Brominated Flame Retardant Standards · 2008. 9. 29. · Cambridge Isotope Laboratories, Inc. Brominated Flame Retardant Standards Catalog 02 Polybrominated Diphenyl Ether Technical

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Brominated FlameRetardant Standards

Cambridge Isotope Laboratories, Inc.

Brominated Flame Retardant Standards Catalog

02

Polybrominated Diphenyl Ether Technical Mix Standards

Catalog# Description Concentration/Solvent Amount

EO-4958-1.2 Bromkal 70-5 Diphenyl Ether Technical Mix (unlabeled) 50 µg/mL in methanol 1.2 mLEO-5031 DE-71 PentaBDE Technical Mix (unlabeled) 50 µg/mL in methanol 1.2 mLEO-5030 DE-79 OctaBDE Technical Mix (unlabeled) 50 µg/mL in methanol 1.2 mLEO-5060 DecaBDE Technical Mix (Saytex 102E) 10 µg/mL in methanol 10 mL *Neat quantities of PBDE Technical mixtures may be available, please inquire

Individual Brominated and Chlorinated Flame Retardant StandardsCatalog# Description Concentration/Solvent Amount

CLM-4694-1.2 Tetrabromobisphenol-A (ring-13C12, 99%) 50 µg/mL in methanol 1.2 mLULM-4694-1.2 Tetrabromobisphenol-A (unlabeled) 50 µg/mL in methanol 1.2 mLULM-6236-1.2 Dimethyl Tetrabromobisphenol-A (unlabeled) 50 µg/mL in nonane 1.2 mLCLM-7922-1.2 α-Hexabromocyclododecane (13C12,99%) 50 µg/mL in toluene 1.2 mLULM-4834-1.2 α-Hexabromocyclododecane (unlabeled) 50 µg/mL in toluene 1.2 mLCLM-7923-1.2 β-Hexabromocyclododecane (13C12,99%) 50 µg/mL in toluene 1.2 mLULM-4835-1.2 β-Hexabromocyclododecane (unlabeled) 50 µg/mL in toluene 1.2 mLCLM-7924-1.2 γ-Hexabromocyclododecane (13C12,99%) 50 µg/mL in toluene 1.2 mLULM-4836-1.2 γ-Hexabromocyclododecane (unlabeled) 50 µg/mL in toluene 1.2 mLULM-7375-2X1.2 1,2-bis(pentabromophenyl)ethane (unlabeled; chemical purity 96%) (DBDPE) 25 µg/mL in toluene 2 x 1.2 mLULM-7595-1.2 1,2-bis(2,4,6-tribromophenoxy)ethane (unlabeled) (BTBPE) 50 µg/mL in nonane 1.2 mLCLM-1921-1.2 Hexabromobenzene (13C6,99%) 100 µg/mL in toluene 1.2 mLULM-7607-1.2 Hexabromobenzene (unlabeled) 100 µg/mL in toluene 1.2 mLCLM-8006-1.2 Tetrachlorobisphenol-A (ring-13C12,99%) 50 µg/mL in methanol 1.2 mLULM-7606-1.2 Tetrachlorobisphenol-A (unlabeled) 50 µg/mL in methanol 1.2 mLULM-7777-1.2 Dechlorane Plus® Technical Product unlabeled 100 µg/mL in nonane 1.2 mLULM-7886-1.2 Dechlorane Plus® Syn Isomer (unlabeled) 50 µg/mL in nonane 1.2 mLULM-7887-1.2 Dechlorane Plus® Anti Isomer (unlabeled) 50 µg/mL in nonane 1.2 mL

Individual 13C-labeled Polybrominated Diphenyl Ether (PBDE) Standards


EO-4999 4-MonoBDE (13C12,99%) (BDE-3) 50 µg/mL in nonane 1.2 mLEO-5001 4,4’-DiBDE (13C12,99%) (BDE-15) 50 µg/mL in nonane 1.2 mLEO-5002 2,4,4’-TriBDE (13C12,99%) (BDE-28) 50 µg/mL in nonane 1.2 mLEO-4982 2,2’,4,4’-TetraBDE (13C12,99%) (BDE-47) 50 µg/mL in nonane 1.2 mLEO-1439 3,3’,4,4’-TetraBDE (13C12,99%) (BDE-77) 50 µg/mL in nonane 1.2 mLEO-4983 2,2’,4,4’,5-PentaBDE (13C12,99%) (BDE-99) 50 µg/mL in nonane 1.2 mLEO-4993 2,2’,4,4’,6-PentaBDE (13C12,99%) (BDE-100) 50 µg/mL in nonane 1.2 mLEO-5034 2,3’,4,4’,5-PentaBDE (13C12,99%) (BDE-118) 50 µg/mL in nonane 1.2 mLEO-4930 3,3’,4,4’,5-PentaBDE (13C12,99%) (BDE-126) 50 µg/mL in nonane 1.2 mLEO-5035 2,2’,3,4,4’,5’-HexaBDE (13C12,99%) (BDE-138) 50 µg/mL in nonane 1.2 mLEO-5165 2,2’,3,4,4’,6-HexaBDE (13C12,99%) (BDE-139) 50 µg/mL in nonane 1.2 mLEO-4984 2,2’,4,4’,5,5’-HexaBDE (13C12,99%) (BDE-153) 50 µg/mL in nonane 1.2 mLEO-5161 2,2’,4,4’,5,6’-HexaBDE (13C12,99%) (BDE-154) 50 µg/mL in nonane 1.2 mLEO-4985 2,2’,3,4,4’,5’,6-HeptaBDE (13C12,99%) (BDE-183) 50 µg/mL in nonane 1.2 mLEO-5355 2,2’,3,4,4’,5,6,6’-OctaBDE (13C12,99%) (BDE-204) 50 µg/mL in nonane 1.2 mLEO-5362 2,3,3’,4,4’,5,5’,6-OctaBDE (13C12,99%) (BDE-205) 50 µg/mL in nonane 1.2 mLEO-5240 2,2’,3,3’,4,4’,5,5’,6-NonaBDE (13C12,99%)(BDE-206) 50 µg/mL in nonane 1.2 mLEO-5241 2,2’,3,3’,4,4’,5,6,6’-NonaBDE (13C12,99%) (BDE-207) 50 µg/mL in nonane 1.2 mLEO-5242 2,2’,3,3’,4,5,5’,6,6’-NonaBDE (13C12,99%) (BDE-208) 50 µg/mL in nonane 1.2 mLEO-5003 Decabromodiphenyl ether (13C12,99%) (BDE-209) 50 µg/mL in nonane 1.2 mL

Multiple unit pricing for individual 13C- PBDE Standards: 2-3 units = 20%; 4 or more units = 33% 01

