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8/11/2019 3 Presentasi - Fire & Explosion
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KELOMPOK:
1. Cinthia Yunitha
2. Irwan Junawanto3. Ronald Sebastian
4. Anindhita Yuriska
5. Mengku Harjanti
6. Muh. Reza Pahlepi7. Gisda Irwanti
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ChainReaction
Fuel O2
Heat
All Elements are required to have afire
Ignition Temperature :Activation energy (heat)
which is needed to activatechain reaction.
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Class IA : Flash point < 22,8oC and boiling point < 37,8oC.
Class IB : Flash point < 22,8oC and boiling point 37,8oC.
Class IC : Flash point 22,8oC and boiling point < 37,8oC.
Class II : Flash point > 37o
C and boiling point < 60o
C. Class IIIA : Flash point 60oC and boiling point < 93,4oC.
Class IIIB : Flash point > 93,4oC.
Flash point :The lowest temperature that will allow a liquid to produce aflammable vapor.
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Classification from forensic standpoint
Natural Fires : Lightning strikes, Natural gasses escapefrom ground.
Accidental Fires : Malfunction of furnace, spontaneouscombustion (cloth+fuel chain reaction).
Deliberate Fires : burn trash, arson.
Classification from fire scene investigator
Direct Ignition : Flameor sparkfuel
Electrical Fires : spark
heat
fuel + O2 Weather-Related Fires : Lightning strikes or magnifying
glass effect.
Mechanical Fires : overheat machines.
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Fire scenes investigator must be aware of :1. Causes of fires.
2. Burning patterns.
3. How different materials react on fire.
4. The characteristic of points of fire origin.
5. How fires normally proceed through a structure.
6. Unusual fire characteristics.
7. The effects of fire suppresion on the scene.The investigator must proceed in an orderly, methodicalway and must make accurate, records of the investigation,examination from outside to inside or the point of origin.
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Arson Dogs:(+)Enable to search for accelerants
much faster and more efficiently.
(-)Cant discriminate between a real
accelerant and a hydrocarbon
that is part of some object and was released by the fire.
Point of Entry and Exit :
In the case of deliberate fire within building, there would be apoint where this person entered the building.
Physical evidence can be found includes fingerprints, shoeprints, hairs and fibers, and even blood.
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Low Burning : start in low area of a building.
V-Patterns : the point of origin near wall or corner of theroom.
Wood Charring : depend on intensitt of heat and time ofexposure.
Spalling of plaster or cencrete : destruction due to heat.
Material Distortion : metal and glass may melt or distort
owing to high heat. Soot and smoke staining : soot may indicate point of origin
and direction of travel of the fire.
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The presence of an accelerant : usually present at or nearthe point of origin.
Elimination of natural or accidental causes of fire.
Fire trails : normally would not be seen in acciedental ornatural fire.
Multiple points of origin.
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Airtight Container
Metal Container : paint cans, glass jar.
Bags :
- Paper bags : cant exposed to water- Polyethylene bags : may be reactive to some
hydrocarbon
- Polyvinylidine bags : impervious to solvents andflammable materials
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Consist of two major steps :1. Isolation of Accelerant Residue
Typical types of exhibits encountered :
Neat Ignitable liquid
Partially burned accelerants Nearly completely burned accelerants
Headspace Methods
The residue is put in a sealed metal
container. The vapor of accelerant can besampled on the headspace with a gastightsyringe.
Fire debris
headspace
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Adsorbtion Methods
Passive adsorption : charcoal or tenax placed inside thecontainer.
Active adsorption (adsorption-elution) : two tubescontaining charcoal or tenax inserted into the containerthrough holes in the top.
Air PumpVacuum
CS2
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Solvent Extraction
Small quantity of suitable solvent (carbon disulfide) added to thecontainer. The solvent is poured off and filtered and then evaporated toa small volume.
( - ) First, the solvent will dissolve unwanted pyrolysis products, matrixmaterials, and other substances. Second, the evaporation steps mayalso evaporate volatile components of accelerant residues.
