32
74 CHAPTER 4 STUDIES ON THE RELATIONSHIP BETWEEN DRAPE AND MECHANICAL PROPERTIES OF GOAT SUEDE LEATHERS 4.1 INTRODUCTION Goat leathers account for about 8-10% of the total world leather production (John 1997). The application of goat leathers includes clothing, fancy goods, shoe uppers, gloves and lining leather. In raw goat skin, papillary layer represents about 30-40% and the reticular layer about 40-50% of the total thickness of 1-2 mm (John 1997). Both layers are tightly connected with each other such that loose grain, as found frequently in sheep skin is less often observed. Average size of the goat skins is about 0.5-0.9 m 2 . Goat skins are generally processed in to grain or suede finish for apparel application. Goat suede leather has a nap or velvet effect on the flesh side and the grain layer is completely removed. Full-grain leather is made from the outer side (grain) of an animal skin whereas suede leather uses the inner side (flesh). Goat suede leather is the thinnest among the apparel leathers. In recent years, there has been a renewed interest in investigating the aesthetic behavior of clothing materials due to the developments in objective evaluation techniques (Kenkare and May-Plumlee 2005). In this study, drape properties namely drape coefficient and number of drape nodes and other related mechanical properties such as softness, flexural rigidity, formability, initial tensile modulus, weight and thickness of goat suede leathers were quantified and correlated.

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74

CHAPTER 4

STUDIES ON THE RELATIONSHIP BETWEEN

DRAPE AND MECHANICAL PROPERTIES

OF GOAT SUEDE LEATHERS

4.1 INTRODUCTION

Goat leathers account for about 8-10% of the total world leather

production (John 1997). The application of goat leathers includes clothing,

fancy goods, shoe uppers, gloves and lining leather. In raw goat skin,

papillary layer represents about 30-40% and the reticular layer about 40-50%

of the total thickness of 1-2 mm (John 1997). Both layers are tightly

connected with each other such that loose grain, as found frequently in sheep

skin is less often observed. Average size of the goat skins is about 0.5-0.9 m2.

Goat skins are generally processed in to grain or suede finish for apparel

application. Goat suede leather has a nap or velvet effect on the flesh side and

the grain layer is completely removed. Full-grain leather is made from the

outer side (grain) of an animal skin whereas suede leather uses the inner side

(flesh). Goat suede leather is the thinnest among the apparel leathers. In recent

years, there has been a renewed interest in investigating the aesthetic behavior

of clothing materials due to the developments in objective evaluation

techniques (Kenkare and May-Plumlee 2005). In this study, drape properties

namely drape coefficient and number of drape nodes and other related

mechanical properties such as softness, flexural rigidity, formability, initial

tensile modulus, weight and thickness of goat suede leathers were quantified

and correlated.

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75

4.2 MATERIALS

Goat suede leathers of Indian origin (commercially available, top

grade) were procured from four different firms. Four leathers were chosen

from each firm with fairly uniform thickness and size (area around 0.5 m2).

Four circular samples were cut from each leather and the samples were

designated as SL (shoulder left), SR (shoulder right), BL (butt left) and BR

(butt right) based on location. These circular samples were used to measure

drape coefficient, number of nodes, softness, thickness and weight. From

these circular samples, rectangular samples were cut along, across and bias

backbone directions as shown in Figure 4.1 for measurement of flexural

rigidity and tensile modulus. Bias backbone samples were cut in order to

understand the tensile and bending behavior in 45° to backbone line. The

tensile strength, % elongation and tear strength values of the goat suede

leathers from four different firms are given in Table 4.1.

Figure 4.1 Schematic of location of the circular sample at butt right

position and the rectangular samples inside the circular

sample in goat suede leather

L1

X2

X1

L2

C1

X4

X3

C2

Back

bone

Lin

e

Circular sample at Butt Right

Legend:L1 and L2 Samples along backboneC1 and C2 Samples across backboneX1 to X4 Samples bias backbone

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Table 4.1 Tensile and tear properties of goat suede leathers from

different sources

Tensile strength(MPa)

Elongation(%)

Tear strength(N)

Firm 1Leather 1 19.73 ± 3.03 45.16 ± 2.37 24.42 ± 6.04

2 21.06 ± 3.45 48.93 ± 4.53 22.91 ± 3.763 25.42 ± 3.51 46.24 ± 5.15 29.07 ± 2.874 25.72 ± 2.49 46.14 ± 4.95 29.00 ± 8.51

Firm 2Leather 5 19.15 ± 2.52 46.73 ± 4.20 23.22 ± 4.94

6 20.55 ± 3.72 49.06 ± 7.04 20.06 ± 1.567 20.69 ± 2.16 46.38 ± 7.12 24.42 ± 3.208 21.90 ± 2.56 46.92 ± 5.53 23.48 ± 2.44

Firm 3Leather 9 20.88 ± 3.76 43.15 ± 5.90 18.30 ± 1.40

10 19.62 ± 2.81 46.29 ± 8.69 21.62 ± 1.1011 19.77 ± 3.25 47.71 ± 3.71 22.38 ± 5.6012 20.93 ± 2.04 44.19 ± 5.32 18.79 ± 2.91

