2015 GS Caltex Solvent Catalog

GS Tower, 508, Nonhyeon-ro, Gangnam-gu, Seoul 135-985, KoreaTel : (82) 2-2005-6800~6814http://kixxlube.gscaltex.com

Aromatics &Solvent Chemicals

NAPHTHA

- Solvent

- Polystyrene- ABS, SAN- Nylon 6& 66- Epoxy Resin- Poly Carbonate- Phenol

- Polyurethane(TDI)- Solvent

- Solvent- Gasoline stock

- Polyester Fiber- PTA, PET

- Paraxylene- Orthoxylene- Solvent

CCRPLATFORMER

BT EXTRACTIONUNIT

BENZENECOLUMN

TOLUENECOLUMN

TATORAYUNIT

PAREX & ISOMARUNIT

Hv.AROMATICSCOLUMN

MTPXTOLUENE

CRYSTALIZER

BENZENE

TECHSOL-100

P-XYLENE

M-XYLENE

TOLUENE

BENZENE

P-XYLENE

XYLENECOLUMN

TECHSOL-S

Company History Aromatics Process flow ׀

1966 Signed the joint Venture Agreement with Caltex Petroleum Corp of the US1967 Incorporated Honam Oil Refinery in Seoul, Korea1969 Commenced the operations at Yeosu Refinery (60,000 BPSD) Completed the construction of Incheon lubricant plant1986 Established Technology Research Center Revised joint Venture Agreement to establish a Korea based independent management1988 Completed the polypropylene plant (120,000 MTA)1990 Completed the No. 1PX plant (200,000 MTA) and the No. 1 BTX plant (500,000MTA)1995 Became the first company to launch gasoline brand (Techron) Completed the second PX plant (350,000 MTA, total 650,000 MTA) Completed the No. 1 HOU (RFCC, 70000 BPSD)1996 Name changed to LG-Caltex Oil Corporation and new CI announced Refinery capacity expanded to 650,000 BPSD1998 Completed the construction of Central Technology R&D Center1999 Introduced “Six sigma” management innovation scheme2000 Prodaimed “The Leader in Providing Toal Energy Service” as new corporate vision Completed the No.2 BTX plant (400,000 MTA, BTX: from 600,000 MTA to 1 million MTA, PX: 650,000 MTA)

2003 Completed the No.3 PX plant (550,000MTA, BTX: 1 million MTA, PX: from 650,000 MTA to 1.2 million MTA) 2004 Established GS Holdinsgs and vecame a subsidiary of GS Holdings2005 Renamed as GS Caltex Corporation2006 Launched GS Caltex Foundation 2007 Completed the No.2 HOU (VDU 150,000 BPSD, HCR 55,000 BPSD) Completed the Base Oil Plant (16,000 BPSD)2008 Received the USD 15 billion Export Tower Award2010 Completed the No. 3 HOU (VR HCR, 60,000 BPSD, total 215,000 BPSD)2011 Celebrated the No, 3HOU (VRHCR) building completion ceremony Received the USD 20 billion Export Tower Award2012 Established GS Energy Established GS Caltex China Co, Ltd Received the USD 25 billion Export Tower Award2013 Completed the No. 4 HOU (VGOFCC, 53,000 BPSD, total 268,000 BPSD) Completed Czech and jinju Compounded Resin plant2014 Proclaimed “Value no. 1 Energy & Chemical Partner” as new corporate vision

2+3

Aromatics Process flowEnergy has been mankind's constant companion and will continue to be crucial in the future.As Korea’s leading energy company based on the success of petroleum, petrochemical and lubricant businesses, GS Caltex has always been at the heart of the energy industry.GS Caltex will continue to strengthen its competitiveness to become a global energy leader.

