and hydrophobicity can trap an air layer in the depressions on the surface and result in the formation of an air–water interface that is supported by the peaks in the surface roughness. This is known as the Cassie–Baxter state (Cassie and Baxter 1944). The presence of the air– water interface increases the contact angle and reduces the contact angle hysteresis (Quere 2008). As a result, droplets have been shown to move very easily on superhydrophobic surfaces because the droplet pinning force is known to be proportional to the contact angle hysteresis (Hammer et al. D. Song School of Marine Engineering, Northwestern Polytechnical University, 127 Youyi Xilu, Xi’an 710072, Shaanxi, People’s Republic of China D. Song R. J. Daniello J. P. Rothstein (&) Department of Mechanical and Industrial Engineering, University of Massachusetts, Amherst, 160 Governors Drive, Amherst, MA 01003-2210, USA e-mail: [email protected] 123 Exp Fluids (2014) 55:1783 DOI 10.1007/s00348-014-1783-8

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RESEARCH ARTICLE

Drag reduction using superhydrophobic sanded Teflon surfaces

Dong Song • Robert J. Daniello • Jonathan P. Rothstein

Received: 8 January 2014 / Revised: 13 June 2014 / Accepted: 2 July 2014

� Springer-Verlag Berlin Heidelberg 2014

Abstract In this paper, a series of experiments are pre-

sented which demonstrate drag reduction for the laminar

flow of water through microchannels using superhydro-

phobic surfaces with random surface microstructure. These

superhydrophobic surfaces were fabricated with a simple,

inexpensive technique of sanding polytetrafluoroethylene

(PTFE) with sandpaper having grit sizes between 120- and

600-grit. A microfluidic device was used to measure the

pressure drop as a function of the flow rate to determine the

drag reduction and slip length of each surface. A maximum

pressure drop reduction of 27 % and a maximum apparent

slip length of b = 20 lm were obtained for the superhy-

drophobic surfaces created by sanding PTFE with a

240-grit sandpaper. The pressure drop reduction and slip

length were found to increase with increasing mean particle

size of the sandpaper up to 240-grit. Beyond that grit size,

increasing the pitch of the surface roughness was found to

cause the interface to transition from the Cassie–Baxter

state to the Wenzel state. This transition was observed both

as an increase in the contact angle hysteresis and simulta-

neously as a reduction in the pressure drop reduction. For

these randomly rough surfaces, a correlation between the

slip length and the contact angle hysteresis was found. The

surfaces with the smallest contact angle hysteresis were

found to also have the largest slip length. Finally, a number

of sanding protocols were tested by sanding preferentially

along the flow direction, across the flow direction and with

a random circular pattern. In all cases, sanding in the flow

direction was found to produce the largest pressure drop

reduction.

1 Introduction

Superhydrophobic surfaces can be found in nature in a

number of plants and insects around the world (Barthlott

and Neinhuis 1997; Hebets and Chapman 2000; Hu et al.

2003; Nørgaard and Dacke 2010; Shirtcliffe et al. 2006a, b;

Zheng et al. 2007). Superhydrophobic surfaces have large

advancing contact angles, hA [ 150�, and little difference

between their advancing and receding contact angles,

hA & hR. The extreme water repellency of naturally

occurring superhydrophobic surfaces gives the lotus leaves

and other plants their self-cleaning properties (Barthlott

and Neinhuis 1997), allows water striders to walk on water

(Hu et al. 2003) and makes it possible for insects and

spiders to breath under water (Hebets and Chapman 2000;

Shirtcliffe et al. 2006a). There are two important factors

needed to produce superhydrophobic surfaces: low surface

energy and micro/nanoroughness. The combination of

surface roughness and hydrophobicity can trap an air layer

in the depressions on the surface and result in the formation

of an air–water interface that is supported by the peaks in

the surface roughness. This is known as the Cassie–Baxter

state (Cassie and Baxter 1944). The presence of the air–

water interface increases the contact angle and reduces the

contact angle hysteresis (Quere 2008). As a result, droplets

have been shown to move very easily on superhydrophobic

surfaces because the droplet pinning force is known to be

proportional to the contact angle hysteresis (Hammer et al.

