ANALYTICAL REPORT 6 - Asarco · ANALYTICAL REPORT TestAmerica Laboratories, Inc. TestAmerica Corpus Christi 1733 N. Padre Island Drive Corpus Christi, TX 78408 Tel: (361)289-2673

ANALYTICAL REPORTTestAmerica Laboratories, Inc.TestAmerica Corpus Christi1733 N. Padre Island DriveCorpus Christi, TX 78408Tel: (361)289-2673

TestAmerica Job ID: 560-31034-1TestAmerica Sample Delivery Group: March 1, 2012Client Project/Site: Former ASARCO Groundwater

For:Malcolm Pirnie, Inc. Invoice to Arcadis211 North Florence StreetSuite 202El Paso, Texas 79901

Attn: Ms. Marla Miller

Authorized for release by:3/18/2012 4:29:08 PM

Timothy KelloggCustomer Service [email protected]

The test results in this report meet all 2003 NELAC and 2009 TNI requirements for accreditedparameters, exceptions are noted in this report. This report may not be reproduced except in full,and with written approval from the laboratory. For questions please contact the Project Managerat the e-mail address or telephone number listed on this page.

This report has been electronically signed and authorized by the signatory. Electronic signature isintended to be the legally binding equivalent of a traditionally handwritten signature.

Results relate only to the items tested and the sample(s) as received by the laboratory.

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Definitions/GlossaryTestAmerica Job ID: 560-31034-1Client: Malcolm Pirnie, Inc. Invoice to Arcadis

SDG: March 1, 2012Project/Site: Former ASARCO Groundwater

Qualifiers

Metals

Qualifier Description

U Analyte was not detected at or above the SDL.

Qualifier

J Result is less than the MQL but greater than or equal to the SDL and the concentration is an estimated value.

General Chemistry

Qualifier Description

U Analyte was not detected at or above the SDL.

Qualifier

J Result is less than the MQL but greater than or equal to the SDL and the concentration is an estimated value.

Glossary

These commonly used abbreviations may or may not be present in this report.

☼ Listed under the "D" column to designate that the result is reported on a dry weight basis

Abbreviation

%R Percent Recovery

CNF Contains no Free Liquid

DL, RA, RE, IN Indicates a Dilution, Reanalysis, Re-extraction, or additional Initial metals/anion analysis of the sample

EDL Estimated Detection Limit

EPA United States Environmental Protection Agency

MDL Method Detection Limit

ML Minimum Level (Dioxin)

ND Not detected at the reporting limit (or MDL or EDL if shown)

PQL Practical Quantitation Limit

QC Quality Control

RL Reporting Limit

RPD Relative Percent Difference, a measure of the relative difference between two points

TEF Toxicity Equivalent Factor (Dioxin)

TEQ Toxicity Equivalent Quotient (Dioxin)

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Client Sample ResultsTestAmerica Job ID: 560-31034-1Client: Malcolm Pirnie, Inc. Invoice to Arcadis


Lab Sample ID: 560-31034-1Client Sample ID: EP-85Matrix: WaterDate Collected: 03/01/12 08:00

Date Received: 03/02/12 10:25

Method: 6020 - Metals (ICP/MS)MQL MDL

Aluminum 0.0225 U 0.0500 0.0225 mg/L 03/07/12 09:30 03/07/12 19:36 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

0.00500 0.00161 mg/L 03/07/12 09:30 03/07/12 19:36 1Antimony 0.0422

0.00500 0.00109 mg/L 03/07/12 09:30 03/08/12 19:15 1Arsenic 1.25

0.00500 0.000810 mg/L 03/07/12 09:30 03/07/12 19:36 1Barium 0.0352

0.00200 0.000854 mg/L 03/07/12 09:30 03/07/12 19:36 1Cadmium 0.00168 J

0.500 0.198 mg/L 03/07/12 09:30 03/07/12 19:36 1Calcium 98.9

0.00500 0.00140 mg/L 03/07/12 09:30 03/07/12 19:36 1Chromium 0.00239 J

0.00500 0.00136 mg/L 03/07/12 09:30 03/07/12 19:36 1Cobalt 0.00136 U

0.0100 0.00200 mg/L 03/07/12 09:30 03/07/12 19:36 1Copper 0.00200 U

0.250 0.101 mg/L 03/07/12 09:30 03/07/12 19:36 1Iron 0.101 U

0.00500 0.000733 mg/L 03/07/12 09:30 03/07/12 19:36 1Lead 0.000733 U

0.500 0.113 mg/L 03/07/12 09:30 03/08/12 19:15 1Magnesium 47.9

0.0500 0.0116 mg/L 03/07/12 09:30 03/07/12 19:36 1Manganese 0.0116 U

0.00500 0.00140 mg/L 03/07/12 09:30 03/07/12 19:36 1Molybdenum 0.572

0.00500 0.00217 mg/L 03/07/12 09:30 03/07/12 19:36 1Nickel 0.00217 U

1.00 0.407 mg/L 03/07/12 09:30 03/07/12 19:36 1Potassium 27.3

0.00500 0.00108 mg/L 03/07/12 09:30 03/07/12 19:36 1Selenium 0.132

1.00 0.727 mg/L 03/07/12 09:30 03/08/12 19:52 10Sodium 783

0.00100 0.000693 mg/L 03/07/12 09:30 03/08/12 19:15 1Thallium 0.00974

0.0250 0.00355 mg/L 03/07/12 09:30 03/07/12 19:36 1Zinc 0.00355 U

Method: 6020 - Metals (ICP/MS) - DissolvedMQL MDL

Antimony 0.0394 0.00500 0.00161 mg/L 03/08/12 09:30 03/08/12 23:31 1


0.00500 0.00109 mg/L 03/08/12 09:30 03/08/12 23:31 1Arsenic 1.30

0.00500 0.000810 mg/L 03/08/12 09:30 03/08/12 23:31 1Barium 0.0315

0.00200 0.000854 mg/L 03/08/12 09:30 03/08/12 23:31 1Cadmium 0.000854 U

0.00500 0.00140 mg/L 03/08/12 09:30 03/08/12 23:31 1Chromium 0.00302 J

0.00500 0.00136 mg/L 03/08/12 09:30 03/08/12 23:31 1Cobalt 0.00136 U

0.0100 0.00200 mg/L 03/08/12 09:30 03/08/12 23:31 1Copper 0.00200 U

0.250 0.101 mg/L 03/08/12 09:30 03/08/12 23:31 1Iron 0.101 U

0.00500 0.000733 mg/L 03/08/12 09:30 03/08/12 23:31 1Lead 0.000733 U

0.00500 0.00140 mg/L 03/08/12 09:30 03/08/12 23:31 1Molybdenum 0.537

0.00500 0.00217 mg/L 03/08/12 09:30 03/08/12 23:31 1Nickel 0.00217 U

0.00500 0.00108 mg/L 03/08/12 09:30 03/08/12 23:31 1Selenium 0.130

0.00100 0.000693 mg/L 03/08/12 09:30 03/08/12 23:31 1Thallium 0.0100

0.0250 0.00355 mg/L 03/08/12 09:30 03/08/12 23:31 1Zinc 0.00355 U

Method: 7470A - Mercury (CVAA)MQL MDL

Mercury 0.000130 U 0.00200 0.000130 mg/L 03/07/12 12:30 03/07/12 18:14 1


Method: 7470A - Mercury (CVAA) - DissolvedMQL MDL

Mercury 0.000130 U 0.00200 0.000130 mg/L 03/07/12 12:30 03/07/12 18:16 1


General ChemistryMQL MDL

Total Dissolved Solids 2640 10.0 10.0 mg/L 03/05/12 10:45 1


3.00 3.00 mg/L 03/06/12 09:15 1Total Suspended Solids 3.00 U

1.00 0.192 mg/L 03/02/12 16:18 50Chloride 314

0.500 0.200 mg/L 03/02/12 12:59 4Nitrate Nitrite as N 9.37


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General Chemistry (Continued)MQL MDL