Firm 4Leather 13 18.03 ± 2.84 50.19 ± 6.40 27.84 ± 2.65

14 28.54 ± 7.15 56.05 ± 5.65 37.06 ± 2.7415 34.51 ± 5.31 50.53 ± 5.49 26.20 ± 5.4016 30.00 ± 3.95 57.81 ± 7.68 36.22 ± 4.07

The values are average of sixteen samples along with standard deviation

4.3 MEASUREMENT AND CALCULATION

Measurement and calculation of drape coefficient, number of nodes

and other mechanical properties were carried out as explained in section 3.2.2

of Chapter 3. Softness was determined following IUP36 (2000) test method

using ST300 digital leather softness tester and the size of the reducing ring

used in the softness tester was 20 mm. All the samples were conditioned at a

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temperature of 20±2°C and relative humidity 65±5% for 48 h immediately

before its use in an experiment.

4.4 RESULTS AND DISCUSSION

4.4.1 Drape Parameters

Drape parameters of circular goat suede leather samples were

measured with grain as well as flesh side up. To find out the correlation, mean

drape coefficient values of grain side up samples were plotted against flesh

side up samples from individual leathers as shown in Figure 4.2. The

correlation between the two values seems to be linear, as indicated by the

correlation coefficient value of 0.98. Hence, the mean value of both

measurements was used for further comparison. Similarly, the number of

nodes of grain side up samples was plotted against flesh side up samples as

shown in Figure 4.3. From the plot, it is evident that the correlation between

the two values is good (R = 0.87). Hence, the mean value of both

measurements was calculated and used for further analysis.

15 20 25 30 35 40 45 5015

20

25

30

35

40

45

50

55

Mea

n dr

ape

coef

ficie

nt, f

lesh

sid

e up

(%)

Mean drape coefficient, grain side up (%)

Y = 1.11X - 3.74 R = 0.98

Figure 4.2 Mean drape coefficient of flesh side up samples versus grain

side up samples of individual goat suede leathers

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5.0 5.5 6.0 6.5 7.0 7.5 8.0 8.5

5.0

5.5

6.0

6.5

7.0

7.5

8.0

8.5

9.0

Mea

n nu

mbe

r of n

odes

, fle

sh s

ide

up

Mean number of nodes, grain side up

Y = 0.83 X + 1.00 R2 = 0.87

Figure 4.3 Mean number of nodes of flesh side up samples versus grain

side up samples of individual goat suede leathers

The mean values of drape coefficient and number of nodes formed

for circular samples from goat suede leathers procured from four differentfirms are given in Table 4.2 along with standard deviation. The leathers are

numbered based on the increasing order of their apparent density for eachfirm. Mean drape coefficient value varies from 19.8 to 50.4% for individual

goat suede leathers. The variation can be attributed to the differences in the

processes as well as mechanical operations adopted by various firms. It isevident that the observed drape coefficient values for goat suede leathers are

lower than the sheep nappa leathers meant for garment application. This may

be due to the low thickness, low weight per unit area and high softness of goat

suede leathers compared to sheep nappa leathers. The mean of number of

nodes formed varies between 5.5 and 8.5. The mean values of drapecoefficient were plotted against mean number of nodes in order to find the

interdependence as shown in Figure 4.4. The value of R suggests that there isa good correlation between the two values with negative slope. The drape

coefficient values decrease with the increase in number of nodes showing the

inverse relationship between the two. In other words, lesser value of drapecoefficient and higher value of number of nodes indicate better drape ability.

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Table 4.2 Drape parameters of goat suede leathers from different sources

Drape coefficient (%) Number of nodes*

Firm 1Leather 1 35.3 ± 3.6 6.5 ± 0.5

2 33.3 ± 3.5 6.5 ± 0.53 38.1 ± 7.7 6.0 ± 1.04 43.6 ± 3.1 5.5 ± 0.0

Firm 2Leather 5 20.5 ± 1.6 8.0 ± 1.0

6 20.4 ± 1.6 7.0 ± 0.57 19.8 ± 1.3 8.5 ± 0.58 22.5 ± 3.2 8.0 ± 1.0

Firm 3Leather 9 24.4 ± 1.6 7.0 ± 0.5

10 28.4 ± 0.8 7.0 ± 0.511 24.4 ± 0.8 7.5 ± 0.512 25.5 ± 3.1 7.0 ± 0.5

Firm 4Leather 13 50.4 ± 6.0 5.5 ± 0.0

14 43.4 ± 7.9 5.5 ± 0.515 33.9 ± 3.1 6.5 ± 0.516 33.9 ± 3.1 6.5 ± 0.5

The values are average of four samples along with standard deviation*Number of node values is round off to nearest 0.5

Drape coefficient and number of nodes of each circular goat suede

sample from different locations were plotted as radar chart as shown in

Figures 4.5 and 4.6. From the figures it is observed that, even though the

variation in drape coefficient is more between leathers from different firms,

the variation is less between different positions in any particular leather. The

standard deviation in drape coefficient between different locations such as SL,

SR, BL and BR is less than 3.7 (except in three leathers). The variation in

number of nodes is also not significant between different locations.

