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    Chapter 2Energy, Work and Heat

    (Tenaga, Kerja & Haba)

    OlehLt Kol Prof Madya Ir Khalid bin Abd Jalil TUDM

    Jabatan Kejuruteraan Mekanikal

    Universiti Pertahanan Nasional Malsysia.

    012-2094234

    Duty, Honor and

    Integrity

    Thermodynamics I (EMM2503)

    Chapter 2- Energy, Work and Heat

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    Objectives

    Introduce the concept of energy and define its various forms. Discuss the nature of internal energy.

    Define the concept of heat and the terminology associated with energy

    transfer by heat.

    Discuss the three mechanisms of heat transfer: conduction, convection,

    and radiation.

    Define the concept of work, including electrical work and several forms of

    mechanical work.

    Introduce the first law of thermodynamics, energy balances, and

    mechanisms of energy transfer to or from a system.

    Determine that a fluid flowing across a control surface of a control volumecarries energy across the control surface in addition to any energy transfer

    across the control surface that may be in the form of heat and/or work.

    Define energy conversion efficiencies.

    Discuss the implications of energy conversion on the environment.

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    Introduction to Energy

    Define as capacity to do work and an important part of daily life.

    is an extensive properties which have an ability to change the state of systemand it surrounding.

    1st Law of Thermodynamics , energy conservation principle (Prinsipkeabadian tenaga).

    Under the 1st law,, energy cannot be created or destroyed during theprocess; it can only changed from one form to another form (work is done).

    Forms of energy i.e. Electrical energy, potential , chemical & kinetic.

    Example: place a refrigerator in a well insulated room with its open. What willhappen to the room temperature?? Increasing or decreasing??

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    4

    INTRODUCTION If we take the entire roomincluding the air and the refrigerator (or fan)as

    the system, which is an adiabatic closed system since the room is well-sealed

    and well-insulated, the only energy interaction involved is the electrical energycrossing the system boundary and entering the room.

    As a result of the conversion of electric energy consumed by the device to

    heat, the room temperature will rise.

    A refrigerator

    operating with its

    door open in a well-

    sealed and well-

    insulated room

    A fan running in awell-sealed and

    well-insulated room

    will raise the

    temperature of air in

    the room.

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    5

    FORMS OF ENERGY

    Energy can exist in numerous forms such as thermal, mechanical, kinetic,

    potential, electric, magnetic, chemical, and nuclear, and their sum

    constitutes the total energy, Eof a system. Thermodynamics deals only with the changeof the total energy.

    Macroscopic forms of energy: Those a system possesses as a whole

    with respect to some outside reference frame, such as kinetic and potential

    energies.

    Microscopic forms of energy: Those related to the molecular structure ofa system and the degree of the molecular activity.

    Internal energy, U:The sum of all the microscopic forms of energy.

    The macroscopic energy of

    an object changes withvelocity and elevation.

    Kinetic energy, KE: The energy that

    a system possesses as a result of itsmotion relative to some reference

    frame.

    Potential energy, PE: The energy

    that a system possesses as a result

    of its elevation in a gravitational field.

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    Forms of Energy conts.Total energy of a system

    Kinetic energy (KE) related to motion and the influence ofsome external effects such as gravity, magnetism, electricity and

    surface tension

    Unit mass basis (kJ/kg)

    (kJ)

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    Forms of Energy cont.

    Potential Energy (PE)a result of its elevation in agravitational field.

    Unit mass

    basis

    (kJ)

    (kJ/kg)

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    Forms of Energy cont.

    Total energy system is expressed as

    E = U + +

    e = u + +

    Note: most of closed system remain stationary during process and thusexperience no change on their kinetic and potential energies.

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    9

    Total energy

    of a system

    Energy of a system

    per unit mass

    Potential energy

    per unit mass

    Kinetic energyper unit mass

    Potential energy

    Total energy

    per unit mass

    Kinetic energy

    Mass flow rate

    Energy flow rate

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    Mechanical EnergyMechanical energy:The form of energy that can be converted to

    mechanical work completely and directly by an ideal mechanical device such

    as an ideal turbine.Kinetic and potential energies: The familiar forms of mechanical energy.