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Individual Unlabeled Polybrominated Diphenyl Ether (PBDE) Certified StandardsCatalog# Description Concentration/Solvent Amount

BDE-1-CS 2-MonoBDE (unlabeled Certified Standard) (BDE-1) 50 µg/mL in nonane 1.2 mLBDE-2-CS 3-MonoBDE (unlabeled Certified Standard) (BDE-2) 50 µg/mL in nonane 1.2 mLBDE-3-CS 4-MonoBDE (unlabeled Certified Standard) (BDE-3) 50 µg/mL in nonane 1.2 mLBDE-7-CS 2,4-DiBDE (unlabeled Certified Standard) (BDE-7) 50 µg/mL in nonane 1.2 mLBDE-8-CS 2,4’-DiBDE (unlabeled Certified Standard) (BDE-8) 50 µg/mL in nonane 1.2 mLBDE-10-CS 2,6-DiBDE (unlabeled Certified Standard) (BDE-10) 50 µg/mL in nonane 1.2 mLBDE-11-CS 3,3’-DiBDE (unlabeled Certified Standard) (BDE-11) 50 µg/mL in nonane 1.2 mLBDE-12-CS 3,4-DiBDE (unlabeled Certified Standard) (BDE-12) 50 µg/mL in nonane 1.2 mLBDE-13-CS 3,4’-DiBDE (unlabeled Certified Standard) (BDE-13) 50 µg/mL in nonane 1.2 mLBDE-15-CS 4,4’-DiBDE (unlabeled Certified Standard) (BDE-15) 50 µg/mL in nonane 1.2 mLBDE-17-CS 2,2’,4-TriBDE (unlabeled Certified Standard) (BDE-17) 50 µg/mL in nonane 1.2 mLBDE-25-CS 2,3’,4-TriBDE (unlabeled Certified Standard) (BDE-25) 50 µg/mL in nonane 1.2 mLBDE-28-CS 2,4,4’-TriBDE (unlabeled Certified Standard) (BDE-28) 50 µg/mL in nonane 1.2 mLBDE-30-CS 2,4,6-TriBDE (unlabeled Certified Standard) (BDE-30) 50 µg/mL in nonane 1.2 mLBDE-32-CS 2,4’,6-TriBDE (unlabeled Certified Standard) (BDE-32) 50 µg/mL in nonane 1.2 mLBDE-33-CS 2’,3,4-TriBDE (unlabeled Certified Standard) (BDE-33) 50 µg/mL in nonane 1.2 mLBDE-35-CS 3,3’,4-TriBDE (unlabeled Certified Standard) (BDE-35) 50 µg/mL in nonane 1.2 mLBDE-37-CS 3,4,4’-TriBDE (unlabeled Certified Standard) (BDE-37) 50 µg/mL in nonane 1.2 mLBDE-47-CS 2,2’,4,4’-TetraBDE (unlabeled Certified Standard) (BDE-47) 50 µg/mL in nonane 1.2 mLBDE-49-CS 2,2’,4,5’-TetraBDE (unlabeled Certified Standard) (BDE-49) 50 µg/mL in nonane 1.2 mLBDE-51-CS 2,2’,4,6’-TetraBDE (unlabeled Certified Standard) (BDE-51) 50 µg/mL in nonane 1.2 mLBDE-66-CS 2,3’,4,4’-TetraBDE (unlabeled Certified Standard) (BDE-66) 50 µg/mL in nonane 1.2 mLBDE-71-CS 2,3’,4’,6-TetraBDE (unlabeled Certified Standard) (BDE-71) 50 µg/mL in nonane 1.2 mLBDE-75-CS 2,4,4’,6-TetraBDE (unlabeled Certified Standard) (BDE-75) 50 µg/mL in nonane 1.2 mLBDE-77-CS 3,3’,4,4’-TetraBDE (unlabeled Certified Standard) (BDE-77) 50 µg/mL in nonane 1.2 mLBDE-79-CS 3,3’,4,5’-TetraBDE (unlabeled Certified Standard) (BDE-79) 50 µg/mL in nonane 1.2 mLBDE-85-CS 2,2’,3,4,4’-PentaBDE (unlabeled Certified Standard) (BDE-85) 50 µg/mL in nonane 1.2 mLBDE-99-CS 2,2’,4,4’,5-PentaBDE (unlabeled Certified Standard) (BDE-99) 50 µg/mL in nonane 1.2 mLBDE-100-CS 2,2’,4,4’,6-PentaBDE (unlabeled Certified Standard) (BDE-100) 50 µg/mL in nonane 1.2 mLBDE-105-CS 2,3,3’,4,4’-PentaBDE (unlabeled Certified Standard) (BDE-105) 50 µg/mL in nonane 1.2 mL BDE-116-CS 2,3,4,5,6-PentaBDE (unlabeled Certified Standard) (BDE-116) 50 µg/mL in nonane 1.2 mLBDE-118-CS 2,3’,4,4’,5-PentaBDE (unlabeled Certified Standard) (BDE-118) 50 µg/mL in nonane 1.2 mLBDE-119-CS 2,3’,4,4’,6-PentaBDE (unlabeled Certified Standard) (BDE-119) 50 µg/mL in nonane 1.2 mLBDE-120-CS 2,3’,4,5,5’-PentaBDE (unlabeled Certified Standard) (BDE-120) 50 µg/mL in nonane 1.2 mL BDE-126-CS 3,3’,4,4’,5-PentaBDE (unlabeled Certified Standard) (BDE-126) 50 µg/mL in nonane 1.2 mLBDE-128-CS 2,2’,3,3’,4,4’-HexaBDE (unlabeled Certified Standard) (BDE-128) 50 µg/mL in nonane 1.2 mLBDE-138-CS 2,2’,3,4,4’,5’-HexaBDE (unlabeled Certified Standard) (BDE-138) 50 µg/mL in nonane 1.2 mLBDE-139-CS 2,2’,3,4,4’,6-HexaBDE (unlabeled Certified Standard) (BDE-139) 50 µg/mL in nonane 1.2 mL BDE-140-CS 2,2’,3,4,4’,6’-HexaBDE (unlabeled Certified Standard) (BDE-140) 50 µg/mL in nonane 1.2 mLBDE-153-CS 2,2’,4,4’,5,5’-HexaBDE (unlabeled Certified Standard) (BDE-153) 50 µg/mL in nonane 1.2 mLBDE-154-CS 2,2’,4,4’,5,6’-HexaBDE (unlabeled Certified Standard) (BDE-154) 50 µg/mL in nonane 1.2 mLBDE-155-CS 2,2’,4,4’,6,6’-HexaBDE (unlabeled Certified Standard) (BDE-155) 50 µg/mL in nonane 1.2 mLBDE-166-CS 2,3,4,4’,5,6-HexaBDE (unlabeled Certified Standard) (BDE-166) 50 µg/mL in nonane 1.2 mLBDE-181-CS 2,2’,3,4,4’,5,6-HeptaBDE (unlabeled Certified Standard) (BDE-181) 50 µg/mL in nonane 1.2 mLBDE-183-CS 2,2’,3,4,4’,5’,6-HeptaBDE (unlabeled Certified Standard) (BDE-183) 50 µg/mL in nonane 1.2 mLBDE-190-CS 2,3,3’,4,4’,5,6-HeptaBDE (unlabeled Certified Standard) (BDE-190) 50 µg/mL in nonane 1.2 mLBDE-203-CS 2,2’,3,4,4’,5,5’,6-OctaBDE (unlabeled Certified Standard) (BDE-203) 50 µg/mL in nonane 1.2 mLBDE-204-CS 2,2’,3,4,4’,5,6,6’-OctaBDE (unlabeled Certified Standard) (BDE-204) 50 µg/mL in nonane 1.2 mLBDE-205-CS 2,3,3’,4,4’,5,5’,6-OctaBDE (unlabeled Certified Standard) (BDE-205) 50 µg/mL in nonane 1.2 mLBDE-206-CS 2,2’,3,3’,4,4’,5,5’,6-NonaBDE (unlabeled Certified Standard) (BDE-206) 50 µg/mL in nonane 1.2 mLBDE-207-CS 2,2’,3,3’,4,4’,5,6,6’-NonaBDE (unlabeled Certified Standard) (BDE-207) 50 µg/mL in nonane 1.2 mLBDE-208-CS 2,2’,3,3’,4,5,5’,6,6’-NonaBDE (unlabeled Certified Standard) (BDE-208) 50 µg/mL in nonane 1.2 mLBDE-209-CS DecaBDE (unlabeled Certified Standard) (BDE-209) 50 µg/mL in nonane 1.2 mL