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5.5 6.0 6.5 7.0 7.5 8.0 8.515

20

25

30

35

40

45

50

55

Mea

n dr

ape

coef

ficie

nt (%

)

Mean number of nodes

Y = -9.50 X + 95.56 R = - 0.92

Figure 4.4 Mean drape coefficient versus mean number of nodes of

individual goat suede leathers

Figure 4.5 Graph of drape coefficient of circular goat suede samples

based on location

1 to 16: Leathers0 to 60: Drape coefficient

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Figure 4.6 Graph of number of nodes of circular goat suede samples

based on location

4.4.2 Softness Versus Drape Parameters

The mean value of softness of goat suede leathers from different

firms are given in Table 4.3 along with standard deviation. Mean softness

values were shown to be from 5.22 to 6.39 mm for individual goat suede

leathers. It has been reported that highly soft leathers meant for different

applications possess softness values in the order of 4 to 8 (Landmann et al

1994). It is seen that the softness values of the goat suede leathers procured

from different firms are higher than that of the values reported previously for

sheep nappa leathers meant for garment application. The variation of softness

values of leathers between different firms may be attributed to different

processing conditions.

1 to 16: Leathers0 to 10: Nodes

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Table 4.3 Softness, thickness and weight of goat suede leathers from

different sources

Softness (mm) Thickness (mm) Weight (g/dm2)Firm 1

Leather 1 6.02 ± 0.10 0.63 ± 0.01 3.73 ± 0.092 5.62 ± 0.38 0.66 ± 0.02 3.97 ± 0.233 5.64 ± 0.32 0.70 ± 0.02 4.21 ± 0.164 5.32 ± 0.19 0.68 ± 0.01 4.08 ± 0.10

Firm 2Leather 5 6.32 ± 0.11 0.56 ± 0.02 2.89 ± 0.12

6 6.33 ± 0.05 0.53 ± 0.03 2.80 ± 0.137 6.39 ± 0.22 0.55 ± 0.01 2.97 ± 0.058 5.61 ± 0.19 0.52 ± 0.04 2.84 ± 0.25

Firm 3Leather 9 6.22 ± 0.23 0.58 ± 0.02 2.94 ± 0.12

10 5.75 ± 0.15 0.63 ± 0.01 3.31 ± 0.1111 6.05 ± 0.13 0.60 ± 0.02 3.17 ± 0.0912 6.13 ± 0.21 0.58 ± 0.02 3.07 ± 0.12

Firm 4Leather 13 5.22 ± 0.16 0.63 ± 0.02 3.24 ± 0.19

14 5.75 ± 0.30 0.74 ± 0.01 3.86 ± 0.0315 6.04 ± 0.16 0.57 ± 0.03 3.21 ± 0.1716 6.15 ± 0.11 0.68 ± 0.02 3.91 ± 0.21

The values are average of four samples along with standard deviation

The mean drape coefficient values of the individual leathers have

been plotted against the mean softness values as shown in Figure 4.7. It is

observed that the drape coefficient values are inversely related to softness and

exhibit a negative slope. The drape coefficient values decrease with the

increase in softness values. The value of correlation coefficient (R = –0.77)

shows a fairly good correlation between the drape coefficient and softness of

goat suede leathers. The mean of number of nodes of individual leathers has

been plotted against the mean softness values as shown in Figure 4.8. It is

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seen that the number of drape nodes formed increases with increase in

softness with a positive slope.

5.2 5.4 5.6 5.8 6.0 6.2 6.415

20

25

30

35

40

45

50

55

Mea

n dr

ape

coef

ficie

nt (%

)

Mean softness (mm)

Y = -20.10 X + 149.90 R = -0.77

Figure 4.7 Mean softness versus mean drape coefficient of individual

goat suede leathers

5.2 5.4 5.6 5.8 6.0 6.2 6.4

5.5

6.0

6.5

7.0

7.5

8.0

8.5

Mea

n nu

mbe

r of n

odes

Mean softness (mm)

Y = 1.66 X - 3.03 R = 0.66

Figure 4.8 Mean softness versus mean number of nodes of individual

goat suede leathers

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4.4.3 Thickness Versus Drape Parameters

The thickness of circular samples was measured at four different

positions equidistant from the center and circumference of the sample and

averaged. The mean values of the thickness of circular leather samples from

different firms are shown in Table 4.3. The thickness of leather samples varies

from 0.52 to 0.74 mm for individual goat suede leathers from different firms.

The thickness of goat suede leathers is comparable to that of sheep nappa and

cow nappa leathers used in the previous study. To find out the relationship

between the DC and thickness, the mean thickness values of individual

leathers have been plotted against mean drape coefficient as shown in Figure

4.9. It is observed that the drape coefficient increases with the increase in

thickness as evidenced from fairly good correlation coefficient value.

It is interesting to note that the thickness and drape coefficient have a

positive linear relationship for goat suede leather, whereas for cow nappa

leather it is inversely related. This may be due to the uniformity in structure

over the entire cross section of goat suede leather. The cross section of goat

suede (0.6 mm thick) leather captured using scanning electron microscope

with 300 X magnification is shown in Figure 4.10 (Krishnaraj 2002). In goat

suede leather grain layer is more or less removed and the entire cross section

is made up of more spongy, porous, corium proper layer whereas in cow

nappa leather it is made up of both densely packed, grain and corium proper

layers. So, any increase in thickness of goat suede leather is associated with

increase of same kind of porous, corium proper layer, which does not change

the uniformity of the cross section and hence lead to increase in drape

coefficient.