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TEST ITEM TEST METHOD SPEC. RESULT

APPEARANCE ASTM D4176 CLEAR CLEAR

ACIDITY, mg/100mL ASTM D847 NO FREE ACID NO FREE ACID

COLOR, ACID WASH ASTM D848 NO.1 Max NO.1

COLOR, Pt-Co SCALE ASTM D1209 NO.20 Max NO.1

COPPER CORR', 30m/100℃ ASTM D849 PASS PASS

Dist. IBP, ℃ ASTM D850 79.9

Dist. 50%, ℃ ASTM D850 80.1

Dist. DP, ℃ ASTM D850 80.2

Dist. RECOVERY, vol% ASTM D850 97.0 Min 98.5

Distillation IBP~DP Range ASTM D850 1 Max 0.3

SULFUR COMPOUNDS ASTM D853 FREE FREE

SOLIDIFICATION POINT, ℃ ASTM D852 5.39 Min 5.52

SPECIFIC GRAVITY AT 15.56℃ ASTM D4052 0.882~0.886 0.8845

THIOPHENE, wtppm ASTM D4735 1.0 Max 0

NON AROMATICS, wt% ASTM D4492 0.10 Max 0.049

BENZENE, wt% ASTM D4492 99.8 Min 99.932

TOLUENE, wt% ASTM D4492 0.05 Max 0.019

Major use : Raw material for phenol, maleic acid, caprolactam, alkylbenzene, styrene and dyestuff intermediate.







Dist. 50%, ℃ ASTM D850 138.4


Dist. RECOVERY, vol% ASTM D850 To be reported 98.5

Distillation IBP~DP Range ASTM D850 2 Max 0.3

DOCTOR TEST UOP 41 SWEET SWEET

SOLIDIFICATION POINT, ℃ ASTM D6875 12.86 Min 13.15


NON AROMATICS, wt% UOP 720 0.2 Max 0.009

BENZENE, wt% UOP 720 0

TOLUENE, wt% UOP 720 0.009

ETHYL BENZENE, wt% UOP 720 0.08

PARA XYLENE, wt% UOP 720 99.7 Min 99.723

Major use : Raw material for Pure Terephthalic Acid (PTA Polyester, PET Resin).








Dist. 50%, ℃ ASTM D850 110.6


Dist. RECOVERY, vol% ASTM D850 To be reported 98.5

Distillation IBP~DP Range ASTM D850 1.0 Max 0.3



NON AROMATICS, wt% ASTM D2360 1.5 Max 0.112

BENZENE, wt% ASTM D2360 0.018

TOLUENE, wt% ASTM D2360 99.85

H20,wtppm UOP 481 To be reported 10.9

Major use : Solvent for paint, rubber and adhesive. Raw material for toluene di-isocyanate.



SPECIFIC GRAVITY,60℉/60℉ ASTM D4052 0.860~0.880 0.878

COLOR SAYBOLT,30m/100℃ ASTM D156 +28 Min 30.0

COPPER CORROSION ASTM D849 PASS PASS

AROMATIC CONTENT,wt% UOP 744 98 Min 99.50

MIXED ANILINE POINT,℃ ASTM D611 16 Max 13.2

FLASH POINT℃ ASTM D56 38 Min 48.0

Dist. IBP,℃ ASTM D86 155 Min 160.0

Dist. 50%,℃ ASTM D86 164.0

Dist. DP,℃ ASTM D86 181 Max 179.0

H20,wtppm UOP 481 11.1

REACTION TEST FM 5101 NEUTRAL

Major use : Solvent for baking paint, metal cleaning, agricultural pesticides. Mogas blending stock.

Major use : Raw material for H � , CO, H � O � .







Dist. IBP, ℃ ASTM D850 137 Min 139.4

Dist. 50%, ℃ ASTM D850 139.8

Dist. DP, ℃ ASTM D850 143.0 Max 140.9

Dist. RECOVERY, vol% ASTM D850 98.5

Distillation IBP~DP RANGE ASTM D850 5 Max 1.5



BROMINE INDEX, mg/100g ASTM D1492 20 Max 0.5

NON AROMATICS, wt% UOP 744 1.0 Max 0.412

ETHYL BENZENE, wt% UOP 744 18.0 Max 13.944

PARA XYLENE, wt% UOP 744 18.0 Min 19.633

Major use : Solvent for paint and agricultural pesticides. Raw material for paraxylene, orthoxylene and ethylbenzene. Pharmaceutical intermediates.

