Chemical Admixture 2

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    ustry

    Chemical AdmixturesChronology, Classifications and

    Effective Usesby

    T. P. Banerjee

    Head

    Training

    Need for Indian Concrete InCement superplasticizer interaction in concrete is a complex blend ofchemical and physical mechanisms that are interdependent.

    Studies on cement-water reducer interactions in India have beenlimited to the workability evaluation of concretes containing thesechemicals, in specific regions where rapid slump loss has been observed in

    concreting operations. There have not been any investigations tounderstand the physico-chemical nature of this interaction. Thus, theresults from these studies are not broad-based, i.e. they apply to a small

    group of cements and/or chemical admixtures.

    There is a distinct need for the characterization of Indian cement andadmixture properties, in order to understand the nature of theirinteractions. Moreover, the wide range of cements used, varyingtransportation durations and climatic conditions necessitate afundamental study that explains the mechanisms of interaction and helps

    establish methods for identifying incompatibility in practical situations.

    Explosion of Chemical Admixtures in the

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    Twentieth Century with the change in Rheologyof Concrete

    Those that disperse cement particles

    Those that modify the kinetics of hydrationThose that react with the sub-products of hydration reactions

    Those that have only physical action

    Normal Plastic

    Concrete

    Fluid

    Concrete

    Self Consolidated

    Concrete

    Development in AdmixturesConcrete

    performance

    Mega-

    plasticizer

    Super-

    plasticizer

    Plasticizer

    Different types ofVEAs

    Polycarboxylates

    Poly Acrylates

    Naphthalene Sulphonates

    Melamine Sulphonates

    Lignosulphonates

    1950 1970 1980 1990 2000

    Plastic

    concrete

    Rheoplastic

    concrete

    Self compacting

    concrete

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    ADMIXTURES

    As per BIS 9103

    An Admixture is defined as a material other than water,

    aggregates, hydraulic cement and additives like pozzolana

    or slag and fibre reinforcement used as an ingredient of

    concrete or mortar, and added to the batch immediately

    before or during its mixing to modify one or more properties

    of concrete in the plastic or hardened state.

    Advantages of using ChemicalAdmixtures

    The purpose of using chemical admixtures is to modify certain properties ofmortar, concrete or grout.

    In the fresh / plastic state:

    To increase workability without increasing water content

    To reduce water content (5 40%) without changing the workability To accelerate or retard the initial setting time

    To reduce or prevent settlement / to create slight expansion

    To arrest / reduce bleeding

    To reduce segregation & increase cohesiveness

    To improve pumpability

    To reduce slump loss / modify slump retention time

    To improve finishability

    Also to entrain air in concrete for specific purposes

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    Advantages of using Chemical

    Admixtures

    And in the hardened state

    To accelerate rate of strength development at early ages

    To retard or reduce rate of heat evolution during early hydration of

    cement

    To increase physical strengths (compressive, tensile or flexural)

    To increase durability by decrease in permeability

    To reduce expansion due to alkali-aggregate reaction

    To counterfreeze & thawphenomenon

    To reduce scaling caused by deicing salts

    Advantages of using ChemicalAdmixtures

    And in the hardened state (Contd)

    To increase bond to steel reinforcement and between existing and new

    concrete

    To improve impact resistance and abrasion resistance

    To inhibit corrosion of embedded metal

    To produce coloured concrete or mortar

    To reduce drying shrinkage

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    Types of Chemical AdmixturesGeneral Admixtures

    Plasticizer

    Superplasticizer

    Retarder

    Accelerator

    Retarder cum water reducer

    Accelerator cum water reducer

    Air Entraining Compound

    Special Purpose Admixtures

    Corrosion Inhibiting Admixture Anti wash-out Admixture Gas Forming Admixtures

    Grouting Admixtures

    Shotcrete Admixtures Extended et Control Admixtures (Surface Retarders) Pumping Aids / Flocculating Admixtures Bonding Admixtures Colouring Admixtures

    Fungicidal Germicidal Insecticidal Admixtures Permeability Reducing Admixtures

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    ASTM C 494 1999

    AASHTO M 194TYPEA : Water Reducing

    TYPE B : Retarder

    TYPE C : Accelerator

    TYPE D : Water Reducer cum Retarder

    TYPE E : Accelerator cum Water Reducer

    TYPE F : High Range Water Reducer

    TYPE G : High Range Water Reducer cum Retarder

    BIS 9103 1999 (Reaffirmed 2007)