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85

0.50 0.55 0.60 0.65 0.70 0.7515

20

25

30

35

40

45

50

55

Mea

n dr

ape

coef

ficie

nt (%

)

Mean thickness (mm)

Y = 113.05 X - 38.41 R = 0.77

Figure 4.9 Mean thickness versus mean drape coefficient of individual

goat suede leathers

Figure 4.10 Cross section of goat suede leather (300X magnification)

Grain side

Flesh side

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86

The mean number of nodes formed has been plotted against mean

thickness of individual leathers as shown in Figure 4.11. Inverse relationship

was observed between the number of nodes and the thickness and the

correlation coefficient is –0.78. It can be attributed that thinner goat suede

leathers have better drape ability and vice versa. These results are in

agreement with the observation made in drape parameter study.

0.50 0.55 0.60 0.65 0.70 0.75

5.5

6.0

6.5

7.0

7.5

8.0

8.5

Mea

n nu

mbe

r of n

odes

Mean thickness (mm)

Y = - 11.12 X + 13.62 R = - 0.78

Figure 4.11 Mean thickness versus mean number of nodes of individual

goat suede leathers

4.4.4 Weight Versus Drape Parameters

The weight of each circular sample was measured and the weight

per unit area of the samples was calculated. From the calculated values,

leather wise average of the samples was obtained and the values are shown in

Table 4.3. The mean weight per unit area of goat suede samples was found to

be between 2.80 and 4.21 g/dm2 for individual leathers from different firms.

The mean weight per unit area of individual leathers has been plotted against

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87

mean drape coefficient values as shown in Figure 4.12. As in the case of

thickness, the value of drape coefficient increases with the increase in weight

per unit area of goat suede leathers. Also the value of correlation coefficient

(R = 0.71) suggests fairly good correlation between the two values.

Figure 4.13 shows the plot of mean weight per unit area of individual leathers

and the mean number of nodes generated during drape measurement. As

expected, the plot shows an inverse relation between the weight and number

of nodes. The correlation coefficient value is similar to that of mean drape

coefficient versus mean weight, however with a negative slope. Increasing

weight of leather indicates increase in drape coefficient and decrease in

number of nodes, leading to poor drape ability. Hence, light goat suede

leathers have better drape ability. These results are in good agreement with

that of thickness and drape parameter study.

2.6 2.8 3.0 3.2 3.4 3.6 3.8 4.0 4.2 4.415

20

25

30

35

40

45

50

55

Mea

n dr

ape

coef

ficie

nt (%

)

Mean weight per unit area (g/dm2)

Y= 13.58 X - 14.89 R = 0.71

Figure 4.12 Mean weight versus mean drape coefficient of individual

goat suede leathers

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88

2.6 2.8 3.0 3.2 3.4 3.6 3.8 4.0 4.2 4.4

5.5

6.0

6.5

7.0

7.5

8.0

8.5

Mea

n nu

mbe

r of n

odes

Mean weight per unit area (g/dm2)

Y = - 1.33 X + 11.29 R = - 0.71

Figure 4.13 Mean weight versus mean number of nodes of individual

goat suede leathers

4.4.5 Flexural Rigidity Versus Drape Parameters

Flexural rigidity was calculated from the bending length measured

using stiffness tester (IS 6490 1971). Higher values of flexural rigidity

indicate more resistance to flexing, while lower values indicate easier flexing

and hence better drape ability. Flexural rigidity of goat suede leathers was

measured along, across and bias backbone directions and the mean values are

given in Table 4.4 along with standard deviation. The mean value of flexural

rigidity in all the three directions varies from 11.3 to 60.8 mNmm among

individual leathers from different firms. Although the flexural rigidity values

are varying significantly for leathers from different firms, such variations are

negligible within individual leathers for different directions. In other words,

there is no significant difference in flexural rigidity values measured bias

backbone compared to that of along and across backbone directions in most of

the leathers.

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Table 4.4 Flexural rigidity of goat suede leathers from different sources

Flexural rigidity (mNmm)Along

backbone*Across

backbone*Bias

backbone#

Firm 1Leather 1 40.4 ± 10.2 28.1 ± 7.0 35.6 ± 5.8

2 37.8 ± 11.7 28.4 ± 4.9 34.4 ± 8.63 53.1 ± 11.6 41.0 ± 10.3 50.1 ± 12.34 44.5 ± 6.7 43.9 ± 6.2 49.5 ± 4.8

Firm 2Leather 5 13.6 ± 1.2 12.1 ± 1.6 14.1 ± 1.1

6 12.7 ± 1.7 11.3 ± 1.0 13.7 ± 1.87 13.3 ± 1.3 11.9 ± 1.2 13.5 ± 0.88 14.6 ± 1.7 14.9 ± 3.8 16.5 ± 4.6