Benzene Toluene Mixed-Xylene

Para-Xylene Techsol-100(C9 Aromatics) Low Sulfur Naphtha

Petrochemicals are altematives that

address the l imitations of natural

resources l ike wood, rubber and fiber.

Used as basic materials in virtually all

sectors, from automobiles and

electronics to construction, textiles

and etc. , petrochemicals form

backbone of industry.

Though ongoing facil ity expansion,

GS Caltex has one of the world's

largest aromatics capacity as a single-

site factory with production capacity of

2.80 mill ion MTA for aromatics

(benzene, toluene, xylene) including

1.35 mill ion MTA of paraxylene.

Aromatics

Aromatics ׀ Aromatics & Solvent Chemicals ׀


BROMINE NUMBER, g/100g ASTM D1159 200 Max 7.97

DENSITY, @15℃g/㎤ ASTM D4052 To be repor ted 0.668

Dist. IBP ℃ ASTM D86 30 Min 36.0

Dist. EP ℃ ASTM D86 140 Max 114.0

SULFUR,wtppm ASTM D5453 2 Max 0.50

PARAFFINES, vol% ASTM D5443 93.2

AROMATICS, vol% ASTM D5443 0.35

NEUTRALITY KSM 2012 NEUTRAL NEUTRAL

A r o m a t i c s & S o l v e n t C h e m i c a l s

6+7


ANILINE POINT,℃ ASTM D611 45 Min 67.8

COPPER CORR',3hr/50℃ ASTM D130 1 Max 1A

DENSITY, @15℃g/㎤ ASTM D4052 To be reported 0.668

Dist. IBP ℃ ASTM D86 30 Min 36.0

Dist. 50% ℃ ASTM D86 90 Max 70.10

Dist. EP ℃ ASTM D86 150 Max 116.0


ODOR OLFACTORY SWEET SWEET



APPEARANCE ASTM D4176 PASS PASS

DENSITY, @15℃, kg/L ASTM D4052 To be reported 0.7455


COLOR, SAYBOLT ASTM D156 25 Min 30

Cu-strip(50℃,3h) ASTM D130 1 Max 1A

Dist. IBP ℃ ASTM D86 80 Min 89

Dist. 50% ℃ ASTM D86 120 Max 109.7

Dist. EP ℃ ASTM D86 160 Max 143

DOCTOR TEST ASTM D4952 SWEET SWEET





APPEARANCE ASTM D4176 PASS PASS

DENSITY, @15℃,kg/L ASTM D4052 To be reported 0.7811




Dist. IBP,℃ ASTM D86 150 ~ 158 157

Dist. 50%,℃ ASTM D86 180 Max 166.9

Dist. EP,℃ ASTM D86 197 ~ 210 197

DOCTOR TEST ASTM D4952 SWEET SWEET

FLASH POINT,TAG,℃ ASTM D56 38 Min 43.5




AROMATICS,vol% IP 391 19.8




COLOR SAYBOLT ASTM D156 To be reported 30


Dist. IBP,℃ ASTM D86 150 Min 150

Dist. 50%,℃ ASTM D86 260 Max 212.8

Dist. EP,℃ ASTM D86 300 Max 292

FLASH POINT,TAG,℃ ASTM D56 38 Min 44.5

SULFUR,wtppm ASTM D5453 3.0 Max 2

Total Aromatics, % IP 391 To be reported 12.4



ANILINE POINT,℃ ASTM D611 To be reported 89


Dist. IBP,℃ ASTM D86 280 Min 280

Dist. 50%,℃ ASTM D86 To be reported 319

Dist. EP,℃ ASTM D86 370 Max 365

FLASH POINT,COC,℃ ASTM D92 50 Min 154

POUR POINT,℃ ASTM D97 -15 Max -24

SULFUR, wtppm ASTM D5453 To be reported 3

VISCOS. KIN. @40℃,㎟/s ASTM D445 To be reported 6.33


VISCOSITY INDEX ASTM D2270 To be reported 88

Refractive Index ASTM D1218 To be reported 1.464

CA,% ASTM D3238 To be reported 3.2

CP,% ASTM D3238 To be reported 59.3

CN,% ASTM D3238 To be reported 37.6

Micro Carbon Residue,wt% ASTM D4530 To be reported 0




ANILINE POINT,℃ ASTM D611 To be reported 71.8

COLOR, SAYBOLT ASTM D156 To be reported 30

Dist. IBP,℃ ASTM D86 280 Min 280.9

Dist. 50%,℃ ASTM D86 305.3

Dist. EP,℃ ASTM D86 360 Min 367

FLASH POINT,COC,℃ ASTM D92 To be reported 146

POUR POINT,℃ ASTM D97 To be reported -30

SULFUR, wtppm ASTM D5453 To be reported 1


VISCOS. KIN. @100℃,㎟/s ASTM D445 2.191

VISCOSITY INDEX ASTM D2270 88.36

Refractive Index, @25℃ ASTM D1218 To be reported 1.487

CA,% ASTM D3238 To be reported 0.62

CP,% ASTM D3238 To be reported 30.89