Sulfate 632 1.00 0.377 mg/L 03/07/12 08:07 50


0.100 0.0200 mg/L 03/05/12 09:50 2Fluoride 3.30

0.0500 0.0131 mg/L 03/02/12 11:10 1Sulfide 0.0131 U

1.00 0.285 mg/L 03/07/12 12:15 1Total Organic Carbon 2.37

5.00 5.00 mg/L 03/05/12 12:55 1Total Alkalinity as CaCO3 396




Aluminum 0.0317 J 0.0500 0.0225 mg/L 03/07/12 09:30 03/07/12 19:41 1


0.00500 0.00161 mg/L 03/07/12 09:30 03/07/12 19:41 1Antimony 0.00342 J

0.00500 0.00109 mg/L 03/07/12 09:30 03/08/12 19:20 1Arsenic 0.749

0.00500 0.000810 mg/L 03/07/12 09:30 03/07/12 19:41 1Barium 0.0442

0.00200 0.000854 mg/L 03/07/12 09:30 03/07/12 19:41 1Cadmium 0.00116 J

0.500 0.198 mg/L 03/07/12 09:30 03/07/12 19:41 1Calcium 131

0.00500 0.00140 mg/L 03/07/12 09:30 03/07/12 19:41 1Chromium 0.00140 U

0.00500 0.00136 mg/L 03/07/12 09:30 03/07/12 19:41 1Cobalt 0.00136 U

0.0100 0.00200 mg/L 03/07/12 09:30 03/07/12 19:41 1Copper 0.00466 J

0.250 0.101 mg/L 03/07/12 09:30 03/07/12 19:41 1Iron 0.101 U

0.00500 0.000733 mg/L 03/07/12 09:30 03/07/12 19:41 1Lead 0.000733 U

0.500 0.113 mg/L 03/07/12 09:30 03/08/12 19:20 1Magnesium 51.0

0.0500 0.0116 mg/L 03/07/12 09:30 03/07/12 19:41 1Manganese 0.0116 U

0.00500 0.00140 mg/L 03/07/12 09:30 03/07/12 19:41 1Molybdenum 0.320

0.00500 0.00217 mg/L 03/07/12 09:30 03/07/12 19:41 1Nickel 0.00217 U

1.00 0.407 mg/L 03/07/12 09:30 03/07/12 19:41 1Potassium 30.1

0.00500 0.00108 mg/L 03/07/12 09:30 03/07/12 19:41 1Selenium 0.131

1.00 0.727 mg/L 03/07/12 09:30 03/07/12 19:41 1Sodium 293

0.00100 0.000693 mg/L 03/07/12 09:30 03/08/12 19:20 1Thallium 0.000752 J

0.0250 0.00355 mg/L 03/07/12 09:30 03/07/12 19:41 1Zinc 0.00831 J


Antimony 0.00335 J 0.00500 0.00161 mg/L 03/08/12 09:30 03/09/12 00:13 1


0.00500 0.00109 mg/L 03/08/12 09:30 03/09/12 00:13 1Arsenic 0.743

0.00500 0.000810 mg/L 03/08/12 09:30 03/09/12 00:13 1Barium 0.0400

0.00200 0.000854 mg/L 03/08/12 09:30 03/09/12 00:13 1Cadmium 0.000854 U

0.00500 0.00140 mg/L 03/08/12 09:30 03/09/12 00:13 1Chromium 0.00140 U

0.00500 0.00136 mg/L 03/08/12 09:30 03/09/12 00:13 1Cobalt 0.00136 U

0.0100 0.00200 mg/L 03/08/12 09:30 03/09/12 00:13 1Copper 0.00391 J

0.250 0.101 mg/L 03/08/12 09:30 03/09/12 00:13 1Iron 0.101 U

0.00500 0.000733 mg/L 03/08/12 09:30 03/09/12 00:13 1Lead 0.000733 U

0.00500 0.00140 mg/L 03/08/12 09:30 03/09/12 00:13 1Molybdenum 0.295

0.00500 0.00217 mg/L 03/08/12 09:30 03/09/12 00:13 1Nickel 0.00217 U

0.00500 0.00108 mg/L 03/08/12 09:30 03/09/12 00:13 1Selenium 0.127

0.00100 0.000693 mg/L 03/08/12 09:30 03/09/12 00:13 1Thallium 0.000937 J

0.0250 0.00355 mg/L 03/08/12 09:30 03/09/12 00:13 1Zinc 0.00847 J


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Mercury 0.000130 U 0.00200 0.000130 mg/L 03/07/12 12:30 03/07/12 18:18 1



Mercury 0.000130 U 0.00200 0.000130 mg/L 03/07/12 12:30 03/07/12 18:20 1






1.00 0.192 mg/L 03/02/12 14:05 4Chloride 159


1.00 0.377 mg/L 03/07/12 08:29 25Sulfate 678

0.100 0.0200 mg/L 03/05/12 09:50 2Fluoride 3.22

0.0500 0.0131 mg/L 03/02/12 11:10 1Sulfide 0.0200 J



Lab Sample ID: 560-31034-3Client Sample ID: OBS-1Matrix: WaterDate Collected: 03/01/12 10:15



Aluminum 0.0225 U 0.0500 0.0225 mg/L 03/07/12 09:30 03/07/12 19:47 1


0.00500 0.00161 mg/L 03/07/12 09:30 03/07/12 19:47 1Antimony 0.0435

0.00500 0.00109 mg/L 03/07/12 09:30 03/08/12 19:26 1Arsenic 1.78

0.00500 0.000810 mg/L 03/07/12 09:30 03/07/12 19:47 1Barium 0.0268

0.00200 0.000854 mg/L 03/07/12 09:30 03/07/12 19:47 1Cadmium 0.00209

0.500 0.198 mg/L 03/07/12 09:30 03/07/12 19:47 1Calcium 149

0.00500 0.00140 mg/L 03/07/12 09:30 03/07/12 19:47 1Chromium 0.00140 U

0.00500 0.00136 mg/L 03/07/12 09:30 03/07/12 19:47 1Cobalt 0.00136 U

0.0100 0.00200 mg/L 03/07/12 09:30 03/07/12 19:47 1Copper 0.00200 U

0.250 0.101 mg/L 03/07/12 09:30 03/07/12 19:47 1Iron 0.101 U

0.00500 0.000733 mg/L 03/07/12 09:30 03/07/12 19:47 1Lead 0.000733 U

0.500 0.113 mg/L 03/07/12 09:30 03/08/12 19:26 1Magnesium 68.7

0.0500 0.0116 mg/L 03/07/12 09:30 03/07/12 19:47 1Manganese 0.0116 U

0.00500 0.00140 mg/L 03/07/12 09:30 03/07/12 19:47 1Molybdenum 0.449

0.00500 0.00217 mg/L 03/07/12 09:30 03/07/12 19:47 1Nickel 0.00462 J

1.00 0.407 mg/L 03/07/12 09:30 03/07/12 19:47 1Potassium 54.8

0.00500 0.00108 mg/L 03/07/12 09:30 03/07/12 19:47 1Selenium 0.222

1.00 0.727 mg/L 03/07/12 09:30 03/08/12 20:24 10Sodium 844

0.00100 0.000693 mg/L 03/07/12 09:30 03/08/12 19:26 1Thallium 0.0163

0.0250 0.00355 mg/L 03/07/12 09:30 03/07/12 19:47 1Zinc 0.0392


Antimony 0.0388 0.00500 0.00161 mg/L 03/08/12 09:30 03/09/12 00:19 1


0.00500 0.00109 mg/L 03/08/12 09:30 03/09/12 00:19 1Arsenic 1.77

0.00500 0.000810 mg/L 03/08/12 09:30 03/09/12 00:19 1Barium 0.0245

0.00200 0.000854 mg/L 03/08/12 09:30 03/09/12 00:19 1Cadmium 0.00122 J

0.00500 0.00140 mg/L 03/08/12 09:30 03/09/12 00:19 1Chromium 0.00140 U


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Lab Sample ID: 560-31034-3Client Sample ID: OBS-1Matrix: WaterDate Collected: 03/01/12 10:15