Filter Accelerant residue
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Steam DistillationThis method is not very sensitive and relatively needed largequantity of matrix and also complicated to run.
2. Determine the type of ignitable liquid
This process involves gas chromatography. The basic analysis ofgas chromatography is the pattern of peaks that is characteristicof the accelerant type.
Mass spectrometry
It provides features in identifying ignitable liqueds presence ofcontaminants or in mixture of multiple ignitable liquids.
Selective ion monitoring
Target compund analysis
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Explosion The Process of internal burning
Rapid oxidation reaction
Production of large quantities of gases
Heat expands gases Sudden build up of gas pressure
Explosive Chemical composition ( solid, liquid, gas)
unstable
Initiated by friction, shock or heat
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Velocity of detonation below 3,280 fps
Produces greater propellant effect and few
blasting effectdisrupts surroundings
Generally sensitive to fire, impact and
friction and are easily initiated
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Black powder Potassium or sodium nitrate Charcoal Sulfur
Pipe bombs Potassium chlorate Fuels
Sugar Carbon Sulfur Starch Magnesium filings
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Smokeless powder
Most powerful
Single base powder
Nitrated cotton or
nitrocellulose
Double base powder
Nitroglycerin and
nitrocellulose
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Ammonium nitrate soaked in fuel oil
Inexpensive
Safe to handle
Ammonium nitrate
fertilizer used
in home-madeexplosives
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Velocity of detonation above 3,280 fps
Extremely rapid oxidation
Accompanied by violent disruptive shock
Disrupts surroundings
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Very powerful dan very sensitive
Provide major ingredients found in blastingcaps or primers used to detonate otherexplosives
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Relatively insensitive to heat, shock, or friction
Normally burn rather than detonate if ignited insmall quantities in the open air
Majority of commercial and military blasting Dynamite
TNT - trinitrotoluene
PETN pentaerythritol tetranitrate
RDX cyclotrimethylenetrinitramine Tetryl 2, 4, 6-trinitrophenylmethylnitramine
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Dynamite: Nobel Nitroglycerine
Kieselguhr(diatomacious earth)
Modern
Nitroglycerine
Wood pulp
Sodium nitrate (oxygen) Stabilizer (calcium carbonate
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Replaced by ammonium nitrate-basedexplosives
Water gels
EmulsionsANFO explosives
Low cost
Very stable
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Set gelatin or gel toothpaste
Water resistant: underwater blasting
Composition
Ammonium nitrate
Sodium nitrate
Gelled with guar gum
Aluminum as fuel
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Oil phase
Water phase
Droplet of supersaturated ammonium nitrate
solution Surrounded by hydrocarbon fuel
Typical Water
One or more inorganic nitrate oxidizers
Oil
Emulsifying agents
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Microspheres/microballoons Micron-sized glass
Resin
Ceramic spheres Control
Sensitivity
Detonation velocity
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Triacetone triperoxideAcetone
Hydrogen peroxide
Catalyst (HCl) Terrorist explosives
Friction sensitive
Impact sensitive Potent in confined container
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Accessible outside US
RDX
Composition
C-4 (US military) Pliable plastic
Dough-like
consistency
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Most important military bursting charge explosive Wide application
Shells Bombs
Grenaqdes Demolition explosives Propellant compositions
Military dynamite No nitroglycerin RDX and TNT
Rarely encountered in US
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Used with TNT
Small caliber projectiles and grenades
Detonating cord/primacord
Connect explosive charges
Detonate immediately
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BOM
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Fragmentation Effect
Thermal Effect
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Undetonated residues at site
Samples taken from
appropriate locations
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Terkena luka, deskripsi lukanya jika jari tangannyahancur?
Cara screening area sekitar ledakan, screening residu
Pmx forensik bekas terkena petir
Proses perubahan2 kulit pada kebakaran
Tanda intravital korban kebakaran msh hidup