CN,% ASTM D3238 To be reported 68.49

Techsol-S

Techsol-2 Techsol-1527 Techsol-2836 i

Techsol-5 Techsol-2836

Major use : Raw material for thinner. Solvent for cleaning.

Major use : Solvent for paint, rubber, metal cleaning and dry cleaning.

Major use : Solvent for paint, wash oil, printing ink, plasticizer.

Major use : Metal working fluid, Special printing ink.

Major use : Solvent for newspaper printing ink. Substitute product for base oil (2cSt).

Aliphatic solvents are paraffin-rich

hydrocarbon disti l lates extracted from

Naphtha, Kerosene and Gasoil .

Those products are used to dissolve or

transport other substances during

industrial processes.

Solvency, evaporation rate and

cleaning power depend on

aromatic contents,

disti l lation range

and flash point.

Applications

Techsol series are applied

extensively to the

production process of

paints, printing inks, dyes,

perfumes, furs, leathers and

agricultural chemicals as well

as cleaning.

Major use : Solvent for paint, rubber and metal cleaning.

Aliphatics

Aliphatics ׀ Aromatics & Solvent Chemicals ׀ A r o m a t i c s & S o l v e n t C h e m i c a l s

8+9

Iso-Paraffin

GS Caltex Iso-Paraffin G/H/L/M are often used in metal working fluid formulations toreduce noise, dissipate pressure and friction, lubricate and carry away heat, flush and remove metal chips and dirt, and to protect from rust and moisture.

GS Caltex Iso-Paraffin G/H/L/M are particularly recommended for applications like: - Punching oil, Metal forming fluids, Evaporative oils and Electro discharge machining (EDM). - Rust preventing oils for which stability at low and high temperature is a key feature.

GS Caltex Iso-Paraffin G/H/L/M are often used in LDPE & EVA polymerization process, etc(Carriers for catalysts, PTFE dispersions).High purity (aromatic and sulfur free), low odor and non polar character make them particularly suitable for many polymerization processes.

GS Caltex Iso-Paraffin G/H/L/M with high purity have good characteristics without compromising safety, health and environmental standards. And they have properties as below.

- Odorless or mild - High purity and stability reduce oxygen , moisture and rust attack - Narrow boiling ranges for controlled drying rate - Low surface tension provides better fluid spreading on metal surfaces - Ultra low sulfur content confers non staining properties - Low pour points reduce risks of haze development in films at low temperatures - Low odor as well as ultra low aromatic content greatly improve workers’ comfort

1. Characteristics

• Metal working fluids

2. Applications

• Polymerization

GS Caltex Iso-ParaffinG H L M

Polymerization Process ○ ○ ○ ○

Industrial Cleaning ○ ○ ○ ○

Metal Working Fluid ○ ○ ○ ○

Spray & Candle ○ ○

Adhesives ○ ○

Paints & Ink ○

Water treatment ○

Techsol-1527

TEST ITEM

TEST METHOD

Iso-Paraffin G Iso-Paraffin H Iso-Paraffin L Iso-Paraffin M

SPEC. RESULT SPEC. RESULT SPEC. RESULT SPEC. RESULT

Dist. IBP, ℃ ASTM D86 160 Min 166 170 Min 180 180 Min 190 210 Min 220

Dist. EP, ℃ ASTM D86 190 Max 178 200 Max 189 210 Max 204 270 Max 258

FLASH POINT,TAG, ℃ ASTM D56 To be repor ted 43 To be

repor ted 54 To be repor ted 61 To be

repor ted 87

TOTAL AROMATICS, wt% UOP 495 0.01 Max 0.00 0.01 Max 0.00 0.01 Max 0.00 0.01 Max 0.00