Method: 6020 - Metals (ICP/MS) - Dissolved (Continued)MQL MDL

Cobalt 0.00136 U 0.00500 0.00136 mg/L 03/08/12 09:30 03/09/12 00:19 1


0.0100 0.00200 mg/L 03/08/12 09:30 03/09/12 00:19 1Copper 0.00200 U

0.250 0.101 mg/L 03/08/12 09:30 03/09/12 00:19 1Iron 0.101 U

0.00500 0.000733 mg/L 03/08/12 09:30 03/09/12 00:19 1Lead 0.000733 U

0.00500 0.00140 mg/L 03/08/12 09:30 03/09/12 00:19 1Molybdenum 0.420

0.00500 0.00217 mg/L 03/08/12 09:30 03/09/12 00:19 1Nickel 0.00388 J

0.00500 0.00108 mg/L 03/08/12 09:30 03/09/12 00:19 1Selenium 0.205

0.00100 0.000693 mg/L 03/08/12 09:30 03/09/12 00:19 1Thallium 0.0167

0.0250 0.00355 mg/L 03/08/12 09:30 03/09/12 00:19 1Zinc 0.0357


Mercury 0.000130 U 0.00200 0.000130 mg/L 03/07/12 12:30 03/07/12 18:23 1



Mercury 0.000130 U 0.00200 0.000130 mg/L 03/07/12 12:30 03/07/12 18:25 1






1.00 0.192 mg/L 03/02/12 17:02 50Chloride 373


1.00 0.377 mg/L 03/07/12 09:35 50Sulfate 1310

0.100 0.0200 mg/L 03/05/12 09:50 2Fluoride 2.90

0.0500 0.0131 mg/L 03/02/12 11:10 1Sulfide 0.0260 J



Lab Sample ID: 560-31034-4Client Sample ID: FD030212Matrix: WaterDate Collected: 03/01/12 00:00



Aluminum 0.0225 U 0.0500 0.0225 mg/L 03/07/12 09:30 03/07/12 20:14 1


0.00500 0.00161 mg/L 03/07/12 09:30 03/07/12 20:14 1Antimony 0.0452

0.00500 0.00109 mg/L 03/07/12 09:30 03/07/12 20:14 1Arsenic 1.41

0.00500 0.000810 mg/L 03/07/12 09:30 03/07/12 20:14 1Barium 0.0370

0.00200 0.000854 mg/L 03/07/12 09:30 03/07/12 20:14 1Cadmium 0.00178 J

0.500 0.198 mg/L 03/07/12 09:30 03/07/12 20:14 1Calcium 104

0.00500 0.00140 mg/L 03/07/12 09:30 03/07/12 20:14 1Chromium 0.00248 J

0.00500 0.00136 mg/L 03/07/12 09:30 03/07/12 20:14 1Cobalt 0.00136 U

0.0100 0.00200 mg/L 03/07/12 09:30 03/07/12 20:14 1Copper 0.00200 U

0.250 0.101 mg/L 03/07/12 09:30 03/07/12 20:14 1Iron 0.274

0.00500 0.000733 mg/L 03/07/12 09:30 03/07/12 20:14 1Lead 0.000733 U

0.500 0.113 mg/L 03/07/12 09:30 03/08/12 19:31 1Magnesium 50.3

0.0500 0.0116 mg/L 03/07/12 09:30 03/07/12 20:14 1Manganese 0.0116 U

0.00500 0.00140 mg/L 03/07/12 09:30 03/07/12 20:14 1Molybdenum 0.620

0.00500 0.00217 mg/L 03/07/12 09:30 03/07/12 20:14 1Nickel 0.00217 U

1.00 0.407 mg/L 03/07/12 09:30 03/07/12 20:14 1Potassium 28.3


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Lab Sample ID: 560-31034-4Client Sample ID: FD030212Matrix: WaterDate Collected: 03/01/12 00:00


Method: 6020 - Metals (ICP/MS) (Continued)MQL MDL

Selenium 0.135 0.00500 0.00108 mg/L 03/07/12 09:30 03/07/12 20:14 1


1.00 0.727 mg/L 03/07/12 09:30 03/08/12 20:29 10Sodium 789

0.00100 0.000693 mg/L 03/07/12 09:30 03/07/12 20:14 1Thallium 0.00966

0.0250 0.00355 mg/L 03/07/12 09:30 03/07/12 20:14 1Zinc 0.00544 J


Antimony 0.0408 0.00500 0.00161 mg/L 03/08/12 09:30 03/09/12 00:24 1


0.00500 0.00109 mg/L 03/08/12 09:30 03/09/12 00:24 1Arsenic 1.29

0.00500 0.000810 mg/L 03/08/12 09:30 03/09/12 00:24 1Barium 0.0332

0.00200 0.000854 mg/L 03/08/12 09:30 03/09/12 00:24 1Cadmium 0.000854 U

0.00500 0.00140 mg/L 03/08/12 09:30 03/09/12 00:24 1Chromium 0.00226 J

0.00500 0.00136 mg/L 03/08/12 09:30 03/09/12 00:24 1Cobalt 0.00136 U

0.0100 0.00200 mg/L 03/08/12 09:30 03/09/12 00:24 1Copper 0.00200 U

0.250 0.101 mg/L 03/08/12 09:30 03/09/12 00:24 1Iron 0.101 U

0.00500 0.000733 mg/L 03/08/12 09:30 03/09/12 00:24 1Lead 0.000733 U

0.00500 0.00140 mg/L 03/08/12 09:30 03/09/12 00:24 1Molybdenum 0.559

0.00500 0.00217 mg/L 03/08/12 09:30 03/09/12 00:24 1Nickel 0.00217 U

0.00500 0.00108 mg/L 03/08/12 09:30 03/09/12 00:24 1Selenium 0.130

0.00100 0.000693 mg/L 03/08/12 09:30 03/09/12 00:24 1Thallium 0.0100

0.0250 0.00355 mg/L 03/08/12 09:30 03/09/12 00:24 1Zinc 0.00355 U


Mercury 0.000130 U 0.00200 0.000130 mg/L 03/07/12 12:30 03/07/12 18:27 1



Mercury 0.000130 U 0.00200 0.000130 mg/L 03/07/12 12:30 03/07/12 18:36 1






1.00 0.192 mg/L 03/02/12 18:08 50Chloride 310


1.00 0.377 mg/L 03/07/12 09:57 50Sulfate 1080

0.100 0.0200 mg/L 03/05/12 09:50 2Fluoride 3.02

0.0500 0.0131 mg/L 03/02/12 11:10 1Sulfide 0.0180 J






Aluminum 0.0376 J 0.0500 0.0225 mg/L 03/07/12 09:30 03/07/12 20:20 1


0.00500 0.00161 mg/L 03/07/12 09:30 03/07/12 20:20 1Antimony 0.00700

0.00500 0.00109 mg/L 03/07/12 09:30 03/07/12 20:20 1Arsenic 50.5

0.00500 0.000810 mg/L 03/07/12 09:30 03/07/12 20:20 1Barium 0.0231


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Method: 6020 - Metals (ICP/MS) (Continued)MQL MDL