    TYPEA : Water Reducer

    TYPE B : Retarder

    TYPE C : Accelerator

    TYPE D : Air EntrainerTYPE E : High Range Water Reducer

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    ASTM C 260 and AASHTO M 154Air Entraining Admixture

    ASTM D 98 and AASHTO M 144

    Accelerating Admixtures Calcium Chloride

    ASTM C 1017Admixtures for producing Flowing Concrete

    Air Entraining AdmixturesAs per BIS 9103 ACI 116 R

    Air-entraining admixture is defined as an admixture for concrete or

    mortar which causes air to be incorporated in the form of minute bubbles

    in concrete or mortar during mixing usually to increase workability andresistance to freezing and thawing and disruptive action of de-icing salts

    The entrained air void system is distinct from air voids physically

    entrapped in concrete during placement and consolidation.

    These Admixtures are useful for :

    Freeze & Thaw Effect

    Cohesive Concrete

    Arresting Bleeding

    Making Movement of Higher Sized Coarse Aggregate

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    Air Entraining Admixtures

    Air-entraining admixture usually reduces the compressive strength of

    hardened concrete, particularly in concretes with moderate to highcementitious material contents. The reduction is normally 5% for eachpercent of air entrained.

    But the at the same time, entrained air reduces the total water content

    required to maintain a specific slump. The resulting water cementitiousmaterial ratio (w/cm) partially offsets the reduction in strength. This

    proves to be true in case of using air-entraining admixtures for lean mass

    concretes or concretes with higher size aggregates.

    Standard Methods of measuring air content in concrete

    The Gravimetric Method (ASTM C 138)

    The Volumetric Method ( ASTM C 173)

    The Pressure Method (ASTM C 231)

    AcceleratorsAs per BIS 9013 and ACI 116 R

    An accelerating admixture is defined as an admixture when added to concrete,

    mortar or grout increases the rate of hydration of the hydraulic cement,

    shortens the time of set or increases the rate of hardening or strengthdevelopment.

    Though Calcium Chloride is the most efficient and economical accelerator; but

    its uses are reduced in RCC structures as the free chlorides stay strongly with C-

    S-H phase in a chemisorbed or interlayer positions. Chloride free accelerating

    admixtures like Calcium Formate and others are widely used now-a-days.

    Calcium Formate increases the formation of ettringite at ordinary temperatures

    accelerating the hydration of the C3S surface.

    Accelerators are normally used for cold weather concreting (Not antifreezeAdmixture no depression in the freezing point of water).In tropical atmospheres, they help in :

    1. Earlier de-shuttering

    2. Earlier handling of pre-cast concrete

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    RetardersAs per BIS 9013 and ACI 116 R

    Retarding admixtures are defined as the materials which delay the setting time ofcement paste and hence of mixtures, such as mortar or concrete containingcement.

    Retarders are absorbed on C3S phase of cement forming a film around cement and

    preventing or reducing its reaction with water. This film breaks with time.

    Retarders are useful when concreting in hot weather, when normal setting time is

    shortened by the higher temperature, and in preventing the formation of

    cold joints between successive lifts in concreting.

    Precautions

    Dosage of retarders are very sensitive extra dosage than recommendedspecifications lead to a very extended set retardation sometimes no setting

    at all.

    Water Reducing Admixtures(Plasticizers)

    As per BIS 9013 and ACI 116 R

    A water reducing admixture is defined as an admixture which either increases

    workability of freshly mixed mortar or concrete without increasing watercontent or maitains workability with a reduced amount ofwater.

    So, if concrete is being for a particular workability (slump value), the additionof a water reducing admixture can give these advantages:

    1. Higher compressive strength with less water addition.

    2. Compressive strength in concrete can be increased without any additional

    cement.

    3. Cement content can be reduced, but the target strength can be achieved

    with desired workability (Commercial and Environment friendly)

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    Admixtures for Flowing Concrete Super Plasticizers (SPs)

    ASTM C 1017 defines flowing concrete as concrete that ischaracterized as having a slump greater than 190 mm (7.5 inch) whilemaintaining a cohesive nature

    Such Flowing Concretes are only achievable through the use ofadmixtures known as High-Range Water Reducers (HRWR) orSuperplasticisers which enable to reduce water significantly up to 20 to40%. These admixtures conform to ASTM C 494 Type F and Type G;BIS 9103 Type E and also meet the requirements of ASTM C 1017 Type

    1 or Type 2 respectively.