D. Song

School of Marine Engineering, Northwestern Polytechnical

University, 127 Youyi Xilu, Xi’an 710072, Shaanxi,

People’s Republic of China

D. Song � R. J. Daniello � J. P. Rothstein (&)

Department of Mechanical and Industrial Engineering,

University of Massachusetts, Amherst, 160 Governors Drive,

Amherst, MA 01003-2210, USA

e-mail: [email protected]

123

Exp Fluids (2014) 55:1783

DOI 10.1007/s00348-014-1783-8

2010; Reyssat et al. 2006; Richard and Quere 2000; Nils-

son and Rothstein 2011, 2012). The presence of the air–

water interface has also been found to change the boundary

condition on a superhydrophobic surface from the classic

no-slip boundary condition to a partial slip boundary con-

dition resulting in substantial drag reduction in both lami-

nar and turbulent flows (Rothstein 2010).

Over the past decade, there have been a large number of

studies investigating the drag reduction properties of su-

perhydrophobic surfaces containing both regular and

irregular patterns of micron and nanometer-sized surface

roughness (Bocquet and Barrat 2007; Choi et al. 2006;

McHale et al. 2009; Ou et al. 2004; Ou and Rothstein 2005;

Rothstein 2010; Tretheway and Meinhart 2002, 2004;

Truesdell et al. 2006). Ou et al. (2004, 2007), and Ou and

Rothstein (2005) were one of the first to demonstrate that

superhydrophobic surfaces could produce drag reduction.

Their measurements showed pressure drop reductions of up

to 40 % in laminar flows using superhydrophobic surfaces

consisting of regular arrays of posts and ridges fabricated

through photolithography. In addition, they used micro-

particle image velocimetry (l-PIV) to measure the velocity

profile above a superhydrophobic surface and demonstrated

peak slip velocities along the air–water interface as large as

60 % of the average velocity. The numerous papers that

followed focused primarily on superhydrophobic surfaces

with regularly patterned geometries with the goals of

understanding how the microstructure pattern and size

affect slip (Ybert et al. 2007) and maximizing drag

reduction (Lee and Kim 2009) for superhydrophobic sur-

faces (Rothstein 2010).

It is important to note, however, if we hope to establish

wide, commercial application of superhydrophobic sur-

faces that more drag reduction studies need to be per-

formed on substrates with random microstructures

(Bocquet and Lauga 2013). Such surfaces are often easier

and less costly to fabricate than precisely patterned sur-

faces and they have the potential to be applied over large

surface areas making them ideal for application on ships. A

number of theoretical works including Sbragaglia and

Prosperettii (2007) and Feuillebois et al (2009) have

demonstrated that randomly rough surfaces can produce

significant drag reduction. Additionally, over the last few

years, there have been a number of experiments performed

on randomly rough superhydrophobic surfaces. Gogte et al.

(2005) investigated drag reduction on a hydrofoil coated

with a hydrophobic sandpaper. Their results showed up to

20 % drag reduction. McHale et al. (2009) coated a series

of spheres with a sharp, hydrophobic sand and found as

much as a 30 % reduction in the drag coefficient. More

recently, Srinivasan et al. (2013) spray coated a number of

different surfaces with a mixture of PMMA and fluorodecyl

POSS producing a superhydrophobic surface decorated

with a random array of hydrophobic 20 lm beads. Mea-

surements using a parallel plate rheometer showed slip

lengths of more than 30 lm on flat substrates and much

larger slip lengths when theses coatings were applied to a

series of woven metal meshes.

In this work, an easy, inexpensive method involving the

sanding of polytetrafluoroethylene (PTFE) with different

grit sandpapers was employed to make randomly structured

superhydrophobic surfaces with a wide range of wetting

properties (Nilsson et al. 2010). The pressure drop across a

microfluidic rectangular microchannel was then used to

experimentally characterize the drag reduction ability of

these superhydrophobic sanded Teflon surfaces.