Cadmium 0.0443 0.00200 0.000854 mg/L 03/07/12 09:30 03/07/12 20:20 1


0.500 0.198 mg/L 03/07/12 09:30 03/07/12 20:20 1Calcium 560

0.00500 0.00140 mg/L 03/07/12 09:30 03/07/12 20:20 1Chromium 0.00140 U

0.00500 0.00136 mg/L 03/07/12 09:30 03/07/12 20:20 1Cobalt 0.0541

0.0100 0.00200 mg/L 03/07/12 09:30 03/07/12 20:20 1Copper 0.00867 J

0.250 0.101 mg/L 03/07/12 09:30 03/07/12 20:20 1Iron 13.6

0.00500 0.000733 mg/L 03/07/12 09:30 03/07/12 20:20 1Lead 0.00208 J

0.500 0.113 mg/L 03/07/12 09:30 03/08/12 19:36 1Magnesium 216

0.0500 0.0116 mg/L 03/07/12 09:30 03/07/12 20:20 1Manganese 6.34

0.00500 0.00140 mg/L 03/07/12 09:30 03/07/12 20:20 1Molybdenum 0.412

0.00500 0.00217 mg/L 03/07/12 09:30 03/07/12 20:20 1Nickel 0.178

1.00 0.407 mg/L 03/07/12 09:30 03/07/12 20:20 1Potassium 185

0.00500 0.00108 mg/L 03/07/12 09:30 03/07/12 20:20 1Selenium 0.0203

1.00 0.727 mg/L 03/07/12 09:30 03/08/12 20:35 10Sodium 774

0.00100 0.000693 mg/L 03/07/12 09:30 03/07/12 20:20 1Thallium 0.00301

0.0250 0.00355 mg/L 03/07/12 09:30 03/07/12 20:20 1Zinc 8.04


Antimony 0.00725 0.00500 0.00161 mg/L 03/08/12 09:30 03/09/12 00:29 1


0.00500 0.00109 mg/L 03/08/12 09:30 03/09/12 00:29 1Arsenic 45.2

0.00500 0.000810 mg/L 03/08/12 09:30 03/09/12 00:29 1Barium 0.0207

0.00200 0.000854 mg/L 03/08/12 09:30 03/09/12 00:29 1Cadmium 0.0427

0.00500 0.00140 mg/L 03/08/12 09:30 03/09/12 00:29 1Chromium 0.00140 U

0.00500 0.00136 mg/L 03/08/12 09:30 03/09/12 00:29 1Cobalt 0.0513

0.0100 0.00200 mg/L 03/08/12 09:30 03/09/12 00:29 1Copper 0.00200 U

0.250 0.101 mg/L 03/08/12 09:30 03/09/12 00:29 1Iron 12.9

0.00500 0.000733 mg/L 03/08/12 09:30 03/09/12 00:29 1Lead 0.000733 U

0.00500 0.00140 mg/L 03/08/12 09:30 03/09/12 00:29 1Molybdenum 0.390

0.00500 0.00217 mg/L 03/08/12 09:30 03/09/12 00:29 1Nickel 0.179

0.00500 0.00108 mg/L 03/08/12 09:30 03/09/12 00:29 1Selenium 0.0187

0.00100 0.000693 mg/L 03/08/12 09:30 03/09/12 00:29 1Thallium 0.00319

0.0250 0.00355 mg/L 03/08/12 09:30 03/09/12 00:29 1Zinc 7.92


Mercury 0.000189 J 0.00200 0.000130 mg/L 03/07/12 12:30 03/07/12 18:38 1



Mercury 0.000206 J 0.00200 0.000130 mg/L 03/07/12 12:30 03/07/12 18:40 1





3.00 3.00 mg/L 03/06/12 09:15 1Total Suspended Solids 30.0

1.00 0.192 mg/L 03/02/12 19:14 100Chloride 347

0.500 0.200 mg/L 03/02/12 15:11 4Nitrate Nitrite as N 0.800 U

1.00 0.377 mg/L 03/07/12 10:21 100Sulfate 2820

0.100 0.0200 mg/L 03/05/12 09:50 10Fluoride 7.42

0.0500 0.0131 mg/L 03/02/12 11:10 1Sulfide 0.0190 J



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General Chemistry (Continued)MQL MDL

Total Alkalinity as CaCO3 614 5.00 5.00 mg/L 03/05/12 12:55 1





Aluminum 0.532 0.0500 0.0225 mg/L 03/07/12 09:30 03/07/12 20:25 1


0.00500 0.00161 mg/L 03/07/12 09:30 03/07/12 20:25 1Antimony 0.0451

0.00500 0.00109 mg/L 03/07/12 09:30 03/07/12 20:25 1Arsenic 2.19

0.00500 0.000810 mg/L 03/07/12 09:30 03/07/12 20:25 1Barium 0.0315

0.00200 0.000854 mg/L 03/07/12 09:30 03/07/12 20:25 1Cadmium 0.292

0.500 0.198 mg/L 03/07/12 09:30 03/07/12 20:25 1Calcium 249

0.00500 0.00140 mg/L 03/07/12 09:30 03/07/12 20:25 1Chromium 0.00204 J

0.00500 0.00136 mg/L 03/07/12 09:30 03/07/12 20:25 1Cobalt 0.0110

0.0100 0.00200 mg/L 03/07/12 09:30 03/07/12 20:25 1Copper 2.67

0.250 0.101 mg/L 03/07/12 09:30 03/07/12 20:25 1Iron 3.42

0.00500 0.000733 mg/L 03/07/12 09:30 03/07/12 20:25 1Lead 0.299

0.500 0.113 mg/L 03/07/12 09:30 03/08/12 19:41 1Magnesium 15.2

0.0500 0.0116 mg/L 03/07/12 09:30 03/07/12 20:25 1Manganese 0.503

0.00500 0.00140 mg/L 03/07/12 09:30 03/07/12 20:25 1Molybdenum 0.233

0.00500 0.00217 mg/L 03/07/12 09:30 03/07/12 20:25 1Nickel 0.0329

1.00 0.407 mg/L 03/07/12 09:30 03/07/12 20:25 1Potassium 27.2

0.00500 0.00108 mg/L 03/07/12 09:30 03/07/12 20:25 1Selenium 0.488

1.00 0.727 mg/L 03/07/12 09:30 03/08/12 19:41 1Sodium 140

0.00100 0.000693 mg/L 03/07/12 09:30 03/07/12 20:25 1Thallium 0.335

0.0250 0.00355 mg/L 03/07/12 09:30 03/07/12 20:25 1Zinc 1.05


Antimony 0.0146 0.00500 0.00161 mg/L 03/08/12 09:30 03/09/12 00:34 1


0.00500 0.00109 mg/L 03/08/12 09:30 03/09/12 00:34 1Arsenic 1.68

0.00500 0.000810 mg/L 03/08/12 09:30 03/09/12 00:34 1Barium 0.0203

0.00200 0.000854 mg/L 03/08/12 09:30 03/09/12 00:34 1Cadmium 0.256

0.00500 0.00140 mg/L 03/08/12 09:30 03/09/12 00:34 1Chromium 0.00140 U

0.00500 0.00136 mg/L 03/08/12 09:30 03/09/12 00:34 1Cobalt 0.0104

0.0100 0.00200 mg/L 03/08/12 09:30 03/09/12 00:34 1Copper 1.21

0.250 0.101 mg/L 03/08/12 09:30 03/09/12 00:34 1Iron 0.101 U

0.00500 0.000733 mg/L 03/08/12 09:30 03/09/12 00:34 1Lead 0.00933

0.00500 0.00140 mg/L 03/08/12 09:30 03/09/12 00:34 1Molybdenum 0.216

0.00500 0.00217 mg/L 03/08/12 09:30 03/09/12 00:34 1Nickel 0.0299

0.00500 0.00108 mg/L 03/08/12 09:30 03/09/12 00:34 1Selenium 0.441

0.00100 0.000693 mg/L 03/08/12 09:30 03/09/12 00:34 1Thallium 0.291

0.0250 0.00355 mg/L 03/08/12 09:30 03/09/12 00:34 1Zinc 0.836


Mercury 0.00320 0.00200 0.000130 mg/L 03/08/12 10:00 03/08/12 14:22 1



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Mercury 0.000130 U 0.00200 0.000130 mg/L 03/08/12 10:00 03/08/12 14:24 1





