4
g 28th July 11th A C 2017 13th Aug 2017 23th Aug 201 7 29th Aug 29th Aug 2017 29th Aug 201 7 29th Aug 2017 Time of Trip 15.25 03.30 07.40 19.10 00.02 00.33 09.26 11.26 Date Back on line 08th Aug 201 7 11 th Aug 2017 13th Aug 2017 23th Aug 201 7 29th Aug 2017 29th Aug 201 7 29th Aug 2017 29th Aug 201 7 Time Back line Oil- t 1.40 10.32 14.23 20.1 0 00.15 00.44 10.18 I I .47 Cause Summer shutdown Low levels alarm on the boiler feed tank Low levels alarm on the boiler feed tank Charging MTBE into PEPTCHA B-I 32-4 Transferring 199 from Reactor A I 0 to Reactor AI 1 LOBW-132- Transferring 199 from Reactor A I 0 to Reactor A1 1 LOBW-132- Level Sensor on the boiler Emptying Dual Scrubber as LEL’s were high Corrective action Put back on line Put back on line Put back on line Put back on line Put back on line Put back on line Put back on line Put back on line Emissions 300mg Org C at a rate of 65 m3hr-I = 0.01 95Kg Org Chr-I of TUC i.e.5.074875 kg for the duration. No ground level concentrations were exceeded with this mass emission. 21 55.1 rng Org C at a rate of 66.0m3hr-I= 0.1422366Kg Org Chr-I of TOC i.e.l.0003974 kg for the duration. No ground level concentrations were exceeded with this mass emission. 556.0mg Org C at a rate of 270.8m3hr-1= 0.1505648Kg Org Chr-I of TOC i.e.l.0112935 kg for the duration. No ground level concentrations were exceeded with this mass emission. 15445.5mg Org C at a rate of 90.3m3hr- 1 = 1.3947286Kg Org Chr-I of TOC i.e.l.3947286 kg for the duration. No ground level concentrations were exceeded with this mass emission. 8315.8rng Org C at a rate of 16.5m3hr-I= 0.1372107Kg Org Chr-I of TOC i.e.0.0297289 kg for the duration. No ground level concentrations were exceeded with this mass emission. 6459.9mg Org C at a rate of 14.8m3hr-1= 0.0956065Kg Org Chr-1 of TOC i.e.O.Ol75278kg for the duration. No ground level concentrations were exceeded with this mass emission. 3214.lmg Org C at a rate of 50.4m3hr-l= 0.1619906Kg Org Chr-I of TOC i.e.0.1403918 kg for the duration. No ground level concentrations were exceeded with this mass emission. 9695.1 mg Org C at a rate of 31.2m3hr-1= 0.3024871 Kg Org Chr-1 of TOC i.e.0.1058704 kg for the duration. No ground level concentrations were exceeded with this mass emission. For inspection purposes only. Consent of copyright owner required for any other use. EPA Export 11-12-2017:03:33:02

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Page 1: Cause of action · 2017. 12. 11. · action Put back on line Put back on line Put back on line Put back on line Put back on line Put back on line Put back on line Put back on line

g 28th July

11th A C 201 7

13th Aug 201 7

23th Aug 201 7

29th Aug

29th Aug 201 7

29th Aug 201 7

29th Aug 201 7

Time of

Trip

15.25

03.30

07.40

19.10

00.02

00.33

09.26

11.26

Date Back on

line

08th Aug 201 7

1 1 th Aug 201 7

13th Aug 2017

23th Aug 201 7

29th Aug 201 7

29th Aug 201 7

29th Aug 201 7

29th Aug 201 7

Time Back

line Oil-

t 1.40

10.32

14.23

20.1 0

00.15

00.44

10.1 8

I I .47

Cause

Summer shutdown

Low levels alarm on the boiler feed

tank

Low levels alarm on the boiler feed

tank

Charging MTBE into PEPTCHA B-I 32-4

Transferring

199 from Reactor A I 0 to Reactor

A I 1

LOBW-132-

Transferring

199 from Reactor A I 0 to Reactor

A1 1

LOBW-132-

Level Sensor on the boiler

Emptying Dual

Scrubber as LEL’s were

high

Corrective action

Put back on line

Put back on line

Put back on line

Put back on line

Put back on line

Put back on line

Put back on line

Put back on line

Emissions

300mg Org C at a rate of 65 m3hr-I = 0.01 95Kg Org Chr-I of TUC i.e.5.074875

kg for the duration. No ground level concentrations were exceeded with this mass emission.

