AminesQ 0120 DOI: 10.1002/chin.201151050

Allyl and Benzyl Dance under Basic Conditions. — A new reversible rearrange-ment is observed when Ugi—Smiles adducts are treated with NaH in MeCN. Allyl, pro-pargyl and benzyl groups migrate between two nitrogen atoms what is explained by formation of a highly stabilized aniline anion. — (EL KAIM*, L.; GRIMAUD, L.; PURUMANDLA, S. R.; Synlett 2011, 13, 1816-1820, http://dx.doi.org/10.1055/s-0030-1260964 ; Lab. Chim. Procedes, Ec. Natl. Super. Tech. Avancees, F-75739 Paris, Fr.; Eng.) — Mais

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