3 Presentasi - Fire & Explosion

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    KELOMPOK:

    1. Cinthia Yunitha

    2. Irwan Junawanto3. Ronald Sebastian

    4. Anindhita Yuriska

    5. Mengku Harjanti

    6. Muh. Reza Pahlepi7. Gisda Irwanti

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    ChainReaction

    Fuel O2

    Heat

    All Elements are required to have afire

    Ignition Temperature :Activation energy (heat)

    which is needed to activatechain reaction.

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    Class IA : Flash point < 22,8oC and boiling point < 37,8oC.

    Class IB : Flash point < 22,8oC and boiling point 37,8oC.

    Class IC : Flash point 22,8oC and boiling point < 37,8oC.

    Class II : Flash point > 37o

    C and boiling point < 60o

    C. Class IIIA : Flash point 60oC and boiling point < 93,4oC.

    Class IIIB : Flash point > 93,4oC.

    Flash point :The lowest temperature that will allow a liquid to produce aflammable vapor.

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    Classification from forensic standpoint

    Natural Fires : Lightning strikes, Natural gasses escapefrom ground.

    Accidental Fires : Malfunction of furnace, spontaneouscombustion (cloth+fuel chain reaction).

    Deliberate Fires : burn trash, arson.

    Classification from fire scene investigator

    Direct Ignition : Flameor sparkfuel

    Electrical Fires : spark

    heat

    fuel + O2 Weather-Related Fires : Lightning strikes or magnifying

    glass effect.

    Mechanical Fires : overheat machines.

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    Fire scenes investigator must be aware of :1. Causes of fires.

    2. Burning patterns.

    3. How different materials react on fire.

    4. The characteristic of points of fire origin.

    5. How fires normally proceed through a structure.

    6. Unusual fire characteristics.

    7. The effects of fire suppresion on the scene.The investigator must proceed in an orderly, methodicalway and must make accurate, records of the investigation,examination from outside to inside or the point of origin.

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    Arson Dogs:(+)Enable to search for accelerants

    much faster and more efficiently.

    (-)Cant discriminate between a real

    accelerant and a hydrocarbon

    that is part of some object and was released by the fire.

    Point of Entry and Exit :

    In the case of deliberate fire within building, there would be apoint where this person entered the building.

    Physical evidence can be found includes fingerprints, shoeprints, hairs and fibers, and even blood.

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    Low Burning : start in low area of a building.

    V-Patterns : the point of origin near wall or corner of theroom.

    Wood Charring : depend on intensitt of heat and time ofexposure.

    Spalling of plaster or cencrete : destruction due to heat.

    Material Distortion : metal and glass may melt or distort

    owing to high heat. Soot and smoke staining : soot may indicate point of origin

    and direction of travel of the fire.

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    The presence of an accelerant : usually present at or nearthe point of origin.

    Elimination of natural or accidental causes of fire.

    Fire trails : normally would not be seen in acciedental ornatural fire.

    Multiple points of origin.

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    Airtight Container

    Metal Container : paint cans, glass jar.

    Bags :

    - Paper bags : cant exposed to water- Polyethylene bags : may be reactive to some

    hydrocarbon

    - Polyvinylidine bags : impervious to solvents andflammable materials

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    Consist of two major steps :1. Isolation of Accelerant Residue

    Typical types of exhibits encountered :

    Neat Ignitable liquid

    Partially burned accelerants Nearly completely burned accelerants

    Headspace Methods

    The residue is put in a sealed metal

    container. The vapor of accelerant can besampled on the headspace with a gastightsyringe.

    Fire debris

    headspace

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    Adsorbtion Methods

    Passive adsorption : charcoal or tenax placed inside thecontainer.

    Active adsorption (adsorption-elution) : two tubescontaining charcoal or tenax inserted into the containerthrough holes in the top.

    Air PumpVacuum

    CS2

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    Solvent Extraction

    Small quantity of suitable solvent (carbon disulfide) added to thecontainer. The solvent is poured off and filtered and then evaporated toa small volume.

    ( - ) First, the solvent will dissolve unwanted pyrolysis products, matrixmaterials, and other substances. Second, the evaporation steps mayalso evaporate volatile components of accelerant residues.