    As per BIS 9013

    A Super plasticizer is defined as an admixture for mortar or concrete

    which imparts very high workability or allows a large decrease in

    water content for a given workability

    Normal Water ReducingAdmixtures

    Normal WRAs /plasticisers are based on various chemical

    compounds:

    1. Lignosulphonate salts of Sodium and Calcium

    2. Hydroxycarboxylic acids (Citric and Gluconic acid)

    3. Carbohydrates (Corn syrup and Dextrin)

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    Types of Superplasticizers

    Super plasticisers are based on 5 types of chemical compounds:

    1. Modified Ligno Sulphonates (MLS)

    2. Sulphonated Melamine Formaldehyde Condensate (SMF)

    3. Sulphonated Naphthalene Formaldehyde Condensate (BNS / SNF)

    4. Poly Acrylate (AP)

    5. Poly Carboxylated Ether (PCE)

    CementParticles

    Entrappedwater

    ElectrostaticRepulsion

    (for sulphonatedpolymers)

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    Electrostatic and Steric Repulsion

    (for acrylic and polycarboxylate polymers)

    Comparative Analysis on Action of SPs

    Electrostatic repulsion depends on the composition of the solutionphase and the adsorbed amount of the SP ; greater the adsorption,

    better the repulsion. [Nakajima and Yamada, 2004].

    On the other hand, steric repulsion depends on the length ofmain

    chain, length and number of side chains [Sugiyama et al., 2003].

    In the case of PCE based admixtures, for fluidity retention, themain chain should be short, with large numbers of long side chains

    [Sugiyama et al., 2003]. Because of the steric repulsion mechanism,

    PCEs are generally more effective than the sulphonate based

    admixtures, and generally do not experience much problems at low

    water to cement ratios. However, they are more sensitive to

    overdosing and can lead to problems like excessive air entrainment

    and retardation.

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    SPECIAL ADMIXTURES

    Corrosion Inhibitors

    Corrosion Inhibitors are added to the reinforced cement

    concrete to delay corrosion of the steel.

    Corrosion Inhibitors can be broadly classified under

    three classes:

    1. Anodic Inhibitors

    2. Cathodic Inhibitors

    3. Mixed Inhibitors

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    Corrosion Inhibitors

    Effects on Concrete

    Fresh Stage: Increase in workability

    Setting Stage: Accelerate initial and final set

    Hardening Stage:

    1. Increase compressive strength

    2. Slight decrease the bond strength between steel and concrete

    Hardened Stage:

    1. Probable increase in alkali-aggregate reactions in presence ofreactive aggregates

    2. May increase efflorescence

    Anti-washout AdmixturesThese admixtures are used for underwater concreting reducing segregation by

    increased cohesiveness.

    The concrete admixed with such compounds shows high cohesiveness compared to ordinary

    concrete increasing the viscosity of water. As a result, when such a concrete is placed orpoured under the water by a free fall, it does not segregate. The resistance to segregation

    depends mainly on the dosage and molecular weight of the admixture.

    Application Areas

    Foundation of bridge piers in water and slabs.Piled piers, breakwaters of portsProtection of river bedsConcrete for reinforcing rubblestone of backwaters etc.Testing of Effectiveness (Falling through Water Test)

    3 litres of concrete are allowed to fall through water in a container of 30 cm diameter and 50

    cm height. The pH value and turbidity of the water near the surface are measured after 60

    seconds.

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    Gas Forming AdmixturesThey generate or liberate bubbles of gas in the fresh mixture during

    the hydration process before the initial set of the cement paste matrix

    takes place. Generally four types of GFAs are used depending on the typeof gas (Hydrogen, Oxygen , Nitrogen or Air) produced.

    Areas of Applications

    Grouts , Mortars or Concretes with controlled expansion

    To control settlement and bleeding causing the concrete to retain its

    initial volume

    Intrusion Grouts or Mortars for preplaced aggregate concrete

    To improve the intrusion of grouts and mortars in preplaced aggregate

    concrete by producing a positive expansion to the extent of 5 to 10%

    Cellular Concrete

    To produce aerated lightweight concrete and mortar when used at

    higher addition rates

    Other Grouting Admixtures

    These admixtures exhibit special properties to the grout

    1. To impart extreme fluidity without any segregation to the grout

    2. To keep the pumpable ability of geotechnical cement grouts (ACI

    552) and oil-well cementing grouts over large distances under high

    temperatures and pressures

    3. To resist fast drying and loss of water through adsorption by the

    substrate and the tiles in case of bonding and joint filling grouts

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    es

    es

    Shotcrete AdmixturThese admixtures are also called Quick Accelerators or Stiffening Admixtures as

    they accelerate the stiffening process in fresh concrete.