3.00 3.00 mg/L 03/06/12 09:15 1Total Suspended Solids 28.8

1.00 0.192 mg/L 03/02/12 19:36 100Chloride 323


1.00 0.377 mg/L 03/07/12 14:01 100Sulfate 1970

0.100 0.0200 mg/L 03/05/12 09:50 2Fluoride 3.68

0.0500 0.0131 mg/L 03/02/12 11:10 1Sulfide 0.0220 J






Aluminum 0.0225 U 0.0500 0.0225 mg/L 03/07/12 09:30 03/07/12 20:31 1


0.00500 0.00161 mg/L 03/07/12 09:30 03/07/12 20:31 1Antimony 0.0161

0.00500 0.00109 mg/L 03/07/12 09:30 03/07/12 20:31 1Arsenic 3.32

0.00500 0.000810 mg/L 03/07/12 09:30 03/07/12 20:31 1Barium 0.0206

0.00200 0.000854 mg/L 03/07/12 09:30 03/07/12 20:31 1Cadmium 0.0494

0.500 0.198 mg/L 03/07/12 09:30 03/07/12 20:31 1Calcium 200

0.00500 0.00140 mg/L 03/07/12 09:30 03/07/12 20:31 1Chromium 0.00406 J

0.00500 0.00136 mg/L 03/07/12 09:30 03/07/12 20:31 1Cobalt 0.00136 U

0.0100 0.00200 mg/L 03/07/12 09:30 03/07/12 20:31 1Copper 0.00716 J

0.250 0.101 mg/L 03/07/12 09:30 03/07/12 20:31 1Iron 0.101 U

0.00500 0.000733 mg/L 03/07/12 09:30 03/07/12 20:31 1Lead 0.00896

0.500 0.113 mg/L 03/07/12 09:30 03/08/12 19:47 1Magnesium 37.7

0.0500 0.0116 mg/L 03/07/12 09:30 03/07/12 20:31 1Manganese 0.0175 J

0.00500 0.00140 mg/L 03/07/12 09:30 03/07/12 20:31 1Molybdenum 0.248

0.00500 0.00217 mg/L 03/07/12 09:30 03/07/12 20:31 1Nickel 0.0118

1.00 0.407 mg/L 03/07/12 09:30 03/07/12 20:31 1Potassium 78.3

0.00500 0.00108 mg/L 03/07/12 09:30 03/07/12 20:31 1Selenium 2.08

1.00 0.727 mg/L 03/07/12 09:30 03/08/12 20:45 10Sodium 843

0.00100 0.000693 mg/L 03/07/12 09:30 03/07/12 20:31 1Thallium 0.00244

0.0250 0.00355 mg/L 03/07/12 09:30 03/07/12 20:31 1Zinc 0.0660


Antimony 0.0159 0.00500 0.00161 mg/L 03/08/12 09:30 03/09/12 00:40 1


0.00500 0.00109 mg/L 03/08/12 09:30 03/09/12 00:40 1Arsenic 3.35

0.00500 0.000810 mg/L 03/08/12 09:30 03/09/12 00:40 1Barium 0.0210

0.00200 0.000854 mg/L 03/08/12 09:30 03/09/12 00:40 1Cadmium 0.0491

0.00500 0.00140 mg/L 03/08/12 09:30 03/09/12 00:40 1Chromium 0.00400 J

0.00500 0.00136 mg/L 03/08/12 09:30 03/09/12 00:40 1Cobalt 0.00136 U

0.0100 0.00200 mg/L 03/08/12 09:30 03/09/12 00:40 1Copper 0.00457 J

0.250 0.101 mg/L 03/08/12 09:30 03/09/12 00:40 1Iron 0.101 U

0.00500 0.000733 mg/L 03/08/12 09:30 03/09/12 00:40 1Lead 0.00434 J


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Method: 6020 - Metals (ICP/MS) - Dissolved (Continued)MQL MDL

Molybdenum 0.248 0.00500 0.00140 mg/L 03/08/12 09:30 03/09/12 00:40 1


0.00500 0.00217 mg/L 03/08/12 09:30 03/09/12 00:40 1Nickel 0.0124

0.00500 0.00108 mg/L 03/08/12 09:30 03/09/12 00:40 1Selenium 2.12

0.00100 0.000693 mg/L 03/08/12 09:30 03/09/12 00:40 1Thallium 0.00175

0.0250 0.00355 mg/L 03/08/12 09:30 03/09/12 00:40 1Zinc 0.0675


Mercury 0.000130 U 0.00200 0.000130 mg/L 03/08/12 10:00 03/08/12 14:27 1



Mercury 0.000130 U 0.00200 0.000130 mg/L 03/08/12 10:00 03/08/12 14:29 1






1.00 0.192 mg/L 03/02/12 19:58 50Chloride 376


1.00 0.377 mg/L 03/07/12 14:23 50Sulfate 1580

0.100 0.0200 mg/L 03/05/12 09:50 2Fluoride 2.94

0.0500 0.0131 mg/L 03/02/12 11:10 1Sulfide 0.0131 U




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QC Sample ResultsTestAmerica Job ID: 560-31034-1Client: Malcolm Pirnie, Inc. Invoice to Arcadis


Method: 6020 - Metals (ICP/MS)