    Mechanical energy of a

    flowing fluid per unit mass

    Rate of mechanical

    energy of a flowing fluid

    Mechanical energy change of a fluid during incompressible flow per unit mass

    Rate of mechanical energy change of a fluid during incompressible flow

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    11

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    Internal energy U (KJ)the sum of all microscopic forms of energy of asystem. It is related to the molecular structure and the degree of molecular activity

    and may be viewed as the sum of kinetic and potential energies of the molecules; it is

    comprised of the following types of energies

    Forms of Energy cont.

    Type Composition of Internal Energy (U)

    Sensible energy (haba

    rasa)

    the portion of the internal energy of a system associated with kinetic

    energies (molecular translation, rotation, and vibration; electron translation

    and spin; and nuclear spin) of the molecules.

    Latent energy (haba

    pendam)the internal energy associated with the phase of a system.

    Chemical energy the internal energy associated with the atomic bonds in a molecule.

    Nuclear energythe very large amount of energy associated with the strong bonds within the

    nucleus of the atom itself.

    Energy interactions

    those types of energies not stored in the system (e.g. heat transfer, mass

    transfer, and work), but which are recognized at the system boundary as they

    cross it, which represent gains or losses by a system during a process.

    Thermal energy the sum of sensible and latent forms of internal energy.(cannot be convertedto work directly and completely)

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    http://en.wikipedia.org/wiki/States_of_matterhttp://en.wikipedia.org/wiki/Chemical_bondshttp://en.wikipedia.org/wiki/Nuclear_energyhttp://en.wikipedia.org/wiki/Heat_transferhttp://en.wikipedia.org/wiki/Mass_transferhttp://en.wikipedia.org/wiki/Mass_transferhttp://en.wikipedia.org/wiki/Work_(thermodynamics)http://en.wikipedia.org/wiki/Thermodynamic_systemhttp://en.wikipedia.org/wiki/Thermodynamic_systemhttp://en.wikipedia.org/wiki/Work_(thermodynamics)http://en.wikipedia.org/wiki/Mass_transferhttp://en.wikipedia.org/wiki/Mass_transferhttp://en.wikipedia.org/wiki/Heat_transferhttp://en.wikipedia.org/wiki/Nuclear_energyhttp://en.wikipedia.org/wiki/Chemical_bondshttp://en.wikipedia.org/wiki/States_of_matter
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    Some Physical Insight to Internal Energy

    The internal energy of a

    system is the sum of all forms

    of the microscopic energies.

    The various forms of

    microscopic

    energies that make

    up sensible energy.

    Sensible energy:The portion

    of the internal energy of a

    system associated with the

    kinetic energies of the

    molecules.

    Latent energy: The internal

    energy associated with the

    phase of a system.Chemical energy: The internal

    energy associated with the

    atomic bonds in a molecule.

    Nuclear energy: The

    tremendous amount of energy

    associated with the strongbonds within the nucleus of the

    atom itself.

    Internal = Sensible + Latent + Chemical + Nuclear

    Thermal = Sensible + Latent

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    Forms of Energycont.

    The internal energy U (KJ) is essentially defined by the first law ofthermodynamics which states that energy is conserved:

    Where

    U= Q + W + W

    Uis the change in internal energy of a system during a process.

    Q is heatadded to a system (measured injoules in SI); that is, a positivevalue forQ represents heat flow into a system while a negative value

    denotes heat flow out ofa system.

    Wis the mechanical workdone on a system (measured in joules in SI)

    W'is energy added by all other processes

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    http://en.wikipedia.org/wiki/Heathttp://en.wikipedia.org/wiki/Joulehttp://en.wikipedia.org/wiki/SIhttp://en.wikipedia.org/wiki/Positivehttp://en.wikipedia.org/wiki/Negativehttp://en.wikipedia.org/wiki/Mechanical_workhttp://en.wikipedia.org/wiki/Mechanical_workhttp://en.wikipedia.org/wiki/Negativehttp://en.wikipedia.org/wiki/Positivehttp://en.wikipedia.org/wiki/SIhttp://en.wikipedia.org/wiki/Joulehttp://en.wikipedia.org/wiki/Heat
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    Energy can cross the boundary of closed system in 2 distinct

    forms:

    Heat & WorkHeat energy (Q) crosses the boundary due to the

    temperature difference between a system and its

    surroundings.

    Work energy (W) crosses the boundary under the

    action of a forces. Work can be thought of as the

    energy expended to lift a weight.

    Sign Convention

    Heat transfertoa system and work done bysystem are positive.