    These admixtures contribute special requirements in the shotcreting process :

    1. Impart fast stiffening makes possible the spraying of concrete on vertical andoverhead surfaces

    2. Help to build up thick layers

    3. Reduce rebound loss

    They may also be in applications for rapid setting and early strength

    development like sealing of leaks in below-grade structures, patchwork

    and emergency repairs.

    Mechanism of Action

    Accelerate the reaction between C3A and gypsum forming larger quantities of

    ettiringite at early age. Sometimes the rapid reaction of C3A disturbs

    the harmonious reaction between the calcium silicates and water.

    Shotcrete AdmixturTypes of Shotcrete Admixtures

    Shotcrete Admixtures are available in two forms Powder and Liquid.Powder admixtures are used for dry shotcreting and liquid for wet shotcreting.

    Dosage

    Powder admixtures are used normally at addition rates 2 to 10 % by weight of cement.(Checking the moisture content of aggregate is vital to have a better performance)

    Liquid admixtures are usually batched by volume ratios, with the admixture :water ratios ranging from 1:1 to 1:20. then the mix shold be accurately dispensed by

    positive flow pumps into the gauge water to have a good overall distribution.

    General Specifications

    The initial and final set sold occur within 3 and 12 minutes respectively.

    Rate of strength development : 4 MPa in 8 hours and 10 MPa in 24 hours (May vary with

    specific site requirements

    The decrease in strength at 28 days should be less than 30% compared to concrete

    without any admixture.

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    ixtures

    Extended Set Control Admixtures(Surface Retarders)

    These admixtures are used to stop or severely retard the cement hydrationprocess in unhardened concretes. They should be added and thoroughly mixedwith the unhardened concrete (either freshly batched or returned) before the

    concrete approaches its initial setting time.

    Extended set control admixtures differ from the conventional set controlling

    admixtures as they stop the hydration process of both the silicate and

    aluminate phases in Portland cement while the conventional act only on the

    silicate phases.

    Applications

    1. Creating anchor aggregate finish at construction or segmental joints

    2. Disposal of residual unhardened concrete from transit mixer drums / tippers

    Examples : Carboxylic Acids and Phosphorus containing organic acids and salts

    Pumping Aids / Flocculating AdmThese admixtures are used to enhance the pumpability of Concrete.

    Fresh concrete for pumping must be sufficiently mobile, cohesive(no segregation) and capable of flowing with reduced friction along the pipe

    walls. Pumping Aids act by physical means imparting lubrication to the freshconcrete increasing its cohesiveness and reducing bleeding in low cement

    mixes.

    Such admixtures normally contain highly charged groups in their chains

    and absorbed on cement particles, linking them together. The net result is

    to an increase in inter-particle attraction, which increases the tendency of thepaste to behave as one large floc.

    Dosage

    Dosage varies with types of polymers used as pumping aids. Normally 0.02% to

    1.5% by weight of cement are used.

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    Permeability Reducing Admixtures

    BIS 2645 - 2003

    Permeability reducing admixtures delay the ingress of moisture whenthe concrete is subjected to short or intermittent exposure to rain.

    Adding these admixtures actually reduces the rate of water inflowthrough the capillary pores in the concrete delaying the process ofdamage.

    Examples: Soaps, Butyl Stearate and certain petroleum products

    Admixture Selection by Application

    Congested reinforcement

    Difficult to ensure compactness of concreteSuperplasticizers increase the workability and flow.Viscosity modifying admixtures prevent segregation.

    Early removal of formwork

    Rapid strength gain is needed.Superplasticizers can be used to decrease w/c leading to

    higher early strength.

    Accelerators may be necessary, especially in colderclimates.

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    Admixture Selection by Application

    Flooring concrete

    Concrete floors require mix to be easy to place and minimalshrinkage.

    Plasticizers should be non-retarding.Accelerators may be necessary, especially in colder climates.Shrinkage reducing admixtures will be helpful

    High strength concrete

    Superplasticizers essential to overcome cohesiveness due tolow w/c and high binder content.

    Admixture Selection by Application

    Hot-weather concreting

    High temperatures lead to rapid workability loss and quicksetting.

    Retarding and plasticizing admixtures help. Marine concrete

    Superplasticizers essential to limit permeability.Corrosion inhibiting admixtures increase the corrosion

    threshold of the steel.

    Anti-washout admixtures for placing concrete under water.