Client Sample ID: Method BlankLab Sample ID: MB 560-70320/1-A

Matrix: Water Prep Type: Total/NA

Analysis Batch: 70352 Prep Batch: 70320

MQL MDL

Aluminum 0.0225 U 0.0500 0.0225 mg/L 03/07/12 09:30 03/07/12 18:09 1

MB MB

Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier

0.00161 U 0.001610.00500 mg/L 03/07/12 09:30 03/07/12 18:09 1Antimony

0.000810 U 0.0008100.00500 mg/L 03/07/12 09:30 03/07/12 18:09 1Barium

0.000854 U 0.0008540.00200 mg/L 03/07/12 09:30 03/07/12 18:09 1Cadmium

0.198 U 0.1980.500 mg/L 03/07/12 09:30 03/07/12 18:09 1Calcium

0.00140 U 0.001400.00500 mg/L 03/07/12 09:30 03/07/12 18:09 1Chromium

0.00136 U 0.001360.00500 mg/L 03/07/12 09:30 03/07/12 18:09 1Cobalt

0.00200 U 0.002000.0100 mg/L 03/07/12 09:30 03/07/12 18:09 1Copper

0.101 U 0.1010.250 mg/L 03/07/12 09:30 03/07/12 18:09 1Iron

0.000733 U 0.0007330.00500 mg/L 03/07/12 09:30 03/07/12 18:09 1Lead

0.0116 U 0.01160.0500 mg/L 03/07/12 09:30 03/07/12 18:09 1Manganese

0.00140 U 0.001400.00500 mg/L 03/07/12 09:30 03/07/12 18:09 1Molybdenum

0.00217 U 0.002170.00500 mg/L 03/07/12 09:30 03/07/12 18:09 1Nickel

0.407 U 0.4071.00 mg/L 03/07/12 09:30 03/07/12 18:09 1Potassium

0.00108 U 0.001080.00500 mg/L 03/07/12 09:30 03/07/12 18:09 1Selenium

0.00355 U 0.003550.0250 mg/L 03/07/12 09:30 03/07/12 18:09 1Zinc




MQL MDL

Aluminum 0.0225 U 0.0500 0.0225 mg/L 03/07/12 09:30 03/08/12 16:46 1

MB MB


0.00161 U 0.001610.00500 mg/L 03/07/12 09:30 03/08/12 16:46 1Antimony

0.00109 U 0.001090.00500 mg/L 03/07/12 09:30 03/08/12 16:46 1Arsenic

0.000810 U 0.0008100.00500 mg/L 03/07/12 09:30 03/08/12 16:46 1Barium

0.000854 U 0.0008540.00200 mg/L 03/07/12 09:30 03/08/12 16:46 1Cadmium

0.198 U 0.1980.500 mg/L 03/07/12 09:30 03/08/12 16:46 1Calcium

0.00140 U 0.001400.00500 mg/L 03/07/12 09:30 03/08/12 16:46 1Chromium

0.00136 U 0.001360.00500 mg/L 03/07/12 09:30 03/08/12 16:46 1Cobalt

0.00200 U 0.002000.0100 mg/L 03/07/12 09:30 03/08/12 16:46 1Copper

0.101 U 0.1010.250 mg/L 03/07/12 09:30 03/08/12 16:46 1Iron

0.000733 U 0.0007330.00500 mg/L 03/07/12 09:30 03/08/12 16:46 1Lead

0.113 U 0.1130.500 mg/L 03/07/12 09:30 03/08/12 16:46 1Magnesium

0.0116 U 0.01160.0500 mg/L 03/07/12 09:30 03/08/12 16:46 1Manganese

0.00140 U 0.001400.00500 mg/L 03/07/12 09:30 03/08/12 16:46 1Molybdenum

0.00217 U 0.002170.00500 mg/L 03/07/12 09:30 03/08/12 16:46 1Nickel

0.407 U 0.4071.00 mg/L 03/07/12 09:30 03/08/12 16:46 1Potassium

0.00108 U 0.001080.00500 mg/L 03/07/12 09:30 03/08/12 16:46 1Selenium

0.727 U 0.7271.00 mg/L 03/07/12 09:30 03/08/12 16:46 1Sodium

0.000693 U 0.0006930.00100 mg/L 03/07/12 09:30 03/08/12 16:46 1Thallium

0.00355 U 0.003550.0250 mg/L 03/07/12 09:30 03/08/12 16:46 1Zinc

Client Sample ID: Lab Control SampleLab Sample ID: LCS 560-70320/2-A



Aluminum 4.00 3.599 mg/L 90 80 - 120

Analyte

LCS LCS

DUnitResult Qualifier %Rec

Spike

Added

%Rec.

Limits

Antimony 0.400 0.4095 mg/L 102 80 - 120


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Method: 6020 - Metals (ICP/MS) (Continued)




Barium 0.400 0.4252 mg/L 106 80 - 120

Analyte

LCS LCS


Spike

Added

%Rec.

Limits

Cadmium 0.400 0.3868 mg/L 97 80 - 120

Calcium 40.0 41.33 mg/L 103 80 - 120

Chromium 0.400 0.4084 mg/L 102 80 - 120

Cobalt 0.400 0.4091 mg/L 102 80 - 120

Copper 0.400 0.4078 mg/L 102 80 - 120

Iron 40.0 42.51 mg/L 106 80 - 120

Lead 0.400 0.4896 mg/L 122 80 - 120

Manganese 4.00 4.656 mg/L 116 80 - 120

Molybdenum 0.400 0.4000 mg/L 100 80 - 120

Nickel 0.400 0.3987 mg/L 100 80 - 120

Potassium 40.0 39.27 mg/L 98 80 - 120

Selenium 0.400 0.3607 mg/L 90 80 - 120

Zinc 0.400 0.4236 mg/L 106 80 - 120




Aluminum 4.00 3.484 mg/L 87 80 - 120

Analyte

LCS LCS


Spike

Added

%Rec.

Limits

Antimony 0.400 0.3680 mg/L 92 80 - 120

Arsenic 0.400 0.3743 mg/L 94 80 - 120

Barium 0.400 0.3731 mg/L 93 80 - 120

Cadmium 0.400 0.3633 mg/L 91 80 - 120

Calcium 40.0 38.74 mg/L 97 80 - 120

Chromium 0.400 0.3654 mg/L 91 80 - 120

Cobalt 0.400 0.3712 mg/L 93 80 - 120

Copper 0.400 0.3611 mg/L 90 80 - 120

Iron 40.0 37.40 mg/L 94 80 - 120

Lead 0.400 0.3882 mg/L 97 80 - 120

Magnesium 40.0 34.83 mg/L 87 80 - 120

Manganese 4.00 3.997 mg/L 100 80 - 120

Molybdenum 0.400 0.3686 mg/L 92 80 - 120

Nickel 0.400 0.3688 mg/L 92 80 - 120

Potassium 40.0 36.23 mg/L 91 80 - 120

Selenium 0.400 0.3636 mg/L 91 80 - 120

Sodium 40.0 33.19 mg/L 83 80 - 120

Thallium 0.200 0.1868 mg/L 93 80 - 120

Zinc 0.400 0.3703 mg/L 93 80 - 120




MQL MDL

Antimony 0.00161 U 0.00500 0.00161 mg/L 03/08/12 09:30 03/08/12 23:20 1

MB MB


0.00109 U 0.001090.00500 mg/L 03/08/12 09:30 03/08/12 23:20 1Arsenic

0.000810 U 0.0008100.00500 mg/L 03/08/12 09:30 03/08/12 23:20 1Barium

0.000854 U 0.0008540.00200 mg/L 03/08/12 09:30 03/08/12 23:20 1Cadmium


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MQL MDL

Chromium 0.00140 U 0.00500 0.00140 mg/L 03/08/12 09:30 03/08/12 23:20 1

MB MB


0.00136 U 0.001360.00500 mg/L 03/08/12 09:30 03/08/12 23:20 1Cobalt

0.00200 U 0.002000.0100 mg/L 03/08/12 09:30 03/08/12 23:20 1Copper

0.101 U 0.1010.250 mg/L 03/08/12 09:30 03/08/12 23:20 1Iron

0.000733 U 0.0007330.00500 mg/L 03/08/12 09:30 03/08/12 23:20 1Lead

0.00140 U 0.001400.00500 mg/L 03/08/12 09:30 03/08/12 23:20 1Molybdenum

0.00217 U 0.002170.00500 mg/L 03/08/12 09:30 03/08/12 23:20 1Nickel

0.00108 U 0.001080.00500 mg/L 03/08/12 09:30 03/08/12 23:20 1Selenium

0.000693 U 0.0006930.00100 mg/L 03/08/12 09:30 03/08/12 23:20 1Thallium

0.00355 U 0.003550.0250 mg/L 03/08/12 09:30 03/08/12 23:20 1Zinc




Antimony 0.400 0.3705 mg/L 93 80 - 120

Analyte

LCS LCS


Spike

Added

%Rec.