DENSITY, @15.56℃, kg/L ASTM D4052 0.74~0.77 0.754 0.75~0.78 0.764 0.76~0.79 0.777 0.77~0.81 0.798

ANILINE POINT, ℃ ASTM D611 To be repor ted 82.0 To be

repor ted 82.3 To be repor ted 79.9 To be

repor ted 86.8

APPEARANCE ASTM D4176 PASS PASS PASS PASS PASS PASS PASS PASS

COLOR SAYBOLT ASTM D156 28 Min 30 28 Min 30 28 Min 30 28 Min 30

VISCOSITY, @40℃ cSt ASTM D445 1.050~1.350 1.170 1.250~1.550 1.384 1.350~1.650 1.491 2.700~3.000 2.876

BROMINE INDEX, mg/100g ASTM D2710 20 Max 12 10 Max 3 50 Max 31 100 Max 53

Iso-Paraffin, % 2D GC-FID To be repor ted 100 To be

repor ted 100 To be repor ted 100 To be

repor ted 100

Iso-Paraffin ׀ Aromatics & Solvent Chemicals ׀ A r o m a t i c s & S o l v e n t C h e m i c a l s

10+11

De-Aromatics Base Oil

- Paints and coatings - Adhesives - Process aids - Ink - Dry cleaning - Polymerization - Metal forming - Mining solvent - Aerosol - Lubricants - Water treatment

1) Automotive Oil - Engine Oil (Gasoline/Diesel/LPG) - Transmission Fluid (ATF/MTF) - Gear Oil - Power Steering Oil - Brake Oil

2) Industrial Oil - Hydraulic Fluid - Gear Oil - Compressor Oil - Turbine Oil

3) Specialties - Transformer Oil - Refrigerating Machine Oil - Metal Working Fluid - Process Oil (FDA 21 CFR 178.3620) - White Oil (FDA 21 CFR 172.878) - Textile Oil

Dearomatized Kixxsol series replace traditional solvents such as mineral spirits. Kixxsol series products have ultra-low aromatic content, low odor and low toxicity thus offering greater flexibility in customer's product formulation.

High quality lubricants start with high quality base oils.The newest name in high quality base oils produced with GS Caltex cutting edge technology.Opening a new era in high quality base oil with greater performance and quality competitiveness.

1. Characteristics

1. Characteristics2. Applications

2. Applications

TEST ITEM

TEST METHOD

Kixxsol(D40) Kixxsol-D80 Kixxsol-D100 Kixxsol-D110 Kixxsol-D130

SPEC. RESULT SPEC. RESULT SPEC. RESULT SPEC. RESULT SPEC. RESULT

ANILINE POINT, ℃ ASTM D611 To be repor ted 68.7 To be


repor ted 81.9 To be repor ted 85.5

APPEARANCE ASTM D4176 PASS PASS PASS PASS PASS PASS PASS PASS PASS PASS

DENSITY, @15℃, kg/L ASTM D4052 0.75~0.80 0.780 0.78~0.83 0.812 0.81~0.84 0.823 0.82~0.85 0.827 0.83~0.86 0.834

TOTAL AROMATICS, wt% UOP 495 0.5 Max 0.01 0.5 Max 0.01 0.5 Max 0.04 0.5 Max 0.22 0.5 Max 0.04

COLOR SAYBOLT ASTM D156 28 Min 30.0 28 Min 30.0 28 Min 30.0 28 Min 30.0 28 Min 30.0