    Heat transferfroma system and Work done on a system are negative.

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    Heat Q [J, kJ] (Haba)Heat defined as the form of energy that transferred

    between two system by virtue of a temperature

    difference.

    heat is energy transition (crosses the

    boundary) heat is not a properties.

    heat is about the state of process.

    (depend on process path between end of

    process)

    Haba dibekalkan kpd

    sistem oleh sekitaran (Q>0)

    Haba yang disingkirkan oleh

    sistem kpd sekitaran. (Q

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    Heat transfer mechanisms:

    Conduction:The transfer of energy from the more energetic particles of a

    substance to the adjacent less energetic ones as a result of interaction between

    particles.

    Convection:The transfer of energy between a solid surface and the adjacent fluid

    that is in motion, and it involves the combined effects of conduction and fluid

    motion.

    Radiation:The transfer of energy due to the emission of electromagnetic waves

    (or photons).

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    Mechanisms of Heat Transfer

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    1. Conduction through Plane Walls

    - Conduction heat transfer is progressive exchange or

    energy between the molecules of substance

    Note: thermal conductivity value can be refer in table 2-3 page 98

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    Mechanisms of Heat Transferconts.

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    2. Convection Heat Transfer- Convection heat transfer is a mode of energy transfer

    between a surface and the adjacent liquid or gas that is

    in motion and it involves the combined effects of

    conduction and fluid motion.

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    Mechanisms of Heat Transferconts.

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    3. Radiation Heat Transfer

    - Radiative heat transfer is energy in transition from the

    surface of one body to the surface of another due to

    electromagnetic radiation.

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    Adiabatic Process a process during which there is no

    heat transfer (Q = 0)

    well insulated (negligible amount of heat can passthrough the boundary)

    Tsystem= Tsurrounding

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    Adiabatic System although there is no

    heat transfer during the process, energy

    content and temp. of the system can stillchanged by other mean such as work.

    Example: see figure 2-40 Page71

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    Heat transfer perunit mass (kJ/kg) of

    a system is donated q :

    (kJ/kg)

    Heat transfer perunit time

    Amount of heat transferred during

    the processes (dependent on the

    process path)

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    ENERGY TRANSFER BY WORK Work:The energy transfer associated with a force acting through a distance.

    A rising piston, a rotating shaft,andan electric wire crossing the

    system boundaries are all associated with work interactions Formal sign convention:Heat transfer to a system and work done by a

    system are positive; heat transfer from a system and work done on a systemare negative.

    Alternative to sign convention is to use the subscripts inand outto indicatedirection. This is the primary approach in this text.

    Specifying the directions

    of heat and work.

    Work done

    per unit mass

    Power is the

    work done per

    unit time (kW)

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    Heat vs. Work Both are recognized at the boundaries of

    a system as they cross the boundaries.

    That is, both heat and work are boundary

    phenomena.

    Systems possess energy, but not heat or

    work.

    Both are associated with aprocess, not a

    state.

    Unlike properties, heat or work has nomeaning at a state.

    Both arepath functions(i.e., their

    magnitudes depend on the path followed

    during a process as well as the end

    states).

    Properties are point functions

    have exact differentials (d).

    Path functions

    have inexact

    differentials ()

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    Electrical Work (Kerja Elektrik)

    - in electric field, electrons in a wire move under the

    effect of electromotive forces, doing work.

    Electrical power W = VI = IR = V/R

    -Unit : watt/ kW.

    V = voltage

    I = current

    t = time interval

    (kJ)Electrical work

    done

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    Note: (W0) kerja dilakukan oleh sistem

    Mechanical work (Joule / Nm)

    - Related to a force acting through a distance

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    Step 1: A car is to climb a hill in 12 s. The power needed is to be determined for three different cases.

    Step 2: Draw the diagram.

    Step 3 : Assumptions: Air drag, friction, and rolling resistance are negligible.

    Step 4 Analysis The total power required for each case is the sum of the rates of changes inpotential and kinetic energies. That is,

    Step 5 Properties g=9.81m/s

    Step 6 Calculation:

    (a) =0 since the velocity is constant. Also, the vertical rise is h = (100 m)(sin 30) = 50 m. Thus, &Wa=0

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    Step7 Discussion:

    The car required 90.1 kW of power to climb the 30 hill in 12s and need to

    reduced their power to -57.5 kW to achieve velocity 5 m/s.