    Filter Accelerant residue

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    Steam DistillationThis method is not very sensitive and relatively needed largequantity of matrix and also complicated to run.

    2. Determine the type of ignitable liquid

    This process involves gas chromatography. The basic analysis ofgas chromatography is the pattern of peaks that is characteristicof the accelerant type.

    Mass spectrometry

    It provides features in identifying ignitable liqueds presence ofcontaminants or in mixture of multiple ignitable liquids.

    Selective ion monitoring

    Target compund analysis

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    Explosion The Process of internal burning

    Rapid oxidation reaction

    Production of large quantities of gases

    Heat expands gases Sudden build up of gas pressure

    Explosive Chemical composition ( solid, liquid, gas)

    unstable

    Initiated by friction, shock or heat

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    Velocity of detonation below 3,280 fps

    Produces greater propellant effect and few

    blasting effectdisrupts surroundings

    Generally sensitive to fire, impact and

    friction and are easily initiated

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    Black powder Potassium or sodium nitrate Charcoal Sulfur

    Pipe bombs Potassium chlorate Fuels

    Sugar Carbon Sulfur Starch Magnesium filings

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    Smokeless powder

    Most powerful

    Single base powder

    Nitrated cotton or

    nitrocellulose

    Double base powder

    Nitroglycerin and

    nitrocellulose

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    Ammonium nitrate soaked in fuel oil

    Inexpensive

    Safe to handle

    Ammonium nitrate

    fertilizer used

    in home-madeexplosives

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    Velocity of detonation above 3,280 fps

    Extremely rapid oxidation

    Accompanied by violent disruptive shock

    Disrupts surroundings

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    Very powerful dan very sensitive

    Provide major ingredients found in blastingcaps or primers used to detonate otherexplosives

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    Relatively insensitive to heat, shock, or friction

    Normally burn rather than detonate if ignited insmall quantities in the open air

    Majority of commercial and military blasting Dynamite

    TNT - trinitrotoluene

    PETN pentaerythritol tetranitrate

    RDX cyclotrimethylenetrinitramine Tetryl 2, 4, 6-trinitrophenylmethylnitramine

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    Dynamite: Nobel Nitroglycerine

    Kieselguhr(diatomacious earth)

    Modern

    Nitroglycerine

    Wood pulp

    Sodium nitrate (oxygen) Stabilizer (calcium carbonate

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    Replaced by ammonium nitrate-basedexplosives

    Water gels

    EmulsionsANFO explosives

    Low cost

    Very stable

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    Set gelatin or gel toothpaste

    Water resistant: underwater blasting

    Composition

    Ammonium nitrate

    Sodium nitrate

    Gelled with guar gum

    Aluminum as fuel

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    Oil phase

    Water phase

    Droplet of supersaturated ammonium nitrate

    solution Surrounded by hydrocarbon fuel

    Typical Water

    One or more inorganic nitrate oxidizers

    Oil

    Emulsifying agents

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    Microspheres/microballoons Micron-sized glass

    Resin

    Ceramic spheres Control

    Sensitivity

    Detonation velocity

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    Triacetone triperoxideAcetone

    Hydrogen peroxide

    Catalyst (HCl) Terrorist explosives

    Friction sensitive

    Impact sensitive Potent in confined container

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    Accessible outside US

    RDX

    Composition

    C-4 (US military) Pliable plastic

    Dough-like

    consistency

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    Most important military bursting charge explosive Wide application

    Shells Bombs

    Grenaqdes Demolition explosives Propellant compositions

    Military dynamite No nitroglycerin RDX and TNT

    Rarely encountered in US

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    Used with TNT

    Small caliber projectiles and grenades

    Detonating cord/primacord

    Connect explosive charges

    Detonate immediately

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    BOM

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    Fragmentation Effect

    Thermal Effect

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    Undetonated residues at site

    Samples taken from

    appropriate locations

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    Terkena luka, deskripsi lukanya jika jari tangannyahancur?

    Cara screening area sekitar ledakan, screening residu

    Pmx forensik bekas terkena petir

    Proses perubahan2 kulit pada kebakaran

    Tanda intravital korban kebakaran msh hidup