Multiple unit pricing for individual PBDE unlabeled Certified Standards: 5-7 units = 20%; 8-11 units = 33%; 12 or more units = 50% 02



04

PBDE Metabolite Standards 13C-labeled Hydroxylated Brominated Diphenyl Ethers


OHBDE-5190-1.2 6-Hydroxy-2,2’,4,4’-TetraBDE (ring-13C12, 99%) (92%+ pure) 50 µg/mL in toluene 1.2 mLOHBDE-5191-1.2 2-Hydroxy-2’,4,4’,5’,6-PentaBDE (ring-13C12, 99%) (94% pure) 50 µg/mL in toluene 1.2 mL

Unlabeled Hydroxylated Brominated Diphenyl Ethers


OHBDE-5206-1.2 6-Hydroxy-2,2’,4,4’-TetraBDE (unlabeled) 50 µg/mL in nonane 1.2 mLOHBDE-5212-1.2 4’-Hydroxy-2,2’,4,5’-TetraBDE (unlabeled) 50 µg/mL in nonane 1.2 mLOHBDE-5214-1.2 6’-Hydroxy-2,2’,4,5’-TetraBDE (unlabeled) 50 µg/mL in nonane 1.2 mLOHBDE-5228-1.2 6-Hydroxy-2,2’,4,4’,5-PentaBDE (unlabeled) 50 µg/mL in nonane 1.2 mL

Unlabeled Methoxylated Brominated Diphenyl Ethers


MEOBDE-5153-1.2 2’-Methoxy-2,3’,4,5’-TetraBDE (unlabeled) 50 µg/mL in nonane 1.2 mLMEOBDE-5205-1.2 6-Methoxy-2,2’,4,4’-TetraBDE (unlabeled) 50 µg/mL in nonane 1.2 mL

Individual Polybrominated Biphenyl (PBB) StandardsCatalog# Description Concentration/Solvent Amount

EB-5055 3,3’,4,4’-TetraBB (13C12,99%) (PBB-77) 40 µg/mL in nonane 3 mLPBB-77-CS 3,3’,4,4’-TetraBB (unlabeled Certified Standard) (PBB-77) 100 µg/mL in isooctane 1.2 mL EB-5056 3,3’,4,4’,5-PentaBB (13C12,99%) (PBB-126) 40 µg/mL in nonane 3 mL PBB-126-CS 3,3’,4,4’,5-PentaBB (unlabeled Certified Standard) (PBB-126) 100 µg/mL in isooctane 1.2 mLPBB-153-CS 2,2’,4,4’,5,5’-HexaBB (unlabeled Certified Standard) (PBB-153) 100 µg/mL isooctane 1.2 mLEB-5106 2’,3,3’,4,4’,5-HexaBB (13C12,99%) (PBB-157) 40 µg/mL in nonane 3 mLPBB-157-CS 2’,3,3’,4,4’,5-HexaBB (unlabeled Certified Standard) (PBB-157) 100µg/mL in isooctane 1.2 mL* New PBB standards may become available, please inquire

Soil, Sediment and Fish Reference Materials (RMs) with BFR valuesCIL is currently involved in several projects to provide reference materials for the analysis of Brominated Flame Retardants.The first Interlaboratory study for PBDEs was organized by the Bromine and Science Environmental Forum (BSEF) in 1999. Subsequently, CIL has conducted several Interlaboratory Studies for PBDEs using our sediment, soil, and fish tissue reference materials. Over sixty government, academic, and commercial laboratories have participated in these studies, establishing Consensus Values for predominant PBDEs, Tetrabromobisphenol A and dimethyl TBBPA, α-, β-, and γ-Hexabromocyclododecane and PBBs in the following reference materials:

Catalog # Description Amount

EDF-5183 Natural Matrix Reference Material (soil) 2003 10 g EDF-5184 Heavily Contaminated Sediment Reference Material 10 g EDF-2524 Clean Natural Matrix Reference Material (fish) 10 g EDF-2525 Contaminated Natural Matrix Reference Material (fish) 10 g EDF-2526 Fortified Natural Matrix Reference Material (fish) 10 g

Polybrominated Dioxin and Furan Standards and Standard MixturesCIL maintains an extensive range of Polybrominated Dioxin and Furan (PBDD/F) and mixed Brominated/Chlorinated dioxin and furan standards and standard mixtures. Please refer to our product flyer on isotope.com (or contact us for a printed copy) to see a comprehensive listing of our PBDD/F analytical standards.