21 55.1 rng Org C at a rate of 66.0m3hr-I= 0.1422366Kg Org Chr-I of TOC i.e.l.0003974 kg for the duration.

No ground level concentrations were exceeded with this mass emission.

556.0mg Org C at a rate of 270.8m3hr-1= 0.1505648Kg Org Chr-I of TOC i.e.l.0112935 kg for the duration.

No ground level concentrations were exceeded with this mass emission.

15445.5mg Org C at a rate of 90.3m3hr- 1 = 1.3947286Kg Org Chr-I of TOC i.e.l.3947286 kg for the duration.

No ground level concentrations were exceeded with this mass emission.

831 5.8rng Org C at a rate of 16.5m3hr-I = 0.1372107Kg Org Chr-I of TOC i.e.0.0297289 kg for the duration.

No ground level concentrations were exceeded with this mass emission.

6459.9mg Org C at a rate of 14.8m3hr-1= 0.0956065Kg Org Chr-1 of TOC i.e.O.Ol75278kg for the duration.

No ground level concentrations were exceeded with this mass emission.

3214.lmg Org C at a rate of 50.4m3hr-l= 0.1619906Kg Org Chr-I of TOC i.e.0.1403918 kg for the duration.

No ground level concentrations were exceeded with this mass emission.

9695.1 mg Org C at a rate of 31.2m3hr-1= 0.3024871 Kg Org Chr-1 of TOC i.e.0.1058704 kg for the duration.

No ground level concentrations were exceeded with this mass emission.

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 11-12-2017:03:33:02

Page 2: Cause of action · 2017. 12. 11. · action Put back on line Put back on line Put back on line Put back on line Put back on line Put back on line Put back on line Put back on line

DTO Shutdownsb3ypasses: Summary 2017 SAFC Arkluw Limited

Referpnce Date Of Trip Time Of TrL;tr Dare Back Time Back No On-line On-line

Duration of Bypass Cause W S I

~ _. ~~

2017084 11/08/2017 03:30:00 11/08/2017 10:32:00 7.03 Low levels alarm on the boiler feed tank

07:40:00 1 3/08/2017 14:23:00 6.72 Low levels alarm OR the boiler feed tank

2017086 23/08/2017 19: 1o:oo 23/08/2077 20: 1o:oo 1.00 Charging MTBE into PEPTCHA 8-132-4

00:02:00 29/08/2017 00:15:00 0.22 Transferring LOBW-132-199 from Reactor A10 to Reactor A1 1

2017088 29/08/2017 00:33:00 29/08/2017 0044:OO 0.18 Transferring LOBW-132-199 from Reactor A10 to Reactor A l l

2017089 29/08/2017 09:26:00 29/08/2017 10: 18:OO 0.87 Level Sensor on the boiler

11 :26:00 29/08/2017 11:47:00 0.35 Emptying Dual Scrubber as LECa were high

15:34:00 29/08/2017 15:43:00 0.15 Vaccing down A10 Vessel containing MTSE

31 Augm 201 7

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 11-12-2017:03:33:02

Page 3: Cause of action · 2017. 12. 11. · action Put back on line Put back on line Put back on line Put back on line Put back on line Put back on line Put back on line Put back on line

DTO ShutdowndBypasses Sigma Aldrich Ireland Ltd License Reg No P-0089-5

Date Of Trip T h e Of Trip Date Back On-line

T h e Back Duration of Bypass On-line (Hrsl

11 /08/2017

13/08/2017

23/08/2017

29/08/2017

29/08/2017

29/08/2017

29/08/2017

29/06/2017

03:30:00

07:40:00

19: 1o:oo

00:02:00

00:33:00

09:26:00

1 1 :26:00

15:34:00

11/08/2017

13/08/2017

23/08/2017

29/08/20 1 7

29/08/2017

2910a/2017

29/08/2017

29/08/20 1 7

10:32:00

14:23:00

20:10:00

00: 1500

00:44:00

I O : 18:OO

11 :47:00

15:43:00

Total:

7.03

6.72

1 .oo 0.22

0.18

0.87

0.35

0.15

16.52

31 August 2017 Page 1 of I

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 11-12-2017:03:33:02

Page 4: Cause of action · 2017. 12. 11. · action Put back on line Put back on line Put back on line Put back on line Put back on line Put back on line Put back on line Put back on line

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 11-12-2017:03:33:02