2 Experimental setup

Many methods have been used to make high-quality su-

perhydrophobic surfaces with large contact angles, little

hysteresis and the ability to maintain an air–water interface

under reasonable large static pressures. These techniques

include among others: photolithography (Oner and

McCarthy 2000; Ou et al. 2004), phase separation (Li et al.

2006; Yamanaka et al. 2006), chemical vapor deposition

method (Liu et al. 2004; Yao et al. 2011), wet-chemical

method (Lau et al. 2003), electrospinning (Singh et al.

2005), self-assembly (Lee et al. 2009; Pietsch et al. 2009)

and coated porous aluminum oxide (Jin et al. 2005) among

others. Most of these methods are complicated, require

costly clean room facilities or expensive equipment and are

challenging to apply on large area. In this paper, we use an

inexpensive, uncomplicated technique to fabricate super-

hydrophobic surfaces developed by Nilsson et al. (2010).

Specifically, smooth polytetrafluoroethylene (PTFE),

commercially known as Teflon, is sanded using various

grits of sandpaper to impart random surface roughness to a

low-energy surface.

To fabricate our superhydrophobic surfaces, a series of

Teflon sheets were first glued onto glass slides make sure the

surface was flat and smooth. The Teflon samples were then

sanded by hand for a minimum of 2 min using sandpaper

grits of 120, 180, 240, 360 and 600. Several Teflon surfaces

sanded with each sandpaper grit were fabricated and inde-

pendently tested so that the variation associated with pre-

paring the surfaces by hand could be accounted for in the

statistical experimental uncertainty. Three distinct sanding

protocols were used to illustrate the importance of sanding

direction. These protocols involved sanding the Teflon back

and forth only in the flow direction, sanding the Teflon only

in the cross-flow direction and finally randomly sanding the

Teflon with a circular motion. After sanding, the loose Teflon

particles were removed from the surface with a gentle stream

of compressed air and rinsed with water.

1783 Page 2 of 8 Exp Fluids (2014) 55:1783

123

In Fig. 1, the scanning electron microscopy (SEM)

images of smooth and sanded Teflon surfaces are pre-

sented. Nilsson et al. (2010) demonstrated that by sanding

Teflon with a series of different grit sizes, surfaces with a

wide range of hydrophobic properties could be developed.

This includes ideal superhydrophobic surfaces with high

contact angle and low hysteresis for sandpaper grits

between 240 and 320 as well as a range of moderate to high

contact angle and contact angle hysteresis surfaces sanded

with larger or smaller grit sandpapers. Although measure-

ments of contact angle and contact angle hysteresis can

indicate whether a droplet on a surface is in the Cassie–

Baxter state, there is no known direct relationship between

drag reduction and contact angle hysteresis on superhy-

drophobic surfaces (Voronov et al. 2008). By using a wide

range of sandpaper grits to impart different random surface

roughness to Teflon, in this paper, we will test whether it is

possible to correlate contact angle hysteresis to slip length

for randomly rough surfaces.

To test the drag reducing ability of each surface, a

microfluidic device with a rectangular microchannel was

developed to measure the pressure drop across the smooth

and sanded Teflon surfaces. A schematic of the micro-

channel along with an image of the microfluidic device is

shown in Fig. 2. The device contains three parts: the san-

ded/smooth Teflon test surface epoxied to a glass micro-

scope slide; an upper cover made of PDMS bonded to an

acrylic cover slip with a 137-lm-deep, 3.4-mm-wide and

60-mm-long rectangular microchannel formed in the

PDMS; and several clips used to clamp the microfluidic

device together under uniform, consistent pressure. The

acrylic top cover slip functions only as a stiffener to con-

strain the PDMS and distribute the clamping force of the

clips that hold the top and bottom sections of the device

together. The low modulus (*1.8 MPa) of the PDMS

allows the device to make a seal that was experimentally

verified to be leak free with the lower surface but also

necessitates relatively light, even and consistent clamping

force. This is because under pressure the low modulus of

the PDMS means that the microchannel will deform

slightly. The 137 mm depth quoted for the microchannel

was measured after the channel was sealed using micros-

copy and later confirmed by fitting the pressure drop

measurement of the smooth, no-slip Teflon substrate to the

expected pressure drop for Poiseuille flow through a rect-

angular channel (White 1991). Note, however, that at an

aspect ratio of 25:1, the end effects are essentially negli-

gible and the channel can be assumed to be equivalent to

two infinite parallel plates without introducing significant

error.