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Standard Mixtures for US EPA Method 1614EO-5279 Method 1614 Calibration Solutions [CS1 - CS5] 5 x 0.2 mL in nonane Concentration (ng/mL)

Unlabeled Congeners Congener# CS1 CS2 CS3 CS4 CS5 2,4,4’-TriBDE 28 1 5 50 500 2500 2,2’,4,4’-TetraBDE 47 1 5 50 500 2500 2,2’,4,4’,5-PentaBDE 99 1 5 50 500 2500 2,2’,4,4’,6-PentaBDE 100 1 5 50 500 2500 2,2’,4,4’,5,5’-HexaBDE 153 1 5 50 500 2500 2,2’,4,4’,5,6’-HexaBDE 154 1 5 50 500 2500 2,2’,3,4,4’,5’,6-HeptaBDE 183 1 5 50 500 2500 DecaBDE 209 10 50 500 5000 25000 Labeled Congeners 2,4,4’-TriBDE (13C12,99%) 28L 100 100 100 100 100 2,2’,4,4’-TetraBDE (13C12,99%) 47L 100 100 100 100 100 2,2’,4,4’,5-PentaBDE (13C12,99%) 99L 100 100 100 100 100 2,2’,4,4’,6-PentaBDE (13C12,99%) 100L 100 100 100 100 100 2,2’,4,4’,5,5’-HexaBDE (13C12,99%) 153L 100 100 100 100 100 2,2’,4,4’,5,6’-HexaBDE (13C12,99%) 154L 100 100 100 100 100 2,2’,3,4,4’,5’,6-HeptaBDE (13C12,99%) 183L 100 100 100 100 100 DecaBDE (13C12,99%) 209L 1000 1000 1000 1000 1000 Labeled Clean-up 2,2’,3,4,4’,6-HexaBDE (13C12,99%) 139L 100 100 100 100 100 Labeled Injection Internal 2,2’,5,5’-TetraCB (13C12,99%) PCB-52L 100 100 100 100 100 2,2’,3,4,4’,5’-HexaCB (13C12,99%) PCB-138L 100 100 100 100 100

EO-5277 Method 1614 Labeled Surrogate Stock Solution (13C12) 1.2 mL in nonaneLabeled Congeners Congener# Concentration (µg/mL) 2,4,4’-TriBDE (13C12,99%) 28L 1 2,2’,4,4’-TetraBDE (13C12,99%) 47L 1 2,2’,4,4’,5-PentaBDE (13C12,99%) 99L 1 2,2’,4,4’,6-PentaBDE (13C12,99%) 100L 1 2,2’,4,4’,5,5’-HexaBDE (13C12,99%) 153L 1 2,2’,4,4’,5,6’-HexaBDE (13C12,99%) 154L 1 2,2’,3,4,4’,5’,6-HeptaBDE (13C12,99%) 183L 1 DecaBDE (13C12,99%) 209L 10

EO-5276 Method 1614 Labeled Clean-Up Stock Solution (13C12) 1.2 mL in nonaneLabeled Congeners Congener# Concentration (µg/mL) 2,2’,3,4,4’,6-HexaBDE (13C12,99%) 139L 1 EO-5275 Method 1614 Labeled Injection Internal Stock Solution (13C12)1.2 mL in nonaneLabeled Congeners Congener# Concentration (µg/mL) 2,2’,5,5’-TetraCB (13C12,99%) PCB-52L 5 2,2’,3,4,4’,5’-HexaCB (13C12,99%) PCB-138L 5

EO-5278 Method 1614 Native PAR Stock Solution (Unlabeled) 1.2 mL in nonaneUnlabeled Congeners Congener# Concentration (µg/mL) 2,4,4’-TriBDE 28 1 2,2’,4,4’-TetraBDE 47 12,2’,4,4’,5-PentaBDE 99 1 2,2’,4,4’,6-PentaBDE 100 1 2,2’,4,4’,5,5’-HexaBDE 153 1 2,2’,4,4’,5,6’-HexaBDE 154 1 2,2’,3,4,4’,5’,6-HeptaBDE 183 1 DecaBDE 209 10

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PBDE Calibration Solutions and Standard Mixtures

EO-5104 Polybrominated Diphenyl Ether Calibration Solutions [CS1-CS6] 6 x 0.2 mL in nonane

Concentration (ng/mL)

Unlabeled Congeners Congener# CS1 CS2 CS3 CS4 CS5 CS6 2-MonoBDE 1 0.2 1 5 25 100 500 3-MonoBDE 2 0.2 1 5 25 100 5004-MonoBDE 3 0.2 1 5 25 100 5002,4-DiBDE 7 0.2 1 5 25 100 5002,4’-DiBDE 8 0.2 1 5 25 100 5002,6-DiBDE 10 0.2 1 5 25 100 5003,3’-DiBDE 11 0.2 1 5 25 100 5003,4-DiBDE 12 0.2 1 5 25 100 5003,4’-DiBDE 13 0.2 1 5 25 100 5004,4’-DiBDE 15 0.2 1 5 25 100 5002,2’,4-TriBDE 17 0.2 1 5 25 100 5002,3’,4-TriBDE 25 0.2 1 5 25 100 5002,4,4’-TriBDE 28 0.2 1 5 25 100 5002,4,6-TriBDE 30 0.2 1 5 25 100 500 2,4’,6-TriBDE 32 0.2 1 5 25 100 5002’,3,4-TriBDE 33 0.2 1 5 25 100 5003,3’,4-TriBDE 35 0.2 1 5 25 100 500 3,4,4’-TriBDE 37 0.2 1 5 25 100 500 2,2’,4,4’-TetraBDE 47 0.2 1 5 25 100 5002,2’,4,5’-TetraBDE 49 0.2 1 5 25 100 5002,3’,4,4’-TetraBDE 66 0.2 1 5 25 100 500 2,3’,4’,6-TetraBDE 71 0.2 1 5 25 100 5002,4,4’,6-TetraBDE 75 0.2 1 5 25 100 5003,3’,4,4’-TetraBDE 77 0.2 1 5 25 100 500 2,2’,3,4,4’-PentaBDE 85 0.3 1.5 7.5 37.5 150 750 2,2’,4,4’,5-PentaBDE 99 0.3 1.5 7.5 37.5 150 750 2,2’,4,4’,6-PentaBDE 100 0.3 1.5 7.5 37.5 150 7502,3,4,5,6-PentaBDE 116 0.3 1.5 7.5 37.5 150 750 2,3’,4,4’,5-PentaBDE 118 0.3 1.5 7.5 37.5 150 750 2,3’,4,4’,6-PentaBDE 119 0.3 1.5 7.5 37.5 150 750 3,3’,4,4’,5-PentaBDE 126 0.3 1.5 7.5 37.5 150 750 2,2’,3,4,4’,5’-HexaBDE 138 0.6 3 15 75 300 1500 2,2’,4,4’,5,5’-HexaBDE 153 0.4 2 10 50 200 1000 2,2’,4,4’,5,6’-HexaBDE 154 0.4 2 10 50 200 1000 2,2’,4,4’,6,6’-HexaBDE 155 0.4 2 10 50 200 1000 2,3,4,4’,5,6-HexaBDE 166 0.4 2 10 50 200 1000 2,2’,3,4,4’,5,6-HeptaBDE 181 0.5 2.5 12.5 62.5 250 1250 2,2’,3,4,4’,5’,6-HeptaBDE 183 0.5 2.5 12.5 62.5 250 1250 2,3,3’,4,4’,5,6-HeptaBDE 190 0.5 2.5 12.5 62.5 250 1250 Labeled Congeners 4-MonoBDE (13C12,99%) 3L 100 100 100 100 100 100 4,4’-DiBDE (13C12,99%) 15L 100 100 100 100 100 100 2,4,4’-TriBDE (13C12,99%) 28L 100 100 100 100 100 100 2,2’,4,4’-TetraBDE (13C12,99%) 47L 100 100 100 100 100 100 3,3’,4,4’-TetraBDE (13C12,99%) 77L 100 100 100 100 100 100 2,2’,4,4’,5-PentaBDE (13C12,99%) 99L 150 150 150 150 150 150 2,2’,4,4’,6-PentaBDE (13C12,99%) 100L 150 150 150 150 150 150 2,3’,4,4’,5-PentaBDE (13C12,99%) 118L 150 150 150 150 150 150 3,3’,4,4’,5-PentaBDE (13C12,99%) 126L 150 150 150 150 150 150 2,2’,4,4’,5,5’-HexaBDE (13C12,99%) 153L 200 200 200 200 200 200 2,2’,3,4,4’,5’,6-HeptaBDE (13C12,99%) 183L 250 250 250 250 250 250