Limits

Arsenic 0.400 0.3724 mg/L 93 80 - 120

Barium 0.400 0.3752 mg/L 94 80 - 120

Cadmium 0.400 0.3570 mg/L 89 80 - 120

Chromium 0.400 0.3733 mg/L 93 80 - 120

Cobalt 0.400 0.3784 mg/L 95 80 - 120

Copper 0.400 0.3741 mg/L 94 80 - 120

Iron 40.0 37.96 mg/L 95 80 - 120

Lead 0.400 0.3732 mg/L 93 80 - 120

Molybdenum 0.400 0.3643 mg/L 91 80 - 120

Nickel 0.400 0.3694 mg/L 92 80 - 120

Selenium 0.400 0.3536 mg/L 88 80 - 120

Thallium 0.200 0.1841 mg/L 92 80 - 120

Zinc 0.400 0.3668 mg/L 92 80 - 120

Client Sample ID: EP-85Lab Sample ID: 560-31034-1 MS

Matrix: Water Prep Type: Dissolved


Antimony 0.0394 0.400 0.4095 mg/L 93 80 - 120

Analyte

MS MS


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits

Arsenic 1.30 0.400 1.646 mg/L 88 80 - 120

Barium 0.0315 0.400 0.4126 mg/L 95 80 - 120

Cadmium 0.000854 U 0.400 0.3432 mg/L 86 80 - 120

Chromium 0.00302 J 0.400 0.3777 mg/L 94 80 - 120

Cobalt 0.00136 U 0.400 0.3723 mg/L 93 80 - 120

Copper 0.00200 U 0.400 0.3576 mg/L 89 80 - 120

Iron 0.101 U 40.0 37.72 mg/L 94 80 - 120

Lead 0.000733 U 0.400 0.3651 mg/L 91 80 - 120

Molybdenum 0.537 0.400 0.9009 mg/L 91 80 - 120

Nickel 0.00217 U 0.400 0.3664 mg/L 92 80 - 120

Selenium 0.130 0.400 0.4584 mg/L 82 80 - 120

Thallium 0.0100 0.200 0.1880 mg/L 89 80 - 120

Zinc 0.00355 U 0.400 0.3581 mg/L 90 80 - 120


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Client Sample ID: EP-85Lab Sample ID: 560-31034-1 MSD

Matrix: Water Prep Type: Dissolved


Antimony 0.0394 0.400 0.4048 mg/L 91 80 - 120 1 20

Analyte

RPDMSD MSD

DUnitResult Qualifier RPD%Rec

Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits Limit

Arsenic 1.30 0.400 1.640 mg/L 86 80 - 120 0 20

Barium 0.0315 0.400 0.4034 mg/L 93 80 - 120 2 20

Cadmium 0.000854 U 0.400 0.3379 mg/L 84 80 - 120 2 20

Chromium 0.00302 J 0.400 0.3755 mg/L 93 80 - 120 1 20

Cobalt 0.00136 U 0.400 0.3736 mg/L 93 80 - 120 0 20

Copper 0.00200 U 0.400 0.3588 mg/L 90 80 - 120 0 20

Iron 0.101 U 40.0 37.75 mg/L 94 80 - 120 0 20

Lead 0.000733 U 0.400 0.3625 mg/L 91 80 - 120 1 20

Molybdenum 0.537 0.400 0.9013 mg/L 91 80 - 120 0 20

Nickel 0.00217 U 0.400 0.3599 mg/L 90 80 - 120 2 20

Selenium 0.130 0.400 0.4627 mg/L 83 80 - 120 1 20

Thallium 0.0100 0.200 0.1892 mg/L 90 80 - 120 1 20

Zinc 0.00355 U 0.400 0.3504 mg/L 88 80 - 120 2 20

Method: 7470A - Mercury (CVAA)




MQL MDL

Mercury 0.000130 U 0.00200 0.000130 mg/L 03/07/12 12:30 03/07/12 17:37 1

MB MB





Mercury 0.00500 0.004980 mg/L 100 80 - 120

Analyte

LCS LCS


Spike

Added

%Rec.

Limits




MQL MDL

Mercury 0.000130 U 0.00200 0.000130 mg/L 03/08/12 10:00 03/08/12 14:18 1

MB MB





Mercury 0.00500 0.004920 mg/L 98 80 - 120

Analyte

LCS LCS


Spike

Added

%Rec.

Limits


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2

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Method: 160.1 - Solids, Total Dissolved (TDS)

Client Sample ID: Method BlankLab Sample ID: MB 560-70251/1


Analysis Batch: 70251

MQL MDL

Total Dissolved Solids 10.0 U 10.0 10.0 mg/L 03/05/12 10:45 1

MB MB


Client Sample ID: Lab Control SampleLab Sample ID: LCS 560-70251/2



Total Dissolved Solids 2250 2172 mg/L 97 80 - 120

Analyte

LCS LCS


Spike

Added

%Rec.

Limits




Total Dissolved Solids 3260 2250 5605 mg/L 104 75 - 125

Analyte

MS MS


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits

Client Sample ID: EP-117Lab Sample ID: 560-31034-7 DU



Total Dissolved Solids 3260 3370 mg/L 3 20

Analyte

RPDDU DU

DUnitResult Qualifier RPD

Sample

Result

Sample

Qualifier Limit

Method: 160.2 - Solids, Total Suspended (TSS)




MQL MDL

Total Suspended Solids 3.00 U 3.00 3.00 mg/L 03/06/12 09:15 1

MB MB


Method: 300.0 - Anions, Ion Chromatography




MQL MDL

Chloride 0.192 U 1.00 0.192 mg/L 03/02/12 12:15 1

MB MB


0.200 U 0.2000.500 mg/L 03/02/12 12:15 1Nitrate Nitrite as N




Chloride 10.0 9.639 mg/L 96 90 - 110

Analyte

LCS LCS


Spike

Added

%Rec.

Limits


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Method: 300.0 - Anions, Ion Chromatography (Continued)

Client Sample ID: FD030212Lab Sample ID: 560-31034-4 MS



Chloride 310 500 744.2 mg/L 87 80 - 120

Analyte

MS MS


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits

Client Sample ID: FD030212Lab Sample ID: 560-31034-4 MSD



Chloride 310 500 730.8 mg/L 84 80 - 120 2 20

Analyte

RPDMSD MSD


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits Limit




MQL MDL

Chloride 0.192 U 1.00 0.192 mg/L 03/07/12 11:27 1

MB MB



0.377 U 0.3771.00 mg/L 03/07/12 11:27 1Sulfate




MQL MDL

Chloride 0.192 U 1.00 0.192 mg/L 03/06/12 12:37 1

MB MB



0.377 U 0.3771.00 mg/L 03/06/12 12:37 1Sulfate




Chloride 10.0 10.57 mg/L 106 90 - 110

Analyte

LCS LCS


Spike

Added

%Rec.

Limits

Sulfate 25.0 26.24 mg/L 105 90 - 110




Chloride 10.0 10.60 mg/L 106 90 - 110

Analyte

LCS LCS


Spike

Added

%Rec.

Limits

Sulfate 25.0 26.12 mg/L 104 90 - 110




Chloride 151 250 402.9 mg/L 101 80 - 120

Analyte

MS MS


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits

Sulfate 678 500 1169 mg/L 98 80 - 120


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Method: 300.0 - Anions, Ion Chromatography (Continued)




Chloride 151 250 397.4 mg/L 99 80 - 120 1 20

Analyte

RPDMSD MSD


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits Limit

Sulfate 678 500 1153 mg/L 95 80 - 120 1 20

Method: 340.2 - Fluoride




MQL MDL

Fluoride 0.0200 U 0.100 0.0200 mg/L 03/05/12 09:50 1

MB MB





Fluoride 0.800 0.7980 mg/L 100 85 - 115

Analyte

LCS LCS


Spike

Added

%Rec.

Limits

Method: 376.2 - Sulfide




MQL MDL

Sulfide 0.0131 U 0.0500 0.0131 mg/L 03/02/12 11:10 1

MB MB





Sulfide 0.535 0.4770 mg/L 89 80 - 120

Analyte

LCS LCS


Spike

Added

%Rec.

Limits




Sulfide 0.0220 J 0.535 0.5420 mg/L 97 75 - 125

Analyte

MS MS


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits




Sulfide 0.0220 J 0.535 0.5180 mg/L 93 75 - 125 5 20

Analyte

RPDMSD MSD


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits Limit


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Method: 415.1 - TOC




MQL MDL

Total Organic Carbon 0.285 U 1.00 0.285 mg/L 03/07/12 12:15 1

MB MB





Total Organic Carbon 25.0 22.93 mg/L 92 80 - 120

Analyte

LCS LCS


Spike

Added

%Rec.