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    Admixture Selection by Application

    Pumped concrete

    Pumping aids increase the cohesion in the concrete andprevent segregation.

    Shotcrete

    Plasticizing admixtures are used to get high strength and flow.Set-accelerating admixture is added at the nozzle to so that

    the concrete sets rapidly as it hits the substrate.

    Performance Requirements as per

    BIS 9103 - 1999

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    PATIBILITY

    Uniformity Tests and Requirements (Table 2)

    Sr.

    No.

    Property Requirement Reference

    1 Dry material contenta) For liquid admixture

    b) For solid admixture

    0.95T DMC < 1.05T,where

    T = Manufacturersstated value (percentby mass)

    DMC = Test results (percent by mass)

    2 Ash content 0.95T AC < 1.05T,where

    T = Manufacturersstated value (percentby mass)

    AC = Test results (percent by mass)

    3 Relative density Within 0.02 of the value stated by manufacturer

    4 Chloride ion content Within 10% of the value or within 0.2 % whicheveris greater as stated by the manufacturer

    5 pH 6 (Minimum)

    CEMENT

    SUPERPLASTICIZER INCO

    The use of SPs has become very common in India. There has also been a proliferation inthe number of brands of cement, and in the types of cement available.

    It is very difficult to ensure that an admixture that produces all the desired effects withcement A would do the same with cement B.

    Users often suffer when the supply of cement and/or admixture is changed midwaythrough a project. Problems arising out of compatibility issues are often mistakenfor problems with concrete mixture design by practising engineers.

    It must be noted that in such cases, neither the cement nor the admixture is responsible

    for such a result. This is an internationally acknowledged fact, referred asIncompatibility of Materials.

    So far as material science is concerned, some cements are not compatible with certainadmixtures and vice versa.

    Leading researchers have recognized the need to review the acceptance standardsfor both cements and superplasticizers since the incompatibility problems areexpected to grow with further and more extensive use of high performance concrete[Tagnit-Hamou et al., 1992], and also with the number of cements and chemicals availablein the market.

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    Common Problems due toIncompatibility

    Flash Setting

    Delayed Setting

    Rapid Slump Loss

    Improper Strength Gain

    Inordinate Cracking

    These issues in turn affect the hardened properties ofconcrete,primarily strength and durability.

    Complexity of Superplasiticized Concrete System

    On the one hand, there is thecomposition of the SPs ; on the other endof the spectrum is the composition ofcement (Clinker) - particularly therelative proportions of C

    3A, alkalis and

    C3S in the cement and in addition,

    the type of gypsum available (gypsum,hemihydrate or anhydrite) has animportant role to play.

    The fineness of cement could also affect

    its compatibility with a particularadmixture.

    Each of these factors influencesthe phenomenology of cement-waterreducer interaction.

    Incompatibility could also arise as a resultof the use of additional mineral additives,or while using multiple chemicals [Bedardand Mailvaganam, 2006].

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    Effect of Cement on Incompatibility

    1. Content of C3A (controlled by C3A to SO3 ratio)

    2. Availability of Calcium Sulphate in the hydrated cement phase

    depending on quality of Gypsum added during grinding (whether

    Dihydrate (CaSO4.2H20) / Hemihydrate ( CaSO4.1/2 H2O) /Anhydrite

    (CaSO4)

    3. Alkali content and Type of Alkali present in Cement

    4. Process of grinding and Fineness of Cement

    And so on.

    Admixture Factors for Incompatibility

    Admixture

    1. Admixture Type and Dosage

    2. Higher concentration of reducible sugar

    3. Absence of moderate to higher molecular weight chain fractions in

    the polymer4. Reduced chain length

    5. Unstable elementary composition

    6. Location of functional groups in the molecule

    7. Time of addition of SP in concrete

    And so on.

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    atibilityOther Factors for Incomp

    1. Low W/ C ratio in the concrete mix resulting lower interparticle separation

    of the cement particles makes it more sensitive to loss of water by

    evaporation or reaction with cement during transportation of the concrete.

    2. Interaction between a superplasticizer and the fines of the sand leading to a

    high loss of workability during transportation and early-age

    cracking increases even when the concrete is of better quality (which can

    occur when fillers absorb the bleed water, causing higher plastic

    shrinkage, or when a high paste content causes excessive thermal

    shrinkage). The fines content in river sand affects the performance of SPs

    [Papayianni et al., 2005].3. The placing of concrete at high ambient temperatures causes increase

    in reactivity of C3A which causes higher ettringite contents with

    fine morphology in the presence of SP [Greisser, 2002 ; Spiratos et al.,

    2003],

    thus causing a higher rate of slump loss.