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EO-5099 Polybrominated Diphenyl Ether Analytical Standard Solution (Unlabeled/13C12) 1.2 mL in nonaneUnlabeled Congeners (BDE#) Concentration (ng/mL) Unlabeled Congeners (BDE#) Concentration ng/mL)

2-MonoBDE(BDE-1) 100 2,3’,4,4’-TetraBDE (BDE-66) 100 3-MonoBDE (BDE-2) 100 2,3’,4’,6-TetraBDE (BDE-71) 100 4-MonoBDE (BDE-3) 100 2,4,4’,6-TetraBDE (BDE-75) 100 2,4-DiBDE (BDE-7) 100 3,3’,4,4’-TetraBDE (BDE-77) 100 2,4’-DiBDE (BDE-8) 100 2,2’,3,4,4’-PentaBDE (BDE-85) 150 2,6-DiBDE (BDE-10) 100 2,2’,4,4’,5-PentaBDE (BDE-99) 150 3,3’-DiBDE (BDE-11) 100 2,2’,4,4’,6-PentaBDE (BDE-100) 150 3,4-DiBDE (BDE-12) 100 2,3,4,5,6-PentaBDE (BDE-116) 150 3,4’-DiBDE (BDE-13) 100 2,3’,4,4’,5-PentaBDE (BDE-118) 150 4,4’-DiBDE (BDE-15) 100 2,3’,4,4’,6-PentaBDE (BDE-119) 150 2,2’,4-TriBDE (BDE-17) 100 3,3’,4,4’,5-PentaBDE (BDE-126) 150 2,3’,4-TriBDE (BDE-25) 100 2,2’,3,4,4’,5’-HexaBDE (BDE-138) 300 2,4,4’-TriBDE (BDE-28) 100 2,2’,4,4’,5,5’-HexaBDE (BDE-153) 200 2,4,6-TriBDE (BDE-30) 100 2,2’,4,4’,5,6’-HexaBDE (BDE-154) 200 2,4’,6-TriBDE (BDE-32) 100 2,2’,4,4’,6,6’-HexaBDE (BDE-155) 200 2’,3,4-TriBDE (BDE-33) 100 2,3,4,4’,5,6-HexaBDE (BDE-166) 200 3,3’,4-TriBDE (BDE-35) 100 2,2’,3,4,4’,5,6-HeptaBDE (BDE-181) 250 3,4,4’-TriBDE (BDE-37) 100 2,2’,3,4,4’,5’,6-HeptaBDE (BDE-183) 250 2,2’,4,4’-TetraBDE (BDE-47) 100 2,3,3’,4,4’,5,6-HeptaBDE (BDE-190) 250 2,2’,4,5’-TetraBDE (BDE-49) 100 Labeled Congeners (BDE#) Concentration (ng/mL) Labeled Congeners (BDE#) Concentration (ng/mL)

4-MonoBDE (13C12,99%) (BDE-3) 100 2,2’,4,4’,6-PentaBDE (13C12,99%) (BDE-100) 150 4,4’-DiBDE (13C12,99%) (BDE-15) 100 2,3’,4,4’,5-PentaBDE (13C12,99%) (BDE-118) 150 2,4,4’-TriBDE (13C12,99%) (BDE-28) 100 3,3’,4,4’,5-PentaBDE (13C12,99%) (BDE-126) 150 2,2’,4,4’-TetraBDE (13C12,99%) (BDE-47) 100 2,2’,4,4’,5,5’-HexaBDE (13C12,99%) (BDE-153) 200 3,3’,4,4’-TetraBDE (13C12,99%) (BDE-77) 100 2,2’,3,4,4’,5’,6-HeptaBDE (13C12,99%) (BDE-183)250 2,2’,4,4’,5-PentaBDE (13C12,99%) (BDE-99) 150

EO-5100 Polybrominated Diphenyl Ether Surrogate Spiking Solution (13C12) 1.2 mL in nonane

Labeled Congeners (BDE#) Concentration (ng/mL) Labeled Congeners (BDE#) Concentration (ng/mL)

4-MonoBDE (13C12,99%) (BDE-3) 100 2,2’,4,4’,6-PentaBDE (13C12,99%) (BDE-100) 150 4,4’-DiBDE (13C12,99%) (BDE-15) 100 2,3’,4,4’,5-PentaBDE (13C12,99%) (BDE-118) 150 2,4,4’-TriBDE (13C12,99%) (BDE-28) 100 2,2’,4,4’,5,5’-HexaBDE (13C12,99%) (BDE-153) 200 2,2’,4,4’-TetraBDE (13C12,99%) (BDE-47) 100 2,2’,3,4,4’,5’,6-HeptaBDE (13C12,99%) (BDE-183)250 2,2’,4,4’,5-PentaBDE (13C12,99%) (BDE-99) 150 EO-5100-10X-0.5 Polybrominated Diphenyl Ether Surrogate Spiking Stock Solution (13C12) 0.5 mL in nonane

(10X Concentration of Congeners in EO-5100)

EO-5101 Polybrominated Diphenyl Ether Performance Standard Solution (13C12) 1.2 mL in nonane

Labeled Congeners (BDE#) Concentration (ng/mL)

3,3’,4,4’-TetraBDE (13C12,99%) (BDE-77) 1003,3’,4,4’,5-PentaBDE (13C12,99%) (BDE-126) 150