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    37

    Shaft

    Work

    A force Facting through

    a moment arm r

    generates a torque T

    This force acts through a distance s

    The power transmitted through the shaft

    is the shaft work done per unit time

    Shaft

    work

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    Spring Work

    Elongation

    of a spring

    under the

    influence of

    a force.

    When the length of the spring changes by

    a differential amount dxunder the influence

    of a force F, the work done is

    For linear elastic springs, the displacement

    xis proportional to the force applied

    k: spring constant (kN/m)

    Substituting and integrating yield

    x1 andx2: the initial and the final

    displacements

    The

    displacement

    of a linear

    spring doubles

    when the force

    is doubled.

    Work Done on Elastic Solid Bars

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    39

    Work Done on Elastic Solid Bars

    Work Associated with the Stretching of a Liquid Film

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    GravitationalWork

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    W k D t R i t A l t B d

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    41

    Work Done to Raise or to Accelerate a Body

    Nonmechanical Forms of Work

    1. The work transfer needed to raise a body is equal to

    the change in the potential energy of the body.

    2. The work transfer needed to accelerate a body is

    equal to the change in the kinetic energy of the body.

    Electrical work: The generalized force is

    the voltage(the electrical potential) and thegeneralized displacement is the electrical

    charge.

    Magnetic work: The generalized force is

    the magnetic field strengthand the

    generalized displacement is the total

    magnetic dipole moment.

    Electrical polarization work: The

    generalized force is the electric field

    strengthand the generalized displacement

    is thepolarization of the medium.

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    The 1st Law Thermodynamics

    Before.. Learned about heat Q, work W, and total

    energyE,

    No attempt is made to relate them to each other during

    the process. Under the 1st law thermodynamics, its cover the

    relationships among the various form of energy and

    energy interactions.

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    The 1st Law Thermodynamics conts.

    known as the conservation of energy principle,

    also called energy balance.

    Under the 1st Law of Thermodynamics, energy

    can be either created nor destroyed during a

    process; it can only change forms. Thereforeevery bit of energy should be accounted for

    during a process.

    Such as falling rock (combination of potential

    energy and kinetic energy)

    1st law statement is the existence of theproperty total energyE.

    Example, potato baked, blowing water, well

    insulated room heated by heater.

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    The 1st Law Thermodynamics conts.

    1st law statement is the existence of the property total

    energyE.

    Example, potato baked, blowing water, well insulated

    room heated by heater.

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    Potato

    E=5kJ

    Qin=5kJ

    The increase in the energy of a

    potato in a oven is equal to the

    amount of heat transferred to it.

    E=Q net= 12kJ

    In the absence if any work

    interactions, the energy change

    of a system is equal to net the

    heat transfer.

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    52

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    Energy balance:

    The net change in total energy of the system during a process is equal to

    the difference between the total energy entering and the total energy

    leaving the system during that process.

    Total energy entering

    the system

    Total energy leaving

    the system

    Change in the total

    energy of the system=-

    Esystem = Ein - Eout

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    Energy Change of a System:

    Esystem

    (perubahan Tenaga Sistem)

    Energy change of a system during a process involves the evaluation of

    the system at the beginning and at the end of the process.

    Energy at final state Energy at initial state Energy Change=-Esystem = Efinal - Einitial

    Total energy of a system

    Net energy transfer by heat,

    work & mass

    Change in internal,

    kinetic, potential, etc

    energies

    For stationary system, the change in kinetic and potential

    energy is zero.

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    Mechanisms of Energy Transfer, Ein and Eout(Mekanisme Pemindahan Tenaga)

    Energy can transfer in 3 forms, heat, work and mass flow.

    heat transfer heat transfer to a system (heat gain) will increases the

    energy and heat transfer from the system will decreases (heat loss) the

    energy.

    Work transfer work transfer to the system (work done on the system) will

    increases the energy and work transfer from the system (work done by the

    system) will decreases the energy of the system. For example car engine,

    steam, turbine.

    Mass flow an additional mechanisms of energy transfer.

    Mass flow in increases the energy and mass flow out decreases the

    energy of the system.

    Ein Eout = Qin - Qout + W in - Wout + Emass in Emass out =E system

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    Mechanisms of Energy Transfer, Ein and Eout.conts.