    GUIDELINES FOR CHOOSING

    COMPATIBLE COMBINATIONS OFCEMENT & SUPERPLASTICIZER

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    of the

    Marshconeflow

    time

    Fluidity

    MARSH CONE

    MARSH CONE test is very useful for checking compatibility ofadmixtures against cements at site level.

    With a MARSH CONE, the flow time values of cement paste

    with varying dosages of admixtures can be plotted on a

    graph. The X-axis will represent DOSAGE and Y-axis will

    represent FLOW TIME. The site engineer can study the

    graphs plotted with varying dosage of different admixtures

    using the same cement and vice versa. The lowest point in

    the graph will indicate the best suitable combination of

    cement and admixture.

    MarshCone Test: Evaluationcompatibility and dosage

    800-1000 ml

    15.5 cm

    29 cm

    6 cm

    Diameter: 8 mm

    200-500 ml

    SATURATION

    POINT

    % sp/c

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    Paste-Concrete Correlation

    Can the flow behaviour of paste and

    concrete be correlated?

    Can the paste be used to optimise theconcrete mix?

    Cement-Superplasticizer Checklist

    Step 1: Study of Paste Characteristics (1/3)

    Record the basic properties of cement and

    superplasticizer for the quality checks, as well as for

    comparing different batches of products.

    The Hobart mixer or a similar intensive mixer isessential for the preparation of the paste in order for it

    to represent the paste within concrete.

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    Cement-Superplasticizer Checklist

    Step 1: Study of Paste Characteristics (2/3)

    First criterion: A well-defined saturation dosage fromthe Marsh cone test that is within the maximum dosage

    of the superplasticizer recommended by the supplier.

    The dosage obtained from the paste tests can be used as

    the guideline for selecting the dosage of

    superplasticizer for concrete.

    Cement-Superplasticizer Checklist

    Step 1: Study of Paste Characteristics (3/3)

    Second criterion: The influence of superplasticizer onthe setting behaviour of the paste is checked.

    Here, the final setting time of paste is limited to 16

    hours as obtained in the Vicat penetration test. If this

    criterion is satisfied, the final setting time of concrete

    would be not more than 12 hours.

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    Cement-Superplasticizer Checklist

    Step 2: Study of Concrete Characteristics (1/2)

    Tests done on concrete to ensure a mix with the

    required slump.

    Superplasticizer dosage may be increased if the

    saturation dosage is not sufficient; however, it is

    recommended that the dosage is not more than 150% of

    the saturation dosage in order to limit the retardation

    and possible segregation, as well as cost.

    Cement-Superplasticizer Checklist

    Step 2: Study of Concrete Characteristics (2/2)

    From the point of view of productivity, a minimum value

    of 50% of the 28-day compressive strength is

    recommended at 3 days (when the early age strength is

    critical).

    The final choice of the superplasticizer can be based on

    the minimum cost considering the dosage of the

    superplasticizer for obtaining the desired slump among

    the compatible combinations.

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    THANK

    S

    Contact : 9930650145Email : [email protected]

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    mailto:[email protected]:[email protected]:[email protected]
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    Polymeric Materials for GeneralBuilding Repair

    Mr. T. P. Banerjee

    HeadTraining

    Present Scenario

    More than 85% of the concrete produced in India is still by volume batching.There is lack of control of W/C ratio at sites. The control on quality of sandand aggregate is very limited. The concrete usually has high porosity.

    In the foundation concrete there is ingress of salts and water. This causesdeterioration of concrete and also the ground water rises in the walls throughthe capillaries in mortar and bricks. This leads to persistent rising dampnessand peeling of paints in walls at the ground level. The life of such structures isnaturally reduced.

    The pollutants like CO2 etc. along with water enter into the concrete aboveground leading to corrosion and deterioration of concrete.

    The Mortar and Plaster is site mixed cement and sand unlike pre-mix mortarsin other countries. It has lack of adhesion and cohesive propertiescompared to international practice. This leads to cracks in Mortar and Plaster.

    All the above lead to cracks and dampness in structures. Hence, the life ofstructures is lower than the designed life.

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    Cracks leading to ......

    Leakage

    Carbonation

    Corrosion

    Spalling of concrete

    Damage of structure

    Ultimately lead to collapse

    Planning of Repairs Important Steps

    Inspection

    Diagnosis

    Report

    Selection of Materials

    Job Specification

    Methodology

    Execution

    Post Care

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    Why Repairs Fail ?