EO-5101-10X-1.2 Polybrominated Diphenyl Ether Performance Standard Stock solution (13C12) 1.2 mL in nonane (10X Concentration of Congeners in EO-5101)

EO-5103 Polybrominated Diphenyl Ether Predominant Congener Mixture (Unlabeled) 1.2 mL in nonane

Unlabeled Congeners (BDE#) Concentration (ng/mL) Unlabeled Congeners (BDE#) Concentration (ng/mL)

2,2’,4-TriBDE (BDE-17) 2.5 2,2’,4,4’,6-PentaBDE (BDE-100) 2.5 2,4,4’-TriBDE (BDE-28) 2.5 2,2’,3,4,4’,5’-HexaBDE (BDE-138) 3.75 2,2’,4,4’-TetraBDE (BDE-47) 2.5 2,2’,4,4’,5,5’-HexaBDE (BDE-153) 2.5 2,3’,4,4’-TetraBDE (BDE-66) 2.5 2,2’,4,4’,5,6’-HexaBDE (BDE-154) 2.52,3’,4’,6-TetraBDE (BDE-71) 2.5 2,2’,3,4,4’,5’,6-HeptaBDE (BDE-183) 2.5 2,2’,3,4,4’-PentaBDE (BDE-85) 2.5 2,3,3’,4,4’,5,6-HeptaBDE (BDE-190) 2.5 2,2’,4,4’,5-PentaBDE (BDE-99) 2.5 DecaBDE (BDE-209) 10

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EO-5113 Polybrominated Diphenyl Ether PAR Standard Solution (Unlabeled) 0.5 mL in nonane

Unlabeled Congeners (BDE#) Concentration (ng/mL) Unlabeled Congeners (BDE#) Concentration (ng/mL)

2-MonoBDE (BDE-1) 100 2,3’,4,4’-TetraBDE (BDE-66) 100 3-MonoBDE (BDE-2) 100 2,3’,4’,6-TetraBDE (BDE-71) 100 4-MonoBDE (BDE-3) 100 2,4,4’,6-TetraBDE (BDE-75) 100 2,4-DiBDE (BDE-7) 100 3,3’,4,4’-TetraBDE (BDE-77) 100 2,4’-DiBDE (BDE-8) 100 2,2’,3,4,4’-PentaBDE (BDE-85) 150 2,6-DiBDE (BDE-10) 100 2,2’,4,4’,5-PentaBDE (BDE-99) 150 3,3’-DiBDE (BDE-11) 100 2,2’,4,4’,6-PentaBDE (BDE-100) 150 3,4-DiBDE (BDE-12) 100 2,3,4,5,6-PentaBDE (BDE-116) 150 3,4’-DiBDE (BDE-13) 100 2,3’,4,4’,5-PentaBDE (BDE-118) 150 4,4’-DiBDE (BDE-15) 100 2,3’,4,4’,6-PentaBDE (BDE-119) 150 2,2’,4-TriBDE (BDE-17) 100 3,3’,4,4’,5-PentaBDE (BDE-126) 150 2,3’,4-TriBDE (BDE-25) 100 2,2’,3,4,4’,5’-HexaBDE (BDE-138) 300 2,4,4’-TriBDE (BDE-28) 100 2,2’,4,4’,5,5’-HexaBDE (BDE-153) 200 2,4,6-TriBDE (BDE-30) 100 2,2’,4,4’,5,6’-HexaBDE (BDE-154) 200 2,4’,6-TriBDE (BDE-32) 100 2,2’,4,4’,6,6’-HexaBDE (BDE-155) 200 2’,3,4-TriBDE (BDE-33) 100 2,3,4,4’,5,6-HexaBDE (BDE-166) 200 3,3’,4-TriBDE (BDE-35) 100 2,2’,3,4,4’,5,6-HeptaBDE (BDE-181) 250 3,4,4’-TriBDE (BDE-37) 100 2,2’,3,4,4’,5’,6-HeptaBDE (BDE-183) 2502,2’,4,4’-TetraBDE (BDE-47) 100 2,3,3’,4,4’,5,6-HeptaBDE (BDE-190) 250 2,2’,4,5’-TetraBDE (BDE-49) 100

EO-5113-7.5X-0.5 Polybrominated Diphenyl Ether PAR Standard Solution (Unlabeled) 0.5 mL in nonane (7.5X Concentration of Congeners in EO-5113) BFR Calibration Solutions and Standard MixturesEO-5159 BFR Calibration Solutions [CS1-CS10] 10 x 0.5 mL in nonane Concentration (ng/mL)

Unlabeled Congeners (BDE/PCB/PBB#) CS1 CS2 CS3 CS4 CS5 CS6 CS7 CS8 CS9 CS10 2,2’,4-TriBDE (BDE-17) 0.2 0.5 1 5 10 50 100 500 1000 20002,4,4’-TriBDE (BDE-28) 0.2 0.5 1 5 10 50 100 500 1000 20002,2’,4,4’-TetraBDE (BDE-47) 0.2 0.5 1 5 10 50 100 500 1000 20002,3’,4,4’-TetraBDE (BDE-66) 0.2 0.5 1 5 10 50 100 500 1000 20002,2’,4,4’,6-PentaBDE (BDE-100) 0.2 0.5 1 5 10 50 100 500 1000 20002,2’,4,4’,5-PentaBDE (BDE-99) 0.2 0.5 1 5 10 50 100 500 1000 20002,2’,3,4,4’-PentaBDE (BDE-85) 0.2 0.5 1 5 10 50 100 500 1000 20002,2’,4,4’,5,6’-HexaBDE (BDE-154) 0.2 0.5 1 5 10 50 100 500 1000 20002,2’,4,4’,5,5’-HexaBDE (BDE-153) 0.2 0.5 1 5 10 50 100 500 1000 20002,2’,3,4,4’,5’,6-HeptaBDE (BDE-183) 0.2 0.5 1 5 10 50 100 500 1000 20002,2’,3,4,4’,5,5’,6-OctaBDE (BDE-203) 0.2 0.5 1 5 10 50 100 500 1000 20002,2’,3,3’,4,4’,5,5’,6,6’-DecaBDE (BDE-209) 0.2 0.5 1 5 10 50 100 500 1000 20002,2’,4,4’,5,5’-HexaBB (PBB-153) 0.2 0.5 1 5 10 50 100 500 1000 2000γ-Hexabromocyclododecane 0.2 0.5 1 5 10 50 100 500 1000 20002,2’,4,4’,5,5’-HexaCB (PCB-153) 0.2 0.5 1 5 10 50 100 500 1000 2000Labeled Congeners (BDE/PCB/PBB#) 1,2,3,4-TetraCDD (13C6,99%) 25 25 25 25 25 25 25 25 25 252,2’,3,3’,4,5,5’,6,6’-NonaCB (13C12,99%) (PCB-208) 100 100 100 100 100 100 100 100 100 1002,4,4’-TriBDE (13C12,99%) (BDE-28) 75 75 75 75 75 75 75 75 75 752,2’,4,4’-TetraBDE (13C12,99%) (BDE-47) 75 75 75 75 75 75 75 75 75 753,3’,4,4’-TetraBDE (13C12,99%) (BDE-77) 75 75 75 75 75 75 75 75 75 752,2’,4,4’,6-PentaBDE (13C12,99%) (BDE-100) 75 75 75 75 75 75 75 75 75 752,2’,4,4’,5-PentaBDE (13C12,99%) (BDE-99) 75 75 75 75 75 75 75 75 75 752,2’,4,4’,5,6’-HexaBDE (13C12,99%) (BDE-154) 75 75 75 75 75 75 75 75 75 752,2’,4,4’,5,5’-HexaBDE (13C12,99%) (BDE-153) 75 75 75 75 75 75 75 75 75 752,2’,3,4,4’,6-HexaBDE (13C12,99%) (BDE-139) 75 75 75 75 75 75 75 75 75 752,2’,3,4,4’,5’,6-HeptaBDE (13C12,99%) (BDE-183) 75 75 75 75 75 75 75 75 75 75DecaBDE (13C12,99%) (BDE-209) 75 75 75 75 75 75 75 75 75 752,2’,4,4’,5,5’-HexaBB (13C12,99%) (PBB-153) 75 75 75 75 75 75 75 75 75 752,2’,4,4’,5,5’-HexaCB (13C12,99%) (PCB-153) 75 75 75 75 75 75 75 75 75 75

