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Descriptive Inorganic Chemistry Chem 24112-1 M, W, F
Bill Vining232 Physical Sciences [email protected]
Inorganic Chemistry
• One of the three descriptive chemistries:– Organic Chemistry– Biochemistry– Inorganic Chemistry
Theoretical and Practical Chemistries: Physical Chemistry Analytical Chemistry
Inorganic Chemistry: Chemistry for the rest of the elements.
First Assignment:
Find the best periodictable website. Bring URL and list of why youthink it is the best (andany drawbacks).
Hand in paper at startof class Friday.
Chem 241 Topics• Origin of the Elements• Nuclear Chemistry
– Stability– Practical Nuclear Chemistry
• Chemical Formation of the Earth and Ore• Obtaining the Elements: Extraction
– Methods for Metals and Nonmetals• Properties of the Main Group Elements
– The elements themselves– Oxides, halides of the elements
• Bonding and Properties of Metals
Chem 241 Topics• Chemistry in Water
– Charge Density– Enthalpy, Entropy and Solubility– Acid-Base Properties
• Atmospheric Chemistry– Global Warming– Acid Rain– Ozone
• Coordination Chemistry– Complex Types– Bonding– Symmetry in Chemistry– Spectroscopy
Official StuffCourse Website: http://employees.oneonta.edu/viningwj/chem241/
Text: Online pdf
http://employees.oneonta.edu/viningwj/chem241/text/
Grading:
Three exams 300 pointsHomework/In-Class Quizes 100 pointsPoster Session 50 points
Homework: OWL Starting Next Week
http://owl.oit.umass.eduChoose Chemistry General, UMass Amherst, then choose SUNY Oneonta, Chem 241Login: SUCO + your email up to the @ sign (mine would be SUCOviningwj)Password: your A00 number
First Topic
Where do all these elements come from?
How are they made?
Are they made?
Our Guide:
What aspects of this should we explain?
What will our explanations depend on?
Thermodynamics: relative stability
Kinetics: rate and mechanism
General Decrease in Abundance with Atomic Number
Even > Odd
Peak at Fe
Peak at Pb
Trough at Be
Missing Tc and Pm and Above N = 83
Nuclear equations
Nucleosynthesis of the Elements
Hydrogen Burning
1H + 1H 2H + e+ + ve
2H + 1H 3He +
3He + 3He 4He +21H
Why does this happen only in stars?
41H 4He + 2e+ + 2ve
Helium Burning
4He +4He 8Be8Be + 4He 12C* 12C +
3 4He 12C +
Is this easier or harder than hydrogenburning?
Carbon Burning, etc.
12C + 4He 16O + 16O + 4He 20Ne + 20Ne + 4He 24Mg + 12C + 12C 24Mg + 12C + 12C 23Na + 1H12C + 12C 20Ne + 4He
Go back to initial Questions. Can weanswer any?
The -Process
20Ne + 16O + 4He
20Ne + 4He 24Mg +
2 20Ne 16O + 24Mg +
40Ca + 4He 44Ti* + 44Ti* + e- 44Sc* + v+
44Sc* 44Ca + + + v+
44Ca + 4He 48Ti +
Neutron Capture-Beta Decay
65 6629 29
66 6629 30
66 6730 30
67 6830 30
68 6930 30
69 6930 31
69 7031 31
70 7031 32
Cu n Cu
Cu Zn
Zn n Zn
Zn n Zn
Zn n Zn
Zn Ga
Ga n Ga
Ga Ge
B
B
B
r- vs. s-neutron capture
What nuclei exist?