Firm 3Leather 9 17.8 ± 4.3 14.9 ± 2.2 16.1 ± 2.5

10 23.1 ± 1.9 23.4 ± 3.7 26.8 ± 2.811 17.9 ± 3.1 16.9 ± 1.0 18.7 ± 2.112 19.2 ± 1.2 18.0 ± 3.8 20.5 ± 4.1

Firm 4Leather 13 44.9 ± 9.8 60.8 ± 10.4 56.6 ± 11.8

14 57.9 ± 11.6 49.0 ± 12.9 53.6 ± 11.015 28.2 ± 5.1 35.0 ± 6.5 29.7 ± 4.016 39.0 ± 3.9 36.8 ± 8.8 39.0 ± 6.7

* The values are average of eight samples along with standard deviation# The values are average of sixteen samples along with standard deviation

Mean flexural rigidity of individual leathers measured along, across

and bias backbone directions of leathers have been plotted against mean drape

coefficient values of corresponding leathers as shown in Figures 4.14, 4.15

and 4.16, respectively. The correlation between mean flexural rigidity and

mean drape coefficient is very good in all the three backbone directions. The

plots of mean flexural rigidity across as well as bias backbone directions

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90

versus mean drape coefficient show the highest correlation (R = 0.98). It is

seen that, as the mean flexural rigidity values increase the mean drape

coefficient values also increase in all three directions. Hence, the drape ability

of goat suede leathers decreases with the increase in flexural rigidity.

10 20 30 40 50 6015

20

25

30

35

40

45

50

55

Mea

n dr

ape

coef

ficie

nt (%

)

Mean flexural rigidity, along backbone (mNmm)

Y = 0.56 X +14.43 R = 0.91

Figure 4.14 Mean drape coefficient versus mean flexural rigidity ofindividual goat suede leathers along backbone

10 20 30 40 50 6015

20

25

30

35

40

45

50

55

Mea

n dr

ape

coef

ficie

nt (%

)

Mean flexural rigidity, across backbone (mNmm)

Y = 0.61 X + 14.11 R = 0.98

Figure 4.15 Mean drape coefficient versus mean flexural rigidity ofindividual goat suede leathers across backbone

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91

10 20 30 40 50 6015

20

25

30

35

40

45

50

55

Mea

n dr

ape

coef

ficie

nt (%

)

Mean flexural rigidity, bias backbone (mNmm)

Y = 0.59 X + 12.97 R = 0.98

Figure 4.16 Mean drape coefficient versus mean flexural rigidity ofindividual goat suede leathers bias backbone

Similarly, the mean flexural rigidity values measured along, acrossand bias backbone directions have been plotted against the mean number ofnodes of corresponding leathers as shown in Figures 4.17, 4.18 and 4.19,respectively.

10 20 30 40 50 60

5.5

6.0

6.5

7.0

7.5

8.0

8.5

Mea

n nu

mbe

r of n

odes

Mean flexural rigidity, along backbone (mNmm)

Y = -0.05 X + 8.34 R = -0.88

Figure 4.17 Mean number of drape nodes versus mean flexural rigidityof individual goat suede leathers along backbone

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From the plots, it is evident that the number of nodes has inverserelation with the flexural rigidity for goat suede leathers. Fairly highcorrelation coefficients around –0.9 in all the three directions indicate a closelinear relationship between mean flexural rigidity and the mean number ofdrape nodes.

10 20 30 40 50 60

5.5

6.0

6.5

7.0

7.5

8.0

8.5

Mea

n nu

mbe

r of n

odes

Mean flexural rigidity, across backbone (mNmm)

Y = -0.05 X + 8.28 R = -0.89

Figure 4.18 Mean number of drape nodes versus mean flexural rigidityof individual goat suede leathers across backbone

10 20 30 40 50 60

5.5

6.0

6.5

7.0

7.5

8.0

8.5

Mea

n nu

mbe

r of n

odes

Mean flexural rigidity, bias backbone (mNmm)

Y = -0.05 X + 8.42R = -0.91

Figure 4.19 Mean number of drape nodes versus mean flexural rigidityof individual goat suede leathers bias backbone

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4.4.6 Formability Versus Drape Parameters

Formability was calculated for goat suede leather samples cut

along, across and bias backbone directions of the leather and the mean values

are given in Table 4.5 along with standard deviation. The mean formability of

goat suede leathers varies between 0.003 and 0.017 mm2 for all backbone

directions of leathers from different firms. It is seen that the mean formability

values along backbone are similar or higher than that of across backbone

direction.

Table 4.5 Formability of goat suede leathers from different sources

Formability (mm2)Along

backbone*Across

backbone*Bias

Backbone#

Firm 1Leather 1 0.012 ± 0.001 0.007 ± 0.003 0.010 ± 0.001

2 0.011 ± 0.002 0.006 ± 0.001 0.007 ± 0.0023 0.011 ± 0.004 0.008 ± 0.003 0.011 ± 0.0044 0.011 ± 0.004 0.008 ± 0.001 0.010 ± 0.002

Firm 2Leather 5 0.004 ± 0.000 0.003 ± 0.000 0.004 ± 0.000

6 0.003 ± 0.001 0.003 ± 0.001 0.004 ± 0.0017 0.004 ± 0.000 0.004 ± 0.001 0.004 ± 0.0008 0.003 ± 0.000 0.003 ± 0.000 0.003 ± 0.000