The microchannel was fabricated from Sylgard 184

PDMS (Dow Corning) using standard soft lithography

techniques. The flow inlet and outlet were located at the far

ends of the channel, spaced 60 mm apart. The pressure

ports were installed 45 mm apart. The test fluid was

ultrapure water driven by a syringe pump (KD Scientific

Model 100) at a constant flow rate. Pressure drop was

measured by recording the height difference between two

manometer columns attached to the pressure ports. The

resolution of the pressure drop measurements was 0.5 mm

of water or equivalently 5 Pa. Experiments were run over a

wide range of flow rates for a series of smooth/sanded

Teflon surfaces all well below Reynolds numbers of

Fig. 1 SEM images of a series of Teflon surfaces sanded with

sandpapers of various grit designations. The images include a smooth

Teflon, b Teflon sanded with 600-grit, c Teflon sanded with 320-grit and

d Teflon sanded with 240-grit. The SEM images have been reproduced

with permission from Nilsson et al. (2010)

Fig. 2 a A schematic diagram of the PDMS microfluidic devices

used in these experiments with the appropriate dimensions and b an

image of the actual device

Exp Fluids (2014) 55:1783 Page 3 of 8 1783

123

Re � 100 to ensure laminar flows. In all cases, the top

wall was smooth PDMS and was assumed to be no-slip.

3 Results and discussion

Five different grits of sandpaper (120, 180, 240, 360 and

600-grit) were used to roughen an initially smooth Teflon

surfaces. In the initial experiments, the Teflon was sanded

with a bias in the flow direction in an attempt to introduce

scratches or grooves along the length of the microchannel

in order to maximize the drag reduction. To obtain a

baseline for comparing the superhydrophobic surfaces, the

pressure drop of smooth Teflon channel flow was measured

for flows with average velocities varying from 24 to

48 mm/s. As seen in Fig. 3, the experimental measure-

ments for flow past a smooth Teflon surface match the

predictions for flow between two infinite no-slip plates.

These measurements gave us confidence in the quality of

our experimental setup and provided a good no-slip base-

line data set to compare against the results of sanded

Teflon. In Fig. 3, the pressure drop for a series of sanded

Teflon surfaces in the microchannel is also presented as a

function of flow rate. As seen in Fig. 3, the pressure drop of

measured for each of the superhydrophobic sanded Teflon

surfaces was found to be smaller than that of the smooth

Teflon. The percentage of pressure drop reduction for each

of the sanded Teflon surface was found to be independent

of flow rate but strongly dependent on the grit designation.

The maximum pressure drop reduction of 27 % was

measured for the Teflon surface sanded with the 240-grit

sandpaper.

To observe the trends more closely, the data in Fig. 3

were recast as a pressure drop reduction in Fig. 4. Here, the

average pressure drop reduction is presented with error bars

superimposed over the data indicating the 95 % confidence

interval of the average. Each data point represents a min-

imum of five measurements with the microfluidic device

broken down and reassembled for each experiment to

insure repeatability and robustness of the measurement. As

seen in Fig. 4a, the average pressure drop reduction was

found to be very sensitive to the grit designation of the

sandpaper used to create the superhydrophobic surfaces. As

the grit designation was decreased from 600- to 240-grit,

the mean particle size of the sandpaper increased from 25

to 58 lm. Over that range, the RMS roughness on the

Teflon surface increases from 7.6 to 13.7 lm (Nilsson et al.