Limits

Method: SM 2320B - Alkalinity




Total Alkalinity as CaCO3 100 92.60 mg/L 93 85 - 115

Analyte

LCS LCS


Spike

Added

%Rec.

Limits





Analyte

LCS LCS


Spike

Added

%Rec.

Limits





Analyte

LCS LCS


Spike

Added

%Rec.

Limits


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Certification SummaryClient: Malcolm Pirnie, Inc. Invoice to Arcadis TestAmerica Job ID: 560-31034-1

Project/Site: Former ASARCO Groundwater SDG: March 1, 2012

Laboratory Authority Program EPA Region Certification ID

TestAmerica Corpus Christi E-10362NELACKansas 7

TestAmerica Corpus Christi 9968State ProgramOklahoma 6

TestAmerica Corpus Christi T104704210-11-5NELACTexas 6

TestAmerica Corpus Christi P330-11-00060FederalUSDA

Accreditation may not be offered or required for all methods and analytes reported in this package . Please contact your project manager for the laboratory's

current list of certified methods and analytes.


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Method SummaryTestAmerica Job ID: 560-31034-1Client: Malcolm Pirnie, Inc. Invoice to Arcadis


Method Method Description LaboratoryProtocol

SW8466020 Metals (ICP/MS) TAL CC

SW8467470A Mercury (CVAA) TAL CC

MCAWW160.1 Solids, Total Dissolved (TDS) TAL CC

MCAWW160.2 Solids, Total Suspended (TSS) TAL CC

MCAWW300.0 Anions, Ion Chromatography TAL CC

MCAWW340.2 Fluoride TAL CC

MCAWW376.2 Sulfide TAL CC

MCAWW415.1 TOC TAL CC

SMSM 2320B Alkalinity TAL CC

Protocol References:

MCAWW = "Methods For Chemical Analysis Of Water And Wastes", EPA-600/4-79-020, March 1983 And Subsequent Revisions.

SM = "Standard Methods For The Examination Of Water And Wastewater",

SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.

Laboratory References:

TAL CC = TestAmerica Corpus Christi, 1733 N. Padre Island Drive, Corpus Christi, TX 78408, TEL (361)289-2673


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Sample SummaryTestAmerica Job ID: 560-31034-1Client: Malcolm Pirnie, Inc. Invoice to Arcadis


Lab Sample ID Client Sample ID ReceivedCollectedMatrix

560-31034-1 EP-85 Water 03/01/12 08:00 03/02/12 10:25

560-31034-2 EP-81 Water 03/01/12 09:15 03/02/12 10:25

560-31034-3 OBS-1 Water 03/01/12 10:15 03/02/12 10:25

560-31034-4 FD030212 Water 03/01/12 00:00 03/02/12 10:25

560-31034-5 EP-114 Water 03/01/12 11:05 03/02/12 10:25

560-31034-6 EP-116 Water 03/01/12 14:20 03/02/12 10:25

560-31034-7 EP-117 Water 03/01/12 15:20 03/02/12 10:25


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Login Sample Receipt Checklist

Client: Malcolm Pirnie, Inc. Invoice to Arcadis Job Number: 560-31034-1

SDG Number: March 1, 2012

Login Number: 31034

Question Answer Comment

Creator: Magee, Alice J.

List Source: TestAmerica Corpus Christi

List Number: 1

N/ARadioactivity either was not measured or, if measured, is at or below

background

TrueThe cooler's custody seal, if present, is intact.

TrueThe cooler or samples do not appear to have been compromised or

tampered with.

TrueSamples were received on ice.

TrueCooler Temperature is acceptable.

TrueCooler Temperature is recorded.

TrueCOC is present.

TrueCOC is filled out in ink and legible.

TrueCOC is filled out with all pertinent information.

FalseIs the Field Sampler's name present on COC?

TrueThere are no discrepancies between the sample IDs on the containers and

the COC.

TrueSamples are received within Holding Time.

TrueSample containers have legible labels.

TrueContainers are not broken or leaking.

TrueSample collection date/times are provided.

TrueAppropriate sample containers are used.

TrueSample bottles are completely filled.

TrueSample Preservation Verified.

TrueThere is sufficient vol. for all requested analyses, incl. any requested

MS/MSDs

N/AVOA sample vials do not have headspace or bubble is <6mm (1/4") in

diameter.

TrueMultiphasic samples are not present.

TrueSamples do not require splitting or compositing.

N/AResidual Chlorine Checked.


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Default Detection LimitsClient: Malcolm Pirnie, Inc. Invoice to Arcadis TestAmerica Job ID: 560-31034-1


Method: 6020 - Metals (ICP/MS)

0.0500 6020Aluminum mg/L

Analyte Units Method

0.0225

MDLMQL

60200.001610.00500Antimony mg/L

60200.001090.00500Arsenic mg/L

60200.0008100.00500Barium mg/L

60200.0008540.00200Cadmium mg/L

60200.1980.500Calcium mg/L

60200.001400.00500Chromium mg/L

60200.001360.00500Cobalt mg/L

60200.002000.0100Copper mg/L

60200.1010.250Iron mg/L

60200.0007330.00500Lead mg/L

60200.1130.500Magnesium mg/L

60200.01160.0500Manganese mg/L

60200.001400.00500Molybdenum mg/L

60200.002170.00500Nickel mg/L

60200.4071.00Potassium mg/L

60200.001080.00500Selenium mg/L

60200.7271.00Sodium mg/L

60200.0006930.00100Thallium mg/L

60200.003550.0250Zinc mg/L

Method: 6020 - Metals (ICP/MS) - Dissolved

0.00500 6020Antimony mg/L


0.00161

MDLMQL

60200.001090.00500Arsenic mg/L

60200.0008100.00500Barium mg/L

60200.0008540.00200Cadmium mg/L

60200.001400.00500Chromium mg/L

60200.001360.00500Cobalt mg/L

60200.002000.0100Copper mg/L

60200.1010.250Iron mg/L

60200.0007330.00500Lead mg/L

60200.001400.00500Molybdenum mg/L

60200.002170.00500Nickel mg/L

60200.001080.00500Selenium mg/L

60200.0006930.00100Thallium mg/L

60200.003550.0250Zinc mg/L

Method: 7470A - Mercury (CVAA)

0.00200 7470AMercury mg/L


0.000130

MDLMQL

Method: 7470A - Mercury (CVAA) - Dissolved

0.00200 7470AMercury mg/L


0.000130

MDLMQL

General Chemistry

10.0 160.1Total Dissolved Solids mg/L


10.0

MDLMQL

160.23.003.00Total Suspended Solids mg/L

TestAmerica Corpus Christi

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Default Detection LimitsClient: Malcolm Pirnie, Inc. Invoice to Arcadis TestAmerica Job ID: 560-31034-1


General Chemistry (Continued)

1.00 300.0Chloride mg/L


0.192

MDLMQL

300.00.2000.500Nitrate Nitrite as N mg/L

300.00.3771.00Sulfate mg/L

340.20.02000.100Fluoride mg/L

376.20.01310.0500Sulfide mg/L

415.10.2851.00Total Organic Carbon mg/L

SM 2320B5.005.00Total Alkalinity as CaCO3 mg/L

TestAmerica Corpus Christi

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Documents

ANALYTICAL REPORT 6 - Asarco · ANALYTICAL REPORT TestAmerica Laboratories, Inc. TestAmerica Corpus Christi 1733 N. Padre Island Drive Corpus Christi, TX 78408 Tel: (361)289-2673