Firm 3Leather 9 0.003 ± 0.001 0.003 ± 0.001 0.004 ± 0.001

10 0.005 ± 0.001 0.005 ± 0.002 0.006 ± 0.00111 0.005 ± 0.001 0.004 ± 0.001 0.004 ± 0.00112 0.004 ± 0.001 0.003 ± 0.000 0.005 ± 0.001

Firm 4Leather 13 0.011 ± 0.003 0.011 ± 0.001 0.010 ± 0.002

14 0.017 ± 0.004 0.011 ± 0.003 0.015 ± 0.00115 0.007 ± 0.002 0.006 ± 0.002 0.008 ± 0.00216 0.013 ± 0.005 0.010 ± 0.002 0.012 ± 0.003

* The values are average of eight samples along with standard deviation# The values are average of sixteen samples along with standard deviation

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Mean formability values calculated for samples cut along, across

and bias backbone directions have been plotted against mean drape coefficient

values of the individual leathers, as shown in Figures 4.20, 4.21 and 4.22,

respectively. A very good relation between formability and drape coefficient

is seen when fit linearly for all three directional samples. The plot of

formability across backbone and drape coefficient recorded the highest

correlation (R = 0.92). Form the linear relationship, it is evident that the

increase in formability relates to increase in the drape coefficient of goat

suede leathers. In other words lower formability leathers tend to drape better.

Such trend has already been reported for textile fabrics (Griffiths and Kulke

2002).

0.002 0.004 0.006 0.008 0.010 0.012 0.014 0.016 0.01815

20

25

30

35

40

45

50

55

Mea

n dr

ape

coef

ficie

nt (%

)

Mean formability, along backbone (mm2)

Y = 1837.42 X + 16.83 R = 0.86

Figure 4.20 Mean drape coefficient versus mean formability of

individual goat suede leathers along backbone

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0.002 0.004 0.006 0.008 0.010 0.01215

20

25

30

35

40

45

50

55

Mea

n dr

ape

coef

ficie

nt (%

)

Mean formability, across backbone (mm2)

Y =3026.17 X + 13.32 R = 0.92

Figure 4.21 Mean drape coefficient versus mean formability of

individual goat suede leathers across backbone

0.002 0.004 0.006 0.008 0.010 0.012 0.014 0.01615

20

25

30

35

40

45

50

55

Mea

n dr

ape

coef

ficie

nt (%

)

Mean formability, bias backbone (mm2)

Y = 2248.70 X + 14.67 R = 0.88

Figure 4.22 Mean drape coefficient versus mean formability of

individual goat suede leathers bias backbone

The mean formability of leathers measured along, across and bias

backbone directions have been plotted against the mean number of drape

nodes as shown in Figures 4.23, 4.24, and 4.25, respectively. The correlation

coefficients are more than –0.80, which indicates that the correlation between

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the mean formability and the number of nodes is reasonably good and

inversely proportional.

0.002 0.004 0.006 0.008 0.010 0.012 0.014 0.016 0.018

5.5

6.0

6.5

7.0

7.5

8.0

8.5

Mea

n nu

mbe

r of n

odes

Mean formability, along backbone (mm2)

Y = -169.52 X + 8.10 R = -0.82

Figure 4.23 Mean number of nodes versus mean formability of

individual goat suede leathers along backbone

0.002 0.004 0.006 0.008 0.010 0.012

5.5

6.0

6.5

7.0

7.5

8.0

8.5

Mea

n nu

mbe

r of n

odes

Mean formability, across backbone (mm2)

Y = -265.80 X + 8.34 R = -0.83

Figure 4.24 Mean number of nodes versus mean formability of

individual goat suede leathers across backbone

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0.002 0.004 0.006 0.008 0.010 0.012 0.014 0.016

5.5

6.0

6.5

7.0

7.5

8.0

8.5

Mea

n nu

mbe

r of n

odes

Mean formability, bias backbone (mm2)

Y = -212.34 X + 8.33 R = -0.85

Figure 4.25 Mean number of nodes versus mean formability of

individual goat suede leathers bias backbone

4.4.7 Initial Tensile Modulus Versus Drape Parameters

Initial tensile modulus was measured for samples cut along, across

and bias backbone directions of the goat suede leathers and the mean values

are given in Table 4.6 along with standard deviation for different firms. The

mean values of the initial tensile modulus in all the three directions vary from

3.29 to 6.43 N/mm for individual goat suede leathers from different firms.

The mean initial tensile modulus across backbone direction is higher than that

of along and bias backbone directions for most of the leathers. Mean initial

tensile modulus values of samples cut along, across and bias backbone

directions have been plotted against mean drape coefficient values of

individual leathers, as shown in Figures 4.26, 4.27 and 4.28, respectively. It is

seen that the influence of initial tensile modulus on drape coefficient is not

substantial since there is no significant correlation coefficient observed

between the two properties in all the three directions. It is also observed that

the correlation between the mean initial tensile modulus and the mean number

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of drape nodes is not significant (plots not shown). It is observed that the

correlation between initial tensile modulus and drape coefficient is poor in

goat suede leathers, whereas the correlation between the two properties is

fairly good for nappa leathers (sheep and cow). This may be attributed to the

removal of grain layer in suede leathers as against the presence of grain layer

in nappa leathers. In general the epidermis and the top layer of dermis (grain)

contribute more towards tensile strength and initial tensile modulus compared

to the bottom layer.