    Improper surface preparation

    Improper mixing of repair mortars

    Improper use of bonding agents

    Wrong application method

    Hot & humid climate

    Partial repairs

    Corrosion starts again

    Cracks at the interface of repairs

    Other Focus Areas

    An opinion from expert consultants and structural audit, ifnecessary

    Selection of certified repair contractor

    Selection of reputed manufacturer for materials

    Supervision during execution

    Financial planning

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    Inspection of Crack Types

    Inspection of Crack Types

    Structural / Non Structural

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    Inspection of Crack Types

    Live / Dormant

    Ascertaining the width of the crack

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    Ascertaining the Depth of the Crack

    Detailed inspection, diagnosis is the crux of thematter and if the job specification is technical andholistic, repairs will last longer

    Otherwisethe structure will come back to the original state

    quickly after repairs and will call for re repairs.

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    Repair Materials must offer ..

    Compatibility With Old Concrete Excellent Bonding Properties

    Low Shrinkage

    Good Strength

    Dimension Stability

    Crack Resistance

    Impermeability

    Ease of Application

    Durability

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    MCI TREATMENT

    Repair Materials for Specific ApplicationsRebar Treatment

    Rust removers / Rust converters Dr. Fixit Rust Remover

    Zinc rich epoxy primers Dr. Fixit Epoxy Zinc Primer

    Bonding agents

    SBR Base (Internal Areas) Dr. Fixit Super LatexAcrylic Copolymer Base (External Surfaces) Dr. Fixit MPBEpoxy Resin Base (Old to New Concrete) Dr. Fixit Concrete Super Bond

    Crack Filling

    Acrylic paste (cracks below 5 mm)

    Dr. Fixit Crack - X Paste/ Dr. Fixit Crack - XPowder

    Shrink free polymer filling compound (5 10 mm)

    Dr. Fixit Crack - X Shrinkfree

    Polymer modified cement systems (> 10 mm)

    Dr. Fixit Polymer Mortar HB / Dr. Fixit Magic Mortar

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    Repair Materials for Specific Applications

    Anchoring

    High strength polyester resin anchor grouts Dr. Fixit Anchor FixWater insensitive epoxy anchor grouts for underwater applications

    Injection Grouts

    Cementitious Pagel Anchor and Injection GroutLow viscous epoxy Dr. Fixit Epoxy Injection GroutPolyurethane Dr. Fixit PU Injection 1403

    Repair Materials for Specific WP Applications

    Protective Coatings

    Primer and Bond Coatings (as pore sealers)Silane Siloxane (water repellents for external walls)Elastomeric acrylic coatings (external walls)Aliphatic acrylic (anti carbonation)Water based epoxy (damp walls)

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    Dr. Fixit Raincoat - Unique Product toProvideExternal Wall WP

    Heavy duty, waterproof coat for external walls

    Twice the thickness at a slight extra cost (120Microns vs 60 Microns)

    Bridges cracks up to 0.5 mm width

    Highly durable, retains a fresh look and has asuperior sheen

    No water dilution at site

    Higher binding property & more durability

    UV and stain resistant,

    Anti-algae, anti-fungal, Low dirt pickup

    Anti Carbonation CoatingDr. Fixit Concrete Guard

    These coatings are aimed at protecting cementious substratessuch as concrete and plasters.

    Generally pure aliphatic acrylic based resisting UV attack

    Allow moisture to escape from within to the outside

    Elastomeric to withstand small expansion and contractionmovements in the substrate

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    Treatment for Dampness Dr. Fixit Dampguard

    Water based epoxy breathable coatings (internal damp walls)

    Other Treatments for Dampness

    Siliconate injection grouts (rising water dampness) Dr. Fixit Dampfree

    Crystalline materials (internal pore fillers) Dr. Fixit Krystalline

    Polyurethane foam injection (water percolation blockers)Dr. Fixit PU Injection Foam Series

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    Repair Materials for Specific WP Applications

    Liquid Applied Barrier Systems

    Polymer modified cementitious systemsFibre incorporated water based acrylicsPolymer modified bitumen coatings

    Weather Protective Liquid Membrane

    Dr. Fixit New CoatRe-waterproof existing waterproofing systems like brick bat coba etc without

    breaking

    Allows foot traffic

    Bridges cracks upto 2 mm wide

    Ready to use, easy application

    Excellent UV resistance

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    Innovative waterproofing systems with Dr Fixit Newcoat fornew as well as old roofs

    Refurbishment of existing roof usingDr Fixit Newcoat - 7 year life expectancy

    New pitched roof waterproofing usingDr Fixit Newcoat - 7 year life expectancy

    Application of Dr. Fixit New Coat onManglorian Roof Tiles

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    Repair Materials for Specific Applications

    Sealants for Dynamic Cracks and Mechanical Loads

    Polysulphide Polyurethane Epoxy

    Sealants for Joints and Gap Filling

    Polysulphide (expansion joint) Polyurethane (expansion joints)

    Silicone (door / window frame joints) Acrylic (gap filling in tiles / basins / bath tubs etc.)