20 25 30 35 40 45 50400

600

800

1000

1200

1400

Pres

sure

Dro

p [P

a]

Flow Velocity [mm/s]

Fig. 3 Measurement of pressure drop as a function of flow velocity

for a series of smooth and sanded Teflon in microchannel. The

experiment data include both (times) smooth Teflon surface as well as

Teflon surfaces sanded with a series of different sandpaper with grit

designation of (filled diamond) 120-grit, (triangle) 180-grit, (filled

square) 240-grit, (filled circle) 320-grit and (inverted triangle)

600-grit. Superimposed over the data is the theoretical prediction

for flow through the microchannel assuming the walls are no-slip (-)

0

5

10

15

20

25

30

Pres

sure

Dro

p R

educ

tion

[%]

Grit Designation of Sandpaper

(a)

120 180 240 320 600

120 180 240 320 6000

10

20

30

40

50

60

70

Con

tact

Ang

le H

yste

resi

s (

AR)

[deg

]

Grit Designation of Sandpaper

(b)

Fig. 4 Pressure drop reduction (a) and contact angle hysteresis (b) as

a function of the grit designation used to sand the Teflon surfaces. The

contact angel hysteresis in b has been reproduced with permission

from Nilsson et al. (2010)

1783 Page 4 of 8 Exp Fluids (2014) 55:1783

123

2010) and the pressure drop reduction increased from 5 %

to a maximum of about 27 %. As the grit designation

decreased further to 180-grit, the mean particle size of the

sandpaper increased to about 80 lm, and the pressure drop

reduction was found to decrease sharply to only about

12 %. At 120-grit, the pressure drop reduction falls off

even further.

As seen in Fig. 1, the spacing between raised Teflon

features on the sanded surface scales with the particle size

of the sandpaper. As a result when the grit designation is

240-grit or larger, the structures produced by sanding are

separated by gaps small enough to support an air–water

interface on the superhydrophobic surface without col-

lapsing into the features. In the Cassie–Baxter state, a

maximum static pressure exists that can be supported by

the air–water interface before it collapses into the Wenzel

state. That pressure, pwater - pair = -2c cos hA/w,

decreases with increasing feature spacing, w. For a static

pressure of 3,600 Pa, which is typical in our experiments, a

spacing at w = 80 lm can be supported. This corresponds

with the average particle size on the 180-grit sandpaper.

For these coarser, smaller grits, many of the larger scrat-

ches introduced into the Teflon surface will not be able to

support an air–water interface and the effectiveness for

drag reduction should decrease. As the grit designation

increases, the particles on the sandpaper become smaller,

and as seen in Fig. 1, the spacing between surface struc-

tures decreases along with their periodicity. For superhy-

drophobic surfaces with same fraction of shear-free air–

water interface, increasing the microstructures spacing has

been shown both experimentally and theoretically to

increase the maximum of the slip velocity (Ou and Roth-

stein 2005) and the slip length (Ybert et al. 2007). Ybert

et al. (2007) showed that for a regular array of posts, which

one can argue most closely resembles our randomly rough

surface, that the slip length is proportional to the spacing

between features, b / L=ffiffiffiffiffi

/s

p

. Here, /s = d2/L2 is the

solid fraction of the superhydrophobic surface, d is the

diameter of the posts and L = w ? a is the pitch of the

surface roughness. The slip length is defined in this context

using Navier’s (1823) partial slip boundary condition, us ¼b ou=oyj j: Here, us is the slip velocity at the wall and qu/

qy is the velocity gradient at the wall. Thus, larger grit

designations which lead to smaller spaced microstructures,

as seen in Fig. 1, are expected to produce less pressure

drop reduction.

The data in Fig. 4a suggest at least a partial transition

from the Cassie–Baxter state to the Wenzel state for grit

designations less than 240-grit. This observation is further

reinforced by the trends in contact angle hysteresis for

sanded Teflon surface made by Nilsson et al. (2010). In

Nilsson et al. (2010), the advancing and receding contact

angles were measured from digitized images of small

droplets as water was slowly added and withdrawn. Their

contact angle hysteresis data are reproduced in Fig. 4b as a

function of grit designation. An inspection of the data

reveals that the drag reduction and contact angle hysteresis

data in Fig. 4a, b are strongly correlated although no clear

scaling relationship can be extracted from the data. As the

grit decreased from 600 to 240, the contact angle hysteresis

is minimized just as the drag reduction is maximized. This

observation is intuitive as a number of studies have shown

that, for a superhydrophobic surface with fixed size mi-

croposts, the contact angle hysteresis decreases as the pitch

between the microposts is increased (Oner and McCarthy

2000). Xu and Choi (2012) recently demonstrated that the

receding contact angle was not solely dependent on peri-

odicity of the surface roughness, but also on feature size.