Table 4.6 Initial tensile modulus of goat suede leathers from different

sources

Initial tensile modulus (N/mm)Along backbone* Across backbone* Bias backbone#

Firm 1Leather 1 3.35 ± 0.57 3.92 ± 0.61 3.72 ± 0.77

2 3.52 ± 0.86 5.05 ± 1.03 4.67 ± 0.683 4.86 ± 0.38 5.61 ± 0.99 4.53 ± 0.584 4.21 ± 0.97 5.51 ± 0.35 4.98 ± 1.01

Firm 2Leather 5 3.87 ± 0.42 3.74 ± 0.69 3.86 ± 0.54

6 3.96 ± 0.95 4.39 ± 2.38 3.85 ± 0.367 3.32 ± 0.18 3.51 ± 0.86 3.70 ± 0.278 4.93 ± 0.42 5.87 ± 1.44 5.67 ± 1.39

Firm 3Leather 9 5.46 ± 1.87 4.68 ± 1.45 3.85 ± 1.06

10 4.70 ± 0.88 5.17 ± 1.72 4.85 ± 0.8011 3.95 ± 0.48 4.19 ± 1.35 4.39 ± 0.9312 4.64 ± 0.92 5.53 ± 1.60 4.04 ± 0.75

Firm 4Leather 13 4.08 ± 0.49 5.55 ± 1.26 5.39 ± 0.38

14 3.53 ± 0.44 4.66 ± 0.80 3.59 ± 0.5015 4.09 ± 1.38 6.43 ± 2.11 3.71 ± 0.6616 3.38 ± 1.19 3.70 ± 0.11 3.29 ± 0.56

* The values are average of eight samples along with standard deviation# The values are average of sixteen samples along with standard deviation

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3.0 3.5 4.0 4.5 5.0 5.515

20

25

30

35

40

45

50

55

Mea

n dr

ape

coef

ficie

nt (%

)

Mean initial tensile modulus, along backbone (N/mm)

Y = -2.35 X + 40.79 R = -0.16

Figure 4.26 Mean drape coefficient versus mean initial tensile modulus

of individual goat suede leathers along backbone

3.5 4.0 4.5 5.0 5.5 6.0 6.515

20

25

30

35

40

45

50

55

Mea

n dr

ape

coef

ficie

nt (%

)

Mean initial tensile modulus, across backbone (N/mm)

Y = 4.00 X + 11.74 R = 0.37

Figure 4.27 Mean drape coefficient versus mean initial tensile modulus

of individual goat suede leathers across backbone

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3.0 3.5 4.0 4.5 5.0 5.5 6.015

20

25

30

35

40

45

50

55

Mea

n dr

ape

coef

ficie

nt (%

)

Mean initial tensile modulus, bias backbone (N/mm)

Y = 3.23 X + 17.38 R = 0.24

Figure 4.28 Mean drape coefficient versus mean initial tensile modulus

of individual goat suede leathers bias backbone

4.5 COMPARISON OF CORRELATION COEFFICIENTS FOR

SHEEP NAPPA, COW NAPPA AND GOAT SUEDE

LEATHERS

The correlation coefficient values of the various plots between

drape coefficient and mechanical properties of sheep nappa, cow nappa and

goat suede leathers are shown in Table 4.7. It is observed that the flexural

rigidity is directly related to drape coefficient for all the three leather types in

all the three directions as seen from the values of the correlation coefficients.

In most of the cases the correlation coefficient is around 0.9. With respect to

the correlation between flexural rigidity and drape coefficient the various

apparel leathers is in the order of goat suede > sheep nappa > cow nappa. The

correlation between weight of the leather and drape coefficient is consistently

high for all the three leathers and ranges around 0.8. The above observation

indicates that the weight of the leather is one of the influencing parameter on

drape coefficient. In the case of weight versus drape coefficient the various

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apparel leathers can be arranged as sheep nappa > cow nappa > goat suede.

Next to weight, the correlation coefficient of softness versus drape coefficient

ranges around 0.7 and it is also consistent in its behavior for all the three

leather types. Regarding the correlation between softness and drape

coefficient the various apparel leathers is in the order of cow nappa > goat

suede > sheep nappa. It is interesting to note that different type of leather is

preferred over the other considering the mechanical properties namely

flexural rigidity, weight and softness with respect to drape coefficient.

Table 4.7 Correlation coefficients for the plots of drape coefficient

versus various mechanical properties for apparel leathers

Correlation Coefficient (R)Correlation plot Sheep

nappaCow

nappaGoatsuede

DC Vs Softness -0.68 -0.94 -0.77

DC Vs Flexural rigidity (Along backbone) (Across backbone) (Bias backbone)

0.880.91

--

0.780.800.79

0.910.980.98

DC Vs Thickness 0.44 -0.75 0.77

DC Vs Weight 0.83 -0.80 0.71

DC Vs Initial Tensile modulus (Along backbone) (Across backbone) (Bias backbone)

0.340.82

--

0.950.890.90

0.160.370.24

DC Vs Formability (Along backbone) (Across backbone) (Bias backbone)

0.440.34

--

-0.51-0.58-0.59

0.860.920.88

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The correlation coefficient between thickness and drape coefficient

is good for cow nappa and goat suede but not in the case of sheep nappa. For

cow nappa and goat suede, the correlation coefficient between thickness and

DC is almost same but inverse relation is observed in the case of cow nappa.