Cu-strip(50℃,3h) ASTM D130 1 Max 1A 1 Max 1A 1 Max 1A 1 Max 1A 1 Max 1A

Dist. IBP, ℃ ASTM D86 150 Min 156.1 200 Min 201.7 235 Min. 240.1 255 Min. 261.7 275 Min. 279.0

Dist. EP, ℃ ASTM D86 210 Max 199.0 250 Max 244.7 265 Max. 260.4 285 Max. 278.8 320 Max. 305.0

FLASH POINT,TAG, ℃ ASTM D56 To be repor ted 39.5 To be


repor ted 130.0 To be repor ted 148.0

NEUTRALITY KSM 2012 Neutral Neutral Neutral Neutral Neutral Neutral Neutral Neutral Neutral Neutral

SULFUR, wtppm ASTM D5453 2 Max 0.1 2 Max 0.1 2 Max 0.2 2 Max 0.2 2 Max 0.2

Group II Group III

TEST ITEM

TEST METHOD

2cSt 150N 220N 600N 6cSt 8cSt

Guaranteed Typical Guaranteed Typical Guaranteed Typical Guaranteed Typical Guaranteed Typical Guaranteed Typical

Density @15℃, kg/L ASTM D4052 Repor t 0.8474 Repor t 0.8533 Repor t 0.8637 Repor t 0.8670 Repor t 0.8474 Repor t 0.8474

Color, ASTM ASTM D1500 Max 0.5 L0.5 Max 0.5 L0.5 Max 0.5 L0.5 Max 0.5 L0.5 Max 0.5 L0.5 Max 0.5 L0.5

Viscosity @40℃, mm2/s ASTM D445 Repor t 7.9 Repor t 28.9 Repor t 50.0 Repor t 103.7 Repor t 36.4 Repor t 42.9

Viscosity @100℃, mm2/s ASTM D445 1.9~2.4 2.2 4.8~5.6 5.2 7.0~8.0 7.2 12.0~12.9 12.1 5.5~6.5 6.3 7.0~8.5 7.1

Viscosity Index ASTM D2270 - 83 Min 100 112 Min 98 103 Min 95 107 Min 120 124 Min 120 126

Pour Point, ℃ ASTM D6749 Max -35 -47 Max -12 -17 Max -12 -31 Max -12 -14 Max -15 -16 Max -15 -17

Flash Point, ℃ ASTM D92 Min 150 160 Min 200 226 Min 222 242 Min 246 277 Min 200 240 Min 200 250

NOACK Volatility ASTM D5800 - - - 14.2 - 7.4 - - - - - -

CCS @ -20℃, cP ASTM D5293 - - - 1,365 - 3,896 - - - - - -

Aromatics ASTM D3238 Max 1.0 0.0 Max 1.0 0.0 Max 1.0 0.0 Max 1.0 0.0 Max 1.0 0.0 Max 1.0 0.0

CCR, wt% ASTM D189 Max 0.01 L0.01 Max 0.01 L0.01 - L0.01 Max 0.01 L0.01 Max 0.01 L0.01 Max 0.01 L0.01

TAN, mgKOH/g ASTM D974 Max 0.01 0.005 Max 0.01 0.004 Max 0.01 0.004 Max 0.01 0.004 Max 0.01 0.005 Max 0.01 0.004

De-Aromatics ׀ Aromatics & Solvent Chemicals ׀ Base Oil A r o m a t i c s & S o l v e n t C h e m i c a l s

GS Caltex Corporation

GS Tower, 508, Nonhyeon-ro, GS Caltex Corporation, Tokyo BranchMita Haitsu 202, Shiba 4-5-12,Minato-ku, Tokyo 108-0014, JapanTel : +81-3-6435-3983

GS Caltex China, Shanghai OfficeRm2110, TowerA, City Center of Shanghai100 Zunyi Road, Shanghai, China 200051Tel : +86-21-6115-7295

GS Caltex Singapore Pte. Ltd.8 Temasek Boulevard, #26-03, Suntec City Tower 3, Singapore 038988Tel : +65-6832-1348

Gangnam-gu, Seoul 135-985, KoreaTel : +82-2-2005-6274~6280

Documents

2015 GS Caltex Solvent Catalog