They showed that as the contact line receded across a su-

perhydrophobic surface consisting of circular posts that the

force needed to de-pin the contact line from the top of the

posts depended on the ratio of the of the posts’ wetted

perimeter to their pitch, FD� d=L ¼ffiffiffiffiffi

/s

p

. Since, as

described above, the slip length is also known to be

dependent on the solid fraction of the surface, b / L=ffiffiffiffiffi

/s

p

,

these observations for grit designations between 600 and

240-grit make sense if increasing the sandpaper particle

size results in both an increase in pitch, L, as expected, and

simultaneously a decrease in the solid surface fraction, /s,

see Fig. 1. For the Teflon surfaces sanded with sandpaper

below a 240-grit designation, Nilsson et al. (2010) argued,

as we have here, that the increase in contact angel hys-

teresis was the result of a gradual transition from a surface

fully in the Cassie–Baxter state to a surface in the Wenzel

state. For laminar flow across superhydrophobic sanded

Teflon surfaces, it thus appears that one can predict the

surfaces that will produce a maximum drag reduction

simply by finding the surface which minimizes the contact

angle hysteresis.

In order to test the sensitivity of the drag reduction

based on sanding protocol, two other sanding procedures,

circular sanding and cross-sanding, were used for the 240-

and 320-grit sandpapers. In Fig. 5, the results of the pres-

sure measurements are presented as a function of sanding

protocol. Sanding primarily in the flow direction was

consistently found to be the best method to reduce drag and

maximize pressure drop reduction as a large fraction of the

scratches introduced into the Teflon surface are oriented in

the flow direction. Sanding in cross-flow direction was

found to be least effective at reducing drag. In fact, the

cross-flow sanding protocol produces approximately half

the pressure drop reduction of sanding in the flow direction.

This observation agrees well with the experimental and

theoretical work for flow over superhydrophobic surfaces

Exp Fluids (2014) 55:1783 Page 5 of 8 1783

123

containing a regular array of ridges. In those cases, flow

across the ridge was found to give only half the pressure

drop reduction of flow along the ridges (Harting et al. 2010;

Lauga and Stone 2003). The circular sanding protocol

resulted in pressure drop reduction between the other two

cases. Thus, using different sanding protocols, we can

optimize the superhydrophobic surfaces structures and

maximize drag reduction, making this technique more

flexible for engineering application.

Finally, when discussing drag reduction data, it is often

important to present the data as a slip length rather than a

pressure drop reduction because slip length is independent

of channel geometry and flow velocity. For fluid flow

between two infinite parallel plates separated by a distance

H where one wall has a slip length b, the volume flow rate

per unit length, q ¼ H3

4l �dp

dx

� �

13þ b

bþH

h i

; can be expressed

in terms of the channel geometry, the slip length, the

pressure gradient, dp/dx, and the fluid viscosity, l. For a

given fluid and flow rate, the pressure gradient can thus be

significantly affected by slip when the slip length is com-

parable to the height of channel. Using this equation, we

can calculate the slip length directly from the pressure drop

measurements. The pressure drop reduction data from

Fig. 4 is plotted as slip length in Fig. 6 as a function of

mean grit size. As seen in Fig. 6, the slip length was found

to increase approximate linearly with grit size up to a

sandpaper particle size of 60 lm which corresponds to the

240-grit sandpaper. For the 240-grit sandpaper, a maximum

slip length of approximately b = 20 lm was measured.