More detailed studies are needed to analyse the drape behavior of sheep nappa

with respect to thickness. The value of formability is much lesser for goat

suede leathers compared to sheep and cow nappa leathers. On the other hand,

the formability of goat suede leathers had high correlation with drape

coefficient whereas sheep and cow nappa leathers did not show such

correlation. This observation with respect to apparel leathers are in agreement

with the observation for textile materials. Although higher formability

materials lead to low seam puckering and better sewability, such materials

possess poor drape ability (De Boos and Roczniok 1996, Griffiths and Kulke

2002).

Cow nappa leathers show good correlation for the plot of initial

tensile modulus versus drape coefficient for all the three back bone directions,

whereas the correlation is significant only across backbone for sheep nappa

leather. Only in the case of initial tensile modulus, the directional variation in

samples seems to influence the correlation coefficient. Interestingly, goat

suede leather which had high correlation with all the other mechanical

properties does not have any correlation with respect to initial tensile modulus

versus drape coefficient. This behavior may be attributed to the absence of

grain layer in suede leather as against its presence in nappa leathers as

discussed earlier in this Chapter. The correlation coefficient values for bias

backbone samples are almost similar to that of along and across backbone

samples for cow nappa and goat suede leathers.

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4.6 MULTIPLE LINEAR REGRESSION OF DRAPE

COEFFICIENT WITH MECHANICAL PROPERTIES FOR

SHEEP NAPPA, COW NAPPA AND GOAT SUEDE

LEATHERS

All along this thesis, the correlation of drape coefficient with

individual mechanical properties were analysed using simple linear

regression. To find out the combined effect of different mechanical properties

on drape coefficient, it was decided to use multiple linear regression analysis.

Multiple linear regressions are extensions of simple linear regression with

more than one independent variable. Using Origin 7.0 software, multiple

linear regression is carried out and the regression equations were derived

keeping drape coefficient as dependent variable and other mechanical

parameters as independent variables. The regression equation and the

Coefficient of Determination (COD), (R2), for different apparel leathers are

given in Table 4.8. For this analysis, the mean values of along, across and bias

backbone of flexural rigidity, initial tensile modulus and formability values

were used.

Table 4.8 Regression equations and COD values for the multiple linear

regression of drape coefficient with various mechanical

properties for apparel leathers

Regression equation COD (R2)DC Sheep nappa = -5.56 + 5.18 S – 0.04 FR + 2.83 W -60.82 T

+ 14.57 ITM + 733 F0.96

DC Cow nappa = 140.23 + 5.65 S + 0.22 FR + 3.36 W - 68.53 T - 3.88 ITM - 2650 F

0.99

DC Goat suede = 59.59 - 4.18 S + 0.66 FR - 1.83W -22.74 T - 0.77 ITM + 71 F

0.98

S: Softness; FR: Flexural Rigidity; W: Weight; T: Thickness; ITM: Initial Tensile Modulus;

F: Formability

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It is interesting to note that the coefficient of determination values

are above 0.96 for all the three leather types, in fact its value is 0.99 for cow

nappa leathers. The COD value is related to residual variance. The smaller the

variability of the residual values around the regression line relative to the

overall variability, the better is COD value. In other words, COD close to 1.0

indicates that we have accounted for almost all of the variability with the

variables specified in the model. From the values of COD obtained in the

multiple linear regression, it can be determined that all the selected

mechanical properties in combination are related to the drape coefficient even

though some of the mechanical properties do not correlate well with DC in

the individual correlation.

4.7 CONCLUSIONS

Drape parameters such as drape coefficient and number of nodes

were measured for goat suede leathers and correlated with some relevant

mechanical properties related to garment construction. It is found that the

drape coefficient and the number of nodes have inverse relation. In other

words, goat suede leathers having less value of drape coefficient will produce

more number of nodes and possess better drape ability. From this study, it is

observed that flexural rigidity and formability have very good correlation (R

0.8) with drape coefficient as well as number of nodes in all the three

backbone directions. Other properties such as softness, thickness and weight

have fairly good correlation (R 0.7) with both the drape parameters. Overall

all the selected mechanical properties showed good correlation with drape

coefficient and number of drape nodes, except initial tensile modulus for goat

suede leather. When compared with all types of apparel leathers namely

sheep nappa, cow nappa and goat suede, it can be concluded that the flexural

rigidity, weight and softness were most significantly related to drape

coefficient. One of the key findings is that the goat suede leathers possess

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significantly better drape ability compared to sheep nappa and cow nappa

leathers used for apparel application. This would facilitate in the selection of

leathers for apparel requiring more fall, flexibility and textile like clothing. It

is shown that all the selected mechanical properties in combination are

significantly related to drape coefficient using multiple linear regression

analysis.