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Page 1: Contents

Contents lists available at SciVerse ScienceDirect

Journal of Organometallic Chemistry

journal homepage: www.elsevier .com/locate/ jorganchem

Volume 732, 15 May 2013



Veikko Uahengo, Nana Zhou, Bi Xiong,Ping Cai, Kai Hu, Gongzhen Cheng

J. Organomet. Chem. 732 (2013) 102

Synthesis and characterization of a newdinuclear platinum(II) alkynyl complex witha ferrocene bridge and its interaction withsilver ion

Elsevier B.V.http://dx.doi.org/10.1016/S0022-328X(13)00227-1

A new dinuclear alkynyl platinum(II) com-plex with a ferrocene (Fc) bridge (Pt(II)-Fc-Pt(II)), Sensor 1, and it’s chemosensing ofsilver Ion were reported.

Regular Papers

Lei Xue, Zhizhou Yang, Dengxu Wang,Yike Wang, Jie Zhang, Shengyu Feng

J. Organomet. Chem. 732 (2013) 1

Synthesis and characterization of silicon-containing hyperbranched polymers viathiol-ene click reaction

The novel silicon-containing hyperbranchedpolymers were prepared via step-growththiol-ene reaction under mild condition.The degree of branch of the resulting poly-mers for AB2 and AB3 systems was 0.60 and0.22, respectively. The refractive indexes ofP1 and P2 were 1.5269 and 1.5386,respectively.

Eliza Ja�skowska, Iwona Justyniak,Michał K. Cyra�nski,Agnieszka Adamczyk-Wo�zniak,Andrzej Sporzy�nski,Ewa Zygadło-Monikowska,Wanda Ziemkowska

J. Organomet. Chem. 732 (2013) 8

Benzoxaborolate ligands in group 13 metalcomplexes

Benzoxaborolates [R2MOB(o-CH2O)(C6H4)]2[R ¼ tBu, M ¼ Al (2), R ¼ Me, M ¼ Ga (3),R¼ tBu, M¼Ga (4), R¼ tBu, M¼ In (5)] weresynthesized in reactions of 1,3-dihydro-1-hydroxy-2,1-benzoxaborole with group 13metal trialkyls.

Page 2: Contents


Stefania R. Cicco, Carmela Martinelli,Vita Pinto, Francesco Naso,Gianluca M. Farinola

J. Organomet. Chem. 732 (2013) 15

Oxidative cross-coupling of vinylsilanes inwater

The first investigation of palladium-catalyzed oxidative cross-coupling reactionof vinylsilanes bearing substituents withcomplementary electronic effects is repor-ted. Besides being the first example on oxi-dative cross-couplingof vinylic organosiliconreagents, the protocol is a convenient accessto pushepull butadienes.

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Serpil Demir, Murat Yigit, Ismail Özdemir

J. Organomet. Chem. 732 (2013) 21

Synthesis of rhodium complexes derivedfrom benzimidazolin-2-ylidene ligands andfirst used for the addition of arylboron tobenzonitriles

Benzimidazolium salts and their new rho-dium complexes ([Rh(COD)(NHC)Cl]) weresynthesized and characterized. The additionof sodium tetraphenylborate to nitriles inthe presence of a catalytic amount of a rho-dium NHC complexes was examined. Cor-responding carbonyl compounds wereobtained in good yields.

Luciano Canovese, Fabiano Visentin,Carlo Levi, Claudio Santo,Valerio Bertolasi

J. Organomet. Chem. 732 (2013) 27

Synthesis of novel palladium allyl complexesbearing heteroditopic NHCeS ligands. Ki-netic study on the carbene exchange be-tween bis-carbene palladium allyl complexes

Novel palladium allyl complexes withNHCeS ligands were synthesized. Prepara-tion of mixed bis-carbene complexes bear-ing two different carbenes simultaneouslycoordinated to the palladium center yieldthe formation of an equilibrium mixture ofthe two homoleptic and the mixed bis-carbene species. The reaction rates weremeasured and a mechanistic hypothesisadvanced.

Guillermo Ahumada, Paul Hamon,Vincent Dorcet, Thierry Roisnel,Carolina Manzur, David Carrillo,Juan Pablo Soto, Jean-René Hamon

J. Organomet. Chem. 732 (2013) 40

Two substrates, three products: Reactionsbetween ferrocene-carboxaldehyde anddioxaphospholene, characterization andcrystal structures of oxygenated C3- andC4-chain-containing ferrocenes

Depending on the experimental conditionsused, the reaction between biacetyl trime-thylphosphite adduct and ferrocenecarbox-aldehyde gives rise to either 1-ferrocenyl-1,2-propanedione, or 4-methoxy-4-ferrocenyl-3-hydroxy-3-methyl-2-butanone (illustrated)as a single diastereoisomer, or 1-(3-oxo-2-methylbut-1-enyl)ferrocene; this behaviorcould originate from a common charge sep-arated state with a carbonium ion stabilizedby the ferrocene unit.