    Mass in

    Mass in

    Esystem = Ein - EoutNet energy transfer by heat,

    work & mass

    Change in internal,

    kinetic, potential, etc

    energies

    E system = Ein Eout

    = Qin - Qout + W in - Wout + Emass in Emass out

    E system

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    See problem No 2-50 page 101

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    See problem No 2-51 page 101

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    See problem No 2-53 page 101Duty, Honor and

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    Energy conversion efficienciesEfficiencies is the ratio between the useful output of an energy conversion machine

    and the input, in energy terms.

    The useful output may be electric power, mechanical work, or heat.

    Energy conversion efficiency is not defined uniquely, but instead depends on the

    usefulness of the output. All or part of the heat produced from burning a fuel may

    become rejected waste heat if, for example, work is the desired output from a

    thermodynamic cycle.Indicate how well the energy transfer process is accomplished.

    Performance =Desired output

    Required input

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    Chapter 2- Energy Work and Heat

    http://upload.wikimedia.org/wikipedia/commons/0/09/Efficiency_diagram_by_Zureks.svg
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    Efficiencies of Mechanical and Electrical Devices

    Transfer of mechanical energy through

    a rotating shaft, often refer to as shaft

    work, ie water pump, fan, turbine.

    Performance =

    Mechanical energy output

    Mechanical energy input

    Transfer of electrical energy is commonly

    converted to a rotating mechanical energy by

    electrical motor to drive fans, compressors, robot

    arms, car starters and so forth.

    Performance =Mechanical energy output

    Electrical power input

    Thermodynamics I (EMM2503)

    Chapter 2- Energy Work and Heat

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    Chapter 2- Energy, Work and Heat

    Thermodynamics I (EMM2503)

    Chapter 2- Energy Work and Heat

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    Chapter 2 Energy, Work and Heat

    Thermodynamics I (EMM2503)

    Chapter 2- Energy Work and Heat

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    Chapter 2 Energy, Work and Heat

    Thermodynamics I (EMM2503)

    Chapter 2- Energy, Work and Heat

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    Energy and Environment

    The conversion of energy from one form to another often affects the environment.

    For example fossil fuel such as coal, oil and natural gas have been used to

    powering the industrial development since 1700s.

    Pollutants emitted during the combustion of the fossil fuel will produced

    environment pollution such as smog, acid rain and global warming and climatechange.

    The air pollution has been the cause of human health problem such as lung and

    heart diseases.

    To control the environment pollution, the Clean Air Act of 1970 (USA) have been

    introduced. Under the act, emission limits for hydrocarbons (HA), nitrogen oxides

    (NO3) and carbon monoxide (CO) have been reduced form 5 gpkm (grams per

    kilometer) in 1970 to 0.25 gpkm in 1980 and about 0.06 gpkm in 1999.

    Thermodynamics I (EMM2503)

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    Smog in Schanghai, Dezember 1993Smog in So Paulo

    Smog is a kind of air pollution; the word "smog" is

    a portmanteau of smoke and fog.

    The dark yellow or brown haze that builds up in alarge stagnant air mass and hangs over populated

    area on calm hot summer day.

    Beijing air on a day after rain (left) and a smoggy day (right)

    Thermodynamics I (EMM2503)

    Chapter 2- Energy, Work and Heat

    http://upload.wikimedia.org/wikipedia/en/a/a4/Beijing_smog_comparison_August_2005.pnghttp://upload.wikimedia.org/wikipedia/en/a/a4/Beijing_smog_comparison_August_2005.pnghttp://upload.wikimedia.org/wikipedia/en/a/a4/Beijing_smog_comparison_August_2005.pnghttp://upload.wikimedia.org/wikipedia/commons/4/4a/Sha1993_smog_wkpd.jpghttp://upload.wikimedia.org/wikipedia/commons/6/6b/Zona_Leste_-_S%C3%A3o_Paulo-Brasil.jpg
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    Ozone

    ground level layer in the

    stratosphere that protects the

    earth from suns harmful

    ultraviolet's rays.

    - Cause irritates eyes, headaches,fatigue, shortness of breath and

    damages the air sacs in the lungs

    where oxygen and carbon dioxide

    are exchanged (hardening the soft

    and spongy tissue in the lungs)

    -

    Thermodynamics I (EMM2503)

    Chapter 2- Energy, Work and Heat

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    p gy,

    Greenhouse Effect