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EO-5319 CDC BFR Calibration Standards [CS1-CS10] 10 x 0.5mL in nonane

Concentration (ng/mL)

Unlabeled Congeners (BDE/PCB/PBB#) CS1 CS2 CS3 CS4 CS5 CS6 CS7 CS8 CS9 CS10

2,2’,4-TriBDE (BDE-17) 0.2 0.5 1 5 10 50 100 500 1000 2000

2,4,4’-TriBDE (BDE-28) 0.2 0.5 1 5 10 50 100 500 1000 2000

2,2’,4,4’-TetraBDE (BDE-47) 0.2 0.5 1 5 10 50 100 500 1000 2000

2,3’,4,4’-TetraBDE (BDE-66) 0.2 0.5 1 5 10 50 100 500 1000 2000

2,2’,4,4’,6-PentaBDE (BDE-100) 0.2 0.5 1 5 10 50 100 500 1000 2000

2,2’,4,4’,5-PentaBDE (BDE-99) 0.2 0.5 1 5 10 50 100 500 1000 2000

2,2’,3,4,4’-PentaBDE (BDE-85) 0.2 0.5 1 5 10 50 100 500 1000 2000

2,2’,4,4’,5,6’-HexaBDE (BDE-154) 0.2 0.5 1 5 10 50 100 500 1000 2000

2,2’,4,4’,5,5’-HexaBDE (BDE-153) 0.2 0.5 1 5 10 50 100 500 1000 2000

2,2’,3,4,4’,5’,6-HeptaBDE (BDE-183) 0.2 0.5 1 5 10 50 100 500 1000 2000

2,2’,3,3’,4,4’,5,6’-OctaBDE (BDE-196) 0.2 0.5 1 5 10 50 100 500 1000 2000

2,2’,3,3’,4,4’,6,6’-OctaBDE (BDE-197) 0.2 0.5 1 5 10 50 100 500 1000 2000

2,2’,3,4,4’,5,5’,6-OctaBDE (BDE-203) 0.2 0.5 1 5 10 50 100 500 1000 2000

2,2’,3,3’,4,4’,5,5’,6-NonaBDE (BDE-206) 0.2 0.5 1 5 10 50 100 500 1000 2000

2,2’,3,3’,4,4’,5,6,6’-NonaBDE (BDE-207) 0.2 0.5 1 5 10 50 100 500 1000 2000

2,2’,3,3’,4,5,5’,6,6’-NonaBDE (BDE-208) 0.2 0.5 1 5 10 50 100 500 1000 2000

DecaBDE (BDE-209) 0.2 0.5 1 5 10 50 100 500 1000 2000

2,2’,4,4’,5,5’-HexaBB (PBB-153) 0.2 0.5 1 5 10 50 100 500 1000 2000

Hexabromobenzene 0.2 0.5 1 5 10 50 100 500 1000 2000

1,2-Bis(pentabromophenyl)ethane 0.2 0.5 1 5 10 50 100 500 1000 2000

1,2-Bis(2,4,6-Tribromophenoxy)ethane 0.2 0.5 1 5 10 50 100 500 1000 2000

γ-Hexabromocyclododecane 0.2 0.5 1 5 10 50 100 500 1000 2000

Labeled Congeners (BDE/PCB/PBB#)

1,2,3,4-TCDD (13C6,99%) 25 25 25 25 25 25 25 25 25 25

2,2’,3,3’,4,5,5’,6,6’-NonaCB (13C12,99%)(PCB-208) 100 100 100 100 100 100 100 100 100 100

2,4,4’-TriBDE (13C12,99%) (BDE-28) 75 75 75 75 75 75 75 75 75 75

2,2’,4,4’-TetraBDE (13C12,99%) (BDE-47) 75 75 75 75 75 75 75 75 75 75

3,3’,4,4’-TetraBDE (13C12,99%) (BDE-77) 75 75 75 75 75 75 75 75 75 75

2,2’,4,4’,6-PentaBDE (13C12,99%) (BDE-100) 75 75 75 75 75 75 75 75 75 75

2,2’,4,4’,5-PentaBDE (13C12,99%) (BDE-99) 75 75 75 75 75 75 75 75 75 75

2,2’,4,4’,5,6’-HexaBDE (13C12,99%) (BDE-154) 75 75 75 75 75 75 75 75 75 75

2,2’,4,4’,5,5’-HexaBDE (13C12,99%) (BDE-153) 75 75 75 75 75 75 75 75 75 75

2,2’,3,4,4’,6-HexaBDE (13C12,99%) (BDE-139) 75 75 75 75 75 75 75 75 75 75

2,2’,3,4,4’,5’,6-HeptaBDE (13C12,99%) (BDE-183) 75 75 75 75 75 75 75 75 75 75

2,2’,3,3’,4,4’,6,6’-OctaBDE (13C12,99%) (BDE-197) 75 75 75 75 75 75 75 75 75 75

2,2’,3,3’,4,4’,5,5’,6-NonaBDE (13C12,99%) (BDE-206) 75 75 75 75 75 75 75 75 75 75