Page 3: Contents

Contents v

Ale�s R�u�zi�cka, Zde�nka Pad�elková,Petr �Svec, Vladimír Pejchal,Lenka �Ceslová, Jaroslav Hole�cek

J. Organomet. Chem. 732 (2013) 47

Quest for triorganotin(IV) compoundscontaining three C,N- and N,C,N-chelatingligands

Organotin(IV) compounds of general for-mula L3SnR [where i) L is 2-(N,N-dimethy-laminomethyl)phenyl- or 2,6-bis-(N,N-dimethylaminomethyl)phenyl- and R isorganic, hydroxo or a halide group] weresynthesized by various ways. Compoundswere characterized by multinuclear NMRspectroscopy and by the X-ray diffractionanalysis.

Miroslav Kavala, Alison Hawkins,Peter Szolcsányi

J. Organomet. Chem. 732 (2013) 58

Syntheses and properties of cyclosilazanesand cyclocarbosilazanes

The review evaluates known syntheticmethods of cyclo(carbo)silazanes and sum-marises important physico-chemical prop-erties. It is compiled as a guide for thetargeted preparation of various classes ofrespective compounds. The review also in-cludes useful transformations of N-unsub-stituted cyclic derivatives and data onhydrolytic stability of cyclo(carbo)silazanes.

Xiaolin Hu, Chengrong Lu, Bing Wu,Hao Ding, Bei Zhao, Yingming Yao,Qi Shen

J. Organomet. Chem. 732 (2013) 92

Synthesis and structural diversity of lan-thanide amidate complexes and their cata-lytic activities for the ring-openingpolymerization of rac-lactide

Both anionic and neutral lanthanide com-plexes stabilized by amidate ligand can beprepared through protonolysis reactions. Inthe neutral lanthanide amidate complexes,an unprecedented NeHeN bond betweentwo of the amidate ligands is formed, mak-ing it the most notable difference fromnormal neutral analogs.

Dibakar Sardar, Papia Datta, Rajat Saha,Pallepogu Raghavaiah,Chittaranjan Sinha

J. Organomet. Chem. 732 (2013) 109

The CeH activation of pendant naphthylgroup of 1-alkyl-2-(naphthyl-a-azo)imida-zole by rhodium(III). Spectral, structuralcharacterization and, DFT computation

Rh(III) complexes of 1-alkyl-2-(naphthyl-a-azo)imidazole (a-NaiR) present in coordi-nation and cyclometallation states. Thestructures are described by spectroscopic(IR, UVeVis, NMR, Mass) and single crystalX-ray diffraction studies. Density functionaltheory calculation has also been performedto rationalize the electronic structures andtheir spectral properties.

Page 4: Contents



Yuri F. Oprunenko, Igor P. Gloriozov

J. Organomet. Chem. 732 (2013) 116

A study of dynamic behavior of transitionmetal complexes with fullerene C60 usingdensity function theory

Dynamic behavior of [M(NO)Hn(PPh3)2(h -C60)], M ¼ Co, Rh, Ru,1e3was modelized byDFT. Except organometallic group rotationaround the [6, 6] fusion double bond withthe barrier DG ¼ 8.5, 10.5, 15.1 kcal/mol,h2,h2-haptotropic rearrangements over thewhole surface of C60 with DG ¼ 12.2, 11.8,18.6 kcal/mol, respectively were calculated.

Vijaylakshmi Tirkey, Sasmita Mishra,Hirak R. Dash, Surajit Das,Bibhukalyan Prasad Nayak,Shaikh M. Mobin, Saurav Chatterjee

J. Organomet. Chem. 732 (2013) 122

Synthesis, characterization and antibacterialstudies of ferrocenyl and cymantrenylhydrazone compounds

Cymantrenyl and ferrocenyl Schiff baseorganometallic compounds have been syn-thesized by the reaction between respectiveacetylated organometallic fragments andhydrazide compounds. Compounds 4, 5, 8and 9 have been structurally characterizedby single crystal X-ray diffraction studies.Antibacterial studies and electrochemicalanalysis were performed for some of theferrocenyl and cymantrenyl compounds.

Bhaskaran Shankar, Palani Elumalai,Firasat Hussain,Malaichamy Sathiyendiran

J. Organomet. Chem. 732 (2013) 130

Synthesis and characterization of tetragonalprismatic p-stacked metallacycles

Neutral p-stacked tetragonal prismatic met-allacycles were prepared from Re2(CO)10,water/biimidazole, and tetratopic nitrogendonors. The p-stacked supramolecularstructure is formed via intermolecular p/pstacking interactions.

Page 5: Contents

Contents vii

K.K. Bhasin, Ekta Arora, Alka S. Grover,Jyoti, H. Singh, S.K. Mehta,Aman K.K. Bhasin, C. Jacob

J. Organomet. Chem. 732 (2013) 137

Synthesis and characterization of new 2-pyrimidyl chalcogen (S, Se, Te) compounds:X-ray crystal structure of bis(4,6-dimethyl-2-pyrimidyl)diselenide and 4,6-dimethyl-2-(phenylselanyl)pyrimidine

New and synthetically important symmetri-cal bis(4,6-dimethyl-2-pyrimidyl)dichalco-genides, unsymmetrical 4,6-dimethyl-2-(arylchalcogenyl)pyrimidines have beensynthesized and characterized with the helpof various spectroscopic techniques andX-ray crystallography.

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