    Sealing of Cracks by Sealants

    Normally cracks which are dynamic ones are filled withsealants.

    A groove of minimum 6 mm x 6 mm or maximum 10mm x10mm is prepared by cutting with concrete cutting machine.

    The surface preparation and application are carried out as perspecifications and manufacturers guidelines.

    In this case of application, backup materials and bond breakersare not used.

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    Polymer Composites

    Composites

    Polymer Concrete(PC)

    PolymerModified

    Concrete (PMC)

    PolymerImpregnated

    Concrete (PIC)

    Fibre Reinforced Polymer Modified Concrete

    Prime Objective

    To overcome the intrinsic problems of low ductility, highbrittleness and strong cracking propensity of normal RCC

    Comparative Properties of PolymerComposites

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    Micro Concrete

    Flowable Mortar for repairs to damaged reinforced concretemembers

    Free flow and Self compacting

    High early & final strength (55 Mpa @ 28 days)

    Non shrinking,

    Impermeable surface finish

    Highly Durable

    Can be pumped

    RCC beam ready for Microconcrete jacket

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    Pour MICRO CONCRETE under gravity

    MICRO CONCRETE application under Pressure

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    Repaired and Cast with Micro

    Concrete

    Retrofitting / Structural Strengthening

    Fibre Composite Wrapping Systems

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    Fiber Composite Materials

    Fiber phase Filler Matrix phase

    Carbon

    Glass Aramid BoronResin

    High tensile strength(1860-7070 MPa)High cost

    E-Glass S-Glass Kevlar Thermoset Thermoplast

    Strength (3400 MPa)Most popularLess cost

    Strength(4500 MPa)High cost

    Highly cross linked

    Non recyclablee.g. Epoxy,

    Polyurethane

    Not cross linked

    Recyclablee.g. Polyester

    Advantages of FRP Composites

    No corrosion

    Higher ultimate strength

    Higher elastic modulus

    Very good fatigue properties

    Low weight - No increased dead weight

    No increase in cross-sectional area

    Highly flexible composite rolls can take any complex shape

    Clean application

    Joint free with Endless tapes

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    Hence, plethora of materials are available and

    todays polymer science brings new dimension to

    the construction industry.

    But evaluat io n and selectio n of specific

    materials for specific areas with systematic

    approach is the key to the success of any repair

    job

    Selection of Crack RepairSystem

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    Specialized Courses

    Offered by

    A Not-for-profit Knowledge Centre

    Distance Education (Correspondence) Course(For Professionals / Engineers)One Year Graduate Programme

    Concrete Technology, Waterproofing and Repair Management

    Certification by : NICMAR and Dr. Fixit Institute

    Eligibility

    Diploma or Bachelors degree in any branch of Civil Engineering, Mechanical Engineering,Chemical Engineering, Architecture, Town Planning, Building Sciences from a recognizedUniversity.

    How to Apply

    Prospectus and Application Form can be obtained from NICMAR on payment of Rs. 1103 byDemand Draft or downloaded from websites: www.nicmar.ac.in or www.drfixitinstitute.comand sent along with photocopies of required documents & application fee of Rs. 1000 byDemand Draft to NICMAR. The Demand Draft shall be in favour ofNICMARSODEat Pune.

    http://www.nicmar.ac.in/http://www.drfixitinstitute.com/http://www.drfixitinstitute.com/http://www.nicmar.ac.in/
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    Certificate Course on Entrepreneurship(For Contractors / Aspiring Students - Entrepreneurs)

    Dr. Fixit Institute is organizing certificate courses on specific module on

    Entrepreneurship in Waterproofing & Repair Technologies forConcrete Structures

    Modules

    Ten Day Module : For Contractors

    Six Months Module : For Students from ITI and 10+2 Building Maintenance Courses

    THANK YOU

    Tirtha Pratim BanerjeeMob: 9930650145

    Email: [email protected]

    mailto:[email protected]:[email protected]:[email protected]