2,2’,3,3’,4,4’,5,6,6’-NonaBDE (13C12,99%) (BDE-207) 75 75 75 75 75 75 75 75 75 75

2,2’,3,3’,4,5,5’,6,6’-NonaBDE (13C12,99%) (BDE-208) 75 75 75 75 75 75 75 75 75 75

DecaBDE (13C12,99%) (BDE-209) 500 500 500 500 500 500 500 500 500 500

2,2’,4,4’,5,5’-HexaBB (13C12,99%) (PBB-153) 75 75 75 75 75 75 75 75 75 75

Hexabromobenzene (13C6,99%) 75 75 75 75 75 75 75 75 75 75

1,2-Bis(pentabromophenyl)ethane (13C14,99%) 75 75 75 75 75 75 75 75 75 75

1,2-Bis(2,4,6-Tribromophenoxy)ethane (13C12,99%) 75 75 75 75 75 75 75 75 75 75

γ-Hexabromocyclododecane(13C12,99%) 75 75 75 75 75 75 75 75 75 75

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EO-5158 BFR Spiking Standard Solution in Methanol (13C12) 10 mL in 99% methanol, 1% nonane

Labeled Congeners (BDE/PBB#) Concentration (ng/mL)

2,4,4’-TriBDE (13C12,99%) (BDE-28) 7.52,2’,4,4’-TetraBDE (13C12,99%) (BDE-47) 7.52,2’,4,4’,6-PentaBDE (13C12,99%) (BDE-100) 7.52,2’,4,4’,5-PentaBDE (13C12,99%) (BDE-99) 7.52,2’,4,4’,5,6’-HexaBDE (13C12,99%) (BDE-154) 7.52,2’,4,4’,5,5’-HexaBDE (13C12,99%) (BDE-153) 7.5 2,2’,3,4,4’,5’,6-HeptaBDE (13C12,99%) (BDE-183) 7.5 DecaBDE (13C12,99%) (BDE-209) 7.52,2’,4,4’,5,5’-Hexabromobiphenyl (13C12,99%) (PBB-153) 7.5

EO-5169 BFR Recovery Spiking Standard Solution (13C) 10 mL in 88% hexane, 2% dodecane, 10% nonane

Labeled Congeners (BDE/PCB#) Concentration (ng/mL)

1,2,3,4-TetraCDD (13C6,99%) 2.5 3,3’,4,4’-TetraBDE (13C12,99%) (BDE-77) 7.52,2’,3,4,4’,6-HexaBDE (13C12,99%) (BDE-139) 7.52,2’,3,3’,4,5,5’,6,6’-NonaCB (13C12,99%) (PCB-208) 10

EO-5320 CDC BFR Spiking Standard (13C) 10 mL in methanolLabeled Congeners (BDE/PBB#) Concentration (ng/ml) Labeled Congeners (BDE/PBB#) Concentration (ng/ml)

2,4,4’-TriBDE (13C12,99%) (BDE-28) 7.5 2,2’,4,4’,5,5’-HexaBB (13C12,99%) (PBB-153) 7.5 2,2’,4,4’-TetraBDE (13C12,99%) (BDE-47) 7.5 Hexabromobenzene (13C6,99%) 7.52,2’,4,4’,6-PentaBDE (13C12,99%) (BDE-100) 7.5 1,2-Bis(pentabromophenyl)ethane (13C14,99%) 7.52,2’,4,4’,5-PentaBDE (13C12,99%) (BDE-99) 7.5 1,2-Bis(2,4,6-Tribromophenoxy)ethane (13C6,99%) 7.5 2,2’,4,4’,5,6’-HexaBDE (13C12,99%) (BDE-154) 7.5 α-Hexabromocyclododecane (13C12,99%) 7.5 2,2’,4,4’,5,5’-HexaBDE (13C12,99%) (BDE-153) 7.5 2,2’,3,4,4’,5’,6-HeptaBDE (13C12,99%) (BDE-183) 7.5 2,2’,3,3’,4,4’,6,6’-OctaBDE (13C12,99%) (BDE-197) 7.5 2,2’,3,3’,4,4’,5,5’,6-NonaBDE (13C12,99%) (BDE-206) 7.5 2,2’,3,3’,4,4’,5,6,6’-NonaBDE (13C12,99%) (BDE-207) 7.5DecaBDE (13C12,99%) (BDE-209) 50

ES-5321 Multi-Analyte Recovery Spiking Standard (13C) 10 mL in 88% hexane/ 2% dodecane/10% nonane

Labeled Congeners (BDE/PCB#) Concentration (ng/mL)

1,2,3,4-TCDD (13C6, 99%) 2.52,2’,3,3’,4,5,5’,6,6’-NonaCB (13C12,99%) (PCB-208) 103,3’,4,4’-TetraBDE (13C12,99%) (BDE-77) 7.52,2’,3,4,4’,6-HexaBDE (13C12,99%) (BDE-139) 7.5

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Brominated Flame Retardant Standards from CIL

The use of flame retardant chemicals has changed significantly over the past 10 years. Since CIL first introduced polybrominated diphenyl ether (PBDE) standards in 1996, research has repeatedly demonstrated the potentially harmful effects that these chemicals may pose to human health and the environment, leading to the ban or industry withdrawal of most of the PBDE formulations. Despite the discontinued use of these products in many countries however, their persistence in the environment, long-range transport to even remote locations, and bioavailability define a need for continued vigilance.

In the wake of the exclusion of these products many new brominated and chlorinated replacements have been introduced. And with new evidence of biological and chemical debromination, many PBDEs that are not found at significant levels in the manufacturer’s technical products have become relevant as they are identified in various matrices. In addition to the flame retardant compounds themselves, many metabolic by-products have also been studied. CIL has worked closely with the analytical community to match interest in these compounds with the development of new analytical standards to assist further research in these areas.

CIL also maintains an extensive range of Polybrominated Dioxin and Furan (PBDD/F) standards and standard mixtures. These compounds are known combustion by-products, found primarily when industrial wastes are incinerated in the presence of brominated compounds such as BFRs, with toxic factors similar to their chlorinated counterparts. Please refer to our product flyer on our website (or contact us for a printed copy) to see a comprehensive listing of our PBDD/F analytical standards.

The following catalog contains product listings for current interest brominated and chlorinated flame retardants, as well as many metabolites and related compounds. CIL continues to synthesize new 13C-labeled and unlabeled flame retardants and related products, so please contact us to discuss your research needs, or to ask about current and future projects at CIL.

To place an order, contact CIL at 978-749-8000, 800-322-1174 (N. America) fax 978-749-2768 or email [email protected]

Documents

Brominated Flame Retardant Standards · 2008. 9. 29. · Cambridge Isotope Laboratories, Inc. Brominated Flame Retardant Standards Catalog 02 Polybrominated Diphenyl Ether Technical