For a regular array of posts with a small solid surface

fraction, /s, Ybert et al. (2007) showed that

b=L ¼ 0:324=ffiffiffiffiffi

/s

p

� 0:44. Assuming the pitch of the sur-

face features is equal to the average sandpaper particle size,

the approximate solid surface fraction for the 240-grit

sanded Teflon surface can be calculated to be /s & 0.18

which means the superhydrophobic surface created is more

than 80 % air. Alternately, if one assumes the surface is

covered with ridges instead of posts, a slightly larger value

of /s & 0.23 can be calculated for the Teflon surface

sanded with the 240-grit sandpaper. Finally, we note that a

similar value of /s & 0.20 was calculated for the Teflon

surface sanded with the 320-grit sandpaper. Given that the

320-grit sandpaper produces a surface with smaller

roughness spacing, but similar interface coverage, it can be

utilized in flows where the pressure might be too large for

the 240-grit surface to maintain an air–water interface.

4 Conclusion

In this paper, a series of experiments were performed

which demonstrate drag reduction for the laminar flow of

water through microchannels using superhydrophobic sur-

faces fabricated with random surface microstructure. These

superhydrophobic surfaces were fabricated using the sim-

ple, inexpensive technique first developed by Nilsson et al.

(2010) which involves sanding Teflon with various grits of

sandpaper. Teflon surfaces sanded with grit sizes between

120- and 600-grit were studied. A microfluidic device was

used to measure the pressure drop as a function of the flow

Flow Direction Circular Cross Flow Direction5

10

15

20

25

30Pr

essu

re D

rop

Red

uctio

n [%

]

Sanding Protocol

Fig. 5 Pressure drop reduction as a function of sanding protocol. For

each sanding style, flow direction (filled symbols), cross-flow

direction (crossed symbols) and circular sanding protocols (open

symbols) were used with sandpapers with grit designations of (filled

square, open square, crossed square) 240-grit and (filled circle, open

circle, crossed circle) 320-grit

10 20 30 40 50 60 70 80 90 100 110 120 130 1400

5

10

15

20

Slip

Len

gth,

b [

m]

Mean Particle Diameter of Sandpaper [ m]µ

µ

Fig. 6 Slip length, b, measured for a series of sanded Teflon surfaces

as a function of the mean particle diameter of the sandpaper used. The

data include Teflon sanded in the flow direction with (diamond)

120-grit, (triangle) 180-grit, (filled square) 240-grit, (filled circle)

320-grit and (inverted triangle) 600-grit sandpaper; Teflon sanded

with a random circular pattern with (open square) 240-grit and (open

circle) 320-grit sandpaper; and Teflon sanded in the cross-flow

direction with (crossed square) 240-grit and (crossed circle) 320-grit

sandpaper

1783 Page 6 of 8 Exp Fluids (2014) 55:1783

123

rate to determine the drag reduction and slip length of each

surface. A maximum pressure drop reduction of 27 % and

a maximum apparent slip length of b = 20 lm were

obtained for the superhydrophobic surfaces created by

sanding PTFE with a 240-grit sandpaper. The pressure drop

reduction and slip length were found to increase with

increasing grit size up to 240-grit. Beyond that grit size,

increasing periodicity of the surface roughness was found

to cause the interface to transition from the Cassie–Baxter

state to the Wenzel state. This transition was observed both

as an increase in the contact angle hysteresis and simulta-

neously as a reduction in the pressure drop reduction. For

these randomly rough surfaces, a correlation between the

slip length and the contact angle hysteresis was found. The

surfaces with the smallest contact angle hysteresis were

found to also have the largest slip length. Finally, a number

of sanding protocols were tested by sanding preferentially

along the flow direction, across the flow direction and with

a random circular pattern. In all cases, sanding in the flow

direction was found to produce the largest pressure drop

reduction. This work demonstrates that the mechanical

abrasion of hydrophobic surfaces to make them superhy-

drophobic has the potential to establish wide, commercial

application of superhydrophobic surfaces. When compared

to precisely patterned surfaces, they are easier and less

costly to fabricate giving them the potential to be applied

over large surface areas and making them ideal for large-

scale application such as on ocean going vessels.

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